All India Test Series T- 3

Subject : PCM Max. Marks : 300

Date : 17-11-2024 Timing : 03:00 hr

GENERAL INSTRUCTIONS
1. The question paper consists of 3 Parts (Physics, Chemistry, Mathematics). Each Part has two sections
(MCQ & Integer Type).
2. Section A contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out
of which ONLY ONE CHOICE is correct.
3. Section B contains 5 Numerical Value Type Questions. The answer to each question is a NUMERICAL
VALUE. Candidate has to enter the correct integer value of the answer. The answer should be rounded off to
the nearest integer.
4. There will be negative marking for both Section A and Section B.
MARKING SCHEME
1. Section - A: +4 for correct answer, –1 for incorrect answer, 0 for all other cases.
2. Section - B: +4 for correct answer, –1 for incorrect answer, 0 for all other cases.

SYLLABUS

Physics : Heat Kinetic Theory of Gases, Thermodynamics, Wave & Oscillations

Chemistry : Some Basic Principles of Organic Chemistry, Purification and Characteristic of

Organic Compounds, Hydrocarbons

Mathematics : Permutations and Combinations, Conic Sections and Complex Number

NAME OF THE CANDIDATE : ................………………………………… ROLL NO. :……..………………………..

I have read all the instructions I have verified the identity, name and roll and
shall abide by them number of the candidate.

-------------------------- --------------------------

Signature of the Candidate Signature of the Invigilator

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(All India Test Series T- 3) 17-11-2024 PHYSICS
SECTION-A
–1 –1
1. A metal vessel of negligible heat capacity contains 0.5 kg of water (of specific heat capacity 4200 Jkg K ).
It is heated from 15ºC to 85ºC by 750 W immersion heater in 4 minutes. The average loss of heat in watts to
the surroundings from the vessel during this time is nearly:
(A) 70 (B) 123 (C) 138 (D) 212
2. A slab X of thickness ‘t’ thermal conductivity ‘k’ and area of cross-section ‘A’ is placed in thermal contact with
2
another slab Y which is 2n times thicker, 4n times conductive and having n times larger cross-section area.
If the outside face of X is maintained at 100ºC, the outside face of Y at 0ºC, then the temperature of the
junction is represented by the graph (n > 0) :

(A) (B)

(C) (D)

3. Two identical metallic sheets each behaves like a black body are kept parallel to each other with small
separation between them in vacuum. Thermal energy is generated at a constant rate P in one of the sheets
by passing electricity through it. In steady state, temperature of the other sheet is found to be constant at

103 17
300K. Find the value of P in kilo-watt. (given area of plates = A = m2 and σ
= × 10 −8 W / m2K 4 )
17 × 27 3
(A) 3 (B) 4 (C) 5 (D) 6
4. A copper sphere is suspended in an evacuated chamber maintained at 300K. The sphere is maintained at a
constant temperature of 500K by heating it electrically. A total of 300W of electric power is needed to do it.
When half of the surface of the copper sphere is completely blackened 600W is needed to maintain the
same temperature of the sphere. Calculate the emissivity of copper.
1 2 1 1
(A) e = (B) e = (C) (D)
3 3 2 6
–4 2
5. One mole of an ideal gas is kept enclosed under a light and frictionless piston (area = 10 m ) connected by
2
a compressed spring (spring constant 100 N/m). The volume of gas is 0.83 m and its temperature is 100 K.
The gas is heated so that it compresses the spring further by 0.1 m. The work done by the gas in the
–1 –1
process is X joules. Find the value of X. (Take R = 8.3 Jmol K and there is no atmosphere)
1 3 5 3
(A) (B) (C) (D)
2 2 2 4
6. A container encloses 32 g of O2 at 127ºC and of pressure P0. A small hole is made in the container and the
P0
gas leaks out. At a certain state, pressure of gas becomes and its temperature 27ºC. Mass of the gas
2
that has leaked out till this stage is nearly:
(A) 6.3g (B) 7.4g (C) 16.3g (D) 10.7g
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7. Power radiated by a black body is P0 and the wavelength corresponding to maximum energy is around λ 0 .

256P0
On changing the temperature of the black body, it was observed that the power radiated becomes .
81
The shift in wavelength corresponding to the maximum energy will be
λ0 λ0 λ0 λ0
(A) (B) (C) − (D) −
4 2 4 2
8. One mole of an ideal gas contained in a cylinder undergoes a thermodynamic process during which pressure
A
relates to volume as P = 2
, where A and B are constants. As the volume of the gas is changed from
B
1+  
V
V = B to V = 2B, its change of temperature can be expressed as:
6AB AB −3AB 11AB
(A) (B) (C) (D)
5R 2R 5R 10R
9. A uniform semicircular ring having mass m and radius r is hanging at one of its end (P) freely as shown in the
given figure. The ring is slightly disturbed so that it oscillates in its own plane. The time period of oscillation of
the ring is

r r r 2r
(A) 2π (B) 2π (C) 2π (D) 2π
 1  4 
1/2
 2 
1/2
 2
1/2
g 1 + 2  g 1 − 2  g 1 − 2  g 1 + 2 
 π   π   π   π 

10. A body executes SHM of period 20 seconds. Its velocity is 5 cm/s, 2 seconds after it has passed the mean
22
position. Find the amplitude (in cm) of the bob. (cos 36º = 0.809 and π = )
7
(A) 15.67 (B) 17.67 (C) 19.67 (D) 21.67
2
+bt 2 + 2 abxt )
11. The transverse displacement y(x, t) of a wave on a string is given by y(x, t) = e −(ax . This represents
a ……….

a
(A) wave moving along +x-axis with speed
b

b
(B) wave moving along x-axis with speed
a

(C) standing wave of frequency b

1
(D) standing wave of frequency
b

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12. There are two potential energy (PE) displacement curves as shown for two different particles (of same mass)
doing SHM about same mean position x = 0 on x-axis then we can say.

(A) ω1 > ω2 (B) ω1 < ω2 (C) ω1 =ω2 (D) none

13. The correct figure that shows, schematically, the wave pattern produced by superposition of two waves of
frequencies 9 Hz and 11 Hz is :

(A) (B)

(C) (D)

14. A snapshot of a travelling wave is shown in figure-1 and a snapshot of a standing wave is shown in figure-2.
(Particles are at their respective extremes. The amplitude, frequency, and the speed of both the waves is the
same. The string in both the cases is identical). If the energy per unit length of system at point A in figure-1,
x1
is x1 and that in figure-2 is x2. What is value of ?
x2

(A) 2 : 1 (B) 1 : 2 (C) 1 : 1 (D) 3 : 1

15. A block of mass 1kg is connected to a spring of spring constant π N/ m fixed at other end and kept on
2

smooth level ground. The block is pulled by a distance of 1cm from natural length position and released.
1
After what time does the block compress the spring by cm.
2
2 1 1 1
(A) sec (B) sec (C) sec (D) sec
3 3 6 12
2
16. Consider a gas confined to a horizontal container by means of a piston of area 40cm . If a horizontal force 20
N is exerted on the piston to keep the gas from expanding, find the gas pressure. Atmospheric pressure is
100 kPa.
(A) 100.5 kPa (B) 105.0 kPa (C) 95.0 kPa (D) 99.5 kPa

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17. Two hockey players scratch perpendicular x and y axes into the ice. Player 1 hits a puck so that it travels in
the x-axis direction with constant velocity of magnitude v. Thereafter Player 2 strikes the puck with his stick
so that it travels in the positive y-axis direction with constant velocity of magnitude v. The force which player
2's stick exerted on the puck was directed along:
(A) the negative x-axis.
(B) the positive y-axis.
(C) a line 45 degrees from the negative x-axis and 45 degrees from the positive y-axis.
(D) a line 45 degrees from the positive x-axis and 45 degrees from the positive y-axis.
18. An electric saber saw consists of a blade that is driven back and forth by a pin mounted on the
circumference of a rotating circular disk. As it rotates at a constant angular speed, the pin engages a slot and
forces the blade back and forth. If the figure represents the initial position of the blade, what is the correct
expression for the motion of the blade?

 π
(A) x = R sin  ωt +  (B) x = R sin ωt
 2 
 3π 
(C) x = R sin  ωt + (D) x = R sin ( ωt + π )
 2 
19. A faulty barometer contains some air which occupies 10 cc. If it indicates 740 mm when a correct barometer
indicates 750 mm. Now the same air is kept in a vessel. The volume the air would occupy under pressure of
760 mm is
(A) 1 cc (B) 0.13 cc (C) 1.3 cc (D) 7.5 cc
20. We compress 2 gases to half their original volume during an adiabatic process. One of the gases is
monoatomic and another is diatomic. The ratio of final pressure to the initial pressure.
(A) is more for diatomic gas (B) is more for monoatomic gas
(C) is same for both the gases (D) depends on the number of moles contained.

SECTION-B
21. Two identical containers A and B with frictionless pistons contain the same ideal gas at the same
temperature and the same volume V. The mass of the gas in A is mA and that in B is mB. The gas in each
cylinder is now allowed to expand isothermally to the same final volume 2V. The change in pressure in A and
mA 2
B are found to be ∆P and 1.5 ∆P respectively. If = then find the value of λ .
mB λ

9R
22. An ideal gas has a molar heat capacity C = in the process PT = constant. Find the degree of freedom of
2
the gas molecule. (R = ideal gas constant)
23. When an ideal diatomic gas is heated at constant pressure, during a process. If during the given process, the
∆Q n
ratio = . Find the value of n. (where ∆Q = Heat supplied to the gas during the process, ∆W = work
∆W 2
done by the gas during the process)

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24. If P-V diagram of a diatomic gas during a process is plotted, it is a straight line (when extended it passes
through the origin). If molar heat capacity of the gas in the process is nR. Find the value of n. (where R =
ideal gas constant)
25. An open pipe is suddenly closed at one end with the result that the frequency of third harmonic of the closed
pipe is found to be higher by 100 Hz than the fundamental frequency of the open pipe. Find the fundamental
frequency of the open pipe in Hz.

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 CHEMISTRY (All India Test Series T- 3) 17-11-2024

SECTION-A
26. A mixture contains four solid organic compounds, A, B, C and D. On heating only C changes from solid to
vapour state. C can be separated from the rest in the mixture by-
(A) Distillation (B) Sublimation
(C) Crystallisation (D) Fractional distillation
27. The best method to separate the mixture of ortho and para nitrophenol (1:1) is-
(A) Steam distillation (B) Crystallization
(C) Vapourisation (D) Colour spectrum
28. The separation of mixture of two compounds by chromatographic technique is based upon-
(A) Differential solubilities (B) Different densities
(C) Different absorption (D) Differential adsorption
29. In Lassaigne test thiourea is converted into-
(A) NaCNS (B) Na2S (C) NaCN (D) Na2SO4
30. In a Lassaignes’s test for sulphur in the organic compound with sodium nitroprusside solution the
purple colour formed is due to-
(A) Na4 [Fe(CN)5 NOS] (B) Na3 [Fe(CN)5 S]
(C) Na2 [Fe(CN)5 NOS] (D) Na3 [Fe(CN)6]
31. In Duma’s method, the gas which is collected in Nitrometer is-
(A) N2 (B) NO (C) NH3 (D) H2
32. In organic compounds P is estimated as-
(A) H3PO4 (B) P2O5
(C) Mg3(PO4)2 (D) (NH4)3PO4 .12MoO3
33. Kjeldahl’s method cannot be used for the estimation of nitrogen in:
(A) Pyridine (B) Nitro compounds
(C) Azo compounds (D) All
34. If on adding FeCl3 solution to acidified Lassaigne’s solution, a blood red colouration is produced, it indicates
the presence of -
(A) S (B) N (C) N and S (D) S and Cl
35. Which of the following hydrocarbons give same product on hydrogenation?
(A) 2–Methyl hex–1–ene & 3–Methyl hex –3–ene
(B) 3–Ethyl hex –1 –en–4–yne & 2–Methyhept–2–en–4–yne
(C) 3–Ethylcycloprop–1–ene & 1, 2– Dimethylcycloprop–1–ene
(D) 2–Methylbut–2–ene & 3–Methylbut–1–ene
36. Which of the following alkenes give four monochlorination (structural isomer) product after hydrogenation ?
(A) Pent–2–ene (B) 2–Methylbut–2–ene
(C) 3–Methylhex–2–ene (D) 2,3–Dimethylbut–2–ene
37. Identify E in the following sequence of reaction.

E ( C6H10 ) 
H2 /Ni
→ F ( C6H12 ) 
CL 2 /hυ
→ G ( C6H11CI)( only one isomer )

(A) (B) (C) (D)

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38. Which of the following pairs are tautomers ?

,
(A)

(B) HO – CH2 – CH = CH2 , O = C – CH2 – CH3

,

(C)

(D) CH3 − C− C− CH3 , CH3 − C = C − CH3

|| || | |
O O HO OH
39. Which among the following compounds will give maximum enol content in solution ?
O O O O
|| || || ||
(A) C6H5 − C− CH2 − C− CH3 (B) CH3 − C− CH2 − C− CH3
O O
|| ||
(C) CH3 − C− CH2 − CH2 − CH3 (D) CH3 − C− CH2 − COOC2H5

40. If optical rotation produced by is + 36º then that produced by is

(A) –36º (B) 0º (C) +36º (D) unpredictable

41. Match the following columns
Column-I (Compounds) Column-II (No. of geometrical isomers)
(A) (p) 4

(B) (q) 8

(C) (r) 2

(D) (s) 3

Options:
(A) (A–s); (B–q); (C–r); (D–p)
(B) (A–s); (B–r); (C–r); (D–q)
(C) (A–s); (B–r); (C–q); (D–s)
(D) (A–p); (B–q); (C–r); (D–s)
42. Ethyl methanoate and methyl ethanoate are
(A) homologues (B) stereoisomers (C) metamers (D) chain isomers
43. Which one of the following techniques is not used to spot components of a mixture separated on thin layer
chromatographic plate ?
(A) I2 (Solid)
(B) UV light
(C) Visualisation agent as a component of mobile phase
(D) Spraying of an appropriate reagent
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44. In which of the following structures the indicated atoms do not lie in the same plane :

(A) (B) (C) (D)

45. The maximum number of carbon atoms arranged linearly in the molecule CH3 − C ≡ C − CH =
CH2
(A) 5 (B) 4 (C) 2 (D) 1

SECTION-B
46. The separation of two coloured substances was done by paper chromatography. The distances travelled by
solvent front, substance A and substance B from the base line are 3.25 cm, 2.08 cm and 1.05 cm,
respectively. The ratio of Rf values of A to B is …………
47. 0.400 g of an organic compound (X) gave 0.376 g of AgBr in Carius method for estimation of bromine. % of
bromine in the compound (X) is ……….
–1 –1
(Given : Molar mass AgBr = 188 g mol Br = 80 g mol )
48. A compound P (C7H10) on ozonolysis forms compound given below.

The degree of unsaturation of compound P is x then value of x will be ____

49. If 0.32 gm of an organic compound containing Sulphur produces 0.233g of BaSO4. Then the percentage of
Sulphur in organic compound is x then value of x will be ____
50. 0.2 g of an organic compounds on complete combustion produces 0.44 g of CO2, then the percentage of
carbon in organic compound is x then value of x will be ____

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(All India Test Series T- 3) 17-11-2024 MATHEMATICS

SECTION-A
π
51. Let z and w are two non zero complex number such that |z| = |w| , and Arg (z) + Arg (w) = – then
2
(A) z = iw (B) z = i w (C) z = i w (D) z = – i w
52. If the sides AB, BC and CA of a triangle ABC have 3, 5 and 6 interior points respectively, then the total
number of triangles that can be constructed using these points as vertices, is equal to:
(A) 364 (B) 333 (C) 312 (D) 300
2 2
x y x y
53. The straight line + =1 intersect the ellipse + 1 at two points A and B, there is a point P on the
=
4 3 16 9
ellipse such that the area of ∆ PAB is equal to 3. Then the number of possible point P is/are
(A) 1 (B) 2 (C) 4 (D) 3
54. Four slip of papers with the numbers 1, 2, 3, 4 written on them are put in a box. They are drawn one by one
(without replacement) at random. In how many ways it can happen that the ordinal number of atleast one slip
coincide with its own number?
(A) 24 (B) 9 (C) 15 (D) 4
x2 y2
55. The curve represented by the equation + 1 is
=
sin 2 − sin 3 cos 2 − cos 3
(A) an ellipse with the focii on x-axis (B) an ellipse with the focii on y-axis
(C) an hyperbola with focii on x-axis (D) an hyperbola with focii on y-axis
2
56. Let a line with the inclination of 60° from positive x-axis be drawn through the focus F of the parabola y = 8(x
+ 2). If the two intersection points of the line and the parabola are A and B and the perpendicular bisector of
the chord AB intersect the x-axis at the point P, then the length of segment PF is

16 8 16 3
(A) (B) (C) (D) 8 3
3 3 3
1 + (1 − 8α ) z
57. The set of all α ∈ E , for which w = is a purely imaginary number, for all z ∈ C satisfying |z| =
1− z
1 and Re(z) ≠ 1, is:

 1 1
(A) equal to R (B) an empty set (C) {0} (D) 0, , − 
 4 4
2
58. Let O be the vertex and Q be any point on the parabola, x = 8y. If the point P divides the line segment OQ
internally in the ratio 1 : 3, then the locus of P is
2 2 2 2
(A) x = y (B) y = x (C) y = 2x (D) x = 2y
2
59. The locus of the middle points of chords of the parabola y = 4ax which subtend a right angle at the vertex of
the parabola is
2 2 2 2
(A) y = 2a(x – 4a) (B) y = a(x – 4a) (C) y = 2a(x – a) (D) y = a(x – a)

π x2 y2
60. Let 0 < θ < . If the eccentricity of the hyperbola − 1 is greater than 2, then the length of its
=
2 cos2 θ sin2 θ
latus rectum lies in the interval:
(A) (3/2, 2] (B) (2, 3] (C) (1, 3/ 2] (D) (3, ∞ ]
2
61. 3 + 6i z81
Let z0 be a root of the quadratic equation, x + x +1 = 0. If z = 93
0 − 3i z0 , then arg z is equal to:

π π π
(A) 0 (B) (C) (D)
6 3 4
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 y2 x2 
62. Let S = (x,y) ∈ R2 : − = 1 where r ≠ ±1. Then S represents:
 1+ r 1− r 

2
(A) an ellipse whose eccentricity is , when r > 1 .
r +1
2
(B) a hyperbola whose eccentricity is , when 0 < r < 1 .
1− r
1
(C) an ellipse whose eccentricity is , when r > 1
r +1
2
(D) a hyperbola whose eccentricity is , when 0 < r < 1.
r +1
63. The number of permutations of letters of word HINDUSTAN such that neither the pattern ‘HIN’ nor ‘DUS’ nor
‘TAN’ appears are
(A) 12246 (B) 169194 (C) 166680 (D) 181434
64. If a hyperbola whose foci are S ≡ (2, 4) and S' ≡ (8, –2) touches x-axis, then equation of hyperbola is

( x + y − 6) ( x − y − 4) ( x − y − 4) ( x + y − 6)
2 2 2 2

(A) − 1
= (B) − 1
=
10 8 10 8

( x − y − 4) ( x + y − 6) ( x + y − 6) ( x − y − 4)
2 2 2 2

(C) − 1
= (D) − 1
=
20 16 20 16
65. Let z = x + iy be a complex number where x and y are integers then the area of the rectangle whose vertices
are the roots of the equation zz 3 + zz 3 =
738 is
(A) 10 (B) 20 (C) 40 (D) 80
2
66. If AFB is a focal chord of the parabola y = 4ax and AF = 4, FB = 5, then the latus-rectum of the parabola is
equal to
80 9
(A) (B) (C) 9 (D) 80
9 80
2 2
67. If the equation |z – z1| + | z – z2| = k represents the equation of a circle, where z1 ≡ 2+ 3i, z2 ≡ 4 + 3i are
the extremities of a diameter, then the value of k is
(A) 1 (B) 2 (C) 4 (D) 6
68. Six identical coins are arranged in a row. The number of ways in which the number of tails is equal to
number of heads is
(A) 720 (B) 20 (C) 120 (D) 40
2
69. If k denotes the sum of the imaginary parts of the roots of the equation z – 8(1 – i) z + 63 – 16i = 0 then k is
(A) 6 (B) –6 (C) 8 (D) –8
70. If |z| < 4, then | iz +3 – 4i| is less than
(A) 4 (B) 5 (C) 6 (D) 9
71. A person is to walk from A to B. However, he is restricted to walk only to the right of A or upwards of A. but
not necessarily in the order shown in the figure. Then, the number of paths from A to B via C is ___.

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72. If |z1| = 1, |z2| = 2, |z3| = 3, and |z1 + 3z2 + 2z3| = 5, then the value of |z2z3 + 12z1z3 + 18z1z2| is___.
73. Let P1 be a parabola with vertex (1, 8) and focus (3, –1) and P2 is the mirror image of P1 with respect to the
line 3x – y + 10 = 0. If the focus of P2 is ( α, β ) and directrix of P2 is 7x + 6y = γ , then α + β + γ is equal to

___.
x2 y2 PF1 2
74. Suppose points F1, F2 are the focii of ellipse + 1 , P is a point on the ellipse such that
= = , then
9 4 PF2 1

the area of ∆ PF1F2 is equal to ___.

75. If P is a point on the hyperbola of eccentricity e and A, A’ are the vertices and S, S’ are the focii and ∆ SPS’ :
k
∆ APA’ is equal to e . Then |k| is equal to ___.

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