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SCC1226 Worksheet 3 Alkyl Halides 2023

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22 views3 pages

SCC1226 Worksheet 3 Alkyl Halides 2023

Uploaded by

rukipraveen69
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Worksheet 3: Alkyl Halides

1. Name the following halogen-containing compounds:

CH2 CH3
H3C C

a. Br Cl

b.

Cl CH2CH2CH3

C C

c. H3C H

d. I C C I

Cl

e. Cl

f. Br OH

CH3

Cl CH Br
CH CH

g. CH3 CH2CH3

H3C F

C C Br

H3C CH2 CH

h. I

SCC1226D Introduction to Organic Chemistry and Biochemistry Page 1


2. Draw the structure of the following compounds:

a. 2-bromo-2-methylpropane
b. 1-chloro-2, 2-dimethylbutane
c. Fluorocyclobutane
d. 3-chloro-1-cyclopentene
e. 1,1-dibromoethene
f. m-bromoiodobenzene
g. 1,4-chlorophenol

3. Draw all of the isomers for each molecular formula below:

a. C2H4Cl2
b. C3H5Br
c. C4H9Cl
d. C7H7F (aromatic structures only)

4. Synthesis of alkyl halides

a. Draw one possible organic product made by the following substitution reactions:
UV
light
+ Br2

(i)

UV
CH2 CH3 light
+ Br2
(ii) H3C CH2

UV
light
CH3 + Cl2
(iii)

CH3
UV
CH CH3 light
+ Cl2
H3C CH

(iv) CH3

SCC1226D Introduction to Organic Chemistry and Biochemistry Page 2


b. Draw the organic product made by the following addition reactions:
(use Markovnikov’s rule to predict the most likely product, if appropriate)
CH3
+ Cl2
(i)

H CH3

C C + HF

(ii) H3C CH2CH3

(iii) H3C C C CH3 + 2 HBr

+ Br2

(iv) H3C CH2CH3

5. Reactions of alkyl halides

a. Draw the organic product of the following substitution reactions:

CH2 CH2Br
+ OH
(i) H3C CH2

I + Cl
(ii)

b. Draw the organic product of the following elimination reactions:

H3C CH2Br
+ OH
CH

(i) CH3

Br

+ OH
CH CH3
(ii) H3C CH2

SCC1226D Introduction to Organic Chemistry and Biochemistry Page 3

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