Sec: JR.

IIT_*CO SC WAT-29 Date: 10-11-24

Time: 3 Hrs 2019_P1 Max. Marks: 186
KEY SHEET
MATHEMATICS
1 D 2 C 3 A 4 C 5 ABC
6 ABC 7 ABC 8 AD 9 AD 10 ABC
11 CD 12 ABD 13 12 14 4 15 24

16 9 17 2 18 1

PHYSICS
19 A 20 C 21 A 22 C 23 BC
24 AB 25 BC 26 AB 27 ACD 28 ABCD
29 ABCD 30 BD 31 6 32 3 33 0.9

34 83.75 35 250 36 0

CHEMISTRY
37 C 38 D 39 C 40 C 41 ABC

42 ABCD 43 AD 44 ABD 45 BCD 46 BCD

47 ABCD 48 AB 49 6 50 9 51 3

52 16 53 10 54 3
Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
SOLUTIONS
MATHEMATICS
1. g  x   f  tan x  2tan x  4  2sec2 x  tan x  1
1 1 2

since f 11  x   0  f 1  x  incresing tan 2 x  4   tan x  1  3

2

 tan 2 x  2tan x  4  3  f 1  tan 2 x  2tan x  4   f 1  3  0

 given f  3  0  Hence g  x   0 if  tan x  1  0  x   4 , 2 

1 1

2. g x  f 2  x   f x 2 2

g  x   f   2  x   2x   f   x   2x   2x   f   x   f   2  x  
2 2 2 2

since f   x   0  f   x  is a decreasing function

Hence g  x  is increasing in  , 1   0,1
3. By LMVT for f(x) in x  1, 2
c1  1, 2  where
f  2   f 1
f   c1  
2 1
 f   x   1x  R
 f  2   f 1  1  f  2   2
By LMVT for f  x  in  2,3
c1  1, 2  where
f  2   f 1
f   c1  
2 1
 f  x   1x  R

 f  2   f 1  1  f  2   2
By LMVT for f  x  in  2,3
c2   2,3 where
f  3  f  2 
f   c2  
32
4. We have 2a  a  1  3a  4a  1  a  5a  0
2
2 2
 0  a  5......... A 
 1
also 3a 2  4a  1   3a  1 a  1  0  a   ,   1,   ...... B 
 3
 1
intection of (A) and (B) yields a   0,   1,5 
 3
5. f (or) f(x) be increasing at every point in its domain,
f   x   0x  domain of b

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Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL

 21  4b  b 2  2 2I  4b  b 2
i.e., 3  1   x  5  0  x which is possible if 1   1 ........ i 
 b 1  b  1
 

Here, we must have

21  4b  b2  0
or 21  7b  3b  b2  0
i.e., b   7,3  1 ......... i 
Here, we must have 21  4b  b2  0
or 21  7b  3b  b 2  0
i.e., b   7,3  1 ......... ii 
Het b  1, then the inequality (i) is always true
Let b  1
 21  4b  b2  2b  1
 b  2,  since b  1 ......... iii 
 from  ii  and  iii 
b   7, 1   2,3
2 2 2

6. x  y a
3 3 3
 x, y    a cos3 ,a sin 3  
dy
dy d 3a sin 2  cos 
 
dx dx 3a cos 2  sin 
d
sin 
 y  a sin 3    cos 
 x  a cos3  
xsin   ycos   asin  cos 
2
x y x y
1
 1
a  1
 1
a 3

 x1  3  y1  3
x 3
y 3
    1 1
 a  a 
B  0,a sin  

AB  a 2 cos 2   a 2 sin 2   a

A  a cos ,0 
2h  a cos , 2k  sin  4x 2  4y 2  a 2
2 2 2 1 1
2  2 
x  y a
3 3 3
 x 3  y 3 y  0
3 3

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Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
1 1

y 3
x 3

1 
y   y  y1   1
1  x  x1 
x3 y 3
1
1 1 4 4

x  yy  x  y
3
1
3
1
3
1
3
1

 x  sin x x   0,1
7. A f x  x  sin x  
  x  sin x x  [1,0)
f  x  is continuous are as well as f  1  f 1
but f  x  is non-differentiable at x  0
 tan  x 2  1 ln  x 
  x0
 B f  x    1  x 2 x

 0 x0
 C  f  x   x   x  x   x     x     x 
0 x  I
   x     x   
1 x  I
 Discountious at x  1,0
 D  f  x  satisfies all conditon of Rolle's theorem
8.  a,d  by intermediate mean value theorem, we get
f 0  f  2
 f c, 0c2 ....... i 
2
By L.M.V.T, we get
f 1  f  0   f   c1  , 0  c1  1 ....... ii 
f  2   f 1  f   c 2  ,1  c2  2 ....... iii 
On subtracting equation (ii) from equation (i), we get
f  2   f  0   2f 1  f   c 2   f   c1  ....... iv 
f   c2   f   c1 
f   c3   , for some c3   c1 ,c2 
c2  c1
 f   c2   f   c1    c 2  c1  f   c3   0  f   x   0  ........ v 
from equations  iv  and  v  , we get
f  2   f  0   2f 1  0  f  0   f  2   2f 1
9. Since, graph is symmetrical about (4,0)
 g  4  x   g  4  x 
 g  4  x   g  4  x 
 g  x   g  8  x  ... i 
Now, let g(x) = 2022, then
g  8  x   g  x   2022

JR.*CO SC Pg.No: 4
Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
g 1
 2022   g  2022   8
1

Option (a) is true

Also, x  g 10  x  g 10   0
2

 g  100   0 [given]
g 10   0  D  0
 Option (c) is false
Further, g 10   g  2 
g  x   g  8  x  
If g 10   20, then g  2   20 .
10.  A  Letf  x   sin x; x   a,b 
sin b  sin a
Now, from LMVT  cos c;c   a, b 
ba
sin b  sin a
  cos c  1
ba
 sin b  sin   b  a

 B Let f  x   tan x;0  a  b  so, from LMVT
2
tan b  tan a
 sec2 c; c   a, b 
ba
tan b  tan a
  sec2 c  1
ba
 tan b  tan  b  a
x
 C Let f  x   1  x  1  ; x   0,1
2
1 1 x
So,f   x    0x   0,1 decreases in  0,1
2 1 x
 f  x   f  0  x   0,1
x
 f x  0  1  x 1 
2
Put x  sin9
D Let f  x   e x  x  1; x  0
 f   x   e x  1  0x  0
f  2   f  0
 e 2 1 2  0
11. Let f 1  cos  and g 1  sin 

Then, f  2   cos   g 1 , 
JR.*CO SC Pg.No: 5
Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
g  2   sin    g 1 
Similarly,
f  n  1  cos    g 1  g  2   ...  g  n  
g  n  1  sin    g 1  g  2   ...  g  n  
Also, for all x   0,   ,sin x    x , sin x  x  
So,   g 1  g  2   ...  g  n   
   g 1  g  2   ...  g  n  1  
Hence, h(n) is monotonically
Increasing but bounded.
So, limg  n   0
n 

 limf  n   1
n 

Therefore, lim f  n   g  n    1

n 
 lim f   x   1 and f   x  is strictly decreasing x  1,f   c   1 hence f  x+2   f  x   2x  1,  
x 

12.
 1, x0
 2
13. We have, f  x    x  2x  , 0  x  2
  x  , 2x3

As, f  x  satisifes all the conditions of LMVT in  0,3
Sof  x  satisfies all the conditions of LMVT in 0,3
Now, f  0   f  0   1  
Also, f  2   f  2   f  2   9  2  
and f   2   f   2   6      3
 1, x0
 2
So, f  x    x  2x  1, 0  x  2
 6x  3, 2x3

 By LMVT, there exist some c   0,3
f  3  f  0  4
Such that f   c   c
30 3
Hence,   +2+3 +6c   12
14. 2  f   x   2, apply LMVTin x  1,2 and x   2,4
f  2   f 1  f   x   f  2   2   2, 2
f  2    0, 4 .......1
f  4  f  2
  2,2  f  2   f  4    4, 4
2
JR.*CO SC Pg.No: 6
Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
f  2    4,12 ........ 2 
So from 1 and  2  ,f  2   4
15. y  24x  48

  24  4
6

 11 13 
16. We have f  x   x 2  3 x  1 in  ,
 7 7 
 11 13 
We see that (i) f  x  is continuous in  , , Since it is a polynomial function.
 7 7 
 11 13 
(ii) f   x   2 x  3 which exists in  ,  . Thus all the conditions of Lagrange’s
 7 7
Mean Value Theorem are satisfied.
 11 13 
So there must exist at least one real value c in  ,  such that
 7 7

JR.*CO SC Pg.No: 7
Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL

17. Obviously, f is increasing and g is decreasing in  x1 , x 2  , hence

 
f g   2  2   f  g  3  4   as f is increasing
 g  2  2   g  3  4 
  2  2  3  4 as g decreasing
2  5  4  0
    1   4   0    1, 4 
18. Let g(x) = f(f(x), given f(x) is monotonic and differentiable
 g   x   f   f  x    f   x  , since f  x  is monotonic
 f   x   f   f  x    0 for all x  1
Here, g 1  f  f 1 
 g 1  f 1  1 given,f 1  1 ...... i 
Since, g  x  is increasing for x  1.
1
 g  x   g 1  2 1
x  2x  2
1
  1,i.e. only possible when x  1
 
2
x  1  1
 Number of solutions of f  f  x   is 1

PHYSICS
19. Let piston be displaced ‘x’ towards left than volume decreases and pressure increases
PV = constant {As isothermal}
Let P & V are initial pressure & volume
PV   P  P  V  V 
Pisincreasein pressure
PV  PV  PV  PV  PV  neglect P  N 
 PV  PV
x
P  Ah   PAx  P  PA  Ma a  2 x 
h
By comparing
PA 2 Mh
 T  2
Mh  PA
Method-2
Dimension analysis can be done

JR.*CO SC Pg.No: 8
Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
20. In order to lift the whistle.
Pin A  Pout A  mg
Pin  Pressure inside the cooker
Pout  Pressure outside the cooker
0.1  10
Pin  105  5
 2  105
10
PV  nRT 105  10 103  nR300  0
Initially 10  10  10
5 3
 nR 300......1
Finally 2  10  10  10
5 3
 nRT......... 2 
T = 600 k = 327C
21.

 76  20   P1
96  P1
P1  43  P2 x
P2  76  10  86cm
 96  43  86 x
96
x  48cm
2
4 3 4
22.  P0  gh   r1  P0  r23
3 3
1 10  103  10  3.3   2  103 
5 3

 r23
1 10 5

10 5
 3.3  10 4
  8  10 9
 r23
10
r2 ~ 2.2mm
dV
23. a     dV  dt
dt
Let the pumped out gas pressure dp volume of container = v0 . At one pump dv amount of gas has
bee pumped out.
P 1 t
dp dt 
     P  P0 v0
P0
P 0
V0

JR.*CO SC Pg.No: 9
Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
1  t/v0
(b) Half of the gas has been pump out, pressure will be half e
2
t V0 ln 2
 ln 2  t
v0 
24. 50gm ice  10C
20gm steam 100C
Cal.  0C  1.5gm
Let ainal term. = 100C
Heat rel.  50  0.5  10  50  80  50  1kx100  1.5  1  100
 250  4000  5000  150  9400Cal .
heat rel.  20  540
 10800Cal .
Rcm = 10800-9400=1400
1400 140
Steam rem =   2.6gm
540 54
25. The mean free path of molecules of an ideal gas is given as:
V

2d 2 N
V  Volumeof container
where :
N  No of molecules
Hence with increasing temp since volume of container does not change (closed container), so mean
free path is unchanged.
Average collision time
mean freepath 
 
Vav . avgspeed of molecules 
 avg speed  T
1
Avg coll.time 
T
26. The mean free path of molecules of an ideal gas is given as :
V

2d 2 N
V = Volume of container
Where : N = No of molecules
Hence with increasing temp since volume of container does not change (closed container), so mean
free path is unchanged.
Average collision time
mean free path 
 
Vav  avgspeedof molecules 
avgspeed  T
1
Avg coll.time 
T
Hence with increase in temperature the average collision time decreases.

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Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
27.

73  P  69
P=4
Now PV  nRT
4   H  69   nRT...... i 
75  P1  70
P1  5
Now 5  H  70   nRT.... ii  for (i) & (ii)
4  H  69   5  H  70 
H  74
(ii) 69.5  P  h
PV = Nrt
 h  69.5  74  69.5   nRT .... iii 
from (i) & (iii)
 h  69.5 74  69.5   4   5
20
h  69.5   h  73.94
4.5
(iii) 74 = h + p
Now p  v  nRT   74  h  74  h   5  4  h  69.52
28. Pressure of A & C will be same & Temperature of A & B will same
For “C:
1.5
 4V  27
P0 V 1.5
 P1  0   P1  P0 Tc
0
 9  8 T T
For “C” 14V0 V0 4V0
TV 1  constant 9 9
0.5 P1  P2  P1
 4V0  3T0
T0 V0  TC 
0.5
  TC 
 9  2
For (A)
PV
n
RT
ni  nf
 27  14 
P V 
P0 V0  8 0 
 9 0

RT0 nT
21
T  T0
4
For (B)

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Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
P0 V0 P2  V0

PT0 PT
P0 V0 4P2 V0

T0 21T0
21P0
 P2
4
29. (a) Let the equation of parabola be
dN
 a u  u2 
du
1
1
 dN   u 2 u3 
 0  du du  N0  a  2  3   N0
0
a
  N0  a  6 N0
6
dN
 6 N0 u  u 2 
du

 u dN
2

vrms 
N0
1
 dN 
But  u dN   u   du  a   u  u du
2 2 3 4

 du  0

 1 1  a 6 N0 3N0
 a     
 4 5  20 20 10
3
 vrms  unit
10
2
Since the speed axis shows speed in 10 m/s
3
 vrms   100 m/s
10
1 2 1
(b) KT  mvrms   10  10   3000  15J
3

2 2
30.

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Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
Let the initial pressure be Pin .
Piston B is at rest.
After disturbance, piston B will be at rest again at steady state.
So pressure below it (and everywhere) will be Pin again.
And Pin is not sufficient to hold piston A, so it will fall to the bottom.

Initial equilibrium
 A 2  2A1

Volume conservation:
 A1 40   2A1  x
 x  20
 H  40  20  60
31. At H=0 P  P0
FBD of air element at distance r
Force balance in x direction
 P  dP   P  A 0  dm 2 r
dPA 0   A 0dr  2 r
dPA 0   A 0dr  2 r
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Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
Using PM = RT
PM

RT

dP  2 rdr
 PM  2
dP     dr
 RT 
P m
dP M2
 P  RT 0 r dr
P0

M2 r 2
P  P0e 2RT

32. T  T0  V 2
For 1 mol of a gas PV = RT
or
RT
V
P
Substituting this value in eq. (i) we get
2
 RT  R 2T 2
T  T0      T0   2
 P  P
or
TP 2  T0 P 2  R 2T 2
1
or P   RT  T  T0   ii 

2

Differentiating, we get
dP  1
1  
3
  R  T  T0  2    T  T0  2 


dT  2 
dP
For Pmin' 0
dT
 1
1  
3
O   R  T  T0   T  T  T0  2 

2
 2 

Graph

After solving, T = 2T0

3
 R2T0  2T0  T0 

From eq. (ii) Pmin   2R T0 2

33. Let m1 and m 2 be the masses of upper pistons and S1 & S2 are
their respective areas.
For the lower piston
PS2  m 2g  P0S2  T
T   P  P0  S2  mg ....1
Similarly for the upper piston

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Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
P0S1  T  m1g  PS1
T   P  P0  S1  m1g .... 2 
From (1) & (2)
 P  P0  S1  S2    m1  m 2  g
 P  P0  S  mg
mg
So, P   P0  constant
s
For the gas law, PV = nRT
PV  nRT (P is constant)
 mg 
So,  P0   S   R  T
 S 
1
T   P0S  mg    0.9K
R
PV 76  V
34. Initially moles in two bulbs will be n1  n 2   ...1
RT R  273
After 1 bulb is placed in water bath let pressure be P .
PV PV
n1  ,n2  ... 2 
R  273 R  335
Now, n1  n 2  n1  n2
 From (1) & (2)
2  76V PV  1 1 
 
R  273 R  273 335 
P  83.75cmof Hg
P  84cmof Hg
35. Volume of air in the container before it is placed inside water V1  A  L
When inside water, let the length of air column be x .
Volume of airV2  A  x
Pressure of air P2  P0  g  x  h 
For isothermal condition PV 2 2  PV1 1
P2  A  x  P0 AL

 P0  g  x  h  x   P0 L  105  10 4  x  5   x  105  0.775

10 x  x 2  5 x  7.75  x 2  15 x  7.75  0
 x  0.5m
For required = Buoyancy on 0.5 m length of air column  Axgr  g
 0.05  0.5  103  10  250 N

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Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
36.


 
RT/Mg


s os  e Mgh/RT h dh
 h cm   dm h  0

RT
 dm s s  e

 Mgh/RT Mg
o h dh

0
 
1

xe dx  x ex  e x  c
x
Using:

CHEMISTRY
37.


H 2 / Ni


Opticallyactive Opticallyinactive
38.

Br Cl 
Na /DE


39.
OH

S.L.

O n  Butane

OH 
S.L.
 n  Butane
40. Conceptual
41) (a)  CH 3 2 NH is more basic then CH 3 NH 2
Cl
CH 3
Cl CH 3
(or )
CH 3
CH 3
(b) Major product is
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Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL
( c ) Min mol. Mass 68
C5 H 8 : CH 3  CH  C  CH  CH 3   

(d) Iso octane

42. Hydrogen bonding, Aromaticity

43. Ethane –BP(184.4k); Propane – BP(230.9k); Propane – MP(85.3k);
Ethane –MP(101.0k); 2,2- dimethyl propane-MP (256.4k);
2- methyl butane- MP(113.1k)
(Ref : NCERT Text Book)
44.

C 2 /hv C 2 /hv
C 2 /hv
 1product,  1product,  1product,

45. is not possible by Na/dry ether

46.

47. Conceptual
48. A and B are not feasible
49. Only (vii)is not correct
50. Fact based.
51.

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Narayana IIT Academy 10-11-24_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-29 _KEY& SOL

52.

C 2 /hv
 1 , 3 , 4, 3

2 , 3

53.
D
D D O

D D
D D D D
54. i, ii, v will give cycloalkane as product.

JR.*CO SC Pg.No: 18