31 INDIAN ASSOCIATION OF PHYSICS TEACHERS NATIONAL STANDARD EXAMINATION IN CHEMISTRY 2019 -20 Date of Examination: November 24, 2019 Time: 11:00 AM to 1:00 PM. Question Paper Code: 31 Student's Roll No.: Write the question paper code mentioned above on YOUR OMR Answer Sheet (in the space provided), otherwise your Answer Sheet will NOT be assessed. Note that the same Question Paper Code appears on each page of the question paper. Instructions to Candidates: 1. Use of mobile phones, smart watches, and ipads during examination is STRICTLY PROHIBITED. 2. In addition to this question paper, you are given OMR Answers Sheet along with Candidate’s copy. 3. On the Answer Sheet, make all the entries carefully in the space provided, ONLY in BLOCK, CAPITALS as well as by properly darkening the appropriate bubbles. Incomplete/ incorrect/ carelessly filled information may disqualify your candidature. 4. 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CERTIFICATES and AWARDS — Following certificates are awarded by IAPT/ACT to students, successful in the NATIONAL STANDARD EXAMINATION IN CHEMISTRY ~ 2019 () "CENTRE TOP 10%” (ii) “STATE TOP 1%" (iii) “NATIONAL TOP 1%” (iv) “GOLD MEDAL & MERIT CERTIFICATE” to all students who attend OCSC - 2020 at HBCSE All these certificates (except Gold Medal) will be sent/dispatched to the centre in-charge by February 1, 2020 along with the result sheet of the centre. List of students (with centre number and roll number only) having score above MAS will be displayed on the web www.iapt.org.in by December 20, 2019. See the Minimum Admissible score Clause on the Student's brochure on the web. List of Students eligible for National Chemistry Olympiad (INChO — 2020) shall be displayed on wwwaiapt.org.in by December 28, 2019. These students have to register/enroll themselves on the website Olympiads.hbcse.tifr.in of HBCSE Mumbai within the specified period. Useful constants Charge of electron, ¢ =1.602x10-"C Mass of electron, m,=9.1%10"kg Planck's constant, = 6.626x10"*J s Speed of light, ¢ =3.0%10' ms” Avogadro constant, N, = 6.02210" mol~ Molar gas constant, R =0.082L.atmmol"K’ =8.314J mol! K” Faraday’s constant, F = 96487 C mol-* Page 23 INDIAN A‘ NATIONAL S ATION OF PHYSICS TEACHE) rANDARD EXAMINATION IN CHEMISTRY (NSEC 2019-20) TIME: 120 Minutes Max. Marks: 240 Attempt All the Eighty Questions ONLY ONE OUT OF FOUR OPTIONS IS CORRECT (1) The following qualitative plots depict the first, second and third ionization energies (LE) of Mg, Al and K. Among the following, the correct match of LE. and the metal TE mot! (A) X-AL; Y-Mg; Z-K (B) X-Mg ; Y-AL; Z-K (© XMg: ¥-K; Z-Al (D)X-Al; Y-K; ZMg (2) A solid comprises of three types of elements, “P’, “Q” and ‘R’, ‘P* forms an FCC lattice in which *Q* and ‘R? occupy all the tetrahedral voids and half the octahedral voids respectively. The molecular formula of the solid is (A) PQ (B) PQRs CPR (D) P.QR (3) The set in which all the species are diamagnetic is (A) Bs, O:, NO (B) Oz, O2', CO (C)N2, OF, EN~ @) *,NO* Page 33 (4) The structure of compound ‘X’ (CsHsNO) based on the following tests and observations is Reagentis ‘Observation Neutral FeCh, No coloration. TLucas reagent Turbidity NaNOy/HCl at 373 K_[ Yellow oil Ho. on a Ho. on 4 NG ~~ KO HN “ @) © ) (5) Reaction of CcHsMgBr with phenol gives ‘OH @ (8) °. Br © @) (©) The work done (ki) in the irreversible isothermal compression of 2.0 moles of an ideal ‘gas from 1 bar to 100 bar at 25°C at constant external pressure of S00 bar is (A) 2452 (B) 490 (C) 2486 (p)- 490 Page 43 (1) The power and wavelength emitted by a laser pointer commonly used in Power Point presentations are 1.0 mW and 670 nm respectively. Number of photons emitted by this pointer during a presentation of 5 minutes is (A) 101x107 (B) 1.01x10" © 1.6 x10 (D) 1.01 x10 (8) The number of stereoisomers is maximum for (A) [Co(en)s]* (B) [Co(en)2C1Br]~ (© [CoNH):Chy" (D) [Co(NHs).CIBr] (9) Which of the following is NOT correct about hydrides? 1. Saline hydrides are stoichiometric and metallic hydrides are non-stoichiometric IL Bell: is monomeric whereas MgHi is polymeric IIL Hydrides of the elements of Group 13 are electron deficient and those of Group1S are electron rich IV. NaH reacts with water and liberates Hz whereas B21I¢ does not react with water (AD IV only (B) Land U1 (©) Monly (D) Mand Vv (10) Atropine (C1sH2sO3N) is a naturally occurring compound used to treat certain types of poisoning. The degree of unsaturation in atropine is (A) 7 (B)6 ©s (@)4 (11) The compounds *X’ and *Y’ formed in the following reaction are ° H,0" yo = Xt OH (A) hemiacetals with identical physical and chemical properties (B) acetals with identical physical and chemical properties (C) hemiacetals with different physical and chemical properties (D) acetals with different physical and chemical properties Page S3 (12) In which of the following, is a new C-C bond formed in the product? dil. NaOH I. CH;CHO: IL gC C,H,0H —heat_» MI. CO) + CH;MgBr —H20" IV. CyH)+ NaNH, —CHsBr (A) UL and IV (B) Wand UL (© Monly (D) Mand Iv (13) Aqueous solution of slaked lime, Ca(OH)., is extensively used in municipal waste ‘water treatment. Maximum pH possible in an aqueous solution of slaked lime is, (Ky of Ca(OM)2 ~ 5.5 x 107%) (A) 1.66 (B) 8.14 (©) 12.04 (D) 12.34 (14) An electron present in the third excited state of a H atom returns to the first excited state and then to the ground state. If 1 and 2a are the wavelengths of light emitted in these two transitions respectively, ta: Reis ar B59 x1 M21 (15) MnCl.410 (molar mass ~198 g mot") when dissolved in water forms a complex of ‘Mn**, An aqueous solution containing 0.400 g of MnCl:4H20 was passed through. column of a cation exchange resin and the acid solution coming out was neutralized with 10 mL of 0.20 M NaOH. The formula of the complex formed is (A) [Mn@20)sCh] (B) [Mn(H.0).JCh (© [Mn(Hho)scl]cl (D) Na{Mn(H20)sCh} (16) IUPAC name of the following molecule is (A) 4-hydroxyhept2-en-S-yne (B) hept-2-en-5-yn-4-ol (© hept-5-en-2-yn-4-ol (D) 4-hydroxyhept-S-en-2-yne Page 63 (17) The product/s of the following reaction is/are COOH NaOH, C20 heat No, cho CHLOH No, cro S ‘NO, No; No; I 0 Mt IV (A) Tand Il @n om Mv (18) The percentage dissociation of 0.08 M aqueous acetic acid solution at 25°C is (K, of acetic acid at 25°C = 1.8 x 10) (A)2. 92, (BLS 12 Das (19) For which of the following processes, carried out in free space, energy will be absorbed? 1. Separating an electron from an electron IL Removing an electron from a neutral atom TIL Separating a proton from a proton IV. Separating an electron from a proton (A) Tonly (B) Hand IV (© Land IL (D) only (20) Decay of radioisotopes follows first order kinetics. Radioisotope U** undergoes decay to a stable isotope, Th?**, The ratio of the number of atoms of U* to that of Th after three half lives is (a3 (B) 3/4 ou (7 Page 7ay (22) 23) (24) 3 ‘Myoglobin, (Mb), an oxygen storage protein, contains 0.34 % Fe by mass and in each, molecule of myoglobin one ion of Fe is present. Molar mass of ‘Mb (g mol) is (Molar mass of Fe = 55.845 g mot") (A) 16407 (B) 164206 (©) 16425 (D) 164250 ‘The following Ellingham diagram depicts the oxidation of *C’, *CO” and ‘Fe’. Which of the following is correct? I. FeO can be reduced by C below 600 K Il. FeO can be reduced by CO below 600 K IIL, FeO can be reduced by C above 1000 K IV. FeO can be reduced by CO above 1000 K (A) Hand UL (B) and IV (© Tanda (D) Mand IV N*, I, Na’ and Mg* have the same number of electrons. Which of them will have the smallest and the largest ionic radii respectively? (A) Mg and N-(B) Mg” and Na’ (C)N* and Na’ (D)F and N* The reaction of 2,4-hexadiene with one equivalent of bromine at 0°C gives a mixture of two compounds *X” and ‘Y’. If*X’ is 4,5-dibromohex-2-ene, “Y” is (A) 2,5-dibromohex-2-ene _(B) 2,5-dibromohex-3-ene (©) 2,3-dibromohex-3-ene __(D) 3,4- dibromohex-3-ene Page 83 (25) ‘The major product of the following reaction is, 26) en (28) anbyd., AICI, + CHG, heat Excess H.C! CHC, CHCl CHL A) ®B) © @) ‘The kinetic energy of the photoclectrons ejected by a metal surface increased from 0.6 eV to 0.9 eV when the energy of the incident photons was increased by 20 %. ‘The work function of the metal is (A) 0.66 eV (B)072eV (€)0.90ev (0) 030ev An electrochemical cell was constructed with Fe? /Fe and Cd*/Cé at 25°C with initial concentrations of [Fe*'] = 0.800 M and [Ci [C?"] becomes 0.100 M is 0.250 M. The EMF of the cell when Walt cell BW Fe"G@q) / Fe) = 044 cag! dG [-0.40 (A) 0013 V (B)O011V (©) 0.051 V (D) 0.022 V The alkene ligand (x ~CaRs) is both a ‘o" donor and a ‘n’ acceptor, similar to the CO ligand in metal carbonyls, and exhibits synergic bonding with metals. Correct order of C-C bond length in K[PtCls(x -C:R.)] complexes in which R ~H, F or CN is (A)H>F>CN (B)H>CN>F (QCN>F>1 (D)F>1>CN Page 9@) G0) Bb @2) 3 ‘The correct order of CFSE among [Zn(NHs):J"", [Co(NH).]** and [Co(NH: (A) [Co(NHs)e]?" > [Co(NHs)e]** > [Zn(NHs)4]"" (B) [Zn(NH3)-]! > [Co(NHs)6* > [Co(NHs)s}° (©) [Co(NHs)6]** > [Zn(NH3)sF* > [Co(NEB)o}* (D)_ [Co(NHs)e}?* > [Co(NHs)e}?* > [Zn(NHs)aP°* ‘The number of asymmetric carbon atoms in strychnine, whose structure given below is Strychnine ys a4 © 6 7 When acid *X’ is heated to 230°C, along with CO: and 10, a compound *Y” is formed. If “X’ is HOOC(CH:):CH(COOH),, the structure of *Y" is , I ° (A) (B) (©) (D) Number of products formed (ignoring stereoisomerism) in the monochlorination of ethyleyclohexane is (6 Bs Ss (4 Page 10@3) G4) 5) 6) gn 3 ‘Molten NaCl is electrolysed for 35 minutes with a current of 3.50 A at 40°C and 1 bar pressure. Volume of chlorine gas evolved in this electrolysis is (A) 0016 L (B) 0.98 L (98L (D)196L A balance having a precision of 0.001 g was used to measure a mass of a sample of about 15 g. The number of significant figures to be reported in this measurement is (2 3 5 1 Which of the following pairs of compounds can be stable while retaining the identity of each compound in the pair over a period of time? LFeCh,SnCk — TLHgCl, SnCh ML FeCh, SnCl IV. FeCh, KI (A) only (B)Tand IIT (©) Mlonly (D) and Vv Which of the following is correct about the isoelectronic species, Li’ and I" ? 1. His larger in size than Li’ IL Li's a better reducing agent than IT IIL It requires more energy to remove an electron from H than from Li? IV, The chemical properties of the two ions are the same (A) Lonly (B) Wand IIL (CL Mand Iv (D) Land I ‘The major product ‘P” formed in the following sequence of reactions is ° ( Btbylene glycol dry HCI (i) Noone wu, (208% i) 0 ————— P ° D- OO Ss, S, Ss n= N x7 ou (A) 8) © @) Page 11(38) 69) (40) @p (42) (43) 3 Sodium lauryl sulphate (SLS) is a surface active agent, which is adsorbed on water surface. The number of molecules of SLS that can be adsorbed on the surface of a spherical water droplet of diameter 3.5 mm is (cffective area of one molecule of SLS = 4.18 nm?) (A)9.20x 10% —(B) 9.20x 10" (© 1ASx 10% —— D) 3.68 x10 ‘The reaction xX(g) YY (g) + 2Z(g) was carried out at a certain temperature with an initial pressure of X= 30 bar. Initially “Y” and *Z” were not present. If the equilibrium partial pressures of *X”, “Y" and ‘Z° are 20, 5 and 10 bar respectively xy:e is (A) 4:12 (By 212. (yaad (D) Leh ‘The unit of Planck’s constant, *h’, is the same as that of (A) angular momentum —_(B) energy (©) wavelength (D) frequency A commercial sample of oleum (H:8;0;) labeled as “106.5 % oleum’ contains 6.5 g of water. The percentage of free SOs in this oleum sample is (A) 2.88 (B) 28.8 (€) 0.029 (0) 0.28, Among the following, the complex ion/s that will have a magnetic moment of 2.82 BM. is fare 1 [Ni(CO)s] IL (NiCL}* MIL [Ni@O).}°* TV. [N(CN) a} (A) Land IV (B) only (C) Mand I (D) 1H, Mand IV A suboxide of carbon, C302, has a linear structure. Which of the following is correct about C:0:7 1. Oxidation state of all three C atoms is -2 II. Oxidation state of the central C atom is zero IIL, The molecule contains 4 o and 4 7 bonds IV. Hybridization of the central carbon atom is sp* (A) Land IV (B) Mand I (©) Mand IV () Monly Page 123 (44) Among the following, the compounds with highest and lowest boiling points respectively are BINNS Ho TS I 1 MI onO oN IV v (A) Land IL (B) and I (I and IV (D) Hand V (45) Saran wrap, a polymer used in food packaging is a copolymer of 1, I-dichlorocthene and vinyl chloride, In the chain initiation step, 1, I-dichloroethene generates a free radical which reacts with vinyl chloride, Structure of Saran wrap is i (A) (B) ‘ by f © (D) (46) At 25°C Ky of HPO? and HSOs” are 4.8 x10 and 6.3x 10 respectively. Which of the following is correct? (A) HPO¢* is a stronger acid than HSOs" and PO“ is a weaker base than SOs" (B) HPO.* is a weaker acid than HSOs" and PO. is a weaker base than SOs (©) HPO? is a weaker acid than HSO." and PO: is a stronger base than SO. (D) HPO. is a stronger acid than HSOs" and POs* is a stronger base than SO." Page 13,3 (47) The change in internal energy (AU) for the reaction Ha(g) + Bra(g) > 2HBr(0) when 2.0 moles cach of Br: (g) and H2 (g) react is (Ha (g) + Bra (g) > 2HBr (g); AHgeaction=— 109 kJ; AHyap of HBr = 213 kJ mol") (A)- 644 (B) 644k (©3220 (D)- 1070 kt (48) About sea water, which of the following statement/s is/are correct? 1. Frozen sea water melts at a lower temperature than pure ice TI Boiling point of sea water increases as it evaporates IIL Sea water boils at a lower temperature than fresh water IV. Density of sea water at STP is same as that of fresh water (A) Lonly (B) Land I (C)L, Mand I (D) Ml only (49) Which of the following species has one lone pair of electrons on the central atom? (A) CIP: @)Ir (lk (D) SF (50) The alkene *Y” in the following reaction is . . Mes Ww 3 Og A (B) © Page 143 (S1)_ The structure that represents the major intermediate formed in the bromination of toluene is ae HC, Br Ooo “A @) © () (52) The major product *P” formed in the following reaction is (* denotes radioactive carbon) on i) conc. HySOy excess ii) conc.HNO3,, conc. HSO4 iifi) H;O*, heat - P Z ‘OH OH OH NO, No, OH HO" “ ®) OH OH HO Y No, fe OH NO, © 0) Page 153 (53) If the standard electrode potentials of Fe*'/ Fe and Fe*/ Fe are —0.04V and - 0.44 V respectively, then that of Fe''/ Fe" is (A) 0.76 V (B)-0.76V (©0.40V ()-040V (54) Given below is the data for the reaction 2NO (g) No(g) + O2(g) ‘where ‘ky’ and *ks’ are rate constants of the forward and reverse reactions respectively Temperature (K) | ke(mol"! dm’ s+) ky (mol! dm’ ') 1400 0.20 Li x10 1500 13 14x10" ‘The reaction is (A) exothermic and Keg at 1400 K = 3.79 x10-* (B) endothermic and Key at 1400 K = 2.63 x10 (©) exothermic and Keg at 1400 K ~ 1.8 x10° (D) endothermic and Keg at 1500 K = 9.28 x10“ (85) The crystal defect indicated in the diagram below is ©. (A) Frenkel defect (B) Schotky dees (C) Frenkel and Schottky defects (D) Interstitial defect Page 163 (56) In solid state, PCls exists as [PCli]' [PCL] ~. The hybridization of P atoms in this, solid is/are (A) sp'd d= dk") (B) sp’d (d= de") (©) sp? and sp'e? (@ a) (D) sp'd and dsp’ (d= d+) (87) Which of the following compounds have chiral carbon atom/s? QOL OA ‘1 1 1 sit Vv v (A) Tand I (B)1, UI, IV and V (C)U, Vand V (D) Il, Mand IV (58) Lipoic acid with the following structure is a growth factor required by many organisms. Percentages of “S’ and ‘O” in lipoic acid respectively are (atomic masses of *S" and ‘O” are 32.065 g mol"! and 15.999 g mot" respectively) ° = ‘OH Lipoic acid (A) 33.03, 16.48 (B) 31.11, 18.24 (© 31.11, 15.52 (D) 31.42, 15.68 (59) Among the halides NCls (I), PCls (Il) and AsCls (IID, more than one type of acid in aqueous solution is formed with (A) 1, Hand I (B) only (land (D) Wand I Page 173 (60) A helium cylinder in which the volume of gas = 2.24 L at STP (1 atm, 273 K) developed a leak and when the leak was plugged the pressure in the cylinder was seen to have dropped to $50 mm of Hg, The number of moles of He gas that had escaped due to this leak is (A) 0.028 (B) 0.072 (©0972 (D) 0.099 (61) The anhydride of HNOs is (ano (BNO: ON (D) NOs (62) An excess of aqueous ammonia is added to three different flasks (Fs, F2, Fs) containing aqueous solutions of CuSOs, Fes(SOz)s and NiSOs respectively. Which of the following is correct about this addition? 1. A precipitate will be formed in all three flasks TL, Ammonia acts as a base as well as a ligand exchange reagent in F and Fs IIL A soluble complex of NH and the metal ion is formed in Fi and Fs IV. A precipitate will be formed only in F2 (A) Lonly (B)IV only (©) Wand IV () 1, Mand Vv (63) ‘The mass (g) of NaCI that has to be dissolved to reduce the vapour pressure of 100 g of water by 10 % (Molar mass of NaCl ~ 58.5 g mot") is (A) 36.11 g (B) 17.54g (81258 () 361g (64) The reagent/s that can be used to separate norethindrone and novestrol from their mixture is/are on on o Norethindrone Novestrol Lue 1. NaOH MI. NaHCO; IV. NaNIa (aul (B) Land 1V (© Llland mu Page 183 (65) Which of the following is/are electrophilic aromatic substitution reaction/s? a ‘ - - Br, " + (CH),cHe), —— > cH,on WI NH; Vv NaN (A) II, Mand IV (B)II and I (C)LM and — (D) only (66) All four types of carbon (1',2"3° and 4’) are present in u ™ v (A) 1, Mand 11 (B) IL, Mand IV (©)1, Mand IV (D) I and I Page 193 (67) The normal boiling point and AHvap of a liquid 'X’ are 400 K and 40 kJ mol respectively. Assuming AHvp to be constant, which of the following is correct? 1, ASvap >100 JK mol"! at 400 K and 0,5 atm IL, ASvap = 100 JK" mot" at 400 K and 1 atm TIL. ASyap < 100 J Kol" at 400 K and 2 atm TV. ASvap = 100 kJ K"! mot" at 400 K and 1 atm (A) Mand IV (B) Honly (©) Land IIL (D) Ll and IV (68) About the energy level diagram given below, which of the following statement/s is/are correct? Energy ‘Reaction coordinate I. The reaction is of two steps and ‘R’ is an intermediate I, The reaction is exothermic and step 2 is rate determining IIL. *Q' is an intermediate and ‘R’ is the transition state for the reaction M > Q IV, “P’ is the transition state for the reaction Q > N (A) land 1V (B)L,MandIV (©), Wand IV (D) only (69) Mercury is highly hazardous and hence its concentration is expressed in the units of ppb (micrograms of Hg present in 1 L of water). Permissible level of Hg in drinking water is 0.0335 ppb. Which of the following is an alternate representation of this concentration? (A) 3.35 x 10°? mg dr (B) 3.35 x10-> mg dm (©)335x 10S mg mr? (D) 3.35 x10 gL Page 20(70) ay (72) (73) 3 Which of the following is correct? 1. Sodium (Na) is present as metal in nature IL, NaxO2 is paramagnetic TIL NaO: is paramagnetic IV. Na reacts with N2 to form NasN (A)IMonly (8) and IV (©)1, Mand IV (D) 01, Mand TV ‘The F-X- F bond angle is the smallest in (X is the central atom) (A) CE: (BNF: (or. (D) XeF- The correct sequence of reactions which will yield 4-nitrobenzoic acid from benzene is (A) CHACI; HINO; /F2S05; KMnOvOTt (B) HNOs/HS04; CHsCVAICL; KMn0vOH (©) CHsCVAICh; KMnOJOH"; HNOs/H,SOs (D) CHsCVAICh; HINOs /H2S0s; KMn0vOH ‘Two isomeric hydrocarbons “X’ and *Y* (CsH.), give the same product (CeHs0) on catalytic hydration with dilute acid, However, they form different products but with same molecular formula (CsHsBre) when treated with excess bromine. *X? and ‘Y? are | “ AL WQV~ e ZR” “ ®) Sw + eo © © Page 213 (74) Morphine, a pain killer is basic with the molecular formula C17HisNOs. The conjugate acid of morphine is (A) CinNOs' —(B)CryHyNOs— (C) CryHyNO—(D) CrpHLaoNOs' (75) ‘The correct IUPAC name of the compound, [Pt(py)é][P'(Br)4] is (A) tetrapyridineplatimum(I1) tetrabromidoplatinate (I) (B) tetrabromidoplatinum(1V) tetrapyridineplatinate(I1) (C) tetrabromidoplatinate(II) tetrapyridineplatinum({l) (D) tetrapyridineplatinum(IV) tetrabromidoplatinate(IV) (76) Which atom/s will have a 5! charge in the following molecule? to 1 Mm v (A) Land IML (B) only (©) Mand i (D) Mand IV (77) ‘The most acidic hydrogen in the following molecule is 9. oO (ar @n om ov (78) In which of the following species the octet rule is NOT obeyed? Lin I. N20 ML OF, IV.NO" (A)Iand IV (B) Mand I (©) only (D) IV only Page 223 (79) The volume of one dtop of aqueous solution from an eyedropper is approximately 0.05 mL.. One such drop of 0.2 M HCI is added to 100 mL. of distilled water ‘The pH of the resulting solution will be (A400 B)7.0 ©30 (D)ss (80) 2.0 moles of an ideal gas expands isothermally (27°C) and reversibly from a pressure of 1 bar to 10 bar. The heaviest mass that can be lifted through a height of 10m by the work of this expansion is (A) 50.8 kg, B) 5088 OUT RE Mutig Rough Work Page 23,3 Rough Work Page 24