E Waste Mod2 Notes
E Waste Mod2 Notes
- The evolution of EPR (Extended Producer Responsibility) took place in the context of
sustainable development, focusing on a healthy and safe environment. Most principles have been
articulated from the perspectives of environmental safety and sustainability.
- The EU began discussing environmental protection in the early 1970s, considering principles
such as:
1.Precautionary Principle
2. Prevention Principle
3. Polluter Pays Principle
The introduction of EPR was driven by the awareness that existing environmental policy
measures were insufficient to meet environmental goals (ISWA 2014). EPR was first introduced
by Thomas Lindhqvist, a professor at Lund University in Sweden, in 1990. He discussed this
policy principle to promote environmental improvements in production systems in detail in his
2000 doctoral dissertation.
During the 1990s, several European countries were preparing and implementing policy instruments
for improved management of End-of-Life (EoL) products, based on preventive environmental
strategies promoted by UNEP's Cleaner Production Programme. In 1992, Lindhqvist introduced
the formal definition of EPR and revised it in 2000 to emphasize a life cycle perspective.
EPR is a policy principle aimed at promoting environmental improvements across the entire life
cycle of a product, especially focusing on takeback, recycling, and final disposal.
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EPR applied for waste management and extended for e-waste management
o Shift the burden of managing end-of-life (EoL) products from municipalities and
taxpayers to producers and ultimately consumers.
o Redefine responsibilities and incentives to encourage product redesign and reduce
waste destined for final disposal.
Mandated EPR
• In a mandated EPR framework, producers bear the costs of the entire reverse supply chain,
which includes:
o Awareness and access-to-waste initiatives
o Collection, aggregation, transport, depollution, disposal
o Recycling, recovery, and system monitoring and regulation.
• Waste Prevention:
o Contribute to overall waste reduction efforts.
• Use of Non-Toxic Materials and Processes:
o Promote safer materials in product manufacturing.
• Development of Closed Material Cycles:
o Encourage a circular economy by ensuring materials are reused and recycled.
• Durable Products:
o Promote the creation of longer-lasting products to reduce waste.
• Reusable and Recyclable Products:
o Increase the design and availability of products that can be reused or easily
recycled.
• Increased Reuse, Recycling, and Recovery:
o Enhance systems to ensure materials are reclaimed and recycled.
• Transfer of Waste Management Costs:
o Shift the financial burden of waste management for used products onto producers,
aligning with the Polluter Pays Principle.
Policy Instruments
Regulatory Instruments: These instruments establish legal requirements and standards that
producers must follow:
EPR implemented for e-waste management under the existing regulatory frameworks in
different countries.
Policy principle requires manufacturers to accept responsibility for all stages in a product’s
lifecycle, including EoL management.
There are three primary objectives of the EPR principle:
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1. Manufacturers shall be incentivised to improve the environmental design of their products and
the environmental performance of supplying those products.
2. Products should achieve a high utilisation rate.
3. Materials should be preserved through effective and environmentally-sound collection,
treatment, reuse, and recycling.
The primary reason for holding producers or manufacturers responsible for post-consumer product
management is that most environmental impacts are predetermined during the product's design
phase.
Broad variety in the policy measures to implement EPR, the goals, and achievements.
1. No One-Size-Fits-All Approach:
2. Effectiveness will always depend on national circumstances, conditions, priorities, and waste
streams.
3.EPR implementation is a complex topic bringing many potential challenges; therefore, more
‘practical’ or ‘operational’ aspects to be considered for successful EPR implementation.
Process of implementation
The Process to implement the EPR Concept typically involves the following three stages :
Stage 1: Identifying Policy Instrument:
• An appropriate policy instrument that embodies EPR principles is identified.
• A legislative framework is developed to formalize the concept.
Stage 2: Translating Legislation into an EPR Programme:
• The legislation is operationalized into a detailed EPR programme.
• Operational rules are set, including:
• Mechanisms to finance operations.
• Methods to monitor compliance.
• Evaluation procedures for legal adherence.
Stage 3: Executing the EPR Programme:
• The EPR programme is implemented into a practical working system.
• Effective coordination among stakeholders is required.
Heterogeneous Perspectives:
• Efficiency in EPR implementation is influenced by differing perspectives of
various stakeholders.
• Competing interests may arise between producers and the informal sector,
particularly in e-waste collection and recycling mechanisms.
European Countries:
In EU countries, EPR is implemented following the WEEE Directives. Broadly, four models are
observed:
(i) Producers create one common non-profit entity that collects the necessary funding,
cooperates with local authorities and ensures recycling in the most cost-efficient and
environmental way.
(ii) (ii) ‘Dual model’ adopted –shared responsibilities between the producers and local
authorities (municipalities).A separate collection system assigned to local authorities and
the producers have full operational and financial responsibility over collection, sorting and
recycling.
(iii) ‘Shared model’ – between industry and the local authorities based on common agreements
regarding collection. and
(iv) Every PRO signed up with as many municipalities as needed to fulfil targets according to
market shares.
Asian Countries: Asian countries have formulated their own EPR regulations namely China, India,
Japan, South Korea, Vietnam, Cambodia, and Singapore.
• In a circular economy, preserving resources and creating jobs in the areas of equipment
maintenance, component refurbishment, and remanufacturing, were two major concerns
in some countries, based on which a need had emerged for collection and processing of e-
waste through direct regulation or by providing necessary incentives.
• Thus, the ‘take-back system’ as part of EPR was developed under e-waste laws in Asian
countries following the WEEE Directives.
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• PROs must have a solid financial base to ensure that they can effectively meet their
responsibilities.
• Governments must establish strict authorisation processes to ensure that only financially
secure and reliable PROs are licensed.
Types of PROs:
3. Role of PROs and Competition:Governments need to ensure that producers do not exploit
mechanisms to gain an unfair advantage or evade responsibilities. If national legislation permits
multiple PROs (Producer Responsibility Organizations) to compete for the same waste stream, it
must ensure effective cooperation and avoid jeopardizing policy targets.Lessons from the WEEE
Directive show that combining different systems and financing models can help design incentives
for producers.
6.Ambitious and Clever Policy Targets:EPR’s fundamental goal is to increase waste collection
and recycling. Governments should set clear, qualitative and/or quantitative targets for waste
generation, collection, and recycling. Targets could apply to groups of products or specific
categories.
that ends up in landfills. This results in significant environmental benefits. EPR encourages
innovation in efficient production and packaging, while also creating new business opportunities
in the recycling industry. It had following Challenges
• Legal provisions related challenges
• Governance/enforcement related challenges
• Collection and recycling related challenges
☺Nokia’s Take-Back Success: Nokia is an exception to these challenges, having conducted two
successful take-back campaigns in India.
• In 2009, Nokia set up 1,400 secure bins in its Care Centres and branded retail stores
across four Indian cities, collecting 160 tonnes of e-waste (mainly mobile phones)
in 45 days.
• In 2012, Nokia collected 65 tonnes of mobile phones for recycling.
As part of its environmental responsibility, Nokia planted a tree for every phone collected,
showcasing a successful corporate initiative under EPR. This highlights how businesses can take a
proactive approach, known as the Ecosystem Approach, to fulfil their environmental
responsibility through EPR frameworks.
Risks of compliance and adverse consequences: If detailed guidelines and standards are not
provided for collection and recycling, the goals of resource recovery may suffer.
o Without detailed guidelines and standards for collection and recycling, the goals
of resource recovery may suffer.
o Essential guidelines include:
▪ Awareness among stakeholders about compliance requirements.
▪ Periodic monitoring and mechanisms for compliance.
o In the absence of effective monitoring and evaluation, there is a risk of "paper
trading" in the name of compliance, leading to large-scale e-waste leakage.
2. Targeting a Single Stakeholder:
o If policy instruments focus on just one primary stakeholder, compliance risks
increase.
o Effective compliance involves recycling subsidies, disposal fees, and command
and control standards to manage externalities and ensure efficiency.
o Cost allocation, managing uncertainties, and ensuring education and outreach are
critical to achieving compliance under EPR.
3. Producers' Responsibilities:
o Producers bear the costs of collection, aggregation, transportation, storage, and
recycling. If these costs aren't shared with municipalities or government agencies,
compliance motivation is reduced, especially in developing countries where
informal sectors play a significant role in operations.
o Investment in resource recovery and the management of secondary materials
require careful coordination between formal and informal actors to reduce
compliance risks.
4. Economic Challenges for Producers:
o Coordination among entities is difficult for compliance, especially in establishing
collection centers, ensuring adequate e-waste collection, and setting up effective
incentives for consumers.
o Collection and recycling can become financially unviable, adding extra layers of
administration. Producers are often focused on minimizing compliance costs,
which can lead to cutting corners and lobbying to reduce future collection targets.
In conclusion, compliance risks stem from the lack of clear guidelines, inadequate monitoring,
financial disincentives, and the reluctance of producers to bear the full costs of EPR
implementation, especially in countries with informal sectors playing a key role in waste
management.
The success of PROs depends on how well EPR is carried out and how advanced the e-waste sector
is. Producers need to think long-term and support the development of recycling systems. In many
developing countries, PROs are not common, which affects their performance, especially in
collecting e-waste. A lot of e-waste ends up in the informal sector, which causes problems. PROs,
stuck between producers and the government, often face criticism due to issues with transparency.
Experts also note that problems like identifying producers, illegal e-waste imports, a large informal
sector, and weak regulations make it hard for EPR to work effectively in developing countries.
Impact of EPR:
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The impact of EPR is one of the least explored areas, with very few studies addressing it. In many
countries, the informal sector, which pays for different types of scrap, including e-waste,
dominates. This has made it difficult to properly implement EPR.
Research by the European Commission on 36 case studies of EPR in the EU showed that in most
cases, the costs for collecting, transporting, and treating waste were covered by the EPR system.
However, how much of these costs are covered by producers varies greatly and depends on factors
like the division of responsibilities among stakeholders and the national EPR policies.
In a study by Bhaskar and Turaga (2017), they examined the impact of the E-waste
Management Rules, 2011. They found that while EPR regulations made producers take some
action (like following cheaper parts of the rules), the collection and recycling systems were not
made convenient for consumers to deposit their e-waste at formal centres.
The EPR (Extended Producer Responsibility) in India was first introduced through
the E-waste Management Rules, 2011. These rules outlined the responsibilities for
producers of electrical and electronic equipment (EEE) regarding the handling of e-
waste:
However, the EPR rules did not specify any collection or recycling targets in terms of
weight or item-wise requirements, leaving a gap in effective implementation.
1. Campaign Execution:
o Take-back campaigns for mobile phones were held in 2009 and 2012.
o Nokia promised to plant a tree for every handset collected and to ensure
all old phones and accessories were properly recycled.
o Result: Over 50 tonnes of mobiles were collected, and 60,000 trees were
planted.
2. Campaign Branding:
o The campaign was branded as “Planet ke Rakhwaale” (Protectors of the
Planet).
o This platform brought together a community of people willing to take
action for environmental protection, starting with mobile phone
recycling.
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• Ease and Incentive for Consumers: Consumers need easy access to recycling systems
and proper incentives for recycling in an environmentally responsible way.
• Information Systems: Consumers need access to clear information on:
o Why they should recycle,
o How they should recycle,
o When they should recycle, and
o The benefits of recycling for society and the environment.
• Environmental Awareness: A critical factor is the level of existing environmental
awareness and societal momentum toward environmental protection.
• Recycling Infrastructure: Adequate recycling infrastructure is necessary to support the
collection and proper disposal of e-waste.
• Regulatory Framework: The survey results influenced the government to enact e-waste
management legislation, acknowledging the importance of regulations in fostering
responsible recycling practices.
Effectiveness of EPR Post-Rules 2011 in India: The evaluation of the effectiveness of Extended
Producer Responsibility (EPR) in India after the implementation of the E-waste Management
Rules in 2011 has been analysed by Toxics Link in 2014 and 2015. The study assessed the roles
and responsibilities of producers and regulatory agencies regarding e-waste management.
Evaluation Methodology:
• Brands Analysed: A total of 50 brands were evaluated based on their actions towards
fulfilling their responsibilities under the Rules.
• Data Collection:
o 2014 Study: Used secondary data (websites, helplines).
o 2015 Study: Combined primary data (interviews) with secondary data (websites,
social media, print materials).
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• Performance Ratings:
o 17 companies received a "bad performance" rating.
o 15 companies were rated "not so good."
o 11 companies achieved "fair performance."
o 7 companies scored "good performance."
• Defaulters: Cell phone companies were the biggest offenders, with 17 out of
50 companies rated poorly.
• Performance Ratings:
o 18 companies earned a "bad performance."
o 15 companies were rated "not so good."
o 15 companies achieved "fair performance."
o 3 companies scored "good performance."
• Trends: Many cell phone companies continued to perform poorly.
• Compliance: Companies that adhered to RoHS (Restriction of Hazardous Substances)
scored better. Three companies (Lenovo, Microsoft, Ricoh) maintained their good
performance from 2014.
• Survey Details: Conducted in 2015 with 2,030 respondents from five cities (Delhi,
Mumbai, Chennai, Kolkata, Bengaluru).
• E-Waste Awareness:
o 50% of respondents were familiar with the term e-waste, with the highest
awareness in Mumbai and the lowest in Kolkata, Delhi, and Chennai.
o 66% of respondents had no knowledge of the E-waste Management Rules.
o Among the aware respondents, 12% had heard of the rules but did not know the
details.
• Responsibility for E-Waste Management:
o Respondents believed that all stakeholders (government, producers, consumers)
are responsible for e-waste management.
o Many respondents from Kolkata viewed the government as the only responsible
party.
• Toxicity Awareness:
o 90% of Mumbai respondents were unaware of e-waste toxicity, while
respondents in Chennai were fully aware.
• Sources of Information:
o 34% of respondents relied on newspapers.
o 22% used media.
o 16% consulted the internet.
o 14% learned from friends.
o 11% referred to product manuals.
Disposal Practices:
• Disposal Methods:
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Regional Initiatives:
• States such as Kerala, Odisha, Tamil Nadu, and Telangana have taken initiatives for
implementing EPR under the Rules, 2016.
o
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• PCBs are essential components of almost all e-products and contribute to 30% of
total e-waste.
• Made up of:
o Metals (lead, mercury, etc.)
o Non-metals (ceramics, fiber glass)
o Organic substances (resins)
• Toxicological impact: PCB disposal can lead to harmful chemicals leaching into
the soil, water, and air.
Recycling occupies critical space in the discourse of e-waste management, and is considered to be
the best possible solution. With proper recycling, recoverable resources are collected, which further
save other resources, such as, energy, water, and other material footprints; also boost economy.
Consequently, the reduction in landfill may result into reduction in toxic effects on environment,
and human health. Landfilling has been the least favourable waste management option, mainly
because proper treatment to e-waste reduces release of toxins; lesser the toxicity, lesser the adverse
impacts on environment, and human health.
Recycling Importance:
• A crucial technique in e-waste management with significant benefits for the economy,
environment, and society.
Key Takeaway:
• Production
• Consumption
• Resources
• Climate change
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• Water use
• Toxic emissions
• Use of fossil fuels for heating
• Production and use of electrical appliances which lead to the depletion of fossil
energy, contributing to climate change and pollution.
• Life Cycle Thinking: This approach looks at the entire life cycle of a product,
from production to disposal, and how it impacts the environment and human
health.
• Life Cycle Impact Assessment (LCIA): Evaluates the environmental impacts
associated with all stages of a product's life, especially e-waste.
Key Data:
• Design for Environment (DfE): Simplifying the design of e-products can help reduce
environmental toxicity.
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• Material Extraction:
o 23 MJ (megajoules) of energy is required to extract materials for one mobile
phone.
o Key materials: copper, gold, silver, alongside hazardous metals like lead (Pb),
cadmium (Cd), mercury (Hg), arsenic (As), nickel (Ni), and chromium (Cr).
• Component Manufacturing:
o 120 MJ of energy is consumed in manufacturing components such as integrated
circuits (ICs), capacitors, and resistors.
• Assembly:
o Total energy consumption for assembling a mobile phone is around 2 MJ.
• Packaging and Transportation:
o 30 MJ is assumed for packaging and transportation.
• Material Composition:
• Mobile phones contain various valuable metals such as copper, gold, silver, and some
toxic metals including lead (Pb), cadmium (Cd), mercury (Hg), arsenic (As), nickel
(Ni), and chromium (Cr).
• Rare earth elements: Neodymium, terbium, and dysprosium are also involved in mobile
phone production, with approximately half of the elements in the periodic table being
used (UNEMG 2017: 140).
Carbon Emissions:
• In 2009, 2.7 billion mobile phones in use accounted for around 125 million tonnes of
CO2e, which is 0.25% of global emissions (Berners-Lee 2010).
• Apple iPhone emissions: Produces 70 kg of carbon particles, with 81% of those
emissions occurring during the manufacturing phase.
• 80% of GHG emissions arise from raw material extraction and production.
• 14% of emissions are due to mobile phone usage.
• Only 1% of emissions result from end-of-life (EoL) treatment (ILO 2019).
Computers have become an integral part of modern life, but their production and disposal have
significant environmental consequences. Understanding these impacts is essential for promoting
sustainable practices in the technology sector.
CO2 Emissions
• Manufacturing Emissions:
o Producing one tonne of laptops can emit up to 10 tonnes of CO2.
o Source: PACE and WEF 2019: 13
Resource Consumption
• Waste Generated:
o Each laptop produces approximately 1,200 kg of waste over its entire life cycle.
o In total, 500 million PCs contribute to:
▪ 2,872,000 tonnes of plastics
▪ 718,000 tonnes of lead
▪ 1,363 tonnes of cadmium
▪ 287 tonnes of mercury
o Source: Puckett et al. 2002: 437
Composition of Computers
• Mineral Content:
o An average computer consists of over 30 different minerals, including:
▪ Silica, iron, aluminum, copper, lead, zinc, nickel, tin, selenium,
manganese, arsenic, and cadmium.
o These minerals are extracted from the earth, often through environmentally
damaging practices.
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• The amount of fossil fuels used to produce a computer is approximately nine times the
computer’s weight, indicating a heavy reliance on fossil resources.
There were 83.3 million CRT monitors by 2002 in the market across the globe; they begin to replace
by LCD (liquid crystal display) monitors. There are 14 processes involved in producing, using, and
disposing of a CRT.
The major components of the complete CRT monitor are the tube, plastic casing, and associated
PWB assemblies. The glass components contain approximately 70% lead oxide. The total number
of inventory items for the CRT profile was 770; of them, almost 274 chemicals were classified as
potentially toxic. Overall, 18,000 MJ of energy was reported per CRT monitor produced within the
manufacturing stage; roughly 87% of this can be attributed to the glass manufacturing energy alone.
During production, carbon monoxide released from the production of LPG was the top contributor
at 22%, followed by nitrogen oxides (9%) from electricity generation in the use stage, and by
arsenic (9%) in the production of lead that is eventually used in the CRT glass, and phosphorus
(6%) and fluorides (4%).
The average 14-inch monitor uses a tube that contains an estimated 2.5–4 kg of lead. One CRT
television or computer monitor can contain 4–8 pounds of lead’.
• The environmental footprint of recycling is much smaller than for primary production for
example, aluminium recycling uses only 1/20 of the energy required for primary
production.
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• The environmental impacts per kilogram for the production of precious metals (silver,
gold, platinum, and palladium) is higher than for base metals (iron, copper, aluminium,
lead, and nickel); yet recovery of both types of metals may yield a commercial profit, which
may generate a new scope of work for the new generation.
• An example of PCBs is presented here as a resource and as a hazardous object.
• Among environmental concerns, saving CO2 emission is one of the major considerations.
Therefore, harvesting the resources from used e-products substantially less carbondioxide
emissions than mining in the earth’s crust is preferred as part of e-waste management.
• The below example presents an example of PCB
• First stage of recycling is collection from consumers once the EEE have reached their EoL.
This phase is crucial, as this ensures that the collected e-waste is not mixed with others;
and less dependent on technical solution, and highly influenced by socioeconomic factors,
such as level of awareness and disposal by the users,awareness and integrity of vendors
who provide least cannibalised e-waste, and so on.
• Second stage, de-pollution process includes one or several shredding pro-cesses aimed at
reducing the size of devices and elimination of potentially hazardous components. Once
reduced in size, the shredded components in e-waste undergo mechanical sorting, where
different sorting technologies are applied.
Miliute-Plepiene and Youhanan has provided details about what is achieved at the end of this stage,
and what happened to the residues, as follow, in the pre-processing stage four groups of materials
are extracted:
(i) hazardous materials (e.g. batteries),
(ii) valuable components, which could be reused/resold on the market after dismantling,
(iii) valuable recyclable materials (copper, aluminium, plastics) that will be sold for further material
recovery, and
(iv) residues nonhazardous materials (ceramics, some plastics etc.), that are not suitable for
recycling.
• During the third stage – physical recycling, usually – size reduction takes place through
disassembling, dismantling, chopping, shredding, crushing etc. Also, physical separation
of ferrous and non-ferrous parts takes place vis-à-vis magnetic parts, current connecting
parts, electro-static, etc. For chemical recycling, different methods are employed, such as,
magnetic method for recovering ferrous fractions (iron, nickel, and cobalt), gasification,
melting process, hydro metallurgy and bio-metallurgy.
During refining processes, plastics, fuels, oil-based resins, metals, glass, methanol, filler
materials, and phenolic composites are separated. Non-recyclable materials usually end up in
waste incinerators or landfills.
Hazardous substances may pose significant human health and environmental risks. Toxic
substances can be found within the following types of emissions or outputs:
(i) leachates from dumping activities;
(ii) particulate matter (coarse and fine particles) from dismantling activities;
(iii) fly and bottom ashes from burning activities;
(iv) fumes from mercury amalgamate “cooking,” de-soldering and other burning
activities;
(v) wastewater from dismantling and shredding facilities;
(vi) Effluents from cyanide leaching and other leaching activities. Among them,
most researchers have expressed concern about manual disassembly, and acid-leaching
operations for value of valuable components from wires and cables, CRTs, and PCB.
• A particular hazard associated with the disassembly stage is the possibility of accidental
release and spillage of hazardous substances upon breakage of the shell, such as mercury,
which is found within light sources as well as switches.
• The primary hazards of mechanical treatment methods are associated with the size
reduction and separation steps, which can generate dusts from plastics, metals, ceramics,
and silica.
• Open-air storage raises concerns regarding the possibility of lead and other substances
leaching out into the environment.
• Toxic Link report has mentioned potential hazards of e-waste recycling by informal
sector in India. While breaking and removal of copper yoke CRTs, lead, barium, and
other heavy metals leach into groundwater.
• During PCB disordering and removing computer chips, air emission of these substances
remains in air for long time; and while processing dismantled PCBs, that is, open-air
burning to remove the metals, tin and lead contaminate immediate environment including
surface and ground waters, and brominated dioxins, beryllium, cadmium, and mercury
emissions take place.
• For treating chips and other gold plated components, chemical stripping method (using
nitric and hydrochloric acid), along river banks Hydrocarbons, heavy metals, brominated
substances, etc. are discharged directly into river or left on the banks, which acidifies the
river destroying fish and flora.
• 76% of workers in informal recycling operations in India suffer from respiratory ailments
like asthma, bronchitis, choking, coughing, irritation, breathing difficulties and tremors
among others.
• This is primarily due to primitive and polluting methods of processing e-waste, lack of
safety measures, awareness, and negligence.
• Complex processes are employed for recycling of e-waste in India, such as,
1.manual disassembly,
2.heating PCBs to recover solder and chips,
3.acid extraction of metals rom complex mixtures,
4.melting and extruding plastics, and
5. burning plastics to isolate metals.
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6.Mixtures of concentrated nitric acid and hydrochloric acids are used for the extraction of gold
and copper respectively.
Various volatile compounds of nitrogen and chlorine are known to be emitted during such
processes. The heating of PCB for de-soldering and removal of chips exposes workers to fumes
of metals, particularly those in solder (often lead and tin), and other hazardous substances that can
be potentially released.
• Three most prevalent and hazardous technologies for treating e-waste adversely impact
environment and human health.
1. Incineration
2. Open-air burning
3. Landfilling
Incineration: Incineration is a process of destroying waste through burning. The gases released
during the burning and the residue ash are often toxic, especially when incineration, or co-
incineration of e-waste with neither prior treatment nor sophisticated flue gas purification.
Studies of municipal solid waste incineration plants have shown that copper, which is present in
PCBs and cables, acts as a catalyst for dioxin formation when flame retardants are incinerated.
Open-air burning: Open burning is used mostly for waste disposal, at relatively low temperature;
this is far more polluting than controlled incineration process.
Inhalation of open fire emissions can trigger asthma attacks, respiratory infections, and cause
other problems such as, chest pain, coughing, wheezing, and eye irritation.
Chronic exposure to open fire emissions may lead to diseases such as emphysema (lung condition
that causes shortness of breath) and cancer. Open-air burning of PVC releases hydrogen chloride,
which on inhalation mixes with water in the lungs to form hydrochloric acid, which may lead to
corrosion of the lung tissues, and other respiratory complications.
open fires burn with a lack of oxygen, forming carbon monoxide, which poisons the blood when
inhaled. The residual ash becomes airborne, and is dangerous if inhaled
Landfilling: One of the most widely used methods of waste disposal; it is well known that all
landfills leak. The leachate (cadmium, lead, and mercury) often contain heavy metals and other
toxic substances that contaminate groundwater resources.
Even state-of-the-art landfills, which are sealed to prevent toxins from entering the ground, are
not completely tight in the long-term.
There are three major concerns regarding landfills and its impact on environment are – its leach,
vaporization effects, and its proneness to uncontrollable open fires and release of toxic fumes.
Older landfill sites and uncontrolled dumps pose a much greater danger of releasing hazardous
emissions.
o Samples showed high levels of toxic metals and persistent organic pollutants.
o Similar contamination patterns reported in China, India, and Russia.
2. Increased Toxic Exposure:
o Studies from the 1990s and early 2000s indicated higher exposure to toxic
chemicals from e-waste recycling, affecting both workers and nearby residents.
o Specific toxins include:
▪ Chlorinated dioxins and furans (PCDD/Fs)
▪ Polybrominated diphenyl ethers (PBDEs)
▪ Lead
o Notable observations:
▪ In China, children near recycling sites showed elevated lead levels
compared to those in neighboring areas.
▪ Workers in electronics recycling facilities in Europe exhibited higher
PBDE levels than the general population.
Environmental Contamination
• Toxic metals can accumulate in the soil due to e-waste processing, leading to long-term
environmental issues.
• Examples:
o Cadmium: Adheres to organic matter, can be taken up by plants, entering the
food chain.
o Chromium: Deposits in soil and water, potentially contaminating groundwater.
Table 3.4 summarises with four columns: (i) type of elements16 – halogenated compounds, heavy
and other metals, and others; (ii) occurrence in EEE; (iii) how contamination takes place – which
process and through which part of human body; and (iv) details about toxicity and its impact on
human health. Thus, every element is linked with its occurrence in EEE, how that element is
entering human body, and its impact human health.
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• Safe practices are required for these operations, but they are often neglected in the
informal sector. The real focus of existing studies is on the recycling processes
themselves.
1. Heavy Metals: Lead, mercury, cadmium, and chromium can leach into soil and
water, contaminating ecosystems.
2. Dioxins and Furans: Released during the burning of plastics and cables.
3. Polychlorinated Biphenyls (PCBs): Commonly found in older electronics, these
chemicals are persistent and bio accumulative.
• Workers in informal recycling sites are exposed to toxic fumes during activities
like burning plastics or using acid baths to extract metals.
• Health impacts include:
o Respiratory illnesses: Caused by inhaling toxic fumes and dust.
o Skin and eye irritation: From handling toxic materials without proper
protection.
o Heavy metal poisoning: Long-term exposure to substances like lead can
result in neurological damage and developmental problems in children.
• Informal e-waste recycling practices are widespread and highly polluting in these
countries.
o Open burning of plastic waste: Produces toxic air pollutants.
o Toxic solders: Used in electronics can release harmful fumes.
o River dumping of acids: Acid baths used for extracting metals are often
dumped into water bodies, contaminating local water supplies.