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Complex Formation Constants

Complex

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6 views

Complex Formation Constants

Complex

Uploaded by

reza vahdani
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Analytical Chemistry Complex formation constants

Formation Constants of Complex Ions

Complex Ion Equilibrium Kformation


Halide complexes
Al3+ + 6 F-  [AlF6]3- 2.5 x 104
Al3+ + 4 F-  [AlF4]- 2.0 x 108
Be2+ + 4 F  [BeF4]2- 1.3 x 1013
Sn4+ + 6 F-  [SnF6]2- 1.0 x 1025
Cu+ + 2 Cl-  [CuCl2]- 3.0 x 105
Ag+ + 2 Cl-  [AgCl2]- 1.8 x 105
Pb2+ + 4 Cl-  [PbCl4]2- 2.5 x 1015
Zn2+ + 4 Cl-  [ZnCl4]2- 1.6
Hg2+ + 4 Cl-  [HgCl4]2- 5.0 x 1015
Cu+ + 2 Br-  [CuBr2]- 8.0 x 105
Ag+ + 2 Br-  [AgBr2]- 1.0 x 1011
Hg2+ + 4 Br-  [HgBr4]2- 3.0 x 104
Cu+ + 2 I-  [CuI2]- 8.0 x 108
Ag+ + 2 I-  [AgI2]- 1.0 x 1011
Pb2+ + 4 I-  [PbI4]2- 3.0 x 104
Hg2+ + 4 I-  [HgI4]2- 1.9 x 1030
Ammonia complexes
Ag+ + 2 NH3  [Ag(NH3)2]+ 1.6 x 107
Zn2+ + 4 NH3  [Zn(NH3)4]2+ 7.8 x 108
Cu2+ + 4 NH3  [Cu(NH3)4]2+ 1.1 x 1013
Hg2+ + 4 NH3  [Hg(NH3)4]2+ 1.8 x 1019
Co2+ + 6 NH3  [Co(NH3)6]2+ 5.0 x 104
Co3+ + 6 NH3  [Co(NH3)6]3+ 4.6 x 1033
Cd2+ + 6 NH3  [Cd(NH3)6]2+ 2.6 x 105
Ni2+ + 6 NH3  [Ni(NH3)6]2+ 2.0 x 108
Cyanide complexes
Fe2+ + 6 CN-  [Fe(CN)6]4- 1.0 x 1024
Fe3+ + 6 CN-  [Fe(CN)6]3- 1.0 x 1031
Ag+ + 2 CN-  [Ag(CN)2]- 5.3 x 1018
Cu+ + 2 CN-  [Cu(CN)2]- 1.0 x 1016
Cd2+ + 4 CN-  [Cd(CN)4]2- 7.7 x 1016
Au+ + 2 CN-  [Au(CN)2]- 2.0 x 1038
Complexes with other monodentate ligands
Ag+ + 2 CH3NH2  [Ag(CH3NH2)2]+ 7.8 x 106
Cd2+ + 4 SCN-  [Cd(SCN)4]2- 1.0 x 103

Prof. Dr. Thomas Jüstel FH Münster University of Applied Sciences


Analytical Chemistry Complex formation constants

Cu2+ 2 SCN-  [Cu(SCN)2]0 5.6 x 103


Fe3+ 3 SCN-  [Fe(SCN)3]0 2.0 x 106
Hg2+ 4 SCN-  [Hg(SCN)4]2- 5.0 x 1021
Cu2+ 4 OH-  [Cu(OH)4]2- 1.3 x 1016
Zn2+ 4 OH-  [Zn(OH)4]2- 2.0 x 1020
Complexes with bidentate ligands
(en = ethylenediamine)
Mn2+ + 3 en  [Mn(en)3]2+ 6.5 x 105
Fe2+ + 3 en  Fe(en)3]2+ 5.2 x 109
Co2+ + 3 en  [Co(en)3]2+ 1.3 x 1014
Co3+ + 3 en  [Co(en)3]3+ 4.8 x 1048
Ni2+ + 3 en  [Ni(en)3]2+ 4.1 x 1017
Cu2+ + 2 en  [Cu(en)2]2+ 3.5 x 1019
Co2+ + 3 C2O42-  [Co(C2O4)3]4- 4.5 x 106
Fe3+ + 3 C2O42-  [Fe(C2O4)3]3- 3.3 x 1020

Prof. Dr. Thomas Jüstel FH Münster University of Applied Sciences

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