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MCQ Haloalkanes and Haloarenes

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37 views10 pages

MCQ Haloalkanes and Haloarenes

Uploaded by

siva prakasam
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Haloalkanes and

Haloarenes
1. Which of the following dehydrohalogenated to a maximum extent ?

(1)

(2)

JI
(3)

(4)
LA
2. Phenyl magnesium bromide reacts with methanol to give :-
(1) A mixture of anisole and Mg(OH)Br
(2) A mixture of benzene and Mg(OMe)Br
(3) A mixture of toluene and Mg(OH)Br
(4) A mixture of phenol and Mg(Me)Br
A

3. Rate of SN1 reaction is :-


B

(1) S > Q > R > P


(2) S > R > P > Q
(3) P > Q > R > S
(4) S > R > Q > P

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4. Reactivity order of SN1 is :-

(1) P > Q > R > S


(2) R > Q > P > S
(3) Q > P > R > S
(4) Q > P > S > R

5.

JI
In the above reaction, maximum Hofmann product will be obtained, where X is :
(1) –F
(2) –Cl
(3) –Br
(4) –I
LA
6. Which of the following compound undergo hydrolysis most easily:

(1) (3)

(2)
A

(4)

7. Consider the reaction:


CH3—CH2—CH2—Br + NaCN → CH3CH2CH2—CN + NaBr
B

The correct statement is :-

(1) The reaction will be fastest in water


(2) The reaction will be fastest in N, N–dimethylformamide (DMF)
(3) Transition state of SN2 is tetrahedral and sp3 hybridized
⊖
(4) If conc. of alkyl bromide is tripled and conc. of C N is reduced to half rate of SN2 increased by
2 times

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8. Arrange the following group in order of their decreasing leaving ability:

(A) (B)

(C) (D)

(1) A > D > B > C


(2) A > D > C > B
(3) A > B > C > D
(4) D > C > B > A

9. The correct order for E2 reaction with alc. KOH will be:-

JI
(i) (ii) (iii)

(1) i > ii > iii


(2) iii > ii > i
(3) ii > i > iii
LA
(4) iii > i > ii

10. Which of the following compound is most reactive towards SN2 displacement?
(1) CH3CH2CH2CH2–Cl
(2) (CH3)3C–Cl
(3)

(4)
A

11. Which of the following molecule would have a carbon halogen bond most susceptible to
nucleophilic substitution?
(1) 2-Flourobutane
B

(2) 2-Chlorobutane
(3) 2-Bromo butane
(4) 2-Iodobutane

12. Which of the following is secondary alkyl halide?


(1) Isobutyl chloride
(2) Isopentyl chloride
(3) Isopropyl chloride
(4) Neopentyl chloride

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13. Which reaction is least feasible ?

(1)

(2)

(3)

JI
(4)

14. 2-bromopentane is heated with potassium ethoxide in ethanol. The major product obtained is
LA
(1) 1-Pentene
(2) cis-2-pentene
(3) trans-2-pentene
(4) 2-ethoxypentane

15. Alkyl halides react with Mg in dry ether to form


(1) Magnesium halide
(2) Grignard’s reagent
A

(3) Alkene
(4) Alkyne

16. Chloroform for anesthetic purposes is tested for its purity with the reagent
(1) Silver nitrate
B

(2) Lead nitrate


(3) Ammoniacal Cu2Cl2
(4) Lead nitrate

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17. The major product formed in the following reaction is

(1)

(2)

JI
(3)

(4)
LA
18. When phenyl magnesium bromide reacts with tert-butyl alcohol, the product would be
(1) Benzene
(2) Phenol
(3) t-butyl benzene
(4) t-butyl phenyl ether

19. An alkyl halide may be converted in to an alcohol by


(1) Addition
A

(2) Substitution
(3) Dehydrohalogenation
(4) Elimination

20. Hydrolysis of optically active 2-bromobutane gives-


B

(1) d-butan-2-ol
(2) l-butan-2-ol
(3) (dl)-butan-2-ol
(4) either of these

21. The given reaction is an example of


C2H5Br + KCN(aq.) ⎯⎯→ C2H5CN + KBr
(1) Elimination reaction
(2) Nucleophilic substitution
(3) Electrophilic substitution
(4) Redox change

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22. The reaction of ethyl iodide with sodium ethoxide is
(1) An electrophilic substitution reaction
(2) A nucleophilic addition reaction
(3) A nucleophilic substitution reaction
(4) A free radical substitution reaction

23. The unimolecular elimination involves formation of


(1) A free radical
(2) A carbanion
(3) A carbocation
(4) A biradical

24. The hydrolysis of alkyl halides by aqueous NaOH is best termed as

JI
(1) electrophilic substitution reaction
(2) electrophilic addition reaction
(3) nucleophilic addition reaction
(4) nucleophilic substitution reaction
LA
25. The least reactive chlorine is present in
(1) Methyl chloride
(2) Allyl chloride
(3) Ethyl chloride
(4) Vinyl chloride

26. Following reaction is


A

(1) E1
(2) SN1
B

(3) E2
(4) SN2

27.

In the above reaction the attack of a nucleophile would be from which side
(1) On the front side of Cl of C1 carbon
(2) On C2 carbon
(3) On the rear side of Cl of C1 carbon
(4) On C3 carbon

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28. Which reaction gives elimination as a major product ?

(1)

(2)

(3)

(4)

JI
29. Find the major product of the following reaction:
LA
(1)

(2)

(3)
A

(4)

30. Among the choices of alkyl bromide, the least reactive bromide in SN2 reaction is :
B

(1) 1-bromopentane
(2) 2-bromo-2-methylbutane
(3) 1-bromo-3-methylbutane
(4) 1-bromo-2-methylbutane

31. A mixture of 1-chloropropane and 2-chloropropane when treated with alcoholic KOH gives:
(1) prop-1-ene
(2) prop-2-ene
(3) a mixture of prop-1-ene and prop-2-ene
(4) propanol

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32. Methyl bromide reacts with AgF to give methyl fluoride and silver bromide. This reaction is
called:
(1) Fitting reaction
(2) Swarts reaction
(3) Wurtz reaction
(4) Finkelstein reaction

33. Identify the products X and Y in the given reaction,

(1)

JI
(2)

(3)

(4)
LA
34. Which of following compound give same SN1 and SN2 product?

(1)

(2)
A

(3)

(4)
B

35. Order of nucleophilicity in polar protic solvent?


(1) I> Br > Cl > F
(2) F> Cl > Br > I
(3) I> Cl > Br > F
(4) F> I > Br > Cl

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36. Order of nucleophilicity in polar aprotic solvent?
(1) I> Br > Cl > F
(2) F> Cl > Br > I
(3) I> Cl > Br > F
(4) F> I > Br > Cl

37. When alkyl bromide will yield 3-methyl-1-hexene as the major product upon treatment with
potassium t-butoxide in t-butyl alcohol (Solvent) ?

(1)

(2)

JI
(3)

(4)
LA
38.

(1)

(2)

(3)
A

(4)

39. The relative reactivity of


(I) Benzyl chloride (II) p-methoxybenzyl chloride (III) p-nitrobenzyl chloride
B

towards SN1 reaction follows the order :-


(1) I > II > III
(2) II > III > I
(3) II > I > III
(4) III > II > I

40. A primary alkyl halide would prefer to undergo


(1) SN1 reaction
(2) SN2 reaction
(3) -Elimination
(4) Racemisation

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