Quarterly exam revision test Marks:70 Time::3

hours

1. How much charge in Faradays is required for the reduction of

1mol of Al3+? (1)
2. Haloalkanes easily dissolve in organic solvents. Why? (1)
3.Name the carbohydrate used 1
as storage molecule to store
energy in animals. (1)

4. On mixing liquid X and liquid Y, the volume of the resulting

solution increases. What type of
deviation from Raoult’s law is shown by the resulting solution?
What change in temperature
would you observe mixing liquids X and Y? (2)
5. Define rate constant (k). (1)
6. Write chemical equations when: (2)
(i) Ethyl chloride is treated with aqueous KOH.
(ii) Chlorobenzene is treated with CH3COCl in presence of
anhydrous AlCl3

7.. Name the reagents used in the following reactions: (2)

(i) Nitration of phenol to 2,4,6-trinitrophenol
(ii) Butanal to butanol

8. 3.9 g of benzoic acid dissolved in 49 g of benzene shows a

depression in freezing point of 1.62 K. Calculate the van’t Hoff
factor and predict the nature of solute. (associated or dissociated)
(Given Molar mass of benzoic acid = 122 g mol-1, Kf for benzene =
4.9 KKgmol-1) (3)

9.. Conductivity of 2.5 x 10-4 M methanoic acid is 5.25 x 10-5 Scm-1.

Calculate its molar conductivity and degree of dissociation. (Given
that Λ 0(H+) = 349.5 Scm2mol-1 and Λ 0 (HCOO-) = 50.5 Scm2mol--
11). (3)

10.. What is a nickel-cadmium cell? State its one merit and one
demerit over lead storage cell. Write the overall reaction that
occurs during discharging of this cell. (3)

11.. For a decomposition reaction the values of rate constant, k at

two different temperatures are given below:

k1 = 2.15 x 10-8 Lmol-1s-1 at 650 K

k2 = 2.39 x 10-7 Lmol-1s-1 at 700 K
Calculate the value of activation energy for this reaction. (Given R
= 8.314 JK-1mol-1) (3)

12.. The rate constant for a reaction of zero order in A is 0.0030

molL-1s-1. How long will it take for the initial concentration of A to
fall from 0.10 M to 0.075 M? (2)

13. A first order reaction takes 10 minutes for 25%

decomposition. Calculate t1/2 for the reaction. (Given log 2 =
0.3010, log 3 = 0.4771, log 4 = 0.6021) (2)

14. Give reasons for the following:

(a) Ethyl iodide undergoes SN2 reaction faster than ethyl
bromide.
(b) () 2-Butanol is optically inactive.
(c) C-X bond length in halobenzene is smaller than C-X bond
length in CH3-X. (3)
15.. Calculate the boiling point of one molar aqueous solution
(density 1.06 gmL-1) of KBr. [Given that Kb for H2O = 0.52
Kkgmol-1, Atomic mass of K = 39 and Br = 80] (2)

16..Arrange the following compounds in increasing order of their

property as indicated :
(a) Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-butyl
ketone [Reactivity HCN]
(b)CH3CHO in the presence of dilute NaOH (2)

2
17.. Account for the following :
(a) Transition metals show variable oxidation states.
(b) Zn, Cd and Hg are soft metals.
(c) Eo value for the Mn3+/Mn2+ couple is highly positive (+1.57
V) as compared to Cr3+/Cr2+ (3)

SECTION-C
18. Passage
Molar conductivity of a solution is the conductance of solution
containing one mole of electrolyte, kept between two electrodes
having unit length between them and large cross sectional area so
as to contain the electrolyte. In other words, molar conductivity is
the conductance of the electrolytic solution kept between the
electrodes of a conductivity cell at unit distance but having area of
cross section large enough to accommodate sufficient volume of
solution that contains one mole of the electrolyte. It is denoted by
Λ m.
(a) Write the mathematical expression for molar conductivity.
(b) What are the units of molar conductivity, Λ m?
(c) How does molar conductivity varies with concentration for
strong as well as weak electrolytes?
(d)Why conductivity of CH3COOH decreases on dilution? (4)

19.(a)Explain why H2 and O2 do not react at room temperature.

(b) Write the rate equation for the reaction A2 + 3B2 ––> 2C, if
the overall order of
the reaction is zero.(2)

20.Derive integrated rate equation for rate constant of a first

order reaction (2)

21.Copper atom has completely filled d orbitals (3d10) in its

ground state, yet it is
regarded as a transition element.
(ii) Cr2+ is a stronger reducing agent than Fe2+ in aqueous
solutions (2)

22) How can we separate the product formed by the reaction of

phenol with dilute nitric acid at low temperature(298K)? (1)
23)
a. The above graph represents: A) Elevation in boiling point B)
Raoult’s law C) Negative deviation from Raoult’s law D) Positive
deviation from Raoult’s Law
b. In the above graph, the value of mole fraction X1 =1 stands for:
A) Pure liquid 1 B) Solution containing more moles of liquid 1 C)
Equimolar mixture of liquids 1 and 2 D) Lowest value of mole
fraction
c. Which of the following statements is true for negative deviation
from Raoult’s law? A) Vapour pressure increases B) Escaping
tendency increases C) Interparticle force of attraction becomes
weaker D) Volume decreases
d. Which of the following is an ideal solution? A) Solution of
ethanol and water B) Solution of benzene and toluene C) Solution
of phenol and aniline D) Solution of acetone and chloroform
e. The vapour pressure of a solution of glucose in water is lower
than that of pure water due to: A) Decrease in surface area B)
Evolution of heat C) Decrease in escaping tendency D) increase in
volume (5)
24) Toluene reacts with a halogen in the presence of iron (III)
chloride giving ortho and para halo compounds. The reaction is:
A) Electrophilic addition reaction B) Electrophilic substitution
reaction C) Free radical addition reaction D) Nucleophilic
substitution reaction (1)
25). Which of the following alcohols will yield the corresponding
alkyl chloride on reaction with concentrated HCl at room
temperature? A) Propan-1-ol B) Isopropyl alcohol C) 2-methyl
propan-2-ol D) Butan-1-ol (1) u eo
26). Reaction of C6H5CH2Br with aqueous sodium hydroxide
follows ______. A) SN1 mechanism B) SN2 mechanism C) SN1 or SN2
depending upon the temperature of reaction D) Saytzeff rule (1)
27). Which of the following solutions has highest freezing point?
A) 1 M AlCl3 B) 1 M NaCl C) 1 M CaCl2 D) 1 M glucose (1)
28). Predict the product of the following reactions:
i) 1-bromo-1-methyl cyclohexane is treated with alcoholic KOH
ii) Benzyl magnesium bromide is treated with water
iii) Chloromethane is treated with AgCN
iv) Cyclohexanol treated with SOCl2 (4)
29). Which of the following compounds show highest reactivity
towards SN2 reaction?
A) 1-bromo-2-methyl butane B) 1-bromo-3-methyl butane C) 1-
bromo-2,2-dimethyl propane D) 1-bromobutane (1)
Primary alkyl halide C4H9Br (P) react with alcoholic KOH to give
compound(Q). Compound (Q) on reaction with HBr gives (R)
which is an isomer of (P). When (P) is reacted with sodium metal
it gives compound C8H18,which is different from the compound
formed when n-butyl bromide is reacted with sodium.
Question Nos. 30-32 are based on the above given reactions. (3)
30. IUPAC name of compound ‘P’ is: A) 1-methyl-2-bromobutane
B) 1-bromo-2-methylpropane C) 1-bromobutane D) 2-
bromobutane
31. The product formed when ‘P’ react with metallic Na is: A) n-
octane B) butyl sodium bromide C) 2,5-dimethyl hexane D)
2,3-dimethyl butane
32. The reaction of C4H9Br with Na to give C8H18 is known as: A)
Swarts reaction B) Finkelstien reaction C) Wurtz reaction D)
Fittig reaction
33. Which of the following statements is true for fibrous protein?
A) Soluble in water B) Spherical shape C) Present in hair D)
Both A and B (1)
34. The Zwitter ion form of amino acids contain: A) – NH2 group
and – COOH group B) – NH3 + group and – COO– group C) -NH2
and – H + group D) – COO– group and – NH2 group (1)
35. At equilibrium, the rate of dissolution of a solid solute in a
volatile liquid solvent is ________.
A) less than the rate of crystallisation B) greater than the rate of
crystallisation C) equal to the rate of crystallisation D) zero (1)
36) Denaturation of a protein leads to loss of its biological
activity by,
A) formation of amino acids B) loss of primary structure C) loss
of both primary and secondary structure D) loss of both
secondary and tertiary structures (1)
37) The mass of (COOH)2.2H2O(Molar mass=126 g) needed to
prepare 500ml of 0.1molar solution is: A) 12.6 g B) 6.3 g C) 4.5 g
D) 9 g (1)
38). A dinucleotide is obtained by joining two nucleotides
together by phosphodiester linkage. Between which carbon atoms
of pentose sugars are these linkages present?
A) 5′ and 3′ B) 5′ and 5′ C) 1′ and 5′ D) 3′ and 3′ (1)
39). The number of chiral carbons in ß-D (+) glucose is: A) Five
B) Six C) Three D) Four (1)
40) Which of the following compounds has the highest boiling
point? A) CH3CH2CH2Cl B) CH3CH2CH2CH2Cl C)
CH3CH(CH3)CH2Cl D) (CH3)3CCl (1)
41. Fittig reaction can be used to prepare: A) Toluene B)
Acetophenone C) Diphenyl D) Chlorobenzene (1)
42. IUPAC name of CH3CH2C(Br) = CH — Cl is A) 1-bromo-2-
chloro but-1-ene B) 1-chloro-2-bromo but-1-ene C) 3-chloro-2-
bromo but-1-ene D) 2-bromo-1-chloro but-1-ene (1)
43. Select the correct options for the elimination reaction of 2-
bromopentane to form pent-2-ene. (i) -elimination reaction (ii)
Follows saytzeff rule (iii) Dehydrohalogenation reaction (iv)
Dehydration reaction
A) (i), (ii) B) (i), (ii), (iii) C) (i), (iii) D) (i), (iii), (iv) (1)
In questions 44 to 49, a statement of assertion (A) is given,
followed by a corresponding statement of reason (R) just below it.
Of the statements mark the correct answer as: (6)
A. if both assertion and reason are true and reason is the correct
explanation of assertion. B. if both assertion and reason are true
but reason is not the correct explanation of assertion. C. if
assertion is true but reason is false. D. if both assertion and
reason are false.
44.
(A) : Sprinkling of salt helps in clearing the snow covered roads.
(R) : Addition of a non-volatile solute to a volatile solvent
increases freezing point.
45. (A) : Glucose is a monosaccharide.
(R) : Glucose is an aldohexose.
46. (A) : Osmotic pressure of 1 M KCl solution is greater than 1 M
urea solution.
(R) : Osmosis is a colligative property.
47. (A) : Haloalkanes are insoluble in water.
(R) : Haloalkanes cannot form hydrogen bond with water
molecules.
48. (A) : Solubility of a gas in a liquid increases with increase in
temperature.
(R) : Dissolution of a gas in a liquid is an endothermic process.
49. (A) : The C-Cl bond in chlorobenzene is less polar than the C-
Cl bond in chloromethane
(R) : Benzene ring is electron withdrawing in nature.
50. What type of battery is lead storage battery? Write the anode
and cathode reactions in the operation of a lead storage battery.
(3)
51. Resistance of a conductivity cell filled with 0.1 mol L-1 KCl
solution is 100 . If the resistance of the same cell when filled
with 0.02 mol L-1 KCl solution is 520, calculate the conductivity
and molar conductivity of 0.02 mol L-1 KCl solution. The
conductivity of 0.1 mol L-1 KCl solution is 1.29 x 10-2 -1 cm-1 . (3)
52. What is an ideal solution? Give an example. (1)
53, State a condition under which a bimolecular reaction is
kinetically first order. (1)
54. State Henry’s law. Write one its application. What is the effect
of temperature on solubility of gases in liquids? (2)
55. Define activation energy. How does a catalyst affect activation
energy? Explain with the help of a diagram. (2)