Scribd
Upload
18 views

Experiment - 9

Uploaded by

yashrajsinhp0505
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
18 views

Experiment - 9

Uploaded by

yashrajsinhp0505
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 3

Experiment - 9

Aim: - To identify acidic and basic radical in the given salt.


S.No Experiment Observation Inference
1. Preliminary Test
Physical Examination:
i) Physical State Crystalline Solid May be Ca2+ cation is
present
ii) Colour White Cu2+, Fe2+, Ni2+ are
absent
iii) Odour Odourless
iv) Solubility Soluble May be sulphate,
nitrate or chloride salt
2. Flame Test:- A small amount of Brick red colour Ca2+ may be present
salt is made into paste with flame is observed
conc.HCl in a watch glass
introduce in the flame
Identification of Acidic Radical
1. Dilute H2SO4 Test :- No gas evolved 𝐶𝑂32−, 𝑆𝑂32−, 𝑆 2− is
Salt + dil. H2SO4 absent
2. Concentrated H2SO4 Colourless gas, −
𝐶𝑙 𝑚𝑎𝑦 𝑏𝑒 𝑝𝑟𝑒𝑠𝑒𝑛𝑡
Salt + Conc. H2SO4+ Heat having pungent
smell, gives white
dense fumes with rod
dipped in NH4OH

Preparation of Sodium Carbonate Extract or Soda Extract: - Take 1g of salt in boiling


tube + 3g of solid sodium carbonate + add 15 ml of distilled water and boil for 10 minutes cool
the filtrate and label it as sodium carbonate extract.
Confirmatory Test

4. AgNO3 Test:- To soda extract, White ppt insoluble in 𝐶𝑙 − confirmed


add dil HNO3. Boil off CO2. conc. HNO3 but
Cool and add 1 ml AgNO3 soluble in NH4OH
solution.
5. MnO2Test :- Take about 0.2 g Evolution of greenish 𝐶𝑙 − confirmed
solid salt in test tube. Add aboutyellow gas having
4 g of MnO2 and 2 ml of conc. pungent smell, turns
H2SO4. Heat the tube. moist starch iodide
paper blue
6. Chromyl Chloride Test: - To a Yellow ppt soluble in 𝐶𝑙 − confirmed
small quantity of salt, add solid NaOH solution.
potassium dichromate and
conc. H2SO4. Heat the test tube
and pass the gas evolved

Smita Singh
(chromyl chloride gas) through
NaOH solution. If yellow
solution is obtained, add acetic
acid and 2 ml of lead acetate
solution.
Note :- Write reaction With Pencil
i) Silver nitrate Test: - NaCl + AgNO3 → AgCl ↓ + NaNO3
white ppt
AgCl + 2NH4OH → [ Ag(NH3)2] Cl + 2H2O
Diammine Silver (I) chloride(soluble)

ii) Maganese dioxide Test :-


BaCl2 + MnO2 + 2H2SO4 → BaSO4 + MnSO4 + 2H2O + Cl2 ↑
iii) Chromyl Chloride Test :-
K2CrO7 + 2H2SO4 → 2KHSO4 + 2CrO3 + H2O
Chromic Anhydride
KCl + H2SO4 → HCl + KHSO4

CrO3 + 2 HCl → CrO2Cl2 + H2O


Chromyl Chloride ( Red Vapours)
4 NaOH + Cr2O2Cl2 → Na2CrO4 + 2NaCl + H2O
( Yellow Solution)
(CH3COO)2 Pb + Na2CrO4→ 2CH3COONa + PbCrO4↓
Lead acetate (Yellow ppt)

Identification of Basic Radical

1. To a little salt add 2 ml of No ammoniacal smell O group ( N𝐻4+)


NaOH solution + Heat evolved absent.
2. To about 2 ml of O.S. add dil . No white ppt 1st group ( Pb2+)
HCl obtained absent.
3. To O.S, add dil. HCl and heat. No ppt 2nd group absent
Pass H2S gas into the solution.

4. Take original solution in a 3rd group is absent


beaker and add conc. HNO3 No ppt
and boil this to this solution
add excess of NH4OH until
smell of NH3.

5. Original Solution + NH4Cl + No ppt 4th group is absent


NH4OH + Pass H2S
6. Original solution + + NH4Cl + White ppt 5th group present (
NH4OH + (NH4)2 CO3 Ca2+, Ba2+ ,Sr2+ may
be present)

Smita Singh
Confirmatory Test:-
7. Dissolve the ppt in acetic acid
and divide it into three parts.
a) To 1 part of the solution add No yellow ppt Ba2+ absent
potassium chromate solution.
b) To 2nd part of the solution add No White ppt Sr2+ absent
ammonium sulphate solution.
c) To 3rd part of the solution White ppt Ca2+ confirmed
ammonium oxalate solution
Note :- Write reaction With Pencil
Test for Ca2+
Ca2+ + (NH4)2CO3 → CaCO3 + 2N𝑯𝟒+
CaCO3 + 2CH3COOH → (CH3COO)2 Ca + H2O + CO2
(CH3COO)2Ca + (NH4)2C2O4 → CaC2O4 + 2CH3COONH4
White ppt

Result: - Acid radical – 𝑪𝒍−


Basic radical – Ca2+

Smita Singh

You might also like