!

"# $ %& ' ( )

ST

by R S Nagi Sir
ATOMIC STRUCTURE

Single Correct :
1. The distance of closest approach of an -particle projected towards a nucleus with
momentum p is r. What will be the distance of closest approach, when the momentum of
projected -particle is 2p?

(1) 2r (2) 4r (3) (4)

2. Rutherfords experiment , which established the nuclear model of atom, used a beam of :–
(1) - particles, which impinged on a metal foil and get absorbed.
(2) - rays, which impinged on a metal foil and ejected electron.
(3) Helium atoms, which impinged on a metal foil and got scattered.
(4) Helium nuclie, which impinged on a metal foil and got scattered.

3. The angular momentum of an electron in a certain orbit of Li+2 ion is 3.15 ! 10–34 (in SI units).
What will be the potential energy of electron in that orbit ?
(1) –13.6 eV (2) –27.2 eV (3) + 13.6eV (4) –53.4 eV

4. The energy of electron is maximum at

(1) Nucleus (2) Ground state
(3) First excited state (4) Infinite distance from the nucleus

5. If radius of second stationary orbit (in Bohr's atom) is R. Then radius of third orbit will be
(1) R/3 (2) 9R (3) R/9 (4) 2.25R

6. According to Bohr's atomic theory, which of the following relations is/are incorrect?

(1) Kinetic energy of electron

(2) The product of velocity of electron and the principal quantum number z2

(3) Frequency of revolution of the electron in an orbit

(4) Coulombic force of attraction on the electron

7. The angular momentum of an electron of H - atom is proportional to :
1 1
(1) r2 (2) (3) r (4)
r r

8. The energy of an electron in the first Bohr orbit of H atom is 13.6 eV . The possible energy
value(s) of the excited state(s) for electrons in Bohr orbits of hydrogen is/are :
(1) 3.4 eV (2) 4.2 eV (3) 6.8 eV (4) + 6.8 eV

9. Energy of H–atom in the ground state is –13.6 eV, Hence energy in the second excited state
is –
(1) –6.8 eV (2) –3.4 eV (3) –1.51 eV (4) –4.3 eV

10. The shortest wavelength of He atom in Balmer series is x, then longest wavelength in the
Paschen series of Li+2 is
36x 16x 9x 5x
(1) (2) (3) (4)
5 7 5 9

11. The ratio of difference in wavelengths of 1st and 2nd lines of Lyman series in H–like atom to
difference in wavelength for 2nd and 3rd lines of same series is:
(1) 2.5 : 1 (2) 3.5 : 1 (3) 4.5 : 1 (4) 5.5 : 1

12. Number of possible spectral lines which may be emitted in bracket series in H atom, if
electrons present in 9th excited level returns to ground level, are
(1) 21 (2) 6 (3) 45 (4) 5

13. A mono electronic species in energy level with energy 'X' was provided with excess of energy
so that it jumps to higher energy level with energy Y. If it can emit 6 wavelengths originated
from all possible transition between these group levels, then which of the following relation is
correct:
(Here n is the principal quantum number of energy level X) :
(1) X/Y = (n – 1)2 (2) X/Y = 1 + 3/n
(3) (X / Y) = 1+3/n (4) X/Y = n/6

14. In Bohr series of lines of hydrogen spectrum, third line from the red end corresponds to where
one of the following inter-orbit jumps of electron for Bohr orbits in an atom of hydrogen.
(1) 4 1 (2) 2 5 (3) 3 2 (4) 5 2

15. The longest wavelength of He+ in Paschen series is "m", then shortest wavelength of Be+3 in
Paschen series is (in terms of m):
5 64 53 7
(1) m (2) m (3) m (4) m
36 7 8 64
16. When an excited hydrogen atom returned to its ground state, some visible quanta were
observed along with other quanta. Which of the following transitions must have occurred?
(1) 2 1 (2) 3 1 (3) 3 1 (4) 4 1

17. A photon of 300 nm is absorbed by a gas and then re-emits two photons. One re-emitted
photon has wavelength 496 nm, the wavelength of second re-emitted photon is :
(1) 759 (2) 857 (3) 957 (4) 657

18. Electromagnetic radiations having = 310 Å are subjected to a metal sheet having work
function = 12.8 eV. What will be the velocity of photoelectrons with maximum Kinetic Energy..
(1) 0, no emission will occur (2) 2.18 ! 106 m/s
(3) 2.18 2 ! 106 m/s (4) 8.72 ! 106 m/s

19. Graph between kinetic energy of photoelectron KE(max) Vs frequency(v) of an incident photon
is given when light is incident on a metal plate during photoelectric experiment :

KE(max) (Joule)
0

v1
v
Wavelength of light corresponding to frequency v1 is 200 nm. If monochromatic light of
wavelength 100 nm is incident on metal plate then K.E.(max) of ejected photoelectron is :
(1) 1 ! 10–27 J (2) 9.9 ! 10–17 J (3) 9.9 ! 10–19 J (4) 1 ! 10–22 J

20. Approximate De-Broglie wavelength ratio of particle with respect to proton is, if both are
accelerated through same potential difference :
1 1
(1) (2) (3) 2 (4) 8
8 2

21. Wavelength of the de-Broglie wave of an electron revolving in the sixth orbit of the hydrogen
atom is :
(r0 is the Bohr's radius = 0.529 Å)
(1) r0 (2) 12 r0 (3) 6 r0 (4) 24 r0
22. An electron, a proton and an alpha particle have kinetic energies of 16E, 4E and E
respectively. What is the qualitative order of their de Broglie wavelengths?
(1) e > p = (2) p = > e (3) p > e > (4) < e » p

23. A mosquito of 2 mg is moving with a speed of (20 0.1) m/sec. Uncertainty in its position is:
(1) 2.64 ! 10–29 m (2) 2.64 ! 10–28 m (3) 2.64 ! 10–34 m (4) 2.64 ! 10–31 m

24. Assuming Heisenberg Uncertainity Principle to be true what could be the minimum uncertainty
in de-broglie wavelength of a moving electron accelerated by Potential Difference of 6 V
7
whose uncertainty in position is n.m.
22
(1) 6.25 Å (2) 6 Å (3) 0.625 Å (4) 0.3125 Å

25. What is uncertainity in location of a photon of wavelength 5000Å if wavelength is known to an

accuracy of 1 pm?
(1) 7.96 ! 10–14 m (2) 0.02 m (3) 3.9 !10–8 m (4) none

26. Uncertainity in position of a particle of 25 g in space is 10–5 m. Hence uncertainty in velocity

(ms–1) is (Planck’s constant h = 6.6 ! 10–34 Js)
(1) 2.1 ! 10–28 (2) 2.1 ! 10–34 (3) 0.5 ! 10–34 (4) 5.0 ! 20–24

27. Orbital angular momentum associated with 2p - electron is :

2h h h
(1) (2) 0 (3) 6 (4)
2 2

28. The number of nodal planes in a px orbital is:

(1) one (2) two (3) three (4) zero

29. Which quantum number is not related with Schrodinger equation

(1) Principal (2) Azimuthal (3) Magnetic (4) Spin

30. The quantum numbers +1/2 and –1/2 for the electron spin represent:
(1) rotation of the electron in clockwise and anticlockwise direction respectively.
(2) rotation of the electron in anticlockwise and clockwise direction respectively.
(3) magnetic moment of the electron pointing up and down respectively.
(4) two quantum mechanical spin states which have no classical analogue.
Integer Value :
31. How many unpaired electron are present in Ni2+-

32. In an atom, the total number of electrons having quantum numbers n = 4, |m | = 1 and
ms = –1/2 is

33. Not considering the electronic spin, the degeneracy of the second excited state (n = 3) of H
atom is 9, while the degeneracy of the second excited state of H– is!

34. The minimum and maximum number of electrons which may have magnetic quantum number,
1
m = +1 and spin quantum number, s = – in chromium (Cr) are x & y respectively then find
2
(x + y).

35. What atomic number of an element “X” would have to become so that the 4th orbit around X
would fit inside the 1st Bohr orbit of Hydrogen ?

36. Consider Xenon (Z = 54). The maximum number of electrons in this atom that can have the
1
values for their quantum numbers as n = 4, = 3 and s = in its ground state is :
2