1

Weekly-01 [A] (Solve Sheet)

wm‡jevm: †f±i + ¸YMZ imvqb + mij‡iLv
c~Y©gvb: 400 Set-01 mgq: 2 NÈv

1. GKwU eM©‡ÿ‡Îi `ywU evûi mgxKiY 5x + 12y – 10 = 0 Ges 2. (3, 4) we›`yMvgx GKwU mij‡iLv x A‡ÿi abvZ¥K w`‡Ki m‡½ 45
5x + 12y + 29 = 0; (3, 5) we›`ywU Z…Zxq evûi Dci Aew¯’Z n‡j Gi †KvY Drcbœ K‡i| GB mij‡iLvwU y = 5x + 1 mij‡iLv‡K †h we›`y‡Z †Q`
Aci evû؇qi mgxKiY wbY©q Ki| K‡i, (3, 4) we›`y †_‡K IB we›`yi `~iZ¡ wbY©q Ki|
[Two sides of a square have the equations 5x + 12y – 10 = 0 [A line passing through the point (3, 4) makes an angle of 45
and 5x + 12y + 29 = 0; if the point (3, 5) lies on the third side, with positive direction of the x-axis. Determine the distance
find the equations of the other two sides.] from the point (3, 4) to the point where this line intersects the
line y = 5x + 1.]
mgvavb: D C
mgvavb: Y
(3, 4) B D
5x + 12y – 10 = 0
P

(3, 5) Q
(0, 1)

5x + 12y + 29 = 0 O
C A X
A B [4 marks]
x –3 y–4
awi, ABCD eM©‡ÿ‡Îi AB Ges CD Gi mgxKiY h_vµ‡g 5x + 12y mgvavb: awi, AB †iLvi mgxKiY, cos45 = sin45 = r,
+ 29 = 0 Ges 5x + 12y – 10 = 0| †hLv‡b r nj P(3, 4) †_‡K Q(x, y) Gi `~iZ¡,
AD †iLvi Dc‡i (3, 5) we›`ywU Aew¯’Z| †hLv‡b Q(x, y) nj AB I CD(y = 5x + 1) †iLv؇qi †Q`we›`y|
⸪ AD AB r
x=3+
awi, AD Gi mgxKiY, 2
12x – 5y + k = 0
y=4+
r ⸪ cos45 = 1 
⸪ GwU (3, 5) we›`yMvgx, 2  2
 36 – 25 + k = 0  Q we›`yi ¯’vbv¼, 3 +  4 + 
r r
[5 marks]
 k = – 11  3 2
 AD Gi mgxKiY, ⸪ GwU y = 5x + 1 †iLvi Dci Aew¯’Z,
= 53 +  + 1
12x – 5y – 11 = 0 r r
4+
29 – (– 10) 2  2
AB I DC Gi j¤^ `~iZ¡ = GKK  4 2 + r = 15 2 + 5r + 2
52 + 122
39  – 4r = 12 2
=
13
GKK r=–3 2
= 3 GKK [1 mark]  wb‡Y©q `~iZ¡ = 3 2 GKK| [5 marks]
⸪ BC || AD,
3. A(1, 2) we›`y †_‡K x A‡ÿi abvZ¥K w`‡Ki m‡½ 60 †Kv‡Y bZ
awi, BC Gi mgxKiY 12x – 5y + k1 = 0
mij‡iLv eivei x + y = 6 mij‡iLvwUi `~iZ¡ wbY©q Ki|
(3, 5) we›`y †_‡K 12x – 5y + k1 = 0 Gi Dci j‡¤^i •`N©¨
[Find the distance from the point A(1, 2) to the line x + y = 6
36 – 25 + k1
= along a line inclined at an angle of 60 with the positive
 122 + 52  direction of the x-axis.]
=
k1 + 11 mgvavb:
 13 
k1 + 11
⸪ ABCD GKwU eM©‡ÿÎ, =3
13
 k1 + 11 =  39 n‡j,
N(h, k)
nq k1 = 28 A_ev, k1 = – 50 r
(1, 2)A
 BC Gi mgxKiY, 60
X
12x – 5y + 28 = 0 O
A_ev, 12x – 5y – 50 = 0 [5 marks]
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mgvavb: A(1, 2) we›`yMvgx mij‡iLvwUi mgxKiY, 5. GKwU Av‡jvK iwk¥ , hv (3, 10) we›`y †_‡K wbM©Z nq, 2x + y – 6 = 0
x–1 y–2 mij‡iLv †_‡K cÖwZdwjZ nq Ges Gici (7, 2) we›`yi ga¨ w`‡q AwZµg
=
cos60 sin60 K‡i| AvcwZZ Ges cÖwZdwjZ iwk¥i mgxKiY¸wj wbY©q Ki|
awi, [A light beam, emanating from the point (3, 10) reflects from
mij‡iLvwU x + y = 6 mij‡iLv‡K N(h, k) we›`y‡Z †Q` K‡i| the straight line 2x + y – 6 = 0 and, then passes through the
h–1 k–2 point (7, 2). Find the equations of the incident and reflected
 = = r, †hLv‡b r = AN
1 3 beams.]
2 2
mgvavb: awi, 2x + y – 6 = 0 Gi mv‡c‡ÿ A Ges B Gi cÖwZwe¤^ A(, )
1 3 Ges B(, )
h= r + 1, k = r+2 [5 marks]
2 2
 – 3  – 10
GLb, N(h, k) we›`ywU x + y = 6 mij‡iLvi Dci Aew¯’Z| Zvn‡j, 2
=
1
h+k=6 – 2(6 + 10 – 6)
=
1 3 22 + 12
 r+1+ r+2=6
2 2 =–4
r   = – 5,  = 6
 ( 3 + 1) = 3
2  A  (– 5, 6) [3 marks]
6
r= Y
3+1
6( 3 – 1)
= (– 5, 6)A
2
= 3( 3 – 1) X X
 wb‡Y©q `~iZ¡ = 3( 3 – 1) GKK [5 marks] 2x + y – 6 = 0
B(– 5, 6)
4. `ywU we›`y A Ges B Gi ¯’vbv¼ h_vµ‡g (3, 4) Ges (5, – 2)| we›`y P Gi Y
¯’vbv¼ wbY©q Ki hw` PA = PB Ges PAB Gi †ÿÎdj 10 eM© GKK nq| – 7 –2
Ges 2 = 1
[If the coordinates of two points A and B are (3, 4) and (5, – 2),
respectively. Find the coordinates of any point P if PA = PB – 2(14 + 2 – 6)
=
22 + 12
and area of PAB = 10 square units.]
=–4
mgvavb: awi,
  = – 1,  = – 2
P we›`yi ¯’vbv¼ (x, y)| Zvn‡j PA = PB
 B  (– 1, 2) [3 marks]
A_©vr, PA = PB
 AvcwZZ iwk¥ AB n‡jv:
 PA2 = PB2
10 + 2
 (x – 3)2 + (y – 4)2 = (x – 5)2 + (y + 2)2 y+2=
3+1
(x + 1)
 x – 3y – 1 = 0 ...............(i) A_ev, 3x – y + 1 = 0
GLb, Ges cÖwZdwjZ iwk¥ AB n‡jv:
PAB Gi †ÿÎdj = 10 eM© GKK 2–6
y–6= (x + 5)
1 
x y 1 7 +5
 3 4 1=  10 1
2
5 – 2 1  y – 6 = – (x + 5)
3
 6x + 2y – 26 =  20 A_ev, x + 3y – 13 = 0 [4 marks]
 6x + 2y – 46 = 0 A_ev, 6x + 2y – 6 = 0
 3x + y – 23 = 0 A_ev, 3x + y – 3 = 0 [6 marks] 6. †h wÎfz‡Ri kxl©we›`y¸wj A(5, – 1), B(– 1, 5) Ges C(6, 6) Zvi
x – 3y – 1 = 0 Ges 3x + y – 23 = 0 mgvavb K‡i cvB, cwi‡K‡›`ªi ¯’vbv¼ wbY©q Ki| GQvovI Gi e¨vmva© wbY©q Ki|
x=7 [Find the coordinates of the circumcentre of the triangle
y=2 whose vertices are A(5, – 1), B(– 1, 5) and C(6, 6). Find its
x – 3y – 1 = 0 Ges 3x + y – 3 = 0 mgvavb K‡i cvB, radius also.]
x=1 mgvavb: A(5, – 1) we›`yMvgx;
y=0 25 + 1 + 10g – 2f + c = 0
 P Gi ¯’vbv¼ (7, 2) A_ev, (1, 0) [4 marks]  10g – 2f + c = – 26 ..........(i)
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– we›`yMvgx, 3
 cos + sin =
1 + 25 – 2g + 10f + c = 0 2
 – 2g + 10f + c = – 26 ..........(ii) 1 1 3
 cos+ sin=
C(6, 6) we›`yMvgx, 2 2 2
 
 cos – = cos 
36 + 36 + 12g + 12f + c = 0
 12g + 12f + c = – 72 .........(iii) [6 marks]  4 6 
23  
g=– – = 2n  ; n  I
8 4 6
23 n = 0 Gi Rb¨,
f=–
8
 
c=–3 [3 marks] =±6+4 [⸪ 0   < ]
2 2
e¨vmva©, r = g + f – c = 15, 75 [6 marks]
25 2
= units [1 mark]
8 GKwU mgwØevû wÎfz‡Ri `ywU mgvb evûi mgxKiY h_vµ‡g 7x – y + 3
8.
= 0 Ges x + y – 3 = 0 Ges Gi Z…Zxq evûwU we›`y (1, – 10) Gi ga¨ w`‡q
7. Ggb GKwU mij‡iLvi w`K wbY©q Ki hv (1, 2) we›`yi ga¨ w`‡q
AwZµg Ki‡Z n‡e, hv‡Z Zvi x + y = 4 †iLvi mv‡_ †Q`we›`ywU GB we›`y AwZµg K‡i| Z…Zxq evûi mgxKiY wbY©q Ki|
1 [Two equal sides of an isosceles triangle are given by the
†_‡K 3 6 `~i‡Z¡ _v‡K| equations 7x – y + 3 = 0 and x + y – 3 = 0 and its third side
[Find the direction in which a straight line must be drawn passes through the point (1, – 10). Determine the equation of
through the point (1, 2) so that its point of intersection with the third side.]
1 mgvavb:
the line x + y = 4 may be at a distance 6 from this point.] Y
3
mgvavb: Y A

(0, 4) 6
3
X X
O
A(1, 2)
p–q
X X q
O (4, 0)
E
C
Y
aiv hvK, x A‡ÿi abvZ¥K w`‡Ki mv‡_ D(1, – 10)
B
AZGe, (1, 2) we›`yi ga¨ w`‡q AwZµgKvix mij‡iLvi mgxKiYwUi Y
c¨viv‡gwUªK iƒ‡c nj,
cÖ`Ë wÎfzR ABC Gi `yB mgvb evû AB Ges AC mgxKiYmg~n,
x–1 y–2 1
= = 6 7x – y + 3 = 0 ...............(i)
cos sin 3
Ges x + y – 3 = 0 ................(ii)
6
x=1+ cos †h‡nZz Z„Zxq evûwU D(1, – 10) we›`yi ga¨ w`‡q AwZµg K‡i, Zvi
3
6 mgxKiY nj,
Ges y = 2 + 3 sin [4 marks] y + 10 = m(x – 1) ..............(iii)
mgxKiY (i) Ges (ii) †_‡K AB Ges AC Gi Xvj h_vµ‡g m1 = 7
†h‡nZz 1 + 3 cos 2 + 3 sin we›`ywU x + y = 4 †iLvwU‡Z
6 6
Ges m2 = – 1
Aew¯’Z, ZvB AZGe,
6 6 7–m
1+ cos sin tanABC =
3 3 1 + 7m

tanCB = 
6 1 + m
 (cossin) = 1  1 – m [5 marks]
3
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7–m 1+m 10. 2x + y + 3 = 0 †iLvi mv‡c‡ÿ (1, 2) we›`yi cÖwZwe¤^ KZ?
 =
1 + 7m 1 – m [What is the reflection of the point (1, 2) with respect to the
 (7 – m) (1 – m) = (1 + 7m) (1 + m) line 2x + y + 3 = 0?]
 6m2 + 16m – 6 = 0 mgvavb: cÖ`Ë †iLvi Dci j¤^ Ges (1, 2) we›`yMvgx †iLvÑ
 3m + 8m – 3 = 0
2 x – 2y = 1 – 2  2
 (3m – 1)(m + 3) = 0  x – 2y + 3 = 0
Zv‡`i †Q`we›`y, – 5  5
9 3
1 [3 marks]
m= ,–3
3
9 +1
myZivs, BC Gi mgxKiY `ywU, cÖwZwe¤^ (, ) n‡j, – 5 = 2
1 23
y + 10 = (x – 1) =–
3 5
Ges y + 10 = – 3(x – 1) [5 marks] 3 +2
=
5 2
9. GKwU wÎfz‡Ri ga¨gvi mgxKiY wbY©q Ki, hvi kxl©we›`y¸wji ¯’vbv¼ nj 4
=–
(– 1, 6), (– 3, – 9) Ges (5, – 8)| 5

 cÖwZwe¤^ –  – 
23 4
[Find the equations of the medians of a triangle, the [7 marks]
 5 5
coordinates of whose vertices are (– 1, 6), (– 3, – 9) and
(5, – 8).]
11. g~jwe›`y n‡Z xsin – ysintan = k Ges xsin + ycos = ktan
mgvavb: aiv hvK A(– 1, 6), B(– 3, – 9) Ges C(5, – 8) nj wÎfzR ABC
 
Gi kxl©we›`y| aiv hvK D, E Ges F h_vµ‡g BC, CA Ges AB 2 + kcot 2 †iLvi `~iZ¡ h_vµ‡g 4 Ges 4 5 GKK n‡j, k Gi gvb KZ?
evû¸wj ga¨we›`y| [If the distance of xsin – ysintan = k Ges xsin + ycos =
– 3 + 5  – 9 – 8  
D Gi ¯’vbv¼ 
 2 2  ktan
2
+ kcot
2
lines from the origin is 4 and 4 5 units

A_©vr, 1 – 2 
17 respectively, what is the value of k?]
|k|
mgvavb: =4
 5 – 1  – 8 + 6  sin2
 + sin2tan2
E Gi ¯’vbv¼
 2 2  k2
 2 = 16
A_©vr, (2, – 1) sin (1 + tan2)
–1–3 6–9 k2
Ges F Gi ¯’vbv¼  2  2   2
sin sec2
= 16

 k2cot2 = 16 ............(i)
A_©vr, – 2  – 2
3 [3 marks]
[5 marks]

ktan + cot  
GLv‡b,   2 2
=4 5
sin  + cos 
2 2

ga¨gv AD Gi mgxKiY n‡jv (– 1, 6) Ges 1 – 2  we›`yMvgx †iLvi

17
  2
k2tan + cot 
mgxKiY,  2 2
 = 80
1
17
– –6   2
y–6=
2
(x + 1)  cos 
sin
 
1+1 2 2
 k2 + = 80
 
29
 y – 6 = – (x + 1)
4  sin
2 
cos
2
2
 29x + 4y + 5 = 0
 k2  = 80
1
ga¨gv BE Gi mgxKiY n‡jv, sin cos 
–1+9  2 2
y+9= (x + 3) 2
 k2  = 80  1
2+3 1
 8x – 5y – 21 = 0 2sin  cos  4
CF Gi mgxKiY,  2 2
–3  k2cosec2 = 20.................(ii) [5 marks]
2
+8 (ii) – (i)  k2(cosec2 – cot2) = 20 – 16
y+8=  (x – 5)  k2 = 4
–2–5
 13x + 14y + 47 = 0 [5 marks]  k = ± 2 (Ans.) [2 marks]
 5
12. B(2, 6) I C(x, y) we›`y `yBwU O(0, 0) I A(3, 5) we›`y؇qi ms‡hvM  PQ mij‡iLvi mgxKiY,
mij‡iLvi GKB cv‡k¦© Aew¯’Z| C(x, y) we›`ywU Ggb GKwU we›`y †m‡Ui 3
0
2
m`m¨ hvi cÖwZwU we›`yi Rb¨ OAC = 2OAB. H †mUwU Øviv m„ó y0= (x + 3)
0  ( 3)
mÂvic‡_i mgxKiY wbY©q Ki| 3 1
[Points B(2, 6) and C(x, y) are located on the same side of the line  y = (x + 3) = (x + 3)
6 2
connecting points O(0, 0) and A(3, 5). The point C(x, y) is a  x  2y + 3 = 0 (Ans.) [2 marks]
member of a set of points for which, for every point in the set,
OAC = 2OAB. Determine the equation of the locus created by 14. y + 2 = 0, 3x + 4y = 6 Ges 4x  3y + 12 = 0 †iLvÎq Øviv MwVZ
this set.] wÎfzRwUi AšÍt‡K›`ª (incentre) wbY©q Ki|
mgvavb: C(x, y) [Find the incentre of a triangle formed by the lines y = 2 = 0,
B(2, 6)
3x + 4y = 6 and 4x  3y + 12 = 0.]
mgvavb: wPÎvsKbvbymv‡i,
†iLvÎq Øviv MwVZ wÎfzRwU ABC, hLb
O(0, 0) A(3, 5) AB †iLvwU y + 2 = 0 ......(i)
BC †iLvwU 3x + 4y = 6 ......(ii)
OAB = 3  6 – 2  5 = 8
CA †iLvwU 4x  3y + 12 = 0 ......(iii)
OAC= 3y – 5x
C
cÖkœg‡Z,
C = 2OAB
1 1 x
 |OAC| = 2. |OAB| O
2 2
 | OAC| = 2. |OAB| [6 marks]
B I C we›`y `yBwU O I A we›`y؇qi ms‡hvM mij‡iLvi GKB cv‡k¦© A B
GLb, g~jwe›`ywU (i) I (ii) †iLv؇qi AšÍfz©³ †KvY B Gi AšÍM©Z|
Aew¯’Z e‡j OAB I OAC GKB wPýhy³ n‡e|
 B Gi AšÍwØ©LÛ‡Ki mgxKiY,
 OAC = 2. OAB 
y+2 3x + 4y  6
3y – 5x = 2  8 =
1 32 + 42
 5x – 3y + 16 = 0
 5y + 10 =  3x  4y + 6
BnvB mÂvic‡_i wb‡Y©q mgxKiY| [4 marks]
 3x + 9y + 4 = 0 ......(iv) [4 marks]
Avevi, g~jwe›`ywU (i) I (iii) †iLv؇qi AšÍfz©³ †KvY A Gi AšÍM©Z|
1  A Gi AšÍwØ©LÛ‡Ki mgxKiY,
13. y = 1 +
x+2
eµ‡iLv x-Aÿ‡K P we›`y‡Z Ges y-Aÿ‡K Q we›`y‡Z
y+2 4x  3y + 12
†Q` Ki‡j PQ mij‡iLvi mgxKiY wbY©q Ki| 1
=+
42 + ( 3)2
1
[If the curve y = 1 + intersects the x-axis at point P and  5y + 10 = 4x  3y + 12
x+2
 4x  8y + 2 = 0
the y-axis at point Q, determine equation of the line PQ.]
 2x  4y + 1 = 0 ...........(v) [4 marks]
1
mgvavb: y = 1 + x + 2 ; x Aÿ‡K †Q` Ki‡j y = 0 GLb (iv) I (v) mgxKiYØq‡K mgvavb K‡i cvB,
5 1
1 x= ,y=
1+ =0 6 6
x+2
 wÎfzRwUi wb‡Y©q AšÍt‡K›`ª    
5 1
x+2=1  6 6 [2 marks]
x=3
 P we›`y ( 3, 0) [4 marks] 15. GKwU b`x `wÿY-c~e© w`‡K 10 km/h MwZ‡Z e‡q hv‡”Q| G mg‡q
y Aÿ‡K †Q` Ki‡j x = 0 †Kv‡bv †bŠKv b`xi GK cvi n‡Z Av‡iK cv‡i mivmwi c~e© w`K eivei iIbv
1 n‡jv| †bŠKvi jwä †eM Ges b`x cvi n‡Z mgq wbY©q K‡iv| [†bŠKvi †eM 5
y=1+ km/h Ges b`xi cÖ¯’ 1 km]|
0+2
3 [A river is flowing at constant velocity 10 km/h in south-east
=
2 direction. At that time a boat departs straight to the east. Find
the resultant velocity of the boat & time to cross the river.
A_©vr eµ †iLvwU y Aÿ‡K Q 0 2 we›`y‡Z †Q` K‡i|
3
[4 marks]
[The velocity of boat is 5 km/h & the width of river is 1 km] ]
6
  
mgvavb: DËi (– 2i + j + 8k)
  wbY©q †f±i =  4 
j 22 + 1 + 82
4   
=
69
(
– 2i + j + 8k (Ans.) ) [5 marks]
†bŠKvi †eM
cwðg
 c~e©        
–i  17. 2 wU †f±i †ÿÎ E = 2xi + j + yzk Ges F = xyi – y2j + yzk| (1,
i  
2, 3) we›`y‡Z F Gi j¤^ eivei E Gi Dcvsk wbY©q K‡iv|
b`xi †¯ªvZ        
`wÿY [E = 2xi + j + yzk & F = xyi – y2j + yzk are 2 vector fields. Find
  
–j the component of E to the perpendicular of F at (1, 2, 3) point.]
 mgvavb: 
†bŠKvi †eM, u = 5i km/h
E
 
i – j
b`xi †¯ªvZ, v = 10  
 2 E sin
 
(
= 5 2i – 5 2j km/h[1 marks] )  
F
   E cos
 †bŠKvi jwä †eM, w = 5 2i + 5i – 5 2j km/h [1 marks]
   
  (1, 2, 3) we›`y‡Z, E = 2i + j + 6k [1 marks]
i+j
GLv‡b, b`xi cÖ¯’ eivei GKK †f±i = [1 marks]    
2 Ges F = 2i – 4j + 6k [1 marks]

b`x cvi n‡Z †bŠKvi b`xi †¯ªv‡Zi mv‡c‡ÿ Djø¤^ Dcvsk †Kej mvnvh¨   F
  GLb, F eivei E Gi Dcvsk = E cos   [2 marks]
i+j |F |
Ki‡e| hv b`xi cÖ¯’ eivei GKK †f±i eivei KvR Ki‡e|
2  
E.F F
[2 marks] =    [2 marks]
 b`x cvi n‡Z mvnv‡h¨ Ki‡e b`xi jwä †e‡Mi Dcvsk |F | |F |
4 – 4 + 36   
= w cos
 
=
4 + 16 + 36
2i – 4j + 6k ( )
   i + j  1
{(5 }   9   
= 2 + 5) i – 5 2 j
 2  1 2  1 2 = (
i – 2j + 3k )
[1 marks]
 +
7
 2  2  
F Gi j¤^ eivei E Gi Dcvsk,
5 2+5  
9    
= –5 = 2i + j + 6k – i – 2j + 3k ( ) [2 marks]
2 7
5 5  25  15 
= km/h [3 marks] = i+ j+ k [1 marks]
2 7 7 7
1
 b`x cvi n‡Z mgq jvM‡e = 5   
18. †Kv‡bv GKwU `„p e¯‘ i – 2j + 2k †f±‡ii mgvšÍivj GKwU A‡ÿi
2
mv‡c‡ÿi 3 rad/s †KŠwYK †e‡M Nyi‡Q| D³ Aÿ (2, –3, 1) Mvgx n‡j
2
= hour (Ans.) [2 marks] (1, 3, 4) we›`y‡Z Dnvi •iwLK †eM wbY©q K‡iv|
5
[A rigid body is revolving around an axis with 3 rad/s
  
      
angular velocity and the axis is parallel to i – 2j + 2kvector.
16. P = 2i – 4j + k Ges a = i + 2j | Dfq †f±‡ii mv‡_ j¤^ Ges 4
If the axis goes through (2, – 3, 1), then what is the linear
GKK gvbwewkó †f±i wbY©q K‡iv| velocity of the body?]
         
[P = 2i – 4j + k & a = i + 2j . Find a vector which is mgvavb: †KŠwYK †eM N~Y©b Aÿ eivei KvR Ki‡e A_©vr i – 2j + 2k eivei
perpendicular to both & the magnitude of the vector is 4.]   
     = ||
i j k
mgvavb: P Ges a Gi j¤^ w`K eivei †f±i = 2 –4 1
    
i – 2j + 2k
  =3 2
1 2 0 1 + 22 + 22
[2 marks]
     
= – 2i + j + 8k [5 marks] = i – 2j + 2k
 7
N~Y©b we›`yi mv‡c‡ÿ (1, 3, 4) we›`yi Ae¯’vb †f±i, 21. 2 wU e¯‘ k~‡b¨ †Kv‡bv we›`y n‡Z ci¯úi wecixZ w`‡K h_vµ‡g 3 m/s
      
r = i + 3j + 4k – 2i + 3j – k Ges 4 m/s †e‡M f‚wg eivei wb‡ÿc Kiv nj| hLb MwZi AwfgyL ci¯úi
   j¤^ ZLb Zv‡`i ga¨eZ©x `~iZ¡ KZ?
= – i + 6j + 3k [3 marks]
   [In the air, 2 two objects are thrown in the opposite direction
 •iwLK †eM, v =   r with velocity of 3 m/s and 4 m/s respectively parallel to the
  
 i k horizontal. What is the distance between them when their
= 1 
j
 –2 2 [5 marks] direction of motion is perpendicular?]
–1 6 3 mgvavb: 
   –i i
= – 18i – 5j + 4k (Ans.)
4 m/s 3 m/s
    
19. a I b †f±i؇qi jwä Ges WU †cÖvWv± Df‡qi gvb |a || a †K wظY –j

   
Kiv n‡j bZzb jwä b Gi mv‡_ KZ †Kv‡Y _vK‡e? 1g e¯‘i †eM = ux i – gt j = 3i – 9.8t j [1 marks]
   
   
[The resultant and dot product of a & b is |a |. If a is doubled, 2q Ó Ó = – ux i – gt j = – 4i – 9.8t j [1 marks]

then what is the angle between b & the new resultant vector?]  1   
1g Ó miY = uxti – 2 gt2 j = 3ti – 4.9t j 2
[1 marks]
mgvavb: cÖkœg‡Z,
    1   
| a + b| = | a| 2q Ó Ó = – uxti – 2 gt2 j = – 4ti – 4.9t2 j [1 marks]
  2  2
 | a + b| = | a | [2 marks] e¯‘؇qi MwZi AwfgyL ci¯úi j¤^ n‡j,
     2    
 a .a + a .b + a .b + b .b = a || (3i – 9.8tj ). (– 4i – 9.8tj) = 0
  
(
 2 a + b .b = 0 ) [4 marks] t=
12
9.82
= 0.353 s [3 marks]
  
a †K wظY Kiv n‡j bZzb jwä 2 a + b [2 marks]    


 ga¨eZ©x `~iZ¡ =| 3ti – 4.9t2 j – (– 4ti – 4.9t2 j )|
 bZzb jwä b Gi mv‡_ 90 †Kv‡Y _vK‡e| (Ans.) [2 marks] = 3  0.353 + 4  0.353
= 2.47 m (Ans.) [3 marks]
20. †Kv‡bv mgevû wÎfz‡Ri wZb evû eivei wµqviZ 3 N, 4 N Ges 5 N
gv‡bi wZbwU ej †Kv‡bv e¯‘i Dci wµqv Ki‡Q hvi fi 1 kg| ejÎq xy 22. GKwU †mvjvi c¨v‡bj GKwU evwoi Qv‡` ¯’vwcZ Av‡Q| c¨v‡bjwU‡K
mgZ‡j wµqvkxj n‡j 4 s G e¯‘i miY KZ? (Avw`‡eM = 0 m/s) wb‡¤œv³ we›`y¸wji ¯’vbv‡¼ (wgUv‡i) Ae¯’vbiZ wnmv‡e MY¨ Kiv †h‡Z cv‡i: A
[In an equilateral triangle 3 forces 3 N, 4 N & 5 N are acting (8, 0, 0), B (8, 18, 0), C (0, 18, 8) Ges D (0, 0, 8)| GKwU wbw`©ó mg‡q
on a mass of 1 kg on 3 sides of it. If the forces are acting on xy  1  1  1 
plane, then what is the displacement of the mass in 4 sec? m~‡h©©i w`‡K wb‡`©wkZ GKK †f±i, s = i+ j+ k wn‡m‡e aiv
3 3 3
(Initial velocity = 0 m/s)]  
mgvavb: hvK Ges †mŠi kw³i cÖevn F = 900 s (IqvU cÖwZ eM© wgUvi [W/m2])
wn‡m‡e aiv hvK| c¨v‡bjwU †h cwigvY •e`y¨wZK kw³ Drcv`b Ki‡Z cv‡i,
120
 
Zv †f±i F Ges (hv c¨v‡b‡ji j¤^ †f±i) Gi WU ¸Ydj Øviv wba©vwiZ nq
(Iqv‡U cÖKvwkZ)| Drcbœ •e`y¨wZK kw³ wbY©q K‡iv|
120
60 [A solar panel is mounted on the roof of a house. The panel
may be regarded as positioned at the points of coordinates (in
120 meters) A (8, 0, 0), B (8, 18, 0), C (0, 18, 8), and D (0, 0, 8).
 1  1  1 
wPÎ n‡Z, †f±iÎq ci¯ú‡ii mv‡_ 120 †Kv‡Y wµqv K‡i| Assume unit vector s = i+ j+ k points toward the
3 3 3
 jwäi gvb, R = 30 + 4120 + 5240
Sun at a particular time of the day and the flow of solar
= 3N [5 marks]  
energy is F = 900 s (in watts per square meter [W/m2]). Find
3
 Z¡iY = 1 = 3 m/s2 [2 marks] the predicted amount of electrical power the panel can
 
1 3 produce, which is given by the dot product of vectors F and 
 miY = 2 at2 = 2  42
(unit vector perpendicular to the solar panel) (expressed in
= 8 3 m (Ans.) [3 marks] watts).]
8
mgvavb: c¨v‡b‡ji Dci PviwU we›`y A (8, 0, 0), B (8, 18, 0), (i)2 + (ii)2 
2 2
C (0, 18, 8), D (0, 0, 8) w2 = ( 3) + (5 + 4 3)
c¨v‡b‡ji Z‡j Ae¯’vbKvix 2 wU †f±i, = 3 + 25 + 48 + 40 3
        
AB = B – A = 18j ; AD = D – A = – 8i + 8k [3 marks] = 76 + 40 3
  (ii)  (i) 
 AB  AD
c¨v‡b‡ji j¤^ eivei GKK †f±i,  =   (5 + 4 3)
|AB  AD| tan =
3
1  1 
  = tan–1 4 +
= i+ k [3 marks] 5
[3 marks]
2 2  3
 
 wb‡Y©q kw³ = F .  ej¸‡jvi jwäi gvb = 76 + 40 3
    
= 900 
1 1 1  . 1 1  = 2 19 + 10 3,
i+ j+ k i+ k
 3 3 3  2 2 
hv 1 gv‡bi e‡ji wµqv‡iLvi mv‡_ tan–1 4 +
5
†KvY Drcbœ K‡i|
= 900 
2  3
6 (Ans.) [1 marks]
= 734.84 W (Ans.) [4 marks]
       
24. P = 4i – 3j + 2k Ges Q = 2i + 3j – k Øviv MwVZ mgZ‡ji Dci
23. 1, 2, 3, 4, 5 gv‡bi ej¸‡jv †Kvb mylg lofz‡Ri GKwU †KŠwYK we›`y    

†_‡K h_vµ‡g Aci †KŠwYK we›`y¸‡jvi w`‡K wµqviZ Av‡Q| G‡`i jwä j¤^ GKK vector wU a, b Gi †Kvb gv‡bi Rb¨ R = ai – 2bj + k Gi
wbY©q K‡iv| mgvšÍivj n‡e?

[In a hexagon, from an angular point, forces are acting [A perpendicular unit vector lies to the plane formed by P =
towards other angular points of magnitudes 1, 2, 3, 4, 5.       
4i – 3j + 2k and Q = 2i + 3j – k. What are the values of a and
Calculate the resultant.]    

mgvavb: D C b for which R = ai – 2bj + k is parallel to it?]

  
i k
mgvavb: P  Q = 4 
  j
 –3 2
E 4
3 B 2 3 –1
  
5 2 = i (3 – 6) – j (– 4 – 4) + k (12 + 6)
  
O 1 A = – 3i + 8j + 18k [3 marks]
 
mgvavb: g‡b Kwi, OABCDE mylg lof‚‡Ri OA, OB, OC, OD, OE  PQ
=  
eivei h_vµ‡g 1, 2, 3, 4, 5 gv‡bi ej¸‡jv wµqvkxj Ges G‡`i |P  Q|
jwäi gvb w, hv OA Gi mv‡_  †KvY Drcbœ K‡i|   
– 3i + 8j + 18k
360 =
Zvn‡j, AOE = 180 – 6 = 120 Ges 9 + 64 + 324
  
120 – 3i + 8j + 18k
AOB = BOC = COD = DOE = = 30 =
397
[3 marks]
4
 
GLb OA eivei Dcvsk wb‡q cvB,  I R mgvšÍivj nIqvi kZ©,
w cos = 1 cos0 + 2 cos30 + 3 cos60 + 4 cos90 + 5 cos120 a –2b 1
= =
1 1 –3 8 18
=1+1 3+3 +40+5– + +
2 2 397 397 397
= 3 ........ (i) Ges [3 marks] a –2b 1
 = = [2 marks]
–3 +8 +18
w sin = 1 sin0 + 2 sin30 + 3 sin60 + 4 sin90 + 5 sin120
–3 –1
1 3 3 a= = [1 marks]
=10+2 +3 +41+5 18 6
2 2 2
–4 –2
b= = (Ans.) [1 marks]
= 5 + 4 3 ...... (ii) [3 marks] 18 9
 9
              
25. †f±i a = i + 2j + k, †f±i b = i + j Ges c = j + k Gi mv‡_ 27.    wbY©q K‡iv; †hLv‡b, r = xi + yj + zk.
1
  
  | r |
mgvb †KvY  •Zwi K‡i Ges b I c Gi mv‡_ GKB mgZ‡j Aew¯’Z|  I     
[Find   ; where r = xi + yj + zk.]
1
 Gi gvb KZ?  
          | r |
[The vector a = i + 2j + k, vector b = i + j and c = j + k 
  mgvavb: | r | = x2 + y2 + z2 [1 marks]
form equal angles  and b and c lie in the same plane. What  1
 =   i +  j +  k  2 1 2 2
  
  
| x y z   x + y + z 
are the magnitudes of  and ?] [3 marks]

mgvavb: ab = ac

 r |
  
 cosab = cos ac 1 2xi 2yj 2zk 
=–  3 + 3 3
  2
a .b a .c (x2 + y2 + z2)2 (x2 + y2 + z2)2 (x2 + y2 + z2)2
 = [3 marks] [3 marks]
ab ac
  
2+ 2+ xi + yj + zk
 = =–
2 + 4 + 2. 2 2 + 4 + 2. 2 ( x2 + y2 + z2)3
+2=2+ 
r
= [2 marks] =–
r3
(Ans.) [3 marks]
  
a , b , c GKB mgZ‡j nIqvq,
28. A: K2[HgI4] `ªeY
 2 
1 1 0 = 0 [2 marks] B: KOH `ªeY
0 1 1 X2SO4(aq) + (A + B)  ev`vwg Aat‡ÿc
 (1 – 0) – 2(1 – 0) + (1 – 0) = 0 (a) X+ AvqbwU wewµqvmn kbv³ K‡iv
–2+=0 (b) B `ªe‡Yi cwie‡Z© Ba(OH)2 e¨envi Ki‡j X+ AvqbwU kbv³Ki‡Yi
+=2 RwUjZv e¨vL¨v K‡iv|
 2 = 2 [(i) n‡Z] [A: K2[HgI4] solution
=1 B: KOH solution
  = 1 (Ans.) [3 marks] X2SO4(aq) + (A + B)  brown precipitate
(a) Identify the X+ ion with the reaction.
+
26. GKwU wÎfz‡Ri kxl©we›`y wZbwU (2, 3, 1), (1, 1, 3) Ges (2, 2, 5) n‡j (b) Explain the complication of identifying the X ion if
Ba(OH)2 is used instead of B solution.]
wÎfzRwUi †ÿÎdj wbY©q K‡iv|
mgvavb:
[If three vertices of a triangle are (2, 3, 1), (1, 1, 3) & (2, 2, 5),
(a) DÏxcK Abyhvqx A n‡jv K2[HgI4] Ges B n‡jv KOH
then find the area of the triangle.]
myZivs A I B Gi `ªeY n‡jv †bmjvi `ªeY †hvM Kiv n‡j A¨vwg‡bv
mgvavb: wÎfz‡Ri kxl©we›`y wZbwU h_vµ‡g P (2, 3, 1), Q (1, 1, 3) Ges R
gviwKDwiK Av‡qvWvB‡Wi ev`vgx e‡Y©i Aat‡ÿc c‡o|
(2, 2, 5)
       (NH4)2SO4 + 2KOH  K2SO4 + 2NH3 + 2H2O
 PQ = (1 – 2) i + (1 – 3) j + (3 – 1) k = – i – 2j + 2k 2K2[HgI4] + 2NH3  NH2Hg2I3 + NH4I + 4KI
[2 marks] (ev`vgx Aat‡ÿc) [4 marks]
     
 PR = (2 – 2)i + (2 – 3)j + (5 – 1)k = – j + 4k [2 marks] (b) KOH `ªeY GKwU kw³kvjx ÿvi Ges Rjxq `ªe‡Y m¤ú~Y©iƒ‡c we‡qvwRZ
1   nq| KOH `ªeY (NH4)2SO4 Gi mv‡_ wewµqvq cvwb‡Z `ªeYxq
 wÎfz‡Ri †ÿÎdj = 2 PQ  PR | | K2SO4 `ªeY Drcbœ K‡i| K2SO4 cvwb‡Z `ªeYxq nIqvq cieZ©x
  
 i k A¨vwg‡bv gviwKDwiK Av‡qvWvB‡Wi Aat‡ÿc •Zwi‡Z †Zgb cÖfve
= –1 
j
 –2 2 [3 marks] †d‡j bv| cÿvšÍ‡i KOH Gi cwie‡Z© Ba(OH)2 wb‡j Zv wb¤œiƒ‡c
 0 –1 4 (NH4)2SO4 Gi mv‡_ wewµqv K‡i- (NH4)2SO4 + Ba(OH)2 
1   
=
2
|
(– 8 + 2)i + (0 + 4) j + (1 – k) | BaSO4(s) + 2NH3 + 2H2O
(mv`v Aat‡ÿc)
1   
=
2 |(
– 6i + 4j + k )| Ba(OH)2 `ªeY A¨v‡gvwbqvg mvj‡d‡Ui mv‡_ wewµqv K‡i mv`v e‡Y©i
BaSO4 Gi mv‡_ wewµqvq A¨vwg‡bv gviwKDwiK Av‡qvWvBW (NH2Hg2I3)
1
= 36 + 16 + 1 Gi ev`vgx e‡Y©i Aat‡ÿc c‡o wVKB wKš‘ Zv BaSO4 Gi mv`v
2
1
Aat‡ÿ‡ci Kvi‡Y eY© cwiewZ©Z n‡q RwUj Ae¯’v m„wó K‡i| d‡j
= 53 eM© GKK (Ans.) [3 marks] NH+4 kbv³Ki‡Y RwUjZv †`Lv †`q| [6 marks]
2
10
29. H-cigvYyi cvigvYweK eY©vwj‡Z evgvi wmwi‡R m„ó H I H Gi mgvavb:
K¤úv‡¼i Zzjbv K‡iv| me©wb¤œ kw³wewkó wewKi‡Yi K¤úv¼ wbY©q K‡iv| n2
(i) r1 = (0.529  10–8)   Z 
[Compare the Frequencies of H I H produced in the Balmer
series of the atomic spectrum of the hydrogen atom. 12
K shell e‡j = (0.529  10–8)  cm
Determine the frequency of the radiation with the lowest 3
energy.] = 1.76  10–9 cm
mgvavb: Avgiv Rvwb, = 1.76  10–11 m [3 marks]
c 1 Z2
= =c (ii) En = (– 13.6)  2
  n
= c  RH 2 – 2
1 1 32
 1
n n2  = (– 13.6  1.6  10–19) 
12
= 3  108  1.09678 107 m–1 2 – 2
1 1
= – 1.956  10–17 J
2 3  [4 marks]
2πe2Z
= 4.5699  1014sec–1 (iii) Vn = 
 h n
 K¤úv¼, f = 4.5699  1014 sec–1
2π  (4.8  10–10)2 3
Avgiv Rvwb, = 
6.626  10–27 1
c 1
v= =c = 6.554  108 cms–1
 
= 6.554  106 ms–1 (Ans.)
= c  RH 2 – 2
1 1 [3 marks]
n1 n2 
= 3  108  1.09678 107 m–1 2 – 2
1 1 31. 25C Ges 75C ZvcgvÎvq MA †hŠ‡Mi `ªve¨Zv h_vµ‡g 25 Ges
2 6
–1 50| 20 g MA Gi m¤ú„³ `ªeY‡K 25C ZvcgvÎvq VvÛv Kiv n‡j Kx
= 7.311  10 sec
14

7.311  1014 cwigvY jeY †KjvwmZ n‡e wbY©q K‡iv|

H  H =
4.5699  1014 [At 25C and 75C, the solubility of compound MA is 25 and
= 1.599 ¸Y [7 marks] 50 respectively. If a saturated solution of 20 g MA is cooled to
1
max = 25C, determine the amount of salt that will crystallize.]
RH 2 – 2
1 1
n1 n2  mgvavb: 75C ZvcgvÎvq-
1 Avgiv Rvwb,
=
RH 2 –
1 1  m
n1 (n1 + 1) 2 S=  100
M – m
1 m
 max = cm  50 =  100
109678 2 – 2
1 1 20 – m
2 3   50  20 – 50 m = 100 m
= 6.56  10–7 m (Ans.) [2 marks]
 150 m = 1000
c
fmin =  m = 6.67 g
max [3 marks]

= 4.573  1014 Hz (Ans.) [1 marks]  M = 20 – 6.67 = 13.33 g [1 marks]

25C ZvcgvÎvq
30. GK B‡jKUªbwewkó wØabvZ¥K Avq‡bi B‡jKUªbwU K †k‡j Ae¯’vb K‡i Avgiv Rvwb,
wbDwK¬qvm‡K cwiågY K‡i|
m
(i) wbDwK¬qvm †_‡K B‡jKUªbwU KZ wgUvi `~i‡Z¡ Ae¯’vb K‡i? S=  100
M
(ii) B‡jKUª‡bi kw³i gvb KZ? m
(iii) B‡jKUªbwU KZ ms–1 †e‡M wbDwK¬qvm‡K †K›`ª K‡i cwiågY K‡i?  25 =  100
13.33
[The electron of a doubly positive ion with one electron is  25  13.33 = 100 m
located in the K shell and orbits the nucleus.
 100 m = 333.25
(i) What is the distance of the electron from the nucleus in
meters?  m = 3.33 g [3 marks]
(ii) What is the energy value of the electron? myZivs †Kjv‡mi cwigvY = (6.67 – 3.33)
(iii) What is the speed of the electron in ms–1 as it orbits the = 3.34 g [3marks]
nucleus?]
 11
32. CaF2 Gi Ksp = 4  10–11 mol3 L–3 34. wb¤œwjwLZ †gŠj¸‡jvi B‡jKUªb web¨vm wjL| UvB‡Uwbqvg, †µvwgqvg,
0.05M CaCl2 `ªe‡Y `ªve¨Zv wbY©q K‡iv| Av‡m©wbK, †eªvwgb, wRsK|
[The solubility product (Ksp) of CaF2 is 4  10–11 mol3L–3 [Write the electronic configuration of the following elements:
Determine the solubility in a 0.05 M CaCl2 solution.] Titanium, Chromium, Arsenic, Bromine, Zinc.]
mgvavb: CaCl2  Ca2+ + 2Cl– mgvavb: Ti(22)  1s2 2s2 2p6 3s2 3p6 3d24s2 [2 marks]

0.05 0.05 2  0.05 Cr(24)  1s 2s 2p 3s 3p 3d 4s

2 2 6 2 6 5 1
[2 marks]
As(33)  1s 2s 2p 3s 3p 3d 4s 4p
2 2 6 2 6 10 2 3
[2 marks]
CaF2 ⇌ Ca2+ + 2F–
Br(35) 1s 2s 2p 3s 3p 3d 4s 4p
2 2 6 2 6 10 2 5
[2 marks]
S1 S1 2S1
Zn(30)  1s 2s 2p 3s 3p 3d 4s
2 2 6 2 6 10 2
[2 marks]
CaF2  Ksp = [Ca2+]  [F–]2
= 4  10–11
35. 0.5 L, 0.05 M wmjfvi bvB‡UªU `ªe‡Y KZ MÖvg cUvwkqvg †eªvgvBW
= (S1 + 0.05)  (2S1)2 [4 marks]
2 †`Iqv hv‡e, hv‡Z wmjfvi †eªvgvB‡Wi Aat‡ÿcY ïiæ nq?
4  10–11 = 0.05  4S1
2
[Ksp(AgBr)] = 5  10–13
–11
 4  10 = 0.2S1 [D”PZi NvZ Dcÿv K‡i] [How many grams of Potassium Bromide can be added to 0.5
 S1 = 1.41  10–5 M (Ans.) [6 marks] L of 0.05 M Silver Nitrate just to start the precipitation of
Silver Bromide? [Ksp(AgBr)] = 5  10–13]
33. (K) s AiweUv‡ji B‡jKUªb NbZ¡ Ges †bvW e¨vL¨v Ki| mgvavb: Kip = Ksp
(L) d AiweUvj¸‡jv AvuKvI|  [Ag+][Br–] = Ksp
[(a) Explain the electron density and node of the s orbital.  (0.05)[Br–] = 5  10–13
(b) Draw the d orbitals.]  [Br–] = 10–11 M
mgvavb: n(Br–) = n(KBr) = (10–11  0.5)
(a) 1s, 2s, 3s cÖf…wZ AiweUvj¸‡jv‡Z B‡jKUªb †g‡Ni NbZ¡ †Mvj‡Ki = 5  10–12 mol [4 marks]
–12
g‡a¨ wbDwK¬qv‡mi wbK‡U 1s AiweUv‡ji B‡jKUªb †g‡Ni NbZ¡ me©vwaK  W = 5  10  (39.1 + 79)
A_©vr B‡jKUªb _vKvi m¤¢vebv me©vwaK| wKš‘ wbDwK¬qvm †_‡K `~iZ¡ = 5.9  10–10 g
evovi mv‡_ mv‡_ GKB m¤¢vebv Kg‡Z _v‡K 2s AiweUv‡ji †ÿ‡Î  6 10–10 g (Ans.) [6 marks]

wbDwK¬qvm †_‡K wKQzUv `~‡i B‡jKUªb NbZ¡ e„w× cvq Ges cybivq K‡g
36. Fe(OH)3 Gi m¤ú„³ `ªe‡Y OH– Avq‡bi NbgvÎv 6.6  10–4 g L–1 n‡j,
hvq Ges Avevi †Mvjv‡Ki c„ôfv‡M e„w× cvq| †h ga¨eZ©x ¯’v‡b
Fe(OH)3 Gi Ksp wbY©q Ki|
B‡jKUªb NbZ¡ me©vwaK n«vm cvq Zv‡K ce© ev †bvW (node) e‡j|
[If the concentration of OH– ions in a saturated solution of
[5 marks]
Fe(OH)3 is 6.6  10–4, determine the Ksp of Fe(OH)3]
(b)
mgvavb: Fe(OH)3 ⇌ Fe3+ + 3OH–
z y z z y
y x x 3x
+ – + – –4 –1
+ – [OH ] = 3x = 6.6  10 g L
–

x x x
– + 6.6  10–4
–
+ – + = 17 mol L–1

dxy (l = 2, m = – 2) dyz (l = 2, m = – 1) dzx (l = 2, m = + 1) = 3.88  10–5 mol L–1 [3 marks]

3x
z [Fe3+] = x = 3
z
y y
3.88  10–5
– =
z 3
+ + z z
– = 1.3  10–5 mol L–1
 Ksp = [Fe3+] [OH–]3 [3 marks]
–5 –5 3
d x2 – y 2 (l = 2; m = + 2) d z2 (l = 2; m = 0) = 1.3  10  (3.88  10 )
[5 marks] = 7. 59  10–19 mol4L–4 (Ans.) [4 marks]
12
2–
37. wkLv cixÿvq K+, Cu+, Na+, Ca2+ Gi Lvwj †Pv‡L cixÿv Ges (b) SO3 g~jK mbv³KiY,
†Kvevë eøy Møvm w`‡q cixÿvi eY© e¨vL¨v K‡iv| 2–
wewµqv: SO3 + Br2 + H2O  2HBr + SO4
2–

[Explain the colour of K+, Cu+, Na+, Ca2+ in flame test with 2–
SO4 + BaCl2  2Cl– + BaSO4
naked eye and with cobalt blue glass.]
mgvavb: mv`v [5 marks]

†Kvevë eøy-Møvm w`‡q

Lvwj †Pv‡L wbixÿv wm×všÍ [H2S]H2O
wbixÿv 39. 25C ZvcgvÎvq cvwb I †ebwR‡b H2S Gi eÈb aªæeK
[H2S]C6H6
1. nvjKv †e¸wb wkLv 1. †Mvjvcx jvj/†Mvjvwc
Gi gvb 0.167; GKB ZvcgvÎvq 1.0 wjUvi AvqZ‡bi 0.1 M H2S Gi
†`Lv hvq| wkLv 1. K+ Avqb
Rjxq `ªeY n‡Z GKK av‡c 90% H2S wb®‹vkb Ki‡Z me©wb¤œ KZ AvqZ‡bi
(pale violet) (Pink colour)
†ebwRb `iKvi?
2. bxjvf meyR/Mvp meyR 2. Cu2+ Avqb
2. we‡kl †Kv‡bv eY© †bB| [At 25C, the distribution coefficient of H2S in water and
wkLv †`Lv hvq| (Cu+ Avqb [H2S]H2O
(No special colour)
(bluish green) eY©nxb) benzene is
[H2S]C6H6
with a value of 0.167; at the same
3. †mvbvjx njy` wkLv temperature, how much volume of benzene is required to
3. we‡kl †Kv‡bv eY© †bB|
†`Lv hvq| 3. Na+ Avqb extract 90% of H2S form a 1.0 liter aqueous solution of 0.1 M
(No special colour)
(golden yellow) H2S in a single step?]
4. B‡Ui g‡Zv jvj wkLv [H2S]C H
4. nvjKv meyR wkLv mgvavb: †ebwRb I cvwb‡Z H2S Gi eÈb aªæeK KD = [H S] 6 6
†`Lv hvq| 4. Ca2+ Avqb 2 H2O
(light green) = (0.167)–1
(brick red)
=6 [2 marks]
we‡kl `ªóe¨: 1 Ges 2 bs DËi mwVK †`qvi Rb¨ cÖ‡Z¨KwUi †ÿ‡Î Rjxq `ªe‡Yi AvqZb, V = 1000 mL; †ebwR‡bi AvqZb, S mL
[2 marks] Ges 3 I 4 bs mwVK DËi †`qvi Rb¨ cÖ‡Z¨KwUi †ÿ‡Î
cvwb‡Z H2S Gi Avw` fi = W0 g
[3 marks] cv‡e| W
cvwb‡Z H2S Gi Aewkó fi = W0 Gi 10% = 100
38. (a) Cu++ Ges Zn++ Avq‡bi mbv³Ki‡Yi wbwðZ cixÿvi wewµqv wjL| W V
GLb, 100 = W0 K S + V [3 marks]
(b) GKwU A¤øxq g~j‡Ki wbwðZKiY cixÿvq bgybv `ªe‡Y K‡qK †dvuUv D

1 1000
†eªvwgb cvwb I K‡qK †dvuUv †ewiqvg †K¬vivBW †hvM Kiv n‡jv| Zvici  =
10 6S + 1000
`ªeYwU‡K Mig K‡i †i‡L †`qv n‡jv| K‡qK wgwbU ci mv`v Aat‡ÿc cvIqv
 6S = 9000
†Mj| GwU wK mbv³ Ki‡jv? wewµqv¸‡jv †`LvI|  S = 1500 mL (Ans.) [5 marks]
[(a) Write the reactions that occur in the confirmatory tests
for the identification of Cu2+ and Zn2+ ions.
40. Ca2+ Avq‡bi wkLv cixÿvq m¤ú„³ wewµqv¸‡jv wjL|
(b) In a confirmatory test for an acidic radical, a few drops of
[Write down the reactions involved in the flame test of Ca2+ ion.]
bromine water and a few drops of barium chloride were
added to the sample solution. Then the solution was
mgvavb: CaCO3(s) + 2HCl(l)  CaCl2(s) + CO2(g) + H2O(g)
(Zvc)
heated and allowed to settle. After a few minutes, a white CaCl2(s)  Ca2+(g) + 2Cl–(g)
precipitate was observed. What does this identify? Show
the reactions involved.] Ca2+(g) + 2e–  Ca (g)
mgvavb: kw³ †kvlY
(a) 2CuSO4(aq) + K4[Fe(CN)6](aq)  Cu2[Fe(CN)6] + 2K2SO4(aq) Ca*(g) + nh Ca*(g) (A¯’vqx DÏxwcZ Ae¯’v)
(jvj‡P ev`vwg) 
2ZnSO4(aq) + K4[Fe(CN)6](aq)  Zn2[Fe(CN)6] + 2K2SO4(aq)
(kw³wewKiY)
Ca*(g) Ca (g) + nh (wkLvq B‡Ui g‡Zv jvj eY© m„wó)
(mv`v) [5 marks] [5  2 = 10 Marks]

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