COORDINATION JEE-2021

COMPOUNDS Concept Explorers

Single Correct Answer Type:-
1. Na2S2O3.5H2O is used in photography to
(A) Reduce AgBr to metallic Ag (B) Remove reduced Ag
(C) Remove undecomposed AgBr as a soluble complex
(D) Converts metallic Ag to silver salt
2. Out of [Fe(CN)6]4–, [Ni(CN)4]–2 and [Ni(CO)4]
(A) All have identical geometry. (B) All are paramagnetic.
(C) All are dimagnetic.
(D) [Fe(CN)6]4–is dimagnetic but [Ni(CN)4]–2 and [Ni(CO)4] are paramagnetic
3. Which gives only 25% mole of chloride as AgCl, when reacts with excess AgNO3
(A) PtCl2 . 4NH3 (B) PtCl4 . 5NH3
(C) PtCl4 . 4NH3 (D) PtCl4 . 3NH3
4. Which of the following compound is paramagnetic
(A) Tetracyanonickelate(II) ion (B) Tetraamminezinc(II) ion
(C) Hexaamine chromium(III) ion (D) Diammine silver(I) ion
5. The complexes [Co(NO2) (NH3)5] Cl2 and [Co(ONO) (NH3)5] Cl2 are the examples of
(A) Co-ordination isomerism (B) Ionisation isomerism
(C) Geometrical isomerism (D) Linkage isomerism
6. The complex [Mn(CN)6]4– is
(A) High spin complex (B) Diamagnetic ion
(C) Having magnetic moment 1.73 BM (D) Outer orbital complex
7. Amongst the following, identify the species with an atom in +6 oxidation state
(A) MnO4– (B) Cr(CN)63– (C) NiF62– (D) CrO2Cl2
8. Which of the following statement is incorrect about [Fe(H2O)5NO]SO4
(A) It produce in brown ring test for nitrates (B) Oxidation state of Fe is +1
(C) It exhibits geometrical isomerism (D) Charge on NO is +1
9. Which is/are organometallic compound
(I) Grignard reagent (II) Sodium methoxide (III) Sodium acetylide
(A) II (B) I, III (C) I, II (D) I
10. Which of the following is most likely formula of platinum complex, if 1/4 of total chlorine of the compound
is precipitated by adding AgNO3 to its aqueous solution
(A) PtCl4.6H2O (B) PtCl4. 5H2O (C) PtCl2.2H2O (D) PtCl4.3H2O
11. Which of the following will give maximum number of isomers
(A) [Co(NH3)4Cl2]+ (B) [Ni(en)(NH3)4]+2
(C) [Ni(C2O4)(en)2] (D) [Cr(SCN)2(NH3)4]+
12. In the complexes [Fe(H2O)6] , [Fe(en)3] , [Fe(C2O4)3]3– and [FeCl6]3–, more stability is shown by
3+ 3+

(A) [Fe(H2O)6]3+ (B) [Fe(en)3]3+ (C) [Fe(C2O4)3]3– (D) [FeCl6]3–

13. One mole of the complex compound Co(NH3)5Cl3, gives 3 moles of ions on dissolution in water. One mole
of the same complex reacts with two moles of AgNO3 solution to yield two moles of AgCl (s). The structure
of the complex is
(A) [Co(NH3)3Cl3]. 2NH3 (B) [Co(NH3)4Cl2]Cl.NH3
(C) [Co(NH3)4Cl]Cl2.NH3 (D) [Co(NH3)5Cl]Cl2
14. What are the geometric shape and the oxidation number of the copper atom, respectively, for the complex
ion, [Cu(NH3)4(OH2)2]2+
a) Tetrahedral; + 2 (B) Square planar; – 2 (C) Linear; + 3 (D) Octahedral; + 2
15. Which of the following common shapes (I–IV) can never exist as geometric isomers, regardless of the
identity of the ligands
(I) Linear (II) Square planar (III) Tetrahedral (IV) Octahedral
(A) I only (B) I and II (C) I and III (D) II and IV
Numerical Answer Type:-
16. The ionizable valency of Ni in Ni(CO)4 is
17. Number of chlorides satisifying secondary valency in CoCl3.4NH3
18. The no. of moles of AgCl obtained when excess AgNO3 is added to 250 ml of 0.3M [Cr(NH3)5Cl]Cl2
19. The number of geometrical iosmers for the complex [CoCl2en(NH3)2]+
20. The volume (in mL) of 0.1M AgNO3 required for complete precipitation of chloride ions present in 30 mL of
0.01M solution of [Co(H2O)5Cl]Cl2 as silver chloride is close to
21. The EAN of cobalt in the complex ion [Co(en)2 Cl2]+ is

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22. Crystal field stabilization energy for high spin d4 octahedral complex in terms of Δ0 is
23. The sum of all the donor sites in dimethyl glyoxime, glycinato, diethylene triamine and EDTA is
24. CFSE of a tetrahedral complex of platinum is 400 m-1, What will be the difference in the CFSE of Octahedral
and Tetrahedral complexes of Platinum
25. Oxidation number of Fe in the complex K3[Fe(CN)6]
26. Maximum number of unpaired electrons that can be present in a copper complex with strong field ligands
27. the electronic configuration of metal ion in the ligand field complex [FeCl(CN)4(O2)]—4 is found to be t2g6 eg0
, The bond order of O2 in the complex is
28. The total stereo isomers of the complex [Pt(NH3)2(H2O)2Cl2]—2
29. A complex formed by the combination of calcium ions and ethylene di amine tetra acetate. Number of moles
of calcium ions produced by disulving of one mole of that complex in excess of water is
30. No of non-ionizable Cl ions in the complex CoCl3.5NH3

Multiple Correct Answer Type:-

31. [Co(en)2Cl2]Cl Shows which type of isomerism
(A) Geometrical (B) Ionisation (C) Optical (D) None
32. An example for a double salt is
(A) Cuprammonium sulphate (B) Mohr's salt
(C) Potassium ferricyanide (D) Cobalthexammine chloride
33. Which of the following statement is incorrect
(A) [Cu (NH3)6]2+ is a colourless ion (B) [Ni (CN)4]2– ion has tetrahedral shape
2+
(C) [Zn(H2O)6 ] ion is blue coloured (D) Nickel dimethylglyoxime is red in colour
34. Which of the following have square planar geometry
(A) [NiCl4]–2 (B) [Cu(NH3)4]+2 (C) [Ni(CO)4] (D) ClF4–
35. Pick up the incorrect statement
(A) Cisplatin is a complex of platinum (B) Vitamin B12 is a complex of cobalt
(C) Chlorophyll is a complex of Mangenese (D) Haemoglobin is a complex of iron
36. Which statement is/are correct
(A) [Ni(CO)4] - Tetrahedral, paramagnetic (B) [Ni(CN)4] –2 - Square planar, diamagnetic
(C) [Ni(CO)4] - Tetrahedral, diamagnetic (D) [NiCl4] –2 - Tetrahedral, paramagnetic
37. Which one of the following is expected to not exhibit optical isomerism (en = ethylenediamine)
(A) cis – [Pt(NH3)2Cl2] (B) cis – [Co(en)2Cl2]
(C) trans – [Co(en)2Cl2] (D) trans – [Pt(NH3)2Cl2]
38. Among the following the species having same geometry for central atom are
(A) XeF4 (B) SF4 (C) [NiCl4] 2– (D) [PdCl4] 2–
39. Which of the following is correct about
Tetraamminedithiocyanato-S-cobalt(III) tris(oxalato)cobaltate(III)
(A) Formula of the complex is [Co(NH3)4(SCN)2][Co(ox)3]
(B) It is a chelating complex and show linkage isomerism
(C) It shows optical isomerism
(D) It show geometrical isomerism
40. Which of the following statement(s) is (are) correct?
(A) The complexes [NiCl4]2– and [Ni(CN)4]2– differ in the magnetic properties
(B) The complexes [NiCl4]2– and [Ni(CN)4]2– differ in the geometry
(C) The complexes [NiCl4]2– and [Ni(CN)4]2– differ in primary valencies of nickel
(D) The complexes [NiCl4]2– and [Ni(CN)4]2– differ in the state of hybridization of nickel.

ANSWER KEY

1. C 2. C 3. D 4. C 5. D 6. C 7. D 8. C 9. D 10. D
11. D 12. B 13. D 14. D 15. C 16. 0 17. 2 18. 0.15 19. 2 20. 6
21. 36 22. 0.6 23. 13 24. 500 25. 3 26. 1 27. 15 28. 6 29. 2 30. 1
31. AC 32. B 33. ABC 34. BD 35. ABD 36. BCD 37. AD 38. ACD 39. BCD 40. ABD

SOLUTIONS

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