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Classification of Elements-WORKSHEET

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Classification of Elements-WORKSHEET

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aasim shaikh
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© © All Rights Reserved
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CHEMISTRY WORKSHEET - STD XI

CLASSIFICATION OF ELEMENTS &


PERIODICITY IN PROPERTIES
1. What would be the IUPAC names & symbols for the elements with atomic
numbers 118, 108, 114 & 119.
2. Arrange the following ions in the order of increasing size:
i) Be2+, Cl-, S2-, Na+, Mg2+, Br
ii) Na+, F-, O2-, Mg2+
3. Write the general electronic configuration of p-block, d-block & f-block
elements.
4. Lanthanoids & actinoids are placed in separate rows at the bottom of the
periodic table. Explain the reason.
5. Name a species that will be isoelectronic with each of the following atoms
or ions: i) Ne ii) Cl- iii) Ca2+
6. Mg2+ ion is smaller than O2- although both have same electronic structure.
Explain.
7. The first ionization enthalpy of Mg is higher than that of Na. On the other
hand, the second ionization enthalpy of Na is very much higher than that
of Mg. Explain.
8. Account for the following:
i) Be has slightly higher value of ionization enthalpy than that of B
ii) I.E1 of N is greater than that of O
iii) Second ionization enthalpy is always higher than first ionization
enthalpy
iv) Third period of the periodic table has eight & not eighteen elements
v) Fourth period has eighteen & not eight elements
vi) Electron gain enthalpy of Cl is more negative than that of F
vii) Electron gain enthalpies of noble gases are positive
viii) Halogens have highest negative electron gain enthalpies in their
respective periods
9. The second electron gain enthalpy of O is positive, more negative or less
negative than the first. Explain.
10. What is the basic difference between the terms electron gain enthalpy &
electronegativity?
11. Assign the position of the element having outer electronic configuration:
i) ns2 np4 for n = 3 ii) (n-1)d2 ns2 for n = 4
12. Predict which atom in each of the following pairs has the greater first
ionization enthalpy & explain your answer:
a) B & C b) N & O c) F & Ne
13. Which of the following pairs of elements would have a more negative
electron gain enthalpy? i) N & O ii) F & Cl. Explain.
14. Which will have a larger size & why?
i) K or K+ ii) Cl or Cl- iii) Na+ or Mg2+ iv) O2- or F-
15. The electronic configuration of some elements are given below:
A - 1s2 2s2 B - 1s2 2s2 2p6 3s1 C - 1s2 2s2 2p4 D - 1s2 2s2 2p3
Which of these elements has i) highest first ionization enthalpy
ii) highest second ionization enthalpy?
16. Consider the electronic configuration of the elements X, Y & Z:
X - 1s2 2s2 2Px1 2Py1 Y - 1s2 2s2 2Px2 2Py1 2Pz1
Z - 1s2 2s2 2Px1 2Py1 2Pz1
i) Which element has higher negative ∆egH?
ii) Which element has lowest negative ∆egH?
17. In each of the following sets, arrange the elements in the increasing order
of their negative electron enthalpies:
i) C, N, O ii) O, N, S iii) S, Cl, Ar iv) F, Cl, Br
18. Which of the following pairs of elements would you expect to have
lower ionization enthalpy? Explain.
i) Cl or F ii) Cl or S iii) K or Ar iv) Kr or Xe
19. Show by chemical reaction with water that Na2O is a basic oxide &
Cl2O7 is an acidic oxide.
20. Size of the cation is smaller than that of the neutral atom while the size
of the anion is more than that of the parent atom. Explain.
21. Which of the following species will have the largest & the smallest size?
Mg, Mg2+, Al, Al3+
22. Define: a) ionization enthalpy b) electron gain enthalpy
23. Arrange the following elements in the increasing order of metallic
character: Si, Be, Mg, Na, P
24. a) Elements A, B, C & D have atomic numbers 12, 19, 29 & 36
respectively. On the basis of electronic configuration, write to which
group of the periodic table each element belongs.
b) Predict the blocks to which these elements can be classified. Also
predict their periods & groups.
c) Which of these are representative elements?

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