09-10-2024

1803CJA101029240052 JA

PART-1 : PHYSICS

SECTION-I(i)

1) A barometer tube, containing mercury, is lowered in a vessel containing mercury until 45 cm of

mercury length in the tube is above the level of mercury in the vessel. If the atmosphere pressure is
75 cm of mercury, what is the pressure at top of the tube ?

(A) 61.2 kPa

(B) 102.0 kPa
(C) 40.8 kPa
(D) 163.2 kPa

2) A bar with a crack at its centre buckles as a result of temperature rise of ΔT. If the fixed distance
is 2a and the coefficient of linear expansion of bar is a, find the rise h of centre.

(A)
(B)
(C)
(D)

3) Water in a lake starts freezing at some time when the outside temperature –θ°C. The time taken
in freezing of initial x thickness of lake is 2 hrs then how much extra time it will take to freeze extra
2x thickness ?

(A) 4 hrs
(B) 9 hrs
(C) 16 hrs
(D) 18 hrs

4) A sphere of temperature 127°C is kept in surrounding of constant temperature of 27°C then rate
of heat loss is 17.5W. When temperature of sphere is changed to 227°C then find rate of heat loss.

(A) 17. 5 W
(B) 54.4 W
(C) 40 W
(D) 42.7 W
 SECTION-I(ii)

1) When photons of energy 4.25 eV strike the surface of metal 'A', the ejected photoelectrons have
maximum kinetic energy of TA. Maximum kinetic energy of photoelectrons liberated from another
metal 'B' by photons of energy 4.70 eV is TB = (TA – 1.00)eV. If the de-broglie wavelength of these
photoelectrons is λB = 2λA, then

(A) The work function of A is 2.92 eV

(B) TA = 1.5 eV
(C) The work function of B is 4.37 eV
(D) TB = 0.33 eV

2) A particular hydrogen like atom has its ground state binding energy 122.4 eV. It is in ground
state. Then–

(A) Its atomic number is 3

(B) An electron of 90 eV energy can excite it.
(C) An electron of kinetic energy nearly 91.8 eV can be brought to almost rest by this atom.
An electron of kinetic energy 2.6 eV may emerge from the atom when electron of kinetic energy
(D)
125 eV collides with this atom

3) Atomic masses (in amu) are given below

(1) (2)
(3) (4)
(5)
Considering that mass of electron is 0.00055 amu, which of the following option is/are correct?

(A) is unstable against K-capture

(B) is unstable against K-capture
(C) , and are unstable against β+ decay
(D) and are unstable against β– decay

4) P–V graph is given below : Which of the following graph(s) represent processes
correctly?

(A)
(B)

(C)

(D)

5) How much ice at –20° C can be mixed with 2.5 litre water at 20°C so that final temperature of the
mixture is 0°C ? ρW = 1002.5 kg/m3, Lice = 80 cal/gm, 2 × Sice = Sw = 1 Cal/gm –°C

(A) 500 gm
(B) 1 kg
(C) 5 kg
(D) 20 kg

6) A body of mass ‘M’ is attached to lower end of a metal wire , whose upper end is fixed. If the
elongation in wire is ‘ℓ’, then :

(A) Loss in gravitational potential energy of ‘M‘ is ‘Mgℓ’.

(B) Elastic potential energy stored in wire is ‘ Mgℓ’

(C)
Elastic Potential energy stored in wire is

(D)
Heat produced is

7) Suppose potential energy between electron and proton in hydrogen like atom at a distance ‘r’ is

given by , then (Given ‘me’ is mass of electron).

(A) Energy of nth orbit is proportional to n3

(B) Energy of nth orbit is proportional to n6
2
(C) Energy is proportional to me
–3
(D) Energy is proportional to me

8) A sample of gas follows process represented by PV2 = constant. Bulk modulus of process is ‘B’,
then which of the following graph is/are correct ?
(A)

(B)

(C)

(D)

SECTION-II

1) A vessel containing ice at 0°C is connected through two rods P and Q having temperature of other
ends at 120°C and –20°C, thermal conductivity and area of cross section 40 watt/m-K and 0.0004 m2
but length 2 meter and 1 meter respectively. If latent heat of ice is 335 kJ/kg then what is rate of
melting of ice in gram/sec ? (Assume that there is no heat loss).

2) A sphere and a solid cube both made of copper are heated up to same temperature and are kept
in same surrounding. If radius of sphere and side of cube are same then what will be ratio of initial
rate of cooling of sphere to cube ?

3) 1 mole of a monoatomic ideal gas and 3 mole of a diatomic ideal gas are mixed. If both gasses can

not react then what will be for mixture ? (Cp and Cv are molar specific heat capacities)

4) Binding energy per nucleon for C12 is 7.68 MeV and that for C13 is 7.47 MeV. Find energy required
to remove a neutron from C13 (in MeV).

5) A solid metal sphere of radius r and specific heat s is rotated about an axis passing through its
center at a speed f rotations per second. It is suddenly stopped and half of kinetic energy causes its

temperature to rise. Find rise in temperature of sphere, in the form Find x (taking π2 = 10)
6) A manufacturer wants to produce crude benzene models for the chemistry department. The
manufacturer plans to do this by punching regular hexagons out of steel; such that edge length and
thickness are in ratio 1000 : 1. Steel ruptures at shear stress greater than 4 × 108 N m–2. If total
shearing force applied is 6 × 105 N, then find maximum value of thickness of the hexagonal plane (in
mm)

PART-2 : CHEMISTRY

SECTION-I(i)

1) State T(true)/F(false) for following statements regarding given liquid solutions :

(a) Final volume of solutions if equal volume of

compounds are mixed, is in the order: VI = VII < VIII
(b) ΔSmix for solution I and solution II is positive but for solution III it is zero.
(c) Enthalpy change of mixing is negative for solution II and solution III but positive for solution I.

(A) TFF
(B) FFF
(C) TTF
(D) FTT

2) Which of the following molecule is polar in nature ?

(A)

(B)

(C)

(D) F2C = C = C = CF2

3) The glycosidic linkages in cellulose and amylose are......respectively.

(A) α C–1–C–4 and β C–1–C–4

(B) β C–1–C–4 and α C–1–C–4
(C) β C–1–C–4 and α Cl– C6
(D) α Cl–C4 and α Cl–C2

4) Which of the following statement(s) is(are) correct ?

(a) Smoke and cloud both are aerosol with same dispersion medium.
(b) Surface tension of lyophilic sols is less than the surface tension of dispersion medium while that
of lyophobic sols is more than dispersion medium.
(c) Lyophobic sols can be detected by ultra microscope
(d) Colloidal sol shows low magnitude of colligative properties.

(A) a, c & d
(B) a, b & d
(C) c & d only
(D) All are correct

SECTION-I(ii)

1) Select the correct statements from following -

Hydrolysis of magnesium carbide produces propyne while hydrolysis of beryllium carbide

(A)
produces methane.
Hydrolysis of magnesium carbide produces propyne while hydrolysis of calcium carbide
(B)
produces ethyne.
(C) Hydrolysis of boron trifluoride occurs with 75% coversion into hydrolysed product
(D) Aluminium carbide and beryllium carbide both on hydrolysis produce methane.

2) Out of the above amines which can not give N2 gas with HNO2 but form hydrochloride salt with
HCl ?

(A)

(B)

(C)

(D)

3) 1 gm of monobasic acid when dissolved in 100 gm of water lowers the freezing point by 0.1854°C.
0.2 gm of same acid required 20 ml of 1/10 N alkali for titration, then for solution of acid: (Assume
molarity = molality) (log2 = 0.3, log3 = 0.48) (Kf(H2O) = 1.8 K kg mol–1)

(A) Degree of dissociation = 0.3

–4
(B) Ka of acid = 9 ×10
(C) pH= 2.52
(D) Molar mass of acid = 100 g/mol

4) Consider reactions given for B2H6. Which of the

following statements is/are CORRECT?

(A) X contains two 3C–2e– bond and four 2C – 2e bonds.

(B) Y contains maximum ten atoms in a plane.
(C) Z Contains 2pπ – 2pπ bond.
(D) X, Y and Z, all have same number of 2c-2e bonds.

5) Which of the following can be prepared by Reimer-Tiemann reaction directly?

(A)

(B)

(C)

(D)

6) Which is/are true regarding colloidal solution?

(A) Viscosity of lyophillic sols is greater than their dispersion medium.

(B) Tyndall effect is more prominent for lyophobic sols than lyophilic sols
(C) Brownian movement in colloids is due to collisions among dispersed phase particles.
(D) Sodium salt of fatty acids form colloids at high concentrations and very low temperatures.

7) Which order is/are CORRECT?

(A) Thermal stability: Li2C2O4 < Na2C2O4 < K2C2O4 < Rb2C2O4 < Cs2C2O4
(B) Basic nature: ZnO > BeO > MgO > CaO
(C) Solubility in water: Li2CO3 < Na2CO3 < K2CO3 < Rb2CO3 < Cs2CO3
(D) Melting point: NaF < MgF2 < AlF3

8) Select option having correctly matched polymer with their uses :

(A) Dacron → Crease resistant cloth

(B) Buna-N → Oil seals
(C) Bakelite → Computer discs
(D) HDP → squeeze bottles

SECTION-II

1) A student carried out the experiment to measure the pressure of carbon dioxide in the space
above the carbonated soft drink in a bottle. Initially weight of soft drink in bottle was found to be
853.5g then its weight again measured after CO2 escaped out was found to be 851.3 gm.Volume of
the soft drink is 450 mL. If Henry’s law constant for CO2 in water is 3.4 × 103 atm, find the
approximate pressure (in atm) of CO2 over the soft drink in bottle before it was opened. [Given :
density of soft drink = 1 gm mL–1]
2) Consider the following
(a) N2 > O2 1st ionisation enthalpy
(b) N2 > N 1st ionisation enthalpy
(c) O2 < N 1st ionisation enthalpy
(d) O2 < O 1st ionisation enthalpy
(e) O2 > N2 Bond order
(f) N2 > O2 Bond length
(g) N2 = O2 Bond strength

(h)
After LCAO there will be one new nodal plane formation take place in resulting molecular orbital.
(i) CO+ and N2+ have same bond order.

(j) After LCAO a gerade orbital is produced

How many of the above statements are correct:

3) Find correct. number of matchings.

Repeating unit Polymer

(i) Polypropene

(ii) Polystyrene

(iii) Glyptal

(iv) Polyvinyl chloride

(v) –NH–CO–NH–CH2 — Urea-formaldehyde Resin

(vi) PHBV

(vii) Novalac

(viii) Nylon 6

(ix) Nylon 6,6

(x) poly isoprene

4) 10% sites of catalyst bed has been occupied by H2 gas molecules. On heating H2 gas is evolved
from sites and collected at 0.030 atm and 300K in a vessel of volume 2.46 cm3. Number of sites
available is 6 × 1015 per cm2 and surface area of catalyst is 103 cm2. The number of H2 molecules
adsorbed per site of catalyst are :
(Given NA = 6 × 1023, R = 0.082 L.atm K–1mol–1)

5) In the compound PClK F5–K, possible values of K can be 0 to 5 then sum of all possible values of K
for the compounds having minimum three chlorine in one plane is:

6) How many compounds out of following will give red colour when it is converted into Lasseigne's
extract and FeCl3 is added to the extract

(i) (ii) CH3CH2–NMe2

(iii) (iv)

(v) NH2–NH2 (vi)

(vii) (viii) Me2C = N– OH

(ix)

PART-3 : MATHEMATICS

SECTION-I(i)

1) If A is a square matrix of order 50, then is equal to

(I is an identity matrix of order 50)

(A)

(B) 1

(C)

(D)

2) Let A1 A2... A7 be a polygon and a1, a2,...a7 be the complex number representing vertices

A1, A2... A7. If |a1| = |a2| =...= |a7| = R, then lies in the interval -

(A) [10R2, 20R2)

(B) [20R2, 25R2)
(C) [25R2, 35R2)
(D) [35R2, ∞)

3) Positive integers p, q and r satisfy the condition that the quadratic equation px2 – qx + r = 0 has
two distinct real roots that are strictly between 0 and 1. Then the minimum value of p, is

(A) 2
(B) 1
(C) 5
(D) 4

4) 150 Scientists from all over the world are engaged to find vaccine for COVID and it is known that
if they all work together the vaccine will get prepared in a certain number of days. However, after
the first day of work 4 scientists fell ill and left the task permanently. After the second day, another
4 fell ill and left permanently. This pattern continues until the vaccine is finally made , 8 days over
schedule.
Then the number of days in which the vaccine is made, is

(A) 75
(B) 25
(C) 32
(D) 17

SECTION-I(ii)

1) If A & B are invertible square matrices of order 3 such that A + 2B = 3I and 2B–1 + 4A–1 = 3I, then
(I is dentity matrix of order 3 and adj(A) is adjoint of matrix A)

(A) AB = 4I
(B) |AB| = 8
(C) |adj(AB)| = 64
(D) B adj(AB)A = 8I

2) If z is a complex number and points A(z – i), B(z + i) and origin are vertices of a right angled
triangle, right angled at origin, then

(A) Two values of z are possible

(B) Infinite values of z are possible
(C) |z| = 2
(D) Maximum area of ΔOAB is 1 sq. units.

3) If a and b are non-zero real numbers and the value of expression

is equal to P, then which of the following about P is /are correct?

(A) P is a prime number

(B) P is not a prime number
(C) P is coprime with every other natural numbers
(D) Sum of all the factors of P is a prime number

4) Consider the series : 1 + 2.2 + 3.22 + 4.23 +...+ 100.299 = a.2b + 1

Now, which of the following statements are correct:

(A) a = 99
(B) b = 100
(C) b = 99
(D) a = 100

5) If x, y, z are integers such that x + y + z = 0 and , then

(A) x2 + y2 + z2 = 6
(B) x3 + y3 + z3 = 8
(C) xy + yz + zx = –3
(D) xyz = 8

6) If the equation |z|(z+1)8 = |z+1|.z8 (where z ∈ C and z (z + 1) ≠ 0) has distinct roots.

z1, z2... zn (where n ∈ N), then which of the following is/are true?

(A) z1, z2... zn are concyclic points

(B) z1, z2... zn are collinear points

(C)

(D)

7) Let B = [bij]n × n be a square matrix of order n such that

(A)
(B)

(C)

(D)

8) Let ordered pair (x, y) satisfy the equation ,

then which of the following is/are correct?

(A) Only 1 ordered pair of (x, y) is possible

(B) More than 1 ordered pair of (x, y) are possible
(C) In one of the ordered pair |x|+|y| = 1
(D) In one of the ordered pair x – y = 0

SECTION-II

1) If A and B are two square matrices of same order such that A2B = BA and if (AB)10 = AK.B10 then

the value of is : (Where K ∈ N)

2) If p,q, r are cube roots of unity and complex number , then |z + 3| is equal to

3) The curve y = –x3 + 8x2 + 40x and the line y = K intersect at 3 distinct points. If the x-coordinate

of these 3 points form a geometric progression, then value of , is (K ∈ R)

4) If the value of (i ≠ j ≠ k) can be represented as m/n (where m and n are

coprime) then value of , is

5) Let α1, α2 be the roots of quadratic equation ax2 + bx + c = 0 and β1, β2 be roots of quadratic
equation px2 + qx + r = 0. If the system of equation α1y + α2z = 0 and β1y + β2z = 0 has non-trivial

solution and (Where λ ∈ R) then λ/4 is equal to

6) If (where ), then minimum value of
D(2021, θ) is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. C C C B

SECTION-I(ii)

Q. 5 6 7 8 9 10 11 12
A. A,C,D A,C,D A,B,D B,C,D B,C,D A,C,D B,D A,B,C

SECTION-II

Q. 13 14 15 16 17 18
A. 1.90 to 1.93 0.50 1.43 to 1.45 4.94 to 4.96 4.00 0.50

PART-2 : CHEMISTRY

SECTION-I(i)

Q. 19 20 21 22
A. B B B A

SECTION-I(ii)

Q. 23 24 25 26 27 28 29 30
A. A,B,D A,B C,D A,B,C A,B,C A,B A,C,D A,B,C

SECTION-II

Q. 31 32 33 34 35 36
A. 6.78 to 6.80 5.00 8.00 3.00 12.00 4.00

PART-3 : MATHEMATICS

SECTION-I(i)

Q. 37 38 39 40
A. D D C B

SECTION-I(ii)

Q. 41 42 43 44 45 46 47 48
A. B,C,D B,D B,D A,B A,C B,C,D A,D A,C,D
 SECTION-II

Q. 49 50 51 52 53 54
A. 10.23 6.00 12.50 1.12 0.25 -0.50
 SOLUTIONS

PART-1 : PHYSICS

PART-2 : CHEMISTRY

PART-3 : MATHEMATICS