Material Safety Data Sheets – Standard F/E Lists Version

by the City University of Hong Kong

(This file contains only the MSDSs (in ascending order of MSDS no.) of the chemicals with quantities
specified in the following list. Please refer to the supplementary version for other chemicals which may
be used/kept in your laboratories. Only the list in the full version is hyperlinked to each MSDS. Please
use search function of Acrobat Reader to locate the relevant MSDS i.e. enter “0159” in the search dialog
box for MSDS no.159.)

Chemicals/Reagents Hazard MSDS Quantity in Standard F/E Lists for Sec Schools
Nature* CityU Green Chem Chem Bio Bio IS
MSDS No.
Cross+ (S4-5) (AL) (S4-5) (AL)
Acetanilide (H) 101
Aceto Orcein (C) 554 10 g
Agar 188 500 g 500 g
Albustix, bottle of 50 563 6 bot.
Aluminium, foil 189 250 g 250 g
Aluminium, powder (F) 189
Aluminium chloride, anhydrous (C) 103 100 g
Aluminium chloride, crystal 102 100 g
Aluminium nitrate 555
Aluminium oxide 159 500 g 500 g
Aluminium sulphate 160 500 g
1-Aminobutane 280 250 mL
Aminoethanoic acid 041 100 g
2-Aminopropanoic acid 401
(L-Alanine)
Ammonia, anhydrous F T 402 11/91
Ammonia, solution, 0.880 (C) 006 2.5 L 2.5 L 2.5 L
(35% w/w)
Ammonia, >35% solution C 006
Ammonia, 10-35% solution I 006
Ammonia, ≥ 6 M solution (C) 006
Ammonia, ≥ 3 M & < 6 M solution (I) 006
Ammonium aluminium sulphate 191 500 g
Ammonium carbonate 161 500 g
Ammonium chloride (H) 162 2 kg 500 g
Ammonium dichromate E I 403
Ammonium iron(II) sulphate 192 500 g
Ammonium iron(III) sulphate 193 500 g
Ammonium molybdate(VI)-4-water (H) 008 100 g
Ammonium nitrate (O) 009 250 g
Ammonium sulphate 163 500 g
Ammonium thiocyanate (H) 011
Ammonium vanadate(V) (T) 007 100 g
Amylase 501 10 g
Amyl acetate (Pentyl ethanoate) F 272
Antimony(III) chloride C 165
Antimony(V) chloride C 194
Arsenic compounds T 390
Arsine T 514
Ascorbic acid tablets, bottle of 100 404 1 bottle
tablets

1
 Chemicals/Reagents Hazard MSDS Quantity in Standard F/E Lists for Sec Schools
Nature* CityU Green Chem Chem Bio Bio IS
MSDS No.
Cross+ (S4-5) (AL) (S4-5) (AL)
Barium chloride (H) 014 500 g 250 g
Barium hydroxide (H) 405
Barium nitrate (O) (H) 104 250 g
Barium peroxide O H 406
Barium sulphate 407
Benedict’s solution 484 500 mL 1L
Benzaldehyde F H 105 200 mL
Benzene F T 015 1/91
Benzene-1,2-diol (Catechol) (H) 106
Benzene-1,3-diol (Resorcinol) H 079
Benzene-1,4-diol (Quinol) (H) 408
Benzene-1,3,5-triol (Phloroglucinol) (H) 459 25 g
Benzenecarboxylic acid (Benzoic 016 250 g
acid)
Benzoyl chloride C 109 100 mL
Benzoyl peroxide E I 409
Benzyl alcohol H 110
Benzyl benzoate H 410
Benzyl chloride F I 111
Beryllium T 502
Beryllium compounds (except T 391
alumium beryllium silicates)
Bicarbonate indicator
Bile salt (sodium 100 g
tauroglycochlolate)
Bismuth(III) chloride (I) 166 100 g
Bismuth(III) nitrate (O) (I) 167
Biuret reagent (C) (I) 503
Bleaching powder (O) (C) 504 1 kg
Borax 485
Boric acid, crystal 017
Boron trichloride T 486
Bromine, 1 mL ampoule C 019 5 amp 10 amp
Bromine water (H) 019
2-Bromo-2-methylpropane (F) (H) 114 100 mL
Bromobenzene (F) (I) 018 100 mL
1-Bromobutane (F) (I) 112 100 mL
2-Bromobutane (F) 113 100 mL
Bromocresol green 195
Bromophenol blue 411
Bromothymol blue 196 10 g
Buffer tablet, pH 7 505 50 tab
Butan-1-ol F H 115 1L
Butan-2-ol F H 116 500 mL
Butanal (F) 506 250 mL
Butane F 412
Butanedioic acid (Succinic acid) 117 100 g
Butanoic acid (butyric acid) (C) 157 100 mL
Butanone F 413 1/95 500 mL

2
 Chemicals/Reagents Hazard MSDS Quantity in Standard F/E Lists for Sec Schools
Nature* CityU Green Chem Chem Bio Bio IS
MSDS No.
Cross+ (S4-5) (AL) (S4-5) (AL)
cis-Butenedioic acid (Maleic acid) I 414 100 g
n-Butyl ethanoate F 279 7/97
Butylamine (F) (I) 280
Calcium, turnings (F) 171 50 g 100 g 250 g
Calcium carbide F 507
Calcium carbonate, marble chips 197 2 kg 500 g 2 kg
Calcium carbonate, precipitated 197 500 g 500 g
Calcium chloride, anhydrous (I) 198 1 kg 500 g 1 kg
Calcium chloride, crystal (I) 415
Calcium ethanedioate 416
Calcium ethanoate 199 250 g
Calcium hydroxide (I) 118 1 kg 500 g 500 g 500 g
Calcium hydroxide, solution (Lime 118
water)
Calcium hypochlorite, solution with O C 417
active chlorine >39%
Calcium nitrate (O) (I) 169 500 g 500 g
Calcium oxide (C) 170 500 g 1 kg
Calcium phosphate monobasic 418
(Calcium tetrahydrogen
diphosphate(V))
Calcium sulphate 200 500 g
Calcium sulphate- 2-water 200
Canada balsam, dried 508 25 g
Carbon disulphide F T 020 1/96
Casein, powder 487 100 g 100 g
Castor oil 419 250 mL
Cerium(III) nitrate 509
Cerium(IV) sulphate (I) 187
Charcoal, animal 201 1 kg
Charcoal, block of 70 mm 201 24 pcs 10 pcs
Charcoal, wood powder 201 500 g 500 g
2-Chloro-2-methylpropane 420 500 mL
Chlorobenzene F H 119 11/98 100 mL
1-Chlorobutane (F) 421 100 mL
2-Chlorobutane (F) (H) 510
Chloroethanoic acid T 351 11/97 100 g
Chromium 488
Chromium(III) chloride (H) 023 100 g
Chromium(VI) oxide O C 203
Chlorine T 489
Chlorine water (C) 556
Citric acid 172 25 g 100 g 100 g 500 g
Clinistix, bottle of 50 (T) 6 bot.
Cobalt(II) chloride (H) 422 250 g
Cobalt(II) nitrate (H) 204 250 g
Copper, foil 205 500 g 500 g
Copper, plate 205 500 g
Copper, powder 205 100 g

3
 Chemicals/Reagents Hazard MSDS Quantity in Standard F/E Lists for Sec Schools
Nature* CityU Green Chem Chem Bio Bio IS
MSDS No.
Cross+ (S4-5) (AL) (S4-5) (AL)
Copper, turnings 205 1 kg
Copper, wire, 22 s.w.g. 205 250 g
Copper(II) carbonate (H) 207 500 g
Copper(II) chloride, solid (T) 208 250 g
Copper(II) chloride, ≥ 1.4 M solution (T) 208
Copper(II) chloride, ≥ 0.15 M & (H) 208
< 1.4 M solution
Copper(II) chromate(VI) (T) 557
Copper(II) nitrate-3-water (H) 511 250 g 250 g
Copper(I) oxide (H) 206
Copper(II) oxide (H) 209 250 g 250 g
Copper pyrites
Copper(II) sulphate-5-water (H) 210 2 kg 500 g 500 g 2 kg
Copper(II) sulphate, ≥ 1 M solution (H) 210
Copper(II) sulphide (H) 512
Cotton wool, absorbent 2 reels
Cresol, all isomers T 559
Cresol red 423 5g 5g
Crude oil (F) (T) 120 500 mL 500 mL
Cumene (Isopropyl benzene) F I 424
Cyclohexane F 121 250 mL
Cyclohexanol H 024 3/98 250 mL
Cyclohexanone F H 025 3/97 500 mL
Cyclohexene (F) (I) 122 500 mL
Decanedioyl dichloride (C) 529
Decanedioyl dichloride, hexane (F) 529/
solution 532
Dettol 530 1L
Diastase 513
1,2-Dichlorobenzene H 425
1,4-Dichlorobenzene H 426
1,2-Dichloroethane F H 427
Dichloromethane H 026
2,4-Dichlorophenolindophenol 5g
(DCPIP)
Diethylamine F I 123 250 mL
Dimethylamine F I 291
Dimethylbenzene (H) 100
Dinitrobenzene, all isomers T 560
2,4-Dinitrophenylhydrazine (E) (T) 124 25 g
Dinitrotoluene, all isomers T 490
Diphenylamine (T) 032 100 g
Disulphur dichloride (C) 428 250 mL
Eosin, alcoholic solution (F) 564
Eosin, 16% aqueous solution 430
Eosin B 429 25 g
Eosin Y, yellowish 430 25 g
Eriochrome black T 431
Ester wax, for section cutting

4
 Chemicals/Reagents Hazard MSDS Quantity in Standard F/E Lists for Sec Schools
Nature* CityU Green Chem Chem Bio Bio IS
MSDS No.
Cross+ (S4-5) (AL) (S4-5) (AL)
Ethanal (acetaldehyde) F I 158 11/96 500 mL
Ethanal, >30% solution T 158
Ethanal, 5-30% solution I 158
Ethanamide (H) 393 100 g
Ethane-1,2-diamine F C 036 7/00 500 mL
Ethanedioic acid (Oxalic acid) H 491 3/96 500 g
Ethanedioic acid, salts of H 142
Ethane-1,2-diol (Ethylene glycol) H 305 3/99
Ethanoic acid, glacial F C 002 3/92 500 mL 500 mL 500 mL 1L
Ethanoic acid C 002
Ethanol, absolute F 034 500 mL 500 mL
Ethanol, 95% F 034 2L 1L 1L 2.5 L
Ethanol, denatured F 515
Ethanoyl chloride F C 531
Ethoxyethane F 027 7/96 250 mL
Ethyl benzoate 125 100 mL
Ethyl ethanoate F 035 500 mL 2.5 L
Ethyl propanoate F 432
Ethylamine, 70% w/w aqueous (F) (I) 126 250 mL
solution
Ethylbenzene F I 306
Ethylenediaminetetraethanoic acid 127 500 g
disodium salt
Ethyne F 433
Fehling solution No. 1 (H) 492
Fehling solution No. 2 (C) 493
Fluorine T 494
Fluorescein 434
D(-)-Fructose 211 25 g
Gelatin 435
D(+)-Glucose 516 250 g 500 g 100 g 100 g
Heptane (F) 341
Hexane (F) (H) 042 7/98 500 mL
Hexane, mixture of isomers with F H 495
>5% n-hexane
Hexane, mixture of isomers with F 532
<5% n-hexane
Hexane-1,6-diamine (C) (H) 128 25 g
Hexanedioic acid (Adipic acid) (I) 436
Hexanedioyl dichloride (Adipoyl (C) 437 25 mL
chloride)
Hexan-1-ol (H) 438
Hydrazine F T 497
Hydrazine, 5-64% solution C 496
Hydrochloric acid, conc. (36% w/w) (C) 043 5L 2.5 L 2.5 L
~11 M
Hydrochloric acid, >25% C 043
Hydrochloric acid, 10-25% I 043
Hydrochloric acid, ≥ 6.5 M (C) 043
Hydrochloric acid, ≥ 2 M & < 6.5 M (I) 043

5
 Chemicals/Reagents Hazard MSDS Quantity in Standard F/E Lists for Sec Schools
Nature* CityU Green Chem Chem Bio Bio IS
MSDS No.
Cross+ (S4-5) (AL) (S4-5) (AL)
Hydrofluoric acid T C 044
Hydrogen F 439
Hydrogen chloride, anhydrous C 440
Hydrogen cyanide F T 565
Hydrogen cyanide, salts of, except T 084
complex cyanides eg
ferrocyanides, ferricyanides,
mercuric oxycyanide
Hydrogen fluoride, anhydrous T C 517 3/95
Hydrogen peroxide, 20-60% C 045 5/97
solution
Hydrogen peroxide, 20 volumes (6% (I) 045 250 mL 500 mL 250 mL 500 mL
w/w)
Hydrogen sulphide F T 441 1/00
DL-Hydroxypropanoic acid (C) 518
(DL-Lactic acid)
Indigo carmine 442
Invertase 50 mL
Iodine H 129 9/98 250 g 100 g 100 g 250 g
Iodine, ≥ 1 M solution (H) 498
1-Iodobutane (F) (H) 443 50 mL
Iron, coarse filings 212 1 kg
Iron, fine clean filings 212 500 g 1 kg
Iron, wire 30 s.w.g. 499 1 reel 1 reel
Iron(II) chloride-4-water (H) 500
Iron(II) sulphate (H) 213 100 g 250 g
Iron(II) sulphide (H) 519 250 g
Iron(II) sulphide, granulated (H) 519 250 g
Iron(III) chloride, anhydrous (I) 038
Iron(III) chloride-6-water (I) 376 500 g 250 g
Iron(III) nitrate (O) (I) 214 250 g
Iron(III) oxide, powder 215 500 g
Iron(III) sulphate (I) 444 500 g
Iron pyrites 558
Isopropyl ethanoate F 445 3/00
Isopropyl methanoate F 377
Lacmoid, dry 533 5g
Lead, foil (T) 216 500 g 500 g
Lead, shot, 3mm 378 1 kg
Lead compounds in general H 534
Lead(II) bromide (T) 520 250 g
Lead(II) carbonate (T) 217
Lead(II) chloride (T) 218 100 g
Lead(II) ethanoate (T) 051 500 g
Lead(II) iodide (T) 521
Lead(II) nitrate (O) (T) 052 1 kg
Lead(II) oxide (T) 219 250 g 250 g
Lead(II,IV) oxide (Red lead oxide) (T) 536 100 g
Lead(IV) oxide (T) 173 100 g
Lead(II) sulphate (T) 446

6
 Chemicals/Reagents Hazard MSDS Quantity in Standard F/E Lists for Sec Schools
Nature* CityU Green Chem Chem Bio Bio IS
MSDS No.
Cross+ (S4-5) (AL) (S4-5) (AL)
Lead(II) sulphide (T) 522
Leishman's stain, for blood smears (F) 537 10g
(in methanol solution)
Lithium, in liquid paraffin (F) (C) 221 10 g
Lithium chloride (H) 220 50 g
Litmus, granulated 379 50 g
Luminol 538
Lycopodium powder 539
Lysol (T) 566
Magnesium, powder F 447
Magnesium, ribbon (F) 223 2 reels 4 reels
Magnesium carbonate 380 500 g
Magnesium oxide 448 500 g
Magnesium sulphate, anhydrous 311 500 g
Magnesium sulphate-7-water 224 500 g
Manganese 381
Manganese(II) chloride 225 250 g
Manganese(IV) oxide H 226 500 g 250 g
Manganese(II) sulphate-4-water 540 500 g
Mercury, redistilled (T) 348 1/93
Mercury compounds in general T 054
Mercury(I) chloride (Calomel) H (T) 130
Mercury(II) chloride (T) 054 100 g
Mercury(I) nitrate (T) 175
Mercury(II) nitrate (T) 174
Mercury(II) oxide (T) 176
Metaphosphoric acid 382
Methanal (T) 131 3/91 250 mL 1L 500 mL
Methane F 449
Methanoic acid (formic acid) (C) 039 250 mL
Methanoic acid, >25% C 039
Methanol F T 057 5/92 500 mL
Methoxyethane F 542
Methoxymethane F 541
Methyl cellulose (Polycell), 2-3%
solution
Methyl ethanoate F 353
Methyl 2-methylpropenoate F I 543 250 mL
Methyl orange 227 25 g 50 g
Methyl orange, alcoholic solution (F) 227/
034
Methyl red 228 10 g
Methyl red, alcoholic solution (F) 228
Methyl salicylate (Oil of (H) 134
Wintergreen)
Methylated spirit (F) (T)
Methylene blue, alkaline (F) (H) 383 100 mL
Methylene blue, alkaline (Loeffler), (H) 383 10 g
nuclear stain

7
 Chemicals/Reagents Hazard MSDS Quantity in Standard F/E Lists for Sec Schools
Nature* CityU Green Chem Chem Bio Bio IS
MSDS No.
Cross+ (S4-5) (AL) (S4-5) (AL)
Methylamine F I 450
Methylbenzene (Toluene) F H 096 7/93 1L 500 mL
2-Methylbutane (iso-Pentane) (F) 133
2-Methylpropan-1-ol (H) 451 500 mL
2-Methylpropan-2-ol F H 132 500 mL
Millon’s reagent (T) 544
Naphthalen-2-ol (Naphth-2-ol) (H) 452 100 g
Nickel, plate 229 500 g 500 g
Nickel-chromium wire, 20 s.w.g., 2 reels
reel of 125 g
Nickel-chromium wire, 32 s.w.g., 2 reels
reel of 125 g
Nickel(II) chloride (H) 060 250 g 250 g
Nickel(II) sulphate (H) 231 250 g
Ninhydrin (H) 453
Ninhydrin, aerosol (H) 453
Nitric acid, conc. O C 061 5/96 2.5 L 2.5 L 1L 2.5 L
Nitric acid, >70% (~16M) O C 061
Nitric acid, 20-70% C 061
Nitric acid, ≥ 0.5 M (C) 061
Nitric acid, ≥ 0.1 & < 0.5 M (I) 061
Nitrobenzene T 135
Nutrient agar 545
Octadecan-1-ol 454
Octadecanoic acid (stearic acid) 136 250 g
Octane, all isomers F 455
Paraffin oil (Kerosene) (F) 177 500 mL 1L
Paraffin wax 456 1 kg
Pentan-1-ol (Amyl alcohol) F 457 500 mL
Pentan-3-one F 523
n-Pentane (F) 332
Perchloric acid, >50% O C 062
Perchloric acid, 10-50% C 062
Pepsin 458 25 g
Peptone, bacteriological 546 50 g
Petroleum distillates & coal tar, with F 346
flash point < 66°C
Petroleum ether, 60-80°C (F) (H) 346
Petroleum ether, 100-120°C (F) 346 500 mL
Phenol (C) (T) 063 250 g
Phenol red, dry 232 5g
Phenolphthalein, dry 233 25 g 50 g
Phenolphthalein, 60% alcoholic (F) 233/
solution 034
Phenyl ammonium chloride (T)
Phenylamine (Aniline) T 012 500 mL
Phenylamine, salts T 547
Phenylethene (Styrene) F I 336 5/95 250 mL
Phenylhydrazine (T) 138

8
 Chemicals/Reagents Hazard MSDS Quantity in Standard F/E Lists for Sec Schools
Nature* CityU Green Chem Chem Bio Bio IS
MSDS No.
Cross+ (S4-5) (AL) (S4-5) (AL)
Phenylsalicylate (Salol) 549
Phosphoric(V) acid (C) 065 500 mL
(Orthophosphoric acid)
Phosphoric(V) acid, >25% C 065
Phosphoric(V) acid, 10-25% I 065
Phosphorus(III) chloride C 384 9/97 100 mL
Phosphorus(V) chloride C 139 1/97 50 g
Phosphorus(V) oxide C 140 100 g
Phosphorus, yellow F T 548
Phosphorus, red F 460
Phthalic anhydride (I) 461
Polymer kit. Comprising 8 1 kit
containers of polythene,
polystyrene, perspex, PVC,
polypropene, nylon, bakelite and
urea methanal. Each kind of
plastic being contained in plastic
vial, 80 g.
Potassium, in liquid paraffin (F) (C) 524 25 g
Potassium aluminium sulphate 234 1 kg
Potassium bromate (O) (T) 178 250 g
Potassium bromide 068 250 g 250 g
Potassium carbonate (I) 235 500 g
Potassium chlorate O H 179 1/98
Potassium chloride 236 250 g 250 g
Potassium chromate(VI) I 070 100 g 250 g 500 g
Potassium cyanide T 069 3/93
Potassium dichromate(VI) I 180 9/96 500 g 500 g
Potassium dihydrogen phosphate 237 250 g
di-Potassium hydrogen phosphate 033 250 g
Potassium ethanedioate (H) 142
Potassium fluoride T 385
Potassium hexacyanoferrate(II) (T) 182 250 g 100 g
Potassium hexacyanoferrate(III) (T) 181 250 g 100 g
Potassium hydrogencarbonate 238 250 g 250 g
Potassium hydrogensulphate (C) 239
Potassium hydroxide, pellets C 071 500 g 500 g
Potassium hydroxide, >5% solution C 071
Potassium hydroxide, 1-5% solution I 071
Potassium hydroxide, ≥ 0.5 M (C) 071
solution
Potassium hydroxide, ≥ 0.05 M & (I) 071
< 0.5 M solution
Potassium iodate(V) (O) 072 250 g
Potassium iodide 073 250 g 1 kg 250 g 500 g
Potassium manganate(VII) O H 074 1/99 500 g 250 g 500 g
(Potassium permanganate)
Potassium nitrate (O) 184 500 g 250 g 1 kg
Potassium nitrite O T 392 9/99
Potassium perchlorate O H 141

9
 Chemicals/Reagents Hazard MSDS Quantity in Standard F/E Lists for Sec Schools
Nature* CityU Green Chem Chem Bio Bio IS
MSDS No.
Cross+ (S4-5) (AL) (S4-5) (AL)
Potassium persulphate (O) (H) 143
Potassium sodium (+)-tartrate 075 250 g
Potassium sulphate 240 500 g
Potassium thiocyanate (H) 076 250 g
Propan-1,2,3-triol (Glycerol, 309 500 mL 250 mL 250 mL
Glycerine)
Propan-1-ol F 077 500 mL
Propan-2-ol F 078 9/92 500 mL
Propanal (F) (I) 144 250 mL
Propanedioic acid (malonic acid) (H) 145
Propanoic acid (C) 462
Propanone F 003 7/91 2.5 L 500 mL 1L
Pumice stone 242 200 g 200 g
Pyridine F H 463
Pyrogallol (Benzene-1,2,3-triol), (H) 464 50 g
resublimed
Pyrogallol (Benzene-1,2,3-triol), (C) 561
alkaline solution
Rocksil 250 g 500 g
Safranine, water and alcohol soluble 465 25 g
Safranine, 1% alcoholic solution (F) 465/
034
Salicylic acid (H) 146 100 g
Schiff’s reagent (I) 386
Schultze’s solution (C) 100 mL
Silica 550
Silica gel 466
Silicon 525 100 g
Silicon(IV) oxide 466 500 g
Silicon tetrachloride (I) 147 100 g
Silver nitrate C 081 5/99 50 g 100 g
Silver nitrate, ≥0.5 M solution (C) 081
Silver nitrate, ≥0.2 M & <0.5 M (I) 081
solution
Silver oxide (O) (I) 244 25 g
Soda lime (C) 148 500 g 250 g 500 g
Sodium, in liquid paraffin (F) (C) 149 25 g
Sodium benzoate 467 500 g
Sodium bromide 468 250 g
Sodium carbonate, anhydrous (I) 245 1 kg 1 kg 1 kg
Sodium chlorate O H 469
Sodium chloride, fine 246 2 kg 250 g 2 kg
Sodium citrate 247 100 g 100 g
Sodium cyanide T 084 3/93
Sodium dichromate I 365
Sodium ethanedioate (H) 150 250 g
Sodium ethanoate, anhydrous 470 500 g 500 g
Sodium fluoride (T) 151
Sodium hydrogencarbonate 249 1 kg 500 g 500 g 500 g

10
 Chemicals/Reagents Hazard MSDS Quantity in Standard F/E Lists for Sec Schools
Nature* CityU Green Chem Chem Bio Bio IS
MSDS No.
Cross+ (S4-5) (AL) (S4-5) (AL)
diSodium hydrogenphosphate 471
Sodium hydrogensulphate (C) 250
Sodium hydrogensulphite H 472 500 g
Sodium hydroxide, pellets C 085 1 kg 1.5 kg 500 g 1 kg
Sodium hydroxide, >5% solution C 085
Sodium hydroxide, 1-5% solution I 085
Sodium hydroxide, ≥ 0.5 M solution (C) 085
Sodium hydroxide, ≥ 0.05 M & (I) 085
< 0.5 M solution
Sodium hypochlorite, solution with C 371 9/94
>10% active chlorine
Sodium hypochlorite, solution with I 551
5-10% active chlorine
Sodium iodide 473 250 g
Sodium nitrate (O) (I) 185 250 g
Sodium nitrite O T 152 250 g
Sodium nitroprusside (T) 252
Sodium oxalate 150
Sodium perchlorate O H 387
Sodium peroxide O C 474 100 g
Sodium persulphate (O) (I) 475
Sodium silicate (I) 254
Sodium sulphate 087 500 g
Sodium sulphate, anhydrous 087 500 g
Sodium sulphide C 153
Sodium sulphite 476 250 g 250 g
Sodium thiosulphate 186 500 g 1 kg 500 g
Solder 500 g
Sorbic acid 250 g
Starch 256 250 g 250 g 500 g 100 g 500 g
Strontium chloride 257 100 g
Strontium nitrate (O) (H) 258 100 g
Succinic anhydride I 477
Sucrose 478 250 g 500 g
Sudan III, dry 479 20 g
Sudan III, alcoholic solution (H) (F) 479/
034
Sulphur, crushed (F) 154 1 kg 1 kg
Sulphuric acid, conc. (97% w/w) C 090 11/94 5L 2.5 L 2.5 L
(~18 M)
Sulphuric acid, >15% C 090
Sulphuric acid, 5-15% I 090
Sulphuric acid, ≥ 0.5 M & < 1.5 M (C) 090
solution
Sulphuric acid, ≥ 1.5 M solution (I) 090
Test paper, blue litmus 379 3 packs 1 pk 10 bks
Test paper, cobalt chloride 422 1 pk 10 bks 10 bks
Test paper, lead ethanoate 535 1 pk
Test paper, neutral litmus 379 3 pks 4 pks
Test paper, pH, range 1-14 262 12 pks 4 pks 10 bks 4 rolls

11
 Chemicals/Reagents Hazard MSDS Quantity in Standard F/E Lists for Sec Schools
Nature* CityU Green Chem Chem Bio Bio IS
MSDS No.
Cross+ (S4-5) (AL) (S4-5) (AL)
Test paper, red litmus 379 3 pks 1 pk 10 bks
Test paper, starch iodide 073 1 pk
Tetrachloroethene H 480
Tetrachloromethane T 021 5/91
Thionyl chloride C 337
Thiourea (Thiocarbamide) (H) 094
Thymol blue, dry 481 5g 5g
Thymol blue, alcoholic solution (F) 562
Tin, foil 526 100 g 250 g 250 g
Tin(II) chloride (H) 095 100 g
Tin(IV) chloride C 260 100 g
1,1,1-Trichloroethane H 155 7/92
Trichloromethane H 022 250 mL
Triethylamine F I 482
Trimethylamine F I 483 250 mL
Trypsin 527
Tumeric paper
Turpentine F H 156 11/95
Universal indicator, alcoholic (F) 262 100 mL 100 mL 250 mL
solution
Urea 099 250 g 500 g 500 g
Urease 528 25 g
Vanadium(V) oxide H 388 5/98
Vaseline 552 100 g 500 g 100 g
Volasil 244 F 500 mL 500 mL
Xylene (dimethylbenzene) F H 100 500 mL
Xylene, all isomers F H 100 11/99
Yeast, dry 553
Zinc, foil 265 250 g 250 g
Zinc, granulated 266 1 kg 500 g
Zinc, plate 265 500 g
Zinc, powder (dust) F 265 500 g
Zinc carbonate 263 250 g
Zinc chloride C 264 5/00 250 g
Zinc nitrate (O) (H) 267 100 g
Zinc oxide 389
Zinc sulphate (I) 190 250 g 500 g

* Key to the codes representing hazard natures:

E = Explosive F = Flammable O = Oxidising
T = Toxic H = Harmful C = Corrosive I = Irritant
Classification is made with reference to the “Factories and Industrial Undertakings (Dangerous Substances)
Regulations (Cap. 59 Section 7)” (The regulations apply to industrial undertakings and processes).
Codes in brackets represent recommendations from UK and European regulations.

+ Green Cross is a bimonthly magazine published by the Occupational Safety and Health Council
(OSHC). Usually one Material Safety Data Sheet (MSDS) in Chinese is provided on every issue and MSDSs
for about 60 chemicals have been released so far. The magazine is available in the OSHC Library located at
19/F, China United Centre, 28 Marble Road, North Point, Hong Kong (Tel. 2739 9779) or through free
subscription.
Science Section, ED, Jan 2001

12
 M.S.D.S. 0002

Material Safety Data Sheet

City University of Hong Kong

MSDS ACETIC ACID GLACIAL 0002

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Acetic Acid Glacial

Chinese Name:
Synonyms: Ethanoic Acid,Ethylic Acid, Methane Carboxylic Acid, Vinegar Acid
Chemical Family: Organic Acid
Molecular Formula: CH3COOH
C.A.S. : 64-19-7
Product Use: -

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Appearance And Odour: Colourless with sharp vinegar odour
Boiling Point: 118 deg. C
Vapour Density (Air=1): 2.1
Specific Gravity: 1.05
pH: Not Applicable
Solubility In Water: Complete

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability; Flammable

Flash Point: 43 deg. C
Flammable Limits: Lower 4% Upper 20%
Special Fire Fighting Procedures
Fire-fighter should wear a self-contained breathing apparatus and protective clothing to prevent contact
with skin and eyes. Use water spray to cool nearby containers and structures exposed to fire.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Incompatibility:
Alkalis, oxidizing or reducing materials, cyanides, sulfides, combustible materials, chromic acid, nitric
acid, hydrogen peroxide, active metals, amines, oxides and carbonates.

Hazardous Decomposition Products: May liberate carbon monoxide and carbon dioxide.

========================================================================
HEALTH HAZARD DATA
========================================================================

ROUTE OF ENTRY:
------------------------------------------------------------------------
Eye :
Vapours, liquid, and mists are extremely corrosive to the eyes. Brief contact of the vapours will be
severely irritating. Brief contact of the liquid or mists will severely damage the eyes and prolonged
contact may cause permanent eye injury which may be followed by blindness.

Skin :
Vapours, mists, and liquid are extremely corrosive to the skin. Vapours will severely irritate the skin and
liquid and mists will severely burn the skin. Prolonged liquid contact will burn or destroy surrounding
tissues and death may accompany burns which extend over large portions of the body.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0002
Ingestion : Vapours, mists, and liquid are extremely corrosive to the mouth and throat.
Swallowing :
The liquid burns the tissues, causes severe abdominal pain,nausea, vomiting, and collapse. Swallowing
large quantity can cause death.

Inhalation :
Vapours and mists are extremely corrosive to nose, throat, and mucous membranes. Bronchitis,
pulmonary oedema, and chemical pneumonitis may occur. Irritation, coughing, chest pain, and difficulty
in breathing may occur with brief exposure while prolonged exposure may result in more severe
irritation and tissue damage. Breathing high concentration may result in death.

Toxicological Properties:
Acgih Threshold Limit Value (TLV): 10 ppm
Osha Permissive Exposure Limit (PEL): 10 ppm
Oral: Rat LD 50 = 3310 mg/kg
Dermal: Rabbit LD 50 = 1060 mg/kg
Inhalation: (Irritant); Mouse LC50 = 5620 ppm/ 1 Hr.

========================================================================
FIRST AID MEASURES
========================================================================

Eye : Immediately flush eyes with plenty of water for at least 15 minutes. Call a physician.
Skin :
Immediately flush skin with plenty of water. Remove contaminated clothing and shoes; wash before
reuse. Get immediate medical attention.

Ingestion : Give large amount of water if person is conscious. Call a physician.

Inhalation :
If overexposed, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult,
give oxygen and call a physician.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Ventilation capable of maintaining emissions at the point of use below the pel. Local exhaust
recommended

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
Wear a niosh-approved respirator appropriate for the vapour or mist concentration at the point of use.
Appropriate respirators may be a full facepiece air-purifying cartridge respirator equipped for organic
vapours/acid gas, a self-contained breathing apparatus in the pressure demand mode, or a supplied-air
respirator.

Eye protection: Safety glasses with side shields are recommended.

Skin Protection: Impervious gloves should be worn, wash thoroughly after handling.

Storage Requirements:
Store in a cool, dry, well ventilated area away from incompatible materials. Keep container tightly
closed. Store in accordance with federal, provincial and municipal regulation. Do not store or consume
food, drinks, or tobacco in area where they may become contaminated with this material. Do not store
below 12 deg. C (55 deg. F).

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spills:
Review fire and explosion hazard and safety precaution before proceeding with the clean up, use
appropriate personal protective equipment during clean up. For small spills or drips, mop or wipe up
and dispose of in DOT-approved waste containers. For large spills, contain by diking with soil or other
non-combustible absorbent material and carefully neutralize with soda ash or lime. If soda ash is used,
provide adequate ventilation to dissipate carbon dioxide gas.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0003

Material Safety Data Sheet

City University of Hong Kong

MSDS ACETONE 0003

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Acetone

Chinese Name:
Synonyms: Dimethylketone,2-Propanone,Pyroacetic Ether
Chemical Family : Ketone
Molecular Formular: CH3COCH3
Cas No. 67641

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

Appearance And Odour: Clear, colourless liquid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Boiling Point : 134 deg. F
Specific Gravity: 0.791 (H2O=1)
pH Of Undiluted Product: N.A.
Vapour Pressure: 157@20 mmHg
Viscosity: N.D.
Percent Voc: 100
Vapour Density: 2.0
Solubility In Water: Sol.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Flash Point (Method): -4 deg. F
Flammable Limits (%) Lower: 2.6. Upper: 12.8
Ignition Temp. : N.D.
Recommended Fire Extinguishing Agents And Special Procedures:
According to nfpa guide, use dry chemical, foam, or carbon dioxide. water may be ineffective on
flames, but should be used to cool fire-exposed containers. If a leak or spill has not ignited, use water
spray to disperse the vapours and to provide protection for personnel attempting to stop the leak.

Unusual Or Explosive Hazards:

Danger extremely flammable materials may release vapours that travel a considerable distance to a
source ignition and flash back. Containers may explode in a fire. Do not expose to heat, sparks, flame,
static, or other sources of ignition. When handling, use non-sparking tool, ground and bond all
containers. Explosive air-vapour mixtures may form.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerizations: Will not occur
Incompatibility: Acid, strong oxidizers
Products Evolved When Subjected To Heat Or Combustion:
Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and ketones.

========================================================================
HEALTH HAZARD DATA
========================================================================

Effects Of Overexposure:
Acute:
Eyes:
May cause irritation, experienced as discomfort, and seen as excess redness and swelling of the eye.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0003

Skin:
No adverse effects expected from absorption of material through the skin. Brief contact may cause
slight irritation. Prolonged contact, as with clothing wetted with material, may cause more severe
irritation and discomfort, seen as local redness and swelling.

Inhalation:
Vapours or mist may cause irritation of the nose and throat, headache, nausea, vomiting, dizziness,
drowsiness, euphoria, loss of coordination, and disorientation. In poorly ventilated areas or confined
spaces, unconsciousness and asphyxiation may result.

Ingestion:
If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhea may occur.
Aspiration may occur during swallowing or vomiting resulting in lung damage.

Sensitization properties: unknown.

Chronic: Repeated skin contact may cause a persistent irritation or dermatitis.
Medical Conditions Aggravated By Exposure:
Because of its irritating properties, repeated skin contact may aggravate an existing dermatitis (skin
condition).

Other Remarks: None

Toxicological Information(Animal Toxicity Data)

Median Lethal Dose (LD 50 LC50) (Species)
Oral: 8.5-10.7 g/kg (Rat); Practically non-toxic
Inhalation: N.D.
Dermal: 20 g/kg (Rabbit); Practically non-toxic
Irritation Index, Estimation Of Irritation (Species)
Skin: Believed To Be 0.5-3.0/8.0 (Rabbit); Slightly irritating
Eyes: Believed To Be 25-50/110 (Rabbit); Moderately irritating
Sensitization: N.D.
Other: None

Ventilation: Adequate to meet occupational exposure limits. (see below)

Exposure Limit For Total Product:
750 ppm (1,780 mg/m3) TWA (ACGIH)
750 ppm TWA (OSHA)
1000 ppm STEL (OSHA/ACGIH)

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes. Hold eyelids apart while flushing to
rinse entire surface of eye and lids with water. Get medical attention.

Skin:
Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation
develops or persists.

Ingestion:
If swallowed, get immediate medical attention. Only induce vomiting as directed by a doctor. Never
give anything by mouth to an unconscious or convulsing person.

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, qualified
personnel may administer oxygen. Get immediate medical attention.

Other Instructions:
Note to physician: aspiration of this product during induced emesis can result in lung injury. If
evacuation of stomach contents is considered necessary, use method least likely to cause aspiration, such
as gastric lavage after endotracheal intubation.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Protective Equipment (Type)

Eye/Face Protection:
Avoid eye contact. Chemical type goggles should be worn. Do not wear contact lenses.

Skin Protection:
Workers should wash exposed skin several times daily with soap and water. soiled work clothing should
be laundered or dry-cleaned at least once a week.

Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If vapour, mist or dust is generated,
use respirator approved by MSHA or NIOSH as appropriate. Supplied air respiratory protection should
be used for cleaning large spills or upon entry into tanks, vessels, or other confined spaces. See below
for applicable permissible concentrations.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0003
Precautions To Be Taken In Handling And Storage:
Use spark-proof tools. Keep away from heat, sparks, flame and other sources of ignition. Material may
be at elevated temperatures and/or pressures. Exercise due care when opening bleeders and sampling
ports.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Procedures In Case Of Accidental Release, Breakage Or Leakage:

Eliminate all ignition sources including internal combustion engines and power tools. Ventilate area.
Keep people away. Stay upwind and warn of possible downwind explosion hazard. Avoid breathing
vapour. Wear self-contained breathing apparatus. Avoid contact with skin, eyes or clothing. Use
self-contained breathing apparatus or supplied air mask for large spills or confined areas. Contain spill
if possible. Remove with inert absorbent. Prevent entry into sewers and waterways.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0006

Material Safety Data Sheet

City University of Hong Kong

MSDS AMMONIA SOLUTION 0006

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Ammonia Solution

Chinese Name:
Synonyms: Aqua Ammonia, Ammonium Hydroxide
Chemical Family: Alkali
Formula: NH4OH
CAS No.: 1336-21-6

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

Boiling Point : 82-105 deg. F Vapour Pressure, mmHg/20 deg. C: 560

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point : -97 deg. F Vapour Density (Air=1): 0.60
Specific Gravity (Water=1): 0.90-0.913 Water Solubility, %: 100
Appearance And Odour: Clear, water-white liquid, strong pungent ammonia odour
Evaporation Rate (Butyl Acetate=1): >1

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Nonflammable

Flash Point : None
Flammable Limits Lower: 16 Upper: 25
Extinguishing Media: Use water spray, dry chemical or CO2.
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards:

Flammable ammonia gas will be liberated at all temperatures which can be explosive under some
conditions. The addition of this product to concentrated mineral acids will cause instant boiling and a
possible explosion.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibilities:
Acids, oxidizing materials, copper, aluminum, zinc, galvanized metals, gold, silver, and alloys of these
metals.

Hazardous Decomposition Products: Ammonia gas and oxides of nitrogen.

Conditions To Avoid: Heat, sparks, and open flames.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Inhalation, skin or eye contact.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0006
Signs And Symptoms Of Exposure:
Inhalation:
Vapours and mists are extremely corrosive to the nose, throat, and mucous membranes. Bronchitis,
pulmonary edema, and chemical pneumonitis may occur. Irritation, coughing, chest pain, and difficulty
in breathing may occur with brief exposure while prolonged exposure may result in more severe
irritation and tissue damage. Breathing high concentrations may result in death.

Eye Contact:
Vapours, liquid, and mists are extremely corrosive to the eyes. Brief contact of the vapours will be
severely irritating. Brief contact of the liquid or mists will severely damage the eyes and
pro-prolonged contact may cause permanent eye injury which may be followed by blindness.

Skin Contact:
Vapours, mists, and liquid are extremely corrosive to the skin. Vapours will severely irritate the skin
and liquid and mists will severely burn the skin. Prolonged liquid contact will burn or destroy
surrounding tissue and death may accompany burns which extend over large portions of the body.

Swallowed:
Vapours, mists, and liquid are extremely corrosive to the mouth and throat. Swallowing the liquid
burns the tissues, causes severe abdominal pain, nausea, vomiting, and collapse. Swallowing as little
as a teaspoonful of this product can cause death.

Chronic Effects Of Exposure: No specific information available.

Medical Conditions Generally Aggravated By Exposure:

Persons with pre-existing eye or pulmonary disease may be susceptible to aggravation from exposure.

Oral: Human LDLO=43 mg/kg; Rat LD50=350 mg/kg

Dermal: No data available
Inhalation: Human LDLO=1000 ppm/3hr; mouse LC50=4837 ppm/1hr; Human LCLO=5000 ppm

Carcinogenicity:
This material is not considered to be a carcinogen by the nationaltoxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

Other Data:
Human inhalation TCLO=408 ppm. odour is perceptible at 5 ppm, causes discomfort at 150-200 ppm, is
severely irritating at 400-700 ppm, may be fatal within 30 min at 2000-3000 ppm, and is immediately
fatal at 10,000 ppm.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 30 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately flush skin with lots of running water for 30 minutes. Remove contaminated clothing and
shoes; wash before reuse. Get immediate medical attention.

If Swallowed:
Do not induce vomiting. If conscious, give lots of water. Get immediate medical attention. Do not give
anything by mouth to an unconscious or convulsing person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the pel.

Respiratory Protection:
If use conditions generate vapours or mists, wear a niosh-approved respirator appropriate for those
emission levels. Appropriate respirators may be a full facepiece respirator equipped with ammonia
cartridges, a self-contained breathing apparatus in the pressure demand mode, or a supplied-air
respirator.

Eye Protection:
Chemical goggles and full faceshield unless a full facepiece respirator is also worn. It is generally
recognized that contact lenses should not be worn when working with chemicals because contact lenses
may contribute to the severity of an eye injury.

Protective Clothing:
Alkali-resistant slicker suit with rubber apron, rubber boots with pants outside, and rubber gloves with
gauntlets.

Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0006
Storage And Handling Precautions:
Store in a cool, dry, well-ventilated place away from incompatible materials. Vent container frequently,
and more often in warm weather, to relieve pressure. Keep container tightly closed when not in use. Do
not use pressure to empty container. Wash thoroughly after handling. do not get in eyes, on skin, or on
clothing.

Repair And Maintenance Precautions:

Do not cut, grind, weld, or drill on or near this container.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear alkali-resistant slicker suit and complete protective equipment including rubber gloves, rubber
boots, and a self-contained breathing apparatus in the pressure demand mode or a supplied-air
respirator. If the spill or leak is small, a full face piece air-purifying cartridge respirator equipped with
ammonia filters may be satisfactory. In any event, always wear eye protection. For small spills or
drips, mop or wipe up and dispose of in DOT-approved waste containers. For large spills, contain by
diking with soil or other non-combustible absorbent material and carefully neutralize with dilute
hydrochloric acid. Keep non-neutralized material out of sewers, storm drains, surface waters, and soil.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0007

Material Safety Data Sheet

City University of Hong Kong

MSDS AMMONIUM META-VANADATE 0007

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Ammonium Meta-Vanadate

Chinese Name:
Common Synonyms: Ammonium Vanadate(V); Vanadic Acid, Ammonium Salt
Chemical Family: Vanadium Compounds
Formula: NH4VO3
Formula Wt.: 116.98
Cas No.: 7803-55-6
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapour Pressure (mmHg): N/A
Melting Point: 200 deg. C (392 deg. F) Decomposes Vapour Density (Air=1): 4.0
(@ 760 mmHg)
Specific Gravity: 2.33 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Slight (0.1-1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odour Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odour: White to light yellow crystalline powder. Odourless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Nonflammable

Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Flash Point (Closed Cup): N/A
Flammable Limits: Upper - N/A Lower - N/A
Autoignition Temperature: N/A
Toxic Gases Produced: Ammonia, oxides of vanadium
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: Closed containers exposed to heat may explode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibles: None identified
Decomposition Products: Ammonia, oxides of vanadium
Conditions To Avoid: Moisture

========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): Not established

Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0007
Toxicity Of Components:
Oral Rat LD 50 For Ammonium Meta-Vanadate 160 mg/kg
Intraperitoneal Rat LD 50 For Ammonium Meta-Vanadate 18 mg/kg
Subcutaneous Rat LD50 For Ammonium Meta-Vanadate 23 mg/kg
Carcinogenicity: NTP: No IARC: No Z List: No OSHA Reg: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Effects Of Overexposure:
Inhalation: Irritation of upper respiratory tract
Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified

Target Organs: None identified

Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, give large amounts of water. Induce vomiting.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact:
In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a dust/mist
respirator is recommended. If concentration exceeds capacity of respirator, a self-contained breathing
apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements: Keep container tightly closed. Store in secure poison area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. with clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0008

Material Safety Data Sheet

City University of Hong Kong

MSDS AMMONIUM MOLYBDATE, 4-HYDRATE 0008

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Ammonium Molybdate, 4-Hydrate

Chinese Name:
Common Synonyms: Ammonium Heptamolybdate, Tetrahydrate
Chemical Family: Molybdenum Compounds
Formula: (NH4)6MO7O24 4H2O
Formula Wt.: 1235.86
CAS No.: 12054-85-2
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapour Pressure (mmHg): N/A
Melting Point: 190 deg. C (374 deg. F) Decomposes Vapour Density (Air=1): 2.5
(@ 760 mmhg)
Specific Gravity: 2.27 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: 5 (5% Solution)
Odour Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odour: White to yellow-green crystals. Odourless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Nonflammable

Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Flash Point (Closed Cup): N/A
Flammable Limits: Upper - N/A Lower - N/A
Autoignition Temperature: N/A
Toxic Gases Produced: Ammonia
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: Closed containers exposed to heat may explode.

========================================================================
REACTIVITY DATA
========================================================================

Hazardous Polymerization: Will not occur

Incompatibles: Strong acids
Decomposition Products: Ammonia
Conditions To Avoid: Heat

========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): 5 mg/m3

Tlv Is For Molybdenum, Soluble Compounds, As Mo.
Short-Term Exposure Limit (STEL): Not established

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0008
Permissible Exposure Limit (PEL): 5 mg/m3
Pel Is For Molybdenum, Soluble Compounds, As Mo.
Toxicity Of Components:
Oral Rat LD 50 For Ammonium Molybdate, 4-Hydrate 333 mg/kg
Carcinogenicity: NTP: No IARC: No Z List: No OSHA Reg: No
Carcinogenicity: None Identified.
Reproductive Effects: None Identified.
Effects Of Overexposure:
Inhalation: Irritation of upper respiratory tract
Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: May be harmful
Chronic Effects: None identified

Target Organs: Respiratory System, Lungs, In Animals: Kidneys, blood

Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give water, milk, or milk of
magnesia.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact:
In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
high-efficiency particulate respirator is recommended. If concentration exceeds capacity of respirator, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. with clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0009

Material Safety Data Sheet

City University of Hong Kong

MSDS AMMONIUM NITRATE 0009

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Ammonium Nitrate

Chinese Name:
Common Synonyms: Ammonium (I) Nitrate; Nitric Acid, Ammonium Salt
Chemical Family: Ammonium Salts
Formula: NH4NO3
Formula Wt.: 80.04
CAS NO.: 6484-52-2
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 210 deg. C (410 deg. F) Decomposes Vapour Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 170 deg. C (338 deg. F) Vapour Density (Air=1): 2.8
(@ 760 mmHg)
Specific Gravity: 1.73 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: 5.4 (0.1M Solution)
Odour Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odour: White granules. Odourless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Nonflammable

Fire Extinguishing Media: Use water spray.
Flash Point (Closed Cup): N/A
Flammable Limits: Upper - N/A Lower - N/A
Autoignition Temperature: N/A
Toxic Gases Produced: Ammonia, oxides of nitrogen
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Note: decomposes at boiling point. Strong oxidizer. Contact with combustible materials, flammable
materials, or powdered metals can cause fire or explosion.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibles:
Strong reducing agents, combustible materials, strong acids, organic materials, chemically active metals,
powdered metals

Decomposition Products: Ammonia, oxides of nitrogen

Conditions To Avoid: Heat, shock, flame

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0009
========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): Not established

Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Ammonium Nitrate 4820 mg/kg
Oral Rat LD 50 For Ammonium Nitrate 4820 mg/kg
Oral Rat LD 50 For Ammonium Nitrate 4820 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No
Carcinogenicity: None identified.
Reproductive Effects: None Identified.
Effects Of Overexposure:
Inhalation: tightness and pain in chest, coughing, difficult breathing
Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Headache, nausea, vomiting, gastrointestinal irritation, convulsions, unconsciousness
Chronic Effects: None identified

Target Organs: Eyes, Skin

Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, uniform, butyl rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.
Isolate from incompatible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Keep combustibles (wood, paper,
oil, etc.) away from spilled material. With clean shovel, carefully place material into clean, dry
container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0012

Material Safety Data Sheet

City University of Hong Kong

MSDS ANILINE 0012

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Aniline

Chinese Name:
Common Synonyms: Benzamine; Aniline Oil, Phenylamine; Aminobenzene; Benzenamine
Chemical Family: Amines
Formula: C6H5NH2
Formula Wt.: 93.13
CAS NO.: 62-53-3
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CPHK for their inaccuracies.
Physical State: Liquid
Boiling Point: 184 deg. C (363 deg. F) Vapour Pressure (mmHg): 0.6
(@ 760 mmHg) (20 deg. C)
Melting Point: -6 deg. C (21 deg. F) Vapour Density (Air=1): 3.22
(@ 760 mmHg)
Specific Gravity: 1.02 Evaporation Rate: <1
(H2O=1) (Butyl Acetate = 1)
Solubility(H2O): 3.6% % Volatiles By Volume: 100
(21 deg. C)
pH: 8.1 (0.2M Solution)
Odour Threshold (ppm): 1.0
Coefficient Water/Oil Distribution: N/A
Appearance & Odour: Colourless viscous liquid. Sweet odour.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Fire Extinguishing Media: Use water spray, carbon dioxide, dry chemical or ordinary foam.
Flash Point (Closed Cup): 69 deg. C (158 deg. F)
Flammable Limits: Upper - 11.0 % Lower - 1.3 %
Autoignition Temperature: 614 deg. C (1139 deg. F)
Toxic gases produced: ammonia, oxides of nitrogen, carbon monoxide, carbon dioxide
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapours may flow along surfaces to distant ignition sources and flash back. Closed containers exposed
to heat may explode. Contact with strong oxidizers may cause fire.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibles:
Strong oxidizing agents, strong bases, strong acids, alkalies, zinc, aluminum, leather, solutions containing
iron salts

Decomposition Products: Oxides of nitrogen, ammonia, carbon monoxide, carbon dioxide

Conditions To Avoid: Heat, flame, other sources of ignition, air, light

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CPHK for their inaccuracies.
 M.S.D.S. 0012
========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): 7.6 mg/m3 (2 ppm)

The TLV Listed Denotes TLV (Skin).
Short-Term Exposure Limit (STEL): Not Established
Permissible Exposure Limit (PEL): 8 mg/m3 (2 ppm)
The PEL Listed Denotes PEL (Skin).
Toxicity Of Components:
Oral Rat LD 50 For Aniline 250 mg/kg
Skin Rat LD50 For Aniline 1400 mg/kg
Intraperitoneal Rat LD 50 For Aniline 420 mg/kg
Inhalation-7hr Mouse LC 50 For Aniline 175 ppm
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No
Carcinogenicity: Tests on laboratory animals indicate material may be carcinogenic.
Reproductive Effects: Tests on laboratory animals indicate material may be mutagenic.

Effects Of Overexposure:
Inhalation:
May be fatal, causes methemoglobulin formation in the blood, cyanosis, unconsciousness, headache,
nausea, vomiting, dizziness, confusion, drowsiness

Skin Contact: Irritation

Eye Contact: Severe irritation, permanent eye damage
Skin Absorption:
May be fatal, causes methemoglobulin formation in the blood, cyanosis, unconsciousness, headache,
nausea, vomiting, dizziness, confusion, drowsiness

Ingestion:
May be fatal, causes methemoglobulin formation in the blood, cyanosis, unconsciousness, headache,
nausea, vomiting, dizziness, confusion, drowsiness

Chronic Effects: Anemia, And Skin Lesions, Kidney Damage, Liver Damage

Target Organs: Blood, cardiovascular system, liver, kidneys, central nervous system
Medical Conditions Generally Aggravated By Exposure:
Central nervous system disorders, cardiovascular disorders, liver disorders, bone marrow disease,
kidney disorders

Primary Routes Of Entry: Inhalation, absorption, ingestion, eye contact, skin contact

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CPHK for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, give large amounts of water. Induce vomiting.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Thorough cleansing of the entire contaminated area of the body
including scalp and nails is of the utmost importance.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.
Notes To Physician:
Absorption of this product into the body leads to the formation of methemoglobulin. If signs of excessive
methemoglobinemia develop (cyanosis, vomiting, shock, coma) - give 100% oxygen by mask and 1%
methylene blue solution intravenously (1 to 2 mg/kg of body weight over 5 to 10 minutes). This may be
repeated in 1 hour if necessary. Thorough cleansing of the entire contaminated area of the body is of
utmost importance. Reversion of methemoglobin to hemoglobin occurs spontaneously. Moderate degrees
of cyanosis need be treated only by supportive measures such as bed rest and oxygen. Cyanocobalamin
(B12), 1 mg intramuscularly, may speed recovery. Intravenous fluids and blood transfusions may be
indicated in very severe circumstances.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. at concentrations up to 100
ppm, a chemical cartridge respirator with organic vapour cartridge is recommended. Above this level, a
self-contained breathing apparatus is recommended.

Eye/Skin Protection:
Safety goggles and face shield, uniform, protective suit, butyl rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area or
cabinet. Keep product out of light.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CPHK for their inaccuracies.
 M.S.D.S. 0012
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapours.
take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CPHK for their inaccuracies.
 M.S.D.S. 0014

Material Safety Data Sheet

City University of Hong Kong

MSDS BARIUM CHLORIDE 0014

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Barium Chloride Dihydrate

Chinese Name:
Chemical Family: Chlorates
Molecular Formula: BaCl 2.2H2O
C.A.S. : 10361-37-2
Product Use:
In manufacture of barium salts, insecticide, rat poison, pigments, boiler detergent, etc; in tanning and
finishing leather; in purifying sugar; as mordant in dyeing and printing textiles, as water softener.

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CPHK for their inaccuracies.
Physical State: Solid
Odour And Appearance: Colourless, odourless crystals
Odour Threshold: Not applicable
Vapour Pressure: Not applicable Vapour Density: Not applicable
Evaporation Rate: Not applicable pH: 5% Solution - 5.2 TO 8.2
Boiling Point: Not available Melting Point: 963 deg. C
Solubility In Water: 31 g/100 ml @ 0 deg. C
Specific Gravity: (H2O = 1) 3.856 Molecular Weight: 244.28
% Volatile By Volume: Not available
Bulk Density: Not available
Coefficient Of Water/Oil Distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Conditions Of Flammability: Non-Flammable

Means Of Extinguishing: Dry chemical, sand
Flash Point: Not applicable
Explosion Hazards: None
Upper Flammable Limit: Not applicable
Lower Flammable Limit: Not applicable
Auto Ignition Temperature: Not applicable
Hazardous Combustion Products: Not applicable
Special Fire Fighting Procedures: None

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong acids
Hazardous Reactions/Decompositions:
Contact with strong acid will liberate dangerous gases (I.E. HCl, Cl 2, NO2)

Conditions To Avoid: Reacts violently with bromine trifluoride, 2-furan percaboxylic acid.

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Toxic - TLV 0.5 mg/m3 As Ba

Skin Contact: Irritant
Eye Contact: Irritant
Ingestion: Toxic by ingestion, 0.8 g may be fatal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CPHK for their inaccuracies.
 M.S.D.S. 0014
Chronic Exposure Effects: Not available
Overexposure Effects:
Stiffness, immobility of the limbs, leg cramps, central nervous system stimulation, then depression.

Exposure Limits: Inhalation - TLV 0.5 mg/m3 As Ba

Irritancy: Medium
Mutagenicity: Not available
Carcinogenicity: Not Carcinogenic (IARC and ACGIH)
Sensitization To Product: Not available
Reproductive Toxicity: Not available
Toxicologically Synergistic Materials: Not available
Teratogenicity Data: Not available
Animal Toxicity Data: LD 50 (Oral, Rat) 118 mg/kg

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
Skin Contact:
Immediately flush skin with water for 15 minutes. Wash with salt. Decontaminate clothing before reusing.

Eye Contact: Immediately flush eyes with water for at least 15 minutes. Call physician.
Ingestion:
Immediately give 1 tablespoon of epsom salt in a glass of water induce vomiting by sticking finger down
throat, if necessary. Never give anything by mouth to an unconscious person. Call physician.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection: Approved dust mask or respirator.

Skin Protection: Rubber gloves and impervious clothing.
Eye/Face Protection: Safety goggles.
Special Handling Procedures:
Avoid all contact with eyes and mouth or with food. No eating or smoking during handling.
Decontaminate before breaks or going home.

Storage Requirements: Store away from acids in a dry area.

Engineering Controls: Local and general.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CPHK for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps In The Event Of A Leak Or Spill:

Add an excess of dilute sulphuric acid to a solution of the product in water. Let stand overnight. Remove
any insolubles and bury in an approved chemical landfill. Inform proper authorities.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CPHK for their inaccuracies.
 M.S.D.S. 0016

Material Safety Data Sheet

City University of Hong Kong

MSDS BENZOIC ACID 0016

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Benzoic Acid

Chinese Name:
Common Synonyms: Carboxybenzene; Benzenecarboxylic Acid; Phenylformic Acid; Dracylic Acid
Chemical Family: Organic Acids
Formula: C6H5COOH
Formula Wt.: 122.12
C.A.S.: 65-85-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 249 deg. C (480 deg. F) Vapour Pressure (mmHg): <1
(@ 760 mmHg) (20 deg. C)
Melting Point: 122 deg. C (251 deg. F) Vapour Density (Air=1): 4.2
(@ 760 mmHg)
Specific Gravity: 1.32 Evaporation Rate: <1
(H2O=1) (Butyl Acetate = 1)
Solubility(H2O): Slight (0.1-1%) % Volatiles By Volume: N/A
(21 deg. C)
pH: N/A
Odour Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odour: White crystals. Faint pleasant odour.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Fire Extinguishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)
Flash Point (Closed Cup): 120 deg. C (250 deg. F)
Flammable Limits: Upper - N/A Lower - N/A
Autoignition Temperature: N/A
Toxic Gases Produced: Carbon monoxide, carbon dioxide
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibles: Strong bases, strong oxidizing agents, alkalies
Decomposition Products: Carbon monoxide, carbon dioxide
Conditions To Avoid: Heat, flame, other sources of ignition, moisture

========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): Not established

Short-Term Exposure Limit (STEL): Not established

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0016
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Benzoic Acid 2350 mg/kg
Oral Mouse LD 50 For Benzoic Acid 2370 mg/kg
Intraperitoneal Mouse LD 50 For Benzoic Acid 1460 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No
Carcinogenicity: None Identified.
Reproductive Effects: None Identified.

Effects Of Overexposure:
Inhalation: Severe Irritation Or Burns Of Mucous Membranes
Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None Identified
Ingestion: Gastrointestinal Irritation, Nausea, Vomiting
Chronic Effects: None Identified

Target Organs: None Identified

Medical Conditions Generally Aggravated By Exposure: None Identified
Primary Routes Of Entry: None Indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0018

Material Safety Data Sheet

City University of Hong Kong

MSDS BROMOBENZENE 0018

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Bromobenzene

Chinese Name:
Chemical Family: Aromatic Hydrocarbon
Chemical Formula: C6H5Br
C.A.S.: 108-86-1
Product Use: For Test Purposes

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

Odour And Appearance: Colourless liquid with an aromatic odour

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odour Threshold (ppm): Not available
Vapour Pressure (mmHg): 10 mmHg @ 40 deg. C
Vapour Density (Air=1): 5.441
Evaporation Rate: Not available
Boiling Point : 154-158 deg. C
Freezing Point : -31 deg. C
pH: Not Available
Specific Gravity: 1.497
Coefficient Of Water/Oil Distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flammability: Flammable.
Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur.

Extinguishing Media: CO2, foam, dry powder or vaporizing liquid.

Flash Point (Method Used): 51 deg. C/cc
Upper Flammable Limit (% By Volume): 3.0%
Lower Flammable Limit (% By Volume): .5%
Autoignition Temperature: 566 deg. C
Hazardous Combustion Products: COx

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Incompatibility : Oxidizing materials. mixtures of 1-bromo-butane and sodium metal.
Reactivity: Heat, flame, sparks
Hazardous Decomposition Products: Highly toxic fumes of bromine compounds.

========================================================================
HEALTH HAZARD DATA
========================================================================

LD50: (Oral Rat) 2699 mg/kg

LC50: (Inh. Rat) 20 mg/l
Effects Of Acute Exposure To Product:
Inhaled: Irritates. May be aspirated into lungs with the risk of pneumonia and pulmonary injury.
In Contact With Skin: Irritates. Symptoms parallel ingestion. Assumed harmful if absorbed by skin.
In Contact With Eyes: Irritates
Ingested:
Harmful. Ingestion may cause abdominal pain, nausea, vomiting, diarrhea, headache, dullness, central
nervous system effects, and death.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0018
Effects Of Chronic Exposure To Product:
Carcinogenicity: No information available
Teratogenicity: No information available
Reproductive Effects: No information available
Mutagenicity: No information available
Synergistic Products: None found

========================================================================
FIRST AID MEASURES
========================================================================

Eyes: Wash thoroughly with water. Get medical advice if irritation develops.
Skin:
Remove contaminated clothing. Wash skin with plenty of water for at least fifteen (15) minutes. If
irritation develops seek medical attention.

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing.
Rinse mouth thoroughly with water. Do not induce vomiting. Have victim drink 220-400 ml of water to
dilute. seek medical attention.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls: Local exhaust ventilation recommended

Respiratory Protection: Self-contained breathing apparatus
Eye Protection: Chemical safety goggles or face shield
Skin Protection: Plastic apron, sleeves and boots as appropriate. Nitrile gloves.
Other Personal Protective Equipment: Safety shower and eye-wash fountain in work area.

Handling Procedures And Equipment:

Use approved flammable liquid storage containers in the work area. Ground drums and bond transfer
containers. Use non-sparking tools. Keep material away from sparks, flames and other ignition sources.
Post "no smoking" signs in area of use.

Storage Requirements:
Store in suitable labelled containers. Keep containers tightly closed when not in use and when empty.
Protect from damage. Store in a cool, dry, well-ventilated area, out of direct sunlight. Store away from
ignition sources.

========================================================================
ENVIRONMENTAL PROTECTION DATA

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================

Leak And Spill Procedure:

Absorb on inert absorbent, transfer carefully into container and arrange removal by disposal company.
Wash site of spillage thoroughly with water and detergent.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0019

Material Safety Data Sheet

City University of Hong Kong

MSDS BROMINE 0019

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Bromine

Chinese Name:
Chemical Family: Halogen Element
Molecular Formula: Br 2
C.A.S. : 7726-95-6

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

Boiling Point : 137.8 deg. F Vapour Pressure, mmHg/20 deg. C: 226
Melting Point : N/D Vapour Density (Air=1): 7.139

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Specific Gravity (Water=1): 3.12 Water Solubility, %: N/D
Appearance And Odour: Crystals or dark red liquid
Evaporation Rate (Butyl Acetate=1): N/D

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Extinguishing Media: Use water spray, dry chemical, CO2, or alcohol foam.
Flash Point : None
Flammable Limits In Air, % Lower: N/D Upper: N/D
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards: None.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility:
Reducing agents, combustible materials such as wood, cloth, or organic materials, metals such as iron
and copper and their alloys, alkali, and dirt.

Hazardous Decomposition Products: Hydrogen bromide

Conditions To Avoid: None.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Inhalation, skin or eye contact.

Signs And Symptoms Of Exposure:
Inhalation:
Severe irritation of respiratory and mucous membrane will result, followed by respiratory failure.

Eye Contact:
Vapours, liquid, and mists are extremely corrosive to the eyes. Brief contact of the vapours will be
severely irritating. Brief contact of the liquid or mist will severely damage the eyes and prolonged
contact may cause permanent eye injury which may be followed by blindness.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0019
Skin Contact:
Vapours, mists, and liquid are extremely corrosive to the skin. Vapours will severely irritate the skin
and liquid and mists will severely burn the skin. Prolonged liquid contact will burn or destroy
surrounding tissue and death may accompany burns which extend over large portions of the body.

Swallowed:
Vapours, mists, and liquid are extremely corrosive to the mouth and throat. Swallowing the liquid
burns the tissues, causes severe abdominal pain, nausea, vomiting, and collapse. Swallowing large
quantities can cause death.

Chronic Effects Of Exposure:

May result in areas of destruction of skin tissue or primary irritant dermatitis. Similarly, inhalation of
dusts, vapours, or mists may cause varying degrees of damage to the affected tissues and also
increasing susceptibility to respiratory illness.

Medical Conditions Generally Aggravated By Exposure: None reported.

Oral: No data found
Dermal: No data found
Inhalation: No data found
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

Other Data: None

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed: Do not induce vomiting. Get immediate medical attention.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the
TLV.

Respiratory Protection:
If use conditions generate vapours or mists, wear a niosh-approved respirator appropriate for those
emission levels. Appropriate respirators may be a full facepiece or a half mask air purifying cartridge
respirator equipped for organic vapours/mists, a self-contained breathing apparatus in the pressure
demand mode, or a supplied-air respirator.

Eye Protection:
Chemical goggles. It is generally recognized that contact lenses should not be worn when working with
chemicals because contact lenses may contribute to the severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

Storage And Handling Precautions:

Store in a cool, dry, well-ventilated place away from incompatible materials. Keep container tightly
closed when not in use. Do not use pressure to empty container. Wash thoroughly after handling. Do not
get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: None.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a self-contained
breathing apparatus in the pressure demand mode or a supplied-air respirator. If the spill or leak is
small, a full facepiece air-purifying cartridge respirator equipped for organic vapours may be
satisfactory. In any event, always wear eye protection. For small spills or drips, mop or wipe up and
dispose of in DOT-approved waste containers. For large spills, contain by diking with soil or other
non-combustible absorbent material, and then pump into DOT-approved waste containers; or absorb
with non-combustible sorbent material, place residue in DOT approved waste containers. Keep out of
sewers, storm drains, surface waters, and soils. Comply with all applicable governmental regulations on
spill reporting, and handling and disposal of waste.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0022

Material Safety Data Sheet

City University of Hong Kong

MSDS CHLOROFORM 0022

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name And : Chloroform

Chinese Name:
Synonyms: Hydrocarbon Stabilized; Trichloromethane
Chemical Family: Chlorinated Hydrocarbon
Chemical Formula: CHCl 3
C.A.S.: 67663
Product Use: Laboratory Solvent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odour And Appearance: Clear, colourless liquid with ether-like odour
Odour Threshold (ppm): 200 ppm
Vapour Pressure (mmHg): 159 mmHg @ 20 deg. C
Vapour Density (Air=1): 4.13
Evaporation Rate: 0.5 (N-Butyl Acetate = 1)
Boiling Point : 61.2 deg. C
Freezing Point : -63.5 deg. C
pH: Not Applicable
Specific Gravity: 1.48
Coefficient Of Water/Oil Distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flammability: Non-Flammable
Extinguishing Media: Carbon dioxide, dry chemicals or water spray
Flash Point (Method Used): Non-Flammable
Upper Flammable Limit (% By Volume): Not applicable
Lower Flammable Limit (% By Volume): Not applicable
Autoignition Temperature: Not applicable
Hazardous Combustion Products:
At high temperatures this product decomposes to give off hydrogen chloride gas and small quantities of
other toxic and irritating vapours.

========================================================================
REACTIVITY DATA
========================================================================

Chemical Stability: Stable

Incompatibility : Alkali metals
Hazardous Decomposition Products:
At high temperatures this product decomposes to give off hydrogen chloride gas and small quantities of
other toxic and irritating vapour.

Condition To Avoid: Open flames, sparks and other sources of ignition.

========================================================================
HEALTH HAZARD DATA
========================================================================

Toxicological Properties And Health Data

Toxicological Data:
LD50: (Oral, Rat) 908 mg/kg
LC50: (Inhalation, Rat) 47,702 mg/m3 4 hours
Effects Of Acute Exposure To Product:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0022
Inhaled:
Can cause central nervous system depression, which may progress rapidly to unconsciousness.
Moderate irritant of the respiratory tract.

In Contact With Skin: Mildly irritating to skin. May produce a burning sensation.
In Contact With Eyes: Slight irritant of the eyes causing pain, lacrimation and general inflammation.
Ingested:
Can irritate the gastrointestinal tract. May produce chemical pneumonia if vomiting results in
aspiration into the lungs. Ingestion can result in serious or fatal results.

Effects Of Chronic Exposure To Product:

Carcinogenicity: Has been evaluated by IARC as a carcinogen
Teratogenicity: Not available
Reproductive Effects: Not available
Mutagenicity: Not available
Synergistic Products: Not available

========================================================================
FIRST AID MEASURES
========================================================================

Eyes:
Immediately flush eyes with warm running water for a minimum of fifteen (15) minutes. (using any
available clean container, pour water in a gentle steady stream, over the eye(s). Position casualty lying
on back, face tilted to one side.) Hold eyelids open during flushing. Repeat flushing if irritation
persists. Obtain medical advice immediately. (flushing may be continued while casualty is transported
to medical facility.

Skin:
Immediately flush exposed area with large amounts of warm running water while removing contaminated
clothing (including rings, watches and shoes). Continue flushing the area up to twenty (20) minutes. If
irritation persists, repeat flushing and get medical advice.

Inhalation:
Immediately remove casualty from contaminated area to fresh air. (caution must be used by rescuers to
avoid exposure to contaminating fumes.) If breathing has stopped give artificial respiration. If breathing
and pulse are absent give CPR. Immediately obtain medical attention. Stay with casualty until medical
assistance is reached.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Ingestion:
Do not induce vomiting. Danger of aspiration with vomiting. If the casualty is alert and not convulsing,
rinse out mouth with water. Give 4 to 8 glasses of water to dilute material. Immediately get medical
attention. If spontaneous vomiting occurs, have casualty lean forward with head down to avoid breathing
in of vomitus.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls: local exhaust ventilation recommended.

Respiratory Protection:
Approved air-purifying respirator or self-contained breathing apparatus required for concentrations
exceeding TLV.

Eye Protection: chemical safety goggles.

Skin Protection:
PVC gloves, overalls, apron or protective clothing sufficient to prevent contact if splash occurs.

Other Personal Protective Equipment: Safety shower and eyewash fountain in the work area.
Handling Procedures And Equipment:
Avoid contact with eyes, skin and clothing and inhalation of vapours.

Storage Requirements: Store in cool, well-ventilated area away from heat, sparks and open flame.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Leak And Spill Procedure:

Evacuate area, provide maximum ventilation. Contain spill and collect using absorbent material.
Adequate personal protective equipment and clothing must be worn.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0023

Material Safety Data Sheet

City University of Hong Kong

MSDS CHROMIUM CHLORIDE, 6-HYDRATE 0023

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Chromium Chloride, 6-Hydrate

Chinese Name:
Common Synonyms: Chromium (III) Chloride, Hexahydrate; Chromic Chloride, Hexahydrate
Chemical Family: Chromium Compounds
Formula: CrCl 3 6H2O
Formula Wt.: 266.45
C.A.S.: 10060-12-5
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapour Pressure (mmHg): N/A
Melting Point: 83 deg. C (181 deg. F) Vapour Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.76 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odour Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odour: Purple to black crystals. Odourless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Nonflammable

Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Flash Point (Closed Cup): N/A
Flammable Limits: Upper - N/A Lower - N/A
Autoignition Temperature: N/A
Toxic Gases Produced: Hydrogen chloride, chlorine and chlorine compounds
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibles: Strong oxidizing agents, lithium, nitrogen
Decomposition Products: Hydrogen chloride, chlorine and chlorine compounds
Conditions To Avoid: None documented

========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): 0.5 mg/m3

TLV Is For Chromium (III) Compounds, As Cr.
Short-Term Exposure Limit (STEL): Not established

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0023
Permissible Exposure Limit (PEL): 0.5 mg/m3
PEL Is For Chromium (III) Compounds, As Cr.
Toxicity Of Components:
Oral Rat Ld 50 For Chromium Chloride, 6-Hydrate 1790 mg/kg
Intraperitoneal Mouse LD 50 For Chromium Chloride, 6-Hydrate 520 mg/kg
Carcinogenicity: NTP: Yes IARC: Yes Z LIST: No OSHA REG: No
Carcinogenicity:
Studies indicate Chromium (III) Oxide is not carcinogenic. The national toxicity program (NTP) lists
"chromium and certain chromium compounds" as substances known to be carcinogens. Note: levels and
specific chromium compounds cannot be identified.

Reproductive Effects: None Identified.

Effects Of Overexposure:
Inhalation:
Respiratory tract ulcers, inflammation of larynx, lungs, gastrointestinal tract, and nasal passages

Skin Contact: Irritation

Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified

Target Organs: Skin

Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry:Ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, give large amounts of water. Induce vomiting.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: in case of contact, flush skin with water.

Eye Contact:
In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
A respirator with dust/mist filter is recommended. If airborne concentration exceeds TLV, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. with clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0024

Material Safety Data Sheet

City University of Hong Kong

MSDS CYCLOHEXANOL 0024

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Cyclohexanol

Chinese Name:
Synonyms: Cyclohexanol
Chemical Family:Allcyclic Alcohols
Formula: C6H11OH
C.A.S.: 108-93-0

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State:Liquid
Boiling Point : 322 deg. F Vapour Pressure, mmHg/20 deg. C: 1

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point : 75 deg. F Vapour Density (Air=1): 3.5
Specific Gravity (Water=1): 0.95 Water Solubility, %: 3.6
Appearance And Odour: Evaporation Rate (Butyl Acetate=1): <1
Clear Colourless Liquid; Solid Below 70 deg. F
Aromatic Camphor-Like Odour

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Extinguishing Media: Use water spray, dry chemical, Co2, or alcohol foam. do not use a direct water
stream.
Flash Point : 151 deg. F
Flammable Limits In Air, % Lower: 1.25 Upper: 12.25
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards:

Extinguish all nearby sources of ignition. Vapour is heavier than air and may travel to other ignition
sources.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility: Acids, oxidizing materials, and especially nitric acid.
Hazardous Decomposition Products: May liberate carbon monoxide or carbon dioxide.
Conditions To Avoid: Heat, sparks, and open flames.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Inhalation, skin or eye contact, and swallowing

Signs And Symptoms Of Exposure:
Inhalation:
Vapours and mists irritate the nose, throat, and respiratory tract. Inhalation of higher concentrations
may cause headaches, nausea, vomiting, coma, and intestinal disturbances. Inhalation of very high
concentrations or prolonged exposure may cause unconsciousness or death.

Eye Contact: Vapours will irritate the eyes. Liquid and mists may severely irritate or damage the eyes.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0024
Skin Contact:
Brief contact may dry the skin. Prolonged or repeated contact may irritate the skin, causing dermatitis.
May be absorbed through the skin causing systemic effects similar to inhalation.

Swallowed: Depressant for CNS. May cause reversible or irreversible changes to exposed tissue.
Chronic Effects Of Exposure: None reported for humans. Liver and kidney damage in animal tests.

Medical Conditions Generally Aggravated By Exposure: None reported.

Oral: Rat LD 50=2060 mg/kg
Dermal: Rabbit LDLO=12 g/kg
Inhalation: Human TCLO=75 ppm
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

Other Data:
A limited foreign epidemiological study showed non-specific disturbances of the autonomic nervous
system. These effects have not been observed elsewhere. This product increased the mortality of
offspring when pregnant mice were exposed to 1% concentrations.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
If conscious, immediately induce vomiting by giving 2 glasses of water and sticking a finger down the
throat. Get immediate medical attention. Do not give anything by mouth to an unconscious or convulsing
person.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the pel.

Respiratory Protection:
If use conditions generate vapours or mists, wear a NIOSH-approved respirator appropriate for those
emission levels. Appropriate respirators may be a full facepiece air-purifying cartridge respirator
equipped for organic vapours/mists, a self-contained breathing apparatus in the pressure demand mode,
or a supplied-air respirator.

Eye Protection:
Chemical goggles unless a full facepiece respirator is also worn. It is generally recognized that contact
lenses should not be worn when working with chemicals because contact lenses may contribute to the
severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, neoprene gloves, and neoprene apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

Storage And Handling Precautions:

Store in a cool, dry, well-ventilated place away from incompatible materials. Vent container carefully,
as needed, to relieve pressure. keep container tightly closed when not in use. Do not use pressure to
empty container. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.

Other Precautions:
Vapours of this product are heavier than air and will collect in low places, such as pits or degreasers, or
other poorly ventilated areas. Do not enter places where vapours are suspected unless special
respiratory protection is worn and an observer is present. Containers, even those that have been emptied,
will retain product residue and vapours. Always obey hazard warnings and handle empty containers as
if they were full.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0024
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including neoprene boots, neoprene gloves, neoprene apron, and a
self-contained breathing apparatus in the pressure demand mode or a supplied-air respirator. If the spill
or leak is small, a full facepiece air-purifying cartridge respirator equipped for organic vapours may be
satisfactory. In any event, always wear eye protection. Extinguish all ignition sources. For small spills
or drips, mop or wipe up and dispose of in dot-approved waste containers. For large spills, contain by
diking with soil or other non-combustible sorbent material and then pump into DOT-approved waste
containers; or absorb with non-combustible sorbent material and place residue in DOT-approved waste
containers. Keep out of sewers, storm drains, surface waters, and soil.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0025

Material Safety Data Sheet

City University of Hong Kong

MSDS CYCLOHEXANONE 0025

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Cyclohexanone

Chinese Name:
Chemical Family : Ketone
Formula : C6H10O
Molecular Weight: 98.16
C.A.S : 108-94-1

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State :Liquid

Boiling Point, 760mmHg : 155.6 deg. C

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapour Pressure At 20 deg. C : 5.2 mmHg
% Volatiles By Volume : CA 100
Freezing Point : -45.0 deg. C
Vapour Density (Air=1) : 3.4
Specific Gravity (H2O=1) : @ 20 deg. C 0.95
Evaporation Rate : (BuAc=1) CA 0.3
Solubility In Water : @ 20 deg. C 15%
Appearance And Odour : Clear, colourless liquid with an acetone-like odour.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Flash Point, (Test Method): 44 deg. C (Tag Closed Cup)
Extinguishing Media : Carbon dioxide, dry chemical, or foam.
Flammable Limits In Air % By Volume: Lower Limit 1.2 Upper Limit 8.1
Auto Ignition Temperature: 420 deg. C
Unusual Fire And Explosion Hazards: None, other than combustibility.
Special Fire Fighting Procedures:
Wear full protective clothing and self-contained breathing apparatus. Heat will build pressure and may
rupture closed storage containers. Keep fire-exposed containers cool with water spray.

========================================================================
REACTIVITY DATA
========================================================================

Stability : Stable
Hazardous Polymerization : Not expected to occur.
Incompatibility : Strong oxidizing agents and strong acids and bases.
Hazardous Decomposition Products :
Incomplete combustion can generate carbon monoxide and other toxic vapours.

Conditions To Avoid : Heat, sparks, open flame, open containers, and poor ventilation.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0025
========================================================================
HEALTH HAZARD DATA
========================================================================

Occupational Exposure Limits Concentration Immediately Dangerous

To Health
OSHA 8-hour PEL - 50 ppm OSHA/NIOSH Not listed
Ceiling - Not listed
Peak - Not listed Odour threshold

ACGIH TLV-TWA - 25 ppm (Skin) NSC Not listed

TLV-STEL - 100 ppm NIOSH & OHS 0.12 ppm
(15-min)

NIOSH TLV-TWA - 25 ppm

TLV-C - Not listed

Primary Routes Of Entry:

Cyclohexanone may exert its effects through inhalation, skin absorption, and ingestion.

Industrial Exposure: Route of exposure/signs and symptoms

Inhalation:
Exposure can cause eye, nose, and throat irritation, headache, nausea, dizziness, narcosis, and
unconsciousness.

Eye Contact: Liquid and high vapour concentration can cause irritation and slight corneal clouding.
Skin Contact:
Prolonged or repeated skin contact can cause irritation and dermatitis through defatting of skin.

Ingestion: Can cause gastrointestinal tract irritation, nausea, drowsiness, and narcosis.
Effects Of Overexposure:
Cyclohexanone is an eye and mucous membrane irritant, primary skin irritant, and central nervous system
depressant. Acute exposure irritates the eyes and upper respiratory tract, with high concentrations
producing narcosis.

Medical Condition Aggravated By Exposure:

Preclude from exposure those individuals susceptible to dermatitis.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Immediately remove to fresh air. If not breathing, administer mouth-to-mouth rescue breathing. If there is
no pulse administer cardiopulmonary resuscitation (CPR). Contact physician immediately.

Eye Contact:
Rinse with copious amounts of water for at least 15 minutes. Get Emergency medical assistance.

Skin Contact:
Flush thoroughly for at least 15 minutes. Wash affected skin with soap and water. Remove contaminated
clothing and shoes. Wash clothing before re-use, and discard contaminated shoes. Get emergency
medical assistance.

Ingestion:
Call local poison control centre for assistance. Contact physician immediately. Never induce vomiting or
give anything by mouth to a victim unconscious or having convulsions.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Adequate ventilation is required to protect personnel from exposure to chemical vapours exceeding the
PEL and to minimize fire hazards. The choice of ventilation equipment, either local or general, will
depend on the conditions of use, quantity of material, and other operating parameters.

Respiratory:
Use approved respirator equipment. Follow niosh and equipment manufacturer's recommendations to
determine appropriate equipment (air-purifying, air-supplied, or self-contained breathing apparatus).

Eyes:
Safety glasses are considered minimum protection. Goggles or face shield may be necessary depending
on quantity of material and conditions of use.

Skin:
Protective gloves and clothing are recommended. The choice of material must be based on chemical
resistance and other user requirements. generally, neoprene offers acceptable chemical resistance.
Individuals who are acutely and specifically sensitive to cyclohexanone may require additional
protective equipment.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0025
Storage:
Cyclohexanone should be protected from temperature extremes and direct sunlight. Proper storage of
cyclohexanone must be determined based on other materials stored and their hazards and potential
chemical incompatibility. In general, cyclohexanone should be stored in an acceptably protected and
secure toxic storage room.

Other:
Emergency eye wash fountains and safety showers should be available in the vicinity of any potential
exposure.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill Control:
Protect from ignition. Wear protective clothing and use approved respirator equipment. Absorb spilled
material in an absorbent recommended for solvent spills and remove to a safe location for disposal by
approved methods. If released to the environment, comply with all regulatory notification requirements.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0027

Material Safety Data Sheet

City University of Hong Kong

MSDS ETHYL ETHER 0027

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Ethyl Ether

Chinese Name:
Synonyms: Ether; Diethyl Ether; Ethyl Oxide; Sulfuric Ether
Chemical Family : Ether
Formula: C2H5OC2H5
C.A.S.: 60-29-7

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State : Liquid

Boiling Point : 94.1 deg. F Vapour Pressure, mmHg/20 deg. C: 439

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point : -176.8 deg. F Vapour Density (Air=1): 2.55
Specific Gravity (Water=1): 0.71 Water Solubility, %: 6.9
Appearance And Odour: Clear colourless liquid; sweet pungent odour.
Evaporation Rate (Butyl Acetate=1): 37.5

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Flash Point : <0
Extinguishing Media:
Use water spray, dry chemical, CO2, alcohol or polymer foam. Water may be ineffective.

Flammable Limits In Air, Lower: 1.9 Upper: 48

Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards:

Because of the material's low boiling point, it may be best to treat this chemical as a gas. Exercise
caution to avoid contact between ether vapour and streamlines and other hot metal surfaces. Vapours are
heavier than air and may travel a considerable distance to ignition sources and flash back. In the
presence of oxygen or on long standing or exposure to sunlight in bottles, unstable peroxides sometimes
form which may explode spontaneously or when heated.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Material forms peroxides in the presence of air. The peroxides may be explosive.
Incompatibility:
Strong oxidizing agents, triethylaluminum and air, trimethylaluminum and air, lithium aluminum hydride,
and acetyl peroxide

Hazardous Decomposition Products: Peroxides.

Conditions To Avoid: Heat, sparks, open flames, exposure to light and prolonged exposure to air.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Inhalation, skin or eye contact.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0027
Signs And Symptoms Of Exposure:
Inhalation:
Vapours and mists irritate the nose and throat. Inhalation of higher concentrations may cause
headaches, nausea, vomiting, dizziness, and coma. Inhalation of very high concentrations or prolonged
exposure may cause unconsciousness or death.

Eye Contact: Vapours will irritate the eyes. Liquid and mists will irritate and may burn the eyes.
Skin Contact:
No irritation is likely after brief contact but may be irritating after prolonged contact. Covered contact
may cause burns.

Swallowed:
Swallowing large quantities causes headaches, nausea, vomiting, dizziness, stupor, intoxication, and
perhaps unconsciousness.

Chronic Effects Of Exposure: Prolonged exposure may result in respiratory failure and death.

Medical Conditions Generally Aggravated By Exposure: None reported.

Oral: Rat LD 50 = 1.7 g/kg; Human LDLO = 420 mg/kg
Dermal: None found
Inhalation: Rat LC 50 = 73,000 ppm/150 min.

Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration

Other Data: None

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 If conscious, immediately induce vomiting by giving 2 glasses of water and sticking a finger down the
throat. Get immediate medical attention. Do not give anything by mouth to an unconscious or convulsing
person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the PEL.

Respiratory Protection:
If use conditions generate vapours or mists, wear a niosh-approved respirator appropriate for those
emission levels. Appropriate respirators may be a full facepiece or a half mask air-purifying cartridge
respirator equipped for organic vapours/mists, a self-contained breathing apparatus in the pressure
demand mode, or a supplied-air respirator.

Eye Protection:
Chemical goggles unless a full facepiece respirator is also worn. It is generally recognized that contact
lenses should not be worn when working with chemicals because contact lenses may contribute to the
severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.
Handling And Storage Precautions:
Keep away from heat, sparks, and flames. Store in a cool, dry, well-ventilated place away from
incompatible materials. Keep air out of the container. Electrically ground all equipment when handling
this product and use only non-sparking tools. Keep container tightly closed when not in use. Do not use
pressure to empty container. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.
Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

Other Precautions:
Distillation, evaporation, or exposure to light will accelerate peroxide formation. Addition of reducing
agents or water tend to lessen peroxide formation.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0027
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a self-contained
breathing apparatus in the pressure demand mode or a supplied-air respirator. If the spill or leak is
small, a full facepiece air-purifying cartridge respirator equipped for organic vapours may be
satisfactory. In any event, always wear eye protection. Extinguish all ignition sources and ensure that all
handling equipment is electrically grounded. For small spills or drips, mop or wipe up and dispose of in
DOT-approved waste containers. For large spills, contain by diking with soil or other non-combustible
absorbent materials and then pump into DOT-approved waste containers; or absorb with
non-combustible sorbent material, place residue in DOT-approved waste containers. Keep out of
sewers, storm drains, surface waters, and soil. Comply with all applicable governmental regulations on
spill reporting, and handling and disposal of waste.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0032

Material Safety Data Sheet

City University of Hong Kong

MSDS DIPHENYLAMINE 0032

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Diphenylamine

Chinese Name:
Synonyms: Dpa, Phenylaniline, Biphenylamine
Chemical Family: Aromatic Amine
Molecular Formula: (C6H5)2NH
C.A.S.: 122-39-4
Product Use: Stabilizer for perfume, explosives

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Appearance And Odour: Floral odour, brown flake which may darken slowly on storage.
Odour Threshold: Not available
Boiling Range : 302 deg. C @ 760 mmHg
Melting/Freezing Point : 52.9 deg. C @ 760 mmHg
Vapour Pressure: 1 mmHg @ 109 deg. C
Specific Gravity: 1.16
Vapour Density: No data
Bulk Density: Not applicable
Evaporation Rate: No data
Solubility: Soluble in water; also ethanol, benzene and aqueous mineral acid solutions
% Volatile By Volume: 100%
pH: No data
Coefficient Of Water/Oil Distribution: Not available
Rate Of Burning: Not available
Explosive Power: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Not application

Fire Extinguishing Media: Water, carbon dioxide, dry chemical, foam
Flash Point (Method): 153 deg. C (Closed Cup)
Flammability Limits In Air (%): Uel: Not applicable Lel: Not applicable
Autoignition Temperature: 643 deg. C
Fire Fighting Procedures:
The material will burn if ignited. Sand or earth can be used on small isolated fires. Larger fires may
be extinguished with water, carbon dioxide, dry chemical or foam.

Other Fire Or Explosion Hazards:

Materials release toxic vapours or gases on thermal decomposition. Full protective equipment,
including a self-contained breathing apparatus, should be worn when material is involved in fire.
Possibility of formation of flammable dust clouds.

========================================================================
REACTIVITY DATA
========================================================================

Stability:
Under Normal Conditions: Stable
Under Fire Conditions: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Oxidizing materials
Hazardous Decomposition Or Combustion Products:
Thermal decomposition will cause the release of toxic gases or vapours.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0032
Conditions To Avoid: High temperatures

========================================================================
HEALTH HAZARD DATA
========================================================================

Recommended Exposure Limit: ACGIH TLV/TWA: 10 mg/m3

Toxicological Data: LD 50 (Oral, Guinea Pig) = 300 mg/kg (1)
Carcinogenicity Data:
A potential impurity of this product, 4-aminodiphenyl, is listed by acgih (ammerican conference of
governmental industrial hygienists) as a substance associated with industrial processes, recognized to
have carcinogenic potential. Concentrations of 4-aminodiphenyl in this product are controlled and do
not exceed 20 ppm.

Reproductive Effects: No information is available and no adverse reproductive effects are anticipated.
Mutagenicity Data: No information is available and no adverse mutagenic effects are anticipated.
Teratogenicity Data: No information is available and no adverse teratogenic effects are anticipated.

Synergistic Materials: None known

Effects Of Exposure When:
Inhaled:
Dust is irritating to the nose, throat and respiratory tract, and may cause coughing and sneezing, central
nervous system (CNS) depression, bladder irritation, tachycardia, and systemic poisoning. (see "other
health effects")

In Contact With The Skin:

Dust may cause mild irritation of the intact skin and possible sensitization. May be absorbed through
intact skin causing central nervous system (CNS) depression, bladder irritation, increased pulserate
and systemic poisoning.

In Contact With The Eyes:

May cause irritation, corneal burns, conjunctivitis, and possible corneal damage.

Ingested:
May cause irritation and burning of the mouth, throat and respiratory tract and abdominal pain. Can
cause central nervous system (CNS) depression, bladder irritation, tachycardia, and systemic
poisoning. (see "other health effects")

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Other Health Effects:
Cns depression is characterized by headache, dizziness, drowsiness, nausea, vomiting, abdominal pain
and incoordination. Severe overexposures may lead to coma and possible death due to respiratory
failure. Animal studies have shown that exposure to diphenylamine may cause methemoglobinemia and
damage to the liver, kidney, heart and spleen. Initial manifestation of methemoglobinemia is cyanosis,
characterized by navy blue, almost black, lips, tongue, and mucous membranes, with skin colour being
slate gray. Further manifestation is characterized by headache, weakness, dyspnea, dizziness, stupor,
respiratory distress, and death due to anoxia.

========================================================================
FIRST AID MEASURES
========================================================================

Inhaled:
Move victim to fresh air. Stay with victim and have a second rescuer obtain oxygen equipment and call
an ambulance. Oxygen should be administered by trained personnel. Give artificial respiration only if
breathing has stopped. Give cardiopulmonary resuscitation (CPR) if there is no breathing and no pulse.
Obtain medical attention immediately.

In Contact With The Skin:

Flush skin with running water then continue flushing with running water for a minimum of 20 minutes.
Start flushing while removing contaminated clothing. If irritation persists, repeat flushing. Obtain
medical attention immediately.

In Contact With The Eyes:

Immediately flush eyes with running water for a minimum of 20 minutes. hold eyelids open during
flushing. If irritation persists, repeat flushing. Obtain medical attention immediately.

Ingested:
If victim is alert and not convulsing, give 1/2 to 1 glass of water to dilute material. Immediately contact
local poison control centre. vomiting should be induced under the direction of a physician or a poison
control centre. If spontaneous vomiting occurs, have victim lean forward with head down to avoid
breathing in of vomitus, rinse mouth and administer more water. Immediately transport victim to an
emergency facility.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Recommendations listed in this section indicate the type of equipmentwhich will provide protection
against overexposure to this product. conditions of use, adequacy of engineering or other control
measures, and actual exposures will dictate the need for specific protective devices at your workplace.

Engineering Controls: local exhaust ventilation required.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0032
Respiratory Protection:
A niosh/msha approved air-purifying respirator equipped with organic vapour cartridges for
concentrations up to 10 mg/m3. An air-supplied respirator if concentrations are higher or unknown.

Skin Protection: Gloves found to be impervious under conditions of use.

Eye Protection: Use chemical safety goggles when there is potential for eye contact.
Other Personal Protective Equipment: Impervious clothing as required.
Handling Procedures And Equipment: Not applicable
Storage Temperature ( deg. C): Not critical
Storage Requirements: Store in cool, dry, well-ventilated area.
Other Precautions: The creation of flammable dust clouds should be avoided.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Leak:

Stop discharge and contain run-off from rainwater by dying (eg. Earth) for release to land, or contain
discharge by damming and water diversion if possible for release to water. Collect product and
contaminated soil and water for recovery or disposal.

Environmental Effects:
Harmful to aquatic life at low concentrations. May be an aesthetic nuisance due to colour. No
quantitative data are available.

Deactivating Chemicals: None known

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0033

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM PHOSPHATE, DIBASIC 0033

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Potassium Phosphate, Dibasic

Chinese Name:
Common Synonyms: Dipotassium Hydrogen Phosphate
Chemical Family: Potassium Compounds
Formula: K2HPO4
Formula Wt.: 174.18
CAS NO.: 7758-11-4
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapour Pressure (mmHg): N/A
Melting Point: N/A Vapour Density (Air=1): N/A
Specific Gravity: N/A Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odour Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odour: White powder.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Nonflammable

Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Flash Point (Closed Cup): N/A
Flammable Limits: Upper - N/A Lower - N/A
Autoignition Temperature: N/A
Toxic Gases Produced: Oxides of phosphorus
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibles: None identified
Decomposition Products: Oxides of phosphorus
Conditions To Avoid: None documented

========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): Not established

Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components: No information is available

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0033
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No
Carcinogenicity: None identified.
Reproductive Effects: None identified.
Effects Of Overexposure:
Inhalation: None identified
Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0034

Material Safety Data Sheet

City University of Hong Kong

MSDS ETHANOL 0034

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical: Ethanol
Chinese Name:
Synonyms: Ethyl Alcohol
Chemical Family: Alcohols
Formula: C2H5OH
Molecular Weight: 46.07
C.A.S.: 64-17-5

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility (%): Complete
Boiling Point Of Product: 78.2 deg. C (172.8 deg. F) @ 760 mmHg
Vapour Pressure Of Product: 43 mmHg @ 20 deg. C
Vapour Density Of Product: 1.6 (Air = 1)
Specific Gravity Of Product: 0.8107 @ 20/20 deg. C (H2O=1)
Percent Volatile (%): 100 (By Volume)
Evaporation Rate: 3.2 (Butyl Acetate = 1)
Freezing Point: Below -123 deg. C (-189 deg. F)

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Extinguishing Media:
Alcohol-type foam applied by manufacturers' recommended techniques for large fires; carbon dioxide or
dry chemical for small spill fires

Flash Point Of Product: 62 deg. F (Tag Closed Cup); 74 deg. F (Tag Open Cup)
Lower Explosive Limit: 3.3% (By Volume)
Upper Explosive Limit: 19.0% (By Volume)

Special Fire Fighting Procedures:

Addition of water spray (fog) may reduce intensity of the flames. Use self-contained breathing apparatus
and protective clothing.

Unusual Fire/Explos Hazards:

Vapours form from this product and may travel or move by air currents and ignited by pilot lights, other
flames, smoking, sparks, heaters, electrical equip., Static discharges, or other ignition sources at
locations distant from handling point

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable.
Hazardous Polymerization: Will not occur.
Incompatibility: : None
Hazardous Combustion Or Decomposition Products:
Burning can produce carbon monoxide and/or carbon dioxide

Conditions To Avoid: Heat, fire, ignition sources.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0034
========================================================================
HEALTH HAZARD DATA
========================================================================

TLV'S: 1000 ppm, ACGIH 1984-5; OSHA 29 CFR PARA. 1910.1000 TABLE Z-1
Effects Of Acute Overexposure:
Eye Contact: Minor irritation
Skin Contact: No evidence of adverse effects from available information.
Skin Absorption: No evidence of adverse effects from available information.
Inhalation: May cause dizziness, drowsiness, nausea and vomiting
Ingestion:
Dizziness, drowsiness, decreased reaction, euphoria, nausea, vomiting, staggering gait, and coma

Effects Of Repeated Overexposure: No evidence of adverse effects from available information

Other Health Hazards: none currently known

========================================================================
FIRST AID MEASURES
========================================================================

Eye Contact: Immediately flush eyes with water for at least 15 minutes. Call a physician.
Skin Contact: Flush with water
Inhalation: Remove to fresh air
Ingestion: Give two glasses of water and induce vomiting
Notes To Physician:
Treatment of overexposure should be directed at the control of symptoms and the clinical condition

========================================================================
PREVENTATIVE MEASURES
========================================================================

Eye Protection: Safety glasses

Skin Protection: Protective gloves: neoprene
Respiratory Protection: Self-contained breathing apparatus in high concentrations
Ventilation Requirements:
This product should be confined within closed equipment, in which case general (mechanical) room
ventilation should be suitable. Special, local ventilation is needed at points where vapours are expected
to be vented to the workplace air.

Other Protective Equipment: Eye bath, safety shower

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Storage And Handling:
Keep away from heat, sparks, and flame. Keep container closed. Use with adequate ventilation. Wash
thoroughly after handling. Avoid breathing vapours.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Cleanup:
Extinguish and do not turn on any ignition source until area is determined to be free from explosion or
fire hazards. Collect large spills for disposal. Flush small spills with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0035

Material Safety Data Sheet

City University of Hong Kong

MSDS ETHYL ACETATE 0035

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Ethyl Acetate

Chinese Name:
Synonyms : Ethyl Ethanoate, Acetic Acid Ethyl Ester
Chemical Family : Ester
Molecular Formula : C2H5COOCH3
Molecular Weight : 88.11
C.A.S : 141-78-6

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State : Liquid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Boiling Point, 760mmHg. : 77.11 deg. C
Vapour Pressure At 20 deg. C : 73.0 mmHg
% Volatiles By Volume : CA 100
Freezing Point : -83.97 deg. C
Vapour Density (Air=1) : 3.0
Specific Gravity (H2O=1) : @ 20 deg. C 0.901
Evaporation Rate : (BuAc=1) Ca 5
Solubility In Water : @ 20 deg. C 8.7%
Appearance And Odour : Clear, colourless liquid with a characteristic fruity odour.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Extinguishing Media: Carbon dioxide, dry chemical, or alcohol foam.
Flash Point, (Test Method) -4 deg. C (Tag Closed Cup)
Flammable Limits In Air % By Volume: Lower Limit 2.2 Upper Limit 11.5
Auto Ignition Temperature 426 deg. C
Special Fire Fighting Procedures :
Wear full protective clothing and self-contained breathing apparatus. heat will build pressure and
rupture closed storage containers. Keep fire-exposed containers cool with water spray.

========================================================================
REACTIVITY DATA
========================================================================

Stability : Stable
Hazardous Polymerization : Not expected to occur.
Incompatibility : Strong oxidizing agents and strong acids and bases.
Hazardous Decomposition Products :
Incomplete combustion can generate carbon monoxide and other toxic vapours.

Conditions To Avoid : Heat, sparks, open flame, open containers, and poor ventilation.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0035
========================================================================
HEALTH HAZARD DATA
========================================================================

Occupational Exposure Limits Concentration Immediately Dangerous

To Health
OSHA TWA - 400 ppm
STEL - Not Listed OSHA/NIOSH 10,000 ppm
CEILING - Not Listed
Odour Threshold
ACGIH TLV-TWA - 400 ppm
TLV-STEL - Not Listed NSC 10 ppm
NIOSH 50 ppm

Carcinogenic Data: Ethyl acetate is not listed as a carcinogen by IARC, NTP, OSHA, or ACGIH.
Primary Routes Of Entry:
Ethyl acetate may exert its effects through inhalation, skin absorption, and ingestion.

Industrial Exposure: Route of exposure/signs and symptoms

Inhalation:
Exposure can cause respiratory irritation, headache, nausea, liver and kidney damage and pulmonary
edema.

Eye Contact:
Liquid and high vapour concentration can cause irritation, conjunctivitis, and corneal clouding.

Skin Contact:
Prolonged or repeated skin contact can cause irritation and dermatitis through defatting of the skin.

Ingestion: can cause irritation of gastrointestinal tract.

Effects Of Overexposure:
Ethyl acetate is a mild eye and mucous membrane irritant, primary skin irritant and central nervous
system depressant. Repeated contact with ethyl acetate produces eczematous and sensitization
dermatitis. Acute inhalation may produce narcosis, anemia, liver and kidney damage, and pulmonary
edema.

Medical Condition Aggravated By Exposure:

Preclude from exposure those individuals with diseases of eyes, liver, kidneys, lungs a2nd those
susceptible to dermatitis.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Immediately remove to fresh air. If not breathing, administer mouth-to-mouth rescue breathing. If there
is no pulse administer cardiopulmonary resuscitation (CPR). Contact physician immediately.

Eye Contact:
Rinse with copious amounts of water for at least 15 minutes. Get emergency medical assistance.

Skin Contact:
Flush thoroughly for at least 15 minutes. Wash affected skin with soap and water. Remove contaminated
clothing and shoes. Wash clothing before re-use, and discard contaminated shoes. Get emergency
medical assistance.

Ingestion:
Call local poison control centre for assistance. Contact physician immediately. Never induce vomiting or
give anything by mouth to a victim unconscious or having convulsions.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Adequate ventilation is required to protect personnel from exposure to chemical vapours exceeding the
PEL and to minimize fire hazards. The choice of ventilation equipment, either local or general, will
depend on the conditions of use, quantity of material, and other operating parameters.

Respiratory:
Use approved respirator equipment. Follow niosh and equipment manufacturer's recommendations to
determine appropriate equipment (air-purifying, air-supplied, or self-contained breathing apparatus).

Eyes:
Safety glasses are considered minimum protection. Goggles or face shield may be necessary depending
on quantity of material and conditions of use.

Skin:
Protective gloves and clothing are recommended. The choice of material must be based on chemical
resistance and other user requirements. Generally, neoprene or natural rubber offer acceptable chemical
resistance. Individuals who are acutely and specifically sensitive to ethyl acetate may require additional
protective equipment.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0035
Storage:
Ethyl acetate should be protected from temperature extremes and direct sunlight. Proper storage of ethyl
acetate must be determined based on other materials stored and their hazards and potential chemical
incompatibility. In general, ethyl acetate should be stored in an acceptably protected and secure
flammable liquid storage room.

Other:
Emergency eye wash fountains and safety showers should be available in the vicinity of any potential
exposure. Ground and bond metal containers to minimize static sparks.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill Control:
Protect from ignition. Wear protective clothing and use approved respirator equipment. Absorb spilled
material in an absorbent recommended for solvent spills and remove to a safe location for disposal by
approved methods. If released to the environment, comply with all regulatory notification requirements.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0036

Material Safety Data Sheet

City University of Hong Kong

MSDS ETHYLENEDIAMINE 0036

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Ethylenediamine

Chinese Name:
Synonyms: Ethylenediamine; 1,2-Ethanediamine; EDA; EDA-HP; EDA-UHP
Formula: H2NCH2CH2NH2
C.A.S.:107-15-3

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State : Liquid

Boiling Point : 243.1 deg. F Vapour Pressure, mmHg/20 deg. C: 10
Melting Point : 52 deg. F Vapour Density (Air=1): 2.07

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Specific Gravity (Water=1): 0.898 @ 20/20 deg. C Water Solubility, %: 100
Evaporation Rate (Butyl Acetate=1): 0.91
Appearance And Odour: Water-white liquid; strong amine odour

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Extinguishing Media: Use water spray, dry chemical, CO2, or alcohol foam.
Flash Point : 108 deg. F Tag open cup
Flammable Limits In Air, % Lower: 4.2 Upper: 14.4

Special Fire Fighting Procedures:

Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire. Do not direct a solid stream of water or
foam into hot, burning pools; this may cause splattering and increase fire intensity.

Unusual Fire And Explosion Hazards:

Extinguish all nearby sources of ignition. Vapours may under go spontaneous combustion when mixed
with air.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility:
Acids, oxidizing materials, chlorinated organic compounds, nitromethane, and copper and its alloys.
Also avoid contamination with epoxides, aldehydes, ketones, acryketes and organic halides.

Hazardous Decomposition Products:

May liberate carbon monoxide, carbon dioxide, oxides of nitrogen, and ammonia.

Conditions To Avoid:
Heat, sparks, and open flames. Some decomposition can occur upon vigorous heating.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary routes of exposure: skin or eye contact, inhalation.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0036
Signs And Symptoms Of Exposure:
Inhalation:
Vapours are irritating and may cause nausea, vomiting, and sensitization of the respiratory tract.
Repeated exposure to high vapour concentrations may cause liver and kidney damage. Vapours are
irritating and may cause excessive tear formation, burning sensation of the nose and throat, coughing,
wheezing, shortness of breath, nausea and vomiting. Extremely high vapour concentrations may cause
lung damage. some individuals may develop asthma.

Eye Contact:
Vapours, liquid, and mists are extremely corrosive to the eyes. Brief contact of the vapours will be
severely irritating. Brief contact of the liquid or mists will severely damage the eyes and prolonged
contact may cause permanent eye injury which may be followed by blindness. Exposure to the vapour
may cause minor transient edema of the corneal epithelium. this condition, referred to as "glaucopsia",
"blue haze" or "blue-grey haze" produces a blurring of vision against a general bluish haze and the
appearance of halos around bright objects. The effect disappears spontaneously within a few hours of the
end of an exposure, and leaves no sequelae. Although not detrimental to the eye per se, glaucopsia
predisposes an affected individual to physical accidents, and reduces the ability to undertake skilled
tasks such as driving a motorized vehicle.

Skin Contact:
Causes chemical burns. A strong sensitizer which may cause skin rash. prolonged or repeated exposure
may result in absorption of harmful amounts.

Swallowed:
Swallowing large quantities causes headaches, nausea, vomiting, and perhaps unconsciousness.
Moderately toxic. May also cause dizziness, weakness, thirst, collapse and possible coma. The severity
and nature of these disorders depends on the amount swallowed.

Chronic Effects Of Exposure:

Exposure may sensitize the skin or respiratory tract. Repeated inhalation or skin contact may also cause
an allergic response such as a skin rash or asthma. May cause liver and kidney damage.

Medical Conditions Generally Aggravated By Exposure:

Persons with preexisting asthma, allergies, or known sensitization to ethylenediamine may be more
susceptible to the effects of this product. it may aggravate existing dermatitis. Breathing of vapour and
mists may aggravate inflammatory or fibrotic pulmonary disease.

Oral: Rat LD 50 = 1,160 mg/kg

Dermal: Rabbit LD 50 = 730 mg/kg
Inhalation: Human TCLO = 200 ppm (Irritant Effects)
Rat LCLO = 4,000 ppm / 8 hr

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 30 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately flush skin with lots of running water for 30 minutes. Remove contaminated clothing and
shoes; wash before reuse. Get immediate medical attention.

If Swallowed:
Do not induce vomiting. If conscious, give lots of water. Get immediate medical attention. Do not give
anything by mouth to an unconscious or convulsing person.

Notes To Physician:
There is no specific antidote. Treatment should be directed at the control of symptoms and the clinical
conditions. Due to the irritant nature of the material, the stomach should be evacuated carefully in cases
of poisoning by swallowing.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the
PEL.

Respiratory Protection:
If use conditions generate vapours or mists, wear a niosh-approved respirator appropriate for those
emission levels. Appropriate respirators may be a full facepiece air-purifying cartridge respirator
equipped for organic vapours/mists, a self-contained breathing apparatus in the pressure demand mode,
or a supplied-air respirator.

Eye Protection:
Chemical goggles and full faceshield unless a full facepiece respirator is also worn. It is generally
recognized that contact lenses should not be worn when working with chemicals because contact lenses
may contribute to the severity of an eye injury.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0036
Protective Clothing:
Long-sleeved shirt, trousers, safety shoes, butyl rubber gloves or neoprene gloves and apron.

Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.
Storage And Handling Precautions:
Store in a cool, dry, well-ventilated place away from incompatible materials. Vent container carefully,
as needed, to relieve pressure. keep container tightly closed when not in use. Do not use pressure to
empty container. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Keep away
from heat, sparks, and flames.

Danger:
Causes eye and skin burns. Harmful if inhaled or absorbed through skin. harmful and corrosive if
swallowed. May cause liver and kidney damage. may cause allergic skin reaction. May cause asthma
with possible long-term lung damage. Aspiration may cause lung damage. Combustible.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.
Warning:
Hot organic chemical vapours or mists are susceptible to sudden spontaneous combustion when mixed
with air.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full. Avoid discharge to sewers or natural
waters because this product is toxic to fish and is biodegradable only in very low concentrations (about
10 ppm).

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear alkali-resistant slicker suit and complete protective equipment including butyl rubber boots, butyl
rubber gloves, butyl rubber apron, and a self-contained breathing apparatus in the pressure demand mode
or supplied-air respirator. If the spill or leak is small, a full facepiece air-purifying cartridge respirator
equipped for organic vapours may be satisfactory. In any event, always wear eye protection. Extinguish
all ignition sources. For small spills or drips, mop or wipe up and dispose of in DOT-approved waste
containers. For large spills, contain by diking with soil or other non-combustible sorbent material and
then pump into DOT-approved waste containers; or absorb with non-combustible sorbent material and
place residue in DOT-approved waste containers. Keep out of sewers, storm drains, surface waters, and
soil. Small spills could be flushed with large amounts of water.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0039

Material Safety Data Sheet

City University of Hong Kong

MSDS FORMIC ACID 0039

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Formic Acid

Chinese Name:
Common Synonyms: Hydrogen Carboxylic Acid
Chemical Family: Organic Acids
Formula: HCOOH
Formula Wt.: 46.03
C.A.S.: 64-18-6
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 101 deg. C (213 deg. F) Vapour Pressure (mmHg): 23
(@ 760 mmHg) (20 deg. C)
Melting Point: 8 deg. C (46 deg. F) Vapour Density (Air=1): 1.6
(@ 760 mmHg)
Specific Gravity: 1.21 Evaporation Rate: 2.1
(H2O=1) (Butyl Acetate = 1)
Solubility(H2O): Complete (100%) % Volatiles By Volume: 100
(21 deg. C)
pH: 1.5
Odour Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odour: Colourless liquid. Pungent odour.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Fire Extinguishing Media: Use water spray, alcohol foam, dry chemical or carbon dioxide.
Flash Point (Closed Cup): 49 deg. C (122 deg. F)
Flammable Limits: Upper - 57 % Lower - 18 %
Autoignition Temperature: 433 deg. C (813 deg. F)
Toxic Gases Produced: Carbon monoxide, carbon dioxide
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: None identified.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibles: Strong oxidizing agents, strong bases, sulfuric acid
Decomposition Products: Carbon monoxide, carbon dioxide
Conditions To Avoid: Heat, flame, other sources of ignition

========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): 9 mg/m3 (5 ppm)

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0039
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 9 mg/m3 (5 ppm)
Toxicity Of Components:
Oral Rat LD 50 For Formic Acid 1100 mg/kg
Intraperitoneal Mouse LD 50 For Formic Acid 940 mg/kg
Inhalation-15min Rat LC50 For Formic Acid 15 g/m3
Intraperitoneal Mouse LD 50 For Water 190 g/kg
Intravenous Mouse LD50 For Water 25 g/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No
Carcinogenicity: None identified.
Reproductive Effects: None identified.
Effects Of Overexposure:
Inhalation: Severe irritation of respiratory system, coughing, chest pains, nausea, vomiting
Skin Contact: severe irritation or burns
Eye Contact: severe irritation or burns
Skin Absorption: none identified
Ingestion: Irritation and burns to mouth and stomach, nausea, dizziness, unconsciousness
Chronic Effects: None identified

Target Organs: Respiratory System, Skin, Kidneys, Liver, Eyes

Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give water, milk, or milk of
magnesia.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact:
In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. at concentrations up to 100
ppm, a chemical cartridge respirator with organic vapour cartridge and dust/mist filter is recommended.
Above this level, a self-contained breathing apparatus is recommended.

Eye/Skin Protection:
Safety goggles and face shield, uniform, protective suit, neoprene gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area or
cabinet.

Special Precautions: Bond and ground containers when transferring liquid.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking, or flames in area. Stop leak if you can do so without risk. Neutralize spill with soda ash or
lime. With clean shovel, carefully place material into clean, dry container and cover. Remove from spill
area. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0041

Material Safety Data Sheet

City University of Hong Kong

MSDS GLYCINE 0041

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Glycine

Chinese Name:
Synonyms: Glycocoll; Aminoacetic Acid
Formula: NH2CH2COOH
C.A.S.: 56-40-6

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State : Liquid

Boiling Point : Not applicable
Vapour Pressure, mmHg/20 deg. C: Not applicable

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point : N/D
Vapour Density (Air=1): Not applicable
Specific Gravity (Water=1): 1.595
Water Solubility, %: 217
Appearance And Odour: White crystalline solid.
Evaporation Rate (Butyl Acetate=1): Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Nonflammable

Extinguishing Media:
This material is not combustible. Use extinguishing media appropriate for surrounding fire.

Flash Point : Not applicable

Flammable Limits In Air, % Lower: N/D Upper: N/D
Special Fire Fighting Procedures: Use water spray to cool nearby containers and structures exposed to
fire.
Unusual Fire And Explosion Hazards: Extinguish all nearby sources of ignition.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility: Alkali, oxidizing materials.
Hazardous Decomposition Products:
May liberate carbon monoxide, carbon dioxide, oxides of nitrogen and ammonia.

Conditions To Avoid: None

========================================================================
FIRST AID MEASURES
========================================================================

Primary Routes Of Exposure: Skin or eye contact, inhalation.

Signs And Symptoms Of Exposure:
Inhalation: None currently known.
Eye Contact: Dusts may irritate the eyes.
Skin Contact: Prolonged or repeated contact with the dust may irritate the skin.
Swallowed: None currently known.
Chronic Effects Of Exposure: No specific information available.
Medical Conditions Generally Aggravated By Exposure: None reported.
Oral: No data found.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0041
Dermal: No data found.
Inhalation: No data found.
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
Do not induce vomiting. If conscious, give lots of water. Get immediate medical attention. Do not give
anything by mouth to an unconscious or convulsing person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining dust emissions at the point of use.

Respiratory Protection:
If use conditions generate dusts, wear a NIOSH-approved respirator appropriate for those emission
levels. Appropriate respirators may be a full facepiece or a half mask air-purifying cartridge respirator
with particulate filters, a self-contained breathing apparatus in the pressure demand mode, or a
supplied-air respirator.

Eye Protection:
Chemical goggles and full face shield. It is generally recognized that contact lenses should not be worn
when working with chemicals because contact lenses may contribute to the severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Storage And Handling Precautions:
Store in a cool, dry, well-ventilated place away from incompatible materials. Keep container tightly
closed when not in use. Do not use pressure to empty container. Wash thoroughly after handling. Do not
get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: None.

Other Precautions:
This product is intended for use in food, animal feed, drug, or cosmetic manufacture and it has been
produced and packaged in accordance with strict quality practices. Maintain this quality level by storing
this product away from other chemicals, handling it with care, and avoiding all sources of contamination.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a full facepiece or
a half mask air-purifying cartridge respirator with particulate filters. Wear chemical goggles if a half
mask is worn. For small spills, sweep up and dispose of in DOT-approved waste containers. For large
spills, shovel into DOT-approved waste containers. keep out of sewers, storm drains, surface waters,
and soil. Comply with all applicable governmental regulations on spill reporting, and handling and
disposal of waste.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0042

Material Safety Data Sheet

City University of Hong Kong

MSDS HEXANE 0042

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Hexane

Chinese Name:
Synonyms : n-Hexane
Chemical Family : Aliphatic Hydrocarbon
Molecular Formula : C6H14
Molecular Weight : 86.18
C.A.S : 110-54-3

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State : Liquid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Boiling Point, 760mmHg. 68.7 deg. C
Vapour Pressure @ 20 deg. C 124 mmHg
% Volatiles By Volume CA 100
Freezing Point -95.3 deg. C
Vapour Density (Air=1) 3.0
Specific Gravity (H2O=1) @ 20 deg. C 0.659
Evaporation Rate (Buac=1) Ca 10
Solubility In Water @ 20 deg. C 0.014%
Appearance And Odour : Clear, colourless liquid with a mild hydrocarbon odour.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Extinguishing Media : Carbon dioxide, dry chemical or foam.
Flash Point, (Test Method) -26 deg. C (Tag Closed Cup)
Flammable Limits In Air % By Volume: Lower Limit 1.1 Upper Limit 7.5
Auto Ignition Temperature 225 deg. C
Unusual Fire And Explosion Hazards : Very volatile and extremely flammable.
Special Fire Fighting Procedures :
Water will not be effective in extinguishing a fire and may spread it, but a water spray can be used to
cool exposed containers. Wear full protective clothing and self-contained breathing apparatus. Heat
will build pressure and may rupture closed storage containers.

========================================================================
REACTIVITY DATA
========================================================================

Stability : Stable
Hazardous Polymerization : Not expected to occur.
Incompatibility : Strong oxidizing agents.
Hazardous Decomposition Products :
Incomplete combustion can generate carbon monoxide and other toxic vapours.

Conditions To Avoid : Heat, sparks, open flame, open containers, and poor ventilation.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0042
========================================================================
HEALTH HAZARD DATA
========================================================================

Occupational Exposure Limits Concentration Immediately Dangerous

To Health
OSHA TWA - 50 ppm
STEL - Not Listed OSHA/NIOSH 5,000 ppm
CEILING - Not Listed
Odour Threshold
ACGIH TLV-TWA - 50 ppm
TLV-STEL - Not Listed NSC Not listed
NIOSH Not listed

NIOSH 10 hour TWA - 100 ppm

15 min Ceiling - 510 ppm

Carcinogenic Data: Hexane is not listed as a carcinogen by IARC, NTP, OSHA, or ACGIH.
Primary Routes Of Entry:
Hexane may exert its effects through inhalation, skin absorption, and ingestion.

Industrial Exposure: route of exposure/signs and symptoms

Inhalation: Exposure can cause dizziness, numbness of extremities, and intoxication.
Eye Contact: liquid and high vapour concentration can be irritating.
Skin Contact:
Prolonged or repeated skin contact can cause irritation and dermatitis through defatting of skin.
Ingestion: can cause gastrointestinal tract discomfort.

Effects Of Overexposure:
Hexane is a mild eye and mucous membrane irritant, primary skin irritant, central nervous system
depressant and neurotoxin. Acute exposure causes irritation, narcosis, and gastrointestinal tract
irritation. Chronic inhalation causes peripheral neuropathy. No systemic toxicity has been reported.

Medical Condition Aggravated By Exposure:

Preclude from exposure those individuals susceptible to dermatitis.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Immediately remove to fresh air. If not breathing, administer mouth-to-mouth rescue breathing. If there
is no pulse administer cardiopulmonary resuscitation (CPR). Contact physician immediately.

Eye Contact:
Rinse with copious amounts of water for at least 15 minutes. Get emergency medical assistance.

Skin Contact:
Flush thoroughly for at least 15 minutes. Wash affected skin with soap and water. Remove contaminated
clothing and shoes. Wash clothing before re-use, and discard contaminated shoes. Get emergency
medical assistance.

Ingestion: Contact physician immediately. Aspiration hazard - do not induce vomiting.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Adequate ventilation is required to protect personnel from exposure to chemical vapours exceeding the
pel and to minimize fire hazards. The choice of ventilation equipment, either local or general, will
depend on the conditions of use, quantity of material, and other operating parameters.

Respiratory:
Use approved respirator equipment. Follow NIOSH and equipment manufacturer's recommendations to
determine appropriate equipment (air-purifying, air-supplied, or self-contained breathing apparatus).

Eyes:
Safety glasses are considered minimum protection. Goggles or face shield may be necessary depending
on quantity of material and conditions of use.

Skin:
Protective gloves and clothing are recommended. The choice of material must be based on chemical
resistance and other user requirements. Generally, neoprene or nitrile rubber offer acceptable chemical
resistance. Individuals who are acutely and specifically sensitive to hexane may require additional
protective equipment.

Storage:
Hexane should be protected from temperature extremes and direct sunlight. Proper storage of hexane
must be determined based on other materials stored and their hazards and potential incompatibility. In
general, hexane should be stored in an acceptably protected and secure flammable liquid storage room.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0042
Other:
Emergency eye wash fountains and safety showers should be available in the vicinity of any potential
exposure. Ground and bond metal containers to minimize static sparks.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill Control:
Protect from ignition. Wear protective clothing and use approved respirator equipment. Absorb spilled
material in an absorbent recommended for solvent spills and remove to a safe location for disposal by
approved methods. If released to the environment, comply with all regulatory notification requirements.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0043

Material Safety Data Sheet

City University of Hong Kong

MSDS HYDROCHLORIC ACID 0043

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Hydrochloric Acid

Chinese Name:
Synonym(s): Aqueous Hydrogen Chloride, Muriatic Acid.
Chemical Family: Inorganic Acid
Molecular Formula: HCl
C.A.S.: 7647-01-0
Product Use:
Acidizing (activation) of petroleum wells; scale removal; ore reduction; metal cleaning; pH adjustment.

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Odour And Appearance: Colourless or slightly yellow, fuming liquid with pungent odour.
Odour Threshold: Range 1-35 ppm.
Vapour Pressure: 146 mmHg @ 25 deg. C
Vapour Density: Not available.
Evaporation Rate: Not available.
pH: 0.1 (3.6% W/V, 1N), 1.1 (0.36% W/V, 0.1N)
Boiling Point: 55.5 deg. C
Freezing Point: -25.4 deg. C
Solubility In Water: 100%
Molecular Weight: 36.46
Specific Gravity: 1.18 @ 20 deg. C (Water=1 @ 4 deg. C)
% Volatile By Volume: 100 @ 20 deg. C
Coefficient Of Water/Oil Distribution: Not available.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Conditions Of Flammability: Not combustible

Means Of Extinction:
Use water spray to cool containers to prevent rupture and reduce vapour. Do not get water inside
containers. Extinguishing agents compatible with hydrochloric acid include dry chemical, carbon
dioxide, water spray and foam.

Flash Point: Not combustible (does not burn)

Upper Flammable Limit: Not applicable.
Lower Flammable Limit: Not applicable.
Auto Ignition Temperature: Not applicable.
Hazardous Combustion Products: Hydrogen and chlorine gas form at high temperatures.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Does not occur.
Incompatibility:
Strong Bases
(Eg. Hydroxides, Carbonates, Amines) Can react violently and release considerable heat.
Metals - Many metals react and release flammable hydrogen gas.
Phosphines
May react violently and may produce toxic, spontaneously flammable phosphine gas.
Acetylides, Borides, Carbides, Silicides
Reaction may be very hot and may yield spontaneously flammable gas.
Vinyl Acetate - May polymerize violently.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0043
Formaldehyde
Reaction with formaldehyde solutions may yield a potent human carcinogen, bis(chloromethyl)ether.
Cyanides, Sulfides - May release toxic gas.
Hazardous Decomposition Products: None

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Vapour or mist can cause irritation of the nose, throat, and upper respiratory tract. Symptoms include
coughing, choking, and bleeding of the nose and gums. Severe exposure can result in pulmonary edema
and corrosion of tissues in the nose and throat.

Skin Contact: Causes severe burns if not washed off quickly.

Eye Contact: Causes eye irritation, severe burns, and permanent blindness.

Ingestion:
Causes severe burns of the mouth, esophagus, and stomach with consequent pain, nausea and vomiting,
thirst, diarrhea, circulatory collapse and possibly death.

Chronic Exposure Effects:

Inhalation:
Prolonged exposure can cause erosion and discoloration of the teeth and chronic inflammation of the
nose, throat and airways.

Skin Contact: Repeated or prolonged contact to dilute solutions can cause dermatitis.

Exposure Limits: Ceiling Exposure Limit (TLV-C):

5 ppm (7 mg/m3) (Hydrogen Chloride - ACGIH)
Mutagenicity: Not available.
Carcinogenicity: Not carcinogenic (IARC and ACGIH)
Sensitization To Product: Not available.
Reproductive Toxicity: Not available.
Names Of Toxicologically Synergistic Products: Not available.
Animal Toxicity Data:
LC50 (Rat): 3,124 ppm/1-Hour Exposure. (100% HCl)
LC50 (Rat, Inhalation Of Mists): 5,666 ppm/30 min. (100% HCl)
LC50 (Mouse, Inhalation Of Mist): 2,142 ppm/30 min. (100% HCl)
LD50 (Rabbit, Oral): 900 mg/kg. (100% HCl)

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove source of contamination or move victim to fresh air. If victim is unconscious, do not give
anything by mouth. Check breathing and pulse. If breathing has stopped, give victim artificial respiration.
If heart is stopped give cardiopulmonary resuscitation (CPR) immediately. If breathing becomes rapid
and bubbly, place the person in a sitting position, and give oxygen if possible. Obtain medical attention
immediately.

Skin Contact:
As quickly as possible, flush contaminated area with lukewarm gently running water for at least 15
minutes. Under running water, remove contaminated clothing, shoes, and leather goods. Obtain medical
attention immediately.

Eye Contact:
Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes, holding
the eyelid(s) open. Take care not to rinse the contaminated water into the non-affected eye. Obtain
medical attention immediately.

Ingestion:
Unless victim is unconscious or convulsing, rinse residual hydrochloric acid from the mouth with water.
If victim can swallow, give one cup (250-300 ml) of water or milk to dilute the material in the stomach.
Do not induce vomiting. If vomiting occurs naturally, rinse mouth and give water again. Obtain medical
attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection:
-Up to 50 ppm: supplied air respirator, self contained breathing apparatus, chemical charge respirator,
or a powered air purifying respirator both with cartridge(s) to protect against hydrogen chloride.

-Up to 100 ppm: supplied air respirator operated in a continuous flow mode, full-facepiece supplied air
respirator, or full-facepiece self contained breathing apparatus.

Skin Protection:
Impervious gloves, body suits, boots, and/or other resistant protective clothing. An eye-wash and safety
shower should be located near any area where hydrochloric acid is handled.

Eye/Face Protection: Chemical safety goggles or face shield for emergency or nonroutine conditions.
Materials For Protective Clothing:
Natural rubber, neoprene, buna-n, polyethylene or PVC (polyvinyl chloride).

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0043
Handling Procedures:
When diluting or preparing solutions, slowly add acid to water to avoid boiling and splattering always
use in a well ventilated area, preferably with local ventilation.

Storage Requirements:
Store closed containers in a clean, cool, open or well ventilated area, preferably with local ventilation.

Engineering Controls:
Local ventilation is normally required when handling this chemical. Enclosed systems are preferred.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps In The Event Of A Spill Or Leak:

Only persons wearing protective equipment should be allowed in areas of leaks. Ventilate area. Vapours
evolved from a spill or leak can be knocked down with water fog or spray. Contain spill using absorbent
materials. Prevent entry into bodies of water or sewer systems. Absorbent materials which have been
tested and recommended for concentrated hydrochloric acid are: anionic polyacrylamide (R 1779),
nonionic polyacrylamide (versicol W25), and cellosize WP3H (hydroxyethylcellulose)

Waste Disposal:
Waste hydrochloric acid or acid contaminated water, must never be discharged directly into sewers or
surface water. Contaminated material should be neutralized with soda ash (Na2CO3),lime (CaO), or
limestone (CaCO3). The residual sludge can be shovelled into containers for disposal.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0045

Material Safety Data Sheet

City University of Hong Kong

MSDS HYDROGEN PEROXIDE (30-52%) 0045

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Hydrogen Peroxide (30-52% Peroxide)

Chinese Name:
Synonyms: Hydrogen Peroxide
Chemical Family : Inorganic Peroxide
Formula: H2O2
CAS No.: 7722-84-1

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

Boiling Point : A = 222 deg. F; B = 220 deg. F; C = 226 deg. F; D = 237 deg. F

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapour Pressure, mmHg/30 deg. C: 18-24
Melting Point : A = -151 deg. F; B = -19 deg. F; C = -27 deg. F; D = -62 deg. F
Vapour Density (Air=1): Not Applicable
Specific Gravity (Water=1): A = 1.112; B = 1.11; C = 1.133; D = 1.196
Water Solubility, %: 100
Appearance And Odour: Clear, colourless liquid; pungent odour
Evaporation Rate (Butyl Acetate=1): >1
Where: A = 30%; B = 31%; C = 35%; D = 50%

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Nonflammable

Extinguishing Media: Flood with water.
Flash Point : None
Flammable Limits In Air, % Lower: Not applicable Upper: Not applicable

Special Fire Fighting Procedures:

Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards:

This product may cause a fire if it drys on clothing, wood, or other combustibles. Contact with
flammable liquids or vapours may cause immediate fire or explosion, especially if heated, or it may
result in a delayed explosion. Decomposition will release oxygen which will increase the explosive
limits and burning rate of flammable vapours.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Unstable
Polymerization: Will not occur
Incompatibility:
Reducing agents, combustible materials such as wood, cloth, or organic materials, metals such as iron
and copper and their alloys, and dirt. also rust, cyanides, hexavalent chromium compounds, nitric acid,
potassium permanganate, and heavy metals and their salts.

Hazardous Decomposition Products:

Releases oxygen gas which, in a confined space, will increase explosive limits and burning rate of
flammable vapours. Decomposition will also result in dangerous pressure increases within containers or
storage vessels.

Conditions To Avoid: excessive heat and contamination of any kind.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0045
========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin or eye contact, inhalation.

Signs And Symptoms Of Exposure:
Inhalation: Vapours and mists severely irritate the nose and throat.
Eye Contact:
Vapours will irritate the eyes. Liquid and mists will irritate and may burn the eyes. This product is
corrosive to the eyes and its effects may be delayed. Direct liquid contact on the eyes may cause
irreversible damage, including blindness.

Skin Contact:
Brief exposure will irritate the skin. Longer exposure causes irritation, blisters, and burns.

Swallowed:
The liquid is severely irritating to the mouth and throat. Swallowing the liquid may cause a sudden
evolution of oxygen, which can cause injury by distension of the esophagus or stomach. Local internal
bleeding may result. Swallowing may produce corrosion (burning) of the gastro intestinal tract that
maybe life threatening.

Chronic Effects Of Exposure:

Human health effects of overexposure may initially include skin irritation with discomfort or rash, eye
irritation with discomfort, tearing or blurring of vision, or irritation of the upper respiratory tract.
Higher exposures may lead to eye corrosion with corneal or conjunctival ulceration, skin burns or
ulceration, or temporary lung irritation effects with cough, discomfort, difficulty in breathing, or
shortness of breath. There are inconclusive or unverified reports of human sensitization.

Medical Conditions Generally Aggravated By Exposure: None reported.

Oral: Rat LD 50 = 75 mg/kg (For 75% H2O2)
Dermal: Rabbit LD 50 = 9200 mg/kg (For 70% H2O2)
Inhalation: Rat LC 50 > 2000 ppm/8 hr (90% H2O2)
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Other Data:
This product has been reported to be carcinogenic to mouse duodenum when administered at a level of
0.4% in the drinking water continuously over a 108 week lifetime. However, it is improbable that
humans will be exposed to such high oral doses due to the acute toxicity of concentrated solutions and
the corrosivity of this product to mucous membranes. Accidental human exposure to such high doses is
also unlikely since this dose is expected to cause acute toxicity after one exposure. Tests for mutagenic
activity in mammalian cell cultures or for fetus effects in animals have been inconclusive, with positive
results in some studies and negative results in others. Tests in animals demonstrate no reproductive
toxicity.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately flood skin with lots of running water for 15 minutes. Remove contaminated clothing and
shoes. Get medical attention if irritation persists after flooding. Destroy contaminated clothing and shoes.

If Swallowed:
Do not induce vomiting. If conscious, give lots of water. Get immediate medical attention. Do not give
anything by mouth to an unconscious or convulsing person.

Note To Physician:
Insert a gastric tube to prevent increased pressure that may result from the rapid evolution of oxygen.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the PEL.

Respiratory Protection:
Wear a NIOSH-approved self-contained breathing apparatus in the pressure demand mode, or a
supplied-air respirator if use conditions generate vapours or mists.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0045
Eye Protection:
Chemical goggles and full faceshield unless a full facepiece respirator Is also worn. It is generally
recognized that contact lenses should not Be worn when working with chemicals because contact lenses
may contribute to the severity of an eye injury.

Protective Clothing:
Polyester or acrylic full body covering clothing. Nitrile rubber or neoprene boots, apron, and gloves.
Do not wear leather shoes or shoes that are cracked, suede, or other porous materials.

Other Protective Measures: An eyewash and safety shower should benearby and ready for use.

Storage And Handling Precautions:

Store in a cool, dry place. Store away from all other chemicals and potential sources of contamination.
Keep container tightly closed when not in use. Do not use pressure to empty container. Wash thoroughly
after handling. Do not get in eyes, on skin, or on clothing. Store only in a properly vented container or
approved bulk storage facility. Do not block vent in bung cap. Never add any other product to
container. Never return unused peroxide to original container.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear polyester or acrylic body-covering clothing and rubber boots, rubber apron, rubber gloves, hard
hat with brim, and a self-contained breathing apparatus in the pressure-demand mode. Always wear
chemical goggles and a full face shield if a self-contained breathing apparatus is not worn. Extinguish all
ignition sources and contain by diking with a non-combustible absorbent. Dilute with lots of water and
allow peroxide to decompose. Then pump residue into DOT-approved waste containers or absorb the
residue on non-combustible absorbent and place that residue in DOT-approved waste containers. Keep
out of sewers, storm drains, surface waters, and soil. Comply with all applicable governmental
regulations on spill reporting, and handling and disposal of waste.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0051

Material Safety Data Sheet

City University of Hong Kong

MSDS LEAD ACETATE 0051

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Lead Acetate

Chinese Name:
Common Names/Synonyms:
Lead Acetate (II) Trihydrate; Acetic Acid Lead (II) Salt, Trihydrate
Formula: C4H6O4Pb3H2O
CAS NO.: 301-04-02

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point : 212 deg. F (Decomposes)

Vapor Pressure, mmHg/20 deg. C: Not given

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point : 167 deg. F
Vapor Density (Air=1): Not given
Specific Gravity (Water=1): 2.55
Water Solubility, %: 60
Appearance And Odor: White crystalline granules; slightly acetic odor
Evaporation Rate (Butyl Acetate=1): Not given

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point : Not Flammable Flammable Limits In Air, %

Method Used: N/A Lower: N/A Upper: N/A
Extinguishing Media: Use any medium appropriate for extinguishing surrounding fires.
Special Fire Fighting Procedures: Fire fighters should wear self-contained breathing apparatus.
Unusual Fire And Explosion Hazards:
Extinguish all nearby sources of ignition since vapors decompose to hazardous products. (acetic acid,
carbon monoxide and toxic fumes of lead oxide at high temperatures.)

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Conditions To Avoid: Temperatures above 212 deg. F
Materials To Avoid: Bromates, phenol chloral hydrate, sulfides, and acids.
Hazardous Decomposition Products: Lead, lead oxide, acetic acid, carbon monoxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin or eye contact

Signs And Symptoms Of Exposure
Inhalation:
Lead can be absorbed through the respiratory system. local irritation of bronchia and lungs can occur.
Prolonged exposure or repeated exposure can lead to lead poisoning and death. (see swallowing)

Eye Contact:
Dusts will irritate the eyes and prolonged contact may damage the eyes. Absorption of lead can occur
through eye tissues.

Skin Contact:
May be absorbed through skin. Symptoms of lead poisoning (see swallowed) may occur. Contact over
short periods may cause severe irritation or burns.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0051

Swallowed:
Poison! Early symptoms of lead poisoning are fatigue, disturbance of sleep, constipation. More severe
exposures may result in abdominal pain, nausea, headache, loss of appetite, metallic taste in mouth,
muscle and joint pain, dizziness and hypertension. Prolonged overexposure can severely damage red
blood cell formation, central and peripheral nervous system, kidneys and liver. Resulting high levels
of lead in blood may lead to convulsions, coma and death. Soluble lead compounds, such as lead
acetate, are the most dangerous. OSHA has reported that lead may impair the reproductive systems of
both men and women; damage may also be caused to the unborn fetus.

Chronic Effects Of Exposure:

Lead is a cumulative poison and even exposures to small amounts can raise the body's content to toxic
levels. The symptoms of chronic exposure are like those for ingestion.

Medical Conditions Generally Aggravated By Exposure:

Persons with pre-existing nerve or circulatory disorders or with skin or eye problems may be more
susceptible to the effects of this substance.

Oral: Rat TDLO=8524 mg/kg/78weeks (Carcinogenic)

Dermal: No data found
Inhalation: No data found
Carcinogenicity:
Lead acetate is listed as a carcinogen in the NTP third annual report on carcinogens and it is
considered an animal carcinogen by the IARC. Lead acetate is not regulated as a carcinogen by OSHA.

Other Data: None

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately flush skin with lots of running water for 15 minutes. Remove contaminated clothing and
shoes; wash before reuse. Get immediate medical attention.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
If Swallowed:
If conscious, immediately induce vomiting by giving 2 glasses of water and sticking a finger down the
throat. Get immediate medical attention. Do not give anything to an unconscious or convulsing person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the
lowest PEL.

Respiratory Protection:
NIOSH-approved dust respirator or mask in the absence of adequate environmental controls at the point
of use.

Eye Protection: chemical goggles and full face shield.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, rubber gloves, and rubber apron.

Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.
Storage And Handling Precautions:
Store in a cool, dry place; well ventilated and away from sources of heat or ignition. Store away from
all other chemicals and potential sources of contamination. Keep container tightly closed when not in
use. Do not use pressure to empty container. Wash thoroughly after handling. Do not get in eyes, on
skin, or on clothing.

Repair And Maintenance Precautions: None.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapors. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, chemical goggles and
approved respirators. For small spills, sweep up and dispose of in DOT-approved waste containers.
For large spills, shovel into DOT-approved waste containers. Keep lead residues out of sewers, storm
drains, surface waters and soil. Comply with all applicable governmental regulations on spill reporting,
and handling and disposal of waste.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0052

Material Safety Data Sheet

City University of Hong Kong

MSDS LEAD NITRATE 0052

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Lead Nitrate

Chinese Name:
Synonyms: Lead Dinitrate; Nitric Acid, Lead (2+) Salt
Chemical Family: Lead Salt
Formula: Pb(NO3)2
C.A.S.: 10099-74-8

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point : 13601 deg. F (Decomposes)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point : 880 deg. F (Decomposes) Vapour Density (Air=1): N/A
Vapour Pressure, mmHg/20 deg. C: N/A
Specific Gravity (Water=1): 4.53 Water Solubility, %: 56.5
Appearance And Odour: White or colourless translucent crystals; odourless
Evaporation Rate (Butyl Acetate=1): N/A

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Extinguishing Media: Flood with water.
Flash Point : N/A
Flammable Limits In Air, % Lower: N/A Upper: N/A
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus. Use water spray to cool nearby containers
and structures exposed to fire.

Unusual Fire And Explosion Hazards:

Strong oxidizer. In contact with easily oxidizable substances, it may react rapidly enough to cause
ignition, violent combustion, or explosion. increases the flammability of any combustible substance.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility:
Reducing agents, combustible materials such as wood, cloth, or organic materials, metals such as iron
and copper and their alloys, and any other oxidizable materials.

Hazardous Decomposition Products: Will liberate toxic oxides of nitrogen.

Conditions To Avoid: High temperatures.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Inhalation, skin or eye contact.

Signs And Symptoms Of Exposure:
Inhalation:
Lead can be easily absorbed through the respiratory system. Local irritation of bronchia and lungs may
occur and in cases of acute exposure, symptoms such as metallic taste, chest and abdominal pain and
increased lead blood levels may follow. (see swallowing)

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0052

Eye Contact: dusts may irritate the eyes.

Skin Contact:
Dusts are extremely corrosive to the skin and rapidly cause severe chemical burns. Moisture on the
skin, such as from perspiration, will accelerate tissue destruction. Contact with inorganic lead over
short periods may cause local irritation or burns.

Swallowed:
Poison! Early symptoms of lead poisoning are fatigue, disturbance of sleep, constipation. More severe
exposures may result in abdominal pain, nausea, headache, loss of appetite, metallic taste in mouth,
muscle and joint pain, dizziness and hypertension. Prolonged overexposure can severely damage red
blood cell formation, central and peripheral nervous system, kidneys and liver. Resulting high levels
of lead in blood may lead to convulsions, coma and death. Soluble lead compounds, such as lead
nitrate, are the most dangerous.

Chronic Effects Of Exposure:

Lead is a cumulative poison and exposure to even small amounts can raise the body's content to toxic
levels. The symptoms of chronic exposure are those for lead poisoning (see swallowing) and
restlessness and irritability may also be noted.

Medical Conditions Generally Aggravated By Exposure:

Persons with pre-existing nerve or circulatory disorders or with skin oreye problems may be more
susceptible to the effects of this substance.

Oral: Guinea Pig LDLO = 500 mg/kg

Dermal: No data found
Inhalation: No data found
Carcinogenicity:
This material is not considered to be a carcinogen by the nationaltoxicology program, the international
agency for research on cancer,or the occupational safety and health administration.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
In Case Of Skin Contact:
Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
If conscious, immediately induce vomiting by giving 2 glasses of water and sticking a finger down the
throat. Get immediate medical attention. Do not give anything by mouth to an unconscious or convulsing
person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining dust emissions at the point of use below the
PEL.

Respiratory Protection:
If use conditions generate dusts, wear a NIOSH-approved respirator appropriate for those emission
levels. Appropriate respirators may be a full facepiece or a half mask air-purifying cartridge respirator
with particulate filters, a self-contained breathing apparatus in the pressure demand mode, or a
supplied-air respirator.

Eye Protection:
Chemical goggles unless a full facepiece respirator is also worn. It is generally recognized that contact
lenses should not be worn when working with chemicals because contact lenses may contribute to the
severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, and gloves.

Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

Storage And Handling Precautions:

Store in a cool, dry place. Do not store on wooden floors! Store away from all other chemicals and
potential sources of contamination. Keep container tightly closed when not in use. Do not use pressure
to empty container. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.
Other Precautions:
Containers, even those that have been emptied, will retain product residue. Always obey hazard
warnings and handle empty containers as if they were full.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0052
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a full facepiece or
a half mask air-purifying cartridge respirator with particulate filters. Wear chemical goggles if a half
mask is worn. For small spills, sweep up and dispose of in DOT-approved waste containers. For large
spills, shovel into DOT-approved waste containers. Keep out of sewers, storm drains, surface waters,
and soil.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0054

Material Safety Data Sheet

City University of Hong Kong

MSDS MERCURIC CHLORIDE 0054

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Mercuric Chloride

Chinese Name:
Synonyms: Mercury(2)Chloride; Mercury Bichloride; Mercury Perchloric
Chemical Family: Mercuric Salt
Formula: HgCl 2
C.A.S.: 7487-94-7

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point : 5761 deg. F

Vapour Pressure, mmHg/20 deg. C: Not applicable

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point : 531 deg. F
Vapour Density (Air=1): 8.7
Specific Gravity (Water=1): 5.44
Water Solubility, %: 1-10%
Appearance And Odour: White crystal or powder no odour
Evaporation Rate (Butyl Acetate=1): Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Extinguishing Media:
This material is not combustible. Use extinguishing media appropriate for surrounding fire.

Flash Point : Not applicable

Flammable Limits In Air, % Lower: Not applicable Upper: Not applicable
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards:

Extinguish all nearby sources of ignition since vapours decompose to hazardous products at high
temperatures. Closed containers.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility:
Strong acids, alkalies, carbonates, strong bases, amines and ammonia, most common metals, bromides,
antimony, arsenic, sodium, potassium, metallic, salts, albumin, gelatin, tannic acid, formates, sulfites,
hypophosphites and phosphates.

Hazardous Decomposition Products: Hydrogen chloride and mercury fumes.

Conditions To Avoid: Heat, sparks, open flames, and out of light.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Swallowed, inhalation, skin or eye contact.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0054
Signs And Symptoms Of Exposure:
Inhalation:
Breathing dust may irritate the nose and throat and cause coughing and chest discomfort. Fatal if
inhaled.

Eye Contact: Dusts will irritate the eyes and prolonged contact may damage the eyes.
Skin Contact:
May be absorbed through skin. Dusts are extremely corrosive to the skin and rapidly cause severe
chemical burns. Moisture on the skin, such as from perspiration, will accelerate tissue destruction and
may cause burns.

Swallowed: swallowing the dusts or solids may cause nausea and vomiting.
Chronic Effects Of Exposure:
Prolonged or repeated exposure to high concentrations may cause loss of appetite, nose bleeds, and
liver, kidney, and neural dysfunction. Fatal if swallowed.

Medical Conditions Generally Aggravated By Exposure:

Pre-existing eye, skin or respiratory disorders may be aggravated.

Oral: (Rat) LD 50 = 1 mg/kg

Dermal: (Mouse) LD 50 = 5 mg/kg
Inhalation: (Rat) LD 50 = 14 mg/kg
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately flush skin with lots of running water for 15 minutes. Remove contaminated clothing and
shoes; wash before reuse. Get immediate medical attention.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
If Swallowed:
If conscious, immediately induce vomiting by giving 2 glasses of water and sticking a finger down the
throat. Get immediate medical attention. do not give anything by mouth to an unconscious or convulsing
person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the PEL.

Respiratory Protection:
A respirator is normally not required if this product is used with adequate ventilation.

Eye Protection:
Chemical goggles. It is generally recognized that contact lenses should not be worn when working with
chemicals because contact lenses may contribute to the severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, rubber boots, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.
Storage And Handling Precautions:
Store in a cool, dry, well-ventilated place away from incompatible materials. Keep bags or fibre drums
dry at all times. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a self-contained
breathing apparatus in the pressure demand mode or a supplied-air respirator. If the spill or leak is
small, a full facepiece air-purifying cartridge respirator equipped with particulate filters may be
satisfactory. In any event, always wear eye protection. for small spills, sweep up and dispose of in
DOT-approved waste containers. For large spills, shovel into DOT-approved waste containers. Keep
out of sewers, storm drains, surface waters, and soil. Comply with all applicable governmental
regulations on spill reporting, and handling and disposal of waste.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0057

Material Safety Data Sheet

City University of Hong Kong

MSDS METHANOL 0057

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Methanol

Chinese Name:
Synonyms: Methyl Alcohol, Wood Alcohol, Carbinol, Wood Naptha, Methyl Hydroxide
Chemical Family: Alcohol
Formula: CH3OH
C.A.S.: 67-56-1

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

Boiling Point : 148-148.5 deg. F Vapour Pressure, mmHg/20 deg. C: 96-100

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point : -144 deg. F Vapour Density (Air=1): 1.1
Specific Gravity (Water=1): 0.79 Water Solubility, %: 100
Appearance And Odour: Clear, colourless liquid; mild alcohol odour
Evaporation Rate (Butyl Acetate=1): >2

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Extinguishing Media:
Use water spray, dry chemical, CO2, or alcohol foam. Do not use a direct water stream.

Flash Point : 52-53 deg. F

Flammable Limits In Air, % Lower: 6 Upper: 36.5
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility:
Strong oxidizing agents, aluminum, zinc, any metal that displaces hydrogen, acids, and alkalis.

Hazardous Decomposition Products:

May liberate carbon monoxide, carbon dioxide, formaldehyde and unidentified organic compounds in
black smoke.

Conditions To Avoid: Heat, sparks, and open flames.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Swallowing, skin or eye contact, inhalation.

Signs And Symptoms Of Exposure:
Inhalation:
Prolonged or repeated exposure or breathing very high concentrations may cause headaches, nausea,
vomiting, dizziness, visual disturbances, giddiness, intoxication, sleepiness, unconsciousness, and
death. initial symptoms of inhalation may only be mild intoxication but may become more severe after
12-18 hours. Toxic effects are exerted on the central nervous system, especially the optic nerve.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0057
Eye Contact: Vapours will irritate the eyes. Liquid and mists will irritate and may burn the eyes.

Skin Contact:
Brief contact may dry the skin. Prolonged or repeated contact may irritate the skin, causing dermatitis.
Methanol may be absorbed through intact skin to produce systemic effects.

Swallowed:
Swallowing 100-250 ml of methanol can be fatal. Swallowing lesser quantities can cause blindness,
dizziness, headaches, or nausea. Absorption of methanol is rapid but excretion is slow, resulting in
delayed effects or compounding effects of repeated exposure. Initial symptoms may only be mild
intoxication but these may become more severe 12-18 hours later. Toxic effects are exerted on the
central nervous system, especially the optic nerve.

Chronic Effects Of Exposure:

Prolonged or repeated exposure may result in CNS damage, blindness, damage to pancreas, or death.

Medical Conditions Generally Aggravated By Exposure: None reported.

Oral: Human LDLO = 340 mg/kg; Rat LD50 = 5628 mg/kg
Dermal: Rabbit LD 50 = 20 g/kg
Inhalation: Human TCLO = 86 g/m3 (Irritation); Rat LC 50 = 64,000 ppm/4h
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
If Swallowed:
If conscious, immediately induce vomiting by giving 2 glasses of water and sticking a finger down the
throat. Get immediate medical attention. after patient has vomited have patient drink milk, water, or
solution of sodium bicarbonate in water (1 tsp/1 qt). Do not give anything to an unconscious or
convulsing person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the pel.

Respiratory Protection:
Wear a niosh-approved self-contained breathing apparatus in the pressure demand mode, or a
supplied-air respirator if use conditions generate vapours or mists.

Eye Protection:
Chemical goggles unless a full facepiece respirator is also worn. It is generally recognized that contact
lenses should not be worn when working with chemicals because contact lenses may contribute to the
severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

Handling And Storage Precautions:

Keep away from heat, sparks, and flames. Store in a cool, dry, well-ventilated place away from
incompatible materials. Vent container frequently, and more often in warm weather, to relieve pressure.
electrically ground all equipment when handling this product and use only non-sparking tools. Keep
container tightly closed when not in use. Do not use pressure to empty container. Wash thoroughly after
handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0057
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a self-contained
breathing apparatus in the pressure demand mode or a supplied-air respirator. In any event, always wear
eye protection. Extinguish all ignition sources and ensure that all handling equipment is electrically
grounded. For small spills or drips, mop or wipe up and dispose of in DOT-approved waste containers.
For large spills, contain by diking with soil or other non-combustible absorbent materials and then pump
into DOT-approved waste containers; or absorb with non-combustible sorbent material, place residue in
DOT-approved waste containers. Keep out of sewers, storm drains, surface waters, and soil. Comply
with all applicable governmental regulations on spill reporting, and handling and disposal of waste.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0060

Material Safety Data Sheet

City University of Hong Kong

MSDS NICKEL CHLORIDE 0060

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Nickel Chloride

Chinese Name:
Synonyms: Nickel Chloride Hexahydrate
Chemical Family: Nickel Compound
Formula: NiCl 2 6H2O
C.A.S.: 7791-20-0

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: N/A Vapour Pressure, mmHg/20 deg. C: N/A

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point: N/A Vapour Density (Air=1): N/A
Specific Gravity (Water=1): 1.57 Water Solubility, %: 100
Appearance And Odour: Green, deliquescent crystals; odourless
Evaporation Rate (Butyl Acetate=1): N/A

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Extinguishing Media:
This material is not combustible. Use extinguishing media appropriate for surrounding fire.

Flash Point: Not Flammable

Flammable Limits In Air, % Lower: N/A Upper: N/A
Special Fire Fighting Procedures: None.
Unusual Fire And Explosion Hazards: None.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility: Violent reaction with potassium.
Hazardous Decomposition Products: None
Conditions To Avoid: None

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin or eye contact

Signs And Symptoms Of Exposure:
Inhalation:
Inhalation causes upper respiratory irritation. Breathing dusts may cause lung damage, including cancer.

Eye Contact: dusts will irritate the eyes.

Skin Contact:
Skin contact causes irritation and sensitization or allergic reactions which may be accentuated by heat
and humidity.

Swallowed: Swallowing large quantities may cause nausea, vomiting and giddiness.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0060
Chronic Effects Of Exposure:
Sensitization or allergic reactions and respiratory disorders may result from prolonged exposure to
nickel compounds. Insoluble nickel compounds, when inhaled, are suspected by some scientists of
contributing to the development of cancer in humans. Soluble nickel compounds, such as nickel
chloride, are not considered in the same class. Individuals hypersensitive to nickel may develop
asthma, bronchitis, shortness of breath, or wheezing.

Medical Conditions Generally Aggravated By Exposure: None reported.

Oral: Rat LD 50 = 105 mg/kg
Dermal: No Data Found
Inhalation: No Data Found
Carcinogenicity:
The IARC and NTP have determined that nickel refining is carcinogenic to humans. However, those
agencies cannot specify which nickel compounds are human carcinogens. Some nickel compounds, not
including nickel chloride, are animal carcinogens. Osha does not regulate this material as a carcinogen.

Other Data: nickel is considered to be an animal teratogen.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
If conscious, immediately induce vomiting by giving 2 glasses of water and sticking a finger down the
throat. Get immediate medical attention. Do not give anything to an unconscious or convulsing person.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining dust emissions at the point of use below the
PEL.

Respiratory Protection:
Wear a niosh-approved respirator appropriate for the dust concentration at the point of use. Appropriate
respirators may be a full facepiece or a half mask air-purifying cartridge respirator with particulate
filters, a self-contained breathing apparatus in the pressure demand mode, or a supplied-air respirator.

Eye Protection:
Chemical goggles unless a full facepiece respirator is also worn. It is generally recognized that contact
lenses should not be worn when working with chemicals because contact lenses may contribute to the
severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

Storage And Handling Precautions:

Store in a cool, dry, well-ventilated place away from incompatible materials. Keep bags or fibre drums
dry at all times. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: None.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a self-contained
breathing apparatus in the pressure demand mode or a supplied-air respirator. If the spill or leak is
small, a full facepiece air-purifying cartridge respirator equipped with particulate filters may be
satisfactory. In any event, always wear eye protection. For small spills, sweep up and dispose of in
DOT-approved waste containers. For large spills, shovel into DOT-approved waste containers. Keep
out of sewers, storm drains, surface waters, and soil.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0061

Material Safety Data Sheet

City University of Hong Kong

MSDS NITRIC ACID 0061

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Nitric Acid 57-59%

Chinese Name:
Synonyms: Aqua Fortis, Engravers Acid, Azotic Acid, Hydrogen Nitrate
Chemical Family: Acids
C.A.S.: 7697-37-2
Molecular Formula: HN03
Product Use:
Manufacture of ammonium nitrate for fertilizer and explosives, organic synthesis(dyes, drugs,
explosives, cellulose nitrate, nitrate salts), metallurgy, photoengraving, etching steel, ore flotation,
urethanes, rubber chemicals, reprocessing spent nuclear fuel.

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

Odour And Appearance:
Water white to slightly yellow liquid with a characteristic NO2 odour. (darkens to brownish colour on
aging and exposure to light.

Odour Threshold: Not available

Vapour Pressure: 8@ 20 deg. C. Vapour Density: (Air=1) 1.58
Evaporation Rate: Low pH: Less Than 1
Boiling Point: 122 deg. C. Specific Gravity: 1.42 @ 70.33%
Melting Point: 68+%=Ca-30 deg. F.(-34 deg. C.),100%=-43.6 deg. F.(-41.6 deg. C.)
Solubility In Water: At All %=100% Molecular Weight: 63.01
% Volatile By Volume: Volatiles @ 122 deg. C. At All %=Ca 100%
Bulk Density: Not available
Coefficient Of Water/Oil Distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Conditions Of Flammability: Nonflammable

Means Of Extinguishing:
Use water on fires involving nitric acid to dilute the acid and to absorb liberated oxides of nitrogen.

Flash Point: Nonflammable

Upper Flammable Limit: Not available
Lower Flammable Limit: Not available
Auto Ignition Temperature: Not available
Hazardous Combustion Products:
Nitric acid is nonflammable, however, it is a strong oxidizing agent and can react with combustible
materials to cause fires. It can also react with metals to liberate flammable hydrogen gas.

Special Fire Fighting Procedures:

Self-contained breathing apparatus should be used by firefighters in an enclosed area with full protective
clothing when nitric acid is involved in the fire.

Explosion Hazards: Not available.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0061
========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur.
Incompatibility:
Strong oxidizer and vigorously attacks most metals. May react with many organics to cause a fire or
produce toxic NOx fumes.

Hazardous Reactions/Decompositions:
Nitrogen oxides (NO, NO2, N2O, N2O3) plus nitric acid mist or vapour.

Conditions To Avoid:
Contact with organic materials such as wood, paper, alcohol, turpentine, hydrogen sulphide, etc, may
cause fires. Combustible materials can have an increased flammability after contact with nitric acid.

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Inhalation of nitric acid mist or fumes at 2 to 25 ppm, over an 8 hour period, may cause pulmonary
irritation and symptoms of lung damage. The onset of symptoms following inhalation may be delayed for
several hours. Concentrations over 200 ppm can cause severe pulmonary damage and may be fatal(in
5-10 hours) after several minutes of exposure.

Skin Contact:
This material is corrosive to all body tissues. Skin contact will produce immediate,severe, burns, with a
yellow skin discoloration.

Eye Contact: eye contact will produce immediate burns.

Ingestion: ingestion will produce burns of the digestive tract.
Chronic Exposure Effects: Discoloration of teeth
Exposure Limits: TLV-TWA 2ppm, TLV: 5mg/m3, STEL: 10mg/m3
Irritancy: High
Mutagenicity: Not available
Carcinogenicity: This product is not considered a carcinogen.
Sensitization To Product: Not available
Reproductive Toxicity: Not available
Toxicologically Synergistic Materials: Not available
Teratogenicity Data: Not available
Animal Toxicity Data:
Oral-Rat:0.06 to 0.6 g/kg

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Inhalation-Rat:3124 ppm/1 hr.
Other Health Effects: Not available

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove victim to fresh air. Administer oxygen, if needed, by authorized personnel. Get medical
attention. Observe 4 to 30 hours after exposure for pulmonary edema. Hospitalization may be required.

Skin Contact:
Wash immediately with soap and water. (remove contaminated clothing promptly, under a safety shower
for gross contact.) Get medical attention.

Eye Contact: Immediately wash with water for at least 15 min.. Get medical attention.
Ingestion: Give 3 or more glasses of milk or water. Do not induce vomiting. Get medical attention.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection: Full Face, Cartridge/S.C.B.A.

Skin Protection: Neoprene gloves and body shields should be used where splashing may occur
Eye/Face Protection: safety goggles and full face shield recommended.

Special Handling Procedures:

Nitric acid is a corrosive material and will attack skin, metals and many organic substances. The
nitrogen oxides produced from the acid are all toxic, and proper ventilation should always be used.
Neutralizing and absorbing materials such as soda ash and sand should be readily available to areas of
use and storage of nitric acid. Electrical fixtures to be vapour-proof. Violations are considered serious
when concentration are above 4 ppm.

Storage Requirements:
Store in a clean, cool, well-ventilated area, away from organic chemicals, strong bases, metal powders,
carbides, sulfides, and any readily oxidizable material. Protect from direct sunlight. Protect against
physical damage. (NFPA #43a, code for oxidizer storage.)use tank cars, tank trucks, drums made of
stainless steel. Open vent or pressure vacuum.

Engineering Controls: Use exhausting fans; use stainless steel piping and vessels.
Other Precautions:
Safety showers, and eye wash should be readily available. Hoses should be stainless steel wrapped and
teflon lined.

========================================================================
ENVIRONMENTAL PROTECTION DATA

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0061
========================================================================

Steps In The Event Of A Leak Or Spill:

Stop discharge. Use water spray to control vapour, contain spill by diking. Pump liquid into an
appropriate container.

Environmental Effects: Aquatic Toxicity: 72 mg/l (pH 6.2)/96hr/mosquito fish/ tlm/fresh water
Deactivating Chemicals: Soda ash, sodium bicarbonate,lime.
Waste Disposal Methods:
Contaminated soil may be neutralized with lime. Contact manufacturer and local government authorities.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0063

Material Safety Data Sheet

City University of Hong Kong

MSDS PHENOL 0063

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Phenol

Chinese Name:
Chemical Family: Phenol
Formula: C6H5OH
Molecular Weight: 94.11g/Mol
C.A.S.: 108952

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Appearance And Odour: White/pink solid, colourless liq. Molten; sweet odour; MP 106

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Boiling Point : 358 deg. F
Specific Gravity: 1.1@60 deg. F (H2O=1)
pH Of Undiluted Product: N.D.
Vapour Pressure: 0.3 @ 25 deg. C mmHg
Viscosity: 3.4 Cst @ 50 deg. C
Percent Voc: 100
Vapour Density: 3.24
Solubility In Water: Moder.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Ignition Temp. : 1121 deg. F

Flash Point (Method): 175 deg. F (TCC)
Flammable Limits (%) Lower: 1.5 Upper: 8.6
Recommended Fire Extinguishing Agents And Special Procedures:
According to NFPA guide, use water spray, dry chemical, foam, or carbon dioxide. Water or foam may
cause frothing. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water
spray to disperse the vapours and to provide protection for persons attempting to stop the leak.

Unusual Or Explosive Hazards: None

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerizations: Will not occur
Incompatibility: Acid chlorides ; acid anhydrides.
Decomposition Products: Carbon monoxide, carbon dioxide, irritating aldehydes and ketones.
Condition To Avoid:

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Route Of Exposure: Eye skin inhalation

Effects Of Overexposure:
Eyes:
Causes irritation, experienced as pain, with excess blinking and tear Production, and seen as marked
excess redness and swelling of the eye And chemical burns of the eye. Severe eye damage may cause
blindness.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0063
Skin:
Toxic. Liquid, solid or vapour can be rapidly absorbed through skin. causes weakness, loss of
coordination, difficulty walking, drowsiness, convulsions, cyanosis (blue discoloration of skin or lips),
and collapse. Symptoms may be delayed. May cause liver and kidney damage. widespread skin contact
with liquid may cause death. Liquid or solid can produce severe irritation, with chemical burns and
rapid tissue destruction. Prolonged or widespread skin contact may result in the absorption of harmful
and potentially fatal amounts of material.

Inhalation:
Vapours are irritating and cause burning of the nose, throat and eyes, coughing, and tightness in the chest.
Severe overexposure may result in difficulty breathing, headache, nausea, vomiting, drowsiness,
cyanosis (blue discoloration of the skin or lips), loss of coordination, and unconsciousness. Prolonged or
severe overexposure may result in pulmonary edema, lung damage, or death. Inhalation of vapours or
mist may result in the absorption of potentially harmful amounts of material.

Ingestion:
Causes burning of mouth, throat, and stomach with abdominal and chest pain, nausea, vomiting, diarrhea,
thirst, weakness, and collapse. aspiration may occur during swallowing or vomiting, resulting in lung
damage.

Sensitization Properties: Unknown.

Chronic:
Prolonged and repeated overexposure may cause damage to liver and kidney; skin contact may cause
darkening of skin. Prolonged and repeated overexposure may cause nausea, diarrhea, loss of appetite,
weight loss, weakness, headache, dark urine, and muscle pain. Repeated skin contact may cause a
persistent irritation or dermatitis.

Medical Conditions Aggravated By Exposure:

Repeated overexposure may aggravate existing liver or kidney disease. skin contact may aggravate an
existing dermatitis (skin condition). overexposure to vapour, dust or mist may aggravate existing
respiratory conditions, such as asthma, bronchitis, and inflammatory or fibrotic respiratory disease.

Other Remarks:
Phenol poisoning can occur via the lungs and skin, or by swallowing. acute overexposure to phenol
causes collapse, convulsions, cyanosis (blue dis-coloration of lips or skin) and coma. Symptoms may be
delayed up to several hours. Widespread skin contact can result in rapid onset of symptoms, and death.

Toxicological Information(Animal Toxicity Data)

Median Lethal Dose (LD 50 LC50) (Species)
Oral: Animal data does not reflect human toxicity; see sections 3 & 15
Inhalation: Animal data does not reflect human toxicity; see sections 3 & 15

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Dermal:
Animal data does not reflect human toxicity; see sections 3 & 15 irritation index, estimation of
irritation (species)

Skin: Corrosive
Eyes: Corrosive
Sensitization: N.D.

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If patient is conscious and can swallow, give two glasses of water (16 oz). Do not induce vomiting. Get
immediate medical attention. Never give anything by mouth to an unconscious or convulsing person.

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, or cyanosis (blue
discoloration of skin or lips) is noted, qualified personnel may administer oxygen. Get immediate
medical attention.

Eye Contact:
Immediately flush eyes with large amounts of running water for at least 15 minutes. Hold eyelids apart
while flushing to rinse entire surface of eye and lids with water. Get medical attention immediately.
Continue flushing with water for an additional 15 minutes if medical attention is not immediately
available.

Skin Contact:
Immediately flush skin with large amounts of running water for at least 15 minutes. Remove contaminated
clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Destroy non-resistant
footwear.

Note To Physician:
Due to the corrosive nature of this material, swallowing may result in severe ulceration, inflammation,
and possible perforation of the upper alimentary tract, with haemorrhage and fluid loss. Aspiration of
this product during induced emesis can result in severe lung injury. evacuation of stomach contents
should be done by means least likely to cause aspiration, such as gastric lavage after endotracheal
intubation. contact a poison control centre for additional treatment information. contamination of skin
with phenol can result in rapid collapse and death after exposure. After skin contamination, keep patient
under observation for at least 24-48 hours. When swallowed, absorption of phenol can be reduced by
activated charcoal, followed by careful gastric lavage. Olive or vegetable oils may also be used; do not
use mineral oil. Respiratory arrest, ventricular arrhythmias, seizures, methemoglobinemia, metabolic
acidosis, and renal failure may occur. Contact a poison control centre for additional treatment
information.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0063
Other Instructions:
Phenol-decontaminating fluid containing polyethylene glycol is more effective than water in removing
phenol from the skin and retarding absorption; olive oil or vegetable oil may also be used; do not use
mineral oil. Alcohols enhance absorption and should not be used. If decontaminating fluids are not
immediately available, wipe material away and flush with water. Do not delay treatment.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Eye/Face Protection:
Avoid eye contact. Chemical type goggles with face shield must be worn. do not wear contact lenses.

Skin Protection:
Protective clothing such as uniforms, coveralls or lab coats must be worn. Launder or dry-clean when
soiled. Gloves resistant to chemicals and petroleum distillates required. When handling large quantities,
impervious suits, gloves, and rubber boots must be worn.

Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If vapour, mist or dust is generated,
use respirator approved by msha or niosh as appropriate. Supplied air respiratory protection should be
used for cleaning large spills or upon entry into tanks, vessels, or other confined spaces. See below for
applicable permissible concentrations.

Ventilation: Adequate to meet occupational exposure limits. (see below)

Exposure Limit For Total Product: 5.0 ppm TWA (Skin) (OSHA and ACGIH)
Precautions To Be Taken In Handling And Storage:
Store away from heat and flame. Ground and bond shipping container and unloading line. For low color,
store at 115-125 stainless steel or lined containers. Eye wash and safety shower should be available
nearby when this product is handled or used.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Procedures In Case Of Accidental Release, Breakage Or Leakage:

Contain spill if possible. Ventilate area. Avoid breathing vapour. Use self-contained breathing apparatus
or supplied air mask for large spills and pump to salvage tanks. If material solidifies, melt with water
and pump to tankage. Soak up small spills with absorbent material for disposal. Avoid contact with eyes,
skin, and clothing.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0065

Material Safety Data Sheet

City University of Hong Kong

MSDS PHOSPHORIC ACID 0065

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Phosphoric Acid

Chinese Name:
Synonyms: Phosphoric Acid; Orthophosphoric Acid; Phos Acid.
Chemical Family: Inorganic Acid
Formula: H3PO4
C.A.S.: 7664-38-2

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

Boiling Point : A=275 deg. F; B=316 deg. F

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point : A=0 deg. F; B=70 deg. F
Vapour Pressure, mmHg/20 deg. C: A,B <6
Vapour Density (Air=1): 3.4
Specific Gravity (Water=1): A=1.58; B=1.69
Water Solubility, %: 100
Appearance And Odour: Clear, colourless syrupy liquid, no odour
Evaporation Rate (Butyl Acetate=1): Not applicable

A=75% Phosphoric Acid; B=85% Phosphoric Acid

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Extinguishing Media:
Use water spray, dry chemical, CO2, or alcohol foam. Do not use a direct water stream.

Flash Point: None

Flammable Limits In Air, % Lower: Not applicable Upper: Not applicable
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards:

Extinguish all nearby sources of ignition since flammable hydrogen gas will be liberated from contact
with some metals.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Materials To Avoid:
Alkalis, oxidizing or reducing materials, cyanides, sulfides, combustible materials, active metals, mild
steel, copper, brass, and bronze.

Hazardous Decomposition Products: May liberate phosphorous oxides.

Conditions To Avoid: None

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0065
========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin or eye contact

Signs And Symptoms Of Exposure:
Inhalation:
Vapours and mists are extremely corrosive to the nose, throat, and mucous membranes. Bronchitis,
pulmonary edema, and chemical pneumonitis may occur. Irritation, coughing, chest pain, and difficulty
in breathing may occur with brief exposure while prolonged exposure may result in more severe
irritation and tissue damage. Breathing high concentrations may result in death.

Eye Contact:
Vapours, liquid, and mists are extremely corrosive to the eyes. Brief contact of the vapours will be
severely irritating. Brief contact of the liquid or mists will severely damage the eyes and prolonged
contact may cause permanent eye injury which may be followed by blindness.

Skin Contact:
Vapours, mists, and liquid are extremely corrosive to the skin. Vapours will severely irritate the skin
and liquid and mists will severely burn the skin. Prolonged liquid contact will burn or destroy
surrounding tissue and death may accompany burns which extend over large portions of the body.

Swallowed:
Vapours, mists, and liquid are extremely corrosive to mouth and throat. Swallowing the liquid burns
the tissues, causes severe abdominal pain, nausea, vomiting, and collapse. Swallowing large quantities
can cause death.

Chronic Effects Of Exposure:

May result in areas of destruction of skin tissue or primary irritant dermatitis. Similarly, inhalation of
vapours or mists may cause varying degrees of damage to the affected tissues and also increasing
susceptibility to respiratory illness.

Medical Conditions Generally Aggravated By Exposure:

Persons with pre-existing skin disorders, eye problems, or impaired liver, kidney or respiratory function
may be more susceptible to the effects of phosphoric acid.

Oral: Rat LD 50 = 1,530 mg/kg

Dermal: Rabbit LD 50 = 2,740 mg/kg
Inhalation: Human TCLO = 100 mg/m3 (Irritation)
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 30 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately flush skin with lots of running water for 30 minutes. Remove contaminated clothing and
shoes; wash before reuse. Get immediate medical attention.

If Swallowed:
Do not induce vomiting. If conscious, give lots of water or milk. Get immediate medical attention. Do
not give anything by mouth to an unconscious or convulsing person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the pel.

Respiratory Protection:
Wear a niosh-approved respirator appropriate for the vapour or mist concentration at the point of use.
Appropriate respirators may be a full facepiece or a half mask air-purifying cartridge respirator
equipped for acid gases/mists, a self-contained breathing apparatus in the pressure demand mode, or a
supplied-air respirator.

Eye Protection:
Chemical goggles and full faceshield unless a full face-piece respirator is also worn. It is generally
recognized that contact lenses should not be worn when working with chemicals because contact lenses
may contribute to the severity of an eye injury.

Protective Clothing:
Acid-resistant slicker suit with rubber apron, rubber boots with pants outside, and rubber gloves with
gauntlets.

Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0065
Storage And Handling Precautions:
Store in a dry, well-ventilated place away from incompatible materials. Keep container tightly closed
when not in use. Do not use pressure to empty container. Wash thoroughly after handling. Store away
from heat and out of direct sunlight maintain a constant temperature of not less than 85 deg. F given this
material solidifies at 70 deg. F. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.
Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear acid-resistant slicker suit and complete protective equipment including rubber gloves, rubber
boots, and a self-contained breathing apparatus in the pressure demand mode or a supplied-air
respirator. If the spill or leak is small, a full face-piece air-purifying cartridge respirator equipped for
acid gases may be satisfactory. In any event, always wear eye protection. Extinguish all ignition
sources. For small spills or drips, mop or wipe up and dispose of in DOT-approved waste containers.
For large spills, contain by diking with soil or other non-combustible absorbent material and carefully
neutralize with soda ash or lime. If soda ash is used, provide adequate ventilation to dissipate the
carbon dioxide gas. Keep non-neutralized material out of sewers, storm drains, surface waters, and soil.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0068

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM BROMIDE 0068

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Potassium Bromide

Chinese Name:
Synonyms: Potassium Salt Of Bromide
Chemical Family: Potassium Compound
Formula: KBr
C.A.S.: 7758-02-3

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: 2516 deg. F

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point: 1346 deg. F
Vapour Pressure, mmHg/20 deg. C: Not applicable
Vapour Density (Air=1): Not applicable
Specific Gravity (Water=1): 2.75
Water Solubility, %: 70
Appearance And Odour: White crystalline solid; odourless
Evaporation Rate (Butyl Acetate=1): Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Extinguishing Media:
This material is not combustible. Use extinguishing media appropriate for surrounding fire.

Flash Point: Not applicable

Flammable Limits In Air, % Lower: Not applicable Upper: Not applicable
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire. Contained breathing apparatus.

Unusual Fire And Explosion Hazards: None.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility: Acids, oxidizing materials.
Hazardous Decomposition Products: Will liberate toxic fumes of hydrogen bromide and/or bromine.
Conditions To Avoid: None

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin or eye contact

Signs And Symptoms Of Exposure:
Inhalation: Breathing dust may irritate the nose and throat and cause coughing and chest discomfort.
Eye Contact: Dusts may irritate the eyes and cause slight transient corneal injury.
Skin Contact:
No irritation is likely after brief contact but may be irritating or cause a burn after prolonged contact
with wet or abraded skin.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0068
Swallowed: Low single dose toxicity.
Chronic Effects Of Exposure:
Repeated excessive overexposure may cause nausea, vomiting, muscular weakness, incoordination,
depression, psychosis, endocrine effects, depression of the heart, acneform dermatitis. Bromism has
been reported in offspring of mothers who also had bromide poisoning as a result of ingestion of
bromides during pernancy.

Medical Conditions Generally Aggravated By Exposure: None reported.

Oral: No data found
Dermal: No data found
Inhalation: No data found
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

Other Data: Bromide ion has been shown to interfere with fertility in animal studies.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
If conscious, immediately induce vomiting by giving 2 glasses of water and sticking a finger down the
throat. Get immediate medical attention. Do not give anything by mouth to an unconscious or convulsing
person.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of minimizing dust emissions at the point of use.

Respiratory Protection:
If use conditions generate dusts, wear a NIOSH-approved respirator appropriate for those emission
levels. Appropriate respirators may be a full facepiece or a half mask air-purifying cartridge respirator
with particulate filters, a self-contained breathing apparatus in the pressure demand mode, or a
supplied-air respirator. Absence of adequate environmental controls at the point of use.

Eye Protection:
Safety glasses with side shields. It is generally recognized that contact lenses should not be worn when
working with chemicals because contact lenses may contribute to the severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, and gloves.

Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

Storage And Handling Precautions:

Store in a cool, dry, well-ventilated place away from incompatible materials. Keep bags or fibre drums
dry at all times. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Containers
dry at all times. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: None.

Other Precautions:
Containers, even those that have been emptied, will retain product residue. Always obey hazard
warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a full facepiece or
a half mask air-purifying cartridge respirator with particulate filters. Wear chemical goggles if a half
mask is worn. For small spills, sweep up and dispose of in DOT-approved waste containers. For large
spills, shovel into DOT-approved waste containers. Keep out of sewers, storm drains, surface waters,
and soil.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0070

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM CHROMATE 0070

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Potassium Chromate

Chinese Name:
Common Synonyms: Chromic Acid, Dipotassium Salt; Bipotassium Chromate
Chemical Family: Chromium Compounds
Formula: K2CrO4
Formula Wt.: 194.20
CAS No.: 7789-00-6
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 975 deg. C (1787 deg. F) Vapor Density (Air=1): 6.7
(@ 760 mmHg)
Specific Gravity: 2.73 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Yellow crystals. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: Moderate oxidizer. Contact with other material may cause fire.
Toxic Gases Produced: None identified

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat
Incompatibles: Strong reducing agents, combustible materials, organic materials
Decomposition Products: Chromium oxide fumes

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Excessive inhalation is irritating, may cause respiratory system damage

Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: Is harmful and may be fatal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0070
Ingestion: Is harmful and may be fatal. Gastrointestinal pain
Chronic Effects: Kidney damage, liver damage

Threshold Limit Value (TLV/TWA): 0.05 mg/m3

TLV Is For Chromium (VI) Compounds, Water Soluble, As Cr.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 0.1 mg/m3
PEL (Ceiling) Is For Chromic Acid And Chromates, As CrO3.
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: Yes IARC: Yes Z LIST: No OSHA REG: No

Carcinogenicity:
This substance is listed as a NTP human carcinogen and an IARC human carcinogen (group 1).

Reproductive Effects: None identified.

Target Organs: Blood, respiratory system, lungs, liver, kidneys, eyes, skin, gi tract
Medical Conditions Generally Aggravated By Exposure: Damaged skin
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact, absorption

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, if conscious, give large amounts of water. Induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 A respirator with dust/mist filter is recommended. If airborne concentration exceeds TLV, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements: Keep container tightly closed. Store in secure poison area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Keep combustibles (wood, paper,
oil, etc.) Away from spilled material. With clean shovel, carefully place material into clean, dry
container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0071

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM HYDROXIDE DRY 0071

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Potassium Hydroxide

Chinese Name:
Common Names/Synonyms: Caustic Potash Dry
Chemical Family: Alkali
Formula: KOH
C.A.S.: 1310-58-3

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point : 2500 deg. F

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point : 715 deg. F
Vapour Pressure, mmHg/20 deg. C: 40-50 @ 1000 deg. C.
Vapour Density (Air=1): Not applicable
Specific Gravity (Water=1): 2.044
Water Solubility, %: 52.8
Appearance And Odour: White hygroscopic flake or pellet, no odour
Evaporation Rate (Butyl Acetate=1): Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Extinguishing Media:
This material is not combustible. Contact with water may generate enough heat to ignite combustible
materials.

Flash Point : None

Flammable Limits In Air, % Lower: Not applicable Upper: Not applicable
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards:

This material melts at 715 DEG. F. Hot molten material will react violently with water resulting in
spattering and fuming. In the molten state this product will react with metals such as aluminum, tin, or
zinc to produce flammable hydrogen gas.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility:
Acids, combustible materials, and metals such as aluminum, tin, galvanized zinc, brass, and bronze.
Avoid contact with trichloroethylene to prevent spontaneous formation of flammable dichloroacetylene.

Hazardous Decomposition Products: None

Conditions To Avoid:
Keep water and moist air out of the container. Do not allow contact with acids and reactive metals.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0071
========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin or eye contact

Signs And Symptoms Of Exposure:
Inhalation:
Dusts are extremely corrosive to the entire respiratory tract. Breathing dust can destroy the mucous
membranes and can cause severe pneumonitis.

Eye Contact:
Dusts are extremely corrosive to the eyes. Brief contact causes severe eye damage and prolonged
contact causes permanent eye injury which may be followed by blindness.

Skin Contact:
Dusts are extremely corrosive to the skin and rapidly cause severe chemical burns. Moisture on the
skin, such as from perspiration, will accelerate tissue destruction.

Swallowed:
Dusts or solids are extremely corrosive to the mouth and throat. swallowing dusts or solids causes
severe and rapid burning of the mouth, throat, and digestive tract accompanied by severe pain, vomiting
and collapse. Some effects may be delayed.

Chronic Effects Of Exposure:

May result in areas of destruction of skin tissue or primary irritant dermatitis. Similarly, inhalation of
dusts, vapours, or mists may cause varying degrees of damage to the affected tissues and also
increasing susceptibility to respiratory illness.

Medical Conditions Generally Aggravated By Exposure: None known.

Oral: No data found for solid caustic potash but 45% liquid rat LD 50=205 mg/kg

Dermal:
No Data Found For Solid Caustic Potash But 45% Liquid Rabbit
LD50=1260 mg/kg

Inhalation: No data found

Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Other Data:
5 mg/24hr produced moderate irritation to rabbit skin. 1 mg/24hr produced moderate irritation to rabbit
eye.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 30 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention. Speed is essential.

In Case Of Skin Contact:

Immediately flush skin with lots of running water for 30 minutes. Remove contaminated clothing and
shoes; wash before reuse. Get immediate medical attention.

If Swallowed:
Do not induce vomiting. If conscious, give lots of water or milk. Get immediate medical attention. Do
not give anything by mouth to an unconscious or convulsing person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of minimizing dust emissions at the point of use.

Respiratory Protection:
NIOSH-approved dust respirator or mask in the absence of adequate environmental controls at the point
of use.

Eye Protection: Chemical goggles and full face shield.

Protective Clothing:
Alkali-resistant slicker suit with rubber apron, rubber boots with pants outside, and rubber gloves with
gauntlets.

Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.
Storage And Handling Precautions:
Store in a cool, dry place. Keep container tightly close when not in use. Do not use pressure to empty
container. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0071
Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full. This material generates considerable
heat when dissolved in water. When mixing with water always add caustic potash slowly to water and
stir continuously. Never add water to caustic potash.

Other Precautions:
This product is intended for use in food, animal feed, drug, or cosmetic manufacture and it has been
produced and packaged in accordance with strict quality practices. Maintain this quality level by storing
this product away from other chemicals, handling it with care, and avoiding all sources of
contamination.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and chemical goggles.
For small spills, sweep up and dispose of in DOT-approved waste containers. For large spills, shovel
into DOT-approved waste containers.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0072

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM IODATE 0072

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Potassium Iodate

Chinese Name:
Common Synonyms: Iodic Acid, Potassium Salt
Chemical Family: Potassium Compound
Formula: KIO3
C.A.S.: 7758-05-6

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point :

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point : 1040 deg. F
Vapour Pressure, mmHg/20 deg. C: Not applicable
Vapour Density (Air=1): Not applicable
Specific Gravity (Water=1): 3.9
Water Solubility, %: 89
Appearance And Odour: White crystals; odourless
Evaporation Rate (Butyl Acetate=1): Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Extinguishing Media:
This material is not combustible. Use extinguishing media appropriate for surrounding fire.

Flash Point : Not Applicable

Flammable Limits In Air, % Lower: Not applicable Upper: Not applicable
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards:

May explode when exposed to mechanical shock or friction or upon contact with combustible materials.
Upon heating oxygen may be released which, if confined, can increase the explosive limit or burning rate
of flammable vapours or combustible materials.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility:
Acids, reducing agents, combustible materials such as wood, cloth, or organic materials, metals such as
iron, aluminum, copper and their alloys, hydrogen peroxides, sulfides and any other oxidizable materials.

Hazardous Decomposition Products:

Will liberate toxic fumes of oxides of potassium and iodide and corrosive HI.

Conditions To Avoid: Excessive heat and contamination of any kind.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0072
========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin or eye contact, inhalation.

Signs And Symptoms Of Exposure:
Inhalation:
Breathing dust may irritate the nose , throat, and respiratory tract and cause coughing, chest discomfort
and shortness of breath.

Eye Contact: Dusts may irritate the eyes.

Skin Contact:
Prolonged or repeated contact with the dust may irritate the skin, especially if skin is moist.

Swallowed:
Swallowing the dusts or solids may cause gastrointestinal irritation with resulting abdominal pain,
diarrhea, nausea and vomiting. Animal experiments suggest a potential for kidney and blood cell
damage.

Chronic Effects Of Exposure:

Repeated ingestions may cause kidney dys-function or failure and blood conditions such as hemolysis.
The central nervous system may be affected.

Medical Conditions Generally Aggravated By Exposure:

Persons with impaired liver or kidney function may be more susceptible to the effects of this substance.

Oral: Mouse LDLO = 531 mg/kg

Dermal: No data found
Inhalation: No data found
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
In Case Of Eye Contact:
Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
If conscious, immediately induce vomiting by giving 2 glasses of water and sticking a finger down the
throat. Get immediate medical attention. Do not give anything by mouth to an unconscious or convulsing
person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of minimizing dust emissions at the point of use.

Respiratory Protection:
If use conditions generate dusts, wear a niosh-approved respirator appropriate for those emission levels.
Appropriate respirators may be a full facepiece or a half mask air-purifying cartridge respirator with
particulate filters, a self-contained breathing apparatus in the pressure demand mode, or a supplied-air
respirator. Absence of adequate environmental controls at the point of use.

Eye Protection:
Chemical goggles unless a full facepiece respirator is also worn. It is generally recognized that contact
lenses should not be worn when working with chemicals because contact lenses may contribute to the
severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

Storage And Handling Precautions:

Store in a cool, dry, well ventilated place. Store away from all other chemicals and potential sources of
contamination. Do not store on wooden floors. Protect from heat, shock, and physical damage. Keep
container tightly closed when not in use. Wash hands thoroughly after handling. Do not get in eyes, on
skin, or on clothing.

Repair And Maintenance Precautions: None.

Other Precautions:
Containers, even those that have been emptied, will retain product residue. Always obey hazard
warnings and handle empty containers as if they were full.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0072
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a full facepiece or
a half mask air-purifying cartridge respirator with particulate filters. Wear chemical goggles if a half
mask is worn. For small spills, sweep up and dispose of in DOT-approved waste containers. For large
spills, shovel into DOT-approved waste containers. Keep out of sewers, storm drains, surface waters,
and soil.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0073

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM IODIDE 0073

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Potassium Iodide

Chinese Name:
Common Synonyms: Iodic Acid, Potassium Salt.
Chemical Family: Potassium Compound
Formula: KI
C.A.S.: 7681-11-0

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: 2588 deg. F Vapour Pressure, mmHg/20 deg. C: 1

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point: 1333 deg. F Vapour Density (Air=1): N/D
Specific Gravity (Water=1): 3.1 Water Solubility, %: 140 g/100g
Appearance And Odour: White odourless granules or crystals.
Evaporation Rate (Butyl Acetate=1): N/D

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Extinguishing Media: Use water spray, dry chemical, CO2, or alcohol foam.
Flash Point: N/A
Flammable Limits In Air, % Lower: N/A Upper: N/A
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards: None.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility: Acids, oxidizing materials, bromine trifluoride and trichloride
Hazardous Decomposition Products: Iodine, oxides.
Conditions To Avoid: None

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Inhalation, skin or eye contact, swallowed.

Signs And Symptoms Of Exposure:
Inhalation: Breathing dust may irritate the nose and throat and cause coughing and chest discomfort.
Eye Contact: Dusts may irritate the eyes.
Skin Contact: No irritation is likely after brief contact but may be irritating after prolonged contact.
Swallowed: None currently known.
Chronic Effects Of Exposure:
May produce "iodism" which may be manifested by skin rash, running nose, headache and irritation of
mucous membrane. Weakness, anemia, loss of weight and general depression may also occur.

Medical Conditions Generally Aggravated By Exposure: None reported.

Oral: No data found.
Dermal: No data found.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0073
Inhalation: No data found.
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
If conscious, immediately induce vomiting by giving 2 glasses of water and sticking a finger down the
throat. Get immediate medical attention. Do not give anything by mouth to an unconscious or convulsing
person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining dust emissions at the point of use below the
PEL.

Respiratory Protection:
If use conditions generate dusts, wear a niosh-approved respirator appropriate for those emission levels.
Appropriate respirators may be a full facepiece or a half mask air-purifying cartridge respirator with
particulate filters, a self-contained breathing apparatus in the pressure demand mode, or a supplied-air
respirator.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Eye Protection:
Chemical goggles and full face shield. It is generally recognized that contact lenses should not be worn
when working with chemicals because contact lenses may contribute to the severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

Storage And Handling Precautions:

Store in a cool, dry, well-ventilated place away from incompatible materials. Keep bags or fibre drums
dry at all times. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: None.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a self-contained
breathing apparatus in the pressure demand mode or a supplied-air respirator. If the spill or leak is
small, a full facepiece air-purifying cartridge respirator equipped with particulate filters may be
satisfactory. In any event, always wear eye protection. For small spills, sweep up and dispose of in
DOT-approved waste containers. For large spills, shovel into DOT-approved waste containers. Keep
out of sewers, storm drains, surface waters, and soil.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0074

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM PERMANGANATE 0074

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Potassium Permanganate

Chinese Name:
Synonyms(S): Permanganic Acid, Potassium Salt.
Chemical Family: Not Applicable
Molecular Formula: KMnO 4
Product Use: Water Treatment, Metallurgy
CAS Registry Number: 7722-64-7

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Crystals

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odour And Appearance: Dark purple to bronze crystals with no odour.
Odour Threshold: Odourless.
Specific Gravity: (H2O=1) 2.70
Bulk Density: Not applicable
Vapour Pressure: Not applicable
Boiling Point: Not applicable
Vapour Density: (Air=1) Not applicable
% Volatiles By Volume: 0
Evaporation Rate: (Butyl Acetate=1) Not applicable
Solubility In Water: Moderate 1-10%
Melting Point: Decomposes @ 150 deg. C (302 deg. F)
pH: Not applicable
Coefficient Of Water/Oil Distribution: Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Conditions Of Flammability: Not applicable

Means Of Extinction: Water spray.
Flash Point And Method Of Determination: Not applicable
Upper Flammable Limit: Not applicable
Lower Flammable Limit: Not applicable
Auto Ignition Temperature: Not applicable
Special Fire Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Fire And Explosion Hazards: Strong oxidizer. contact with other material may cause fire.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Incompatibility:
Organic materials, combustible materials strong reducing agents, strong acids, peroxides, alcohols,
chemically active metals.

Hazardous Reactions/Decompositions: Not applicable

Hazardous Polymerization: Will not occur.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0074
========================================================================
HEALTH HAZARD DATA
========================================================================

Chronic And Acute Effects On Route Of Entry:

Inhalation:
Excessive inhalation of dust is irritating and may be severely damaging to respiratory passages and/or
lungs. Prolonged inhalation of manganese in the form of its inorganic compounds may cause manganism.

Eye Contact: May cause severe irritation or burns.

Skin Contact:
Prolonged contact with solutions may be irritating leaving brown stains. Concentrated solutions may
cause burns. Crystals are corrosive to skin.

Ingestion:
Ingestion may cause nausea, vomiting, gastrointestinal irritation, and burns to mouth and throat.

Exposure Limits:
TLV = 5 mg/m3(ACGIH TLV FOR MANGANESE DUST EXPRESSED AS Mn)

Irritancy: Causes irritation

Mutagenicity: Not available
Sensitization To Product: No data
Animal Toxicity Data: LD 50 (Oral-Rat) (mg/kg) - 1090
LD50 (Scu-Mouse) (mg/kg) - 500
Carcinogenicity: IARC, NTP, and OSHA Non Carcinogenic
Reproductive Toxicity: No data
Teratogenicity Data: Not available
Name Of Toxicologically Synergistic Products: No data

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Remove to fresh air. If not breathing give a.r. if breathing is difficult give oxygen.

Eye Contact: Flush eyes with plenty of water for 15 minutes.

Skin Contact: Flush skin with plenty of water for 15 minutes.
Ingestion:
Do not induce vomiting, if conscious, give large amounts of water. Follow with diluted vinegar, fruit
juice or whites of eggs, beaten with water.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
dust/mist respirator such as NIOSH/MSHA TC-21C-287 is recommended. If concentration exceeds
capacity of respirator, self-contained breathing apparatus is advised.

Eye/Face Protection: Safety glasses with sideshields are advised.

Skin Protection: Normal work clothing covering arms and legs. Butyl rubber gloves are recommended.
Respiratory Controls:
Use general or local exhaust ventilation to meet TLV requirements. Materials for protective clothing:
butyl rubber gloves.

Precautions:
Keep container tightly closed. Store separately and away from flammable and combustible materials.

Storage Requirements: Store separately and away from flammable and combustible materials.
Handling Procedures:
Keep combustibles (wood, paper, oil, etc.) away from spilled area in tightly closed container. Wash
thoroughly after handling.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Procedures To Be Followed In Case Of A Leak Or Spill:

Wear self-contained breathing apparatus and full protective clothing. Keep combustibles (wood, paper,
oil, etc.) away from spilled material. With clean shovel, carefully place material into clean, dry
container and cover; remove from area. Flush spill area with water.

Environmental Effects: Not available

Deactivating Chemicals: Not available

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0075

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM SODIUM TARTRATE, 0075

4-HYDRATE
========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Potassium Sodium Tartrate, 4-Hydrate

Chinese Name:
Common Synonyms: Rochelle Salt
Chemical Family: Potassium Compounds
Formula: KOCO(CHOH) 2COONa 4H2O
Formula Wt.: 282.22
C.A.S.: 6381-59-5
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: N/A Vapour Pressure (mmHg): N/A
Melting Point: 70 deg. C (158 deg. F) Vapour Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.79 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odour Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odour: White crystals. odourless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Flash Point (Closed Cup): N/A
Flammable Limits: Upper - N/A Lower - N/A
Autoignition Temperature: N/A
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibles: Metallic salts, mineral acids, strong oxidizing agents
Decomposition Products: Carbon monoxide, carbon dioxide
Conditions To Avoid: Heat

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0075
========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): Not established

Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components: No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No
Carcinogenicity: None identified.
Reproductive Effects: None identified.
Effects Of Overexposure:
Inhalation: None identified
Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0076

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM THIOCYANATE 0076

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Potassium Thiocyanate

Chinese Name:
Common Synonyms: Thiocyanic And Potassium Salt; Potassium Isothiocyanate
Formula: KSCN
C.A.S.: 333-20-0

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: 932 deg. F Vapour Pressure, mmHg/20 deg. C: N/A
Melting Point: 343 deg. F Vapour Density (Air=1): N/A

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Specific Gravity (Water=1): 1.89 Water Solubility, %: >10
Appearance And Odour: White odourless crystals
Evaporation Rate (Butyl Acetate=1): N/A

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Extinguishing Media:
This material is not combustible. Use extinguishing media appropriate for surrounding fire.

Flash Point: N/A

Flammable Limits In Air, % Lower: N/D Upper: N/D
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards: None.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility: Nitric acid, strong oxidizers, active halogen compounds.
Hazardous Decomposition Products: Hydrogen cyanide, oxides of salfur and nitrogen.
Conditions To Avoid: None.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: None indicated.

Signs And Symptoms Of Exposure:
Inhalation: None currently known.
Eye Contact: None currently known.
Skin Contact: Contact may cause ulcers, local discoloration, eczema.
Swallowed: None currently known.
Chronic Effects Of Exposure: No specific information available.
Medical Conditions Generally Aggravated By Exposure: None reported.
Oral: rat LD 50 = 854 mg/kg
Dermal: No data found
Inhalation: No data found

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0076
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer,or the occupational safety and health administration.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
If conscious, immediately induce vomiting by giving 2 glasses of water and sticking a finger down the
throat. Get immediate medical attention. Do not give anything by mouth to an unconscious or convulsing
person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of minimizing dust emissions at the point of use.

Respiratory Protection: None required.

Eye Protection:
Safety glasses with side shields. It is generally recognized that contact lenses should not be worn when
working with chemicals because contact lenses may contribute to the severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Storage And Handling Precautions:
Store in a dry, well-ventilated place away from incompatible materials. Keep container tightly closed
when not in use. Do not use pressure to empty container. Wash thoroughly after handling. Do not get in
eyes, on skin, or on clothing.

Repair And Maintenance Precautions: None.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a full facepiece or
a half mask air-purifying cartridge respirator with particulate filters. Wear chemical goggles if a half
mask is worn. For small spills, sweep up and dispose of in DOT-approved waste containers. For large
spills, shovel into DOT-approved waste containers. Keep out of sewers, storm drains, surface waters,
and soil.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0077

Material Safety Data Sheet

City University of Hong Kong

MSDS PROPANOL-1 0077

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: N-Propanol

Chinese Name:
Synonyms: 1-Propanol; N-Propyl Alcohol; Ethylcarbinol
Chemical Family: Alcohols
Formula: C3H7OH
Molecular Weight: 60.10
C.A.S.: 71-23-8
Use: All-purpose solvent.

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point, @ 760 mmHg 97.2 deg. C
Freezing Point -126.2 deg. C
Specific Gravity (H2O = 1) 0.8045 @ 20/20 deg. C
Vapour Pressure @ 20 deg. C 14.9 mmHg
Vapour Density (Air = 1) 2.1
Solubility In Water, % By Weight 100
% Volatiles By Volume 100
Evaporation Rate (Butyl Acetate = 1) 1.3
Appearance And Odour: Water-white liquid; mild and nonresidual odour.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Extinguishing Media:
Use alcohol-type or all-purpose-type foam by manufacturers' recommended techniques for large fires.
Use carbon dioxide or dry chemical media for small fires.

Flash Point: 24 deg. C, Tag Closed Cup, ASTM D 56.

27 deg. C, Tag Open Cup, ASTM D 1310.

Flammable Limits In Air, % By Volume Upper: 13.7% Lower: 2.1%

Special Fire Fighting Procedures:
Use water spray to cool fire-exposed containers and structures, and to disperse vapours; reignition is
possible. Use self-contained breathing apparatus and protective clothing.

Unusual Fire And Explosion Hazards:

Vapours form from this product and may travel or be moved by air currents and ignited by pilot lights,
other flames, smoking, sparks, heaters, electrical equipment, static discharges, or other ignition sources
at locations distant from product handling point. This material may produce a floating fire hazard.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility:
Avoid concentrated nitric and sulfuric acids, strong oxidizers, aldehydes, halogens, and halogen
compounds.

Hazardous Combustion Or Decomposition Products:

Burning may produce carbon monoxide and/or carbon dioxide.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0077
Conditions To Avoid: Heat, fire, and ignition sources.

========================================================================
HEALTH HAZARD DATA
========================================================================

Exposure Limits: 200 ppm TWA-Skin ACGIH (1989-90)

250 ppm STEL-Skin ACGIH (1989-90)
LC50: 48 g/m3 Inh.-Mouse RTECS (1989)
LD50: 1870 mg/kg Oral-Rat RTECS (1989)
5040 mg/kg Skin-Rabbit RTECS (1989)
Swallowing:
Moderately toxic. May cause nausea, vomiting, diarrhea, abdominal discomfort, drowsiness, and
unconsciousness.

Skin Absorption: No evidence of adverse effects from available information.

Inhalation:
Vapours are irritating to the eyes and respiratory tract. High concentrations may cause headache,
dizziness, drowsiness, narcosis, and unconsciousness.

Skin Contact:
Brief contact is not irritating. Prolonged contact, as from clothing wet with the material, may cause
drying and cracking of the skin due to a defatting action.

Eye Contact:
Causes a stinging sensation and irritation, seen as excess redness and swelling of the conjunctiva.

Effects Of Repeated Overexposure:

The injury produced upon repeated administration is generally associated with the liver.

Medical Conditions Aggravated By Overexposure:

Because of its defatting properties, this material may aggravate an existing dermatitis. Breathing of
vapours and/or mist may aggravate asthma and inflammatory or fibrotic pulmonary disease.

========================================================================
FIRST AID MEASURES
========================================================================

Swallowing: Give two glasses of water and induce vomiting. Call a physician.
Skin: Remove contaminated clothing and flush skin with water. Wash clothing before reuse.
Inhalation:
emove to fresh air. Give artificial respiration if not breathing. Oxygen may be given by qualified
personnel if breathing is difficult. Call a physician.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes. seek medical attention.
Notes To Physician:
There is no specific antidote. Treatment of overexposure should be directed at the control of symptoms
and the clinical condition of the patient.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection:
Niosh or msha approved self-contained breathing apparatus in high vapour concentrations.

Ventilation:
This product should be confined within covered equipment, in which case general (mechanical) room
ventilation should be satisfactory. Special local ventilation may be needed at points where vapours can
be expected to escape to the workplace air.

Protective Gloves: Nitrile, butyl, or PVC-coated

Eye Protection: Monogoggles

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill:
Extinguish and do not turn on any ignition source until the area is determined to be free from explosion or
fire hazards. Wear suitable protective equipment. Small spills could be flushed with large quantities of
water. Larger spills should be collected for disposal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0078

Material Safety Data Sheet

City University of Hong Kong

MSDS 2-PROPANOL 0078

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: 2-Propanol

Chinese Name:
Synonym: Isopropanol (Isopropyl Alcohol, IPA)
Formula: (CH3)2CHOH
CAS No: 67-63-0
Product Use:
In antifreeze compositions; in cosmetics; in quick-drying oils and inks; in extraction processes; as a
solvent for gums, shellac, essential oils; solvent in the electronic industry.

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Appearance And Color: Colourless liquid. slight odour, resembling a mixture of acetone and ethanol.
Odour Threshold: 28.2 ppm
Boiling Point: 82.3 deg. C
Freezing Point:
(Melting Point): -88.5 deg. C
Solubility In Water: Complete
Evaporation Rate (Ether = 1.0): 7.7
Slow <0.3 Fast >3.0
Medium 0.3-3.0
Specific Gravity (H2O=1): 0.785
pH: Neutral
% Volatiles By Volume:(@ 20 deg. C) 100
Vapour Density (Air=1): 2.1
Vapour Pressure:(mmHg @ 20 deg. C) (PSIG) 33
Molecular Weight: 60.10
Coefficient Of Water/Oil Distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Conditions Of Flammability: Flammable

Flash Point: 11.7 deg. C
% By Vol. In Air Upper Flammable Limit: 12 Lower Flammable Limit: 2
Auto Ignition Temperature: 455 deg. C
Hazardous Combustion Products: Carbon monoxide, carbon dioxide.
Explosion Hazards: A moderate explosion hazard when exposed to flames or heat.
Fire Extinguishing Procedures:
Use dry chemical, "alcohol" foam or CO2. Water may be ineffective but water spray may reduce vapours
and cool containers exposed to fire.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: High temperatures
Incompatibility :
Acetaldehyde, chlorine, ethylene oxide, combination of hydrogen-palladium particles, oleum,
hypochlorous acid, isocyanates, nitroform, perchloric acid, hydrogen peroxide-sulfuric acid,
hydrochloric, ammonium hydroxide combinations - strong oxidants in general.

Hazardous Decomposition Products:

No studies available, but carbon monoxide, carbon dioxide and possibly aldehydes would be expected.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0078

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Isopropyl alcohol is about twice as toxic as ethyl alcohol and produces similar symptoms of
intoxication. Gross overexposure can produce severe central nervous system depression, coma and
possibly fatal respiratory failure. TCLO (human): 400 ppm, symptom; irritation of mucous membranes.

Ingestion:
The probable lethal dose in an adult is about 240 ml but as little as 20 ml may produce symptoms.
Findings may include severe nausea, vomiting, abdominal pain, bleeding and central nervous system
depression. Pulmonary damage including tracheo-bronchitis, bronchopneumonia and haemorrhagic
pulmonary edema may occur as result of pulmonary excretion of the alcohol. Other problems that may
occur include a fall in hemoglobin levels due to hemolysis and a reduction in blood sugar levels.

Skin:
Isopropyl alcohol does not seem to be significantly absorbed through the skin but the limited absorption
may add to the effect of inhalation. repeated exposures to the skin may result in dermatitis resulting from
a defatting action.

Eyes:
Isopropyl alcohol vapours at 800 ppm are irritating to humans within 3-5 minutes. Contact with liquid
alcohol produces intense stinging and burning sensations. With prolonged contact to the liquid,
temporary damage to the membranous tissue covering the cornea has been reported, but healing has been
prompt.

Acute Toxicity:
Moderate Toxicity
LDLO (Oral, Man): 8600 mg/kg
LD50 (Oral, Rat): 5045 mg/kg (Depressed Activity)

Chronic Toxicity:
Overexposure (above limits) will result in toxic effects noted above. tests on rats, at relatively high
doses had moderate effects on fertility.

Exposure Limits:
TLV: 980 mg/m3
STEL: 1225 mg/m3

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Biological Exposure Indices (BEI.):
Action Level
Proposed: 100 mg/l in urine or blood, upper limit (sampled at end of workaday.)

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air; if breathing is difficult, give oxygen if qualified personnel are available. Get
medical attention.

Ingestion:
If conscious and alert, give large quantities of water and induce vomiting by touching back of throat with
finger. Never give anything by mouth to a person who is unconscious. Get medical attention.

Skin:
Wash thoroughly with water and promptly remove contaminated clothing. Wash clothing before reuse.

Eyes: Flush with water for at least 15 minutes. If irritation persists, get medical evaluation.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection:
None usually required if handling is in closed ventilation system mentioned below. Otherwise, use
niosh-approved organic vapour cartridge respirator. In the event of a spill or emergency, use
self-contained, niosh-approved breathing apparatus.

Eyes And Face:

Wear chemical goggles if there is reasonable probability of exposure to liquid or mist. Do not wear
contact lenses in this case.

Hands, Arms, And Body:

Protective gloves and protective clothing (neoprene) if there is repeated or prolonged exposure to liquid
or mist. Otherwise, full work clothing. Remove immediately any wet contaminated clothing.

Storage:
Protect from physical damage. Store in a cool, dry well-ventilated area away from ignition sources and
other fire hazards. Do not store with incompatible materials. No smoking in storage areas.

Normal Handling:
Keep away from heat, open flame or other high temperature sources. Avoid contact with skin, eyes and
clothing; avoid breathing vapour or mist. Use good personal hygiene and housekeeping practices.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0078
Engineering Controls:
Provide complete ventilated enclosure of material eg. An exhausted hood of explosion-proof
construction. Isopropanol corrodes many types of rubber. Use neoprene where required. Provide
eyewash and quick drench shower facilities.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill Or Leak (Always Wear Personal Protective Equipment):

Remove personnel from the area. Remove all sources of ignition. Remove leaky sources to the outside if
possible. Small spills: mop up, wipe up, or soak up immediately. Place soaked wiping material in a
metal container and seal. Large spills: use water spray to disperse vapours and protect any persons
attempting to stop a leak, as well as to flush spills away from fire hazard exposures. If possible, dike up.
Use water to dilute spills to non-flammable mixtures.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0079

Material Safety Data Sheet

City University of Hong Kong

MSDS RESORCINOL 0079

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Resorcinol

Chinese Name:
Synonyms: Resorcinol, 1,3-Benzenediol
Chemical Family: Aromatic
Chemical Formula: C6H4(OH) 2
C.A.S.: 108-46-3
Product Use: For test purposes

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odour And Appearance:
White needle-like crystals but becomes pink on exposure to light and air or by contact with iron.

Odour Threshold (ppm): Not available

Vapour Pressure (mmHg): 1 mmHg @ 108 deg. C
Vapour Density (Air=1): 3.74
Evaporation Rate: No Data
Boiling Point ( deg. C): 280 deg. C, but volatilizes at lower temperatures and is slightly volatile with
steam.
Melting Point ( deg. C): 110 deg. C
pH: 5.2
Specific Gravity: 1.272
Coefficient Of Water/Oil Distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flammability: Combustible
Extinguishing Media: Water, dry chemical, CO2
Flash Point (Method Used): 127 deg. C/cc
Autoignition Temperature: 1126 deg. F
Upper Flammable Limit (% By Volume): Not available
Lower Flammable Limit (% By Volume): Not available
Hazardous Combustion Products: CO, CO2

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Incompatibility :
Oxidizers, acetanilide, albumin, alkalies, antipyrine, camphor, ferric salts, methol, spirit nitrous ether,
urethan.

Hazardous Decomposition Products: CO2, CO, H2O

========================================================================
HEALTH HAZARD DATA
========================================================================

Toxicological Data:
LD50: (Oral, Rat) 301 mg/kg
LC50: Not available
Effects Of Acute Exposure To Product:
Inhaled: Harmful

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0079
In Contact With Skin:
Harmful and irritating to skin. Absorption can cause methemoglobinomia, cyanosis, convulsions and
death.

In Contact With Eyes: Causes irritation and burns.

Ingested: Harmful

Effects Of Chronic Exposure To Product:

Carcinogenicity: No
Teratogenicity: No information available
Reproductive Effects: No information available
Mutagenicity: No information available
Synergistic Products: None known

========================================================================
FIRST AID MEASURES
========================================================================

Eyes: Irrigate thoroughly with water for at least ten (10) minutes. Obtain medical attention.
Skin:
Remove contaminated clothing avoiding contamination of unaffected areas and swab contaminated skin
with glycerol, polyethylene glycol 300, or a mixture of liquid polyethylene glycol 70 parts and
methylated spirits 30 parts for at least ten (10) minutes. Flush with water for at least ten (10) minutes if
solvents are not immediately available.

Inhalation:
Remove from exposure, rest and keep warm. In severe cases, or if exposure has been great obtain
medical attention.

Ingestion:
Wash out mouth thoroughly with water and give water to drink, followed by two tablespoons of
magnesium sulphate (epsom salts) in water. Obtain medical attention.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls: Local exhaust ventilation recommended

Respiratory Protection: Self-contained breathing apparatus, dust mask.
Eye Protection: Goggles for face shield.
Skin Protection: Rubber or plastic gloves.
Other Personal Protective Equipment: An eyewash and safety shower should be nearby and ready for use.
Handling Procedures And Equipment: Follow routine safe handling procedures. Avoid generating dust.
Storage Requirements:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Store in suitable labelled containers. Keep containers tightly closed when not in use and when empty.
Protect from damage. Store in a cool, dry, well-ventilated area, out of direct sunlight.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Leak And Spill Procedure:

Mix with sand. Transfer carefully into container and arrange removal by disposal company. Wash site of
spillage thoroughly with water and detergent.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0081

Material Safety Data Sheet

City University of Hong Kong

MSDS SILVER NITRATE 0081

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Silver Nitrate

Chinese Name:
Common Names/Synonyms: Lunar Caustic; Nitric Acid; Silver (+1) Salt
Formula: AgNO3
C.A.S.: 776-18-88

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State:Solid
Boiling Point: 832 deg. F Melting Point, deg. F: 413.6
Vapour Pressure, mmHg/20 deg. C: Not applicable

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapour Density (Air=1): Not applicable
Specific Gravity (Water=1): 4.35 Water Solubility, %: High
Appearance And Odour: White to colourless crystals; odourless
Evaporation Rate (Butyl Acetate=1): Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Extinguishing Media: Use any appropriate medium for extinguishing surrounding fire.
Flash Point: Not Flammable
Flammable Limits In Air, % Lower: Not applicable Upper: Not applicable
Special Fire Fighting Procedures: None.
Unusual Fire And Explosion Hazards: None.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility:
Strong oxidizing or reducing materials, alkalis, alcohols, ammonium hydroxides, antimony salts,
arsenites, bromides, carbonates, chlorides, iodides, thiocyanates, ferrous salts, morphine salts, oils,
creosote, phosphates, tannic acid, tartrates, vegetable dedoctions and extracts, charcoal, sulfur,
phosphorus, plastics, acetylene, acetylides.

Hazardous Decomposition Products:

Thermal decomposition or burning may produce metallic silver and nitrogen oxides.

Conditions To Avoid: Excessive heat and contamination of any kind.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin or eye contact

Signs And Symptoms Of Exposure:
Inhalation:
Breathing dust causes irritation and/or burns of the nose, throat, mucous membranes and respiratory
tract. Repeated exposure may produce generalized argyria.

Eye Contact: Dusts irritate the eyes. Contact with crystals causes burns.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0081
Skin Contact:
Contact with the crystals causes irritation and/or burns. Prolonged or repeated contact with crystals or
dust may result in localized argyria.

Swallowed: Swallowing the solids can cause severe gastroenteritis that may be fatal.
Chronic Effects Of Exposure: No specific information available.

Medical Conditions Generally Aggravated By Exposure: None known.

Oral: muskrat LD50 = 29 mg/kg; rat LDLO = 800 mg/kg
Dermal: No data found
Inhalation: No data found
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed: Do not induce vomiting. Get immediate medical attention.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of minimizing dust emissions at the point of use.

Respiratory Protection:
NIOSH-approved dust respirator or mask in the absence of adequate environmental controls at the point
of use.

Eye Protection: Chemical goggles.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Protective Clothing: Long-sleeved shirt, trousers, safety shoes, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

Storage And Handling Precautions:

Store in a cool, dry place. Store away from all other chemicals and potential sources of contamination.
Keep container tightly closed when not in use. Do not use pressure to empty container. Wash thoroughly
after handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: None.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and chemical goggles.
Due to high cost of material, if it is not contaminated, it is suitable for reuse after cleanup.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0084

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM CYANIDE 0084

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Sodium Cyanide

Chinese Name:
Common Synonyms: Cyanobrik (R);
Cyanogran (R); Cyanide Of Sodium; Prussiate Of Soda
Formula: NaCN
C.A.S.: 143-33-9

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: 2,725 deg. F Melting Point, deg. F: 1,047

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapour Pressure, mmHg/20 deg. C: Nil
Vapour Density (Air=1): Not applicable
Specific Gravity (Water=1): 1.6 Water Solubility, %: 37
Appearance And Odour: White granular solid; slight ammonia and almond odour.
Evaporation Rate (Butyl Acetate=1): Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Extinguishing Media:
Flood with water. Do not use CO2 which reacts with sodium cyanide to produce highly toxic and
flammable hydrogen cyanide gas.

Flash Point: Not Flammable

Flammable Limits In Air, % Lower: Not applicable Upper: Not applicable
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire. Sodium cyanide dissolves readily in
water, therefore cyanide solution run-off may occur if containers are opened. run-off should be contained
and detoxified with hypochlorite. be extremely cautious not to inhale any fumes during a fire because
highly toxic HCN gas may be liberated.

Unusual Fire And Explosion Hazards: Hydrogen cyanide gas is flammable and highly toxic.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Moisture Causes Decomposition.

Polymerization: Will not occur
Incompatibility:
Reacts violently with strong oxidizers. Large amounts of highly toxic, flammable hydrogen cyanide
(HCN) gas will evolve from contact with acids. Water or weak alkaline solution can produce dangerous
amounts of hcn in confined areas. Carbon dioxide from the air is sufficiently acidic to liberate highly
toxic hydrogen cyanide gas from cyanide solutions.

Hazardous Decomposition Products: Poisonous HCN and ammonia gases.

Conditions To Avoid: Moisture, heat.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Inhalation, skin absorption.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0084
Signs And Symptoms Of Exposure:
Inhalation: Inhalation of dust will cause respiratory tract irritation and may be fatal.
Eye Contact: Dusts will irritate the eyes and prolonged contact may burn and/or damage the eyes.
Skin Contact:
Exposure to the dust will cause irritation. Prolonged or repeated contact may result in an itching rash
characterized by macular, popular, and vesicular eruptions. Frequently there is secondary infection.
Fatal amounts of sodium cyanide can be absorbed through the skin.

Swallowed:
Swallowing the solid can cause death. Cyanides inhibit tissue oxidation causing death through chemical
asphyxia.

Chronic Effects Of Exposure:

Exposure to small amounts of cyanide compounds over long periods of time is reported to cause loss of
appetite, headache, weakness, nausea, dizziness, and symptoms of irritation of the upper respiratory
tract and eyes.

Medical Conditions Generally Aggravated By Exposure: None reported.

Oral: Rat LD 50 = 6.44 mg/kg; Human LDLO = 2.857 mg/kg
Dermal: No data found
Inhalation: No data found
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

========================================================================
FIRST AID MEASURES
========================================================================

First Aid For Cyanide Exposure:

Actions to be taken in case of cyanide exposure should be planned and practised before beginning work
with cyanides (in most cases, cyanide poisoning causes a deceptively healthy pink to red skin color;
however, if a physical injury or lack of oxygen is involved, the skin color may be bluish.

Treatment for cyanide poisoning can be provided in two ways, "first aid" and "medical treatment". Both
require immediate action to prevent further harm or death. First aid using amyl nitrite and oxygen is
generally given by a layman before medical help arrives. Medical treatment involves intravenous
injections and must be administered by qualified medical personnel. Even if a doctor or nurse is present,
the need for fast treatment dictates using first aid treatment with amyl nitrite and oxygen while medical
treatment materials for intravenous injection are being prepared. Experience shows that first aid given
promptly is usually the only treatment needed.

Medical treatment is given if the victim does not respond to first aid. it provides a larger quantity of
antidote including sodium thiosulfate to chemically destroy cyanide in the body. However, even under

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
optimum conditions, amyl nitrite can be administered faster and should be used even if medical treatment
follows.

Amyl nitrite and medical treatment kits for cyanide poisoning are available, with doctor's prescription,
from pharmacies.

First aid -- directions for giving amyl nitrite antidote and oxygen

1. Conscious: for inhalation and/or absorption if the victim is alert, oxygen may be all that is needed. But
if he is not fully conscious or shows signs of poisoning, follow paragraph 2 below. For swal- lowing,
see first aid -- swallowing cyanide.

2. Unconscious but breathing: break an amyl nitrite ampule in a cloth and hold lightly under the victim's
nose for 15 seconds, then take away for 15 seconds. Repeat 5-6 times. If necessary, use a fresh ampule
every 3 minutes until the victim regains consciousness (usually 1-4 ampules). Give oxygen to aid
recovery.

3. Not Breathing:
A. Give artificial respiration, preferably with an oxygen resusci- tator. Give amyl nitrite antidote by
placing a broken ampule inside the resuscitator face piece, being careful that the ampule does not
enter the victim's mouth and cause choking.
B. If using manual artificial respiration, give amyl nitrite anti- dote as in paragraph 2 above, except
keep the first amyl nitrite ampule under the nose with replacement every 3 minutes.

4. Amyl Nitrite Notes:

A. Amyl nitrite is highly volatile and flammable; do not smoke or use around source of ignition.
B. If treating poison victim in a windy or drafty area, provide something -- a rag, shirt, wall, drum,
cupped hands, etc. -- to prevent the amyl nitrite vapours from being blown away. Keep the ampule
upwind from the nose. The objective is to get amyl nitrite into the victim's lungs.
C. Rescuers should avoid amyl nitrite inhalation so they won't become dizzy and lose competence.
D. Do not overuse. Amyl nitrite dilates the blood vessels and lowers blood pressure. While excessive
use might put the victim in shock, this has not occurred in practice at DUPONT manufacturing
facilities, and dupont company is not aware of any death from treatment with amyl nitrite.

If Inhaled:
Remove to fresh air. Lay victim down. Administer amyl nitrite antidote and oxygen. Remove
contaminated clothing. Keep patient quiet and warm. call a physician.

In Case Of Eye Contact:

Immediately flush eyes with plenty of water, remove contaminated clothing, and keep victim quiet and
warm. Call a physician.

In Case Of Skin Contact:

Wash skin to remove the cyanide while removing all contaminated clothing, including shoes. Do not
delay. Skin absorption can occur from cyanide dust, solutions, or hcn vapour. Absorption is slower than
inhalation, usually measured in minutes compared to seconds for inhalation. follow first aid directions

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0084
for giving amyl nitrite antidote and oxygen (above) if treatment is needed, but even severe skin contact
may not require treatment if 1) no inhalation or swallowing has occurred; and 2) the cyanide is promptly
washed from the skin and contaminated cloth- ing removed. If skin contact is prolonged, hcn poisoning
may occur with nausea, unconsciousness, and then death possible if source of cyanide intake is not
removed and treatment provided. Even after washing the skin, the victim should be watched for at least
1-2 hours because ab- sorbed cyanide can continue to work into the bloodstream. Wash clothing before
reuse and destroy contaminated shoes.

If Swallowed:
Conscious: immediately give patient one pint of 1% sodium thiosulfate solution (or plain water) by
mouth and induce vomiting with finger in throat. Repeat until vomit fluid is clear. Never give anything by
mouth to an unconscious person. Call a physician. unconscious: follow first aid procedure as in
paragraphs 2 and 3 above and call a physician. If the victim revives, then proceed with *conscious*
paragraph immediately above.

Note To Physician:
Medical treatment is normally provided by a physician, but might be provided by a professionally
trained "qualified medical person" where a need exists and where state and local laws permit. While
preparing for sodium nitrite and sodium thiosulfate injections, use amyl nitrite and oxygen as outlined in
directions for giving amyl nitrite first aid. When ready and if the victim is not responding to first aid,
first inject the solution of sodium nitrite (10 ml of a 3% solution) intravenously at the rate of 2.5
ml/minute, then immediately inject the sodium thiosulfate (50 ml of a 25% solution) at the same rate,
taking care to avoid extravasation. This is a fairly lengthy treatment (24 minutes) since a total of 10 + 50,
or 60 ml is injected at a rate of 2.5 ml/minute. consideration should be given to the size and conditions of
the victim as treatment is proceeding. It is not essential that full quantities be given just because treatment
was started. Injections can be stopped at any point if recovery is evident. Watch patient continuously for
24 - 48 hours if cyanide exposure was severe. If there is any return of symptoms during this period,
repeat this treatment using one-half the amounts of sodium nitrite and sodium thiosulfate solutions.
Caution should be used to avoid overuse of medical treatment chemicals as the prescribed dose is about
1/3 the lethal dose for an average individual. If signs of excessive methemoglobinemia develop (ie, blue
skin and mucous membranes, vomiting, shock and coma), 1% methylene blue solution should be given
intravenously. A total dose of 1 to 2 mg/kg of body weight should be administered over a period of five
to ten minutes and should be repeated in one hour if necessary. In addition, oxygen inhalation will be
helpful. Transfusion of whole fresh blood may be considered if there has been mechanical injury with
external or internal bleeding and simultaneous cyanide exposure. The experience of dupont company, a
cyanide producer, in treating cyanide poison cases is that first aid procedures using amyl nitrite and
oxygen were effective and the only treatment needed in most cases. Medical treatment, using intravenous
injections, was used in a few cases. Both procedures have been successful.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of minimizing dust emissions at the point of use.

Respiratory Protection:
If use conditions generate dusts, wear a NIOSH-approved respirator appropriate for those emission
levels. Appropriate respirators may be a full facepiece air-purifying cartridge respirator with particulate
filters, a self-contained breathing apparatus in the pressure demand mode, or a supplied-air respirator.

Eye Protection:
Chemical goggles unless a full facepiece respirator is also worn. It is generally recognized that contact
lenses should not be worn when working with chemicals because contact lenses may contribute to the
severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, rubber boots, rubber gloves, and rubber apron.
Other Protective Measures:
An eyewash and safety shower should be nearby and ready for use. First aid and medical treatment
supplies, including oxygen resuscitators, should be ready for use by trained personnel.

Storage And Handling Precautions:

Store in a cool, dry, well-ventilated place. Store away from all other chemicals and potential sources of
contamination. Do not store near combustibles or flammables. Do not handle or store food, beverages, or
tobacco in cyanide areas. Keep container tightly closed when not in use. Do not use pressure to empty
container. Wash thoroughly after handling. Do not get in eyes,on skin, or on clothing. Do not store near
acids or oxidizers.

Repair And Maintenance Precautions: None.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0084
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a self-contained
breathing apparatus in the pressure demand modeor a supplied-air respirator. If the spill or leak is small,
a full facepiece air-purifying cartridge respirator equipped with particulate filters may be satisfactory. In
any event, always wear eye protection. for small spills, sweep up and dispose of in DOT-approved
waste containers. For large spills, shovel into DOT-approved waste containers. Keep out of sewers,
storm drains, surface waters, and soil. keep spillage dry. Flush spill area with a dilute solution of
sodium or calcium hypochlorite. This material is highly toxic to marine life.

City University of Hong Kong 7

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0085

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM HYDROXIDE, PELLETS 0085

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Sodium Hydroxide

Chinese Name:
Synonym: Caustic Soda, Lye; Caustic Soda Bead, Dry Or Solid
Formula: NaOH
C.A.S.: 1310-73-2
Product Use:
In rayon and cellophane manufacture; textile industry; food industry; photoengraving and lithography;
water treatment; soap manufacture; in plastic and rubber industry; pharmaceutical and chemical industry.

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Appearance And Color: White pellets. hygroscopic.
Odour Threshold: Odourless
Boiling Point: 1390 deg. C
Freezing Point:
(Melting Point): 318 deg. C
Solubility In Water: 29.6% by wt. @ 0 deg. C.
Evaporation Rate (Ether = 1.0): Negligible at ambient conditions
Slow <0.3 Fast >3.0
Medium 0.3-3.0
Specific Gravity (H2O=1): 2.13 @ 25 deg. C Solid
pH: 5% Solution: 14
% Volatiles By Volume: (@ 20 deg. C) Negligible at ambient conditions
Vapour Density (Air=1): Vapour negligible at ambient conditions
Vapour Pressure:(mmHg @ 20 deg. C) (Psig) Negligible 1 mm @ 739 deg. C
Molecular Weight: 40.00
Coefficient Of Water/Oil Distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Conditions Of Flammability: Not flammable

Flash Point:
Hazardous Combustion Products: Some material may vaporize in a fire.
% By Vol. In Air Upper Flammable Limit: Lower Flammable Limit:
Auto Ignition Temperature:
Explosion Hazards:
Will react with metals such as aluminum, tin and zinc (and alloys of these metals) to liberate hydrogen -
a fire and explosive hazard.

Fire Extinguishing Procedures:

Do not use CO2 because it reacts exothermically with NaOH. Flood with water if involved in fire. Do
not splash or scatter material, keeping it away from common metals (see above). NaOH can melt in a fire
and molten material can react violently with small amounts of water.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility :
Common metals and their alloys; acids and their anhydrides; easily oxidizable compounds, including
explosives, aldehydes and unsaturated organics; nitrocarbons and chlorocarbons. Strong exothermic
reaction with water or moisture (generates much heat).

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0085

Hazardous Decomposition Products:

None. Remains chemically unchanged even at its boiling temperature.

Conditions To Avoid: Open containers - rapidly absorbs carbon dioxide and moisture from the air.

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Inhalation of mist or dust can injure the entire respiratory tract with painful and corrosive action on
tissue. Irritancy estimated to become noticeable at 2 mg/m3. In air. The effects of inhalation can vary,
depending upon extent of exposure, from mild mucous membrane irritation to sudden, severe
bronchopneumonia.

Ingestion:
Severe and rapid corrosive burns of mouth, gullet and gastrointestinal tract will result, if swallowed.
Effects include severe pain, difficulty in breathing, vomiting, diarrhea, collapse. Some effects may be
delayed. Estimated average fatal dose 5 g. (human, adult).

Skin:
Severe and rapid corrosion from contact. Extent of damage depends on duration of contact. Even dilute
solutions exert a destructive effect, following prolonged contact. Mist of solutions is extremely
corrosive. skin - rabbit: 50 mg/24 hours/severe effect.

Eyes:
Contact rapidly causes severe damage. Permanent corneal damage almost inevitably results. Even dilute
solutions may produce similar effects, although less rapidly. Mist of solutions is extremely corrosive.
Eye - rabbit: 50 micrograms/24 hours/severe effect.

Acute Toxicity: Very toxic.

LDLO (Oral, Rabbit): 500 mg/kg (10% Solution)
LD50 (Intraperi8toneal, Mouse): 40 mg/kg
Chronic Toxicity: Not available
Exposure Limits: TLV: 2 mg/m3 (Ceiling Value)

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air (to be handled by protected personnel). If breathing is difficult, or if cyanotic (blue
skin), give oxygen if qualified operator is available. Arrange for medical help.

Ingestion:
Do not induce vomiting. If possible, and if conscious, immediately give large quantities of water or milk.
This may be followed with dilute vinegar or fruit juice to neutralize alkali. Arrange for immediate
medical help.

Skin:
Immediately flush under safety shower. If wearing goggles, flush head and face thoroughly before
removing goggles. Next, wash victim's hands until all chemical is removed. Then remove contaminated
clothing and shoes. Call a physician. Continue washing for one or two hours and remove to a medical
facility if a physician is not available (but only after at least one hour of showering).

Eyes:
Immediately flush with large amounts of water for at least 15 minutes, holding eyelids apart to facilitate
irrigation. Utmost speed is essential. Call a physician. If none is available, irrigate another 15-30
minutes before moving patient to a medical facility. Have an opthamologist make an evaluation of eye
injury.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection:
In the absence of dust or mist, none generally required. For airborne levels of concern, use a
NIOSH-approved, full-facepiece (for eye protection) with a high-efficiency particulate or supplied-air
espirator, or a self-contained breathing apparatus.

Eyes And Face:

Wear chemical safety goggles if there is any possibility of contact with liquid or mist with the eyes. Add
a face shield if there is any possibility of contact with liquid with face. Do not wear contact lenses if
handling liquid or dusty solid material.

Hands, Arms, And Body:

Wear protective gloves and full protective clothing (preferably made of rubber, neoprene or nbr) if there
is any possibility of contact with pellets, dust or liquid or mist. Promptly wash any contaminated
impervious items and remove immediately any non-impervious items that become contaminated.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0085
Storage:
Store in closed containers in a dry, well-ventilated area, separate from acids, peroxides, metals, easily
ignitible materials and other incompatibles. Protect against moisture and water; protect against physical
damage. Drains for storage or use areas for this material should have retention basins for pH adjustment
and dilutions of spills and flushings before discharge.

Normal Handling:
Do not get in eyes, on skin or clothing. Avoid breathing dust or mist, if generated. Keep container closed
when not in use. Use with adequate ventilation and wash thoroughly after handling. When making
solutions, use sufficient agitation and cooling, while adding slowly to surface of solution, to avoid
splattering. Avoid handling conditions that may lead to spills, leaks, ejections, or to the formation of dust
or mist.

Engineering Controls:
Provide local exhaust to meet TLV requirements if making solutions or grinding up and mist or dust is
generated. In the absence of these conditions, natural ventilation may be adequate. Ventilation facilities
should be corrosion resistant. (do not use soft iron, copper, tin, aluminum, zinc or alloys of these
materials in construction or in handling equipment.) Provide eyewash stations and quick-drench showers
near areas of use and handling. In the event hydrogen gas is generated, a severe ventilation problem is
rapidly introduced. Therefore, if such emergency condition is likely to happen, then ventilation facility
must also be explosion resistant.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill Or Leak (Always Wear Personal Protective Equipment):

Dry product can be promptly shovelled up for recovery. (Caution! Avoid dusting and skin and eye
contact. Also, delay in clean-up may allow absorption of moisture from the atmosphere, increasing
clean-up difficulties.) Control the disposal of the waste solid. Flush contaminated surfaces with water
and neutralize with dilute acid (preferably acetic acid) to remove final traces. (sodium bicarbonate may
also be used to partially neutralize.) Finally, rinse area with water; attempt to keep out of sewer.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0087

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM SULFATE 0087

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Sodium Sulfate

Chinese Name:
Synonym: Disodium Sulfate; Sodium Sulfate Anhydrous
Formula: Na 2SO4
C.A.S.: 7757-82-6
Product Use:
In the manufacture of glass, ultramarine, paper pulp; for standardizing dyes and in dyeing and printing
textiles; in freezing mixtures.

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Appearance And Color: White powder or granular material.
Odour Threshold: Odourless
Boiling Point: NA
Freezing Point: NA
(Melting Point): 888 deg. C
Solubility In Water: 17% @ 20 deg. C (By Weight)
Evaporation Rate (Ether = 1.0): Not applicable
Slow <0.3 Fast >3.0
Medium 0.3-3.0
Specific Gravity (H2O=1): 2.68
pH: 5% Solution @ 25 deg. C
pH: 5.2-8.2
% Volatiles By Volume:(@ 20 deg. C) Not applicable
Vapour Density (Air=1): Not applicable
Vapour Pressure: (Mmhg @ 20 deg. C) (Psig) Not applicable
Molecular Weight: 142.04
Coefficient Of Water/Oil Distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Conditions Of Flammability: Not flammable. Flash Point: NA

Hazardous Combustion Products: Not applicable
% By Vol. In Air Upper Flammable Limit: Not applicable
Lower Flammable Limit: Not applicable
Auto Ignition Temperature: NA
Explosion Hazards: Not applicable unless sodium sulfate is melted with aluminum.
Fire Extinguishing Procedures:
Although not flammable, if involved in a fire, firefighters should wear full protective clothing and, if
acrid fumes develop, use NIOSH-approved, self-contained breathing apparatus. Cool fire-exposed
containers with water spray.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility : Molten active metals, including aluminum and magnesium.
Hazardous Decomposition Products: Not applicable.
Conditions To Avoid: Protect from moisture (hygroscopic); keep tightly closed.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0087
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Dust inhalation may irritate nose, throat and lungs.

Ingestion:
Not generally considered toxic (oral-mouse LD50: 5989 mg/kg). however, if swallowed, irritation may
develop in the mouth, esophagus and stomach. the sulfate ion draws water into the intestines and causes
purging.

Skin:
Effects of sodium sulfate are minimal, but irritation may result from prolonged skin contact.

Eyes:Contact with dust or mist may irritate eyes.

Acute Toxicity: Low toxicity - see above.
Chronic Toxicity: Not available
Exposure Limits: None established
Other: Teratogenicity data: parenteral, mouse, TDLO 60 mg/kg (8d preg.) - effects on fetus.
Biological Exposure Indices (BEI.): Not available.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air; if breathing is difficult, give oxygen if a qualified operator is available. Get
medical attention for irritation or discomfort from dust inhalation.

Ingestion:
If conscious, give 2 to 4 glasses of water, then induce vomiting by touching back of throat with finger.
Get medical attention.

Skin:
Wash with soap and water, then flush with water until all chemical is removed. Remove contaminated
clothing and wash before reuse.

Eyes:
Flush promptly with plenty of water for at least 15 minutes; get medical attention if irritation persists.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection:
Under normal conditions, none required. Where dusty conditions develop, use niosh-approved respirator
for dusts.

Eyes And Face:

Under normal conditions, wear safety glasses in the workplace. Under dusty conditions, wear chemical
safety goggles. Do not wear contact lenses.

Hands, Arms, And Body:

Wear long-sleeve shirt and trousers and gloves for routine product use or handling.

Storage: Store in a cool, dry place. Keep well closed and protect from moisture.
Normal Handling:
Avoid contact with skin, eyes or clothing. Avoid breathing dust. Wash thoroughly after handling and
follow good hygiene and housekeeping practices. Keep containers closed. Handle in a manner to
minimize dusting.

Engineering Controls:
Natural ventilation may be adequate in the absence of dusty conditions. If dusty conditions prevail,
provide local exhaust.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill Or Leak (Always Wear Personal Protective Equipment):

Shovel up dry chemical for use or disposal. Sweep up with a minimum of dusting and maximize
recovery. Flush residue with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0090

Material Safety Data Sheet

City University of Hong Kong

MSDS SULFURIC ACID 0090

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Sulfuric Acid

Chinese Name:
Common Synonyms:
Sulfuric Acid; Oil Of Vitriol; Sulfuric Acid > 93%; Sulfuric Acid > 66 Deg Be; Sulfuric Acid > 1.83
Specific Gravity; Sulfuric Acid Reagent.
Formula: H2SO4
C.A.S.: 7664-93-9

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State:Liquid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Boiling Point : A = 529 deg. F; B = 590 deg. F
Vapour Pressure, mmHg/20 deg. C: A,B = Nil
Freezing Point : A = -20 deg. F; B = 30 deg. F
Vapour Density (Air=1): Not applicable
Specific Gravity (Water=1): A = 1.835; B = 1.84
Water Solubility, %: Complete
Appearance And Odour: Colourless to pale yellow, oily liquid. Odourless.
Evaporation Rate (Butyl Acetate=1): <1

A = 93% or 66 deg be sulfuric acid; B = 99% sulfuric acid

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Flash Point : None
Flammable Limits In Air, % Lower: Not applicable Upper: Not applicable
Extinguishing Media:
This material is not combustible. Use extinguishing media appropriate for surrounding fire.

Special Fire Fighting Procedures:

Fire fighters should wear selfcontained breathing apparatus and full protective clothing. Use water spray
to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards:

Extinguish all nearby sources of ignition since flammable hydrogen gas will be liberated from contact
with some metals. Keep water out of containers.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility:
Alkalis, oxidizing or reducing materials, cyanides, sulfides, or combustible materials. Reacts with many
metals. Concentrated acid reacts violeny with water.

Hazardous Decomposition Products:

May liberate carbon monoxide, carbon dioxide, and oxides of sulfur.

Conditions To Avoid: None

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0090
========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin Or Eye Contact

Signs And Symptoms Of Exposure:
Inhalation:
Vapours and mists are extremely corrosive to the nose, throat, and mucous membranes. Bronchitis,
pulmonary edema, and chemical pneumonitis may occur. Irritation, coughing, chest pain, and difficulty
in breathing may occur with brief exposure while prolonged exposure may result in more severe
irritation and tissue damage. Breathing high concentrations may result in death.

Eye Contact:
Vapours, liquid, and mists are extremely corrosive to the eyes. Brief contact of the vapours will be
severely irritating. Brief contact of the liquid or mists will severely damage the eyes and prolonged
contact may cause permanent eye injury which may be followed by blindness.

Skin Contact:
Vapours, mists, and liquid are extremely corrosive to the skin. Vapours will severely irritate the skin
and liquid and mists will severely burn the skin. Prolonged liquid contact will burn or destroy
surrounding tissue and death may accompany burns which extend over large portions of the body.

Swallowed:
Vapours, mists, and liquid are extremely corrosive to the mouth and throat. Swallowing the liquid
burns the tissues, causes severe abdominal pain, nausea, vomiting, and collapse. Swallowing large
quantities can cause death.

Chronic Effects Of Exposure:

May cause erosion of the teeth, lesions on the skin, bronchial irritation, coughing, and pneumonia.

Medical Conditions Generally Aggravated By Exposure: Acute and chronic respiratory diseases.

Oral: Rat LD 50 = 2,140 mg/kg

Dermal: No data found
Inhalation: Guinea Pig LC 50 = 18 mg/m3
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

Other Data:
Although one limited study of refinery workers did suggest a possible link between sulfuric acid
exposure and laryngeal cancer, the study was limited because of the small number of workers and the
mixed exposures to several other materials including diethyl sulfate, an IARC and NTP carcinogen.
Based on the overall weight of evidence from all animal toxicity and human epidemiological studies, no

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 cause-and-effect relationship between cancer and sulfuric acid exposure has been shown. individuals
with preexisting disease of the lungs may have increased susceptibility to the toxicity of excessive
exposures.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 30 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately flush skin with lots of running water for 30 minutes. Remove contaminated clothing and
shoes; wash before reuse. Get immediate medical attention.

If Swallowed:
Do not induce vomiting. If conscious, give lots of water or milk. Get immediate medical attention. Do not
give anything by mouth to an unconscious or convulsing person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the pel.

Respiratory Protection:
Wear a NIOSH-approved respirator appropriate for the vapour or mist concentration at the point of use.
Appropriate respirators may be a full facepiece air-purifying cartridge respirator equipped for acid
gases/mists, a self-contained breathing apparatus in the pressure demand mode, or a supplied-air
respirator.

Eye Protection:
Chemical goggles and full faceshield unless a full face-piece respirator is also worn. It is generally
recognized that contact lenses should not be worn when working with chemicals because contact lenses
may contribute to the severity of an eye injury.

Protective Clothing:
Acid-resistant slicker suit with rubber apron, rubber boots with pants outside, and rubber gloves with
gauntlets.

Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0090
Storage And Handling Precautions:
Store in a cool, dry, well-ventilated place away from incompatible materials. Vent container carefully,
as needed, to relieve pressure. keep container tightly closed when not in use. Do not use pressure to
empty container. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear acid-resistant slicker suit and complete protective equipment including rubber gloves, rubber
boots, and a self-contained breathing apparatus in the pressure demand mode or a supplied-air
respirator. If the spill or leak is small, a full face-piece air-purifying cartridge respirator equipped for
acid gases may be satisfactory. In any event, always wear eye protection. Remove all sources of ignition.
For small spills or drips, mop or wipe up and dispose of in DOT-approved waste containers. For large
spills, contain by diking with soil or other non-combustible absorbent material and carefully neutralize
with soda ash or lime. If soda ash is used, provide adequate ventilation to dissipate The carbon dioxide
gas. Keep non-neutralized material out of sewers, storm drains, surface waters, and soil.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0095

Material Safety Data Sheet

City University of Hong Kong

MSDS STANNOUS CHLORIDE 0095

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Stannous Chloride

Chinese Name:
Common Synonyms: Tin Chloride; Stannous Chloride Dihydrate
Formula: SnCl 2 2H2O
C.A.S.: 7772-99-8

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: N/A Vapour Pressure, mmHg/20 deg. C: N/A
Melting Point: 100 deg. F Vapour Density (Air=1): N/A

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Specific Gravity (Water=1): 2.71 Water Solubility, %: 46
Appearance And Odour: White crystals; no odour
Evaporation Rate (Butyl Acetate=1): <1

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Extinguishing Media: This material is not combustible.
Flash Point: None
Flammable Limits In Air, % Lower: N/A Upper: N/A
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus. Use water spray to cool nearby containers
and structures exposed to fire.

Unusual Fire And Explosion Hazards:

Extinguish all nearby sources of ignition since flammable hydrogen gas will be liberated from contact
with some metals.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility: Oxidizers.
Hazardous Decomposition Products: May liberate irritating fumes.
Conditions To Avoid: None

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin or eye contact

Signs And Symptoms Of Exposure:
Inhalation: Breathing dust may irritate the nose and throat and cause coughing and chest discomfort.
Eye Contact: Dusts will irritate the eyes and prolonged contact may damage the eyes.
Skin Contact: Prolonged or repeated contact with the dust will irritate the skin.
Swallowed: Swallowing the dusts or solids will cause nausea and vomiting.
Chronic Effects Of Exposure: No specific information available.
Medical Conditions Generally Aggravated By Exposure: None known.
Oral: Rat LD 50 = 700 mg/kg
Dermal: No data found.
Inhalation: No data found.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0095
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
Do not induce vomiting. If conscious, give lots of water. Get immediate medical attention. Do not give
anything by mouth to an unconscious or convulsing person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining dust emissions at the point of use below the
PEL.

Respiratory Protection:
NIOSH-approved dust respirator or mask in the absence of adequate environmental controls at the point
of use.

Eye Protection: Chemical goggles.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.
Storage And Handling Precautions:
Store in a cool, dry place. Keep bags dry at all times. Wash thoroughly after handling. Do not get in eyes,
on skin, or on clothing.

Repair And Maintenance Precautions: None.

Other Precautions:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and chemical goggles.
For small spills, sweep up and dispose of in DOT-approved waste containers. For large spills, shovel
into DOT-approved waste containers. Keep this product out of sewers, storm drains, surface waters, and
soil. This product is toxic to aquatic life.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0096

Material Safety Data Sheet

City University of Hong Kong

MSDS TOLUENE 0096

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Toluene

Chinese Name:
Common Synonyms: Toluol; Methyl Benzene
Molecular Weight: 92
Formula: C6H5CH3
C.A.S.: 108-88-3

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

Boiling Point : 231 deg. F(110 deg. C) Vapour Pressure, mmHg/20 deg. C: 22

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point : -139 deg. F(-95 deg. C) Vapour Density (Air=1): 3.2
Specific Gravity (Water=1): 0.87 Water Solubility, %: 0.05
Appearance And Odour: Colourless, clear liquid; aromatic odour
Evaporation Rate (Butyl Acetate=1): 2.0
% Volatile (By Volume): 100
pH: N/D

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Extinguishing Media: Use water spray, dry chemical, foam, or CO2. Do not use a direct water stream.

Flash Point : 40 deg. F (4.44 deg. C)

Flammable Limits In Air, % Lower: 1.2 Upper: 7.6
Autoignition Temperature: N/D
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards:

Avoid accumulation of water because this product will float on water and may reignite on the surface of
the water.

Unusual Fire And Explosion Hazards:

Extinguish all nearby sources of ignition. Avoid accumulation of water because this product will float on
water and may reignite on the surface of the water. Vapours formed from this product are heavier than air
and may travel along the surface to a distant sources of ignition and flashback. Explosive vapour-air
mixtures may be formed above the flash point or between the lower and upper flammable limits. Hot
organic chemical vapours or mist are susceptible to sudden spontaneous combustion when mixed with
air. Ignition may occur at temperatures below the "autoignition" or "ignition temperature".

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility: Oxidizing materials.
Hazardous Decomposition Products:
May liberate carbon monoxide, carbon dioxide, and unidentified organic compounds in black smoke.

Conditions To Avoid: Heat, sparks, and open flames.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0096
========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Inhalation, Skin or eye contact.

Signs And Symptoms Of Exposure:
Inhalation:
Vapours and mists irritate the nose and throat. Inhalation of higher concentrations may cause headaches,
nausea, vomiting,and coma. inhalation of very high concentrations or prolonged exposure may cause
unconsciousness or death. Exposures at concentrations up to 200 ppm generally produce no symptoms.
At 200-500 ppm, headache, nausea, eye irritation, loss of appetite, a bad taste, lassitude, impairment of
coordination and reaction time are reported, but are not usually accompanied by any laboratory or
physical findings of significance. With higher concentrations, the above complaints are increased and,
in addition, anemia, leucopenia, and enlarged liver may be found in rare cases.

Eye Contact: Liquid is severely irritating.

Skin Contact:
Brief contact may dry the skin. Prolonged or repeated contact may irritate the skin, causing dermatitis.

Swallowed:
Swallowing the liquid may result in vomiting. If vomiting occurs spontaneously, do not allow vomitus
to be breathed into the lungs as even a small quantity in the lungs may result in chemical pneumonitis
and pulmonary edema/haemorrhage.

Chronic Effects Of Exposure:

Prolonged or repeated exposure to high concentrations may cause loss of appetite, nose bleeds, and
liver, kidney, and neural dysfunction.

Medical Conditions Generally Aggravated By Exposure:

Pre-existing eye, skin, and respiratory disorders.
Oral: LD 50 RAT = 5 g/kg
Dermal: LD 50 Rabbit = 14 g/kg
Inhalation: LC50 Rat = 8,000 ppm/4 hr
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

Other Data:
While there is no evidence that industrially acceptable levels of toluene vapours (the PEL or TLV) have
produced cardiac effects in humans, animal studies have shown that inhalation of high levels of toluene
produced cardiac sensitization. Such sensitization may cause fatal changes in heart rhythms. This latter
effect was shown to be enhanced by hypoxia or the injection of adrenalin-like agents. Rats exposed to
1400 ppm or 1200 ppm of toluene for 14 hr/day for 4 or 5 weeks (respectively) exhibited high frequency
hearing deficits. The significance of this information to man is unknown. Can cause irreversible changes

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 in the genetic material (DNA) of a cell. The human health consequence of these changes is not fully
understood. Intentional misuse by deliberate inhalation of toluene has been shown to cause liver, kidney
and brain damage. Causes harm to the fetus in laboratory animal studies. The relevance of these findings
to humans is uncertain.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
Do not induce vomiting. Get immediate medical attention. If vomiting occurs spontaneously, keep
victim's head below his hips to prevent his breathing the vomitus into his lungs.

Notes To Physician:
If more than 2.0 ml per kg has been ingested and vomiting has not occurred, emesis should be induced
with supervision. Keep victims head below hips to prevent aspiration. If symptoms such as loss of gag
reflex, convulsions occur before emesis, gastric lavage using a cuffed endotracheal tube should be
considered.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Explosion proof ventilation capable of maintaining emissions at the point of use below the PEL.

Respiratory Protection:
If use conditions generate vapours or mists, wear a NIOSH-approved respirator appropriate for those
emission levels. Appropriate respirators may be a full facepiece or a half mask air-purifying cartridge
respirator equipped for organic vapours/mists, a self-contained breathing apparatus in the pressure
demand mode, or a supplied-air respirator.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0096
Eye Protection:
Chemical goggles unless a full facepiece respirator is also worn. It is generally recognized that contact
lenses should not be worn when working with chemicals because contact lenses may contribute to the
severity of an' eye injury.

Protective Clothing:
Wear chemical resistant gloves and other clothing as required to minimize contact. Test data indicate the
best protection is provided by pva gloves.

Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.
Handling And Storage Precautions:
Keep away from heat, sparks, and flames. Store in a cool, dry, well-ventilated place away from
incompatible materials. Vent container frequently, and more often in warm weather, to relieve pressure.
Electrically ground all equipment when handling this product and use only non-sparking tools. Keep
container tightly closed when not in use. Do not use pressure to empty container. Wash thoroughly after
handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.
Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including chemical resistant boots, chemical resistant gloves, chemical
resistant apron, and a self-contained breathing apparatus in the pressure demand mode or a supplied-air
respirator. If the spill or leak is small, a full facepiece air-purifying cartridge respirator equipped for
organic vapours may be satisfactory. In any event, always wear eye protection. Extinguish all ignition
sources an ensure that all handling equipment is electrically grounded. For small spills or drips, mop or
wipe up and dispose of in dot-approved waste containers. For large spills, contain by diking with soil or
other non-combustible absorbent materials and then pump into DOT-approved waste containers; or
absorb with non-combustible sorbent material, place residue in DOT-approved waste containers. Keep
out of sewers, storm drains, surface waters, and soil.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0099

Material Safety Data Sheet

City University of Hong Kong

MSDS UREA 0099

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Urea

Chinese Name:
Common Synonyms: Carbamide; Carbonyl Diamide; Carbonyl Diamine; Carbamidic Acid; De-Icer 821
Formula: NH2CONH2
C.A.S.: 57-13-6

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

Boiling Point : Not applicable
Melting Point : 271-275 deg. F
Vapour Pressure, mmHg/20 deg. C: Not applicable

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapour Density (Air=1): Not applicable
Specific Gravity (Water=1): 1.335-1.34
Water Solubility, %: >10
Appearance And Odour: White solid, spherical shape (prill) or crystals, slight ammoniacal odour
Evaporation Rate (Butyl Acetate=1): Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Non-Flammable

Extinguishing Media:
This material is not combustible. Use extinguishing media appropriate for surrounding fire.

Flash Point : Not applicable

Flammable Limits In Air, % Lower: N/D Upper: N/D
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards:

Extinguish all nearby sources of ignition. Dust can be an explosion hazard, especially when heated.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will Not Occur
Incompatibility :
Acids, oxidizing materials, strong bases. Forms an explosive salt with nitric acid, reacts violently with
gallium perchlorate, incompatible with sodium nitrate, nitrosyl, perchlorate, corrosive to carbon steel,
copper and copper alloys.

Hazardous Decomposition Products:

May liberate carbon monoxide, carbon dioxide, oxides of nitrogen, ammonia, biuret and cyanuric acid.

Conditions To Avoid: Excessive heat and contamination of any kind.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin or eye contact, inhalation.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0099
Signs And Symptoms Of Exposure:
Inhalation: None currently known.
Eye Contact: Dusts may irritate the eyes.
Skin Contact: Prolonged or repeated contact with the dust may irritate the skin.
Swallowed: None currently known.
Chronic Effects Of Exposure: No specific information available.
Medical Conditions Generally Aggravated By Exposure: None reported.
Oral: Rats LD 50 = 14.3 g/kg
DERMAL: No data found
Inhalation: No data found
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
Do not induce vomiting. If conscious, give lots of water. Get immediate medical attention. Do not give
anything by mouth to an unconscious or convulsing person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining dust emissions at the point of use below the
PEL.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
If use conditions generate dusts, wear a NIOSH-approved respirator appropriate for those emission
levels. Appropriate respirators may be a full facepiece or a half mask air-purifying cartridge respirator
with particulate filters, a self-contained breathing apparatus in the pressure demand mode, or a
supplied-air respirator.

Eye Protection:
Safety glasses with side shields. It is generally recognized that contact lenses should not be worn when
working with chemicals because contact lenses may contribute to the severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.
Storage And Handling Precautions:
Store in a cool, dry, well-ventilated place away from incompatible materials. Keep bags or fibre drums
dry at all times. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Keep away
from heat and source of ignition.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.
Other Precautions:
This product is intended for use in food, animal feed, drug, or cosmetic manufacture and it has been
produced and packaged in accordance with strict quality practices. Maintain this quality level by storing
this product away from other chemicals, handling it with care, and avoiding all sources of contamination.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a self-contained
breathing apparatus in the pressure demand mode or a supplied-air respirator. If the spill or leak is
small, a full facepiece air-purifying cartridge respirator equipped with particulate filters may be
satisfactory. In any event, always wear eye protection. for small spills, sweep up and dispose of in
DOT-approved waste containers. For large spills, shovel into DOT-approved waste containers. Keep
out of sewers, storm drains, surface waters, and soil.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0100

Material Safety Data Sheet

City University of Hong Kong

MSDS XYLENE 0100

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Xylene

Chinese Name:
Common Names/Synonyms: Xylol; Dimethyl Benzene; Methyl Toluene
Formula: C6H4(CH3)2
C.A.S.: Mixture

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

Boiling Point: 281 deg. F Vapour Pressure, mmHg/20 deg. C: 6-6.7
Melting Point: <0 deg. F Vapour Density (Air=1): 3.7

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Specific Gravity (Water=1): 0.87 Water Solubility, %: Nil
Appearance And Odour: Colourless, clear liquid; sweet aromatic odour
Evaporation Rate (Butyl Acetate=1): 0.6

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Condition Of Flammability: Flammable

Flash Point: 79-81 deg. F
Flammable Limits In Air, % Lower: 1 Upper: 7
Extinguishing Media: Use water fog, dry chemical, foam, or CO2. Do not use a direct water stream.
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards:

Avoid accumulation of water because this product will float on water and may reignite on the surface of
the water.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Incompatibility : Oxidizing agents.
Hazardous Decomposition Products:
May liberate carbon monoxide, carbon dioxide, and unidentified organic compounds in black smoke.

Conditions To Avoid: Heat, sparks, and open flames.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Inhalation, skin or eye contact.

Signs And Symptoms Of Exposure:
Inhalation:
Vapours and mists irritate mucous membranes. Inhalation of action of higher concentrations may cause
headaches, nausea, vomiting, and coma. inhalation of very high concentrations or prolonged exposure
may cause unconsciousness or death.

Eye Contact: Liquid and mist may irritate the eyes.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0100
Skin Contact:
Brief contact may dry the skin. Prolonged or repeated contact may irritate the skin, causing dermatitis.

Swallowed:
Swallowing the liquid may result in vomiting. If vomiting occurs spontaneously, do not allow vomitus
to be breathed into the lungs as even a small quantity in the lungs may result in chemical pneumonitis
and pulmonary edema/haemorrhage.

Chronic Effects Of Exposure:

Prolonged or repeated exposure to high concentrations may cause neural dysfunction.

Medical Conditions Generally Aggravated By Exposure: Pre-existing eye, skin, and respiratory
disorders.
Oral: Rat LD 50 > 4.3 g/kg
Dermal: Rabbit LD 50 > 2.0 ml/kg
Inhalation: Human TCLO = 200 ppm (Irritation); Rat LC 50 = 5,000 ppm/4 h
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer,or the occupational safety and health administration.

Other Data:
Laboratory animals exposed by various routes to high doses of xylene showed evidence of effects in the
liver, kidneys, lungs, spleen, heart, and adrenals. Rats exposed to xylene vapour during pregnancy
showed embryo/fetotoxic effects. Mice exposed orally to doses producing maternal toxicity also showed
embryo/fetotoxic effects.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
Do not induce vomiting. Get immediate medical attention. If vomiting occurs spontaneously, keep
victim's head below his hips to prevent his breathing the vomitus into his lungs.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of maintaining emissions at the point of use below the
PEL.

Respiratory Protection:
Wear a niosh-approved respirator appropriate for the vapour or mist concentration at the point of use.
Appropriate respirators may be a full facepiece or a half mask air-purifying cartridge respirator
equipped for organic vapours/mists, a self-contained breathing apparatus in the pressure demand mode,
or a supplied-air respirator.

Eye Protection:
Chemical goggles unless a full facepiece respirator is also worn. It is generally recognized that contact
lenses should not be worn when working with chemicals because contact lenses may contribute to the
severity of an eye injury.

Protective Clothing:
Long-sleeved shirt, trousers, safety shoes, neoprene rubber gloves, and rubber apron.

Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.
Handling And Storage Precautions:
Keep away from heat, sparks, and flames. Store in a cool, dry, well-ventilated place away from
incompatible materials. Vent container frequently, and more often in warm weather, to relieve pressure.
electrically ground all equipment when handling this product and use only non-sparking tools. Keep
container tightly closed when not in use. Do not use pressure to empty container. Wash thoroughly after
handling. Do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.
Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapours. Always obey
hazard warnings and handle empty containers as if they were full.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0100
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a self-contained
breathing apparatus in the pressure demand mode or a supplied-air respirator. If the spill or leak is
small, a full facepiece air-purifying cartridge respirator equipped for organic vapours may be
satisfactory. In any event, always wear eye protection. extinguish all ignition sources and ensure that all
handling equipment is electrically grounded. For small spills or drips, mop or wipe up and dispose of in
DOT-approved waste containers. For large spills, contain by diking with soil or other non-combustible
absorbent materials and then pump into DOT-approved waste containers; or absorb with
non-combustible sorbent material, place residue in DOT-approved waste containers. Keep out of
sewers, storm drains, surface waters, and soil.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0102

Material Safety Data Sheet

City University of Hong Kong

MSDS ALUMINUM CHLORIDE, 6-HYDRATE 0102

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Aluminium Chloride, 6-Hydrate

Chinese Name:
Common Synonyms: Aluminium (III) Chloride, Hexahydrate; Aluminium Trichloride, Hexahydrate
Chemical Family: Aluminium Compounds
Formula: AlCl 3 6H2O
Formula Wt.: 241.43
CAS No.: 7784-13-6
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: 2.40 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White to light yellow crystals. Pungent odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None Identified.

Toxic Gases Produced: Hydrogen chloride

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture
Incompatibles: Water
Decomposition Products: Hydrogen chloride

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0102

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: May be harmful
Chronic Effects: None Identified
Threshold Limit Value (TLV/TWA): 2 mg/m3
TLV Is For Aluminium, Soluble Salts, As Al.
Short-Term Exposure Limit (STEL): Not Established
Permissible Exposure Limit (PEL): 2 mg/m3
PEL Is For Aluminium, Soluble Salts, As Al.
Toxicity Of Components: No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
self-contained breathing apparatus is advised.
Eye/Skin Protection: Safety goggles, rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Store in a dry area.

Special Precautions: Material is hygroscopic.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0103

Material Safety Data Sheet

City University of Hong Kong

MSDS ALUMINUM CHLORIDE, ANHYDROUS 0103

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Aluminum Chloride, Anhydrous

Chinese Name:
Common Synonyms: Aluminum Trichloride; Trichloraluminum
Chemical Family: Aluminum Compounds
Formula: AlCl 3
Formula Wt.: 133.34
CAS No.: 7446-70-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 180 deg. C (356 deg. F) Sublimes Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.44 Evaporation Rate: N/A
(H2O=1)

Solubility(H2O): Decomposes % Volatiles By Volume: 0

(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White to yellow-green powder. Pungent odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use dry chemical or carbon dioxide. Do not use water.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Do not get water inside containers.

Unusual Fire & Explosion Hazards:

A violent exothermic reaction occurs with water. Sufficient heat may be produced to ignite combustible
materials. Note: sublimes at melting point. toxic gases produced: hydrogen chloride

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture, Sunlight
Incompatibles: Water, most common metals, combustible materials, organic materials
Decomposition Products: Hydrogen Chloride

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Severe irritation of respiratory system

Skin Contact: Severe irritation or burns

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0103
Eye Contact: Severe irritation or burns
Skin Absorption: None identified
Ingestion: Severe burns to mouth, throat, and stomach
Chronic Effects: None Identified
Threshold Limit Value (TLV/TWA): 2 mg/m3
TLV Is For Aluminum, Soluble Salts, As Al.
Short-Term Exposure Limit (STEL): Not Established
Permissible Exposure Limit (PEL): 2 mg/m3
PEL Is For Aluminum, Soluble Salts, As Al.
Toxicity Of Components:
Oral Mouse LD50 For Aluminum Chloride 770 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, skin, mucous membranes, gi tract
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give large amounts of water.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store away from water or locations where water may be used to
extinguish fire. Do not store in direct sunlight. Isolate from incompatible materials.

Special Precautions: Material is hygroscopic.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Do not use water. With clean
shovel, place material into clean, dry container and cover. Move container(s) from spill area.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0104

Material Safety Data Sheet

City University of Hong Kong

MSDS BARIUM NITRATE 0104

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Barium Nitrate

Chinese Name:
Common Synonyms: Barium (II) Nitrate; Barium Dinitrate; Nitric Acid, Barium Salt
Chemical Family: Barium Compounds
Formula: Ba(NO3)2
Formula Wt.: 261.35
CAS No.: 10022-31-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 592 deg. C (1097 deg. F) Vapor Density (Air=1): 9.0
(@ 760 mmHg)
Specific Gravity: 3.24 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Moderate (1-10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystalline powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Strong oxidizer. Contact with combustible materials, flammable materials, or powdered metals can
cause fire or explosion.

Toxic Gases Produced: Oxides Of Nitrogen

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles: Combustible materials, strong reducing agents
Decomposition Products: Oxides of nitrogen

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0104
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of nose and throat

Skin Contact: None identified
Eye Contact: May cause irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects:
Irritation of respiratory system, central nervous system damage, damage to spleen, liver, bone marrow
Threshold Limit Value (TLV/TWA): 0.5 mg/m3
TLV Is For Barium, Soluble Compounds, As Ba.
Short-Term Exposure Limit (STEL): Not Established
Permissible Exposure Limit (PEL): 0.5 mg/m3
PEL Is For Barium, Soluble Compounds, As Ba.
Toxicity Of Components:
Oral Rat LD 50 For Barium Nitrate 355 mg/kg
Intravenous Mouse LD50 For Barium Nitrate 8.5 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
dust/mist respirator is recommended. If concentration exceeds capacity of respirator, a self-contained
breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, butyl rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Keep combustibles (wood, paper,
oil, etc.) away from spilled material. With clean shovel, carefully place material into clean, dry
container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0105

Material Safety Data Sheet

City University of Hong Kong

MSDS BENZALDEHYDE 0105

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Benzaldehyde

Chinese Name:
Common Names/Synonyms: Artificial Oil Of Almond
CAS No.: 100-52-7
Formula: C7H6O

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point : 354 deg. F

Vapor Pressure, mmHg/20 deg. C: <1
Melting Point : -15 deg. F

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapor Density (Air=1): 3.66
Specific Gravity (Water=1): 1.046
Water Solubility, %: Slight
Evaporation Rate (Butyl Acetate=1): <1 Less
Appearance And Odor: Colorless to light yellow liquid with an odor bitter almond.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point : 148 deg. F

Flammable Limits In Air, % Lower: N/D Upper: N/D
Method Used: TCC:
Extinguishing Media : Use water spray, dry chemical, CO2, or alcohol foam.
Special Fire Fighting Procedures:
Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards: Extinguish all nearby sources of ignition.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Conditions To Avoid: Heat, sparks, and open flames.
Materials To Avoid: Oxidizers, copper and brass.
Hazardous Decomposition Products:
May liberate carbon monoxide or carbon dioxide and potentially toxic and/or poisonous vapors.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin or eye contact, inhalation.

Inhalation: Vapors and mists irritate the nose and throat. Maybe narcotic.
Eye Contact: Liquid and mist may irritate the eyes.
Skin Contact: No irritation is likely after brief contact but may be irritating after prolonged contact.
Swallowed: None currently known.
Chronic Effects Of Exposure: No specific information available.
Medical Conditions Generally Aggravated By Exposure: None reported.
Oral: Rats LD 50 = 1300 mg/kg

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0105
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed: Do not Induce Vomiting. Get Immediate Medical Attention.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of minimizing emissions at the point of use.

Respiratory Protection:
Wear a NIOSH-approved respirator appropriate for the vapor or mist concentration at the point of use.
Appropriate respirators may be a full facepiece or a half mask air-purifying cartridge respirator
equipped for organic vapors/mists, a self-contained breathing apparatus in the pressure demand mode, or
a supplied-air respirator.

Eye Protection:
Chemical goggles and full faceshield unless a full facepiece respirator is also worn. It is generally
recognized that contact lenses should not be worn when working with chemicals because contact lenses
may contribute to the severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, rubber boots, rubber gloves, and rubber apron.
Other Protective Measures: An eyewash and safety shower should be nearby and read for use.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Handling And Storage Precautions:
Keep away from heat, sparks, and flames. Store in a cool, dry, well-ventilated place away from
incompatible materials. Vent container frequently, and more often in warm weather, to relieve pressure.
Electrically ground all equipment when handling this product and use only non-sparking tools. Keep
container tightly closed when not in use. Do not use pressure to empty container. Wash thoroughly after
handling. Do not get in eyes, on skin, or on clothing.

Additional Precautions:
Benzaldehyde has a low autoignition temperature and can be ignited by for example, exposed low
pressure steam pipes. It may also spontaneously ignite when soaked in rags or absorbed into acti-vated
carbon.

Bulk storage of benzaldehyde should be made under a nitrogen blanket, since benzaldehyde is easily
oxidized to benzoic acid on exposure to air. All storage tank openings should be easily accessible for
cleaning, since they will have a tendency to plug with this benxoic acid.

Store as a NFPA class IIIA liquid. Keep fire and sparks away from drums. Since empty containers retain
product residue, do not cut, drill, grind, or weld on or near the container until it is thoroughly cleaned.

Rags and activated carbon saturated with benzaldehyde may ignite spontaneously. Clean both thoroughly
to remove benzaldeyde before discarding.

Isolate, vent, drain, wash and purge systems or equipment before maintenance or repair. Remove all
ignition sources. Check atmosphere for explosiveness and oxygen deficiencies. Use adequate personal
protective equipment. Comply with regulations governing confined space entry.

Repair And Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.
Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapors. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a self-contained
breathing apparatus in the pressure demand mode or a supplied-air respirator. If the spill or leak is
small, a full facepiece air-purifying cartridge respirator equipped for organic vapors may be
satisfactory. In any event, always wear eye protection. For small spills or drips, mop or wipe up and
dispose of in dot-approved waste containers. For large spills, contain by diking with soil or other non-
combustible sorbent material and then pump into DOT-approved waste containers; or absorb with non-
combustible sorbent material, place residue in DOT-approved waste containers. Keep out of sewers,
storm drains, surface waters, and soils.Comply with all applicable governmental regulations on spill
reporting, and handling and disposal of waste.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0109

Material Safety Data Sheet

City University of Hong Kong

MSDS BENZOYL CHLORIDE 0109

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Benzoyl Chloride

Chinese Name:
Common Synonyms:
Benzoic Acid, Chloride; A-Chlorobenzaldehyde; Benzenecarbonyl Chloride
Chemical Family: Acid Chlorides
Formula: C6H5COCl
Formula Wt.: 140.57
CAS No.: 98-88-4
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Liquid

Boiling Point: 197 deg. C (386 deg. F) Vapor Pressure (mmHg): 1.0
(@ 760 mmHg) (20 deg. C)
Melting Point: -1 deg. C (30 deg. F) Vapor Density (Air=1): 4.88
(@ 760 mmHg)
Specific Gravity: 1.21 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Decomposes % Volatiles By Volume: N/A
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Clear, colorless fuming liquid. Penetrating odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 72 deg. C (162 deg. F)

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use dry chemical or carbon dioxide. Do not use water.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained Breathing apparatus with full
facepiece operated in positive pressure mode. Move exposed containers from fire area if it can be done
without risk. Use water to keep fire-exposed containers cool; do not get water inside containers.

Unusual Fire & Explosion Hazards:

Reacts violently with water producing highly toxic fumes. Contact with strong oxidizers may cause fire
or explosion. Closed containers exposed to heat may explode.

Toxic Gases Produced: Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture, heat, flame
Incompatibles: Strong oxidizing agents, water, alcohols, strong bases
Decomposition Products: Phosgene, carbon monoxide, carbon dioxide, hydrogen chloride

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0109

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Is harmful may be fatal, severe irritation or burns of respiratory system, pulmonary edema, lung
inflammation

Skin Contact: Severe irritation or burns

Eye Contact: Severe irritation or burns
Skin Absorption: None identified
Ingestion: Irritation and burns to mouth and stomach
Chronic Effects: Central nervous system depression
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No
Carcinogenicity: None identified.
Reproductive Effects: None identified.
Target Organs: Respiratory system, lungs, eyes, skin, central nervous system
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give large amounts of water.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep vapor and mist levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a chemical
cartridge respirator with acid/ organic cartridge is recommended. If concentration exceeds capacity of
cartridge respirator, a self-contained breathing apparatus is advised.

Eye/Skin Protection:
Safety goggles and face shield, uniform, protective suit, rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store away from water or locations where water may be used to
extinguish fire. Store in a cool, well-ventilated area away from sources of heat, flame, or ignition.
Isolate from incompatible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking, or flames in area. Stop leak if you can do so without risk. Neutralize spill with soda ash or
lime. With clean shovel, carefully place material into clean, dry container and cover. Remove from spill
area. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0112

Material Safety Data Sheet

City University of Hong Kong

MSDS 1-BROMOBUTANE 0112

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: 1-Bromobutane

Chinese Name:
Common Synonyms: N-Butyl Bromide
Chemical Family: Brominated Hydrocarbons
Formula: CH3CH2CH2CH2Br
Formula Wt.: 137.02
CAS No.: 109-65-9
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 102 deg. C (215 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: -112 deg. C (-169 deg. F) Vapor Density (Air=1): 4.7
(@ 760 mmHg)
Specific Gravity: 1.27 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless liquid.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 18 deg. C (65 deg. F)

Autoignition Temperature: 264 deg. C (509 deg. F)
Flammable Limits: Upper - 6.6 % Lower - 2.6 %
Fire Extinguishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. Closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire.

Toxic Gases Produced: Hydrogen bromide, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, sources of ignition
Incompatibles: Strong oxidizing agents, strong bases
Decomposition Products: Hydrogen bromide, carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0112
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Coughing, chest pains, difficult breathing, unconsciousness

Skin Contact: Burns
Eye Contact: Burns
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Intraperitoneal Rat LD 50 For 1-Bromobutane 4450 mg/kg
Intraperitoneal Mouse LD 50 For 1-Bromobutane 6680 mg/kg
Inhalation-30min Rat LC50 For 1-Bromobutane 237 g/m3
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Skin, eyes
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep vapor and mist levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a chemical
cartridge respirator with organic vapor cartridge is recommended. If concentration exceeds capacity of
cartridge respirator, a self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area.

Special Precautions: Bond and ground containers when transferring liquid.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0113

Material Safety Data Sheet

City University of Hong Kong

MSDS 2-BROMOBUTANE 0113

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: 2-Bromobutane

Chinese Name:
Common Synonyms: Sec-Butyl Bromide; Methylethylbromoomethane
Chemical Family: Brominated Hydrocarbons
Formula: CH3CHBrCH2CH3
Formula Wt.: 137.02
CAS No.: 78-76-2
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 90 deg. C (194 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: -112 deg. C (-169 deg. F) Vapor Density (Air=1): 4.7
(@ 760 mmHg)
Specific Gravity: 1.26 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Clear, colorless liquid. Pleasant odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 21 deg. C (70 deg. F)

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media:
Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)

Special Fire-Fighting Procedures:

Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. Closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire.

Toxic Gases Produced: Hydrogen Bromide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, sources of ignition
Incompatibles: Strong oxidizing agents
Decomposition Products: Hydrogen bromide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0113
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Coughing, difficult breathing, headache, nausea, dizziness, fatigue, weakness in arms and legs
Skin Contact: Burns
Eye Contact: Burns
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep vapor and mist levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a chemical
cartridge respirator with organic vapor cartridge is recommended. If concentration exceeds capacity of
cartridge respirator, a self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area.

Special Precautions: Bond and ground containers when transferring liquid.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0114

Material Safety Data Sheet

City University of Hong Kong

MSDS 2-BROMO-2-METHYLPROPANE 0114

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: 2-Bromo-2-Methylpropane

Chinese Name:
Common Synonyms: Tert-Butyl Bromide; 2-Bromoisobutane; Trimethylbromomethane
Chemical Family: Brominated Hydrocarbons
Formula: (CH3)3CBr
Formula Wt.: 137.02
CAS No.: 507-19-7
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 72 deg. C (161 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: -16 deg. C (3 deg. F) Vapor Density (Air=1): >1.0
(@ 760 mmHg)
Specific Gravity: 1.26 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless liquid.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 16 deg. C (61 deg. F)

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray, alcohol foam, dry chemical or carbon dioxide.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire.

Toxic Gases Produced: Hydrogen bromide, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, sources of ignition
Incompatibles: Strong oxidizing agents
Decomposition Products: Hydrogen bromide, carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0114
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep vapor and mist levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a chemical
cartridge respirator with organic vapor cartridge is recommended. If concentration exceeds capacity of
cartridge respirator, a self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area.

Special Precautions: Bond and ground containers when transferring liquid.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0115

Material Safety Data Sheet

City University of Hong Kong

MSDS 1-BUTANOL 0115

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: 1-Butanol

Chinese Name:
Common Synonyms: Butyl Alcohol; N-Butyl Alcohol
Chemical Family: Alcohols
Formula: CH3CH2CH2CH2OH
Formula Wt.: 74.12
CAS No.: 71-36-3
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 118 deg. C (244 deg. F) Vapor Pressure (mmHg): 4
(@ 760 mmHg) (20 deg. C)
Melting Point: -89 deg. C (-128 deg. F) Vapor Density (Air=1): 2.6
(@ 760 mmHg)
Specific Gravity: 0.81 Evaporation Rate: 0.46
(H2O=1) (Butyl Acetate = 1)
Solubility(H2O): Moderate (1-10%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless liquid. Alcohol odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 34 deg. C (95 deg. F)

Autoignition Temperature: 342 deg. C (650 deg. F)
Flammable Limits: Upper - 11.2 % Lower - 1.4 %
Fire Extinguishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be
ineffective.)

Special Fire-Fighting Procedures:

Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles: Strong oxidizing agents, alkali metals, strong acids, halogen acids, aluminum, aldehydes
Decomposition Products: Carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0115
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Irritation and drying of mucous membranes, headache, nausea, vomiting, dizziness, narcosis, respiratory
failure, low blood pressure, central nervous system depression, unconsciousness

Skin Contact: Irritation, prolonged contact may cause dermatitis

Eye Contact: Irritation, may cause temporary corneal damage
Skin Absorption: None identified
Ingestion:
Headache, nausea, vomiting, dizziness, gastrointestinal irritation, central nervous system depression,
hearing loss, unconsciousness

Chronic Effects: Kidney damage, liver damage

Threshold Limit Value (TLV/TWA): 150 mg/m3 (50 ppm)
TLV (Skin) Listed Denotes Ceiling Limit.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 150 mg/m3 (50 ppm)
PEL (Skin) Listed Denotes Ceiling Limit.
Toxicity Of Components:

Oral Rat LD 50 For 1-Butanol 790 mg/kg

Skin Rabbit LD 50 For 1-Butanol 4200 mg/kg
Intravenous Mouse LD50 For 1-Butanol 377 mg/kg
Inhalation-4hr Rat LC50 For 1-Butanol 8000 ppm
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Skin, eyes, respiratory system, kidneys, liver
Medical Conditions Generally Aggravated By Exposure:
Eye disorders, skin disorders, respiratory system disease

Primary Routes Of Entry: Ingestion, inhalation, eye contact, skin contact

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, give large amounts of water. induce vomiting.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact:
In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 1000
ppm, a chemical cartridge respirator with organic vapor cartridge is recommended. Above this level, a
self-contained breathing apparatus is recommended.

Eye/Skin Protection: Safety goggles, uniform, apron, butyl rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area.

Special Precautions:
Bond and ground containers when transferring liquid. Product may solidify at room temperature.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0116

Material Safety Data Sheet

City University of Hong Kong

MSDS 2-BUTANOL 0116

========================================================================
PRODUCT INFORMATION
========================================================================

CHEMICAL NAME : 2-Butanol

Chinese Name:
SYNONYMS : Sec-Butyl Alcohol
Chemical Family : Alcohol
Molecular Weight : 74.12
Formula : C4H10O
CAS no. : 78-92-2

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point, 760mm Hg : 99.6 deg. C

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapor Pressure At 20 deg. C : 12 mm Hg
% Volatiles By Volume : Ca 100
Freezing Point : -114.7 deg. C
Vapor Density (Air=1) : 2.55
Specific Gravity (H2O=1) : @ 20 deg. C 0.807
Evaporation Rate : (BuAc=1) Ca 1
Solubility In Water : @ 20 deg. C 12.5%
Stability : Stable
Hazardous Polymerization : Not expected to occur.
Appearance And Odor : Clear, colorless liquid with a strong, sweet odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point, (Test Method) : 23.9 deg. C (Tag closed cup)

Auto Ignition Temperature : 405 deg. C
Flammable Limits In Air % By Volume : Lower Limit 1.7 Upper Limit 9.8
Unusual Fire And Explosion Hazards : Volatile and flammable.
Extinguishing Media : Carbon dioxide, dry chemical, or alcohol foam.
Special Fire Fighting Procedures :
Wear full protective clothing and self-contained breathing apparatus. Heat will build pressure and may
rupture closed storage containers. Keep fire- exposed containers cool with water spray.

========================================================================
REACTIVITY DATA
========================================================================

Conditions To Avoid : Heat, sparks, open flame, open containers, and poor ventilation.
Materials To Avoid : Strong oxidizing agents and strong acids and bases.

Hazardous Decomposition Products :

Incomplete combustion can generate carbon monoxide and other toxic vapors.

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Exposure can cause irritation to the respiratory tract, dizziness, headache, nausea, and narcosis.

Eye Contact:
Liquid and high vapor concentration can be very irritating, and can cause conjunctivitis and corneal
burns.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0116
Skin Contact:
Prolonged or repeated skin contact can cause irritation and dermatitis through defatting of skin.

Ingestion: Can cause gastrointestinal tract discomfort.

Occupational Exposure Limits

OSHA 8-hour PEL - 150 ppm
ACGIH TLV-TWA - 100 ppm
TLV-STEL - 150 ppm
(15-min)

Concentration Immediately Dangerous to Health

OSHA/NIOSH 8-hour PEL - 10,000 ppm
NSC & OHS TLV-TWA - 20 ppm
NIOSH TLV-STEL - 43 ppm
(15-min)

Primary Routes of Entry :

2-Butanol may exert its effects through inhalation, skin absorption, and ingestion.

Industrial Exposure: Route of Exposure/Signs and Symptoms

Effects of Overexposure :
2-Butanol is an eye and mucous membrane irritant, primary skin irritant, and central nervous depressant.
Acute exposure causes irritation, narcosis, and gastrointestinal tract irritation.

Medical Condition Aggravated by Exposure :

Preclude from exposure those individuals susceptible to dermatitis.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Immediately remove to fresh air. If not breathing, administer mouth-to-mouth rescue breathing. If there is
no pulse administer cardiopulmonary resuscitation (CPR). Contact physician immediately.

Eye Contact:
Rinse with copious amounts of water for at least 15 minutes. Get emergency medical assistance.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Skin Contact:
Flush thoroughly for at least 15 minutes. Wash affected skin with soap and water. Remove contaminated
clothing and shoes. Wash clothing before re-use, and discard contaminated shoes. Get emergency
medical assistance.

Ingestion:
Call local Poison Control Center for assistance. Contact physician immediately. Never induce vomiting
or give anything by mouth to a victim unconscious or having convulsions.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Adequate ventilation is required to protect personnel from exposure to chemical vapors exceeding the
PEL and to minimize fire hazards. The choice of ventilation equipment, either local or general, will
depend on the conditions of use, quantity of material, and other operating parameters.

Respiratory:
Use approved respirator equipment. Follow NIOSH and equipment manufacturer's recommendations to
determine appropriate equipment (air-purifying, air- supplied, or self-contained breathing apparatus).

Eyes:
Safety glasses are considered minimum protection. Goggles or face shield may be necessary depending
on quantity of material and conditions of use.

Skin:
Protective gloves and clothing are recommended. The choice of material must be based on chemical
resistance and other user requirements. Generally, Buna-N or neoprene offers acceptable chemical
resistance. Individuals who are acutely and specifically sensitive to 2-butanol may require additional
protective equipment.

Storage:
2-Butanol should be protected from temperature extremes and direct sunlight. Proper storage of 2-
butanol must be determined based on other materials stored and their hazards and potential chemical
incompatibility. In general, 2-butanol should be stored in an acceptably protected and secure flammable
liquid storage room.

Other:
Emergency eye wash fountains and safety showers should be available in the vicinity of any potential
exposure. Ground and bond metal containers to minimize static sparks.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0116
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill Control:
Protect from ignition. Wear protective clothing and use approved respirator equipment. Absorb spilled
material in an absorbent recommended for solvent spills and remove to a safe location for disposal by
approved methods. If released to the environment, comply with all regulatory notification requirements.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0117

Material Safety Data Sheet

City University of Hong Kong

MSDS SUCCINIC ACID 0117

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Succinic Acid

Chinese Name:
Common Synonyms: Butanedionic Acid; Amber Acid
Chemical Family: Organic Acids
Formula: HOCOCH2CH2COOH
Formula Wt.: 118.09
CAS No.: 110-15-6
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 235 deg. C (455 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 185 deg. C (365 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.56 Evaporation Rate: N/A
(H2O=1)
SolubilitY(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: 2.7 (0.1M Solution)
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures: None identified.
Unusual Fire & Explosion Hazards:
Can be an explosion hazard, especially when heated. Contact with strong oxidizers may cause fire or
explosion.

Toxic Gases Produced: None identified

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None identified
Incompatibles: Strong oxidizing agents, strong bases
Decomposition Products: None identified

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: None identified
Eye Contact: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0117
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes.
Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a dust/mist
respirator is recommended. If concentration exceeds capacity of respirator, a self-contained breathing
apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Storage Requirements: Keep container tightly closed. Store in corrosion-proof area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0118

Material Safety Data Sheet

City University of Hong Kong

MSDS CALCIUM HYDROXIDE 0118

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Calcium Hydroxide

Chinese Name:
Common Synonyms: Calcium Hydrate; Slaked Lime
Chemical Family: Calcium Compounds
Formula: Ca(OH) 2
Formula Wt.: 74.09
CAS No.: 1305-62-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 580 deg. C (1076 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.3 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals or powder. odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.

Special Fire-Fighting Procedures:

Firefighters should wear self-contained breathing apparatus with full facepiece operated in positive
pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: None identified

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Air, dusting
Incompatibles: Strong acids, nitromethane, nitroethane, nitropropane, phosphorus, maleic anhydride
Decomposition Products: None identified

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Severe irritation or burns, prolonged contact may cause dermatitis
Eye Contact: Severe irritation or burns

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0118
Skin Absorption: None identified
Ingestion: Irritation and burns to mouth and stomach, nausea, vomiting, diarrhea
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 5 mg/m3
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 5 mg/m3
Toxicity Of Components:
Oral Rat LD 50 For Calcium Hydroxide 7340 mg/kg
Oral Mouse LD 50 For Calcium Hydroxide 7300 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, skin
Medical Conditions Generally Aggravated By Exposure: Chronic respiratory disease, skin disorders
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give large amounts of water.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
dust/mist respirator is recommended. If concentration exceeds capacity of respirator, a self-contained
breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Isolate from incompatible
materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0119

Material Safety Data Sheet

City University of Hong Kong

MSDS CHLOROBENZENE 0119

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Chlorobenzene

Chinese Name:
Common Synonyms: Monochlorobenzene; Benzene Chloride; Chlorobenzol; Phenyl Chloride
Chemical Family: Chlorinated Hydrocarbons
Formula: C6H5Cl
Formula Wt.: 112.56
CAS NO.: 108-90-7
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 132 deg. C (269 deg. F) Vapor Pressure (mmHg): 11.8
(@ 760 mmHg) (20 deg. C)
Melting Point: -45 deg. C (-49 deg. F) Vapor Density (Air=1): 3.9
(@ 760 mmHg)
Specific Gravity: 1.11 Evaporation Rate: 1.07
(H2O=1) (Butyl Acetate = 1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Clear, colorless liquid. almond odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 28 deg. C (84 deg. F)

Autoignition Temperature: 592 deg. C (1099 deg. F)
Flammable Limits: Upper - 7.1 % Lower - 1.3 %
Fire Extinguishing Media:
Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)

Special Fire-Fighting Procedures:

Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire.

Toxic Gases Produced:

Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles: Strong oxidizing agents
Decomposition Products: Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0119
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Headache, nausea, vomiting, dizziness, drowsiness, irritation of upper respiratory tract, unconsciousness

Skin Contact: Severe irritation or burns, prolonged contact may cause dermatitis
Eye Contact: Severe irritation or burns
Skin Absorption: None identified
Chronic Effects: Damage to liver, kidneys, lungs, blood, central nervous system

Ingestion: Headache, nausea, vomiting, dizziness, gastrointestinal irritation

Threshold Limit Value (TLV/TWA): 350 mg/m3 (75 ppm)
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 350 mg/m3 (75 ppm)
Toxicity Of Components:
Oral Rat LD 50 For Chlorobenzene 2910 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs:
Respiratory system, lungs, eyes, skin, central nervous system, liver, kidneys, blood

Medical Conditions Generally Aggravated By Exposure: None identified

Primary Routes Of Entry: Inhalation, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give large amounts of water.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Eye Contact:
In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 1000
ppm, a chemical cartridge respirator with organic vapor cartridge is recommended. Above this level, a
self-contained breathing apparatus is recommended.

Eye/Skin Protection:
Safety goggles and face shield, uniform,protective suit, viton gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area.

Special Precautions: Bond and ground containers when transferring liquid.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0120

Material Safety Data Sheet

City University of Hong Kong

MSDS CRUDE OIL 0120

========================================================================
PRODUCT INFORMATION
========================================================================

Trade Name: Crude Oil

Chinese Name:
Synonym(S): Crude Oil; Rock Oil; Seneca Oil; Process Stream
Chemical Family: Hydrocarbon
CAS Number: 8002-05-9
Molecular Formula: Mixture
Molecular Weight: ND

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point: -17.8 - 537.8 deg. C (0-1000 deg. F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Specific Gravity: 0.74 - 1.03
Melting Point: Na
% Volatile: Varies
Vapor Pressure: 0.6 - 10 Lbs. (Reid)
Evaporation Rate (Water=1): ND
Vapor Density (Air=1): > 1
Viscosity: Varies
% Solubility In Water: Negligible
Octanol/Water Partition Coefficient:
Pour Point: Varies
pH: ND
Appearance/Odor: Dark brown/black oil with hydrocarbon/hydrogen sulfide odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point: -42.800 - 93.300 deg. C (-45 - >200 deg. F)

Note: Dependent on crude oil type
Autoignition Temperature: Nd
Flammability Limits In Air (% By Vol.) Lower: ND
Flammability Limits In Air (% By Vol.) Upper: ND
Basic Fire Fighting Procedures:
Use dry chemical, foam or carbon dioxide to extinguish fire. Water may be ineffective but should be used
to cool fire-exposed containers, structures and to protect personnel. If leak or spill has not ignited,
ventilate area and use water spray to disperse gas or vapor and to protect personnel attempting to stop
leak. Use water to flush spills away from sources of ignition. Do not flush down public sewers or other
drainage systems.

Unusual Fire And Explosion Hazards:

Dangerous when exposed to heat or flame. Vapors form flammable or explosive mixtures with air at
room temperature. Vapor or gas may spread to distant ignition sources and flash back. Vapors may
concentrate in confined areas. Containers may explode in heat of fire. Runoff to sewer may cause fire or
explosion hazard. Irritating or toxic substances may be emitted upon thermal decomposition. Exposed
firefighters must wear MSHA/NIOSH approved self-contained breathing apparatus with full face mask
and full protective equipment.

========================================================================
REACTIVITY DATA
========================================================================

Stability/Incompatibility:
Stable under conditions of normal use. Avoid contact with strong oxidizers.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0120
Hazardous Reactions/Decomposition Products:
Irritating and toxic fumes may be emitted upon decomposition. Combustion may produce CO, CO2 and
reactive hydrocarbons. May also produce SOx and hydrogen sulfide. Hydrogen sulfide is corrosive to
many materials when moist.

========================================================================
HEALTH HAZARD DATA
========================================================================

Ingestion:
Aspiration into lungs may cause pneumonitis. May cause gastrointestinal disturbances. Symptoms may
include irritation, nausea, vomiting and diarrhea.

Skin:
Repeated or prolonged contact may result in defatting, oil acne, redness, itching, inflammation, cracking
and possible secondary infection. Absorption from prolonged or massive skin contact may cause
poisoning. May cause allergic reactions in some individuals.

Eye: Direct contact may cause irritation. Exposure to vapors, fumes or mists may cause irritation.
Inhalation:
May cause respiratory tract irritation. Exposure to high concentrations of dense oil mists may lead to oil
pneumonia. May release toxic hydrogen sulfide vapors and cause harmful central nervous system effects.
Effects may include excitation, euphoria, headache, dizziness, drowsiness, blurred vision, fatigue,
tremors, convulsions, loss of consciousness, coma, respiratory arrest and death.

Special Toxic Effects:

Crude oils contain some polynuclear aromatic hydrocarbons which have been shown to be carcinogenic
after prolonged or repeated skin contact in laboratory animals. Some crude oils have been shown to
cause skin cancer in laboratory animals and crude oil fractions have been positive in mutagenic test
systems. Toxic hydrogen sulfide vapors may be released from crude oils. In addition, the presence of
various heavy metals in crude oils may pose a bioaccumulation potential which could lead to systemic
toxicity by repeated or prolonged inhalation, ingestion or skin absorption.

This product contains Benzene. Acute benzene poisoning causes central nervous system depression.
Chronic exposure affects the haematopoietic system causing blood disorders including anemia and
pancytopenia. Mutagenic and clastogenic in mammalian and non-mammalian test systems. Reproductive
toxicant only at doses that are maternally toxic, based on tests with animals. Benzene is carcinogenic to
laboratory animals when given by intubation or by inhalation. There is an association between
occupational exposure to benzene and human leukemia.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Do not induce vomiting because of danger of aspirating liquid into lungs. if spontaneous vomiting occurs,
monitor for breathing difficulty. Get immediate medical attention.

Skin Contact:
Remove contaminated clothing immediately. Wash area of contact thoroughly with soap and water. Do
not use petroleum-based solvents to remove oil from skin. Get medical attention if irritation persists.
Launder clothing before reuse. Discard contaminated leather goods.

Eye Contact:
Flush immediately with large amounts of water for at least 15 minutes. Eyelids should be held away from
the eyeball to ensure thorough rinsing. Get medical attention if irritation persists.

Inhalation:
Remove affected person from source of exposure. If not breathing, ensure clear airway and institute
cardiopulmonary resuscitation (CPR). If breathing is difficult, administer oxygen if available. Get
immediate medical attention.

Notes To Physician :
Aspiration of petroleum hydrocarbons may cause severe pneumonitis (oil pneumonia). Vomiting should
not be induced. In unconscious victims, use of an endotracheal tube should be considered if gastric
lavage is undertaken.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Eye Protection:
Wear safety glasses or chemical goggles to prevent eye contact with dust. Have eye washing facilities
readily available where eye contact can occur. Do not wear contact lenses when working with this
substance.

Skin Protection:
Wear impervious gloves and protective clothing to prevent skin contact. Use good personal hygiene.
Wear regularly cleaned work clothing. Showering and changing into street clothing after work is
desirable.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0120
Respiratory Protection:
Ventilation may be used to reduce airborne concentrations. If ventilation cannot reduce airborne
concentrations below acceptable limits, appropriate respiratory protection should be used. Use NIOSH
or MSHA approved respiratory protective equipment when airborne exposure limits are exceeded.
NIOSH/MSHA approved respiratory protective equipment must be available for non-routine and
emergency use.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill Or Release To The Environment:

Take immediate steps to stop and contain the spill. Caution should be exercised regarding personnel
safety and exposure to the spilled material.

Emergency Action:
Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low
areas. (Also see Personal Protection Information section.) Isolate for 1/2 mile in all directions if tank,
rail car or tank truck is involved in fire.

Spill or Leak Procedure:

Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without
risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces.

Small Spills:
Take up with sand or other noncombustible absorbent material and place into containers for later
disposal.

Large Spills: Dike far ahead of liquid spill for later disposal.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0121

Material Safety Data Sheet

City University of Hong Kong

MSDS CYCLOHEXANE 0121

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Cyclohexane

Chinese Name:
Common Synonyms: Hexahydrobenzene; Hexamethylene; Hexanaphthene
Chemical Family: Aliphatic Hydrocarbons
Formula: C6H12
Formula Wt.: 84.16
CAS No.: 110-82-7
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 81 deg. C (177 deg. F) Vapor Pressure (mmHg): 95
(@ 760 mmHg) (20 deg. C)
Melting Point: 7 deg. C (44 deg. F) Vapor Density (Air=1): 2.9
(@ 760 mmHg)
Specific Gravity: 0.78 Evaporation Rate: >1
(H2O=1) (Butyl Acetate = 1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Clear, colorless liquid. Faint odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): -19 deg. C (-4 deg. F)

Autoignition Temperature: 244 deg. C (473 deg. F)
Flammable Limits: Upper - 8.4 % Lower - 1.3 %
Fire Extinguishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles: Strong oxidizing agents
Decomposition Products: Carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0121
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Headache, nausea, vomiting, dizziness, narcosis, respiratory failure, low blood pressure, central nervous
system depression, severe irritation of respiratory system

Skin Contact: Irritation, prolonged contact may cause dermatitis

Eye Contact: Irritation
Skin Absorption: None identified
Ingestion:
Headache, nausea, vomiting, dizziness, gastrointestinal irritation, central nervous system depression,
hearing loss, and may be fatal

Chronic Effects: None identified

Threshold Limit Value (TLV/TWA): 1050 mg/m3 (300 ppm)
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 1050 mg/m3 (300 ppm)
Toxicity Of Components:
Oral Rat LD 50 For Cyclohexane 29.8 g/kg
Intraperitoneal Mouse LD 50 For Cyclohexane 1297 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, respiratory system, skin, central nervous system
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. if swallowed, do not induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 1000
ppm, a chemical cartridge respirator with organic vapor cartridge is recommended. Above this level, a
self-contained breathing apparatus is recommended.

Eye/Skin Protection: Safety goggles, uniform, apron, neoprene gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area.

Special Precautions: Bond and ground containers when transferring liquid.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0122

Material Safety Data Sheet

City University of Hong Kong

MSDS CYCLOHEXENE 0122

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Cyclohexene

Chinese Name:
Common Synonyms: Benzene Tetrahydride; 1,2,3,4-Tetrahydrobenzene
Chemical Family: Aliphatic Hydrocarbons
Formula: CH:CH(CH2)3CH2
Formula Wt.: 82.15
CAS No.: 110-83-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 83 deg. C (181 deg. F) Vapor Pressure (mmHg): 67
(@ 760 mmHg) (20 deg. C)
Melting Point: -104 deg. C (-155 deg. F) Vapor Density (Air=1): 2.8
(@ 760 mmHg)
Specific Gravity: 0.81 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless liquid. Sweet odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): -12 deg. C (10 deg. F)

Autoignition Temperature: 243 deg. C (471 deg. F)
Flammable Limits: Upper - 5.0 % Lower - 1.0 %
Fire Extinguishing Media:
Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)

Special Fire-Fighting Procedures:

Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. Closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire.

Toxic Gases Produced: None identified

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles: Strong oxidizing agents
Decomposition Products: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0122
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Nausea, vomiting, headache, unconsciousness, may cause narcosis

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 1015 mg/m3 (300 ppm)
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 1015 mg/m3 (300 ppm)
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Skin, Eyes, Respiratory System
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 1000
ppm, a chemical cartridge respirator with organic vapor cartridge is recommended. Above this level, a
self-contained breathing apparatus is recommended.

Eye/Skin Protection:
Safety goggles and face shield, uniform, protective suit, rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area.

Special Precautions: Bond and ground containers when transferring liquid.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0123

Material Safety Data Sheet

City University of Hong Kong

MSDS DIETHYLAMINE 0123

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Diethylamine

Chinese Name:
Common Synonyms: N/A
Chemical Family: Amines
Formula: (C2H5)2NH
Formula Wt.: 73.14
CAS No.: 109-89-7
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 56 deg. C (132 deg. F) Vapor Pressure (mmHg): 194
(@ 760 mmHg) (20 deg. C)
Melting Point: -50 deg. C (-58 deg. F) Vapor Density (Air=1): 2.5
(@ 760 mmHg)
Specific Gravity: 0.71 Evaporation Rate: 16.9
(H2O=1) (Butyl Acetate = 1)
Solubility(H2O): Complete (100%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless liquid. Ammonia odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): -28 deg. C (-20 deg. F)

Autoignition Temperature: 311 deg. C (594 deg. F)
Flammable Limits: Upper - 10.1 % Lower - 1.8 %
Fire Extinguishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire.

Toxic Gases Produced: Oxides of nitrogen, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles: Strong acids, strong oxidizing agents, most common metals
Decomposition Products: Oxides of nitrogen, carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0123
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Severe irritation of respiratory system, may cause pulmonary edema

Skin Contact: Severe irritation or burns
Eye Contact: Severe irritation or burns, prolonged contact may cause skin sensitization
Skin Absorption: Rapid absorption
Ingestion: Nausea, vomiting, gastrointestinal irritation, burns to mouth and throat

Chronic Effects: None Identified

Threshold Limit Value (TLV/TWA): 30 mg/m3 (10 ppm)
Short-Term Exposure Limit (STEL): 75 mg/m3 (25 ppm)
Permissible Exposure Limit (PEL): 30 mg/m3 (10 ppm)
Toxicity Of Components:
Oral Rat LD 50 For Diethylamine 540 mg/kg
Inhalation-4hr Rat LC50 For Diethylamine 4000 ppm
Skin Rabbit LD 50 For Diethylamine 820 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Respiratory System, Skin, Eyes
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, absorption, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give water, milk, or milk of
magnesia.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 1500
ppm, a chemical cartridge respirator with ammonia/amine cartridge is recommended. Above this level, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, neoprene gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area.

Special Precautions: Bond and ground containers when transferring liquid.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0124

Material Safety Data Sheet

City University of Hong Kong

MSDS 2,4-DINITROPHENYLHYDRAZINE 0124

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: 2,4-Dinitrophenylhydrazine

Chinese Name:
Common Synonyms: N/A
Chemical Family: Hydrazines
Formula: (NO2)2C6H3NHNH2
Formula Wt.: 198.14
CAS No.: 119-26-6
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 194 deg. C (381 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: N/A Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Slight (0.1-1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Red crystalline powder.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 209 deg. C (410 deg. F)

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool. Flush area with water until cool so reignition will
not occur.

Unusual Fire & Explosion Hazards:

Can react violently with shock, friction or heat. Dry material is an explosive.

Toxic Gases Produced: Oxides of nitrogen, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Unstable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition, shock, dryness
Incompatibles: Strong oxidizing agents
Decomposition Products: Oxides of nitrogen, carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0124
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: Prolonged contact may cause skin sensitization
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: May be harmful
Chronic Effects: Blood Damage
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For 2,4-Dinitrophenylhydrazine 654 mg/kg
Intraperitoneal Mouse LD 50 For Water 190 g/kg
Intravenous Mouse LD50 For Water 25 g/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, blood
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Skin contact, eye contact, ingestion

=======================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store in cool, dry, well-ventilated area away from heat, sparks, or flame.

Special Precautions:
This product contains at least 10% water - if the water content decreases below this level, it becomes an
explosive. Avoid conditions that could lead to loss of water. Dinitrophenylhydrazine may be shipped dry
as drugs, n.o.s. or medicine, n.o.s. without any other requirements by rail or highway if the amount in one
outside package does not exceed 4 ounces, and material is packaged in securely closed bottles that are
cushioned to prevent breakage. This baker material is wetted and should not be allowed to dry.
Dinitrophenylhydrazine is explosive when dry.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Shut off ignition sources; no flares, smoking, or flames in area.
Moisten material with water and place it into loosely-covered plastic or fiberboard containers for later
disposal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0125

Material Safety Data Sheet

City University of Hong Kong

MSDS ETHYL BENZOATE 0125

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Ethyl Benzoate

Chinese Name:
Common Synonyms: Benzoic Ether; Benzoic Acid, Ethyl Ester
Chemical Family: Esters
Formula: C6H5COOC2H5
Formula Wt.: 150.18
CAS No.: 93-89-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 213 deg. C (415 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: -34 deg. C (-29 deg. F) Vapor Density (Air=1): 5.17
(@ 760 mmHg)
Specific Gravity: 1.05 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless liquid. Aromatic odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 87 deg. C (190 deg. F)

Autoignition Temperature: 510 deg. C (952 deg. F)
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles: Strong oxidizing agents
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of nose and throat

Skin Contact: Irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0125
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Ethyl Benzoate 2100 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None Indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep vapor and mist levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, uniform, apron, proper gloves are recommended.
Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Take up with sand or other non-combustible absorbent material and
place into container for later disposal. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0126

Material Safety Data Sheet

City University of Hong Kong

MSDS ETHYLAMINE, 70% 0126

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Ethylamine, 70%

Chinese Name:
Synonyms: Monoethylamine 70%; ETN-70%; Aminoethane.
Chemical Family: Alkylamines
Formula: C2H5NH2
Molecular Weight: 45.09
CAS Number: 75-04-7
Use:
Used as a solvent in petroleum and vegetable oil refining, as raw material for ethylated amides in
plasticizers, and used in polyester fiber manufacturing.

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point @ 760 mm Hg : 39.1 - 42.0 deg. C

Freezing Point : -83 deg. C
Specific Gravity (H2O = 1) : 0.797 @ 20/20 deg. C
Vapour Pressure At 20 deg. C : 360 mm Hg
Vapour Density (Air = 1) : 1.55 (Ethylamine)
Solubility In Water, % By Weight : 100 @ 20 deg. C
% Volatiles By Volume : 100
Evaporation Rate (Butyl Acetate = 1) : ~20
Appearance And Odour : Water-white liquid; characteristic odour.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point : -25 deg. C, SETA closed cup

Flammable Limits In Air, % By Volume : Upper: 14% Lower: 3.5%
Extinguishing Media :
Use alcohol-type or all-purpose-type foam by manufacturers' recommended techniques for large fires.
Use carbon dioxide or dry chemical media for small fires.

Special Fire Fighting Procedures

Use remote spray monitors or fight fires from behind shields. Use water spray to cool fire-exposed
containers and structures, and to disperse vapours; reignition is possible. Use self-contained breathing
apparatus and protective clothing.

Unusual Fire And Explosion Hazards

Vapours formed from the product may travel or be moved by air currents and be ignited by pilot lights,
other flames, smoking, sparks, heaters, electrical equipment, static discharges, or other ignition sources
at locations distant from product handling point. Vapours may settle in low or confined areas, or travel a
long distance to an ignition source and flash back explosively. This material may produce a floating fire
hazard in extreme fire conditions. During a fire, oxides of nitrogen may be produced.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Conditions To Avoid: None currently known
Incompatibility :
Mineral acids, strong oxidizing agents, and chlorine or hypochlorites. Avoid reaction with chlorine or
alkaline hypochlorite; not only is the reaction highly exothermic, but the products (chloramines) may be
explosive.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0126
Hazardous Combustion Or Decomposition Products:
Burning may produce carbon monoxide and/or carbon dioxide, and oxides of nitrogen. Carbon monoxide
is highly toxic if inhaled; carbon dioxide in sufficient concentrations can act as an asphyxiant. Acute
overexposure to oxides of nitrogen may result in irritation of the respiratory tract.

Hazardous Polymerization: Will not occur

========================================================================
HEALTH HAZARD DATA
========================================================================

Exposure limits: 10 ppm TWA ACGIH (1991-92)

LC50: 2300 mg/M3 Inh. Mammal RTECS (1992)
LD50: 400 mg/kg Oral-Rat RTECS (1992)
390 mg/kg Skin-Rabbit RTECS (1992)
540 mg/kg Oral-Rat Union Carbide

Swallowing :
Moderately toxic. May cause burns of the mouth, throat, oesophagus, and stomach with severe abdominal
and chest pain, nausea, vomiting, diarrhea, dizziness, faintness, drowsiness, thirst, collapse, and coma.
Aspiration into the lungs may occur during ingestion or vomiting, resulting in lung injury.

Skin Absorption :
Toxic. Prolonged or widespread contact may result in the absorption of potentially harmful amounts of
material.

Inhalation :
Vapours are irritating and cause coughing, discomfort and discharge in the nose, discomfort in the throat
and chest, tracheitis, bronchitis, pneumonitis, and pulmonary oedema.

Skin Contact :
Vapours may cause irritation, seen as local redness and possible swelling. Liquid causes local
discomfort or pain, severe excess redness and swelling with chemical burns.

Eye Contact :
Causes pain and severe excess reddening and swelling of the conjunctiva, with chemical burns of the
cornea. Corneal injury may be severe, extensive, and if not treated promptly, could result in permanent
impairment of vision. Vapour may cause temporary disturbance of vision

Effects Of Repeated Overexposure : None currently known

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Medical Conditions Aggravated By Overexposure :
Breathing of vapour and/or mist may aggravate asthma and inflammatory or fibrotic pulmonary disease.
Because of its irritating properties, this material may aggravate an existing dermatitis.

========================================================================
FIRST AID MEASURES
========================================================================

Swallowing :
If patient is fully conscious, give 2 glasses of water or milk at once. Do not induce vomiting. Call a
physician without delay.

Skin :
Immediately flush skin with plenty of water while removing contaminated clothing and shoes. Call a
physician without delay. Wash clothing before wearing again. Discard shoes.

Inhalation :
Remove to fresh air. Give artificial respiration if not breathing. Oxygen may be given by qualified
personnel if breathing is difficult. Call a physician.

Eyes :
Immediately flush eyes thoroughly with water for at least 15 minutes. Seek medical attention urgently,
preferably from an ophthalmologist.

Notes To Physician :
There is no specific antidote. Treatment of overexposure should be directed at the control of symptoms
and the clinical condition of the patient. Due to the severely irritant nature of the material, any aspiration
during vomiting could result in severe lung injury. Therefore, emesis should not be induced mechanically
or pharmacologically. However, the acute peroral systemic toxicity of the material indicates that
evacuation of the stomach contents should be undertaken at the earliest possible time by means carrying
the least likelihood for aspiration (e.g., the use of gastric lavage with endotracheal intubation). Delayed
onset pulmonary oedema may occur after exposure to moderately high vapour concentrations. Patient
should be kept under observation for at least 72 hours after exposure by inhalation. Exposure to the
vapour may cause minor transient oedema of the corneal epithelium. This condition, referred to as
glaucopsia, "blue haze", or "blue-gray haze" produces a blurring of vision against a general bluish haze
and the appearance of halos around bright objects. The effect disappears spontaneously within a few
hours of the end of an exposure, and leaves no sequelae. Although not detrimental to the eye per se,
glaucopsia predisposes an affected individual to physical accidents and reduces the ability to undertake
skilled tasks such as driving a motorized vehicle.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0126
========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection :
NIOSH or MSHA approved self-contained breathing apparatus in high vapour concentrations.

Ventilation :
This product should be confined within vapour-tight equipment, in which case general (mechanical)
room ventilation is satisfactory. Special local ventilation is needed at points where vapours can be
expected to escape to the workplace air.

Protective Gloves : Butyl

Eye Protection : Monogoggle
Other Protective Equipment : Eye bath, safety shower, and chemical apron.
Storage:
Drums should be stored in a shaded area; white drums are used to minimize heat absorption. If a drum is
warm, it should be cooled before opening to reduce internal pressure and minimize venting of vapours
when the bung is unscrewed. Good ventilation should be provided in the area where drums will be
opened and protective equipment should be worn.

Process Hazard:
Sudden release of hot organic chemical vapours or mists from process equipment operating at elevated
temperature and pressure, or sudden ingress of air into vacuum equipment, may result in ignitions without
the presence of obvious ignition sources. Published "autoignition" or "ignition" temperature values
cannot be treated as safe operating temperatures in chemical processes without analysis of the actual
process conditions. Any use of this product in elevated-temperature processes should be thoroughly
evaluated to establish and maintain safe operating conditions. Further information is available in a
technical bulletin entitled "Ignition Hazards of Organic Chemical Vapours."

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill :
Extinguish and do not turn on any ignition source until the area is determined to be free from explosion or
fire hazards. Wear suitable protective equipment. Avoid contact with liquid and vapours. Small spills
could be flushed with large quantities of water. Larger spills should be collected for disposal. Toxic to
fish; avoid discharge to natural waters.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0127

Material Safety Data Sheet

City University of Hong Kong

MSDS ETHYLENEDIAMINETETRAACETIC ACID 0127

DISODIUM SALT
========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Ethylenediaminetetraacetic Acid, Disodium Salt

Chinese Name:
Synonyms: Sodium EDTA
Chemical Family: Edetates
Chemical Formula: C10H14N2O8Na2.2H2O
CAS No. : 600-00-4
Product Use: Detergents, liquid soaps, shampoos; analytical chemistry; spectrophotometric titrations

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Odour and Appearance: White, odourless crystals
Odour Threshold (ppm): Not applicable
Vapour Pressure (mmHg): Not applicable
Vapour Density (Air=1): Not applicable
Evaporation Rate: Not applicable
Boiling Point : Not applicable
Freezing Point : Greater than 300 deg. C (melting point)
pH: 11.8
Specific Gravity: 0.8
Coefficient of Water/Oil distribution: Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flammability: Non Flammable

Point (Method Used): Non combustible
Autoignition Temperature: Not available
Upper Flammable Limit (% by volume): Not available
Lower Flammable Limit (% by volume): Not available
Extinguishing Media: Water spray, carbon dioxide, dry chemical powder
Flash Hazardous Combustion Products: None
Sensitivity to Impact: Not available
Sensitivity to Static discharge: Not available

========================================================================
REACTIVITY DATA
========================================================================

Chemical Stability: Stable

Incompatibility with other substances:
Aluminum reacts with water solutions of product to release hydrogen. Strong oxidizing agents and strong
acids

Hazardous Decomposition Products: Carbon monoxide, carbon dioxide and nitrogen oxides

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0127
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhaled: May cause coughing, wheezing, respirator distress and mucous membrane irritation.
In contact with skin: Slightly irritating to skin
In contact with eyes: Moderately irritating to eyes
Ingested:
May cause burns to the gastrointestinal tract. In large quantities, product may cause hypocalcemic tetany.
Toxicological Data:
LD50: (oral, rat) 2000 mg/kg
LC50: Not available
Carcinogenicity: Not available
Teratogenicity: Not available
Reproductive Effects: Not available
Mutagenicity: Not available
Synergistic Products: Not available

========================================================================
FIRST AID MEASURES
========================================================================

Eyes:
Flush immediately with large amounts of water for fifteen (15) minutes. Call a physician immediately.

Skin:
Wash with plenty of soap and water. Wash clothing before reuse. Seek medical attention if skin shows
signs of irritation.

Inhalation:
Remove to fresh air. If breathing has stopped, perform artificial respiration. Keep victim warm and at
rest.

Ingestion:
Give victim large amounts of water or milk to drink for dilution effect. Do not induce vomiting.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls: Fume hoods or local exhaust recommended.

Respiratory Protection: Use a NIOSH approved respirator
Eye Protection: Safety glasses or face shield
Skin Protection: Impervious gloves and clothing.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Other Personal Protective Equipment: Safety shower and eyewash fountain in work area.

Handling Procedures and Equipment:

Handle as a 1% caustic powder. Do not store in contact with aluminum or copper.

Storage Requirements: Do not store in contact with aluminum of copper.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Leak and Spill Procedure:

Prevent product from entering drinking water supplies or streams. Collect product into containers for
disposal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0128

Material Safety Data Sheet

City University of Hong Kong

MSDS 1,6-HEXANEDIAMINE 0128

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: 1,6-Hexanediamine

Chinese Name:
Common Synonyms: Hexamethylenediamine
Chemical Family: Amines
Formula: NH2(CH2)6NH2
Formula Wt.: 116.21
CAS No.: 124-09-4
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 205 deg. C (401 deg. F) Vapor Pressure (mmHg): 1.1
(@ 760 mmHg) (20 deg. C)
Melting Point: 39 deg. C (102 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 0.84 Evaporation Rate: >1
(H2O=1) (Butyl Acetate = 1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White to yellow crystals. amine-like odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 93 deg. C (200 deg. F)

Autoignition Temperature: N/A
Flammable Limits: Upper - 6.3 % Lower - 0.7 %
Fire Extinguishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Ammonia, oxides of nitrogen, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles: Strong oxidizing agents, strong acids, organic materials
Decomposition Products: Ammonia, oxides of nitrogen, carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Severe irritation or burns of mucous membranes, irritation of upper respiratory tract
Skin Contact: Severe irritation or burns

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0128
Eye Contact: Severe irritation or burns
Skin Absorption: May be harmful
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For 1,6-Hexanediamine 750 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Reproductive Effects: None identified.

Carcinogenicity: None identified.
Target Organs: Eyes, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Eye contact, skin contact, inhalation, absorption

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation:
Call a physician. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing
is difficult, give oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area or
cabinet.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking, or flames in area. With clean shovel, carefully place material into clean, dry container and
cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0129

Material Safety Data Sheet

City University of Hong Kong

MSDS IODINE 0129

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Iodine

Chinese Name:
Common Synonyms: N/A
Chemical Family: Halogens
Formula: I2
Formula Wt.: 253.81
CAS No.: 7553-56-2
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 184 deg. C (363 deg. F) Vapor Pressure (mmHg): 0.31
(@ 760 mmHg) (20 deg. C)
Melting Point: 114 C (237 F) Vapor Density (Air=1): 9.0
(@ 760 mmHg)
Specific Gravity: 4.93 Evaporation Rate: N/A
(H2O=1)
Solubility(H20): Negligible (<0.1%) % Volatiles By Volume: 100
(21 deg. C)
pH: 5.4 (Saturated Solution)
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Purple to black crystals. characteristic odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: Moderate oxidizer. Contact with other material may cause fire.
Toxic Gases Produced: None identified

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition, sunlight
Incompatibles:
Strong reducing agents, ammonia, ammonium salts, acetylene, acetaldehyde, combustible materials,
aluminum, chemically active metals, powdered metals, carbides, ammonium hydroxide

Decomposition Products: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0129
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Irritation of mucous membranes, severe irritation or burns of respiratory system, pulmonary edema, lung
inflammation, and may be fatal

Skin Contact: Severe irritation or burns

Eye Contact:
Severe irritation or burns, prolonged contact may cause permanent corneal damage, and blindness, may
occur

Skin Absorption: None identified

Ingestion:
Irritation and burns of mouth and throat, gastrointestinal pain, nausea, vomiting, fever, shock, bloody
urine, difficult breathing, and may be fatal

Chronic Effects: Lung damage, thyroid damage, bladder damage

Threshold Limit Value (TLV/TWA): 1.0 mg/m3 (0.1 ppm)
TLV listed denotes ceiling limit.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 1 mg/m3 (0.1 ppm)
PEL listed denotes ceiling limit.
Toxicity Of Components:
Oral Rat LD 50 For Iodine 14 g/kg
Oral Mouse LD 50 For Iodine 22 g/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Respiratory system, eyes, skin, central nervous system, cardiovascular system
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give water, milk, or milk of
magnesia.

Inhalation:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes.
Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store in corrosion-proof area. Keep containers out of sun and away from
heat.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0131

Material Safety Data Sheet

City University of Hong Kong

MSDS FORMALIN, 10% V/V SOLUTION, 0131

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Formalin, 10% v/v Solution, Neutralized

Chinese Name:
Common Synonyms: N/A
Chemical Family: Volumetric Solutions And Concentrates
Formula: N/A
Formula Wt.: N/A
CAS No.: 50-00-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: 1.09 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Complete (100%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Clear, colorless liquid. Pungent odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 84 deg. C (185 deg. F)

Autoignition Temperature: N/A
Flammable Limits: Upper - 73.0 % Lower - 7.0 %
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Formaldehyde, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame
Incompatibles:
Strong oxidizing agents, strong acids, strong bases, alkalies, alkali metals, amines and ammonia, phenol,
strong reducing agents

Decomposition Products: Formaldehyde, carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0131
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Is harmful and may be fatal, headache, nausea, vomiting, dizziness, drowsiness, irritation of upper
respiratory tract, unconsciousness

Skin Contact: Severe irritation or burns, prolonged contact may cause skin sensitization
Eye Contact: Severe irritation or burns
Skin Absorption: Rapid absorption
Ingestion:
Is harmful and may be fatal, nausea, vomiting, gastrointestinal irritation, burns to mouth and throat

Chronic Effects: Kidney damage, liver damage

Threshold Limit Value (TLV/TWA): 1.5 mg/m3 (0.75 ppm)
TLV is for formaldehyde.
Short-Term Exposure Limit (STEL): 3 mg/m3 (2 ppm)
STEL is for formaldehyde.
Permissible Exposure Limit (PEL): 1.5 mg/m3 (0.75 ppm)
PEL is for formaldehyde.
Toxicity Of Components:
Oral Rat LD 50 For Formaldehyde 800 mg/kg
Skin Rabbit LD 50 For Formaldehyde 270 mg/kg
Subcutaneous Rat LD50 For Formaldehyde 420 mg/kg
Inhalation Rat LC50 For Formaldehyde 590 mg/kg
Oral Rat LD 50 For Sodium Phosphate, Monobasic 8290 mg/kg
Intraperitoneal Mouse LD 50 For Water 190 g/kg
Intravenous Mouse LD50 For Water 25 g/kg
Carcinogenicity: NTP: YES IARC: No Z LIST: No OSHA REG: No

Carcinogenicity:
This substance is listed as an acgih suspected human carcinogen and a NTP anticipated human
carcinogen.

Reproductive Effects: Tests on laboratory animals indicate that formaldehyde may be mutagenic.
Target Organs: Respiratory system, eyes, skin, liver, kidneys
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Ingestion, inhalation, eye contact, skin contact, absorption

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, give large amounts of water. induce vomiting.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes.
Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 50 ppm,
a chemical cartridge respirator with organic vapor cartridge is recommended. Above this level, a self-
contained breathing apparatus is recommended.

Eye/Skin Protection:
Safety goggles and face shield, uniform, protective suit, proper gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store in secure poison area. Isolate from incompatible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Stop leak if you can do so without
risk. Use water spray to reduce vapors. take up with sand or other non-combustible absorbent material
and place into container for later disposal. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0132

Material Safety Data Sheet

City University of Hong Kong

MSDS TERT-BUTYL ALCOHOL 0132

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Tert-Butyl Alcohol

Chinese Name:
Common Synonyms: 2-Methyl-2-Propanol
Chemical Family: Alcohols
Formula: (CH3)3COH
Formula Wt.: 74.12
CAS No.: 75-65-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 83 deg. C (181 deg. F) Vapor Pressure (mmHg): 31
(@ 760 mmhg) (20 deg. c)
Melting Point: 25 deg. C (77 deg. F) Vapor Density (Air=1): 2.6
(@ 760 mmhg)
Specific Gravity: 0.78 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Complete (100%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless crystals or liquid. Camphor-like odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 11 deg. C (52 deg. F)

Autoignition Temperature: 477 deg. C (892 deg. F)
Flammable Limits: Upper - 8.0 % Lower - 2.4 %
Fire Extinguishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move exposed containers from fire area if it can be done
without risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles: Strong oxidizing agents
Decomposition Products: Carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0132
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Irritation of nose and throat, headache, nausea, dizziness, fatigue, severe irritation of respiratory system,
narcosis, weakness in arms and legs

Skin Contact: Irritation

Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 300 mg/m3 (100 ppm)
Short-Term Exposure Limit (STEL): 450 mg/m3 (150 ppm)
Permissible Exposure Limit (PEL): 300 mg/m3 (100 ppm)
Toxicity Of Components:
Oral Rat LD 50 For Tert-Butyl Alcohol 3500 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 5000
ppm, a chemical cartridge respirator with organic vapor cartridge is recommended. Above this level, a
self-contained breathing apparatus is recommended.

Eye/Skin Protection: Safety goggles, uniform, apron, proper gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area.

Special Precautions:
Bond and ground containers when transferring liquid. Product may solidify at room temperature.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0136

Material Safety Data Sheet

City University of Hong Kong

MSDS STEARIC ACID 0136

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Stearic Acid

Chinese Name:
Common Synonyms: Octadecanoic Acid; 1-Heptadecanecarboxylic Acid
Chemical Family: Organic Acids
Formula: C18H36O2
Formula Wt.: 284.49
CAS No.: 57-11-4
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 383 deg. C (721 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 69 deg. C (156 deg. F) Vapor Density (Air=1): 9.8
(@ 760 mmHg)
Specific Gravity: 0.87 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White to light yellow solid. Tallow-like odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 195 deg. C (385 deg. F)

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: dust may form explosive mixture with air.
Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition, dusting
Incompatibles: Strong bases, strong oxidizing agents
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: None identified
Eye Contact: Irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0136
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Intravenous Mouse LD50 For Stearic Acid 23 mg/kg
Intravenous Rat LD50 For Stearic Acid 21.5 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Store in a cool, well-
ventilated area away from sources of heat, flame, or ignition.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0139

Material Safety Data Sheet

City University of Hong Kong

MSDS PHOSPHORUS PENTACHLORIDE 0139

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Phosphorus Pentachloride

Chinese Name:
Common Synonyms: Phosphorous (V) Chloride; Pentachlorophosphorane; Phosphorous Perchloride
Chemical Family: Phosphorus And Phosphorus Compounds
Formula: PCl 5
Formula Wt.: 208.24
CAS No.: 10026-13-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 162 deg. C (323 deg. F) Sublimes Vapor Density (Air=1): 7.2
(@ 760 mmHg)
Specific Gravity: 3.60 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Decomposes % Volatiles By Volume: N/A
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Light yellow solid. Hydrochloric acid odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use dry chemical or carbon dioxide. Do not use water.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards:

A violent exothermic reaction occurs with water. Sufficient heat may be produced to ignite combustible
materials. note: sublimes at melting point.

Toxic Gases Produced: Hydrogen chloride, oxides of phosphorus

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture, heat
Incompatibles:
Water, chemically active metals, sodium, potassium, aluminum, alkalies, fluorine, magnesium oxide,
hydroxylamine, chlorine dioxide, phosphorus oxides

Decomposition Products: Hydrogen chloride, oxides of phosphorus

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0139
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 1.0 mg/m3 (0.1 ppm)
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 1 mg/m3
Toxicity Of Components:
Oral Rat LD 50 For Phosphorus Pentachloride 660 mg/kg
Inhalation Rat LC50 For Phosphorus Pentachloride 205 mg/m3
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Respiratory system, eyes, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give water, milk, or milk of
magnesia.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes.
Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store away from water or locations where water may be used to
extinguish fire.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water. Do not get
water inside container.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0140

Material Safety Data Sheet

City University of Hong Kong

MSDS PHOSPHORUS PENTOXIDE 0140

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Phosphorus Pentoxide

Chinese Name:
Common Synonyms: Phosphorus (V) Oxide; Phosphorous Pentaoxide; Phosphoric Anhydride
Chemical Family: Phosphorus And Phosphorus Compounds
Formula: P2O5
Formula Wt.: 141.94
CAS No.: 1314-56-3
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 360 deg. C (680 deg. F) Vapor Density (Air=1): 4.9
(@ 760 mmHg)
Specific Gravity: 2.38 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Decomposes % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White Crystals. Acid Odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use dry chemical or carbon dioxide. Do not use water.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards:

A violent exothermic reaction occurs with water. Sufficient heat may be produced to ignite combustible
materials.

Toxic Gases Produced: Oxides of phosphorus

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture
Incompatibles:
Water, ammonia, sodium, potassium, strong bases, most common metals, hydrogen fluoride, alcohols

Decomposition Products: Oxides of phosphorus

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0140
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Severe irritation or burns
Eye Contact:
Severe irritation or burns, prolonged contact may cause ermanent corneal damage, and blindness, may
occur
Skin Absorption: None identified
Ingestion: Severe burns, ulceration - mouth, throat, stomach, nausea, vomiting
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Inhalation-1hr Mouse LC 50 For Phosphorus Pentoxide 271 ppm
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Eye contact, skin contact, inhalation, ingestion

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give large amounts of water.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a dust/mist
respirator is recommended. If concentration exceeds capacity of respirator, a self-contained breathing
apparatus is advised.

Eye/Skin Protection:
Safety goggles and face shield, uniform, protective suit, rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store away from water or locations where water may be used to
extinguish fire. Store in a cool, well-ventilated area away from sources of heat, flame, or ignition.
Isolate from incompatible materials.

Special Precautions:
Note: keep material dry; reaction with water can generate sufficient heat to ignite materials that burn.
Wear goggles, face shield, rubber gloves, and protective clothing when handling. Open container
carefully. Do not allow water to get into container because of violent reaction.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0144

Material Safety Data Sheet

City University of Hong Kong

MSDS PROPIONALDEHYDE 0144

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Propionaldehyde

Chinese Name:
Common Synonyms: Propanal; Propionic Aldehyde; Methylacetaldehyde
Chemical Family: Aldehydes
Formula: CH3CH2CHO
Formula Wt.: 58.08
CAS No.: 123-38-6
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 49 deg. C (120 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: -81 deg. C (-113 deg. F) Vapor Density (Air=1): 2.0
(@ 760 mmHg)
Specific Gravity: 0.81 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Moderate (1-10%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless liquid. Pungent odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): -29 deg. C (-22 deg. F)

Autoignition Temperature: 207 deg. C (405 deg. F)
Flammable Limits: Upper - 17 % Lower - 2.6 %
Fire Extinquishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles: Strong oxidizing agents, mineral acids, organic acids, caustics
Decomposition Products: Carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0144
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Severe irritation of respiratory system, nausea, vomiting

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Irritation and burns to mouth and stomach
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Propionaldehyde 1410 mg/kg
Subcutaneous Rat LD50 For Propionaldehyde 820 mg/kg
Skin Rabbit LD 50 For Propionaldehyde 5040 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Respiratory system, skin, eyes
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give water, milk, or milk of
magnesia.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep vapor and mist levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a chemical
cartridge respirator with organic vapor cartridge is recommended. If concentration exceeds capacity of
cartridge respirator, a self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, proper gloves arerecommended.

Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area or
cabinet.

Special Precautions: Bond and ground containers when transferring liquid.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0146

Material Safety Data Sheet

City University of Hong Kong

MSDS SALICYLIC ACID 0146

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Salicylic Acid

Chinese Name:
Common Synonyms: O-Hydroxybenzoic Acid; 2-Hydroxybenzoic Acid
Chemical Family: Organic Acids
Formula: 2-HOC6H4COOH
Formula Wt.: 138.12
CAS No.: 69-72-7
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 211 deg. C (411 deg. F) Vapor Pressure (mmHg): <1
(@ 760 mmHg) (20 deg. C)
Melting Point: 159 deg. C (318 deg. F) Vapor Density (Air=1): 4.8
(@ 760 mmHg)
Specific Gravity: 1.44 Evaporation Rate: <1
(H2O=1) (Butyl Acetate = 1)
Solubility(H2O): Slight (0.1-1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 157 deg. C (315 deg. F)

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - 1.1 %
Fire Extinquishing Media: Use water spray, carbon dioxide, dry chemical or ordinary foam.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: Dust may form explosive mixture with air.
Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Light, heat, flame, other sources of ignition, moisture
Incompatibles: Strong oxidizing agents, strong bases, mineral acids, iron, most common metals
Decomposition Products: Carbon monoxide, carbon dioxide, phenol

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Irritation, prolonged contact may cause dermatitis

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0146
Eye Contact: Irritation, prolonged contact may cause permanent corneal damage, and blindness, may
occur
Skin Absorption: None identified
Ingestion: Headache, nausea, vomiting, dizziness, gastrointestinal irritation
Chronic Effects: Kidney damage
Threshold Limit Value (TLV/TWA): 10 mg/m3
TLV is for nuisance dusts and particulates.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 15 mg/m3
PEL is for nuisance dusts and particulates.
Toxicity Of Components:
Oral Rat LD 50 For Salicylic Acid 891 mg/kg
Intravenous Mouse LD50 For Salicylic Acid 184 mg/kg
Intraperitoneal Mouse LD 50 For Salicylic Acid 1500 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, skin, respiratory system, gi tract
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Eye contact, skin contact, inhalation, ingestion

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Eye/Skin Protection: Safety goggles, uniform, proper gloves are recommended.
Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Keep product out of light.
Isolate from incompatible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking, or flames in area. With clean shovel, carefully place material into clean, dry container and
cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0147

Material Safety Data Sheet

City University of Hong Kong

MSDS SILICON TETRACHLORIDE 0147

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Silicon Tetrachloride

Chinese Name:
Synonyms: -
Formula: SiCl 4
Nature, Appearance & Odour: Mobile fuming liquid, colourless, suffocating odour.

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point 57.6 deg. C (135.7 deg. F) Specific Gravity (H2O=1 @ 0 deg. C) 1.52 deg. F)
Melting Point -70.0 deg. C (-93 deg. F) Percent Volatile 100%

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapour Pressure (@ 20 deg. C) 26 Evaporation Rate @ 20 deg. C Slow kPa (193
mmHg)
Vapour Density (Air=1) 5.9 Solubility (See Reactivity)

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point Non Flammable

Lower Explosive Limit -
Upper Explosive Limit -
Auto Ignition Temperature -
Hazardous Product Of Combustion : Silica, HCl (in contact with moisture)
Extinguishing Media:
Use extinguishing media for surrounding fires. Dry chemicals not containing Alkalies, reacts with water
releasing much heat. Contain water used to extinguish fires (may contain hydrochloric acid).

Special Fire Fighting Procedures:

Use SCBA when approaching. Chemical (Acid) resistant clothing to be worn if a leak is present or
likely to occur. Cylinders may explode when exposed to fire.

========================================================================
REACTIVITY DATA
========================================================================

Stability : Stable (in absence of moisture, alcohols, amines).

Hazardous Decomposition: May occur under heat or in contact with moisture or Alkali.
Incompatibilities: Water, Alkalies, Alcohol, Acetone
Hazardous Decomposition Products: HCl, Silicic Acid
Corrositivity:
Dry gas will not attach carbon steel. Avoid moisture in cylinders (carbon steel) because cylinder walls
may be corroded.

========================================================================
HEALTH HAZARD DATA
========================================================================

Eyes: Severe irritation on exposure.

Skin: Severe irritation and burns on exposure.
Inhalation:
Exposure may cause choking, coughing, edema, spasms of larynx and death may follow severe exposure.

Ingestion: Burns of digestive routes.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0147
========================================================================
FIRST AID MEASURES
========================================================================

Eyes:
Wash promptly with copious amount of water for 15 mins. keeping eye lids apart. Call a physician.
Repeat wash a second time.

Skin:
Move patient from area. Eliminate contaminated clothes and shoes. Call physician. Wash affected areas.
Do not use ointments unless recommended by a physician. Keep patient warm and quiet.

Inhalation:
Move victim to fresh air. Give oxygen if breathing is difficult. Call physician. Give artificial respiration
if breathing has stopped. If nose membranes are irritated, wash for 15 minutes.

Ingestion:
Burns may result internally. (Solutions are very strong acid and may cause death).

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Provide good ventilation with suction hoods. Corrosion resistant, forced draft fume hoods preferred.

Hand: Neoprene gloves

Eyes And Face: Full face shield and chemical goggles. Clothing: On possible exposure, neoprene
clothes, chemical resistant clothes.

Respiratory Equipment: Self contained breathing apparatus if exposure to vapors is likely to occur.
Storing And Handling:
Store cylinders away from sources of heat. Handle cylinders with cap in place (if supplied).

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill Or Leak Procedure :

Store with adequate ventilation. In case of leak, close source of spill if without risk. Use full protective
clothing on approach. Keep upwind. Evacuate spill area. Reduce vapors with water spray or fog. Do not
walk on spilled material unless neutralized or without rubber (neoprene) boots.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0148

Material Safety Data Sheet

City University of Hong Kong

MSDS SODA LIME 0148

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Soda Lime

Chinese Name:
Common Synonyms: N/A
Chemical Family: Calcium Compounds
Formula: N/A
Formula Wt.: N/A
CAS No.: 8006-28-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: N/A Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Slight (0.1-1%) % Volatiles By Volume: ~20
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White to gray gray odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: Closed containers exposed to heat may explode.
Toxic Gases Produced: Phosgene, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture
Incompatibles: Strong acids, water, fluorine, chloroform, trichloroethylene
Decomposition Products: Phosgene, carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Excessive inhalation is irritating, may cause respiratory system damage, coughing
Skin Contact: Severe irritation or burns
Eye Contact: Severe irritation or burns
Skin Absorption: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0148
Ingestion: May be harmful
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 5 mg/m3
TLV is for calcium hydroxide.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Intraperitoneal Mouse LD 50 For Sodium Hydroxide 40 mg/kg
Oral Rat LD 50 For Potassium Hydroxide 365 mg/kg
Oral Rat LD 50 For Calcium Hydroxide 7340 mg/kg
Oral Mouse LD 50 For Calcium Hydroxide 7300 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, respiratory system, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give large amounts of water.
Follow with diluted vinegar, fruit juice or whites of eggs beaten with water.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a dust/mist
respirator is recommended. If concentration exceeds capacity of respirator, a self-contained breathing
apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements: Keep container tightly closed. Store in corrosion-proof area. Protect from
freezing.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0149

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM METAL 0149

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Sodium

Chinese Name:
Synonyms : Sodium Metal
Chemical Family : Alkali Metal
CAS Number : 7440-23-5
Formula : Na

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point : 881 deg. C (1,618 deg. F) at 760 mmHg.

Vapor Pressure : 1 mmHg At 493 deg. C (920 deg. F)
Vapor Density : Not applicable
Melting Point : 97.8 deg. C (208 deg. F)
Evaporation Rate : Not applicable
Water Solubility : Reacts violently with water.
Odor : Odorless
Form : Metallic Solid
Specific Gravity : 0.97 @ 20 deg. C (68 deg. F)
pH Information : Reacts with water to form sodium hydroxide (high pH) and hydrogen gas.
Color : In inert atmosphere- pinkish silvery when fresh cut. In air- white to gray.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point : Not applicable

Flammable Limits In Air, % by Volume
LEL : Not determined UEL : Not determined
Autodecomposition: Not applicable
Autoignition : ~120-125 deg. C (~248-257 deg. F)
Fire And Explosion Hazards :
Flammable solid. Reacts violently with water releasing hydrogen gas, which will ignite and explode in
air. Burning produces dense, white, irritating smoke.

Extinguishing Media :
Dry Soda Ash, Light (low density, floats on molten sodium) or Class D fire extinguisher. Dry salt or
sand is less effective, but can be used.

Special Fire Fighting Instructions :

DO NOT use water. Do not use Carbon Dioxide (CO2), soda-acid, or chlorinated fire extinguishing
agents such as carbon tetrachloride. Stay upwind and use self-contained breathing apparatus if needed.
Sodium melts and burns with little or no flame, but with yellow to yellow-orange glowing globules that
appear to move on the surface of the molten pool. Reduce fire by diking to limit sodium surface, then
smother with soda ash or cover with a steel lid.

========================================================================
REACTIVITY DATA
========================================================================

Instability : Stable.
Decomposition : Decomposition will not occur.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0149
Polymerization : Polymerization will not occur.
Incompatibility :
Reacts violently with any materials containing water and many materials containing oxygen, halides, or
active hydrogen. Reaction with water gives sodium hydroxide and hydrogen gas, which may explode.
Burning produces sodium oxide fumes.

========================================================================
HEALTH HAZARD DATA
========================================================================

Causes severe eye and skin burns from reactions to sodium hydroxide--effects may be permanent. Fumes
from sodium reactions to sodium oxide may irritate the nose, throat, and lungs. Ingestion will cause burns
of the gastrointestinal tract with perforations by formation of sodium hydroxide.

Sodium reacts rapidly with moisture in air or tissues to form sodium hydroxide and sodium oxide.
Effects following inhalation, ingestion, or skin or eye contact result from direct chemical reaction with
tissue and from thermal reaction with water.

Animal Data:
Oral ALD: 500 mg/kg in rabbits (sodium hydroxide) Sodium is very corrosive to animal skin and eyes
by reactive formation of sodium hydroxide. Toxic effects described in animals from exposure by
inhalation or ingestion include irritation of the respiratory tract, and extensive necrosis of the
gastrointestinal tract.

Human Health Effects:

Overexposure by skin or eye contact include skin burns or ulceration; or eye corrosion with corneal or
conjunctival ulceration. By inhalation, the effects include irritation of the upper respiratory passages
with coughing and discomfort. By ingestion, the effects include abdominal discomfort characterized by
nausea, severe pain, diarrhea, and collapse.

Carcinogenicity :
None of the components in this material is listed by IARC, NTP, OSHA, or ACGIH as a carcinogen.

Exposure Limits :
TLV (ACGIH) : None established
PEL (OSHA) : Particulates not otherwise regulated
15 mg/m3 - 8 hr TWA - Total dust
5 mg/m3 - 8 hr TWA - Respirable dust

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Safety Precautions :
Persons handling sodium should be thoroughly familiar with its hazards and proper first aid procedures.
Do not get in eyes, on skin, or on clothing, and avoid any contact with water. Avoid breathing fumes from
sodium reactions.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation :
If fumes from sodium reactions are inhaled, remove to fresh air immediately. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Call a physician.

Skin Contact :
In case of contact, immediately remove particles of sodium adhering to the body or clothing. This must
be done before washing to avoid additional heat from the reaction between sodium and water. After the
particles are removed, flush the skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Call a physician. Burn or wash clothing and shoes.

Eye Contact :
In case of contact, remove sodium, then immediately flush eyes with plenty of water for at least 15
minutes. Call a physician.

Ingestion :
If swallowed, do not induce vomiting. Give large quantities of water. Call a physician immediately.
Never give anything by mouth to an unconscious person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Generally Applicable Control Measures And Precautions :

Good general ventilation should be provided to keep fume concentrations below the exposure limits and
to prevent the accumulation of hydrogen gas.

Personal Protective Equipment :

Solid Sodium: Sodium bricks can be handled safely using chemical splash goggles and DRY moleskin
mitts. Mitts should be oversized for easy removal and should extend up the arms to prevent caustic burns.
Wear a long sleeve shirt. A full-length face shield, alkali resistant apron, and other special protective
equipment may be needed for specific jobs.

Molten Sodium: When liquid sodium is handled or there is danger of spillage, full protective flameproof
clothing should be available and used as appropriate. This includes: hard hat with brim; chemical splash
goggles; full length face shield; fire resistant ("Nomex" Aramid Fiber or alternative) long underwear,
pants and shirt (or coveralls) neck shroud, spats, apron; and heavy duty work shoes. Two, or preferably
more, layers of flameproof clothing are clearly more effective than one layer. A NIOSH/MSHA air

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0149
supplied or self-contained breathing apparatus is needed if large amounts of sodium oxide smoke are
present; a NIOSH/MSHA approved air purifying respirator can be used for smaller amounts.

Store in segregated area of fire resistant, watertight building without sprinklers, steam, water lines,
skylights, or potential for flooding. Ventilate to avoid hydrogen accumulation. Keep drums covered to
prevent caustic formation from moisture in air. Keep from possible contact with water. Nitrogen purging
of open drums will minimize reactions with moisture and oxygen in air. Keep drums tightly closed. Do
not store with combustibles or flammables as firefighting problems would be compounded. Use only
clean, dry utensils in handling.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill, Leak, Or Release :

NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding
with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up.

Cover with DRY Soda Ash, Light; shovel into a dry metal container and cover again with soda ash, and
dispose of promptly. Avoid putting wet sodium in a covered container because a hydrogen explosion
may occur. Wear proper protective equipment. Comply with Federal, State, and local regulations on
reporting releases. The CERCLA Reportable Quantity is 10 lbs.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0150

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM OXALATE 0150

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Sodium Oxalate

Chinese Name:
Common Synonyms: Oxalic Acid, Disodium Salt; Ethanedioic Acid, Disodium Salt
Chemical Family: Organic Sodium Salts
Formula: NaOCOCOONa
Formula Wt.: 134.00
CAS No.: 62-76-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 260 deg. C (500 deg. F) Decomposes Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.34 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Moderate (1-10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystalline powder. Odorless.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards:

Note: Decomposes at melting point.
Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: Strong acids
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Severe irritation or burns
Eye Contact: Severe irritation or burns

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0150
Skin Absorption: None identified
Ingestion:
Is harmful and may be fatal, nausea, vomiting, unconsciousness, irritationand burns to mouth and stomach
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Chronic Effects: Kidney
Damage Target Organs: Eyes, skin, kidneys
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, if conscious, give lime water, large amount of powdered chalk in water,
or milk. Then induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, uniform, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Store in corrosion-proof area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0152

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM NITRITE 0152

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Sodium Nitrite

Chinese Name:
Common Synonyms: Nitrous Acid,Sodium Salt; Anti-Rust
Chemical Family: Inorganic Sodium Compounds
Formula: NaNO2
Formula Wt.: 69.00
CAS No.: 7632-00-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 320 deg. C (608 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 271 deg. C (519 deg. F) Vapor Density (Air=1): 2.4
(@ 760 mmHg)
Specific Gravity: 2.17 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White to yellow green or purple odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use Water Spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Strong oxidizer. Contact with combustible materials, flammable materials, or powdered metals can
cause fire or explosion. Can react violently with shock, friction or heat.

Toxic Gases Produced: Oxides of nitrogen

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Shock, friction, heat
Incompatibles:
Cyanides, strong acids, strong reducing agents, combustible materials, organic materials, ammonium
salts

Decomposition Products: Oxides of nitrogen

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0152
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion:
Irritation and burns to mouth and stomach, ingestion of large quantities may cause nausea, vomiting,
cyanosis, convulsions, low blood pressure

Chronic Effects: None identified

Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
ORAL RAT LD50 For Sodium Nitrite 85 mg/kg
Intraperitoneal Mouse LD 50 For Sodium Nitrite 158 mg/kg
Intravenous Rat LD50 For Sodium Nitrite 65 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity:
Nitrosamine formation may occur when sodium nitrite comes in contact with various secondary and
tertiary amines. Nitrosamines are potentially carcinogenic compounds.

Reproductive Effects: None identified.

Target Organs: Blood
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, give large amounts of water induce vomiting.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, uniform, butyl rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.

Special Precautions: Material is hygroscopic.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Keep combustibles (wood, paper,
oil, etc.) away from spilled material. With clean shovel, carefully place material into clean, dry
container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0154

Material Safety Data Sheet

City University of Hong Kong

MSDS SULPHUR 0154

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Sulphur

Chinese Name:
Trade Name and Synonyms : Sulphur; Sulphur Elements
Chemical Family : Sulphur
Chemical Formula : S8
Molecular Weight : 32

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State : Solid

Odour and Appearance : Yellowish solid; rotten egg odour when H2S is present

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odour Threshold (ppm) : N.D.
Specific Gravity : 2.07 @ room temp.
Vapour Pressure (mm) : 0.11 mm Hg @ 140 deg. C
Vapour Density (Air = 1) : .2278 lbs/ft3
Evaporation Rate : N/A
Boiling Point : 445 deg. C
Freezing Point : 110-119 deg. C (melt point)
Solubility in Water (20 deg. C) : Negligible
% Volatile (by volume) : 0
pH : N/A
Coefficient of water/oil distribution : N.D.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Conditions of Flammability :
Easily ignitable, combustible solid. Dust or vapour forms explosive mixtures with air.

Means of Extinction :
Small fires may be smothered by covering with inert material such as dirt / sand or use portable
extinguisher. For larger fires, use water spray or steam. Avoid spraying water directly into containers
due to the danger of boil over.

Special Procedures :
Wear self contained breathing apparatus and full protective equipment. If hydrogen sulfide is present, the
flammable limits can range from 4.3 to 45.5% and cause ignition more readily. Avoid straight streams
which may scatter molten sulphur and dust.

Flashpoint ( deg. C) and Method : 207

Upper explosion limit (% by volume) : N.D
Lower explosion limit (% by volume) : N.D
Auto Ignition Temperature : 232 deg. C
Explosion Data - Sensitivity to Static Discharge : Can be ignited by static

========================================================================
REACTIVITY DATA
========================================================================

Stability : Stable
Incompatibility to other substances : Oxidizing agents, mineral acids and alkalines

Reactivity and under what conditions:

At higher temperatures, sulphur will react with hydrocarbons giving off hydrogen sulphide. Hazardous
polymerization will not occur.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0154
Hazardous Decomposition Products: Oxides of sulphur (such as sulphur dioxide), hydrogen sulphide.

========================================================================
HEALTH HAZARD DATA
========================================================================

Exposure limits : LD 50/LC50 Specify Species and Route

Route of Entry : Skin Contact, Eye Contact, Inhalation
Effects of Acute Exposure to Product :
Dusts may be irritating to the eyes, nose, throat and lungs. Solid sulphur (especially when freshly
produced) may release hydrogen sulphide gas which may cause irritation, breathing failure, coma and
death without necessarily any warning odour being sensed. Eye contact with sulfur may be irritating and
may injure eye tissue if not removed promptly.

Effects of Chronic Exposure to Product :

Repeated or prolonged contact may irritate the skin, cause dermatitis and lead to allergic reactions.
Repeated inhalation exposure to dust may cause bronchitis.

========================================================================
FIRST AID MEASURES
========================================================================

Skin :
Remove contaminated clothing - launder clothing before reuse. Wash skin with soap and running water.
Seek medical attention if irritation develops.

Eye : Immediately flush with running water for at least 15 minutes. Seek immediate medical attention.
Inhalation :
Remove to fresh air. If not breathing - apply artificial respiration. Administer oxygen if breathing is
difficult. Seek immediate medical attention.

Ingestion :
Do not induce vomiting. Drink milk or water to dilute stomach contents. Never give anything by mouth
if victim is convulsing or losing consciousness. Keep warm and at rest. Seek immediate medical
attention.

General Advice : Keep victim warm and quiet. Seek medical attention.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Personal Protective Equipment :

Avoid contact with skin, eyes or clothing. if prolonged or repeated skin contact with dust is likely, wear
coveralls.

Gloves (Specify) : Chemical resistant.

Eye (Specify) : Chemical goggles.
Respiratory :
Handle with adequate ventilation and wear a dust mask. If adequate ventilation does not exist or, if
exposure limits of dust mask are exceeded, wear a NIOSH approved air supplied respirator.

Engineering Controls (e.g. ventilation, enclosed process, specify) :

Local exhaust ventilation may be needed to control dust and vapours below the safe exposure limits.

Handling Procedures and Equipment :

Avoid contact with skin, eyes or clothing. If prolonged or repeated skin contact with dust is likely, wear
coveralls. Avoid breathing dust. If hydrogen sulphide or sulphur dioxide is emitted, wear an air
supplied respirator when handling. Material may accumulate static. Static charge build up may become
an ignition source. Transfer using proper grounding procedures. Guard against dust / vapour
accumulation in air. Keep away from heat, sparks or flames.

Storage Requirements :
Store in a cool, well ventilated, dry area at temperatures below 38 deg. C and above 0 deg. C. Protect
from physical damage.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Leak and Spill Procedure :

Contain. Remove ignition sources. Ventilate area. Wear protective equipment and a NIOSH-approved
respirator. Clean up spill creating as little dust as possible. Notify appropriate authorities of
significant spills.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0157

Material Safety Data Sheet

City University of Hong Kong

MSDS BUTYRIC ACID 0157

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: BUTYRIC ACID

Chinese Name:
Common Synonyms: N-Butyric Acid; Butanoic Acid; Ethylacetic Acid; Propylformic Acid
Chemical Family: Organic Acids
Formula: CH3CH2CH2COOH
Formula Wt.: 88.11
Cas No.: 107-92-6
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Honk Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 164 deg. C (327 deg. F) Vapor Pressure (mmHg): 0.84
(@ 760 mmHg) (20 deg. C)
Melting Point: -5 deg. C (23 deg. F) Vapor Density (Air=1): 3.0
(@ 760 mmHg)
Specific Gravity: 0.96 Evaporation Rate: .06
(H2O=1) (Butyl Acetate = 1)
Solubility(H2O): Complete (100%) % Volatiles By Volume: N/A
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless liquid. Suffocating odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 71 deg. C (160 deg. F)

Autoignition Temperature: N/A
Flammable Limits: Upper - 13.4 % Lower - 2.2 %
Fire Extinguishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire.

Toxic Gases Produced: carbon monoxide, carbon dioxide, hydrogen

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, sources of ignition
Incompatibles: Strong oxidizing agents, aluminum, most common metals, alkalies
Decomposition Products: Hydrogen, carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0157
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of mucous membranes, severe irritation of respiratory system, nausea

Skin Contact: Irritation, burns
Eye Contact: Irritation, burns
Skin Absorption: Rapid absorption
Ingestion: Irritation and burns to mouth and stomach
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Butyric Acid 2940 mg/kg
Intraperitoneal Mouse LD 50 For Butyric Acid 3180 mg/kg
Skin Rabbit LD 50 For Butyric Acid 530 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Eye contact, skin contact, ingestion, inhalation, absorption

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, if conscious, give large amounts of water. Induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Honk Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep vapor and mist levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a chemical
cartridge respirator with organic vapor cartridge is recommended. If concentration exceeds capacity of
cartridge respirator, a self-contained breathing apparatus is advised.

Eye/Skin Protection:
Safety goggles and face shield, uniform, protective suit, rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area or
cabinet.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0158

Material Safety Data Sheet

City University of Hong Kong

MSDS ACETALDEHYDE 0158

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Acetaldehyde

Chinese Name:
Common Synonyms: Ethanal; Ethyl Aldehyde; Acetic Aldehyde
Chemical Family: Aldehydes
Formula: CH3CHO
Formula Wt.: 44.05
CAS No.: 75-07-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: 20 deg. C (68 deg. F) Vapor Pressure (mmHg): 750
(@ 760 mmHg) (20 deg. C)
Melting Point: -124 deg. C (-191 deg. F) Vapor Density (Air=1): 1.52
(@ 760 mmHg)
Specific Gravity: 0.78 Evaporation Rate: 49
(H2O=1) (Butyl Acetate = 1)
Solubility(H2O): Complete (100%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Clear, colorless liquid. Pungent odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): -37 deg. C (-36 deg. F)

Autoignition Temperature: 174 deg. C (347 deg. F)
Flammable Limits: Upper - 60.0 % Lower - 4.0 %
Fire Extinquishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. Closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire. Rapid, uncontrolled polymerization can
cause fire or explosion. May form explosive peroxides, especially when heated.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: May occur
Conditions To Avoid: Heat, flame, other sources of ignition, air
Incompatibles:
Strong oxidizing agents, strong bases, amines and ammonia, strong acids, polymerization catalysts &
accelerators, acid anhydrides, alcohols, ketones, phenols, halogens, hydrogen cyanide, hydrogen sulfide

Decomposition Products: Carbon monoxide, carbon dioxide, explosive peroxides

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0158

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Irritation of mucous membranes, headache, nausea, vomiting, dizziness, drowsiness, narcosis, severe
irritation of respiratory system, pulmonary edema, unconsciousness

Skin Contact: Irritation, prolonged contact may cause dermatitis

Eye Contact: Severe irritation or burns, may cause temporary corneal damage
Skin Absorption: None identified
Ingestion:
Headache, nausea, vomiting, dizziness, gastrointestinal irritation, central nervous system depression,
severe burns to mouth, throat, and stomach, respiratory failure, unconsciousness

Chronic Effects: Central nervous system depression, damage to liver, kidneys, and blood

Threshold Limit Value (TLV/TWA): 180 mg/m3 (100 ppm)

Short-Term Exposure Limit (STEL): 270 mg/m3 (150 ppm)
Permissible Exposure Limit (PEL): 180 mg/m3 (100 ppm)
TOXICITY OF COMPONENTS:
Oral Rat LD 50 For Acetaldehyde 1930 mg/kg
Subcutaneous Rat LD50 For Acetaldehyde 640 mg/kg
Intravenous Mouse LD50 For Acetaldehyde 212 g/kg
Inhalation-4hr Mouse LC 50 For Acetaldehyde 1500 ppm
Carcinogenicity: NTP: No IARC: Yes Z LIST: No OSHA REG: No

Carcinogenicity: This substance is listed as an IARC animal carcinogen.

Reproductive Effects: Tests on laboratory animals indicate material may be mutagenic and teratogenic.
Target Organs: Respiratory system, lungs, skin, liver, kidneys, blood, central nervous system
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, if conscious, give large amounts of water. Induce vomiting.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.
Notes To Physician: Signs and symptoms of pulmonary edema can be delayed for several hours.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 1000
ppm, a chemical cartridge respirator with organic vapor cartridge is recommended. Above this level, a
self-contained breathing apparatus is recommended.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area.
Product must be refrigerated at 2 - 8 deg. C (36 - 46 deg. F). Isolate from incompatible materials.

Special Precautions: Bond and ground containers when transferring liquid.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0159

Material Safety Data Sheet

City University of Hong Kong

MSDS ALUMINUM OXIDE 0159

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Aluminum Oxide

Chinese Name:
Common Synonyms: Alumina
Chemical Family: Aluminum Compounds
Formula: Al 2O3
Formula Wt.: 101.96
CAS No.: 1344-28-1
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 2977 deg. C (5390 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 2030 deg. C (3686 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 4.00 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures: None identified.
Unusual Fire & Explosion Hazards: None identified.
Toxic Gases Produced: None identified

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: None identified
Decomposition Products: None identified

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Tightness and pain in chest, coughing, difficult breathing, excessive inhalation is irritating, may cause
respiratory tract ulcers

Skin Contact: Irritation

Eye Contact: Irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0159
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None Identified
Threshold Limit Value (TLV/TWA): 10 mg/m3
TLV Is For Aluminum, Metal And Oxides, As Al.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 10 mg/m3
The Pel For Aluminum Oxide Is Listed Under Alpha-Alumina, Total Dust.
Toxicity Of Components: No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: Lung disease
Primary Routes Of Entry: Inhalation, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
dust/mist respirator is recommended. If concentration exceeds capacity of respirator, a self-contained
breathing apparatus is advised.

Eye/Skin Protection: afety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0160

Material Safety Data Sheet

City University of Hong Kong

MSDS ALUMINUM SULFATE, 18-HYDRA 0160

CRYSTAL
========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Aluminum Sulfate, 18-Hydrate, Crystal

Chinese Name:
Common Synonyms: Cake Alum; Patent Alum
Chemical Family: Aluminum Compounds
Formula: Al2(SO4)3 18H2O
Formula Wt.: 666.42
CAS No.: 7784-31-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 86 deg. C (186 deg. F) Decomposes Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.62 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystalline solid. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: Note: decomposes at melting point.

Toxic Gases Produced: Sulfur dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture
Incompatibles: Most common metals
Decomposition Products: Oxides of sulfur, sulfuric acid

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0160
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Tightness and pain in chest, coughing, difficult breathing

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Nausea, vomiting, gastrointestinal irritation
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 2 mg/m3
TLV Is For Aluminum, Soluble Salts, As Al.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Mouse LD 50 For Aluminum Sulfate, 18-Hydrate 6207 mg/kg
Intraperitoneal Mouse LD 50 For Aluminum Sulfate, 18-Hydrate 270 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Ingestion, inhalation, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
dust/mist respirator is recommended. If concentration exceeds capacity of respirator, a self-contained
breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

=======================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0161

Material Safety Data Sheet

City University of Hong Kong

MSDS AMMONIUM CARBONATE 0161

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Ammonium Carbonate

Chinese Name:
Common Synonyms: Carbonic Acid, Ammonium Salt; Diammonium Carbonate
Chemical Family: Ammonium Salts
Formula: (NH4)2CO3
Formula Wt.: 96
CAS No.: 506-87-6
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): 2.7
Specific Gravity: 1.50 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White powder. Ammonia odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Ammonia, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat
Incompatibles: Strong acids, nitrates, nickel, copper
Decomposition Products: Ammonia, carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of nose and throat, tightness and pain in chest, coughing, difficult breathing
Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0161
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Intravenous Mouse LD50 For Ammonium Carbonate 96 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, nitrile gloves are recommended.

Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Store below 30 deg. C.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0162

Material Safety Data Sheet

City University of Hong Kong

MSDS AMMONIUM CHLORIDE 0162

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Ammonium Chloride

Chinese Name:
Common Synonyms: Sal Ammoniac
Chemical Family: Ammonium Salts
Formula: NH4Cl
Formula Wt.: 53.49
CAS No.: 12125-02-9
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 338 deg. C (640 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.53 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals or granules. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Ammonia, hydrogen chloride

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture, heat
Incompatibles:
Strong oxidizing agents, strong acids, strong bases, most common metals, bromine trifluoride and
trichloride, silver and silver compounds

Decomposition Products: Ammonia, hydrogen chloride

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0162
Skin Contact: Irritation, prolonged contact may cause dermatitis
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Nausea, vomiting, irritation and burns to mouth and stomach
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 10 mg/m3
Short-Term Exposure Limit (STEL): 20 mg/m3
Permissible Exposure Limit (PEL): 10 mg/m3
Toxicity Of Components:
Oral Rat LD 50 For Ammonium Chloride 1650 mg/kg
Intraperitoneal Mouse LD 50 For Ammonium Chloride 485 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
one required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
dust/mist respirator is recommended. If concentration exceeds capacity of respirator, a self-contained
breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Isolate from incompatible
materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0163

Material Safety Data Sheet

City University of Hong Kong

MSDS AMMONIUM SULFATE 0163

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Ammonium Sulfate

Chinese Name:
Common Synonyms: Sulfuric Acid, Diammonium Salt; Diammonium Sulfate
Chemical Family: Ammonium Salts
Formula: (NH4)2SO4
Formula Wt.: 132.14
CAS No.: 7783-20-2
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 280 deg. C (536 deg. F) Decomposes Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.77 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals or granules. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards:

Contact with strong oxidizers may cause fire or explosion. note: decomposes at melting point.

Toxic Gases Produced: Ammonia, sulfur dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat
Incompatibles: Strong oxidizing agents, copper, brass, bronze, strong acids
Decomposition Products: Ammonia, oxides of sulfur

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Prolonged contact may cause irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0163
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Gastrointestinal irritation
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Ammonium Sulfate 3000 mg/kg
Intraperitoneal Mouse LD 50 For Ammonium Sulfate 610 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Respiratory system, lungs
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Ingestion, inhalation, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, if conscious, give large amounts of water. induce vomiting.

Inhalation:
f inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
one required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, rubber gloves are Recommended.

Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Do not store near
oxidizing materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0166

Material Safety Data Sheet

City University of Hong Kong

MSDS BISMUTH TRICHLORIDE 0166

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Bismuth Trichloride

Chinese Name:
Common Synonyms: Bismuth (III) Chloride
Chemical Family: Bismuth Compounds
Formula: BiCl 3
Formula Wt.: 315.34
CAS No.: 7787-60-2
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 447 deg. C (836 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 227 deg. C (440 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 4.56 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Decomposes % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White to yellow crystals. Hydrochloric acid odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Hydrogen chloride

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture
Incompatibles: Water
Decomposition Products: Hydrogen chloride

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: None identified
Eye Contact: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0166
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: Kidney damage, liver damage
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None Indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a dust/mist
respirator is recommended. If concentration exceeds capacity of respirator, a self-contained breathing
apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, proper gloves arerecommended.

Storage Requirements: Keep container tightly closed. Store in secure poison area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0169

Material Safety Data Sheet

City University of Hong Kong

MSDS CALCIUM NITRATE, 4-HYDRATE 0169

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Calcium Nitrate, 4-Hydrate

Chinese Name:
Common Synonyms: Calcium (II) Nitrate, Tetrahydrate; Nitric Acid, Calcium Salt, Tetrahydrate
Chemical Family: Calcium Compounds
Formula: Ca(NO3)2 4H2O
Formula Wt.: 236.15
CAS No.: 13477-34-4
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 45 deg. C (113 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.82 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Strong oxidizer. Contact with combustible materials, flammable materials, or powdered metals can
cause fire or explosion. Can react violently with shock, friction or heat.

Toxic Gases Produced: Oxides of nitrogen

Explosion Data-Sensitivity To Mechanical Impact: Yes.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, shock
Incompatibles: Combustible materials, strong reducing agents, organic materials, ammonia
Decomposition Products: Oxides of nitrogen

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0169
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Gastrointestinal irritation, nausea, vomiting
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Calcium Nitrate, 4-Hydrate 3900 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Skin contact, eye contact, inhalation, ingestion

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, give large amounts of water. induce vomiting.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levelsas low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, uniform, butyl rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.

Special Precautions:
Do not expose to heat. Product melts at 45 deg. C (113 deg. F). Store/transport at or below 30 deg. C (86
deg. F).

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Keep combustibles (wood, paper,
oil, etc.) away from spilled material. With clean shovel, carefully place material into clean, dry
container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 170

Material Safety Data Sheet

City University of Hong Kong

MSDS CALCIUM OXIDE 0170

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Calcium Oxide

Chinese Name:
Common Synonyms: Lime; Calx; Quicklime; Calcium Monoxide; Burnt Lime
Chemical Family: Calcium Compounds
Formula: CaO
Formula Wt.: 56.08
CAS No.: 1305-78-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 2850 deg. C (5162 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 2572 deg. C (4661 deg. F) Vapor Density (Air=1): 1.9
(@ 760 mmHg)
Specific Gravity: 3.34 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White to gray solid. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures: None identified.
Unusual Fire & Explosion Hazards:
Contact with moisture or water may generate sufficient heat to ignite combustible materials.

Toxic Gases Produced: None identified

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture, air
Incompatibles: Water, fluorine, strong acids
Decomposition Products: None identified

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Tightness and pain in chest, coughing, difficult breathing

Skin Contact: Severe irritation or burns
Eye Contact: Severe irritation or burns
Skin Absorption: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 170
Ingestion: Irritation and burns to mouth and stomach
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 2 mg/m3
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 5 mg/m3
Toxicity Of Components: No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Respiratory system, lungs, kidneys, prostate, blood
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give large amounts of water.
Follow with diluted vinegar, fruit juice or whites of eggs beaten with water.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Skin contact: in case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 11 ppm,
a dust/mist respirator is recommended. Above this level, a self-contained breathing apparatus is
advised.

Eye/Skin Protection: Safety goggles, uniform, rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Store in a dry area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0171

Material Safety Data Sheet

City University of Hong Kong

MSDS CALCIUM, TURNINGS 0171

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Calcium, Turnings

Chinese Name:
Common Synonyms: N/A
Chemical Family: Metals
Formula: Ca
Formula Wt.: 40.08
CAS No.: 7440-70-2
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 850 deg. C (1562 deg. F) Vapor Density (Air=1): 1.4
(@ 760 mmHg)
Specific Gravity: 1.57 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Silvery-white crystals.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Smother with dry soda ash. Never use water or chemical fire extinguishers.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move exposed containers from fire area, if it can be done
without risk. Use water to keep fire exposed containers cool; do not get water inside containers.

Unusual Fire & Explosion Hazards: Reacts violently with water liberating and igniting hydrogen.
Toxic Gases Produced: None identified

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture, heat, flame, other sources of ignition
Incompatibles: Water
Decomposition Products: None identified

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: Severe irritation or burns
Eye Contact: Severe irritation or burns

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0171
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a dust/mist
respirator is recommended. If concentration exceeds capacity of respirator, a self-contained breathing
apparatus is advised.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Storage Requirements:
Keep container tightly closed. Store in cool, dry, well-ventilated area away from heat, sparks, or flame.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Shut off ignition sources; no flares, smoking, or flames in area. With
clean shovel, carefully place material into clean, dry container and cover; remove from area. Flush spill
area with water. Do not put any water on leak or spills.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0172

Material Safety Data Sheet

City University of Hong Kong

MSDS CITRIC ACID 0172

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Citric Acid Anhydrous

Chinese Name:
Chemical Family: Organic Acid
Molecular Formula: HOC(CH2CO2H)2CO2H
C.A.S. : 77-92-9
Product Use:
Preparation of citrates, flavouring extracts, confections, soft drinks, effervescent salts, acidifier,
dispersing agent, medicines, acidulant and anti oxidant in foods, sequestering agent, water conditioning
agent, detergent builder, cleaning and polishing stainless steel and other metals, alkyd resins, mordant,
removal of sulfur dioxide from smelter waste gases, abscission of citrus fruit in harvesting, cultured
dairy products.

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Odour And Appearance: White crystals, odourless.
Odour Threshold: Not available
Vapour Pressure: Not applicable Vapour Density: Not applicable
Evaporation Rate: Not applicable pH: of 0.1 N solution is 2.2
Boiling Point: Not applicable Melting Point: 153 deg. C
Solubility In Water: 60% at 20 deg. C Soluble Molecular Weight: 192.14
Specific Gravity: 1.665 Volatile By Volume: Not applicable
Bulk Density: 1.665
Coefficient Of Water/Oil Distribution: Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Conditions Of Flammability: Not applicable

Flash Point: Nonflammable
Upper Flammable Limit: Not available
Lower Flammable Limit: Not available
Auto Ignition Temperature: Not available
Hazardous Combustion Products: Not available
Special Fire Fighting Procedures:
Firefighters should wear the usual protective gear; self-contained breathing apparatus.
Explosion Hazards: Not available

========================================================================
REACTIVITY DATA
========================================================================

Stability: Very stable

Hazardous Polymerization: Will not occur
Incompatibility: Alkali metals, organic acids, oxides of sulphur, strong bases.
Hazardous Reactions/Decompositions: Carbon monoxide, carbon dioxide.
Conditions To Avoid: Contact with incompatibles.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0172
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Dust may irritate the nose and throat.

Skin Contact: May cause irritation.
Eye Contact: May cause eye irritation.
Ingestion: Irritation of mucous membranes. May cause gastrointestinal irritation.
Chronic Exposure Effects:
Non-toxic, non-volatile, non-hazardous nuisance dust symptoms, low risk allergen.

Exposure Limits: Not available Irritancy: See above

Mutagenicity: None known Carcinogenicity: None known
Sensitization To Product: Not available
Reproductive Toxicity: None known
Toxicologically Synergistic Materials: None known
Teratogenicity Data: Not available
Animal Toxicity Data: LD50,Route,Specie 6730 mg/kg,oral,rats
LC50,Route,Specie not available

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call Physician.

Skin Contact:
Immediately flush skin with water for 15 min. Remove contaminated clothing. Seek medical attention.

Eye Contact: Immediately flush eyes with water for 15 min. Call physician.
Ingestion: Give large quantities of water or milk. Call physician.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection: Wear dust mask.

Skin Protection: Wear impervious protective clothing.
Eye/Face Protection: Chemical goggles.
Special Handling Procedures: Avoid all skin contact
Storage Requirements:Keep containers closed when not in use. Store in a cool and Well ventilated area.
Engineering Controls: Ventilate adequately.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps In The Event Of A Leak Or Spill:

Contain the spill. Pick up solids and place in a tightly sealed container.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0173

Material Safety Data Sheet

City University of Hong Kong

MSDS LEAD DIOXIDE 0173

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Lead Dioxide

Chinese Name:
Common Synonyms: Lead (IV) Oxide; Lead Peroxide; Lead Brown; Lead Oxide Brown
Chemical Family: Lead Compounds
Formula: PbO2
Formula Wt.: 239.19
CAS No.: 1309-60-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): 8.2
Specific Gravity: 9.38 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Dark brown powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Strong oxidizer. Contact with combustible materials, flammable materials, or powdered metals can
cause fire or explosion. Can react violently with shock, friction or heat.

Toxic Gases Produced: Lead fumes

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Shock, friction, heat
Incompatibles: Strong reducing agents, combustible materials, organic materials, chemically active
metals
Decomposition Products: Lead Fumes

========================================================================
HEALTH HAZARD DATA
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0173
Inhalation: Irritation of upper respiratory tract
Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion:
Headache, nausea, vomiting, gastrointestinal irritation, convulsions, unconsciousness, and may be fatal

Chronic Effects: Anemia, kidney damage, blurred vision, lead build-up in the central nervous system

Threshold Limit Value (TLV/TWA): 0.15 mg/m3

TLV Is For Lead, Inorganic Dusts And Fumes, As Pb.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 0.05 mg/m3
PEL Is For Lead, Inorganic Dusts And Fumes, As Pb.
Toxicity Of Components:
Intraperitoneal Guinea Pig LD 50 For Lead Dioxide 220 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: YES

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Gi tract, central nervous system, gingival tissue, kidneys, blood
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
one required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
high-efficiency particulate respirator is recommended. If concentration exceeds capacity of respirator, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, butyl rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.
Isolate from incompatible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Keep combustibles (wood, paper,
oil, etc.) away from spilled material. With clean shovel, carefully place material into clean, dry
container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0177

Material Safety Data Sheet

City University of Hong Kong

MSDS PARAFFIN OIL 0177

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Paraffin Oil

Chinese Name:
Common Synonyms: Mineral Oil; White Mineral Oil; Nujol
Chemical Family: Oils
Formula: N/A
Formula Wt.: N/A
CAS No.: 8012-95-1
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Liquid
Boiling Point: N/A Vapor Pressure (mmHg): <0.5
(20 deg. C)
Melting Point: -18 deg. C (-0 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 0.88 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Clear, colorless viscous liquid. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 215 deg. C (420 deg. F)

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame
Incompatibles: Strong oxidizing agents, chlorine
Decomposition Products: Carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0177
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Irritation of mucous membranes, headache, nausea, vomiting, dizziness, drowsiness, irritation of upper
respiratory tract, unconsciousness

Skin Contact: Prolonged contact may cause irritation

Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Nausea, vomiting, diarrhea
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 5 mg/m3
TLV Is For Oil Mist, Mineral.
Short-Term Exposure Limit (STEL): 10 mg/m3
STEL Is For Oil Mist, Mineral.
Permissible Exposure Limit (PEL): 5 mg/m3
PEL Is For Oil Mist, Mineral.
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Respiratory system, lungs, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 250
mg/m3, a high-efficiency particulate respirator is recommended. Above this level, a self-contained
breathing apparatus is advised.

Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Do not store near
oxidizing materials.

Special Precautions: Product may solidify at room temperature.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Take up with sand or other non-combustible absorbent material and
place into container for later disposal. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0178

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM BROMATE 0178

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Potassium Bromate

Chinese Name:
Common Synonyms: Bromic Acid, Potassium Salt
Chemical Family: Potassium Compounds
Formula: KBrO3
Formula Wt.: 167.00
CAS No.: 7758-01-2
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 434 deg. C (813 deg. F) Decomposes Vapor Density (Air=1): 5.80
(@ 760 mmHg)
Specific Gravity: 3.27 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Moderate (1-10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals or granules. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Strong oxidizer. Contact with combustible materials, flammable materials, or powdered metals can
cause fire or explosion. Closed containers exposed to heat may explode.

Toxic Gases Produced: Hydrogen bromide

Explosion Data-Sensitivity To Mechanical Impact: Yes.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, shock, dusting
Incompatibles:
Aluminum, organic materials, combustible materials, strong reducing agents, ammonium salts, sulfuric
acid, strong acids

Decomposition Products: Hydrogen bromide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0178
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: May cause irritation
Eye Contact: May cause irritation
Skin Absorption: None identified
Ingestion: Nausea, vomiting, headache, dizziness, gastrointestinal irritation
Chronic Effects: Kidney Damage, Liver Damage
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Potassium Bromate 321 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Kidneys, liver
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Ingestion, inhalation, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, butyl rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Keep combustibles (wood, paper, oil, etc.) away from spilled
material. With clean shovel, carefully place material into clean, dry container and cover; remove from
area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0180

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM DICHROMATE 0180

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Potassium Dichromate

Chinese Name:
Common Synonyms: Dichromic Acid, Dipotassium Salt; Bichromate Of Potash
Chemical Family: Chromium Compounds
Formula: K2Cr2O7
Formula Wt.: 294.19
CAS No.: 7778-50-9
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 500 deg. C (932 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 398 deg. C (748 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.67 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: 3.6 (10% solution)
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Orange to red crystals. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained Breathing apparatus with full
facepiece operated in positive pressure Mode. Move containers from fire area if it can be done without
risk. Use Water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Strong oxidizer. Contact with combustible materials, flammable materials, or powdered metals can
cause fire or explosion. Note: decomposes at boiling point.

Toxic Gases Produced: None identified

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat
Incompatibles: Combustible materials, organic materials, strong reducing agents, strong acids
Decomposition Products: Chromium oxide fumes

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0180
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Severe irritation of respiratory system, prolonged contact may cause perforated septum
Skin Contact: Irritation, prolonged contact may cause dermatitis, and ulceration
Eye Contact: Severe irritation or burns
Skin Absorption: Is harmful and may be fatal
Ingestion: Severe burns, ulceration - mouth, throat, stomach, and may be fatal
Chronic Effects: Damage to liver, kidneys, blood, lungs
Threshold Limit Value (TLV/TWA): 0.05 mg/m3
TLV is for chromium (VI) compounds, water soluble, as Cr.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 0.1 mg/m3
PEL (ceiling) is for chromic acid and chromates, as CrO3.
Toxicity Of Components:
Intraperitoneal Mouse LD 50 For Potassium Dichromate 37 mg/kg
Carcinogenicity: NTP: Yes IARC: Yes Z LIST: No OSHA REG: No

Carcinogenicity:
This substance is listed as a NTP human carcinogen and an IARC human carcinogen (group 1).

Reproductive Effects: None identified.

Target Organs: Blood, respiratory system, lungs, liver, kidneys, eyes, skin, gi tract
Medical Conditions Generally Aggravated By Exposure: Damaged skin
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact, absorption

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, give large amounts of water. induce vomiting.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact:
In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
A respirator with dust/mist filter is recommended. If airborne concentration exceeds TLV, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Keep combustibles (wood, paper,
oil, etc.) Away from spilled material. With clean shovel, carefully place material into clean, dry
container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0181

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM FERRICYANIDE 0181

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Potassium Ferricyanide

Chinese Name:
Common Synonyms: Potassium Hexacyanoferrate (III)
Chemical Family: Iron Compounds
Formula: K3Fe(CN) 6
Formula Wt.: 329.26
CAS No.: 13746-66-2
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: 1.89 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Orange to red crystals. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Cyanides

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Light, heat
Incompatibles: Ammonia, chromic acid, strong acids
Decomposition Products: Cyanides

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0181
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 5 mg/m3
TLV (Skin) Is For Cyanides, As CN.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 5 mg/m3
PEL Is For Cyanides, As CN.
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Keep container tightly closed. Suitable for any general chemical storage area. Store in light-resistant
containers.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0182

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM FERROCYANIDE 0182

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Potassium Ferrocyanide,

Chinese Name:
Synonyms: Tetra Potassium Hexacyanoferrate (II)
Chemical Family: Inorganic Salt
Chemical Formula: K4Fe(CN) 6.3H2O
CAS No. : 13943-58-3
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odour and Appearance: Lemon yellow crystals or powder; odourless
Odour Threshold (ppm): Not applicable
Vapour Pressure (mmHg): Not applicable
Vapour Density (Air=1): Not applicable
Evaporation Rate: Not applicable
Boiling Point : Decomposes
Melting Point : Not available
pH: Not Available
Specific Gravity: 1.850
Coefficient of Water/Oil distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flammability: Nonflammable
Extinguishing Media: Use an extinguisher appropriate to the surrounding material that is burning.
Flash Point (Method Used): Not applicable
Autoignition Temperature: Not applicable
Upper Flammable Limit (% by volume): Not applicable
Lower Flammable Limit (% by volume): Not applicable
Hazardous Combustion Products: Toxic fumes of cyanides

========================================================================
REACTIVITY DATA
========================================================================

Chemical Stability: Normally stable

Incompatibility with other substances: NH3, CrO3, NaNO2, acids and acid fumes
Reactivity: Cyanides plus heat
Hazardous Decomposition Products:
Highly toxic fumes of cyanides, oxides of carbon, nitrogen and potassium.

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhaled: Sore throat, coughing

In contact with skin: Causes irritation
In contact with eyes: Causes irritation
Ingested:
Moderately toxic via oral route. This material is not as powerful a poison as the simple cyanides.

LD50: Not available

LC50: Not available
Carcinogenicity: Not a carcinogen.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0182
Teratogenicity: No information available
Reproductive Effects: No information available
Mutagenicity: No information available
Synergistic Products: None known

========================================================================
FIRST AID MEASURES
========================================================================

Eyes:
Wash eyes with plenty of water for at least fifteen (15) minutes, holding eyelids open. Seek medical
attention.

Skin:
Remove any contaminated clothing. Wipe off excess from skin. Wash skin with soap and water for at
least fifteen (15) minutes. Unless contact has been Slight, seek medical attention if irritation persists.

Inhalation:
Remove patient to fresh air. Give artificial respiration if not breathing. Seek immediate medical
attention.

Ingestion:
Never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing.
Rinse mouth thoroughly with water. Do not induce vomiting. Have victim drink 200-400 ml of water to
dilute. Seek medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls: Local exhaust ventilation recommended

Respiratory Protection:
Dust mask. Self-contained breathing apparatus. An approved respirator may be adequate-refer to CSA
Standard Z94.4-M1982 Selection Care, and use respirators.

Eye Protection:
Chemical safety goggles or face shield as appropriate.Skin Protection: Gloves, rubber or plastic

Other Personal Protective Equipment: Plastic apron, sleeves and boots as appropriate.
Handling Procedures and Equipment: Avoid generating dust. Follow routine safe handling procedures.
Storage Requirements:
Store in suitable labelled containers, in a cool, dry well ventilated area. Keep containers tightly closed
when not in use and when empty. Protect from damage, and also from light.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Leak And Spill Procedure:

Before dealing with spillages take necessary protective measures. Shovel carefully into container and
arrange removal by disposal company. Wash site of spillage thoroughly with water and detergent.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0184

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM NITRATE 0184

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Potassium Nitrate

Chinese Name:
Common Synonyms: Saltpeter; Nitric Acid, Potassium Salt
Chemical Family: Potassium Compounds
Formula: KNO3
Formula Wt.: 101.11
CAS No.: 7757-79-1
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 334 deg. C (633 deg. F) Vapor Density (Air=1): 3.00
(@ 760 mmHg)
Specific Gravity: 2.11 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystalline powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Strong oxidizer. Contact with combustible materials, flammable materials, or powdered metals can
cause fire or explosion. Closed containers exposed to heat may explode.

Toxic Gases Produced: Oxides of nitrogen

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat
Incompatibles: Organic materials, combustible materials, strong reducing agents
Decomposition Products: Oxides of nitrogen

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0184
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract, irritation of mucous membranes.

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Nausea, vomiting, diarrhea
Chronic Effects: Bladder, central nervous system depression
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rabbit LD 50 For Potassium Nitrate 1901 mg/kg
Oral Rat LD 50 For Potassium Nitrate 3750 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Blood, central nervous system
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, butyl rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Keep combustibles (wood, paper, oil, etc.) Away from spilled
material. With clean shovel, carefully place material into clean, dry container and cover; remove from
area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0185

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM NITRATE, CRYSTAL 0185

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Sodium Nitrate, Crystal

Chinese Name:
Common Synonyms: Sodium (I) Nitrate; Nitric Acid, Sodium Salt; Soda Niter; Chile Saltpeter
Chemical Family: Inorganic Sodium Compounds
Formula: NaNO3
Formula Wt.: 84.99
CAS No.: 7631-99-4
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 306 deg. C (582 deg. F) Vapor Density (Air=1): 2.90
(@ 760 mmHg)
Specific Gravity: 2.26 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless crystals or powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Strong oxidizer. Contact with combustible materials, flammable materials, or powdered metals can
cause fire or explosion. Can react violently with shock, friction or heat.

Toxic Gases Produced: Oxides of nitrogen

=======================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Shock, friction, heat
Incompatibles: Cyanides, combustible materials, organic materials, strong reducing agents, aluminum
Decomposition Products: Oxides of nitrogen

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0185
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Irritation of upper respiratory tract, cyanosis, unconsciousness, headache, nausea, vomiting, dizziness,
weakness, rapid ineffective breathing, low blood pressure, convulsions

Skin Contact: Irritation, prolonged contact may cause dermatitis

Eye Contact: Irritation
Skin Absorption: None identified
Ingestion:
Gastrointestinal irritation, cyanosis, unconsciousness, headache, nausea, vomiting, dizziness, weakness,
rapid ineffective breathing, low blood pressure, convulsions

Chronic Effects: None identified

Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, butyl rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Keep combustibles (wood, paper, oil, etc.) Away from spilled
material. With clean shovel, carefully place material into clean, dry container and cover; remove from
area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0186

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM THIOSULFATE, 5-HYDRATE 0186

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Sodium Thiosulfate, 5-Hydrate

Chinese Name:
Common Synonyms: Sodium Thiosulfate, Pentahydrate; Sodium Hyposulfite, 5-Hydrate
Chemical Family: Inorganic Sodium Compounds
Formula: Na 2S2O3 5H2O
Formula Wt.: 248.18
CAS No.: 10102-17-7
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 48 deg. C (118 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.69 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals or powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Sulfur dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat
Incompatibles: Iodine, strong acids, mercury, strong oxidizing agents, sodium, potassium
Decomposition Products: Oxides of sulfur

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Prolonged contact may cause irritation
Eye Contact: Irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0186
Skin Absorption: None identified
Ingestion: Gastrointestinal irritation
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Intraperitoneal Mouse LD 50 For Sodium Thiosulfate, 5-Hydrate 5600 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Then induce
vomiting.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Isolate from incompatible
materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0188

Material Safety Data Sheet

City University of Hong Kong

MSDS AGAR AGAR 0188

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Agar Agar

Chinese Name:
Common Synonyms: Polysaccharide Complex
Chemical Family: Natural Products
Formula: N/A
Formula Wt.: N/A
CAS No.: 9002-18-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: N/A Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White to light yellow crystalline powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture
Incompatibles: Strong oxidizing agents
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): Not established

Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0188
Toxicity Of Components:
Oral Rat LD 50 For Agar Agar 11 g/kg
Oral Mouse LD 50 For Agar Agar 16 g/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Effects Of Overexposure:
Inhalation: None identified
Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified

Target Organs: None identified

Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None Indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0189

Material Safety Data Sheet

City University of Hong Kong

MSDS Aluminum Granules 0189

========================================================================
PRODUCT INFORMATION
========================================================================

Material Name: Aluminum Granules

Chinese Name:
CAS NO.: 7429-90-5

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance & Odor: Silvery - gray

Boiling point (Approx.): 2630°C
Evaporation rate: N.A.
Vapor pressure: 1 mm at 20°C
Specific gravity (H2O=1): 2.7

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Water solubility %: Insoluble
Melting point: 660°C
Vapor density (air=1): N.A.
% Volatile by volume: N.A.
Molecular weight: 26.98

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Flash point & method: N.A.

Lower explosion limit: 590°C
Upper explosion limit: 45 mg/L
Extinguishing media:
Dry sand, dry inert granular material or powder, or dry powder extinguishing agent.

========================================================================
REACTIVITY DATA
========================================================================

Material is stable. Hazardous polymerization will not occur.

CHEMICAL INCOMPATIBILITIES:
Acids, strong Alkalies, strong bases, Silver Chloride, Iodates, Chlorinated Hydrocarbons, Oxides,
Nitrates, Nitrites, Carbon Disulfide, Chlorides, Sodium Peroxide plus CO2, Sulfur Dichloride,
Palladium, Manganese, Magnesium plus Potassium Chlorate, Sodium Carbonate, Sulfates,
Diborane.

HAZARDOUS DECOMPOSITION PRODUCTS:

Corrodes rapidly in contact with may other metals. Reacts with water, acids, and caustic alkalies
evolving flammable hydrogen gas. May form explosive mixtures with oxidizing agents.

CONDITIONS TO AVOID:
Improper storage which would allow introduction of water and, or foreign matter.

========================================================================
HEALTH HAZARD DATA
========================================================================

This product is not considered a carcinogen.

TARGET ORGANS: Eyes, skin, lungs, mucous membranes, central nervous system, gastrointestinal.
PRIMARY ENTRY ROUTE(S): Inhalation, skin or eye contact, ingestion.
ACUTE EFFECTS:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0189
Aluminum powder is an eye and mucous membrane irritant. Chronic inhalation may affect the
respiratory system and result in aluminum pneumoconiosis and pulmonary fibrosis. Membrane and
upper respiratory tract irritation may result from liberation of acid by hydrolysis.

Excessive level of aluminum in the brain has been associated with senility and Alzheimer's disease.

========================================================================
FIRST AID MEASURES
========================================================================

EYE CONTACT:
Immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper
lids. Get medical attention immediately. Contact lenses should not be worn when working with this
chemical.

SKIN CONTACT:
Immediately flush contaminated skin with water. Get medical attention promptly.

INHALATION:
Move the person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep
the affected person warm and at rest. Get medical attention as soon as possible.

INGESTION: If this chemical is ingested, do not induce vomiting. Seek

========================================================================
PREVENTATIVE MEASURES
========================================================================

PERSONAL PROTECTIVE EQUIPMENT: Flame resistant coverall.

GOGGLES: Safety goggles with side shields.
GLOVES: Required
RESPIRATOR: Dust mask, use in well-ventilated areas.
WORKPLACE CONSIDERATIONS:
Sufficient ventilation, in volume and pattern, should be provided to keep air contamination below
current applicable OSHA permissible exposure limits.

SPECIAL HANDLING:
Keep away from water. Store in cool, dry area. Keep sources of ignition away. Handle only with
non-sparking, non-static implements.

========================================================================
ENVIRONMENTAL PROTECTION DATA

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================

SPILL/LEAK PROCEDURES:
Sweep spill gently to avoid dust cloud formation. Use only non-sparking, non-static generating
implements. DO NOT USE WATER. Have sand pails available. Keep spill from contaminating
water sources and sewers.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0190

Material Safety Data Sheet

City University of Hong Kong

MSDS ZINC SULFATE, 7-HYDRATE 0190

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Zinc Sulfate, 7-Hydrate

Chinese Name:
Common Synonyms: N/A
Chemical Family: Zinc Compounds
Formula: ZnSO4 7H2O
Formula Wt.: 287.56
CAS No.: 7446-20-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 100 deg. C (212 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.97 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless crystalline powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Sulfur dioxide, zinc fumes

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, moisture
Incompatibles: Water
Decomposition Products: Oxides of sulfur, oxides of zinc

========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): Not established

Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0190
Toxicity Of Components: No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Inhalation: None identified
Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Gastrointestinal pain
Chronic Effects: None identified
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure:None identified
Primary Routes Of Entry: Ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0191

Material Safety Data Sheet

City University of Hong Kong

MSDS ALUMINUM AMMONIUM SULFATE, 0191

12-HYDRATE
========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Aluminum Ammonium Sulfate, 12-Hydrate

Chinese Name:
Common Synonyms: Ammonium Alum
Chemical Family: Aluminum Compounds
Formula: AlNH4(SO4)2 12H2O
Formula Wt.: 453.33
CAS No.: 7784-26-1
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 94 deg. C (201 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.65 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Ammonia, sulfur dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: None identified
Decomposition Products: Ammonia, oxides of sulfur

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0191
========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): Not established

Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Aluminum Ammonium Sulfate 2750 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Effects Of Overexposure:
Inhalation: None identified
Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified

Target Organs: None identified

Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0192

Material Safety Data Sheet

City University of Hong Kong

MSDS FERROUS AMMONIUM SULFATE, 0192

6-HYDRATE
========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Ferrous Ammonium Sulfate, 6-Hydrate

Chinese Name:
Common Synonyms: Ammonium Iron (II) Sulfate, Hexahydrate
Chemical Family: Iron Compounds
Formula: Fe(NH4)2(SO4)2 6H2O
Formula Wt.: 392.14
CAS No.: 7783-85-9
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): >1.0
Specific Gravity: 1.86 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Slight (0.1-1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Light blue-green solid. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Use water to keep fire-exposed containers cool. Move
exposed containers from fire area, if it can be done without risk.

Unusual Fire & Explosion Hazards: Closed containers exposed to heat may explode.
Toxic Gases Produced: Ammonia, oxides of nitrogen, sulfur dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Light
Incompatibles: Sulfuric acid
Decomposition Products: Oxides of sulfur, oxides of nitrogen, ammonia

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0192
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established

Toxicity Of Components:
Oral Rat LD 50 For Ferrous Ammonium Sulfate 3250 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Store in light-resistant
containers.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0193

Material Safety Data Sheet

City University of Hong Kong

MSDS FERRIC AMMONIUM SULFATE, 0193

12-HYDRATE
========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Ferric Ammonium Sulfate, 12-Hydrate

Chinese Name:
Common Synonyms: Ammonium Iron (III) Sulfate, Dodecahydrate; Ferric Alum; Iron Alum
Chemical Family: Iron Compounds
Formula: FeNH4(SO4)2 12H2O
Formula Wt.: 482.19
CAS No.: 7783-83-7
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 40 deg. C (104 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.71 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Light purple crystals. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained Breathing apparatus with full
facepiece operated in positive pressure Mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Sulfur dioxide, ammonia

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat
Incompatibles: None identified
Decomposition Products: Ammonia, oxides of sulfur

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0193
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 1 mg/m3
TLV Is For Iron Salts, Soluble, As Fe.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 1 mg/m3
PEL Is For Iron Salts, Soluble, As Fe.
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
dust/mist respirator is recommended. If concentration exceeds capacity of respirator, a self-contained
breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0196

Material Safety Data Sheet

City University of Hong Kong

MSDS BROMOTHYMOL BLUE 0196

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Bromothymol Blue

Chinese Name:
Common Synonyms: 3',3"-Dibromothymolsulfonphthalein
Chemical Family: Dyes, Stains, And Indicators
Formula: C27H28Br2O5S
Formula Wt.: 624.39
CAS No.: 76-59-5
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 200 deg. C (392 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: N/A Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Pink to purple powder.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Sulfur dioxide, hydrogen bromide, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: Strong oxidizing agents
Decomposition Products: Oxides of sulfur, hydrogen bromide, carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0196
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Eye/Skin Protection:
This is a laboratory-use product for which no industrial protective equipment has been designated.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0197

Material Safety Data Sheet

City University of Hong Kong

MSDS CALCIUM CARBONATE (Limestone) 0197

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Calcium Carbonate (Limestone)

Chinese Name:
CAS #: 1317-65-3
Chemical Formula: CaCO3
Product Uses: Mineral filler and pigment

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Density: 2.7 g/ml

Solubility in Water; 1.3 mg/100 g @ 18 deg. C
Appearance and Odor: White powder, no odor

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point: Non-Flammable

Unusual Fire and Explosion Hazards: None
Special Firefighting Procedures: None

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Reactivity in Water: None
Hazardous Decomposition Products: None
Hazardous Polymerization: Will not occur
Incompatibility (Materials to Avoid): Reacts with strong acid to liberate carbon dioxide.

========================================================================
HEALTH HAZARD DATA
========================================================================

Effects And Hazards Of Acute Exposure:

Inhalation:
Can be irritating to the respiratory tract. Symptoms include sneezing and slight nose irritation.

Eye Contact: Mild irritation. Symptoms include watering and irritation.

Skin Contact: Can be irritating to the skin. Symptoms include redness and irritation.

Ingestion:
Ingestion of very large quantities may result in intestinal obstruction and/or constipation. Considered to
be of very low toxicity.

Effects And Hazards Of Chronic Exposure:

There are no reported health effects associated with repeated or prolonged Exposure to pure calcium
carbonate.

If this is crystalline silica (quartz) present in the calcium carbonate, Exposure to airborne concentrations
may increase the risk of developing a Disabling lung disease called silicosis.

This product contains crystalline silica as a minor impurity; it is present At the 0.5% to 3.5% level,
depending on the product and the lot. Crystalline Silica has been reviewed by IARC and they have found
limited evidence for Pulmonary carcinogenicity in humans.

This product itself, calcium carbonate, is not listed as a carcinogen by OSHA, NTP, or IARC.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0197

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove source of contamination or move victim to fresh air. Obtain medical Advice if required.

Eye Contact:
Immediately flush the contaminated eye(s) with lukewarm, gently flowing Water, for 10 minutes, by the
clock, holding the eyelid(s) open. If Irritation persists, obtain medical advice immediately.

Skin Contact:
If irritation occurs, flush area with lukewarm, gently running water for at least 10 minutes. If irritation
persists, obtain medical advice immediately.

Ingestion:
Never give anything by mouth if victim is rapidly losing consciousness or is Unconscious or convulsing.
Rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 8 to 10 oz. (240
to 300 ml) of water to dilute Material in stomach. Obtain medical advice immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Handling:
When there is large-scale use of this material, engineering control methods To reduce exposures may be
necessary. Use local exhaust ventilation and Process enclosure to control airborne dust. A dust
collecting system attached To the ventilation system may also be necessary. Supply sufficient
Replacement air to make up for air removed by exhaust systems. If engineering controls and work
practices are not effective in controlling exposure to this material, then wear suitable personal protective
equipment including NIOSH or OSHA approved dust respirators.

Storage Conditions: Store in closed containers in a dry place separate from incompatible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill And Leak Procedures:

Respiratory protection should be worn by those in cleanup operations to Protect from airborne dust.
Measures should be taken to reduce airborne dust during cleanup operations.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0198

Material Safety Data Sheet

City University of Hong Kong

MSDS CALCIUM CHLORIDE 0198

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Calcium Chloride

Chinese Name:
Synonym(S): High Test Fines, High Test Powder, 77%
Chemical Family: Inorganic Salt
Molecular Formula: CaCl 2
Product Use: Industrial uses, drilling mud additive, workover fluids, completion fluids.

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid.

Odour And Appearance: Odourless white to off white grains.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odour Threshold: Not applicable.
Vapour Pressure: 0.005 mmHg, at 20 deg. C.
Vapour Density: Not applicable. Evaporation Rate: Not applicable.
pH: Of aqueous solution >7. Boiling Point: 815 deg. C.
Solubility In Water: Very soluble.
Specific Gravity: 2.2 % Volatile By Volume: ~ 0

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Conditions Of Flammability: Not applicable.

Means Of Extinguishing: Use water, dry chemical or carbon dioxide
Flash Point: Not applicable.
Upper Flammable Limit: Not applicable.
Lower Flammable Limit: Not applicable.
Special Fire Fighting Procedures:
Wear self-contained breathing apparatus when fighting large fires. Combustion produces toxic fumes.

Explosion Hazards: Explosion when mixed with Furan 2 - Peroxy - Carboxylic Acid.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Very stable.

Hazardous Polymerization: Will not occur
Incompatibility: None.
Hazardous Decomposition Products: Combustion produces toxic fumes.
Conditions To Avoid: Heat, open flames, metal will corrode in aqueous solutions of calcium chloride.

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Dust may cause irritation to upper respiratory tract.

Skin Contact: Prolonged exposure may cause skin irritation or burns.
Eye Contact: May cause severe irritation with corneal injury, which may be slow to heal.
Ingestion: Large ingestions may cause gastro-intestinal irritation or ulcerations.
Chronic Exposure Effects: Overexposure to calcium chloride can led to stomach disturbances.
Exposure Limits: Nuisance particulate level of 10 mg/m3.
Irritancy: Slight.
Mutagenicity: Not available
Carcinogenicity: Not regulated.
Sensitization To Product: Not available.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0198
Reproductive Toxicity: Not available.
Animal Toxicity Data:
LD50 - 1090 1668 mg/kg oral, rat.
- 123 mg Sr/kg intravenous, rat

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. Give artificial respiration if necessary. Seek medical attention if irritation persists.

Eye And Skin Contact:

Immediately flush eyes and/or skin with water. Remove contaminated clothing. Seek medical attention if
irritation persists.

Ingestion:
Give large quantities of milk or water. Never give anything by mouth to an unconscious person. Seek
medical attention if irritation persists.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection: Dusty atmospheres require approved NIOSH dust respirator.

Eye And Face Protection:
Safety goggles or chemical goggles in very dusty atmospheres. Eye wash fountain should be located in
immediate work area. In these conditions do not wear contact lenses.

Protective Clothing: Impervious clothing suitable to task, normal work clothing usually sufficient
Storage Requirements:
Store in a dry location. Prolonged storage may cause product to cake and become wet from atmospheric
moisture.

Engineering Controls: General and/or local exhaust to control airborne dust.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Procedures To Be Followed In Case Of A Leak Or Spill:

Shovel and sweep up spill and place in a container with a cover. Flush Residue with large amounts of
water. Keep contaminated water from entering Sewers and water courses.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0199

Material Safety Data Sheet

City University of Hong Kong

MSDS CALCIUM ACETATE, POWDER 0199

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Calcium Acetate, Powder

Chinese Name:
Common Synonyms: N/A
Chemical Family: Calcium Compounds
Formula: (CH3COO)2Ca
Formula Wt.: 158.17
CAS No.: 5743-26-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: 1.50 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame
Incompatibles: Strong oxidizing agents
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of mucous membranes

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Ingestion of large quantities may cause gastrointestinal irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0199
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Calcium Acetate 4280 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0200

Material Safety Data Sheet

City University of Hong Kong

MSDS CALCIUM SULFATE, DIHYDRATE, 0200

POWDER
========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Calcium Sulfate, Dihydrate, Powder

Chinese Name:
Common Synonyms: Gypsum; Alabaster; C.I. 77231; C.I. Pigment White 25
Chemical Family: Calcium Compounds
Formula: CaSO4 2H2O
Formula Wt.: 172.17
CAS No.: 10101-41-4
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 1450 deg. C (2642 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.32 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Slight (0.1-1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Sulfur dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, dusting
Incompatibles: Aluminum, strong acids
Decomposition Products: Oxides of sulfur

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0200
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: None identified
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 10 mg/m3
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 15 mg/m3
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
dust/mist respirator is recommended. If concentration exceeds capacity of respirator, a self-contained
breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0201

Material Safety Data Sheet

City University of Hong Kong

MSDS ACTIVATED CHARCOAL, POWDER 0201

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Activated Charcoal, Powder

Chinese Name:
Common Synonyms: Activated Carbon; Carboraffin; Carborafine
Chemical Family: Carbon
Formula: C
Formula Wt.: 12.01
CAS No.: 7440-44-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 3500 deg. C (6332 deg. F) Vapor Density (Air=1): 0.4
(@ 760 mmHg)
Specific Gravity: 2.30 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Black powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray, carbon dioxide, dry chemical or ordinary foam.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained Breathing apparatus with full
facepiece operated in positive pressure Mode. Move containers from fire area if it can be done without
risk. Use Water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: Contact with strong oxidizers may cause fire or explosion.
Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles: Strong oxidizing agents
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Irritation of upper respiratory tract, excessive inhalation is irritating, may cause respiratory system
damage

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0201

Skin Contact: None identified

Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Intravenous Mouse LD50 For Activated Carbon 440 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give large amounts of water.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a dust/mist
respirator is recommended. If concentration exceeds capacity of respirator, a self-contained breathing
apparatus is advised.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store in cool, dry, well-ventilated area away from heat, sparks, or flame.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Shut off ignition sources; no flares, smoking, or flames in area. With
clean shovel, carefully place material into clean, dry container and cover; remove from area. Flush spill
area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0204

Material Safety Data Sheet

City University of Hong Kong

MSDS COBALT NITRATE, 6-HYDRATE 0204

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Cobalt Nitrate, 6-Hydrate

Chinese Name:
Common Synonyms: Cobalt (II) Nitrate, Hexahydrate; Cobalt Dinitrate, Hexahydrate
Chemical Family: Cobalt Compounds
Formula: Co(NO3)2 6H2O
Formula Wt.: 291.03
CAS No.: 10026-22-9
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 55 deg. C (131 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 56 deg. C (132 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.54 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Complete (100%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Red crystals. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Strong oxidizer. Contact with combustible materials, flammable materials, or powdered metals can
cause fire or explosion.

Toxic Gases Produced: Oxides of nitrogen

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None identified
Incompatibles: Combustible materials, strong reducing agents
Decomposition Products: Oxides of nitrogen

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0204
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of nose and throat, headache, coughing, dizziness, difficult breathing
Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: Nausea, vomiting
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Cobalt Nitrate, 6-Hydrate 691 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, butyl rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Keep combustibles (wood, paper,
oil, etc.) away from spilled material. With clean shovel, carefully place material into clean, dry
container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0205

Material Safety Data Sheet

City University of Hong Kong

MSDS COPPER METAL 0205

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name And Synonyms: Copper Metal

Chinese Name:
Chemical Family: Metal
Chemical Formula: Cu
CAS No.: 7440-50-8
Product Use: Laboratory Use, Industrial Processes

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Odour and Appearance: A bright reddish metal in the form of foil, wire or turnings.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odour Threshold (ppm): Not applicable
Vapour Pressure (mm Hg): 1 mm Hg at 1628 deg. C
Vapour Density (Air=1): Not applicable
Evaporation Rate: Not applicable
Boiling Point : 2324 deg. C
Melting Point : Not available
pH: Not available
Specific Gravity: 8.920
Coefficient of Water/Oil distribution: Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flammability: Nonflammable
Extinguishing Media: Use any means suitable for surrounding fire
Flash Point (Method Used): None
Autoignition Temperature: Not available
Upper Flammable Limit (% by volume): Not applicable
Lower Flammable Limit (% by volume): Not applicable
Hazardous Combustion Products: None
Sensitivity to Impact: None
Sensitivity to Static discharge: None

========================================================================
REACTIVITY DATA
========================================================================

Chemical Stability: Stable

Incompatibility with other substances:
Oxidizers, acetylene, 1-bromo-2 propyne, acid chlorides, halogens, acids

Reactivity: May discolour on exposure to air and moisture.

Hazardous Decomposition Products: None known

========================================================================
HEALTH HAZARD DATA
========================================================================

LD50: TLlo (oral, rat) 1.2 mg/kg

LC50: Not Available

Inhaled: Not applicable

In contact with skin: No known harmful effects.
In contact with eyes: Mechanical irritant
Ingested: No information available

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0205
Carcinogenicity: No information available
Teratogenicity: No information available
Reproductive Effects: No information available
Mutagenicity: No information available
Synergistic Products: None known

========================================================================
FIRST AID MEASURES
========================================================================

Eyes: Wash thoroughly with water. Get medical advice if irritation develops.
Skin:
Remove contaminated clothing. Wash skin with plenty of water for at least fifteen (15) minutes. If
irritation develops seek medical attention.

Inhalation: Not applicable

Ingestion:
Never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing.
Rinse mouth thoroughly with water. Do not induce vomiting. Have victim drink 220-400 ml of water to
dilute. Seek medical attention.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls:
The hazard potential of this material is relatively low. General ventilation is usually sufficient.

Respiratory Protection: Not usually required

Eye Protection: Chemical safety gogglesSkin Protection: Rubber gloves
Other Personal Protective Equipment: Safety shower and eye-wash fountain in work area.
Handling Procedures and Equipment: Follow routine safe handling procedures
Storage Requirements:
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Store under nitrogen. Protect
from damage.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Leak and Spill Procedure: Sweep or gather up and transfer to a container for recovery or disposal.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0207

Material Safety Data Sheet

City University of Hong Kong

MSDS CUPRIC CARBONATE 0207

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Cupric Carbonate

Chinese Name:
Common Synonyms: Copper (II) Carbonate; Cupric Carbonate, Basic; Copper Carbonate Hydroxide
Chemical Family: Copper Compounds
Formula: Mixture Cu(CO3) & Cu(OH) 2
Formula Wt.: N/A
CAS No.: 12069-69-1
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: 3.90 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Blue-green powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures: None identified.
Unusual Fire & Explosion Hazards: None identified.
Toxic Gases Produced: None identified

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: Strong acids
Decomposition Products: None identified

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: None identified
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Nausea, vomiting, gastrointestinal pain
Chronic Effects: Kidney damage, liver damage
Threshold Limit Value (TLV/TWA): 1 mg/m3
Short-Term Exposure Limit (STEL): Not established

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0207
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 6 ppm, a
high-efficiency particulate respirator is recommended. Above this level, a self-contained breathing
apparatus is advised.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0208

Material Safety Data Sheet

City University of Hong Kong

MSDS CUPRIC CHLORIDE, DIHYDRATE 0208

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Cupric Chloride, Dihydrate

Chinese Name:
Common Synonyms: Copper (II) Chloride, Dihydrate
Chemical Family: Copper Compounds
Formula: CuCl 2 2H2O
Formula Wt.: 170.48
CAS No.: 10125-13-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 100 deg. C (212 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.51 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Complete (100%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Blue-green crystals or powder.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Hydrogen chloride

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture
Incompatibles: Potassium, sodium, water
Decomposition Products: Hydrogen chloride

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of nose and throat, headache, coughing, dizziness, difficult breathing
Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0208
Ingestion: Nausea, vomiting
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 1 mg/m3
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 9 ppm, a
high-efficiency particulate respirator is recommended. Above this level, a self-contained breathing
apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, rubber gloves are recommended

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0209

Material Safety Data Sheet

City University of Hong Kong

MSDS CUPRIC OXIDE 0209

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Cupric Oxide

Chinese Name:
Common Synonyms: Copper (II) Oxide; Black Copper Oxide
Chemical Family: Copper Compounds
Formula: CuO
Formula Wt.: 79.55
CAS No.: 1317-38-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 1326 deg. C (2418 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 6.40 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Black crystalline powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures: None identified.
Unusual Fire & Explosion Hazards: None identified.
Toxic Gases Produced: None identified

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: None identified
Decomposition Products: None identified

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 0.2 mg/m3

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0209
TLV Is For Copper, Fume, As Cu.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 0.1 mg/m3
PEL Is For Copper Fume, As Cu.
Toxicity Of Components: No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Respiratory system, lungs, eyes, skin
Medical Conditions Generally Aggravated By Exposure: Wilson's disease
Primary Routes Of Entry: Inhalation, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 15 ppm,
a high-efficiency particulate respirator is recommended. Above this level, a self-contained breathing
apparatus is advised.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0210

Material Safety Data Sheet

City University of Hong Kong

MSDS CUPRIC SULFATE, 5-HYDRATE 0210

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Cupric Sulfate, 5-Hydrate

Chinese Name:
Common Synonyms: Copper (II) Sulfate, Pentahydrate; Blue Vitriol
Chemical Family: Copper Compounds
Formula: CuSO4 5H2O
Formula Wt.: 249.68
Cas No.: 7758-99-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 653 deg. C (1207 deg. F) Decomposes Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.28 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Blue crystals or granules. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: Note: decomposes at melting point.

Toxic Gases Produced: Sulfur dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat
Incompatibles: Strong reducing agents, strong oxidizing agents, magnesium
Decomposition Products: Oxides of sulfur

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract, irritation of mucous membranes

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0210
Ingestion: Nausea, vomiting, diarrhea, gastrointestinal pain
Chronic Effects: Blood damage
Threshold Limit Value (TLV/TWA): 1 mg/m3
TLV Is For Copper, Dusts And Mists, As Cu.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 1 mg/m3
PEL Is For Copper Dust And Mist, As Cu.
Toxicity Of Components:
Oral Rat LD 50 For Cupric Sulfate, 5-Hydrate 300 mg/kg
Intraperitoneal Mouse LD 50 For Cupric Sulfate, 5-Hydrate 33 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, Skin, blood
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, give large amounts of water. induce vomiting.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Skin contact: in case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 8 ppm, a
dust/mist respirator is recommended. Above this level, a self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Isolate from incompatible
materials.

========================================================================

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0211

Material Safety Data Sheet

City University of Hong Kong

MSDS D-(-)-FRUCTOSE 0211

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: D-(-)-Fructose

Chinese Name:
Common Synonyms: D-Fructopyranose
Chemical Family: Carbohydrates And Polysaccharides
Formula: OCH2(CHOH) 3COHCH2OH
Formula Wt.: 180.16
CAS No.: 57-48-7
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 103 deg. C (217 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: N/A Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: None identified
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0211
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components: No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 212

Material Safety Data Sheet

City University of Hong Kong

MSDS IRON POWDER 0212

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Iron Powder

Chinese Name:
Formula : Fe
CAS.: 7439-89-6

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point: 5432 deg. F

Vapor Pressure (mm Hg.): 1 mm @ 1787 deg. C
Vapor Density (AIR = 1): N/A
Specific Gravity (H2O = 1): Apparent density 2.55-2.90 g/cm

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point: 2,795 deg. F
Evaporation Rate (Butyl Acetate = 1): N/A
Solubility in Water: None - rusts
Appearance and Odor: Silver-greyish to black in color; odor >> none

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Method Used): N/A

Flammable Limits: Not known LEL UEL
Extinguishing Media : Water or CO2 foam or dry chemical extinguishing agents
Special Fire Fighting Procedures : Regular procedures

========================================================================
REACTIVITY DATA
========================================================================

Stability : Stable
Hazardous Polymerization : Will not occur
Incompatibility (Materials to Avoid) :
Violently combustible when mixed with oxidizing agents (ex: potassium chlorate, sodium nitrate)

Hazardous Decomposition or Byproducts : If exposed to strong acids will release hydrogen

========================================================================
HEALTH HAZARD DATA
========================================================================

Health Hazards (Acute and Chronic) :

As for sand or grit or other fine granular substances, iron powder can be Irritant to eyes and respiratory
system. Annual chest X-Rays of our Plant workers including those with 20 years service give negative
Results.

Carcinogenicity: None
Signs and Symptoms of Exposure : Irritation of eyes and possibly of respiratory tract.
Medical Conditions Generally Aggravated by Exposure : Not known

========================================================================
FIRST AID MEASURES
========================================================================

To remove iron particles from eyes; bathe eyes as for sand or grit. Use of magnet possible.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 212
========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection (Specify Type) : Filter type dust masks may be worn ***

Ventilation : Local exhaust

Protective Gloves: None
Eye Protection: Safety type glasses optional
Other Protective Clothing or Equipment None
Work/Hygienic Practices Regular
Precautions to Be Taken in Handling and Storing : Normal good plant housekeeping

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In Case Material Is Released Or Spilled :

Normal plant housekeeping procedures to remove spilled materials, Sweeping, shovelling, magnetic
pick-ups, etc...

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0213

Material Safety Data Sheet

City University of Hong Kong

MSDS FERROUS SULFATE, 7-HYDRATE 0213

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Ferrous Sulfate, 7-Hydrate

Chinese Name:
Common Synonyms: Iron (II) Sulfate, Heptahydrate; Copperas; Green Vitriol
Chemical Family: Iron Compounds
Formula: FeSO4 7H2O
Formula Wt.: 278.02
CAS No.: 7782-63-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: 1.90 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Blue-Green Crystals Or Granules. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Sulfur dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture
Incompatibles: Strong bases, carbonates, potassium
Decomposition Products: Oxides of sulfur

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0213
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 1 mg/m3
TLV Is For Iron Salts, Soluble, As Fe.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 1 mg/m3
PEL Is For Iron Salts, Soluble, As Fe.
Toxicity Of Components:
Oral Mouse LD 50 For Ferrous Sulfate, 7-Hydrate 1520 mg/kg
Intravenous Mouse LD50 For Ferrous Sulfate, 7-Hydrate 51 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
dust/mist respirator is recommended. If concentration exceeds capacity of respirator, a self-contained
breathing apparatus is advised.

Eye/skin protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.
Special Precautions: Note: do not use product if it is coated with brownish yellow basic sulfate.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0214

Material Safety Data Sheet

City University of Hong Kong

MSDS FERRIC NITRATE, 9-HYDRATE 0214

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Ferric Nitrate, 9-Hydrate

Chinese Name:
Common Synonyms: Nitric Acid, Iron (3+) Salt; Iron (III) Nitrate, Nonahydrate; Iron Nitrate
Chemical Family: Iron Compounds
Formula: Fe(NO3)3 9H2O
Formula Wt.: 404.00
CAS No.: 7782-61-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 47 deg. C (116 deg. F) Vapor Density (Air=1): 14.0
(@ 760 mmHg)
Specific Gravity: 1.68 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Gray to light purple crystals. Faint acid odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Strong oxidizer. Contact with combustible materials, flammable materials, or powdered metals can
cause fire or explosion. Closed containers exposed to heat may explode.

Toxic Gases Produced: Oxides of nitrogen

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, shock, friction
Incompatibles: Strong reducing agents, most common metals, combustible materials, organic materials
Decomposition Products: Oxides of nitrogen

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0214
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Severe irritation or burns
Eye Contact: Severe irritation or burns
Skin Absorption: None identified
Ingestion: Gastrointestinal irritation
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 1 mg/m3
TLV Is For Iron Salts, Soluble, As Fe.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 1 mg/m3
PEL Is For Iron Salts, Soluble, As Fe.
Toxicity Of Components:
Oral Rat LD 50 For Ferric Nitrate, Nonahydrate 3250 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure:
Damaged skin, eye disorders, respiratory system disease

Primary Routes Of Entry: Inhalation, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, give large amounts of water. Induce vomiting.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin contact: in case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
dust/mist respirator is recommended. If concentration exceeds capacity of respirator, a self-contained
breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, proper gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Keep combustibles (wood, paper,
oil, etc.) away from spilled material. With clean shovel, carefully place material into clean, dry
container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0215

Material Safety Data Sheet

City University of Hong Kong

MSDS FERRIC OXIDE 0215

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Ferric Oxide

Chinese Name:
Common Synonyms: Iron (III) Oxide; Red Iron Oxide; C.I. 77491; Iron Sesquioxide
Chemical Family: Iron Compounds
Formula: Fe2O3
Formula Wt.: 159.69
CAS No.: 1309-37-1
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 1565 deg. C (2849 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 5.24 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A Physical State: Solid
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Red to brown powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Iron fumes

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: Hydrazine, calcium hypochlorite, performic acid
Decomposition Products: None identified

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Prolonged contact may cause irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0215
Chronic Effects: Lung damage
Threshold Limit Value (TLV/TWA): 5 mg/m3
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 10 mg/m3
Toxicity Of Components:
Intraperitoneal Rat LD 50 For Ferric Oxide 5500 mg/kg
Intraperitoneal Mouse LD 50 For Ferric Oxide 5400 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Respiratory system, lungs
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0216

Material Safety Data Sheet

City University of Hong Kong

MSDS LEAD FOIL 0216

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Lead Foil

Chinese Name:
Formula : Pb
CAS : 7439-92-1

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point:............... N/A

Vapor Pressure:.............. N/A
Vapor Density: .............. N/A
Evaporation Rate:............ N/A

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility In Water: ........ N/A
Sp. Gravity:................. N/A
Percent Volatile: ........... N/A
Volatile Organics: .......... N/A
Voc Less H2O & Exempt Solvent N/D
pH: ......................... N/A
Viscosity: .................. N/A
Melting Point................ N/D
Appearance And Odor: Lead foil, silver color

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point:................. N/A

Flammable Limits - LEL: ..... N/A
Flammable Limits - UEL: ..... N/A
Autoignition Temperature: ... N/A
Extinguishing Media: Water, carbon dioxide, dry chemical, foam
Special Fire Fighting Procedures: Not applicable
Unusual Fire And Explosion Hazards: Not applicable.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Incompatibility - Materials To Avoid: Strong oxidizing agents
Hazardous Polymerization: Will not occur
Hazardous Decomposition Products: Not applicable.

========================================================================
HEALTH HAZARD DATA
========================================================================

Lead Foil.............. 0.15 mg/m3 TWA ACGIH as Pb dust or fume

Lead Foil.............. 0.05 mg/m3 TWA OSHA as Pb
Eye Contact: No adverse health effects are expected from eye contact.
Mechanical Eye Irritation:
Signs/symptoms can include irritation, redness, scratching of the cornea and tearing.

Skin Contact:
Mild Skin Irritation (After Prolonged Or Repeated Contact):
Signs/symptoms can include redness, swelling, and itching.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0216
Mechanical Skin Irritation:
Signs/symptoms can include itching and redness. Excessive skin contact and poor hygiene could result in
accidental ingestion of lead. See symptoms and health effects of lead under ingestion.

Inhalation:
No adverse health effects are expected from inhalation exposure. Health effects from inhalation are not
expected unless product is heated. Vapors of heated material may cause respiratory system irritation.
Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system.

While the following effects are associated with one or more of the individual ingredients in this product
and are required to be included on the msds by the U.S. OSHA hazard communication standard, they are
not expected effects during foreseeable use of this product.

Prolonged Or Repeated Overexposure, Above Recommended Guidelines, May Cause:

Blood Disorders: signs/symptoms can include prolonged weakness and fatigue.
Kidney Effects: Signs/symptoms can include reduced urine volume, blood in urine and back pain.
Liver Effects: Signs/symptoms can include yellow skin(jaundice) and tenderness of upper abdomen.

If Swallowed:
Anemia (Decreased Number Of Red Blood Cells Or Amount Of Hemoglobin):
Signs/symptoms can include prolonged weakness and fatigue.

Irritation of Gastrointestinal Tissues:

Signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood
in feces.

Peripheral Neuropathy:
Signs/symptoms can include tingling of extremities, incoordination, numbness, weakness and tremors.
Lead is a cumulative poison. Absorption of lead is influenced by the diet.
While the following effects are associated with one or more of the individual ingredients in this product
and are required to be included on the msds by the U.S. OSHA hazard communication standard, they are
not expected effects during foreseeable use of this product.

Blood disorders: Signs/symptoms can include prolonged weakness and fatigue.

Heart Effects: Signs/symptoms can include arrhythmia, heart attack and death.
Immune System Impairment (immunosuppression):
Signs/symptoms can include inability to fight infections.

Kidney Effects: Signs/symptoms can include reduced urine volume, blood in urine and back pain.
Liver Effects: Signs/symptoms can include yellow skin(jaundice) and tenderness of upper abdomen.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Cancer:
Lead (Elemental) (7439-92-1) is a potential cancer hazard causing kidney cancer by the dietary and
parenteral routes of exposure in laboratory animal studies (NTP anticipated human carcinogen, IARC
possible human carcinogen 2B).

Reproductive/Developmental Toxins:
Lead (7439-92-1) is a reproductive hazard causing behavioral defects, teratogenicity, fetotoxicity, and
male reversible fertility effects based on human experience (California Proposition 65).

========================================================================
FIRST AID MEASURES
========================================================================

Eye Contact:
Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical
attention.

Skin Contact: Flush skin with large amounts of water. If irritation persists, get medical attention.
Inhalation: No need for first aid is anticipated.
If Swallowed: Do not induce vomiting. Drink two glasses of water. Call a physician.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Eye Protection: Avoid eye contact.

Skin Protection: Avoid skin contact..
Ventilation Protection: Not applicable.
Respiratory Protection: Not applicable..
Prevention Of Accidental Ingestion:
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and
water. Wash hands after handling and before eating. Do not ingest.

Recommended Storage:
Store away from areas where product may come into contact with food Or pharmaceuticals. Keep out of
the reach of children.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill Response: Not applicable.

Recommended Disposal: Dispose of waste product in a hazardous waste facility. Reclaim if feasible.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0218

Material Safety Data Sheet

City University of Hong Kong

MSDS LEAD CHLORIDE 0218

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Lead Chloride

Chinese Name:
Common Synonyms: Lead (II) Chloride; Lead Dichloride
Chemical Family: Lead Compounds
Formula: PbCl2
Formula Wt.: 278.10
CAS No.: 7758-95-4
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 950 deg. C (1742 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 501 deg. C (933 deg. F) Vapor Density (Air=1): 9.6
(@ 760 mmHg)
Specific Gravity: 5.85 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Moderate (1-10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystalline powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: Can be an explosion hazard, especially when heated.
Toxic Gases Produced: Lead fumes, chlorine, hydrogen chloride

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame
Incompatibles: None identified
Decomposition Products: Lead fumes, hydrogen chloride

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0218
Eye Contact: Irritation
Skin Absorption: May be harmful
Ingestion:
Headache, nausea, vomiting, gastrointestinal irritation, convulsions, unconsciousness, and may be fatal

Chronic Effects: Anemia, kidney damage, blurred vision, lead build-up in the central nervous system
Threshold Limit Value (TLV/TWA): 0.15 mg/m3
TLV Is For Lead, Inorganic Dusts And Fumes, As Pb.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 0.05 mg/m3
PEL Is For Lead, Inorganic Dusts And Fumes, As Pb.
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: Yes

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Gi tract, central nervous system, gingival tissue, kidneys, blood
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact, absorption

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Skin contact: in case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
high-efficiency particulate respirator is recommended. If concentration exceeds capacity of respirator, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, proper gloves are recommended.
Storage Requirements: Keep container tightly closed. Store in secure poison area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0219

Material Safety Data Sheet

City University of Hong Kong

MSDS LEAD OXIDE 0219

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Lead Oxide

Chinese Name:
Common Synonyms: Lead (II) Oxide; Lead Monoxide; Lead Oxide, Yellow
Chemical Family: Lead Compounds
Formula: PbO
Formula Wt.: 223.19
CAS No.: 1317-36-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 888 deg. C (1630 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 9.53 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Yellow to red powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Lead fumes

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat
Incompatibles:
Strong reducing agents, combustible materials, chemically active metals, aluminum, sodium

Decomposition Products: Lead fumes

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0219
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion:
Headache, nausea, vomiting, gastrointestinal irritation, convulsions, unconsciousness, and may be fatal

Chronic Effects:
Anemia, kidney damage, blurred vision, lead build-up in the central nervous system
Threshold Limit Value (TLV/TWA): 0.15 mg/m3
TLV Is For Lead, Inorganic Dusts And Fumes, As Pb.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 0.05 mg/m3
PEL Is For Lead, Inorganic Dusts And Fumes, As Pb.
Toxicity Of Components:
Intraperitoneal Rat LD 50 For Lead Oxide 430 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: Yes

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Gi tract, central nervous system, gingival tissue, kidneys, blood
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
high-efficiency particulate respirator is recommended. If concentration exceeds capacity of respirator, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, proper gloves are recommended.
Storage Requirements: Keep container tightly closed. Store in secure poison area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0220

Material Safety Data Sheet

City University of Hong Kong

MSDS LITHIUM CHLORIDE 0220

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Lithium Chloride

Chinese Name:
Common Synonyms: Hydrochloric Acid, Lithium Salt
Chemical Family: Lithium Compounds
Formula: LiCl
Formula Wt.: 42.39
CAS No.: 7447-41-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 1355 deg. C (2471 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 608 deg. C (1126 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.07 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White solid. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Hydrogen chloride

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture
Incompatibles: Strong acids, bromine trifluoride and trichloride
Decomposition Products: Hydrogen chloride

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract, irritation of mucous membranes

Skin Contact: Irritation
Eye Contact: Irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0220
Skin Absorption: None identified
Ingestion: Gastrointestinal irritation, nausea, vomiting, diarrhea
Chronic Effects: Kidney damage, central nervous system depression
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Lithium Chloride 526 mg/kg
Intraperitoneal Rat LD 50 For Lithium Chloride 514 mg/kg
Subcutaneous Rat LD50 For Lithium Chloride 499 mg/kg
Intravenous Mouse LD50 For Lithium Chloride 363 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: Tests on laboratory animals indicate material may be teratogenic.
Target Organs: Gi tract, central nervous system, kidneys
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, give large amounts of water. induce vomiting.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, uniform, rubber gloves are recommended.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Isolate from incompatible
materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0221

Material Safety Data Sheet

City University of Hong Kong

MSDS LITHIUM 0221

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Lithium

Chinese Name:
CAS # : 7439-93-2

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point : 714 deg. C

% Volatile by Vol: Not applicable
Bulk Dens./Spec. Grav: 0.53 g/cc
pH Level: Not applicable
Vapor Pressure: Not applicable

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Coef. H2O/Oil Dist.: Not available
Melting Point: Not available
Freezing Point : Not available
Molecular Weight: Not available
Odour Threshold Conc.: Not available
Vapor Density (Air=1): Not applicable
Evaporation Rate: Not applicable Vs.: Not applicable
Solubility In Water: Reacts with water.
Appearance, Odour : Lithium is a silvery-white, soft metallic solid with no odour.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point And Method: Not available

Auto-Ignition Temperature : Not available
Lower Explosion Limit: Not available
Upper Explosion Limit: Not available
Means Of Extinction :
Do not use water, sand or CO2 to fight fire. Use graphite, lith-x (ansul). If not available, use dry sodium
chloride, dry (anhydrous) calcium, dry lithium chloride.

Special Procedures :
Due to possibility of toxic fume, if involved in fire wear self contained breathing apparatus.

Hazardous Combustion Products :

Corrosive lithium oxide and/or lithium hydroxide fumes may be released.

========================================================================
REACTIVITY DATA
========================================================================

Stability? Stable
Hazardous Polymerization Will not occur.
Incompatibility To Other Substances :
If the cartridge seal is broken, the lithium metal is incompatible with moisture, acids, oxidizers, nitrogen,
oxygen and carbon dioxide.

Hazardous Decomposition Products :

Reacts violently with many materials. With water, reacts to give off flammable hydrogen gas and heat.

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute: If cartridge seal is broken, lithium is corrosive.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0221
Signs And Symptoms Of Exposure : Burns

========================================================================
FIRST AID MEASURES
========================================================================

Eyes: Flush with copious amounts of water; consult physician immediately.

Skin: Wash with soap and water; if irritation persists, consult physician.
Inhalation: Remove person to fresh air; consult physician as soon as possible.
Ingestion: Do not induce vomiting; consult physician immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection : Not applicable

Ventilation : Not applicable
Engineering Controls: Not applicable
Gloves: Insulating gloves
Eye: Goggles
Clothing/Equipment:
Wear full flame resistant face shield and body protective clothing when adding cartridges to molten
metal bath.

Work/Hygiene Practices : Practice good housekeeping and good personal hygiene.

Precautions To Be Taken In Handling And Storing :
Store in a dry, cool area, away from water, acids and oxidizing materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In Case Material Is Released Or Spilled :

If cartridge seal is broken, and in order to prevent ignition, coat with mineral oil (or kerosene), soaking
thoroughly and place in oiled steel drumes, closing securely and tightly.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0223

Material Safety Data Sheet

City University of Hong Kong

MSDS MAGNESIUM, RIBBON 0223

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Magnesium, Ribbon

Chinese Name:
Common Synonyms: N/A
Chemical Family: Metals
Formula: Mg
Formula Wt.: 24.30
CAS No.: 7439-95-4
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 1107 deg. C (2024 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 650 deg. C (1202 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.74 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Decomposes % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Silver metallic strips.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): 634 deg. C (1175 deg. F) Nfpa 704m Rating: 0-1-2 W
Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Smother with dry soda ash. Never use water or chemical fire extinguishers.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool. Burns with a very bright flame, fire glasses must be
worn.

Unusual Fire & Explosion Hazards:

Reacts violently with water producing highly flammable vapors. Contact with strong oxidizers may
cause fire or explosion. Dust may form explosive mixture with air.

Toxic Gases Produced: Hydrogen

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will Not Occur
Conditions To Avoid: Moisture, Heat, Flame, Other Sources Of Ignition
Incompatibles: Strong oxidizing agents, strong acids, water, halogens, cyanides
Decomposition Products: Hydrogen

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0223
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Irritation of mucous membranes, tightness and pain in chest, coughing, difficult breathing, leukocytosis

Skin Contact: Irritation

Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 10 mg/m3
TLV Is For Magnesium Oxide Fume.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Respiratory System, Eyes
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give large amounts of water.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, flush skin with water.

Eye Contact:
In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, a dust/mist
respirator is recommended. If concentration exceeds capacity of respirator, a self-contained breathing
apparatus is advised.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store away from water or locations where water may be used to
extinguish fire. Store in a cool, well-ventilated area away from sources of heat, flame, or ignition.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Shut off ignition sources; no flares, smoking, or flames in area. With
clean shovel, carefully place material into clean, dry container and cover; remove from area. Flush spill
area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0224

Chinese Name:
Material Safety Data Sheet

City University of Hong Kong

MSDS MAGNESIUM SULFATE, 7-HYDRATE 0224

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Magnesium Sulfate, 7-Hydrate

Chinese Name:
Common Synonyms: Magnesium Sulfate, Heptahydrate
Chemical Family: Magnesium Compounds
Formula: MgSO4 7H2O
Formula Wt.: 246.48
CAS No.: 10034-99-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 250 deg. C (482 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.05 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Clear, colorless crystals. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Sulfur dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Air, heat
Incompatibles: None identified
Decomposition Products: Oxides of sulfur

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Irritation
Eye Contact: Irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0224
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Subcutaneous Mouse LD50 For Magnesium Sulfate, 7-Hydrate 980 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0225

Material Safety Data Sheet

City University of Hong Kong

MSDS MANGANESE CHLORIDE 0225

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Manganese Chloride Tetrahydrate

Chinese Name:
Synonyms: Manganous Chloride Tetrahydrate; Manganese dichloride
Chemical Family: Inorganic Salt
Chemical Formula: MnCl2.4H2O
Product Use: Laboratory Reagent
CAS No. : 13446-34-9

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odour and Appearance: Reddish-pink, odourless crystals.
Odour Threshold (ppm): Not applicable
Vapour Pressure (mm Hg): Not applicable
Vapour Density (Air=1): Not applicable
Evaporation Rate: Not applicable
Boiling Point : 198 deg. C
Melting Point : 58 deg. C
pH: 5.0-6.0 (5% solution)
Specific Gravity: 2.01
Coefficient of Water/Oil distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flammability: Nonflammable
Extinguishing Media: Use an extinguisher appropriate to the surrounding material that is burning.
Flash Point (Method Used): Not applicable
Autoignition Temperature: Not applicable
Upper Flammable Limit (% by volume): Not applicable
Lower Flammable Limit (% by volume): Not applicable
Hazardous Combustion Products: Toxic fumes
Sensitivity to Impact: None
Sensitivity to Static discharge: None

========================================================================
REACTIVITY DATA
========================================================================

Chemical Stability: Stable

Incompatibility with other substances: Strong reducing agents, potassium, sodium, zinc
Reactivity: Deliquescent. Excessive heat will cause decomposition.
Hazardous Decomposition Products: Mits toxic fumes of chloride when heated to decomposition.

========================================================================
HEALTH HAZARD DATA
========================================================================

Toxicological Data:
LD50: (oral, rat) 1484 mg/kg
LC50: Not available

Inhaled: May cause irritation. Inhalation may irritate the respiratory tract.
In Contact With Skin: No effects expected. Assumed harmful if absorbed by the skin.
In Contact With Eyes: May cause irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0225
Ingested:
Harmful. Ingestion may cause abdominal pain, nausea, hypoglycemia, and decreases calcium blood
levels.

Carcinogenicity: No information available

Teratogenicity: No information available
Reproductive Effects: No information available
Mutagenicity: No information available
Synergistic Products: None known

========================================================================
FIRST AID MEASURES
========================================================================

Eyes: Wash thoroughly with water. Get medical advice if irritation develops.
Skin:
Remove contaminated clothing. Wash skin with plenty of water for at least fifteen (15) minutes. If
irritation develops seek medical attention.

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing.
Rinse mouth thoroughly with water. Do not induce vomiting. Have victim drink 220-400 ml of water to
dilute. Seek medical attention.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls: Local exhaust ventilation recommended

Respiratory Protection:
Dust mask. Approved air-purifying respirator or self-contained breathing apparatus for exposures
exceeding TLV.

Eye Protection: Chemical safety goggles or face shield.

Skin Protection: Plastic apron, sleeves and boots as appropriate. Rubber or plastic gloves.
Other Personal Protective Equipment: Safety shower and eye-wash fountain in work area.
Handling Procedures and Equipment: Follow routine safe handling procedures. Avoid generating dust.
Storage Requirements:
Store in suitable labelled containers. Keep containers tightly closed when not in use and when empty.
Protect from damage. Store in a cool, dry, well-ventilated area, out of direct sunlight. Protect from
moisture.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Leak and Spill Procedure:

Mix with sand, transfer carefully into container and arrange removal by disposal company. Wash site of
spillage thoroughly with water and detergent.

Waste Disposal:
Store in suitable labelled containers. Keep containers tightly closed when Not in use and when empty.
Protect from damage. Store in a cool, dry, Well-ventilated area, out of direct sunlight. Protect from
moisture.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0226

Material Safety Data Sheet

City University of Hong Kong

MSDS MANGANESE DIOXIDE 0226

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Manganese Dioxide

Chinese Name:
Common Synonyms: Black Manganese Oxide; Cement Black; Manganese (IV) Oxide
Chemical Family: Manganese Compounds
Formula: MnO2
Formula Wt.: 86.94
CAS No.: 1313-13-9
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 535 deg. C (995 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 5.02 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: N/A
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Black crystalline powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move exposed containers from fire area if it can be done
without risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Strong oxidizer. Contact with combustible materials, flammable materials, or powdered metals can
cause fire or explosion.

Toxic Gases Produced: None identified

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles:
Strong oxidizing agents, strong acids, strong reducing agents, nitrates, combustible materials, hydrogen
peroxide, azides, chlorine, chlorates, chlorine trifluoride

Decomposition Products: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0226
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation:
Irritation of upper respiratory tract, excessive inhalation may cause nausea, weakness, chills, loss of
appetite, manganism

Skin Contact: Irritation

Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Central nervous system depression
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 5 mg/m3
TLV Listed Denotes Ceiling Limit.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Respiratory system, central nervous system, blood, kidneys
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Ingestion, inhalation

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, proper gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Keep combustibles (wood, paper, oil, etc.) Away from spilled
material. With clean shovel, carefully place material into clean, dry container and cover; remove from
area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0227

Material Safety Data Sheet

City University of Hong Kong

MSDS METHYL ORANGE pH INDICATOR 0227

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Methyl Orange pH Indicator

Chinese Name:
Synonyms : Methyl Orange pH Indicator
Chemical Family: Azo Dye
Chemical Formula: C14H14N3SO3Na
Product Use: Laboratory Solvent
CAS No. : 547-58-0

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odour and Appearance: Yellow-orange powder or crystals; odourless
Odour Threshold (ppm): Not available
Vapour Pressure (mm Hg): Not available
Vapour Density (Air=1): Not applicable
Evaporation Rate: Not applicable
Boiling Point : Not available
Melting Point : Not available
pH: Not available
Specific Gravity: Not available
Coefficient of Water/Oil distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flammability: Nonflammable
Extinguishing Media: Water spray, foam, CO2
Flash Point (Method Used): None
Autoignition Temperature: Not available
Upper Flammable Limit (% by volume): Not available
Lower Flammable Limit (% by volume): Not available
Hazardous Combustion Products: None known
Sensitivity to Impact: None
Sensitivity to Static discharge: None

========================================================================
REACTIVITY DATA
========================================================================

Chemical Stability: Stable

Incompatibility with other substances: Oxidizers
Reactivity: Stable
Hazardous Decomposition Products: Toxic fumes of nitrogen, sulphur, sodium and carbon compounds.

========================================================================
HEALTH HAZARD DATA
========================================================================

Toxicological Data:
LD50: (oral, rat) 60 mg/kg
LC50: Not available

Inhaled: May be harmful

In contact with skin: May irritate. May be harmful if absorbed.
In contact with eyes: Irritates
Ingested: Toxic

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0227
Carcinogenicity: Suspected carcinogen
Teratogenicity: No information available
Reproductive Effects: No information available
Mutagenicity: Mutation references cited
Synergistic Products: None found

========================================================================
FIRST AID MEASURES
========================================================================

Eyes: Wash thoroughly with water. Get medical advice if irritation develops.
Skin:
Remove contaminated clothing. Wash skin with plenty of water for at least fifteen (15) minutes. If
irritation develops seek medical attention.

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing.
Rinse mouth thoroughly with water. Do not induce vomiting. Have victim drink 220-400 ml of water to
dilute. Seek medical attention.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls: Local exhaust ventilation recommended

Respiratory Protection: Dust mask, self-contained breathing apparatus as appropriate.
Eye Protection: Chemical safety goggles
Skin Protection: Plastic apron, sleeves and boots as appropriate. Rubber gloves.
Other Personal Protective Equipment: Safety shower and eye-wash fountain in work area.
Handling Procedures and Equipment: Follow routine safe handling procedures. Avoid generating dust.
Storage Requirements:
Store in suitable labelled containers. Keep containers tightly closed when not in use and when empty.
Protect from damage. Store in a cool, dry, well-ventilated area, out of direct sunlight.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Leak and Spill Procedure:

Transfer carefully into container and arrange removal by disposal company. Wash site of spillage
thoroughly with water and detergent.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0228

Material Safety Data Sheet

City University of Hong Kong

MSDS METHYL RED pH INDICATOR 0228

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Methyl Red, pH Indicator

Chinese Name:
Synonyms : Methyl Red, pH Indicator
Chemical Family: Mono Azo Dye
Chemical Formula: C15H14N3O2Na
Product Use: Laboratory Reagent
CAS No. : 845-10-3

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odour and Appearance: Orange-red powder; odourless
Odour Threshold (ppm): Not applicable
Vapour Pressure (mm Hg): Not available
Vapour Density (Air=1): Not available
Evaporation Rate: Not available
Boiling Point : Not available
Freezing Point : Not available
pH: Not available
Specific Gravity: Not available
Coefficient of Water/Oil distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flammability: Noncombustible
Extinguishing Media: Use an extinguisher appropriate to the surrounding material that is burning.
Flash Point (Method Used): None
Autoignition Temperature: Not available
Upper Flammable Limit (% by volume): Not available
Lower Flammable Limit (% by volume): Not available
Hazardous Combustion Products: None known
Sensitivity to Impact: None
Sensitivity to Static discharge: None

========================================================================
REACTIVITY DATA
========================================================================

Chemical Stability: Stable

Incompatibility with other substances: Reducing agents
Reactivity: Extreme heat and ignition sources
Hazardous Decomposition Products: COx, nitrogen compounds

========================================================================
HEALTH HAZARD DATA
========================================================================

Toxicological Data:
LD50: Not available
LC50: Not available
Inhaled: May be harmful
In contact with skin: No information available
In contact with eyes: No information available
Ingested: May be harmful
Carcinogenicity: No information available

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0228
Teratogenicity: No information available
Reproductive Effects: No information available
Mutagenicity: May cause adverse mutagenic effects
Synergistic Products: None found

========================================================================
FIRST AID MEASURES
========================================================================

Eyes: Wash thoroughly with water. Get medical advice if irritation develops.
Skin:
Remove contaminated clothing. Wash skin with plenty of water for at least fifteen (15) minutes. If
irritation develops seek medical attention.

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing.
Rinse mouth thoroughly with water. Do not induce vomiting. Have victim drink 220-400 ml of water to
dilute. Seek medical attention.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls: Local exhaust ventilation recommended

Respiratory Protection: Dust mask or self-contained breathing apparatus as appropriate.
Eye Protection: Chemical safety goggles
Skin Protection: Plastic apron, sleeves and boots as appropriate. Neoprene gloves.
Other Personal Protective Equipment: Safety shower and eye-wash fountain in work area.
Handling Procedures and Equipment: Follow routine safe handling procedures. Avoid generating dust.
Storage Requirements:
Store in suitable labelled containers. Keep containers tightly closed when not in use and when empty.
Protect from damage. Store in a cool, dry, well-ventilated area, out of direct sunlight. Store away from
ignition sources.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Leak and Spill Procedure:

Mix with sand, transfer carefully into container and arrange removal by disposal company. Wash site of
spillage thoroughly with water and detergent.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0229

Material Safety Data Sheet

City University of Hong Kong

MSDS NICKEL 0229

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Nickel

Chinese Name:
Common Synonyms: N/A
Chemical Family: Metals
Formula: Ni
Formula Wt.: 58.71
CAS No.: 7440-02-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 2732 deg. C (4949 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 1453 deg. C (2647 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 8.90 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Gray pellets.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Nickel fumes

========================================================================
FIRST AID MEASURES
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: Strong acids, ammonia, aluminum, strong oxidizing agents
Decomposition Products: None identified

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Headache, coughing, dizziness, difficult breathing

Skin Contact: Prolonged contact may cause dermatitis

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0229
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: Headache, nausea, vomiting, dizziness, gastrointestinal irritation
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 1 mg/m3
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 1 mg/m3
Toxicity Of Components: no information is available
Carcinogenicity: NTP: Yes IARC: Yes Z LIST: No OSHA REG: No

Carcinogenicity:
This substance is listed as a NTP anticipated human carcinogen and an IARC probable human
carcinogen (groups 2A and 2B).

Reproductive Effects: None Identified.

Target Organs: Nasal cavities, lungs, skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes.
Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration exceeds TLV, a
dust/mist respirator is recommended. If exceeds capacity of respirator, a self-contained breathing
apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements: Keep container tightly closed. Store in secure poison area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0231

Material Safety Data Sheet

City University of Hong Kong

MSDS NICKEL SULPHATE 0231

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: Nickel Sulphate Hexahydrate

Chinese Name:
Common Name/Synonym: Nickel Sulphate Hexahydrate
CAS Registry Number: 7786-81-4
Chemical Family: N/D
Formula: NiSO4.6H2O
Molecular Weight: N/D
Product Use: Metal finishing.

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Boiling Point: N/AP
Melting Point: N/AP
Freezing Point: N/AP
Specific Gravity (Water=1): 2.07
Vapour Pressure: N/AP
Vapour Density: N/AP
pH: N/D
Solubility in Water: 62.5 g/100 cc at 0 deg. C
% Volatile: N/D
Evaporation Rate (Butyl Acetate=1): N/AP
Odour Threshold: N/AP
Coefficient of Water/Oil Distribution: N/D
Appearance and Odour: Green crystals, odourless.
Physical State: N/D

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point/Method: N/D

Lower Flammable Limit: N/D
Upper Flammable Limit: N/D
Autoignition Temperature: N/D
Extinguishing Media: Use water, carbon dioxide or foam.
Special Fire Fighting Procedures: None expected.
Unusual Fire and Explosion Hazards: Not a fire or explosion hazard.
Hazardous Combustion Products: N/D

========================================================================
REACTIVITY DATA
========================================================================

Stability: Generally considered stable.

Hazardous Polymerization: Polymerization is not expected to occur.
Conditions to Avoid: None expected.
Materials to Avoid: None expected.
Hazardous Decomposition Products: None expected.
Conditions of Reactivity: N/AP

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes of Exposure: Inhalation, skin and eye contact, ingestion.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0231
Inhalation:
Causes respiratory tract irritation. Individuals hypersensitive to NICKEL may develop asthma,
bronchitis, shortness of breath or wheezing.

Eye Contact: Causes eye irritation.

Skin Contact:
Causes skin irritation and sensitization or allergic reactions which may be accentuated by heat and
humidity.

Ingestion: Harmful if swallowed.

Chronic Effects of Exposure: Refer to carcinogenicity.
Medical Conditions Aggravated by Exposure:
May aggravate existing medical conditions such as allergies, dermatitis, asthma, bronchitis or any other
respiratory ailment.

LD50 Oral (rat): N/D

LD50 Dermal (rabbit): N/D
LC50 (species): N/D
Carcinogenicity:
SUSPECT CANCER HAZARD. Risk of cancer depends on duration and level of exposure. Nickel and
certain nickel compounds, including nickel oxide and nickel carbonate, are listed as carcinogens by the
National Toxicology Program and the International Agency for Research on Cancer.

Sensitization: May cause allergic skin and respiratory reaction.

Irritancy: N/D
Reproductive Effects: N/D
Teratogenicity: N/D
Mutagenicity: N/D
Toxicologically Synergistic Products: N/D
Other Data: N/D
Environmental Effects: N/D

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled: Remove to fresh air. If breathing is difficult, give oxygen. Call a physician.
In Case of Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes. Call a physician.

In Case of Skin Contact: Flush skin with water.

If Ingested: If swallowed, induce vomiting immediately as directed by medical personnel.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation (Engineering Controls):

General; local exhaust ventilation as necessary to control any air contaminants to within their TLVs
during the use of this product.

Personal Protective Equipment Respiratory: A NIOSH/MSHA-approved respirator as necessary.

Eye: Chemical goggles as needed to prevent irritation.
Clothing: Body protection as necessary to prevent skin contact.
Footwear: N/D
Hands: Rubber or neoprene gloves.
Other Protective Measures: N/D

Storage and Handling Precautions and Equipment:

Wash thoroughly after handling. Avoid breathing dust. Avoid contact with eyes, skin and clothing. Use
only with adequate ventilation. Keep container closed.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action to Take for Spills or Leaks:

Contain spillage and scoop up or vacuum. Avoid dusting. Refer to applicable provincial and local
regulations for current response information.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0232

Material Safety Data Sheet

City University of Hong Kong

MSDS PHENOL RED 0232

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Phenol Red

Chinese Name:
Common Synonyms: Phenolsulfonphthalein
Chemical Family: Dyes, Stains, And Indicators
Formula: C6H4SO2OC(C6H4-4-OH) 2
Formula Wt.: 354.39
CAS No.: 143-74-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: N/A Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Slight (0.1-1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Red to brown crystals.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Sulfur dioxide, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: None identified
Decomposition Products: Oxides of sulfur, carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0232
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Eye/Skin Protection:
This is a laboratory-use product for which noindustrial protective equipment has been designated.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0233

Material Safety Data Sheet

City University of Hong Kong

MSDS PHENOLPHTHALEIN 0233

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Phenolphthalein

Chinese Name:
Common Synonyms: 3,3-bis(p-Hydroxyphenyl)Phthalide
Chemical Family: Dyes, Stains, And Indicators
Formula: C6H4COOC(C6H4-4-OH) 2
Formula Wt.: 318.33
CAS No.: 77-09-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 260 deg. C (500 deg. F) Vapor Density (Air=1): 11
(@ 760 mmHg)
Specific Gravity: 1.29 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White to yellow powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Humidity, heat
Incompatibles: Strong oxidizing agents, alkalies
Decomposition Products: Carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0233
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: Irritation, allergic reaction may develop
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Gastrointestinal irritation
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Skin, eyes, gi tract
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0234

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM ALUM SULFATE 0234

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Potassium Alum

Chinese Name:
Common Names/Synonyms: Potassium Alum Sulfate; Potash Alum; Alum
Formula: K Al S2 O8 12H2O
CAS No.: 10043-67-1

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point : Not Applicable

Vapor Pressure, mmHg/20 deg. C: Not Applicable
Melting Point : Unk

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapor Density (Air=1): Not Applicable
Specific Gravity (Water=1): 1.75
Water Solubility, %: 10
Appearance And Odor: Clear to white powder or crystals; odorless
Evaporation Rate (Butyl Acetate=1): Not applicable

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point : None

Method Used: Not Applicable
Flammable Limits In Air, % Lower: Not applicable Upper: Not applicable
Extinguishing Media:
This material is not combustible. Use any appropriate medium for extinguishing surrounding fire.

Special Fire Fighting Procedures:

Fire fighters should wear self-contained breathing apparatus and full protective clothing. Use water
spray to cool nearby containers and structures exposed to fire.

Unusual Fire And Explosion Hazards: Toxic sulfur oxides may be released under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Polymerization: Will not occur
Conditions To Avoid: None
Materials To Avoid:
Alum lowers the pH in liquid mixtures resulting in incompatibility where products of mixture are pH
sensitive. Corrosive to steel and iron.

Hazardous Decomposition Products: Will liberate toxic fumes of oxides of sulfur.

========================================================================
HEALTH HAZARD DATA
========================================================================

Primary Routes Of Exposure: Skin or eye contact, inhalation.

Signs And Symptoms Of Exposure
Inhalation:
Breathing dust may irritate the nose, throat, and mucous membrane and cause coughing and chest
discomfort.

Eye Contact: Dusts may irritate the eyes.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0234
Skin Contact: Prolonged or repeated contact with the dust may irritate the skin.

Swallowed: Swallowing the dusts or solids may cause nausea and vomiting.
Chronic Effects Of Exposure: No specific information available.
Medical Conditions Generally Aggravated By Exposure: None reported.
Oral: No data found
Dermal: No data found
Inhalation: No data found
Carcinogenicity:
This material is not considered to be a carcinogen by the national toxicology program, the international
agency for research on cancer, or the occupational safety and health administration.

========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled:
Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

In Case Of Eye Contact:

Immediately flush eyes with lots of running water for 15 minutes, lifting the upper and lower eyelids
occasionally. Get immediate medical attention.

In Case Of Skin Contact:

Immediately wash skin with lots of soap and water. Remove contaminated clothing and shoes; wash
before reuse. Get medical attention if irritation persists after washing.

If Swallowed:
Do not induce vomiting. If conscious, give lots of water. Get immediate medical attention. Do not give
anything by mouth to an unconscious or convulsing person.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Local mechanical exhaust ventilation capable of minimizing dust emissions at the point of use.

Respiratory Protection:
If use conditions generate dusts, wear a NIOSH-approved respirator appropriate for those emission
levels. Appropriate respirators may be a full facepiece or a half mask air-purifying cartridge respirator
with particulate filters, a self-contained breathing apparatus in the pressure demand mode, or a
supplied-air respirator.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Eye Protection:
Chemical goggles unless a full facepiece respirator is also worn. It is generally recognized that contact
lenses should not be worn when working with chemicals because contact lenses may contribute to the
severity of an eye injury.

Protective Clothing: Long-sleeved shirt, trousers, safety shoes, and gloves.

Other Protective Measures: An eyewash and safety shower should be nearby and ready for use.
Storage And Handling Precautions:
Store in a cool, dry, well-ventilated place away from incompatible materials. Keep bags or fiber drums
dry at all times. Wash thoroughly after handling. do not get in eyes, on skin, or on clothing.

Repair And Maintenance Precautions: None.

Other Precautions:
Containers, even those that have been emptied, will retain product residue and vapors. Always obey
hazard warnings and handle empty containers as if they were full.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action To Take For Spills Or Leaks:

Wear protective equipment including rubber boots, rubber gloves, rubber apron, and a full facepiece or
a half mask air-purifying cartridge respirator with particulate filters. Wear chemical goggles if a half
mask is worn. For small spills, sweep up and dispose of in DOT-approved waste containers. For large
spills, shovel into DOT-approved waste containers. Keep out of sewers, storm drains, surface waters,
and soil.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0235

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM CARBONATE 0235

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Potassium Carbonate, Anhydrous

Chinese Name:
Common Synonyms: Carbonic Acid, Dipotassium Salt; Pearl Ash; Salt Of Tartar; Potash
Chemical Family: Potassium Compounds
Formula: K2CO3
Formula Wt.: 138.21
CAS No.: 584-08-7
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 891 deg. C (1635 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.29 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White granules. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: Note: decomposes at boiling point.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture, dusting, heat
Incompatibles: Water, strong acids
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Severe irritation or burns
Eye Contact: Severe irritation or burns
Skin Absorption: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0235
Ingestion: Irritation and burns to mouth and stomach
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Potassium Carbonate, Anhydrous 1870 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, skin, mucous membranes
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give large amounts of water.
Follow with diluted vinegar, fruit juice or whites of eggs beaten with water.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, uniform, rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Suitable for any general chemical storage area. Do not store near acids.

Special Precautions: Material is hygroscopic.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0236

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM CHLORIDE 0236

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Potassium Chloride

Chinese Name:
Common Synonyms: Potassium Monochloride; Potassium Muriate
Chemical Family: Potassium Compounds
Formula: KCl
Formula Wt.: 74.55
CAS No.: 7447-40-7
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 1437 deg. C (2618 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 773 deg. C (1423 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.98 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals or powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Hydrogen chloride

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: Bromine trifluoride and trichloride
Decomposition Products: Hydrogen chloride

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Irritation
Eye Contact: Irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0236
Skin Absorption: None identified
Ingestion: Insomnia, may cause gastrointestinal irritation
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
TOXICITY OF COMPONENTS:
Oral Rat LD 50 For Potassium Chloride 3020 mg/kg
Oral Mouse LD 50 For Potassium Chloride 383 mg/kg
Intraperitoneal Rat LD 50 For Potassium Chloride 660 mg/kg
Intravenous Rat LD50 For Potassium Chloride 39 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: Kidney disorders
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Eye/Skin Protection: Safety goggles, rubber gloves are recommended.
Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0237

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM PHOSPHATE, MONOBASIC 0237

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Potassium Phosphate, Monobasic

Chinese Name:
Common Synonyms: Potassium Dihydrogen Phosphate
Chemical Family: Potassium Compounds
Formula: KH2PO4
Formula Wt.: 136.09
CAS No.: 7778-77-0
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: 2.34 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystalline powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures: None identified.
Unusual Fire & Explosion Hazards: None identified.
Toxic Gases Produced: Oxides of phosphorus

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture
Incompatibles: None identified
Decomposition Products: Oxides of phosphorus

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0237
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.
Special Precautions: Material is hygroscopic.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0238

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM BICARBONATE 0238

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Potassium Bicarbonate

Chinese Name:
Common Synonyms: Potassium Acid Carbonate; Potassium Hydrogen Carbonate
Chemical Family: Potassium Compounds
Formula: KHCO3
Formula Wt.: 100.12
CAS No.: 298-14-6
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 100 deg. C (212 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.17 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals, granules, or powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: None identified
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0238
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components: No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0240

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM SULFATE 0240

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Potassium Sulfate

Chinese Name:
Common Synonyms: Sulfuric Acid, Dipotassium Salt
Chemical Family: Potassium Compounds
Formula: K2SO4
Formula Wt.: 174.27
CAS No.: 7778-80-5
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 1670 deg. C (3038 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 1067 deg. C (1952 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.66 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Moderate (1-10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals or powder.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Sulfur dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: Aluminum, magnesium
Decomposition Products: Oxides of sulfur

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Prolonged contact may cause irritation
Eye Contact: Irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0240
Skin Absorption: None identified
Ingestion: Nausea, vomiting
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Respiratory system, lungs
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0242

Material Safety Data Sheet

City University of Hong Kong

MSDS PUMICE STONE 0242

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Pumice Stone

Chinese Name:

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point: N/A

Vapor Pressure (mm Hg): N/A
Vapor Density (AIR-1): N/A
Solubility in Water: Nil
Specific Gravity (H2O-1): 2.2
Melting Point: N/A

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Evaporation Rate (Butyl Acetate-1): N/A
Appearance and Odor: Fine powder, grey in color, earthy odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (T.C.C.): Non-Flammable

Flammable Limits: LEL: N/A UEL: N/A
Extinguishing Media: N/A
Special Fire Fighting Procedures: N/A
Unusual Fire and Explosion Hazards: None known

========================================================================
REACTIVITY DATA
========================================================================

Stability Stable
Conditions to Avoid: N/A
Incompatibility (Materials to Avoid): N/A
Hazardous Decomposition or By-products: N/A
Polymerization Will Not Occur

========================================================================
HEALTH HAZARD DATA
========================================================================

Route (s) of Entry:

Eyes? N/A
Inhalation? N/A
Skin? N/A
Ingestion? N/A
Health Hazards: Avoid excessing dusting
Carcinogenicity: No
NTP? N/A IARC Monographs? N/A OSHA Regulated N/A
Signs and Symptoms of Exposure: N/A
Medical Conditions Aggravated by Exposure: N/A

========================================================================
FIRST AID MEASURES
========================================================================

In Eyes: N/A
If Breathed: N/A
If in Skin: N/A

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0242
If Swallowed: N/A

========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection (Specify Type): Particle mask.

Ventilation : Local Exhaust
Protective Gloves: N/A
Eye Protection: N/A
Other Protective Clothing or Equipment: N/A
Handling and Storing Precautions: N/A
Other Precautions: Do not get in eyes. Avoid breathing of vapors or dust. Keep out of reach of children.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps to be Taken in Case Material is Released or Spilled: Sweep up as trash

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0245

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM CARBONATE, ANHYDROUS 0245

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Sodium Carbonate, Anhydrous

Chinese Name:
Common Synonyms: Soda Ash; Disodium Carbonate
Chemical Family: Inorganic Sodium Compounds
Formula: Na 2CO3
Formula Wt.: 105.99
CAS No.: 497-19-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 851 deg. C (1563 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.53 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White to gray crystals. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide, oxides

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Humidity
Incompatibles: Strong acids, aluminum, fluorine, oxides of phosphorus, lithium
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract, irritation of mucous membranes

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0245
Ingestion:
Ingestion of large quantities may cause gastrointestinal irritation, nausea, vomiting, diarrhea

Threshold Limit Value (TLV/TWA): Not established

Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established

Toxicity Of Components:
Intraperitoneal Mouse LD 50 For Sodium Carbonate, Anhydrous 117 mg/kg
Inhalation-2hr Mouse LC 50 For Sodium Carbonate, Anhydrous 1200 mg/m3
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Chronic Effects: None identified
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0246

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM CHLORIDE 0246

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Sodium Chloride

Chinese Name:
Common Synonyms: Salt; Rock Salt; Saline; Table Salt
Chemical Family: Inorganic Sodium Compounds
Formula: NaCl
Formula Wt.: 58.44
CAS No.: 7647-14-5
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 1413 deg. C (2575 deg. F) Vapor Pressure (mmHg): <1
(@ 760 mmHg) (20 deg. C)
Melting Point: 801 deg. C (1473 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.16 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystalline solid. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Hydrogen chloride

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: Strong oxidizing agents, lithium, inter-halogens (ex. bromine trifluoride), iron, cement
Decomposition Products: Hydrogen chloride

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Irritation
Eye Contact: Irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0246
Skin Absorption: None identified
Ingestion: Ingestion of large quantities may cause gastrointestinal irritation
Chronic Effects: High blood pressure, rapid ineffective breathing
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Sodium Chloride 3000 mg/kg
Intraperitoneal Mouse LD 50 For Sodium Chloride 2602 mg/kg
Subcutaneous Mouse LD50 For Sodium Chloride 3150 mg/kg
Intravenous Mouse LD50 For Sodium Chloride 645 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, skin, respiratory system, mucous membranes
Medical Conditions Generally Aggravated By Exposure: High blood pressure
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0247

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM CITRATE, DIHYDRATE 0247

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Sodium Citrate, Dihydrate

Chinese Name:
Common Synonyms: Trisodium Citrate
Chemical Family: Organic Sodium Salts
Formula: HOC(COONa)(CH2COONa)2 2H2O
Formula Wt.: 294.10
CAS No.: 6132-04-3
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: N/A Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals, granules, or powder. odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Flame
Incompatibles: None identified
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Irritation of upper respiratory tract

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0247
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Intraperitoneal Rat LD 50 For Sodium Citrate, Dihydrate 1548 mg/kg
Intravenous Mouse LD50 For Sodium Citrate, Dihydrate 170 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure:None identified
Primary Routes Of Entry: Inhalation, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0249

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM BICARBONATE 0249

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Sodium Bicarbonate

Chinese Name:
Common Synonyms: Baking Soda; Sodium Acid Carbonate
Chemical Family: Inorganic Sodium Compounds
Formula: NaHCO3
Formula Wt.: 84.01
CAS No.: 144-55-8
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 50 deg. C (122 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 2.16 Evaporation Rate: N/A
(H2O=1)

Solubility(H2O): Moderate (1-10%) % Volatiles By Volume: 0

(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystalline powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, humidity
Incompatibles: None identified
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: Irritation
Eye Contact: Irritation

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0249
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Sodium Bicarbonate 4220 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0256

Material Safety Data Sheet

City University of Hong Kong

MSDS STARCH, SOLUBLE 0256

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Starch, Soluble

Chinese Name:
Common Synonyms: Amglogen; Amylodextrin
Chemical Family: Natural Products
Formula: (C6H10O5)N
Formula Wt.: N/A
CAS No.: 9005-84-9
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: N/A Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Slight (0.1-1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White powder. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: Strong oxidizing agents
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0256
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 10 mg/m3
TLV Is For Nuisance Dusts And Particulates.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 15 mg/m3
PEL Is For Nuisance Dusts And Particulates.
Toxicity Of Components:
No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, Skin
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Eye contact, skin contact, inhalation

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to ppm, a
dust/mist respirator is recommended. Above this level, a self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0257

Material Safety Data Sheet

City University of Hong Kong

MSDS STRONTIUM CHLORIDE 0257

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Strontium Chloride, 6-Hydrate

Chinese Name:
Common Synonyms: N/A
Chemical Family: Strontium Compounds
Formula: SrCl 2 6H2O
Formula Wt.: 266.62
CAS No.: 10025-70-4
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 1250 deg. C (2282 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 872 deg. C (1601 deg. F) Vapor Density (Air=1): N/A
(@ 760 mmHg)
Specific Gravity: 1.96 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Hydrogen chloride, chlorine

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: None identified
Decomposition Products: Hydrogen chloride, chlorine

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: None identified
Eye Contact: None identified

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0257
Skin Absorption: None identified
Ingestion: May be harmful
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components: No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Ingestion

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact: In case of contact, immediately wash skin with plenty of soap and water for at least 15
minutes.
Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, rubber gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0258

Material Safety Data Sheet

City University of Hong Kong

MSDS STRONTIUM NITRATE 0258

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Strontium Nitrate

Chinese Name:
Common Synonyms: Strontium (II) Nitrate
Chemical Family: Strontium Compounds
Formula: Sr(NO3)2
Formula Wt.: 211.63
CAS No.: 10042-76-9
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 570 deg. C (1058 deg. F) Vapor Density (Air=1): 7.30
(@ 760 mmHg)
Specific Gravity: 2.99 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White green or purple odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Strong oxidizer. Contact with combustible materials, flammable materials, or powdered metals can
cause fire or explosion. Closed containers exposed to heat may explode.

Toxic Gases Produced: Oxides of nitrogen

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, shock
Incompatibles: Strong reducing agents, combustible materials, organic materials
Decomposition Products: Oxides of nitrogen

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0258
========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: None identified

Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): Not established
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Strontium Nitrate 2750 mg/kg
Intraperitoneal Rat LD 50 For Strontium Nitrate 540 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Skin contact: in case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, butyl rubber gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Keep combustibles (wood, paper, oil, etc.) Away from spilled
material. With clean shovel, carefully place material into clean, dry container and cover; remove from
area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0260

Material Safety Data Sheet

City University of Hong Kong

MSDS STANNIC CHLORIDE, 5-HYDRATE 0260

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Stannic Chloride, 5-Hydrate

Chinese Name:
Common Synonyms: Tin (IV) Chloride, 5-Hydrate; Tin Perchloride, 5-Hydrate; Tin Tetrachloride
Chemical Family: Tin Compounds
Formula: SnCl 4 5H2O
Formula Wt.: 350.58
CAS No.: 10026-06-9
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Physical State: Solid
Boiling Point: 114 deg. C (237 deg. F) Vapor Pressure (mmHg): 30
(@ 760 mmHg) (20 deg. C)
Melting Point: -33 deg. C (-27 deg. F) Vapor Density (Air=1): 9.0
(@ 760 mmHg)
Specific Gravity: 2.26 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White solid. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use dry chemical or carbon dioxide. Do not use water.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move exposed containers from fire area if it can be done
without risk. Use water to keep fire-exposed containers cool; do not get water inside containers.

Unusual Fire & Explosion Hazards: Closed containers exposed to heat may explode.
Toxic Gases Produced: Hydrogen chloride

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture
Incompatibles: Water, strong reducing agents
Decomposition Products: Hydrogen chloride

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Severe irritation of respiratory system

Skin Contact: Severe irritation or burns

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0260
Eye Contact: Severe irritation or burns
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 2 mg/m3
TLV Is For Tin, Oxide And Inorganic Compounds, Except SnH 4, As Sn.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 2 mg/m3
PEL Is For Tin, Inorganic Compounds, Except Oxides, As Sn.
Toxicity Of Components:
Intraperitoneal Mouse LD 50 For Stannic Chloride, 5-Hydrate 41 mg/kg
Intravenous Mouse LD50 For Stannic Chloride, 5-Hydrate 32 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Target Organs: Eyes, Skin, Respiratory System
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, do not induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 100
mg/m3, a high-efficiency particulate respirator is recommended. Above this level, a self-contained
breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves arerecommended.

Storage Requirements: Keep container tightly closed. Store in corrosion-proof area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0262

Material Safety Data Sheet

City University of Hong Kong

MSDS UNIVERSAL pH Indicator 0262

========================================================================
PRODUCT INFORMATION
========================================================================

Trade Name UNIVERSAL pH Indicator

Chinese Name
Form/Appearance Dark Blue Odourless Liquid
Recommended Use Test Kit Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

pH (Conc) 100%=7 Boiling Point 100 deg. C

Freezing Point 0 deg. C % Volatiles 99
Solubility in Water Complete Specific Gravity 1.0
Vapor Density NA Evaporation Rate <1 (ether=1)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point None

Extinguishing Medium Product does not support combustion

========================================================================
REACTIVITY DATA
========================================================================

Stable YES
Hazardous Polymerization Will Not Occur
Hazardous Conditions to Avoid/Incompatibility:
Do not mix with other chemicals. Use only as specified by test kit instructions.

========================================================================
HEALTH HAZARD DATA
========================================================================

Effects of Overexposure
Skin and Eyes: May cause irritation
If Swallowed: May cause stomach distress, nausea or vomiting.

========================================================================
FIRST AID MEASURES
========================================================================

Eyes:
Flush immediately with plenty of cool running water. Remove contact lenses. Continue flushing for 15
minutes.

Skin: Flush skin with plenty of cooling running water. Wash thoroughly with soap and water.
If Swallowed:
Rinse mouth; then drink 1 or 2 large glasses of water. DO NOT induce vomiting. Never give anything by
mouth to an unconscious person. If irritation or discomfort persists, call a physician

========================================================================
PREVENTATIVE MEASURES
========================================================================

Eye Protection : Not required

Protective Gloves : Not required. Product may stain skin
Ventilation : NA

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0262
Other Measures : Keep out of reach of children

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill Response : Wipe up or flush to sewer

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0263

Material Safety Data Sheet

City University of Hong Kong

MSDS ZINC CARBONATE 0263

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Zinc Carbonate

Chinese Name:
Common Synonyms: Carbonic Acid, Zinc Salt
Chemical Family: Zinc Compounds
Formula: N/A
Formula Wt.: N/A
CAS No.: 3486-35-9
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: N/A Vapor Density (Air=1): N/A
Specific Gravity: 4.40 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Negligible (<0.1%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A Physical State: Solid
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White powder.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards: None identified.

Toxic Gases Produced: Carbon monoxide, carbon dioxide, zinc fumes

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None documented
Incompatibles: Strong acids
Decomposition Products: Carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): Not established

Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components: No information is available
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0263
Carcinogenicity: None identified.
Reproductive Effects: None identified.
Effects Of Overexposure:
Inhalation: None identified
Skin Contact: None identified
Eye Contact: None identified
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified

Target Organs: None identified

Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: None indicated

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact: In case of contact, immediately wash skin with plenty of soap and water for at least 15
minutes.
Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use adequate general or local exhaust ventilation to keep fume or dust levels as low as
possible.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, proper gloves are recommended.

Storage Requirements: Keep container tightly closed. Suitable for any general chemical storage area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0264

Material Safety Data Sheet

City University of Hong Kong

MSDS ZINC CHLORIDE 0264

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Zinc Chloride

Chinese Name:
Common Synonyms: Zinc Dichloride; Butter Of Zinc
Chemical Family: Zinc Compounds
Formula: ZnCl 2
Formula Wt.: 136.30
CAS No.: 7646-85-7
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point: 732 deg. C (1349 deg. F) Vapor Pressure (mmHg): N/A
(@ 760 mmHg)
Melting Point: 290 deg. C (554 deg. F) Vapor Density (Air=1): 4.7
(@ 760 mmHg)
Specific Gravity: 2.91 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A Physical State: Solid
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White to off-white granules. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards: Closed containers exposed to heat may explode.
Toxic Gases Produced: Hydrogen chloride, zinc fumes

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Moisture, dusting
Incompatibles: Potassium, cyanides, sulfides
Decomposition Products: Chlorine, oxides of zinc, hydrogen chloride

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0264
========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): 1 mg/m3

TLV Is For Zinc Chloride Fume.
Short-Term Exposure Limit (STEL): 2 mg/m3
STEL Is For Zinc Chloride Fume.
Permissible Exposure Limit (PEL): 1 mg/m3
PEL Is For Zinc Chloride Fume.
Toxicity Of Components:
Oral Rat LD 50 For Zinc Chloride 350 mg/kg
Oral Mouse LD 50 For Zinc Chloride 350 mg/kg
Intraperitoneal Mouse LD 50 For Zinc Chloride 31 mg/kg
Subcutaneous Mouse LD50 For Zinc Chloride 330 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects:
Tests on laboratory animals indicate material may be mutagenic and embryotoxic.

Effects Of Overexposure:
Inhalation: Headache, coughing, difficult breathing, chest pains, severe lung irritation, pulmonary edema
Skin Contact: Severe irritation or burns
Eye Contact: Severe irritation or burns
Skin Absorption: None identified
Ingestion: Nausea, vomiting, gastrointestinal irritation, burns to mouth and throat
Chronic Effects: Damage to liver, kidneys, lungs

Target Organs: Respiratory system, lungs, eyes, skin, gi tract, liver, kidneys
Medical Conditions Generally Aggravated By Exposure: Lung disease
Primary Routes Of Entry: Inhalation, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give water, milk, or milk of
magnesia.

Inhalation :
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Skin Contact :
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact : In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation : Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection :
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 9 ppm, a
high-efficiency particulate respirator is recommended. Above this level, a self-contained breathing
apparatus is advised.

Eye/Skin Protection : Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements :
Keep container tightly closed. Store in corrosion-proof area. Isolate from incompatible materials.

Special Precautions : Material is hygroscopic.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge :

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place
material into clean, dry container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0265

Material Safety Data Sheet

City University of Hong Kong

MSDS ZINC DUST 0265

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Zinc Dust

Chinese Name:
Common Name/Synonym: None
CAS Registry Number: 7440-66-6
Chemical Name: Zinc Dust
Chemical Family: Metal/Metal Oxide
Formula: Zn
Molecular Weight: N/AP
Product Use: General uses.

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point: 906 deg. C

Melting Point: N/D
Freezing Point: N/AP
Specific Gravity (Water=1): 7.1
Vapour Pressure (mmHg): N/AP
Vapour Density: N/AP
pH: N/AP
Solubility in Water: Insoluble
% Volatile: N/AP
Evaporation Rate (Butyl Acetate=1): N/AP
Odour Threshold: N/AP
Coefficient of Water/Oil Distribution: N/D
Appearance and Odour: Grey dust/powder
Physical State: Solid

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point/Method: N/AP

Lower Explosion Limit (% by volume): Zinc dust 480 g/m3
Upper Explosion Limit: N/AP
Autoignition Temperature: 600 deg. C
Extinguishing Media: Class D extinguisher. Dry powder type. Avoid water.
Special Fire Fighting Procedures:
Use approved self-contained breathing apparaus and full protective clothing if fighting fire.

Unusual Fire and Explosion Hazards: N/D

Hazardous Combustion Products: Zinc oxide fume.
Explosion Data :
Sensitivity to Mechanical Impact: N/AP
Sensitivity to Static Discharge: Yes
Explosive Power: N/D

Rate of Burning: N/AP

Flammability: Yes
Conditions of Flammability:
Finely divided zinc dust may form explosive mixtures with air if ignited. Contact with acids or alkaline
hydroxides may evolve hydrogen.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0265
========================================================================
REACTIVITY DATA
========================================================================

Stability: Yes
Hazardous Polymerization: N/D
Conditions to Avoid: Avoid moisture or high humidity.
Materials to Avoid:
Halogen gases, acids, bases, oxidizers may react violently or cause hydrogen to be evolved.

Hazardous Decomposition Products: Heat generates zinc oxide fume.

Conditions of Reactivity:
Bulk dust in damp state may heat spontaneously and ignite on exposure to air. Contact with acids or
alkaline hydroxides may evolve explosive hydrogen gas. Forms zinc oxide when heated.

========================================================================
HEALTH HAZARD DATA
========================================================================

LD50 Oral (rat): N/D

LD50 Dermal (rabbit): N/D
LC50 (species): N/D
Carcinogenicity: Does not meet WHMIS criteria.
Sensitization: None reported.
Irritancy: Mechanical irritant to eyes and skin.
Reproductive Effects: Does not meet WHMIS criteria.
Teratogenicity: Does not meet WHMIS criteria.
Mutagenicity: Does not meet WHMIS criteria.
Toxicologically Synergistic Products: None reported.
Other Data: N/D
Environmental Effects: N/D
Primary Routes of Exposure: Skin, eye, inhalation.
Signs, Symptoms and Effects of Exposure
Inhalation: When zinc fumes are inhaled they may cause flu-like symptoms or fever, chills and nausea.
Eye Contact: May irritate.
Skin Contact: May irritate.
Ingestion: May cause fever, stomach cramps and diarrhea.

Chronic Effects of Exposure: N/D

Medical Conditions Aggravated by Exposure: N/D
Additional Information: N/D

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRST AID MEASURES
========================================================================

If Inhaled : Consult physician immediately.

In Case of Eye Contact :
Flush eyes with lukewarm gently running water. If irritation persists, consult physician.

In Case of Skin Contact : Wash thoroughly with soap and water.

If Ingested : Consult physician immediately.
General Advice : Seek medical advice except for minor instances of eye or skin exposure.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation (Engineering Controls): Keep dust levels low.

Personal Protective Equipment - Respiratory and eye protection.
Respiratory: NIOSH/MSHA; Dust/Fume.
Eye: Safety glasses.
Clothing: N/AP
Other Protective Measures: None

Storage and Handling Precautions and Equipment:

Keep in dry, cool, well-ventilated area away from heat. Keep dust levels low. Avoid moisture.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Action to Take for Spills or Leaks: Restrict access to clean-up personnel. Ventilate area well.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0266

Material Safety Data Sheet

City University of Hong Kong

MSDS ZINC, GRANULAR 0266

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name and Synonyms: Zinc, Granular, No. 20 Mesh

Chinese Name:
Chemical Family: Metal
Chemical Formula: Zn
Product Use: Laboratory Solvent
CAS No.: 7440-66-6

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

Physical State: Solid

Odour and Appearance: Bluish-gray metal in different forms; odourless

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odour Threshold (ppm): Not applicable
Vapour Pressure (mmHg): 1 mmHg at 487 deg. C
Vapour Density (Air=1): Not applicable
Evaporation Rate: Not applicable
Boiling Point ( deg. C): 908 deg. C
Melting Point ( deg. C): 419.5 deg. C
pH: Not available
Specific Gravity: 7.140
Coefficient of Water/Oil distribution: Not available

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flammability: Powder form is flammable under almost all ambient conditions.

Extinguishing Media:
USE ONLY dry powder or sand (for powder). Avoid water since contact will cause the liberation of
highly flammable gases.

Flash Point (Method Used): Not available

Autoignition Temperature: Not available
Upper Flammable Limit (% by volume): Not available
Lower Flammable Limit (% by volume): Not available
Hazardous Combustion Products: None
Sensitivity to Impact: None
Sensitivity to Static discharge: May be ignited by static discharge

========================================================================
REACTIVITY DATA
========================================================================

Chemical Stability:
Stable in dry air. Becomes covered with a white coating of basic carbonate on exposure to moist air.

Incompatibility with other substances:

Water, acids, oxidizers, halogenated hydrocarbons, strong alkalies, alkali hydroxides

Reactivity:
Powder may ignite spontaneously with air, especially when damp. Powder forms explosive mixtures
with air and may explode if ignited by flame.

Hazardous Decomposition Products: Explosive hydrogen gas, ZnO

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0266
========================================================================
HEALTH HAZARD DATA
========================================================================

LD50: Not available

LC50: Not available
Inhaled:
Inhalation of fumes may result in sweet taste, throat dryness, cough, weakness, generalized aching, chills,
fever, nausea and vomiting.

In Contact With Skin: Causes irritation

In Contact With Eyes: Physical irritation
Ingested: Harmful/toxic. May cause severe gastroenteritis.
Carcinogenicity: No
Teratogenicity: No information available
Reproductive Effects: No information available
Mutagenicity: No information available
Synergistic Products: None known

========================================================================
FIRST AID MEASURES
========================================================================

Specific Measures :
Eyes : Wash thoroughly with water. Get medical advice if irritation develops.
Skin:
Remove contaminated clothing. Wash skin with plenty of water for at least fifteen (15) minutes. If
irritation develops seek medical attention.

Inhalation : Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing.
Rinse mouth thoroughly with water. Do not induce vomiting. Have victim drink 220-400 ml of water to
dilute. Seek medical attention.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls: Local exhaust recommended

Respiratory Protection: Dust masks
Eye Protection: Chemical safety goggles
Skin Protection: Wear protective gloves and clean body-covering clothing.
Other Personal Protective Equipment: Safety shower and eye-wash fountain in work area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Handling Procedures and Equipment:
Follow routine safe handling procedures. Avoid generating dust. Wash thoroughly after handling. Use
non-sparking tools.

Storage Requirements:
Store in suitable labelled containers. Keep containers tightly closed when not in use and when empty.
Protect from damage. Store in a cool, dry, well-ventilated area, out of direct sunlight. Store away from
incompatible materials. Store away from ignition sources. Air and moisture sensitive.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Leak and Spill Procedure:

Mix with sand, transfer carefully into container and arrange removal by a disposal company. Wash site
of spillage thoroughly with water and detergent.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0267

Material Safety Data Sheet

City University of Hong Kong

MSDS ZINC NITRATE 0267

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Zinc Nitrate

Chinese Name:
Common Synonyms: Nitric Acid, Zinc Salt, Hydrated Form
Chemical Family: Zinc Compounds
Formula: Zn(NO3)2 nH2O
Formula Wt.: N/A
CAS No.: 10196-18-6
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

=======================================================================
PHYSICAL DATA
=======================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Boiling Point: N/A Vapor Pressure (mmHg): N/A
Melting Point: 36 deg. C (96 deg. F) Vapor Density (Air=1): 8.4
(@ 760 mmHg)
Specific Gravity: 2.07 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A Physical State: Solid
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: White crystals. Odorless.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinquishing Media: Use water spray.
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Can react violently with shock, friction or heat. Strong oxidizer. contact with combustible materials,
flammable materials, or powdered metals can cause fire or explosion.

Toxic Gases Produced: Oxides of nitrogen

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, shock
Incompatibles:
Strong reducing agents, combustible materials, organic materials, strong acids, strong bases

Decomposition Products: Oxides of nitrogen

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0267
========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): Not established

Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components:
Oral Rat LD 50 For Zinc Nitrate, 6-Hydrate 1190 mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Effects Of Overexposure:
Inhalation: Irritation of upper respiratory tract
Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Nausea, vomiting
Chronic Effects: None identified

Target Organs: None identified

Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, ingestion, skin contact, eye contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: Call a physician. If swallowed, if conscious, immediately induce vomiting.

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Skin contact: in case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.

Respiratory Protection:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 None required where adequate ventilation conditions exist. If airborne concentration is high, use an
appropriate respirator or dust mask.

Eye/Skin Protection: Safety goggles, uniform, proper gloves are recommended.

Storage Requirements:
Keep container tightly closed. Store separately and away from flammable and combustible materials.
Isolate from incompatible materials.

=======================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Keep combustibles (wood, paper,
oil, etc.) away from spilled material. With clean shovel, carefully place material into clean, dry
container and cover; remove from area. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0280

Material Safety Data Sheet

City University of Hong Kong

MSDS BUTYLAMINE 0280

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Butylamine

Chinese Name:
Common Synonyms: N-Butylamine; 1-Aminobutane
Chemical Family: Amines
Formula: CH3CH2CH2CH2NH2
Formula Wt.: 73.14
CAS No.: 109-73-9
Product Use: Laboratory Reagent

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
=======================================================================
PHYSICAL DATA
=======================================================================

Boiling Point: 77 deg. C (170 deg. F) Vapor Pressure (mmHg): 82

(@ 760 mmHg) (20 deg. C)
Melting Point: -50 deg. C (-58 deg. F) Vapor Density (Air=1): 2.5
(@ 760 mmHg)
Specific Gravity: 0.74 Evaporation Rate: 7.3
(H2O=1) (Butyl Acetate = 1)
Solubility(H2O): Complete (100%) % Volatiles By Volume: 100
(21 deg. C)
pH: N/A
Odor Threshold (ppm): N/A Physical State: Liquid
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless liquid. Amine-like odor.

=========================================================================
FIRE AND EXPLOSION DATA
=========================================================================

Flash Point (Closed Cup): -12 deg. C (10 deg. F)

Autoignition Temperature: 311 deg. C (594 deg. F)
Flammable Limits: Upper - 9.8 % Lower - 1.7 %
Fire Extinquishing Media: Use alcohol foam, dry chemical or carbon dioxide. (water may be ineffective.)
Special Fire-Fighting Procedures:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode. Move containers from fire area if it can be done without
risk. Use water to keep fire-exposed containers cool.

Unusual Fire & Explosion Hazards:

Vapors may flow along surfaces to distant ignition sources and flash back. closed containers exposed to
heat may explode. Contact with strong oxidizers may cause fire.

Toxic Gases Produced: Oxides of nitrogen, carbon monoxide, carbon dioxide

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition
Incompatibles: Strong oxidizing agents, strong acids
Decomposition Products: Oxides of nitrogen, carbon monoxide, carbon dioxide

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0280
========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): 15 mg/m (5 ppm)

TLV (Skin) Listed Denotes Ceiling Limit.
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 15 mg/m (5 ppm)

Toxicity Of Components:
Oral Rat LD 50 For Butylamine 366 mg/kg
Skin Rabbit LD 50 For Butylamine 850 mg/kg
Inhalation-2hr Mouse LC 50 For Butylamine 800 mg/m
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No

Carcinogenicity: None identified.

Reproductive Effects: None identified.
Effects Of Overexposure:
Inhalation:
Severe irritation of respiratory system, coughing, difficult breathing, chest pains, pulmonary edema,
unconsciousness

Skin Contact: Severe irritation or burns

Eye Contact: Severe irritation or burns
Skin Absorption: Rapid absorption
Ingestion: Nausea, vomiting, gastrointestinal irritation, burns to mouth and throat
Chronic Effects: None identified

Target Organs: Respiratory system, skin, eyes, mucous membranes

Medical Conditions Generally Aggravated By Exposure:
Skin disorders, eye disorders, respiratory system disease

Primary Routes Of Entry: Inhalation, absorption, ingestion, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
Call a physician. If swallowed, do not induce vomiting. If conscious, give large amounts of water.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Prompt action is essential.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use general or local exhaust ventilation to meet TLV requirements.

Respiratory Protection:
Respiratory protection required if airborne concentration exceeds TLV. At concentrations up to 250
ppm, a chemical cartridge respirator with ammonia/amine cartridge is recommended. Above this level, a
self-contained breathing apparatus is advised.

Eye/Skin Protection: Safety goggles, uniform, apron, rubber gloves are recommended.
Storage Requirements:
Keep container tightly closed. Store in a cool, dry, well-ventilated, flammable liquid storage area.

Special Precautions: Bond and ground containers when transferring liquid.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear self-contained breathing apparatus and full protective clothing. Shut off ignition sources; no flares,
smoking or flames in area. Stop leak if you can do so without risk. Use water spray to reduce vapors.
Take up with sand or other non-combustible absorbent material and place into container for later
disposal. Flush area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0309

Material Safety Data Sheet

City University of Hong Kong

MSDS GLYCEROL, ANHYDROUS 0309

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Glycerol, Anhydrous

Chinese Name:
Common Synonyms: 1,2,3-Propanetriol; Glycerin; Glycyl Alcohol
Chemical Family: Carbohydrates And Polysaccharides
Formula: HOCH2CHOHCH2OH
Formula Wt.: 92.10
CAS No.: 56-81-5
Product Use: Laboratory reagent

========================================================================
RISK SYMBOL
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PHYSICAL DATA
========================================================================

Boiling Point: 290 °C (554 °F) Vapor Pressure (mmHg): <0.1

(At 760 mmHg) (20 °C)
Melting Point: 18 °C (64 °F) Vapor Density (Air=1): 3.1
(At 760 mmHg)
Specific Gravity: 1.26 Evaporation Rate: N/A
(H2O=1)
Solubility(H20): Complete (100%) % Volatiles By Volume: 0
(21 °C)
pH: N/A
Odor Threshold (ppm): N/A Physical State: Liquid
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Clear, colorless liquid. Odorless.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Flash Point (Closed Cup): 198 °C (390 °F)

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - 0.9 %
Fire Extinquishing Media : Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures :
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full
facepiece operated in positive pressure mode.

Unusual Fire & Explosion Hazards : Contact with strong oxidizers may cause fire or explosion.
Toxic Gases Produced : Carbon monoxide, carbon dioxide, acrolein

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: None identified
Incompatibles: Strong oxidizing agents, strong acids, strong bases
Decomposition Products: Carbon monoxide, carbon dioxide, acrolein

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0309
========================================================================
HEALTH HAZARD DATA
========================================================================

Effects Of Overexposure :
Inhalation: Coughing, difficult breathing
Skin Contact: Irritation, prolonged contact may cause dermatitis
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: Headache, nausea, vomiting, gastrointestinal irritation, convulsions, unconsciousness
Chronic Effects: None identified
Threshold Limit Value (TLV/TWA): 10 mg/m
Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): 10 mg/m

Toxicity Of Components :
Oral Rat LD 50 For Glycerol, Anhydrous 12.6 g/kg
Intraperitoneal Mouse LD 50 For Glycerol, Anhydrous 63 mg/kg
Subcutaneous Rat LD50 For Glycerol, Anhydrous 100 mg/kg
Intravenous Rat LD50 For Glycerol, Anhydrous 5566
mg/kg
Carcinogenicity: NTP: No IARC: No Z LIST: No OSHA REG: No
Carcinogenicity : None identified.
Reproductive Effects : None identified.
Target Organs : Eyes, skin, mucous membranes
Medical Conditions Generally Aggravated By Exposure : None identified
Primary Routes Of Entry : Eye contact, skin contact, inhalation, ingestion

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion:
If swallowed and the person is conscious, immediately give large amounts of water. Get medical
attention.

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact: In case of contact, immediately wash skin with plenty of soap and water for at least 15
minutes.
Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Use general or local exhaust ventilation to meet TLV requirements. Respiratory Protection: Respiratory
protection required if airborne concentration exceeds TLV. At concentrations above 10 mg/m , a
dust/mist respirator is recommended.

Eye/Skin Protection: Safety goggles, uniform, apron, proper gloves are recommended.
Storage Requirements :
Keep container tightly closed. Suitable for any general chemical storage area. Isolate from incompatible
materials.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge :

Wear suitable protective clothing. Take up with sand or other non-combustible absorbent material and
place into container for later disposal. Flush spill area with water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0311

Material Safety Data Sheet

City University of Hong Kong

MSDS MAGNESIUM SULFATE ,ANHYDRATE 0311

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Magnesium Sulfate

Chinese Name:
Synonyms: Magnesium sulfate
CAS No: 7487-88-9
Molecular Weight: 246.47
Chemical Formula: MgSO4

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Transparent crystals, or white powder.

Boiling Point: Not applicable.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odor: Odorless.
Melting Point: 1124 °C (2055 °F) Decomposes.
Solubility: Very soluble in water.
Vapor Density (Air=1): No information found.
Density: 1.67 g/ml @ 4°C
Vapor Pressure (mm Hg): No information found.
pH: Aqueous solution is neutral or slightly acid.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information: Use protective clothing and breathing equipment appropriate for the surrounding fire.

========================================================================
REACTIVITY DATA
========================================================================

Stability:
Stable under ordinary conditions of use and storage. Loses some moisture on exposure to dry air at room
temperatures.

Hazardous Decomposition Products: Oxides of sulfur and the contained metal.

Hazardous Polymerization: Will not occur.
Incompatibilities:
Ethoxy ethyl alcohols, arsenates, phosphates, tartrates, lead, barium, strontium, and calcium

Conditions to Avoid: Heat, moisture, incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Inhalation: Dust may be slightly irritating. Sore throat or coughing may occur.
Ingestion:
Since magnesium salts are slowly absorbed, abdominal pain, vomiting and diarrhea may be the only
symptoms. However, if elimination is blocked by bowel blockage or other reasons, CNS depression,
lack of reflexes, hypocalcemia (deficiency of calcium in the blood) may occur.

Skin Contact: No adverse effects expected but may cause minor skin irritation.
Eye Contact: No adverse effects expected but dust may cause mechanical irritation.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0311
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice.

Skin Contact:
Remove any contaminated clothing. Wash skin with soap and water for at least 15 minutes. Get medical
attention if irritation develops or persists.

Eye Contact:
Wash thoroughly with running water. Get medical advice if irritation develops.

Note to Physician:
IV administration of calcium gluconate will partially reverse the effects of acute magnesium toxicity.
Ventricular support with calcium chloride infusion and mannitol forced diuresis has also been
successful.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as
possible. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the
ACGIH document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition,
for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator
may be worn. For emergencies or instances where the exposure levels are not known, use a full-face
positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers
in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

Handling and Storage :

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.
Isolate from incompatible substances. Containers of this material may be hazardous when empty since
they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Disposal Considerations:
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved
waste disposal facility. Processing, use or contamination of this product may change the waste
management options. State and local disposal regulations may differ from federal disposal regulations.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0336

Material Safety Data Sheet

City University of Hong Kong

MSDS STYRENE 0336

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name : Styrene

Chinese Name:
Trade Name/Synonyms Styrene, Vinylbenzene, Ethenylbenzene, Styrol
Product Use : Monomer for polystyrene, elastomers, plastics, resins, polyesters
CAS No.: 100-42-5

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Physical State : Liquid

Odour : Sweet, aromatic at low concentrations; sharp, penetrating, disagreeable at high concentrations.
Odour Threshold : 0.009 ppm (perception); 0.05-0.96 ppm (recognition)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Appearance : Clear, colourless
Specific Gravity : 0.904 at 20°C
Freezing Point : -30.6°C
Boiling Point : 144.5°C
Vapor Pressure : 5 mm Hg (0.67 kPa) at 20°C
Vapor Density (air=1) : 3.6
Evaporation Rate: (n-Butyl acetate=1) Not available
Volatile, Percent by Volume : 100
Solubility in Water at 20°C : 0.032 wt.%
pH : Not applicable
Water/Oil Distribution Coefficient : 2.95 (log p(OCT))

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Flammable/Combustible (yes/no) : Yes

If yes, under what conditions? Temperature above 31°C and presence of an ignition source.

Extinguishing Media : Water fog, foam, carbon dioxide, dry chemical

Special Firefighting :
Wear NIOSH approved self-contained breathing Instructions apparatus. Water should be used to keep
fire- exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapours
and to protect the workers. Do not get water inside containing vessels.

Flashpoint and Method : 31.0°C (TCC)

Lower Explosive Level (% volume) : 1.1%
Upper Explosive Level (% volume) : 6.1%
Auto Ignition Temp. : 490°C
Impact/Shock Sensitivity : Not available
Rate of Burning : Not available
Sensitivity to Static Discharge : Not available
Hazardous Combustion Products :
Acid vapour upon heating. Production of carbon monoxide and carbon dioxide.

========================================================================
REACTIVITY DATA
========================================================================

Chemically Stable (yes/no): No

If no, under what conditions?
Polymerizes slowly and discolours on exposure to light and air at room temperature.

Incompatible with other substances: Yes

If yes, which ones?

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0336
Metal salts, acids (sulphuric and chlorosulphonic acids), caustic, butyllithium, dibenzoyl peroxide,
aluminum chloride, ferric chloride, chlorine gas, oleum, peroxides and oxidizing agents

Conditions of Reactivity:
Hazardous polymerization (exothermic) will occur if inhibitor is depleted or if styrene is heated.

Hazardous Decomposition
Acid vapour upon heating. Production of Products carbon monoxide, carbon dioxide and styrene oxide.

========================================================================
HEALTH HAZARD DATA
========================================================================

Eye Effects: Eye irritant.

Skin Effects: Skin irritant.
Acute Oral Effects: LD50; 320 mg/kg (oral, mouse)
Acute Inhalation Effects : LC50; 2800 ppm/4H (Rat, inhal.)
Irritancy of Product :
Skin, eye and respiratory irritant. Irritation can occur from brief exposures to 200 ppm or longer
exposures at 100 ppm.

Sensitization : Not a sensitizer

Synergism with : None known
Carcinogenicity :
The International Agency for Research on Cancer (IARC) has classified styrene as a possible carcinogen
to human's bases on "inadequate evidence" in humans, "limited evidence" in animals and "other relevant
data". These "other relevant data" demonstrate that styrene oxide (a metabolite of styrene) is known to
induce cancer in animals. Additionally, styrene has been shown to be mutagenic in several "in vitro"
assays. The following four points should be considered when evaluating styrene's alleged
carcinogenicity. 1) Ten epidemiology studies conducted on over 50,000 styrene-exposed workers,
covering a 45- year period, showed no evidence of a causal link between exposure to styrene and any
type of cancer. 2) Eleven bio-assays on styrene showed no consistent findings and all the studies have
major shortcomings either in protocol design or with the interpretation of results. 3) Metabolism data on
styrene oxide was cited in support of the reclassification of styrene. Yet, current research is inadequate
in assessing the relevance of the toxicity of styrene oxide to styrene, the issue currently being pursued in
the U.S. and Europe to determine the relevance of styrene oxide to styrene. 4) Mutagenicity data used by
IARC have shown inconsistent results. NTP, ACGIH, EPA, NIOSH and OSHA do not support IARC's
classification of styrene as a possible human carcinogen (Group 2B). Preliminary results of inhalation
studies indicate that rats exposed to 800 parts per million (ppm) styrene suffered hearing loss. Relevance
to occupational exposures to styrene has not been established.

Emergency Overview:
Styrene is a clear colourless oily flammable liquid with a sweet aromatic odour at low concentrations
and sharp, penetrating disagreeable odour at higher concentrations. High concentrations will cause eye,

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 nose and throat irritation, dizziness and light headedness. Hazardous polymerization is possible and may
be initiated by heat, acidic or basic conditions and some sorbents.

Potential Health Effects:

Skin:
Liquid and vapours are very irritating to skin. May cause defatting dermatitis. Repeated or prolonged
skin contact may cause blistering and dermatitis (itching, drying, redness).

Eyes: Liquid and vapours are very irritating to eyes.

Breathing:
Vapours are very irritating to nose and throat. Breathing vapours at concentrations above recommended
exposure limits can cause headache, nausea, cramps, loss of appetite, vomiting, dizziness, tremors,
weakness, drowsiness; decreased appetite, dexterity and coordination. May cause narcosis and central
nervous system (CNS) depression. Extreme exposures may cause unconsciousness or death. Possible
long term effects are decreased coordination and concentration and possible neurotoxic effects.

Swallowing:
Styrene may cause irritation of the mouth and throat, nausea vomiting and loss of appetite.

Chronic Hazards :
Inhalation:
Field studies of workers exposed to styrene found symptoms of CNS depression (decreased coordination
and concentration) and abnormal EEG patterns (electrical activity of the brain) in some of the workers.
These effects were thought to be reversible. Skin Contact: Repeated or prolonged contact may cause
blistering and dermatitis (itching, drying, redness). Effects on the Eyes: A study of workers in a styrene
plant found no evidence of eye disorders, other than occasional irritation.

Reproductive :
No human information. No adverse reproductive effects Effect were seen in a 3-generation rat study.

Teratogenicity :
In 2 case reports, women exposed to styrene at work during pregnancy gave birth to children with central
nervous system defects. The significance of the reports is unclear because the women were exposed to
other chemicals and such defects can occur by chance. Styrene was not teratogenic in two animal tests.

Mutagenicity :
Styrene and styrene oxide (a metabolite) are positive mutagens in a number of short term tests.

Carcinogenicity : Styrene is "Possibly carcinogenic to humans" (Group 2B, IARC, 1987)

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0336
========================================================================
FIRST AID MEASURES
========================================================================

Skin : Remove contaminated clothing. Wash skin thoroughly with soap and water.
Eye : Flush immediately with clean water for at least 15 minutes. Obtain medical attention.
Breathing : Remove to fresh air. Assist breathing if necessary. Obtain medical attention.
Swallowing : DO NOT INDUCE vomiting. Obtain medical attention immediately.

An Emergency Medical Response Protocol is available for this product. These are available to first
responders and medical personnel.

NOTES TO PHYSICIAN:
Styrene is rapidly absorbed by the lungs and gastrointestinal tract. It is not considered highly toxic but
exposure to high concentrations will produce CNS depression: headache, nausea, vomiting, dizziness,
emphoria, poor judgement, slurred speech and behavioral disturbances. Severe effects include blurred
vision, delirium, tremors, shallow and rapid respiration, unconsciousness, coma and death. There is no
specific antidote for styrene poisoning. Treatment consists of supportive measures such as oxygen (by
mask). Sympathomimetics or catecholamines should be avoided or used with caution to avoid inducing
ventricular fibrillation.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls:
Sufficient to keep exposure levels below permissible limits. In confined areas, local and general
ventilation should be provided to maintain airborne concentrations below permissible exposure limits.
Ventilation systems must be designed according to approved engineering standards.

PERSONAL PROTECTIVE EQUIPMENT (PPE)

Gloves:
Use chemically resistant gloves (PVA, Viton) to minimize skin contact. Respiratory Wear a NIOSH
approved organic vapour respirator if necessary, to prevent over-exposure.

Eye: Monogoggles or face shield.

Footwear: Appropriate safety footwear.
Clothing Appropriate to prevent skin contact. Chemical resistant apron if splashing is possible.
Other: Not applicable.

PPE must not be considered a long term solution to exposure control. PPE must be accompanied by
employer programs to properly select, maintain, clean, fit and use. Consult a competent industrial hygiene
resource to determine hazard potential and/or the PPE manufacturers to ensure adequate protection.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Exposure Limits:
Styrene:
ACGIH TLV-TWA = 50 ppm,
TLV-STEL = 100 ppm - Skin notation;
OSHA PEL- TWA = 100 ppm
Mexico: Maximum Permissible Concentration TWA = 50 ppm;
STEL = 100 ppm Consult local authorities for acceptable exposure limits.

Storage:
Store below 31°C. Use t-Butyl catechol (TBC) at levels between 10 ppm and 50 ppm to inhibit chemical
reaction. Store in totally enclosed equipment, designed to avoid human contact. Avoid storage with
incompatible materials. Monitor inhibitor content and polymer formation. Complete elimination of
dissolved oxygen in the monomer rapidly causes polymerization.

Handling:
Handle as flammable liquid. No smoking or open flame in storage, use or handling areas. Use explosion
proof electrical equipment. Ensure proper electrical grounding procedures are in place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill or Leak Response:

Styrene is a flammable liquid subject to polymerization if the inhibitor becomes depleted. Spill or leak
area should be isolated immediately for 25-50 meters (80-160 feet). Keep upwind. Keep out of low
areas. Ventilate closed spaces before entering. Shut off leak, if without risk. Use water spray to disperse
vapours. Eliminate all ignition sources, contain spill and use sorbent materials. Polymerization reactions
can occur with some sorbent materials: acids, bases and/or soil. Pretesting of available sorbents for
compatibility under controlled conditions is recommended. Use clean non-sparking materials to collect
absorbed materials. Recover styrene; prevent it from entering sewer, drains or waterways. Restrict
access of unprotected personnel. SCBA and protective clothing must be worn. For large spills consider
evacuation for 300 meters (1000 feet). A vapour suppressing foam or water spray may be used to control
vapours. Do not get water inside containing vessels.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0346

Material Safety Data Sheet

City University of Hong Kong

MSDS PETROLEUM ETHER 0346

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name and Synonyms: Petroleum ether; Ligroine; Petroleum benzin

Chinese Name:
Chemical Family: Paraffin hydrocarbon
Chemical Formula: Mixture
Product Use: Laboratory solvent

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Physical State: Liquid

Odour and Appearance: Clear liquid, mild gasoline-like odour
Odour Threshold (ppm): 300-500 ppm

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapour Pressure (mm Hg): 7.99 psi @ 20°C
Vapour Density (Air=1): 2.5
Evaporation Rate: >1 (n-butyl acetate =1)
Boiling Point (°C): 37 to 60°C
Freezing Point (°C): -73°C
pH: Not applicable
Specific Gravity: 0.643
Coefficient of Water/Oil distribution: No data

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Flammability: Flammable. Vapour can travel to distant sources of ignition and flash back
Extinguishing Media: Foam, dry chemical, CO2
Flash Point (Method Used): -49°C (TCC)
Autoignition Temperature: 245°C
Upper Flammable Limit (% by volume): 7.8%
Lower Flammable Limit (% by volume): 1.4%
Hazardous Combustion Products: COx, hydrocarbons
Sensitivity to Impact: No
Sensitivity to Static discharge: May be ignited by static discharge

========================================================================
REACTIVITY DATA
========================================================================

Chemical Stability: Stable

Incompatibility with other substances:
Avoid strong oxidizing agents (e.g. Peroxides, nitrates and perchlorates), acids, bases, amines

Reactivity: Avoid heat, sparks and open flame.

Hazardous Decomposition Products: COx, hydrocarbons

========================================================================
HEALTH HAZARD DATA
========================================================================

Toxicological Data:
LD50: (ivn, mouse) 40 mg/kg
LC50: (inhalation, rat) 3400 ppm/4 hours
Effects of Acute Exposure to Product:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0346
Inhaled:
High concentrations cause dizziness and headache, nausea, confusion and loss of consciousness.

In contact with skin:

Brief contact is not irritating. Extreme contact may cause itching, redness, pigmentation, swelling,
burning and pain.

In contact with eyes:

May cause eye irritation including pain, inflammation of the iris and mucous membranes, redness and
tearing.

Ingested:
May cause central nervous system depression, hemorrhaging of mucous membranes and diarrhea.

Effects of Chronic Exposure to Product:

Carcinogenicity: No information available
Teratogenicity: No information available
Reproductive Effects: Insufficient data
Mutagenicity: Negative in Ames Test
Synergistic Products: None known

========================================================================
FIRST AID MEASURES
========================================================================

Eyes:
IMMEDIATELY flush eyes with warm running water for a minimum of fifteen (15) minutes, holding
eyelids open while flushing. If irritation persists repeat flushing and obtain medical advice immediately.
(Flushing may be continued while casualty is transported to medical facility.)

Skin:
IMMEDIATELY flush exposed area with large amounts of warm running water while removing
contaminated clothing (including rings, watches and shoes). Continue flushing the area up to twenty (20)
minutes. If irritation persist, repeat flushing and obtain medical advice immediately.

Inhalation:
IMMEDIATELY remove casualty from contaminated area to fresh air (caution must be used by rescuers
to avoid exposure to contaminating fumes). Five oxygen for breathing difficulty. If breathing has stopped
give artificial respiration. If breathing and pulse are absent, give CPR. IMMEDIATELY OBTAIN
MEDICAL ATTENTION. Stay with casualty until medical assistance is reached.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Ingestion:
Do not induce vomiting. Danger of aspiration with emesis. If casualty is alert and not convulsing, rinse
out mouth with water. Immediately get medical attention. If spontaneous vomiting occurs have casualty
lean forward with head down to avoid breathing in of vomitus.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls: Local exhaust ventilation required.

Respiratory Protection:
NIOSH/MSHA approved respirator or self-contained breathing apparatus for exposures exceeding TLV.

Eye Protection: Chemical safety goggles.

Skin Protection: Neoprene gloves, Plastic apron, sleeves, boots, as appropriate.
Other Personal Protective Equipment: Safety shower and eye wash readily available in work area.

Handling Procedures and Equipment:

Keep away from heat, sparks, and flame and all sources of ignition. Ground and bond during liquid
transfer. Use non- sparking tools. Avoid contact with eyes, skin and clothing. Avoid breathing vapour.

Storage Requirements:
Store in a cool, dry, well-ventilated area, out of direct sunlight. Keep away from incompatible materials
and heat, sparks and flame.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Leak and Spill Procedure:

Evacuate area, provide maximum ventilation and protect from ignition. Contain spill and collect using
inert absorbent material. Transfer to container and arrange removal by disposal company. Wash site of
spillage thoroughly with detergent and water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0351

Material Safety Data Sheet

City University of Hong Kong

MSDS Chloroacetic acid 0351

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Chloroacetic acid

Chinese Name:
CAS: 79-11-8

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Physical State: Solid.

Odor and Appearance: Pungent acidic odor.
Taste: Not available.
Molecular Weight: Not available.
pH (1% soln/water) : Not available.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Colour: White.
Boiling Point: 189 °C (372.2 °F)
Melting Point: 62 °C (143.6°F)
Critical Temperature: Not available.
Specific Gravity: 1 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: 3.3 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Evaporation rate: Not available.
Viscosity: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not available.
Solubility: Not available.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

The Product is: May be combustible at high temperature.

Auto-Ignition Temperature: 470°C (878°F)
Flash Points: CLOSED CUP: 126°C (258.8°F). (Pensky-Martens.)
Flammable Limit: Not available.
Products of Combustion:
Products of combustion: Very toxic substances including carbon monoxide, hydrochloric acid and
formaldehyde are produced by the thermal decomposition of this product.

Fire Hazards in Presence of Various Substances: Not available.

Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.

========================================================================
REACTIVITY DATA
========================================================================

Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability: Thermal decomposition occurs above 250C.
Incompatibility with various substances: Not available.
Corrosivity: Not available.
Special Remarks on Reactivity:
Thermal decomposition products include toxic and corrosive hydrogen chloride gas, oxides of carbon
and formaldehyde.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0351

Conditions to Avoid:
Contact with strong bases, amines, base metals and prolonged storage at elevated temperatures should be
avoided.
Special Remarks on Corrosivity: Not available.
Hazardous Polymerization: Will not occur.

========================================================================
HEALTH HAZARD DATA
========================================================================

Potential Acute Health Effects:

Extremely hazardous in case of skin contact (corrosive), of eye contact (corrosive). Very hazardous in
case of ingestion, of inhalation. The amount of tissue damage depends on length of contact. Eye contact
can result in corneal damage or blindness. Skin contact can produce inflammation and blistering.
Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by
burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking,
unconsciousness or death.

Potential Chronic Health Effects :

CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY:
Not available. The substance may be toxic to kidneys, lungs, liver, heart, brain, upper respiratory tract,
central nervous system (CNS), teeth. Repeated or prolonged exposure to the substance can produce
target organs damage. Repeated exposure of the eyes to a low level of dust can produce eye irritation.
Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust
can produce varying degree of respiratory irritation or lung damage. Repeated exposure to an highly
toxic material may produce general deterioration of health by an accumulation in one or many human
organs.

Chronic Effects on Humans:

CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY:
Not available. The substance may be toxic to kidneys, lungs, liver, heart, brain, upper respiratory tract,
central nervous system (CNS), teeth. Repeated or prolonged exposure to the substance can produce
target organs damage. Repeated exposure of the eyes to a low level of dust can produce eye irritation.
Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust
can produce varying degree of respiratory irritation or lung damage. Repeated exposure to an highly

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 toxic material may produce general deterioration of health by an accumulation in one or many human
organs.

Other Toxic Effects on Humans:

Extremely hazardous in case of skin contact (corrosive), of eye contact (corrosive). Very hazardous in
case of ingestion, of inhalation. The amount of tissue damage depends on length of contact. Eye contact
can result in corneal damage or blindness. Skin contact can produce inflammation and blistering.
Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by
burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking,
unconsciousness or death.

Special Remarks on Toxicity to Animals:

It has been reported the MCA, when administered to pregnant rats at 140mg/kg caused malformations in
the cardiovasucular system of the fetuses, however, skeletal malformations were not observed.

Special Remarks on Chronic Effects on Humans: No additional remark.

Special Remarks on Other Toxic Effects on Humans:
Inhalation Chronic Exposure:
Repeated or prolonged inhalation exposure may cause erosion of teeth, inflammatory and ulcerative
changes in the mouth, and possible jaw necrosis. Nasal ulceration, bronchial irritation, and chronic
cough may result from repeated or prolonged inhalation exposure. Gastrointestinal disturbances may be
caused by repeated or prolonged inhalation.

========================================================================
FIRST AID MEASURES
========================================================================

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Get medical attention immediately.

Skin Contact:
Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Thoroughly clean shoes before reuse. A solution of sodium bicarbonate (3-5%) may be used to
neutralize the monochloroacetic acid. When making the treatment bath, use approximately 1 lb of sodium
carbonate (baking soda) per gallon of water.

Hazardous Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek
immediate medical attention.

Inhalation:
Get medical attention immediately. If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen.

Hazardous Inhalation: Not available.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0351
Ingestion:
DO NOT induce vomiting. Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Control:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels
below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to
keep exposure to airborne contaminants below the exposure limit.

Personal Protection:
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified
respirator or equivalent. Gloves.

Exposure Limits: Not available.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning
by spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.

Large Spill:
Corrosive solid. Poisonous solid. Stop leak if without risk. DO NOT get water inside container. DO
NOT touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or
confined areas; dike if needed. Eliminate all sources of ignition. Call for assistance on disposal. Finish
cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary
system.

Spill:
Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.

City University of Hong Kong 5

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0376

Material Safety Data Sheet

City University of Hong Kong

MSDS FERRIC CHLORIDE 0376

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : FERRIC CHLORIDE

Chinese Name:
Synonyms: Iron chloride hexahydrate; ferric trichloride hexahydrate
CAS No: 7705-08-0
Molecular Weight: 270.30
Chemical Formula: FeCl 3 6H2O

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Yellow brown deliquescent crystals.

Boiling Point: No information found.
Odor: Slight odor of hydrochloric acid.
Melting Point: 37°C (99°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Soluble in water.
Vapor Density (Air=1): No information found.
Density: 2.90 @ 25°C/4°C
Vapor Pressure (mm Hg): 1.1 @ 194°C (381°F)
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard. Irritating hydrogen chloride fumes may form in fire.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media:
Water, dry chemical, foam or carbon dioxide. Do not allow water runoff to enter sewers or waterways.

Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Emits toxic fumes of chloride when heated to decomposition.
Hazardous Polymerization: This substance does not polymerize.
Incompatibilities:
Metals, allyl chloride, sodium, potassium. Will react with water to produce toxic and corrosive fumes.

Conditions to Avoid: Incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Danger! Corrosive. Causes burns to any area of contact. Harmful if swallowed or inhaled. Affects the liver.

Potential Health Effects

Inhalation:
Extremely destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms may include
burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.

Ingestion:
Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach. Can cause sore throat, vomiting,
diarrhea. Low toxicity in small quantities but larger doses (30 mg/kg) may cause nausea, vomiting and diarrhea. Pink
urine discoloration is a strong indicator of iron poisoning. Liver damage, coma and death may follow, sometimes
delayed as long as three days.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0376

Skin Contact: Corrosive. Symptoms of redness, pain, and severe burn can occur.
Eye Contact: Corrosive. Contact can cause blurred vision, redness, pain and severe tissue burns.
Chronic Exposure:
Repeated ingestion may cause liver damage. Prolonged exposure of the eyes may cause discoloration.

Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.

Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an
unconscious person. Get medical attention immediately.

Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

-ACGIH Threshold Limit Value (TLV): 1 mg/m3 (TWA) soluble iron salt as Fe

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit
or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever
is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use
concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection:
Maintain eye wash fountain and quick-drench facilities in work area. Use chemical safety goggles and/or full face
shield where dusting or splashing of solutions is possible.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from incompatible substances. Containers of this material may be hazardous when empty since they retain product
residues (dust, solids); observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate
personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for
reclamation or disposal, using a method that does not generate dust. US Regulations (CERCLA) require reporting
spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast
Guard National Response Center is (800) 424-8802.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0378

Material Safety Data Sheet

City University of Hong Kong

MSDS LEAD METAL 0378

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : LEAD METAL

Chinese Name:
Synonyms: Granular lead, pigment metal; C.I. 77575
CAS No: 7439-92-1
Molecular Weight: 207.19
Chemical Formula: Pb

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Small, white to blue-gray metallic shot or granules.

Boiling Point: 1740°C (3164°F)
Odor: Odorless.
Melting Point: 327.5°C (622°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Insoluble in water.
Vapor Density (Air=1): No information found.
Density: 11.34
Vapor Pressure (mm Hg): 1.77 @ 1000°C (1832°F)
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard. Powder/dust is flammable when heated or exposed to flame.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire. Do not allow water runoff to enter sewers or waterways.

Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode. Can produce toxic lead fumes at
elevated temperatures and also react with oxidizing materials.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products:
Does not decompose but toxic lead or lead oxide fumes may form at elevated temperatures.

Hazardous Polymerization: Will not occur.

Incompatibilities:
Ammonium nitrate, chlorine trifluoride, hydrogen peroxide, sodium azide, zirconium, disodium acetylide, sodium
acetylide and oxidants.

Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Poison! Danger! May be fatal if swallowed or inhaled. Causes irritation to skin, eyes and respiratory tract.
Neurotoxin. Affects the gum tissue, central nervous system, kidneys, blood and reproductive system. Possible
cancer hazard. May cause cancer based on animal data. Risk of cancer depends on duration and level of exposure.

Potential Health Effects

Inhalation:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0378
Lead can be absorbed through the respiratory system. Local irritation of bronchia and lungs can occur and, in cases
of acute exposure, symptoms such as metallic taste, chest and abdominal pain, and increased lead blood levels may
follow. See also Ingestion.

Ingestion:
Poison! The symptoms of lead poisoning include abdominal pain and spasms, nausea, vomiting, headache. Acute
poisoning can lead to muscle weakness, "lead line" on the gums, metallic taste, definite loss of appetite, insomnia,
dizziness, high lead levels in blood and urine with shock, coma and death in extreme cases.

Skin Contact:
Lead and lead compounds may be absorbed through the skin on prolonged exposure; the symptoms of lead poisoning
described for ingestion exposure may occur. Contact over short periods may cause local irritation, redness and pain.

Eye Contact:
Absorption can occur through eye tissues but the more common hazards are local irritation or abrasion.

Chronic Exposure:
Lead is a cumulative poison and exposure even to small amounts can raise the body's content to toxic levels. The
symptoms of chronic exposure are like those of ingestion poisoning; restlessness, irritability, visual disturbances,
hypertension and gray facial color may also be noted.

Aggravation of Pre-existing Conditions:

Persons with pre-existing kidney, nerve or circulatory disorders or with skin or eye problems may be more
susceptible to the effects of this substance.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Get medical attention.

Skin Contact:
Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and
shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Airborne Exposure Limits:
For lead, metal and inorganic dusts and fumes, as Pb:
-OSHA Permissible Exposure Limit (PEL): 0.05 mg/m3 (TWA)
For lead, elemental and inorganic compounds, as Pb:
-ACGIH Threshold Limit Value (TLV): 0.05 mg/m3 (TWA), A3 animal carcinogen
ACGIH Biological Exposure Indices (BEI): 30 ug/100ml, notation B
For lead, inorganic: -NIOSH Recommended Exposure Limit (REL): 0.1 mg/m3 (TWA)

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a half-face high efficiency dust/mist respirator may be worn for up to ten times
the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator
supplier, whichever is lowest. A full-face piece high efficiency dust/mist respirator may be worn up to 50 times the
exposure limit, or the maximum use concentration specified by the appropriate regulatory agency or respirator
supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-
facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in
oxygen-deficient atmospheres.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain
eye wash fountain and quick-drench facilities in work area.

Other Control Measures:

Eating, drinking, and smoking should not be permitted in areas where solids or liquids containing lead compounds
are handled, processed, or stored.

See OSHA substance-specific standard for more information on personal protective equipment, engineering and
work practice controls, medical surveillance, record keeping, and reporting requirements. (29 CFR 1910.1025).

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from incompatible substances. Areas in which exposure to lead metal or lead compounds may occur should be
identified by signs or appropriate means, and access to the area should be limited to authorized persons. Containers
of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings
and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of
reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0379

Material Safety Data Sheet

City University of Hong Kong

MSDS Litmus 0379

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : Litmus

Chinese Name:
Synonyms: Lacmus, Lichenblue
CAS No: 1393-92-6
Molecular Weight: Not applicable.
Chemical Formula: Not applicable.

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Blue Powder.

Boiling Point: No information found.
Odor: No information found.
Melting Point: No information found.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Moderate (1-10%)
Vapor Density (Air=1): Not applicable.
Specific Gravity: No information found.
Vapor Pressure (mm Hg): Not applicable.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not expected to be a fire hazard.

Explosion: None identified.
Fire Extinguishing Media: Water, dry chemical, foam or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: No information found.
Hazardous Polymerization: Will not occur.
Incompatibilities: No information found.
Conditions to Avoid: No information found.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Warning! Harmful if swallowed, inhaled or absorbed through skin. Causes irritation.

Potential Health Effects

Inhalation: Is harmful
Ingestion: May be irritant to the gastro-intestinal tract.
Skin Contact: Is irritating, May be absorbed through the skin with possible systemic effects.
Eye Contact: Is irritating.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0379
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Prompt action is essential.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Get medical attention.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.
Note to Physician: This material is anticipated to have low toxicity. Treatment is symptomatic and supportive.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved): Not expected to require personal respirator usage.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain
eye wash fountain and quick-drench facilities in work area.

Other Control Measures:

There is insufficient data in the published literature to assign complete numerical SAF-T-DATA* ratings and
laboratory protective equipment for this product. Special precautions must be used in storage, use and handling.
Protective equipment for laboratory bench use should be chosen using professional judgement based on the size and
type of reaction or test to be conducted and the available ventilation, with overriding consideration to minimize
contact with the chemical.

Handling and Storage:

Keep container tightly closed. Suitable for any general chemical storage area. Containers of this material may be
hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed
for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place material
into clean, dry container and cover; remove from area. Flush spill area with water.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0380

Material Safety Data Sheet

City University of Hong Kong

MSDS Magnesium Carbonate, n-Hydrate 0380

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : Magnesium Carbonate, n-Hydrate

Chinese Name:
Synonyms: Magnesium (II) Carbonate, Hydrate; Magnesium carbonate (1:1) hydrate
CAS No: 546-93-0 (USP: 23389-33-5).
Molecular Weight: Not applicable to mixtures.
Chemical Formula: MgCO3.nH2O

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White Powder.

Boiling Point: No information found.
Odor: Odorless.
Melting Point: No information found.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Negligible (< 0.1%)
Vapor Density (Air=1): Not applicable.
Specific Gravity: 2.95
Vapor Pressure (mm Hg): Not applicable.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability:
Stable under ordinary conditions of use and storage. Magnesium carbonate reacts with acids to liberate carbon
dioxide.

Hazardous Decomposition Products: Forms magnesium oxide and carbon dioxide when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Formaldehyde.
Conditions to Avoid: Incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview: Caution! May cause irritation to eyes and respiratory tract.
Potential Health Effects
Inhalation:
May cause irritation to the respiratory tract. Symptoms may include coughing and shortness of breath.

Ingestion:
Magnesium carbonate is a food additive and non-toxic unless ingested in very large quantities. May cause diarrhea.

Skin Contact: No adverse effects expected. May cause mild irritation and redness.
Eye Contact: May cause irritation, redness and pain.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0380

FIRST AID MEASURES

========================================================================

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact: Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally.
Get medical attention if irritation persists.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

- OSHA Permissible Exposure Limit (PEL): 15 mg/m3 total dust, 5 mg/m3 respirable fraction for nuisance dusts.
- ACGIH Threshold Limit Value (TLV):
10 mg/m3 total dust containing no asbestos and < 1% crystalline silica for Particulates Not Otherwise Classified
(PNOC).

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit
or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever
is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use
concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers
of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings
and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0383

Material Safety Data Sheet

City University of Hong Kong

MSDS METHYLENE BLUE 0383

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : METHYLENE BLUE

Chinese Name:
Synonyms:
Basic Blue 9,trihydrate; Methelyne blue trihydrate; 3,7-Bis(dimethylamino) phenazathionium chloride trihydrate

CAS No: 61-73-4

Molecular Weight: 373.91
Chemical Formula: C16H18ClN3S . 3H2O

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Dark green crystals with bronze luster or crystalline powder.

Boiling Point: Decomposes.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odor: Odorless.
Melting Point: 100 - 110°C (212 - 230°F)
Solubility: Soluble in water.
Vapor Density (Air=1): 13
Specific Gravity: No information found.
Vapor Pressure (mm Hg): Not applicable.
pH: No information found
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Methylene blue does not burn. Not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products:
May produce oxides of nitrogen, sulfur and carbon when heated to decomposition.

Hazardous Polymerization: Will not occur.

Incompatibilities:
Strong oxidizing agents, alkali, dichromates, alkali iodides, reducing agents.

Conditions to Avoid: Heat, flame, ignition sources, dusting and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview: Warning! Harmful if swallowed.

Potential Health Effects: This material is relatively nonhazardous in routine industrial situations.
Inhalation:
No adverse health effects expected from inhalation. May cause a short period of rapid or difficult breathing.

Ingestion:
A burning sensation of the mouth may be noted following ingestion of methylene blue. May cause nausea, vomiting,
diarrhea, and gastritis. Large doses may cause abdominal and chest pain, headache, profuse sweating, mental
confusion, painful micturation, and methemoglobinemia.

Skin Contact:
Not expected to be a health hazard from skin exposure. Methylene blue may color the skin a bluish color. May cause
photosensitization.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0383

Eye Contact: No adverse effects expected. May cause mechanical irritation.

Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person.

Skin Contact:
Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and
shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation
develops.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally.
Get medical attention if irritation persists.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
In general, dilution ventilation is a satisfactory health hazard control for this substance. However, if conditions of
use create discomfort to the worker, a local exhaust system should be considered.

Personal Respirators (NIOSH Approved):

Not expected to require personal respirator usage. For conditions of use where exposure to the dust or mist is
apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are
not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not
protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain
eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Avoid dust
formation and control ignition sources. Isolate from incompatible substances. Containers of this material may be
hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed
for the product.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0384

Material Safety Data Sheet

City University of Hong Kong

MSDS PHOSPHORUS TRICHLORIDE 0384

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : PHOSPHORUS TRICHLORIDE

Chinese Name:
Synonyms: Phosphorus Chloride; Chloride of Phosphorus
CAS No: 7719-12-2
Molecular Weight: 137.32
Chemical Formula: PCl 3

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Colorless, fuming liquid.

Boiling Point: 75.3°C (167°F)
Odor: Pungent, irritating odor.
Melting Point: -111.8°C (-170°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Decomposes exothermically in water.
Vapor Density (Air=1): 4.75
Specific Gravity: 1.57 @ 21°C
Vapor Pressure (mm Hg): 100 @ 21°C (70°F)
pH: No information found.
Evaporation Rate (BuAc=1): > 1
% Volatiles by volume @ 21°C (70°F): 100

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Non-flammable but reacts exothermically with water and may produce flashes of fire. Substance is a strong oxidizer
and its heat of reaction with reducing agents or combustibles may cause ignition.

Explosion: Not considered to be an explosion hazard.

Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Do not use water.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode. In contact with water, may be an
ignition source. Reacts with water to produce hydrochloric acid and phosphoric acid. The reaction may lead to flash
fires die to the spontaneous ignition of diphosphine. Hydrochloric and phosphoric acid will react with most
common metals except nickel and lead, to form flammable and potentially explosive hydrogen gas.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products:
Hydrogen chloride, hydrochloric and phosphorous acids at high temperatures or in contact with water. Thermal
decomposition products may also include phosphine and diphosphine.

Hazardous Polymerization: Will not occur.

Incompatibilities:
Water, potassium or sodium metal, strong oxidants, hydroxylamine, nitric acid, alcohols, fluorine and lead oxide.
Phosphorous trichloride is corrosive to most common construction materials, especially if moisture is present.
(Steel corrosion at 0.5 - 3 mils per year would be expected).

Conditions to Avoid: Moisture and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Danger! Corrosive. May be fatal if swallowed or inhaled. Causes burns to any area of contact. May cause delayed
lung injury. Water reactive. Contact with water or moist air liberates corrosive hydrochloric and phosphoric acid and
may cause flash fires. Strong oxidizer. Contact with other material may cause fire.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0384

Potential Health Effects

Inhalation:
Corrosive. Extremely destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms may
include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.
Inhalation may be fatal as a result of spasm inflammation and edema of the larynx and bronchi, chemical
pneumonitis and pulmonary edema.

Ingestion:
Corrosive, causes severe burns. Forms hydrochloric and phosphorous acids by hydrolysis. Symptoms include
abdominal pain, vomiting, diarrhea. Aspiration of the swallowed product or vomitus can cause severe pulmonary
complications. Ingestion may be fatal.

Skin Contact:
Corrosive, causes severe burns. Local pain, redness, and possible acid burns on acute or prolonged contact. Vapors
can cause irritation, as seen by redness and swelling.

Eye Contact:
Corrosive, causes severe burns. Vapors can cause pain, redness, and blurred vision. Irreversible eye damage can
occur from vapors and liquid splashes.

Chronic Exposure:
Chronic ingestion or inhalation may induce systemic phosphorous poisoning. Liver damage, kidney damage,
jaw/tooth abnormalities, blood disorders and cardiovascular effects can result.

Aggravation of Pre-existing Conditions:

Persons with pre-existing skin disorders or eye problems, jaw/tooth abnormalities, or impaired liver, kidney or
respiratory function may be more susceptible to the effects of the substance.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.

Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an
unconscious person. Get medical attention immediately.

Skin Contact:
Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse.
Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

-OSHA Permissible Exposure Limit (PEL): 0.5 ppm (TWA)
-ACGIH Threshold Limit Value (TLV): 0.2 ppm (TWA), 0.5 ppm (STEL)

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, wear a supplied air, full-facepiece respirator, airlined hood, or full-facepiece self-
contained breathing apparatus. This substance has unknown warning properties.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and
quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage and
moisture. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from incompatibles,
combustibles, organic or other readily oxidizable materials. Isolate from incompatible substances. Keep away from
water. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid);
observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate the area of the leak or spill. Clean-up personnel require protective clothing and respiratory protection
from vapors. Keep out of sewers and surface waters. Contain spill and collect if possible. Arrange with supplier to
ship back recovered material for reclamation. If recovery is not possible, cover spill with dry sand. Cover this with
excess soda ash/slaked lime (1:1 mix). Cautiously spray with a small amount of water (exothermic reaction), then
saturate with water and mix. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in
excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800)
424-8802.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0393

Material Safety Data Sheet

City University of Hong Kong

MSDS ACETAMIDE 0393

========================================================================
PRODUCT INFORMATION
========================================================================

Product Name: Acetamide

Chinese Name:
Common Synonyms: Acetic Acid Amide; Methanecarboxamide; Ethanamide
Chemical Family: Amides
Formula: CH3CONH2
Formula wt.: 59.07
CAS no.: 60-35-5

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Boiling Point: 222°C (431°F) Vapor Pressure (mmHg): 1

(At 760 mm Hg) (65°C)
Melting Point: 81°C (177°F) Vapor Density (Air=1): N/A

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 (At 760 mm Hg)
Specific Gravity: 1.16 Evaporation Rate: N/A
(H2O=1)
Solubility(H2O): Appreciable (>10%) % Volatiles By Volume: 0
(21°C)
pH: N/A
Odor Threshold (P.P.M.): N/A Physical State: Solid
Coefficient Water/Oil Distribution: N/A
Appearance & Odor: Colorless Crystals. Faint Odor.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Flash Point (Closed Cup): N/A

Autoignition Temperature: N/A
Flammable Limits: Upper - N/A Lower - N/A
Fire Extinguishing Media : Use extinguishing media appropriate for surrounding fire.
Special Fire-Fighting Procedures
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full facepiece
operated in positive pressure mode.

Unusual Fire & Explosion Hazards : None identified.

Toxic Gases Produced : Cyanides, oxides of nitrogen, carbon monoxide, carbon dioxide
Explosion Data-Sensitivity To Mechanical Impact : None identified.
Explosion Data-Sensitivity To Static Discharge: None identified.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid: Heat, flame, other sources of ignition, air, light
Incompatibles: Strong acids, strong oxidizing agents
Decomposition products: Cyanides, oxides of nitrogen, carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Threshold Limit Value (TLV/TWA): Not established

Short-Term Exposure Limit (STEL): Not established
Permissible Exposure Limit (PEL): Not established
Toxicity Of Components :
Oral Rat LD50 For Acetamide 7000 mg/Kg
Intraperitoneal Mouse LD50 For Acetamide 10 m/Kg
Subcutaneous Mouse LD50 For Acetamide 8300 mg/Kg
Carcinogenicity: NTP: No IARC: Yes Z List: No OSHA Reg: No

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0393
Carcinogenicity:
Some experiments with test animals indicated that this substance may be anticipated to be a carcinogen.

Reproductive Effects: None identified.

Effects Of Overexposure
Inhalation: Irritation of upper respiratory tract
Skin Contact: Irritation
Eye Contact: Irritation
Skin Absorption: None identified
Ingestion: None identified
Chronic Effects: None identified
Target Organs: None identified
Medical Conditions Generally Aggravated By Exposure: None identified
Primary Routes Of Entry: Inhalation, eye contact, skin contact

========================================================================
FIRST AID MEASURES
========================================================================

Ingestion: if swallowed and the person is conscious, immediately give large amounts of water. Get medical attention.
Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Skin Contact: In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.
Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation: Use adequate general or local exhaust ventilation to keep fume or dust levels as low as possible.
Respiratory Protection:
None required where adequate ventilation conditions exist. If airborne concentration is high, use an appropriate
respirator or dust mask.

Eye/Skin Protection: Safety goggles, butyl rubber gloves are recommended.

Storage Requirements : Keep container tightly closed. Suitable for any general chemical storage area.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps To Be Taken In The Event Of A Spill Or Discharge:

Wear suitable protective clothing. Carefully sweep up and remove.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0404

Material Safety Data Sheet

City University of Hong Kong

MSDS Ascorbic acid 0404

========================================================================
PRODUCT INFORMATION
========================================================================

Synonyms: Ascorbic acid

Chinese Name:
CAS No: 50-81-7
Molecular Weight: 176.13
Chemical Formula: C6H8O6

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White crystals.

Boiling Point: Not applicable.
Odor: Odorless.
Melting Point: 192°C (378°F) Slightly decomposes.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: 33g/100g water.
Vapor Density (Air=1): No information found.
Density: 1.65
Vapor Pressure (mm Hg): No information found.
pH: 3 for 5mg/L aqueous solution; 2 for 50mg/L aqueous solution.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.

Explosion: Not considered to be an explosion hazard.

Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability:
Stable under ordinary conditions of use and storage. Aqueous solutions are rapidly oxidized by air.

Hazardous Decomposition Products:

May produce acrid smoke and irritating fumes when heated to decomposition.

Hazardous Polymerization: Will not occur.

Incompatibilities:
Strong oxidizers and alkali hydroxides, alkalis, iron, copper, sodium salicylate, sodium nitrite, theobromine and
methenamine.

Conditions to Avoid: Air, light and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview:
As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the
chemical substance and ensure prompt removal from skin, eyes and clothing.

Potential Health Effects:

Ascorbic acid is relatively non-hazardous in routine industrial situations. It is not expected to present significant
health risks to the workers who use it.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0404
Inhalation: May cause mild irritation to the respiratory tract.
Ingestion: Large oral doses may cause gastrointestinal disturbances.
Skin Contact: May cause mild irritation.
Eye Contact: May cause mild irritation.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention if irritation persists.

Ingestion:
Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice.

Skin Contact:
Wash exposed area with soap and water. Get medical advice if irritation develops.

Eye Contact:
Wash thoroughly with running water. Get medical advice if irritation develops.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

- OSHA Permissible Exposure Limit (PEL):
15 mg/m3 total dust, 5 mg/m3 respirable fraction for nuisance dusts.

- ACGIH Threshold Limit Value (TLV):

10 mg/m3 total dust containing no asbestos and < 1% crystalline silica for Particulates Not Otherwise Classified
(PNOC).

Ventilation System:
In general, dilution ventilation is a satisfactory health hazard control for this substance. However, if conditions of
use create discomfort to the worker, a local exhaust system should be considered.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit
or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever
is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use
concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

Handling and Storage

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Store in
light-resistant containers. Isolate from any source of heat or ignition. Isolate from incompatible substances.
Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe
all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0413

Material Safety Data Sheet

City University of Hong Kong

MSDS METHYL ETHYL KETONE 0413

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name and Synonyms: 2-Butanone; ethyl methyl ketone; MEK; Methyl acetone
Chinese Name:
CAS No: 78-93-3
Molecular Weight: 72.11
Chemical Formula: CH3COCH2CH3

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Clear, colorless liquid.

Boiling Point: 80°C (176°F)
Odor: Sharp mint-like odor.
Melting Point: -86°C (-123°F)
Solubility: 29 g in 100 g of water.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapor Density (Air=1): 2.5
Specific Gravity: 0.81 @ 20°C/4C
Vapor Pressure (mm Hg): 78 @ 20°C (68°F)
pH: No information found.
Evaporation Rate (BuAc=1): 2.7 (Ether = 1)
% Volatiles by volume @ 21°C (70°F): 100

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Flash point: -9°C (16°F) CC
Autoignition temperature: 404°C (759°F)
Flammable limits in air % by volume: LEL: 1.4; UEL: 11.4
Extremely Flammable.

Explosion:
Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Vapors can flow along
surfaces to distant ignition source and flash back. Contact with strong oxidizers may cause fire. Sealed containers
may rupture when heated. Sensitive to static discharge.

Fire Extinguishing Media:

Dry chemical, foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool, dilute spills
to nonflammable mixtures, protect personnel attempting to stop leak and disperse vapors.

Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode. This highly flammable liquid must be
kept from sparks, open flame, hot surfaces, and all sources of heat and ignition.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities:
Oxidizing materials, caustics, amines, ammonia, strong bases, chloroform, chlorosulfonic acid, oleum, potassium-t-
butoxide, heat or flame, hydrogen peroxide, nitric acid. Can attack many plastics, resins and rubber.

Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0413
Danger! Extremely flammable liquid and vapor. Vapor may cause flash fire. Harmful or fatal if swallowed. Harmful
if inhaled or absorbed through skin. Affects central nervous system. Causes irritation to skin, eyes and respiratory
tract.

Potential Health Effects

Inhalation:
Causes irritation to the nose and throat. Concentrations above the TLV may cause headache, dizziness, nausea,
shortness of breath, and vomiting. Higher concentrations may cause central nervous system depression and
unconsciousness.

Ingestion:
May produce abdominal pain, nausea. Aspiration into lungs can produce severe lung damage and is a medical
emergency. Other symptoms expected to parallel inhalation.

Skin Contact:
Causes irritation to skin. Symptoms include redness, itching, and pain. May be absorbed through the skin with
possible systemic effects.

Eye Contact: Vapors are irritating to the eyes. Splashes can produce painful irritation and eye damage.

Chronic Exposure:
Prolonged skin contact may defeat the skin and produce dermatitis. Chronic exposure may cause central nervous
system effects.

Aggravation of Pre-existing Conditions:

Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible
to the effects of the substance.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Ingestion:
Aspiration hazard. If swallowed, vomiting may occur spontaneously, but DO NOT INDUCE. If vomiting occurs, keep
head below hips to prevent aspiration into lungs. Never give anything by mouth to an unconscious person. Call a
physician immediately.

Skin Contact:
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing
and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally.
Get medical attention.

========================================================================

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

-OSHA Permissible Exposure Limit (PEL): 200 ppm (TWA)
-ACGIH Threshold Limit Value (TLV): 200 ppm (TWA), 300 ppm (STEL)

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details. Use
explosion-proof equipment.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a full facepiece respirator with organic vapor cartridge may be worn up to 50
times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or
respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use
a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect
workers in oxygen-deficient atmospheres.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact. Butyl rubber is a suitable material for personal protective equipment.

Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and
quick-drench facilities in work area.

Handling and Storage:

Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire
hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be
bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use
non-sparking type tools and equipment, including explosion proof ventilation. Containers of this material may be
hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed
for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as
specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and
recover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an appropriate container or
absorb with an inert material (e. g., Vermiculite, dry sand, earth), and place in a chemical waste container. Do not use
combustible materials, such as saw dust. Do not flush to sewer! If a leak or spill has not ignited, use water spray to
disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0414

Material Safety Data Sheet

City University of Hong Kong

MSDS MALEIC ACID 0414

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name(s) : MALEIC ACID

Chinese Name:
Synonyms: (Z)-Butenedioic acid; cis-butenedioic acid; maleinic acid, toxilic acid
CAS No: 110-16-7
Molecular Weight: 116.08
Chemical Formula: HOCOCH:CHCOOH

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White crystals.

Boiling Point: 135C (275F) Decomposes.
Odor: Faint acidulous odor.
Melting Point: 130 - 139C (266 - 282F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Soluble in water.
Vapor Density (Air=1): 4.0
Density: 1.590 @ 20C/4C
Vapor Pressure (mm Hg): No information found.
pH: < 7 Acidic.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21C (70F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.

Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust
explosion hazard.

Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers.
Conditions to Avoid: Heat, dusting and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Danger! Corrosive. Causes severe eye irritation and possible burns. Causes irritation to skin and respiratory tract.
May be harmful if swallowed or absorbed through skin.

Potential Health Effects

Inhalation:
Inhalation of dust is irritating to the mucous membrane and upper respiratory tract. May cause coughing, sore throat,
shortness of breath.

Ingestion:
Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. May cause mild
burning of mouth, throat, and stomach.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0414
Skin Contact:
Causes irritation to skin. Symptoms include redness, itching, and pain. May be absorbed through the skin. Wet skin
may exacerbate skin exposure.

Eye Contact:
Causes severe eye irritation with redness and pain. May cause burns. May cause conjunctivitis or corneal damage.

Chronic Exposure:
Abnormalities of kidney function with protein in the urine may develop from chronic exposure.

Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Get medical attention.

Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn.
For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain
eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from incompatible substances. Containers of this material may be hazardous when empty since they retain product
residues (dust, solids); observe all warnings and precautions listed for the product. Avoid dust formation and control
ignition sources. Employ grounding, venting and explosion relief provisions in accord with accepted engineering
practices in any process capable of generating dust and/or static electricity. Empty only into inert or non-flammable
atmosphere. Emptying contents into a non-inert atmosphere where flammable vapors may be present could cause a
flash fire or explosion due to electrostatic discharge.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as
specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking
tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for
recovery or disposal and place in a closed container. US Regulations (CERCLA) require reporting spills and
releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard
National Response Center is (800) 424-8802.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0419

Material Safety Data Sheet

City University of Hong Kong

MSDS Castor Oil 0419

========================================================================
PRODUCT INFORMATION
========================================================================

chemical name(s) : Castor Oil, U.S.P.

Chinese Name:
Synonyms: Ricinus Oil
CAS No: 8001-79-4
Molecular Weight: Not applicable.
Chemical Formula: Not applicable.

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Light yellow viscous liquid.

Boiling Point: 313°C (595°F)
Odor: Slight characteristic odor.
Melting Point: -10°C (14°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Negligible (< 0.1%)
Vapor Density (Air=1): Not applicable.
Specific Gravity: 0.961-0.963 @ 15.5°C/15.5°C
Vapor Pressure (mm Hg): Not applicable.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 100

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Flash point: 229°C (444°F) CC
Autoignition temperature: 449°C (840°F)
Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.

Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire. Water or foam may cause frothing.

Special Information: Use protective clothing and breathing equipment appropriate for the surrounding fire.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers.
Conditions to Avoid: Excessive heat, freezing and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
As part of good industrial and personal hygiene and safety procedure, avoid
all unnecessary exposure to the chemical substance and ensure prompt
removal from skin, eyes and clothing.

Potential Health Effects

Inhalation: No adverse health effects expected from inhalation.
Ingestion: No adverse effects expected. Large oral doses may cause spasmodic intestinal or abdominal pain.
Skin Contact: Not expected to be a health hazard from skin exposure. May cause mild irritation and redness.
Eye Contact: No adverse effects expected. May cause mild irritation, possible reddening.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0419
========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Not expected to require first aid measures.

Ingestion: If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact:
Not expected to require first aid measures. Wash exposed area with soap and water. Get medical advice if irritation
develops.

Eye Contact:
Not expected to require first aid measures. Wash thoroughly with running water. Get medical advice if irritation
develops.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
In general, dilution ventilation is a satisfactory health hazard control for this substance. However, if conditions of
use create discomfort to the worker, a local exhaust system should be considered.

Personal Respirators (NIOSH Approved):

Airborne exposure is not expected to be a problem under ordinary handling conditions.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and
quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Protect
from excessive heat. Protect from freezing.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Contain
and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e. G.,
Vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as
saw dust. Small amounts of residue may be flushed to sewer with plenty of water.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0420

Material Safety Data Sheet

City University of Hong Kong

MSDS 2-CHLORO-2-METHYLPROPANE 0420

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : 2-CHLORO-2-METHYLPROPANE

Chinese Name:
Synonyms: tert-Butyl chloride; 2-chloroisobutane; Trimethylchloromethane
CAS No: 507-20-0
Molecular Weight: 92.57
Chemical Formula: (CH3)3CCl

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Clear, colorless liquid.

Boiling Point: 51 - 52°C (124 - 126°F)
Odor: No information found.
Melting Point: -25°C (-13°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Sparingly soluble in water.
Vapor Density (Air=1): 3.2
Specific Gravity: 0.87
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 100

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Flash point: < 0°C (< 32°F)
Flammable liquid.
Dangerous fire hazard when exposed to heat, flame, sparks, or oxidizers.

Explosion:
Above the flash point, explosive vapor-air mixtures may be formed. Vapors can flow along surfaces to distant
ignition source and flash back. Sealed containers may rupture when heated. Contact with strong oxidizers may cause
fire. Sensitive to static discharge.

Fire Extinguishing Media:

Dry chemical, alcohol foam or carbon dioxide. Water may be ineffective. Water spray may be used to keep fire
exposed containers cool, dilute spills to nonflammable mixtures, protect personnel attempting to stop leak and
disperse vapors.

Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products:
May emit oxides of carbon and hydrogen chloride gas when heated to decomposition.

Hazardous Polymerization: Will not occur.

Incompatibilities: Strong oxidizers and strong bases.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Warning! Flammable liquid and vapor. May be harmful if swallowed, inhaled or absorbed through skin. May affect
central nervous system. May cause irritation to skin, eyes, and respiratory tract.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0420

Potential Health Effects

There is limited information available on the hazards of this chemical. It is assumed that it will behave similarly to
other chlorinated hydrocarbons.

Inhalation:
No information found, but compound should be handled as a potential health hazard. May cause irritation to the
respiratory tract; symptoms may include coughing, shortness of breath, headache, and dullness. High concentrations
have a narcotic effect.

Ingestion: May cause abdominal pain, vomiting. Other symptoms parallel inhalation.
Skin Contact:
May cause irritation with redness and pain. May be absorbed through the skin with possible systemic effects.

Eye Contact: May cause irritation, redness and pain.

Chronic Exposure:
Similar compounds demonstrate toxic effects after repeated exposures too low to result in acute effects.

Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a
physician.

Ingestion:
Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical
attention.

Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before reuse. Call a physician.

Eye Contact:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Call a physician if irritation persists.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the substance is apparent, consult an industrial hygienist. For emergencies,
or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator.
WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and
quick-drench facilities in work area.

Handling and Storage:

Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire
hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be
bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use
non-sparking type tools and equipment, including explosion proof ventilation. Containers of this material may be
hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed
for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as
specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and
recover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an appropriate container or
absorb with an inert material (e. G., Vermiculite, dry sand, earth), and place in a chemical waste container. Do not
use combustible materials, such as saw dust. Do not flush to sewer! If a leak or spill has not ignited, use water spray
to disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures. J. T.
Baker SOLUSORB(R) solvent adsorbent is recommended for spills of this product.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0421

Material Safety Data Sheet

City University of Hong Kong

MSDS n-Butyl Chloride 0421

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name: n-Butyl Chloride

Chinese Name:
Chemical Family: Chlorinated Hydrocarbon
Molecular Weight: 92.57
Formula: C4H9Cl
Synonyms: Butyl Chloride, 1-Chlorobutane
CAS Number: 109-69-3

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Boiling Point, 760 mm Hg: 78.4°C

Vapor Pressure at 20°C: 80.1 mm Hg
% Volatiles by Volume: ca 100

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Freezing Point: -123.1°C
Vapor Density (air=1): 3.2
Specific Gravity (H2O=1): @ 20°C 0.886
Evaporation Rate: (BuAc=1) ca 10
Solubility in Water: @ 20°C 0.11%

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Flash Point (test method): -9°C (Tag closed cup)

Auto Ignition Temperature: 460°C
Flammable Limits in Air % by Volume: Lower Limit: 1.8 Upper Limit: 10.1
Unusual Fire and Explosion Hazards: Very volatile and extremely flammable
Extinguishing Media: Carbon dioxide, dry chemical or foam
Special Fire Fighting Procedures:
Wear full protective clothing and self-contained breathing apparatus. Heat will build pressure and may rupture
closed storage containers. Keep fire-exposed containers cool with water spray.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable
Hazardous Polymerization: Not expected to occur
Appearance and Odor: Clear, colorless liquid with a sharp, unpleasant odor
Conditions to Avoid: Heat, sparks, open flame, open containers, and poor ventilation
Materials to Avoid: Active metals and strong bases
Hazardous Decomposition Products:
Incomplete combustion can generate phosgene, hydrogen chloride, and other toxic vapors

========================================================================
HEALTH HAZARD DATA
========================================================================

Carcinogenic Data: n-Butyl Chloride is not listed as a carcinogen by IARC, NTP, OSHA, or ACGIH.
Primary Routes of Entry:
N-Butyl Chloride may exert its effects through inhalation, skin absorption, and ingestion.

Industrial Exposure: Route of Exposure/Signs and Symptoms

Inhalation: Exposure can cause depression or stimulation of the central nervous system.
Eye Contact: Liquid and high vapor concentration can cause irritation.
Skin Contact: Prolonged or repeated skin contact can cause mild irritation and dermatitis through defatting of skin.
Ingestion: Can cause gastrointestinal tract discomfort.
Effects of Overexposure:
N-Butyl Chloride is a mild irritant. Acute exposure irritates the eyes and upper respiratory tract. Chronic toxicity
properties have not been adequately determined.

Medical Condition Aggravated by Exposure: Preclude from exposure those individuals susceptible to dermatitis.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0421
========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Immediately remove to fresh air. If not breathing, administer mouth-to-mouth rescue breathing. If there is no pulse,
administer cardiopulmonary resuscitation (CPR). Contact physician immediately.

Eye Contact: Rinse with copious amounts of water for at least 15 minutes. Get emergency medical assistance.
Skin Contact:
Flush thoroughly for at least 15 minutes. Wash affected skin with soap and water. Remove contaminated clothing
and shoes. Wash clothing before re-use, and discard contaminated shoes. Get emergency medical assistance.

Ingestion:
Call local Poison Control Center for assistance. Contact physician immediately. Never induce vomiting or give
anything by mouth to a victim unconscious or having convulsions.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Ventilation:
Adequate ventilation is required to protect personnel from exposure to chemical vapors exceeding the PEL and to
minimize fire hazards. The choice of ventilation equipment, either local or general, will depend on the conditions of
use, quantity of material, and other operating parameters.

Respiratory:
Use approved respirator equipment. Follow NIOSH and equipment manufacturer's recommendations to determine
appropriate equipment (air-purifying, air-supplied, or self-contained breathing apparatus).

Eyes:
Safety glasses are considered minimum protection. Goggles or face shield may be necessary depending on quantity
of material and conditions of use.

Skin:
Protective gloves and clothing are recommended. The choice of material must be based on chemical resistance and
other user requirements. Generally, neoprene or nitrile rubber offers acceptable chemical resistance. Individuals
who are acutely and specifically sensitive to n-Butyl Chloride may require additional protective equipment.

Storage:
N-Butyl Chloride should be protected from temperature extremes and direct sunlight. Proper storage of n-Butyl
Chloride must be determined based on other materials stored and their hazards and potential chemical
incompatibility. In general, n-Butyl Chloride should be stored in an acceptably protected and secure flammable
liquid storage room.

Other:
Emergency eyewash fountains and safety showers should be available in the vicinity of any potential exposure.
Ground and bond metal containers to minimize static sparks.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spill Control:
Protect from ignition. Wear protective clothing and use approved respirator equipment. Absorb spilled material in
an absorbent recommended for solvent spills and remove to a safe location for disposal by approved methods. If
released to the environment, comply with all regulatory notification requirements. CERCLA Reportable Quantity:
None.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0422

Material Safety Data Sheet

City University of Hong Kong

MSDS COBALT CHLORIDE 0422

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : COBALT CHLORIDE

Chinese Name:
Synonyms: Cobaltous chloride, hexahydrate; cobalt (2+) chloride hexahydrate, cobalt dichloride
CAS No: 7646-79-9
Molecular Weight: 237.93
Chemical Formula: CoCl 2.6H2O

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Rose-red crystals.

Boiling Point: 110°C (230°F) (Loses 6H2O)
Odor: Odorless.
Melting Point: 86°C (187°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: 76.7 g/100 cc water @ 0°C
Vapor Density (Air=1): No information found.
Density: 1.92 @ 20°C
Vapor Pressure (mm Hg): 40 @ 770°C (1418°F)
pH: 4.6
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information: Use protective clothing and breathing equipment appropriate for the surrounding fire.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products:
Emits toxic chlorides and possibly cobalt fumes when heated to decomposition. Cobalt oxide fumes may form in
fire.

Hazardous Polymerization: Will not occur.

Incompatibilities:
Strong oxidizers, strong mineral acids, tert-butyl hydroperoxide, potassium and metal halides, sodium dispersions.

Conditions to Avoid: Incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Warning! Harmful if swallowed or inhaled. Causes irritation to skin, eyes and respiratory tract. May cause allergic
skin or respiratory reaction. Chronic exposure may affect thyroid, lungs, heart, and kidneys.

Potential Health Effects

Inhalation:
Causes irritation to the respiratory tract, symptoms may include coughing, shortness of breath, and nausea.
Respiratory hypersensitivity, asthma may appear. Inhalation of cobalt dust and fumes is associated with an increased
incidence of lung disease.

Ingestion:
Toxic. Causes abdominal pain, nausea, vomiting, flushing of the face and ears, mild hypotension, rash, and ringing in
the ears. May have cumulative toxic action where elimination cannot keep pace with absorption. Large amounts
depress erythrocyte production.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0422

Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. May cause dermatitis.
Eye Contact: Causes irritation, redness, and pain.
Chronic Exposure:
Repeated oral administration may produce goiter and reduced thyroid activity. Prolonged or repeated skin exposure
may cause dermatitis. Chronic exposure associated with kidney, liver, heart and lung damage.

Aggravation of Pre-existing Conditions:

Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be
more susceptible to the effects of the substance. Persons with allergies or sensitivity to cobalt may also be more
susceptible to the effects of the substance.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Get medical attention.

Skin Contact:
Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes.
Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean
shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

For Cobalt Compound:
-OSHA Permissible Exposure Limit (PEL): 0.1 mg/m3 (TWA) Cobalt metal dust and fume as Co
-ACGIH Threshold Limit Value (TLV): inorganic cobalt compounds: 0.02 mg/m3 (TWA) as Co,
A3: Animal carcinogen.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a half-face high efficiency dust/mist respirator may be worn for up to ten times
the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator
supplier, whichever is lowest. A full-face piece high efficiency dust/mist respirator may be worn up to 50 times the
exposure limit, or the maximum use concentration specified by the appropriate regulatory agency or respirator
supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-
facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in
oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain
eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from incompatible substances. Wash hands before eating and do not eat, drink, or smoke in workplace. Containers
of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings
and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of
reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0423

Material Safety Data Sheet

City University of Hong Kong

MSDS Cresol Red 0423

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : Cresol Red

Chinese Name:
Synonyms: Cresol Red test solution
CAS No: 1733-12-6
Molecular Weight: 382.42
Chemical Formula: C21H18O5S

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Clear, deep red solution.

Boiling Point: No information found.
Odor: No information found.
Melting Point: No information found.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: No information found.
Vapor Density (Air=1): No information found.
Specific Gravity: No information found.
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: May form oxides of carbon and sulfur when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: No information found.
Conditions to Avoid: No information found.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the
chemical substance and ensure prompt removal from skin, eyes and clothing.

Potential Health Effects

Inhalation: No adverse health effects via inhalation.
Ingestion: Large doses may cause stomach upset.
Skin Contact: No adverse effects expected.
Eye Contact: No adverse effects expected.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0423
Inhalation: Not expected to require first aid measures.
Ingestion: If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact: Not expected to require first aid measures.
Eye Contact: Wash thoroughly with running water. Get medical advice if irritation develops.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn.
For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Handling and Storage:
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers
of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all
warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Contain
and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e. G.,
Vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as
saw dust.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0428

Material Safety Data Sheet

City University of Hong Kong

MSDS Sulfur Monochloride 0428

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name. : Sulfur Monochloride

Chinese Name:
Chemical Family: Inorganic acid
Synonyms : Sulfur monochloride; Disulfur dichloride; Sulfur chloride
CAS Number : 10025-67-9
Formula : S2Cl2

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

PHYSICAL FORM. : Liquid

COLOR. : Brownish (red-orange)
ODOR. : Pungent, irritating
ODOR THRESHOLD. : 0.001 ppm in air

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
MOLECULAR WEIGHT. : 135.03
pH . : Not Applicable
BOILING POINT. : 280 °F (130 °C) @ 1013 mbar
MELTING/FREEZING POINT. : -105 °F (-76 °C)
VISCOSITY. : 0.9 cP @ 77 °F (25 °C)
SOLUBILITY IN WATER . : Reacts
SPECIFIC GRAVITY . : 1.678 @ 68 °F (20 °C)
BULK DENSITY. : Not Established
% VOLATILE BY VOLUME. : 100%
VAPOR PRESSURE . : 14.7 mbar @ 68 °F (20 °C)
VAPOR DENSITY . : Approx. 4.66 (Air = 1)

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

FLASH POINT. : Up to 266 °F (130 °C) no flash point.

FLAMMABLE LIMITS:
UPPER EXPLOSIVE LIMIT (UEL)(%): 32.5 % by volume in air at 1000 mbar.
LOWER EXPLOSIVE LIMIT (LEL)(%): 4.2 % by volume in air at 1000 mbar.
AUTO-IGNITION TEMPERATURE. : 734 °F (390 °C); DIN 51794.
EXTINGUISHING MEDIA. : Carbon Dioxide; Dry Chemical
SPECIAL FIRE FIGHTING PROCEDURES: Sulfur monochloride is not combustible.
However, if sulfur monochloride is involved in a fire, use carbon dioxide or dry chemicals. Firefighters should wear
full protective clothing including a self-contained breathing apparatus. Toxic and irritating gases may be present
including hydrochloric acid, sulfur dioxide, chlorine, hydrogen disulfide or others. Drums exposed to excessive
temperatures can rupture due to the decomposition of sulfur monochloride. Water will react with sulfur
monochloride generating irritating gases. However, water spray should be used to keep fire exposed containers cool
and to help scrub acid gases from the air.

========================================================================
REACTIVITY DATA
========================================================================

STABILITY. : This is a stable material.

HAZARDOUS POLYMERIZATION. : Will not occur.
INCOMPATIBILITIES. :
Reacts slowly with water, as a skin of sulfur will form at the interfacial boundary. Avoid contact with reducing
agents and organic matter. Reacts violently with titanium metal to generate fires. Sulfur monochloride mixtures with
organic chemicals must be stored in containers equipped with a pressure relief device. Refer to Section X (special
precautions & storage data).

INSTABILITY CONDITIONS. : Excessive temperatures.

DECOMPOSITION TEMPERATURE.: Decomposition begins at 572 °F (300 °C).
DECOMPOSITION PRODUCTS. :
By thermal decomposition: Chlorine, hydrogen disulfide, sulfur dioxide, sulfur. In contact with water: Hydrochloric
acid, sulfur dioxide and sulfur.

========================================================================
HEALTH HAZARD DATA

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0428
========================================================================

EMERGENCY OVERVIEW:
[ DANGER] Corrosive; Color: Brownish (red-orange); Form: Liquid; Odor: Pungent, irritating; Causes respiratory
tract irritation; May be fatal if inhaled; Causes skin burns; Causes eye burns; May cause blindness; Harmful if
swallowed; Causes digestive tract burns; Mixtures with organic material can be explosive; Contact with water or
moist air liberates irritating gas; Contact with water causes the formation of corrosive material; Reaction with water
or foam can be vigorous; Closed container may explode under extreme heat or when contaminated with water; Toxic
gases/fumes are given off during burning or thermal decomposition.

POTENTIAL HEALTH EFFECTS:

ROUTE(S) OF ENTRY. : Skin and eye contact, inhalation.

HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE:

ACUTE EFFECTS OF EXPOSURE. :
Direct contact with sulfur monochloride can cause burns. It is corrosive to the skin, eyes and mucous membranes.
The vapors of sulfur monochloride are strong irritants to the eyes and respiratory tract. Symptoms of exposure
include a burning sensation in the eyes and violent coughing. In contact with humid air, hydrogen chloride (HCl) and
sulfur dioxide (SO2) are produced which are themselves irritating. Significant overexposure to sulfur monochloride
vapors and its related decomposition products (which could occur if a person is trapped or sprayed) may cause
delayed pulmonary edema.

CHRONIC EFFECTS OF EXPOSURE. :

Chronic overexposure to sulfur monochloride can cause symptoms of nonfibrotic lung injury similar to other
irritating vapors.

CARCINOGENICITY. : This product is not listed by NTP, IARC or regulated as a carcinogen by OSHA.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE. :
Asthma, other respiratory disorders (bronchitis, emphysema, bronchial hyperreactivity), skin allergies, eczema.

========================================================================
FIRST AID MEASURES
========================================================================

FIRST AID FOR EYES. :

Immediately flush eyes with running water for at least 15 minutes. To assure thorough flushing of all eye tissue, the
eyelids should be held apart during irrigation. Permanent eye injury can occur, particularly if rinsing is delayed.
Immediately refer to a physician, preferably an eye specialist, for medical treatment.

FIRST AID FOR SKIN. :

Rinse immediately with large amounts of cool, running water. Avoid using hot water and hard rubbing. When
splashed with sulfur monochloride, immediately proceed to an emergency shower and begin removing all
contaminated clothing while rinsing. Flushing the body with large amounts of water should continue until all of the
sulfur monochloride is removed. If the eyes are not contaminated, do not remove safety goggles to avoid washing
sulfur monochloride into the eyes. If contact is extensive or burns develop, a physician should be contacted
immediately.

FIRST AID FOR INHALATION:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Remove to fresh air. Keep person calm and avoid any unnecessary exertion or movement. Trained persons should
administer oxygen if breathing is difficult. If not breathing, give artificial respiration. Immediately contact a
physician.

FIRST AID FOR INGESTION:

In case of ingestion, drink copious amounts of water (if available, give several glasses of milk). Do not induce
vomiting. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. If vomiting occurs
spontaneously, keep airway clear and give more water. Immediately call a physician.

========================================================================
PREVENTATIVE MEASURES
========================================================================

EYE PROTECTION REQUIREMENTS. : Chemical worker safety glasses and full face shield.
SKIN PROTECTION REQUIREMENTS. :
Neoprene, PVC, Polyethylene or Viton (R) gloves, boots and aprons as appropriate for exposure conditions.

VENTILATION REQUIREMENTS:
Use local exhaust or general room ventilation sufficient to prevent overexposure.

RESPIRATOR REQUIREMENTS:
NIOSH approved for acid gases. Do not exceed the use limits of the respirator.

ADDITIONAL PROTECTIVE MEASURES. :

Full body acid resistant suits and positive pressure, self-contained breathing apparatus should be available in case of
large spills or other similar emergencies. Emergency showers and eyewash fountains should be located in areas
where sulfur monochloride is handled. Educate and train employees in the safe use and handling of this product.

STORAGE TEMPERATURE (MIN/MAX): Ambient/122 °F (50 °C).

SHELF LIFE: Unlimited in closed containers and in the absence of moisture. In drums - one year maximum.
SPECIAL SENSITIVITY: Moisture and heat greater than 122 °F (50 °C).
HANDLING/STORAGE PRECAUTIONS:
This product is extremely corrosive. Do not breathe vapors or mists. Do not get on eyes or on skin. Wash
thoroughly after handling. Store containers in a cool, dry and well-ventilated area, out of sunlight and away from fire
hazards. Storage containers and associated equipment must be constructed of materials compatible with sulfur
monochloride. Do not allow moisture to enter storage containers, as this will cause increased corrosion and release
of Hydrochloric Acid and Sulfur Dioxide. Moisture and heat greater than 122 °F (50 °C) will result in build-up of
internal pressure in containers. Each storage vessel should be equipped with pressure relief devices which are
constructed with materials compatible with sulfur monochloride.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

SPILL OR LEAK PROCEDURES. :

Evacuate area and stay upwind. If it is safe to do so, trained personnel should attempt to stop or reduce leak. Large
spills should be contained and pumped into salvage drums or other appropriate containers. Full acid resistant suits
and self-contained breathing apparatus should be worn during emergency operations. Vapor clouds formed by
reaction of the spilled sulfur monochloride with atmospheric moisture can be controlled by water fog or water
spray. After bulk of material is removed, large quantities of soda ash, lime or a combination of these can be used to
soak up and neutralize the remaining sulfur monochloride. Small spills can be handled by absorption and reacted
with large amounts of dry alkali (soda ash and/or lime). Shovel into appropriate container for disposal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0429

Material Safety Data Sheet

City University of Hong Kong

MSDS Eosin B 0429

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : Eosin B (C.I. 45400)

Chinese Name:
Synonyms: CI 45400
CAS No: 548-24-3
Molecular Weight: 624.05
Chemical Formula: C20H6Br2N2Na2O9

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Green to reddish-brown Powder.

Boiling Point: No information found.
Odor: No information found.
Melting Point: 295°C (563°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Moderate (1-10%)
Vapor Density (Air=1): Not applicable.
Specific Gravity: No information found.
Vapor Pressure (mm Hg): Not applicable.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not expected to be a fire hazard.

Explosion: None identified.
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Information:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full facepiece
operated in positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products:
Oxides of nitrogen, hydrogen bromide, carbon monoxide, carbon dioxide.

Polymerization: Will not occur.

Incompatibilities: Strong oxidizing agents.
Conditions to Avoid: No information found.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview: CAUTION! MAY CAUSE IRRITATION.

Potential Health Effects:
Inhalation: None identified.
Ingestion: None identified.
Skin Contact: Allergic reaction may develop.
Eye Contact: None identified.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0429
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Prompt action is essential.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Get medical attention.

Skin Contact: In case of contact, flush skin with water.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the substance is apparent, consult an industrial hygienist. For emergencies,
or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator.
WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain
eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Keep container tightly closed. Suitable for any general chemical storage area. Containers of this material may be
hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed
for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place material
into clean, dry container and cover; remove from area. Flush spill area with water.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0430

Material Safety Data Sheet

City University of Hong Kong

MSDS EOSIN Y 0430

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s): EOSIN Y

Chinese Name:
Synonyms: Acid red 87; CI 45380; Eosin Y Certified (Yellowish); 2',4',5',7'-tetra bromo fluorescein
CAS No: 17372-87-1
Molecular Weight: 691.91
Chemical Formula: C20H6Br4Na2O5

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Brown powder.

Boiling Point: No information found.
Odor: Odorless.
Melting Point: No information found.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Soluble in water.
Vapor Density (Air=1): No information found.
Specific Gravity: Unknown
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): No information found.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products:
Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides. Combustion will produce carbon dioxide,
carbon monoxide, hydrogen bromide gas.

Hazardous Polymerization: Will not occur.

Incompatibilities: Strong oxidizers.
Conditions to Avoid: Incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview: Caution! May irritate eyes, respiratory tract.

Potential Health Effects
Inhalation: Inhalation of dust may cause irritation to the respiratory tract.
Ingestion: Not expected to be a health hazard via ingestion.
Skin Contact: Not expected to cause any adverse health effects from skin contact.
Eye Contact: May cause irritation.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0430
Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Not expected to require first aid measures. If large amounts were swallowed, give water to drink and get medical
advice.

Skin Contact: Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally.
Get medical attention if irritation persists.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn.
For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers
of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings
and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0437

Material Safety Data Sheet

City University of Hong Kong

MSDS Adipyl Chloride 0437

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : Adipyl Chloride

Chinese Name:
Synonyms: None
CAS No: 111-50-2
Molecular Weight: 183.03
Chemical Formula: ClCO(CH2)4COCl

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Yellow liquid.

Boiling Point: 126°C (259°F) (pure) at 12mm Hg
Odor: No information found.
Melting Point: No information found.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Decomposes
Vapor Density (Air=1): No information found.
Specific Gravity: 1.26
Vapor Pressure (mm Hg): Not applicable.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 100

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Flash point: 110°C (230°F) CC

Explosion: Fire or excessive heat may produce hazardous decomposition products.
Fire Extinguishing Media: Water, dry chemical, foam or carbon dioxide.
Special Information:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Use water
with caution. Reacts with water.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, Hydrogen chloride gas
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents. Strong bases. water, alcohols.
Conditions to Avoid: No information found.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Danger! Water reactive. Combustible. May cause a fire. Corrosive. Causes severe burns to eyes, skin and respiratory
tract. Contact with water may form toxic gas. The toxicological properties of this material have not been
investigated.

Potential Health Effects

Inhalation: None identified.
Ingestion: None identified.
Skin Contact: None identified.
Eye Contact: None identified.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0437

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Prompt action is essential.

Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an
unconscious person. Get medical attention immediately.

Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Wash clothing before re-use.

Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the substance is apparent, consult an industrial hygienist. For emergencies,
or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator.
WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and
quick-drench facilities in work area.

Other Control Measures:

There is insufficient data in the published literature to assign complete numerical SAF-T-DATA* ratings and
laboratory protective equipment for this product. Special precautions must be used in storage, use and handling.
Protective equipment for laboratory bench use should be chosen using professional judgment based on the size and
type of reaction or test to be conducted and the available ventilation, with overriding consideration to minimize
contact with the chemical.

Handling and Storage:

Keep container tightly closed and away from water or alcohols. Do not add water to a closed container. Reaction
may result in violent rupture of the container. Keep from contact with oxidizing materials. Containers of this

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and
precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Absorb material in sand or other suitable absorbent and place in container.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0443

Material Safety Data Sheet

City University of Hong Kong

MSDS 1-IODOBUTANE 0443

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : 1-IODOBUTANE

Chinese Name:
Synonyms: Butane, 1-iodo-; n-butyliodide
CAS No: 542-69-8
Molecular Weight: 184.02
Chemical Formula: C4H9I

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Light yellow liquid.

Boiling Point: 130.4°C (266°F)
Odor: No information found.
Melting Point: -103.0°C (-153°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Practically insoluble in water.
Vapor Density (Air=1): 5
Specific Gravity: 1.616 @ 20°C/4°C
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): No information found.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Flash point: 33°C (91°F) CC
Flammable Liquid and Vapor! Contact with strong oxidizers may cause fire.

Explosion:
Above the flash point, explosive vapor-air mixtures may be formed. Vapors can flow along surfaces to distant
ignition source and flash back. Sealed containers may rupture when heated.

Fire Extinguishing Media:

Dry chemical, foam, carbon dioxide, or water spray. Water may be ineffective. Water spray may be used to keep fire
exposed containers cool. Do not allow water runoff to enter sewers or waterways.

Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products:
Oxides of carbon as well as ionic or oxidized halogen. Burning may produce toxic iodine vapors.

Hazardous Polymerization: Will not occur.

Incompatibilities: Strong oxidizers, strong bases; may discolor on exposure to light.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Warning! Flammable liquid and vapor. Harmful if swallowed or inhaled. Causes irritation to skin, eyes and
respiratory tract.

Potential Health Effects

Inhalation:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0443
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath.

Ingestion:
No information found, but compound should be handled as a potential health hazard. May cause irritation to the
gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea.

Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain.
Eye Contact: Causes irritation, redness, and pain.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person.

Skin Contact:
Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and
shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the substance is apparent, consult an industrial hygienist. For emergencies,
or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator.
WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and
quick-drench facilities in work area.

Handling and Storage:

Protect from light. Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area
where the fire hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles.
Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No
Smoking areas. Use non-sparking type tools and equipment, including explosion proof ventilation. Containers of this
material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and
precautions listed for the product. Do Not attempt to clean empty containers since residue is difficult to remove.
Do not pressurize, cut, weld, braze, solder, drill, grind or expose such containers to heat, sparks, flame, static
electricity or other sources of ignition: they may explode and cause injury or death.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as
specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and
recover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an appropriate container or
absorb with an inert material (e. G., Vermiculite, dry sand, earth), and place in a chemical waste container. Do not
use combustible materials, such as saw dust. Do not flush to sewer! If a leak or spill has not ignited, use water spray
to disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0444

Material Safety Data Sheet

City University of Hong Kong

MSDS FERRIC SULFATE 0444

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : FERRIC SULFATE

Chinese Name:
Synonyms: Iron (III) sulfate; iron persulfate; sulfuric acid, iron (3+) salt (3:2) hydrate
CAS No: 10028-22-5
Molecular Weight: 399.87
Chemical Formula: Fe 2(SO4)3. xH2O

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Grayish-white powder or rhombic crystals.

Boiling Point: Not applicable.
Odor: Odorless.
Melting Point: 480°C (896°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Soluble in water.
Vapor Density (Air=1): No information found.
Density: 3.097 (Anhydrous)
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Dry chemical, foam, carbon dioxide, or water spray.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage. Very hygroscopic.
Hazardous Decomposition Products: Oxides of sulfur and the contained metal.
Hazardous Polymerization: This substance does not polymerize.
Incompatibilities: No incompatibility data found.
Conditions to Avoid: Heat, light, moisture.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Warning! Harmful if swallowed or inhaled. Causes irritation to skin, eyes and respiratory tract. Affects the liver.

Potential Health Effects

Inhalation:
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath.

Ingestion:
Low toxicity in small quantities but larger dosages may cause nausea, vomiting, diarrhea, and black stool. Pink urine
discoloration is a strong indicator of iron poisoning. Liver damage, coma, and death from iron poisoning has been
recorded.

Skin Contact:
Causes irritation to skin. Symptoms include redness, itching, and pain. May cause skin discoloration with irritation.

Eye Contact: Causes irritation, redness, and pain.

Chronic Exposure:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0444
Prolonged exposure of the eyes may cause discoloration. Repeated high exposure could cause too much iron to
build up in the body. Symptoms of upset stomach, nausea, constipation and black bowel movements may occur.
Chronic exposure may cause liver effects.

Aggravation of Pre-existing Conditions:

Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be
more susceptible to the effects of the substance.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Get medical attention.

Skin Contact:
Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and
shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

-ACGIH Threshold Limit Value (TLV): 1 mg/m3 (TWA) soluble iron salt as Fe
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit
or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever
is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use
concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Maintain eye wash fountain and quick-drench facilities in work area. Use chemical safety goggles and/or full face
shield where dusting or splashing of solutions is possible.

Handling and Storage:

Keep in a tightly closed light-resistant container, stored in a cool, dry, ventilated area. Protect against physical
damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids);
observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal. For ferric chloride anhydrous: US Regulations (CERCLA) require reporting spills and releases to soil,
water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response
Center is (800) 424-8802.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0448

Material Safety Data Sheet

City University of Hong Kong

MSDS MAGNESIUM OXIDE 0448

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : MAGNESIUM OXIDE

Chinese Name:
Synonyms: Calcinated magnesia; Magnesia; Calcined Magnesite
CAS No: 1309-48-4
Molecular Weight: 40.32
Chemical Formula: MgO

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================
Appearance: Bulky white powder.
Boiling Point: 3600°C (6512°F)
Odor: Odorless.
Melting Point: 2800°C (5072°F)
Solubility: Insoluble in water.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapor Density (Air=1): No information found.
Specific Gravity: 3.58 @ 25°C (77°F)
Vapor Pressure (mm Hg): No information found.
pH: 10.3
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion:
Magnesium oxide reacts violently or ignites with interhalogens such as chlorine trifluoride (ClF3) or bromine
pentafluoride (BrF5), and incandescently with phosphorus pentachloride (PCl 5).

Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage. Absorbs carbon dioxide and water from air.
Hazardous Decomposition Products: None known.
Hazardous Polymerization: Will not occur.
Incompatibilities: Acids, interhalogens, phosphorus pentachloride, and chlorine trifluoride.
Conditions to Avoid: Air, moisture, and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview: Caution! May cause irritation to eyes and respiratory tract.
Potential Health Effects
Inhalation:
Nuisance dust. May cause irritation to the nasal passages, respiratory tract. Inhalation can cause a flu-like illness
(metal fume fever). This 24- to 48-hour illness is characterized by chills, fever, aching muscles, dryness in the
mouth and throat and headache.

Ingestion: Magnesium oxide is slowly absorbed. Ingestion may cause rapid bowel evacuation.
Skin Contact: No adverse effects expected.
Eye Contact: May cause irritation.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0448
========================================================================

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice.
Skin Contact: Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact: Wash thoroughly with running water. Get medical advice if irritation develops.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

For Magnesium Oxide Fume:
- OSHA Permissible Exposure Limit (PEL): 15 mg/m3 (TWA).
- ACGIH Threshold Limit Value (TLV): 10 mg/m3 (TWA).

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a full facepiece respirator with dust/mist filter may be worn up to 50 times the
exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator
supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-
facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in
oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Handling and Storage:
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from incompatible substances. Containers of this material may be hazardous when empty since they retain product
residues (dust, solids); observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0451

Material Safety Data Sheet

City University of Hong Kong

MSDS ISOBUTYL ALCOHOL 0451

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : ISOBUTYL ALCOHOL

Chinese Name:
Synonyms: 1-Hydroxymethylpropane; isobutanol; 2-methylpropanol; 2-methyl-1-propanol; Isopropylcarbinol
CAS No: 78-83-1
Molecular Weight: 74.12
Chemical Formula: (CH3)2 CHCH2OH

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Clear, colorless solution.

Boiling Point: 108°C (226°F)
Odor: Sweet-musty odor.
Melting Point: -108°C (-162°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: 9.5g/100ml water @ 20°C (68°F).
Vapor Density (Air=1): 2.6
Specific Gravity: 0.803
Vapor Pressure (mm Hg): 8.8 @ 20°C (68°F)
pH: No information found.
Evaporation Rate (BuAc=1): 0.8
% Volatiles by volume @ 21°C (70°F): 100

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Flash point: 28°C (82°F) CC
Autoignition temperature: 415°C (779°F)
Flammable limits in air % by volume:
LEL: 1.7; UEL: 10.6
Flammable Liquid and Vapor!

Explosion:
Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Containers may explode in
heat or fire.

Fire Extinguishing Media:

Dry chemical, foam or carbon dioxide. Do not use a solid stream of water, since the stream will scatter and spread
the fire. Water spray may be used to keep fire exposed containers cool.

Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode. Vapors can flow along surfaces to
distant ignition source and flash back.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide and isobutylene.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents, inorganic acids, aldehydes, isocyanates.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Warning! Flammable liquid and vapor. Harmful if swallowed, inhaled or absorbed through skin. Affects central
nervous system. Causes irritation to skin, eyes and respiratory tract. Potential health effects

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0451
Inhalation:
Causes irritation to respiratory tract. Effects from overexposure include headache, dizziness, muscle weakness,
drowsiness, incoordination, confusion, and coma. High concentrations can cause central nervous system damage,
pulmonary edema, and liver damage. Death may occur from respiratory failure.

Ingestion:
Ingestion may cause nausea, vomiting, and diarrhea. Large doses may cause central nervous system damage,
pulmonary edema, and liver damage. Death may occur from respiratory failure.

Skin Contact:
Skin contact causes irritation, redness, and pain. May be absorbed through the skin; symptoms of absorption may be
similar to those from ingestion exposure.

Eye Contact:
Vapors cause irritation, redness, and blurred vision. Splashes may cause severe irritation or eye damage.

Chronic Exposure: Prolonged or repeated skin exposure may cause dermatitis.

Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be
more susceptible to the effects of the substance.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a
physician.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person.

Skin Contact:
Remove any contaminated clothing. Wash skin with soap or mild detergent and water for at least 15 minutes. Wash
clothes before reuse. Get medical attention if irritation develops or persists.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

-OSHA Permissible Exposure Limit (PEL): 100 ppm (TWA)
-ACGIH Threshold Limit Value (TLV): 50 ppm (TWA)

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a full facepiece respirator with organic vapor cartridge may be worn up to 50
times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or
respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use
a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect
workers in oxygen-deficient atmospheres.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and
quick-drench facilities in work area.

Handling and Storage:

Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire
hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be
bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use
non-sparking type tools and equipment, including explosion proof ventilation. Containers of this material may be
hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed
for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as
specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and
recover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an appropriate container or
absorb with an inert material (e. G., Vermiculite, dry sand, earth), and place in a chemical waste container. Do not
use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting
spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast
Guard National Response Center is (800) 424-8802. J. T. Baker SOLUSORB(R) solvent adsorbent is recommended
for spills of this product.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0452

Material Safety Data Sheet

City University of Hong Kong

MSDS 2-NAPHTHOL 0452

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : 2-NAPHTHOL

Chinese Name:
Synonyms: 2-Naphthalenol; (beta)-naphthol; (beta)-Hydroxynaphthalene; Isonaphthol
CAS No: 135-19-3
Molecular Weight: 144.17
Chemical Formula: C10H8O

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White to yellowish-white crystals.

Boiling Point: 285 - 286°C (545 - 547°F)
Odor: Slight phenolic odor.
Melting Point: 121 - 123°C (250 - 253°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Slightly soluble in water.
Vapor Density (Air=1): 4.97
Density: 1.22
Vapor Pressure (mm Hg): 10 @ 145.5°C (295°F)
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Flash point: 153°C (307°F) CC
Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.

Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability:
Stable under ordinary conditions of use and storage. Darkens with age or exposure to light. Sublimes when heated.

Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers, strong bases, phenol, acid chlorides and acid anhydrides.
Conditions to Avoid: Heat, flame, sources of ignition, light and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Warning! Harmful if swallowed or inhaled. Causes irritation to skin, eyes and respiratory tract.

Potential Health Effects: Information on the human health effects from exposure to this substance is limited.
Inhalation: Inhalation of dust is irritating to the upper respiratory tract.
Ingestion: Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea.
Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain.
Eye Contact: Causes irritation, redness, and pain.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0452

FIRST AID MEASURES

========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Get medical attention.

Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get
medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn.
For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain
eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from incompatible substances. Containers of this material may be hazardous when empty since they retain product
residues (dust, solids); observe all warnings and precautions listed for the product.

========================================================================

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0456

Material Safety Data Sheet

City University of Hong Kong

MSDS Paraffin 0456

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : Paraffin

Chinese Name:
Synonyms: None
CAS No: 8002-74-2
Molecular Weight: Not applicable.
Chemical Formula: Not applicable.

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Wax-like prills.

Boiling Point: No information found.
Odor: Odorless.
Melting Point: 56°C (133°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Negligible (< 0.1%)
Vapor Density (Air=1): Not applicable.
Specific Gravity: 0.90
Vapor Pressure (mm Hg): Not applicable.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Flash point: 204°C (399°F) CC

Explosion: No information found.

Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Special Information:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full facepiece
operated in positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents.
Conditions to Avoid: Heat, flame, other sources of ignition.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the
chemical substance and ensure prompt removal from skin, eyes and clothing.

Potential Health Effects

Inhalation: None identified.
Ingestion: Irritation of mucous membranes.
Skin Contact: Irritation.
Eye Contact: Irritation.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0456

Inhalation: If a person breathes in large amounts, move the exposed person to fresh air.
Ingestion: If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact: In case of contact, immediately wash skin with plenty of soap and water for at least 15 minutes.
Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

-ACGIH Threshold Limit Value (TLV): 2 mg/m3 (TWA)

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the substance is apparent, consult an industrial hygienist. For emergencies,
or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator.
WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: None required.

Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain
eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Keep container tightly closed. Suitable for any general chemical storage area. Containers of this material may be
hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed
for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear suitable protective clothing. Carefully sweep up and remove.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0457

Material Safety Data Sheet

City University of Hong Kong

MSDS AMYL ALCOHOL 0457

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : AMYL ALCOHOL

Chinese Name:
Synonyms: n-amyl alcohol; 1-pentanol; pentyl alcohol; n-butyl carbinol
CAS No: 71-41-0
Molecular Weight: 88.15
Chemical Formula: C5H11OH

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Clear, colorless liquid

Boiling Point:. 134 - 138°C (273 - 280°F)
Odor: Characteristic odor.
Melting Point: -79°C (-110°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: 2.7gm/100gm water @ 22°C (71.6°F).
Vapor Density (Air=1): 3.04
Specific Gravity: 0.81 @ 20°C/4°C
Vapor Pressure (mm Hg): 1 @ 13.6°C (57°F)
pH: No information found.
Evaporation Rate (BuAc=1): 0.18
% Volatiles by volume @ 21°C (70°F): 100

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Flash point: 33°C (91°F) CC
Autoignition temperature: 300°C (572F)
Flammable limits in air % by volume:
LEL: 1.2; UEL: 10
Flammable. Upper explosive limit is for 100°C (212°F).

Explosion:
Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Vapors can flow along
surfaces to distant ignition source and flash back. Sensitive to static discharge.

Fire Extinguishing Media:

Dry chemical, foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool. Water may
be ineffective.

Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable at room temperature in sealed containers.

Hazardous Decomposition Products:
Carbon dioxide and carbon monoxide may form when heated to decomposition. Can form aldehydes burning in
limited air.

Hazardous Polymerization: Will not occur.

Incompatibilities: Strong oxidizers. Strong inorganic acids. Heat and sources of ignition.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0457
Warning! Flammable liquid and vapor. Harmful if swallowed, inhaled or absorbed through skin. Vapors cause
respiratory tract irritation and severe eye irritation. Liquid causes skin irritation, severe eye irritation and possible
eye burns. Affects central nervous system.

Potential Health Effects

Inhalation:
Inhalation of vapors can irritate the nose, throat, and upper respiratory passages. Higher concentrations have a
narcotic effect and may cause headache, nausea, vomiting, dizziness, double vision, shortness of breath, and
delirium. In severe cases, inhalation may be fatal.

Ingestion:
Moderately toxic by ingestion, can cause headache, nausea, delirium and methemoglobin formation in the blood.
Other symptoms may parallel those from inhalation exposure. Vomiting may cause aspiration into lungs and result
in chemical pnuemonia.

Skin Contact:
Brief contact is not irritating. Prolonged contact may cause severe irritation with pain, redness, swelling, and
possible tissue damage. Suspected to be a systemic poison by absorption through skin; systemic effects paralleling
ingestion may occur.

Eye Contact:
Vapors cause severe irritation. Symptoms may include tearing, pain, redness, swelling. Liquid contact causes severe
irritation and possible burns.

Chronic Exposure: Repeated inhalation of aerosols may result in lung and kidney injury.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or eye problems, or impaired kidney or respiratory function may be more
susceptible to the effects of the substance.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an
unconscious person. Get medical attention immediately.

Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

The following exposure limits for isoamyl alcohol (CAS 123-51-3) may be used as models.
-OSHA Permissible Exposure Limit (PEL): 100 ppm (TWA)
-ACGIH Threshold Limit Value (TLV): 100 ppm (TWA), 125 ppm (STEL)

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details. Use explosion-proof equipment.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the substance is apparent, consult an industrial hygienist. For emergencies,
or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator.
WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and
quick-drench facilities in work area.

Handling and Storage:

Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire
hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be
bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use
non-sparking type tools and equipment, including explosion proof ventilation. Containers of this material may be
hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed
for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as
specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and
recover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an appropriate container or
absorb with an inert material (e. G., Vermiculite, dry sand, earth), and place in a chemical waste container. Do not
use combustible materials, such as saw dust. Do not flush to sewer! If a leak or spill has not ignited, use water spray
to disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0458

Material Safety Data Sheet

City University of Hong Kong

MSDS PEPSIN 0458

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : PEPSIN

Chinese Name:
Synonyms: Pepsin A; Pepsin NF; Pepsinum; Puerzym
CAS No: 9001-75-6
Molecular Weight: 34500
Chemical Formula: Not applicable.

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White to light yellow powder.

Boiling Point: No information found.
Odor: Characteristic odor.
Melting Point: No information found.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Soluble in water.
Vapor Density (Air=1): No information found.
Specific Gravity: No information found.
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source. Being an
animal protein, Pepsin is assumed to be combustible. Avoid inhalation of combustion fumes. Pepsin powder may, on
being transferred from container to container, generate static electrical charge, which could discharge violently.

Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust
explosion hazard.

Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage. Somewhat hygroscopic.
Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides.
Hazardous Polymerization: Will not occur.
Incompatibilities: Tannin, alkalis, salts of heavy metals, strong oxidizers.
Conditions to Avoid: Moisture, heat, flames, ignition sources and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
WARNING! MAY CAUSE IRRITATION TO SKIN AND EYES. MAY CAUSE ALLERGIC SKIN
REACTION.

Potential Health Effects

Inhalation: No adverse health effects expected from inhalation.
Ingestion: Large doses may cause gastro-intestinal upset. May cause an allergic reaction.
Skin Contact: May cause irritation, allergic reaction. May result in reddening, burning sensation.
Eye Contact: May cause irritation.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0458
Chronic Exposure: Possible hypersensitivity, dermatitis.
Aggravation of Pre-existing Conditions:
Individuals with dermatitis or hypersensitivity to material may be more susceptible to the effects of the substance.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact:
Immediately flush skin with plenty of soap and water. Remove contaminated clothing and shoes. Get medical
attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally.
Get medical attention if irritation persists.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System: Not expected to require any special ventilation.
Personal Respirators (NIOSH Approved): Not expected to require personal respirator usage.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Handling and Storage:
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers
of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings
and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as
specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking
tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for
recovery or disposal and place in a closed container.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0459

Material Safety Data Sheet

City University of Hong Kong

MSDS PHLOROGLUCINOL DIHYDRATE 0459

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : PHLOROGLUCINOL DIHYDRATE

Chinese Name:
Synonyms: 1,3,5-Benzenetriol; benzene-s-triol
CAS No: 108-73-6 (Anhydrous)
Molecular Weight: 162.14
Chemical Formula: C6H6O3 . 2H2O

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White to yellow crystals or powder.

Boiling Point: No information found.
Odor: Odorless.
Melting Point: 218 - 221°C (424 - 430°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Soluble in 100 parts water.
Vapor Density (Air=1): 4.3
Specific Gravity: No information found.
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.

Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust
explosion hazard.

Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability:
Stable under ordinary conditions of use and storage. Discolors in light.
Sublimes with decomposition.

Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers.
Conditions to Avoid: Heat, flame, sources of ignition, light and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES
AND RESPIRATORY TRACT.

Potential Health Effects

Information on the human health effects from exposure to this substance is limited.

Inhalation: Excessive inhalation of dust may be irritating to the respiratory tract.

Ingestion: No information found, but compound should be handled as a potential health hazard.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0459
Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain.
Eye Contact: Causes irritation, redness, and pain.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Get medical attention.

Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get
medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn.
For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.
Refrigerate. Protect from light. Isolate from incompatible substances. Containers of this material may be hazardous
when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the
product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as
specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking
tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for
recovery or disposal and place in a closed container.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0464

Material Safety Data Sheet

City University of Hong Kong

MSDS PYROGALLIC ACID 0464

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : PYROGALLIC ACID

Chinese Name:
Synonyms: 1,2,3-Trihydroxybenzene; pyrogallol; 1,2,3-benzenetriol
CAS No: 87-66-1
Molecular Weight: 126.11
Chemical Formula: C6H3(OH) 3

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White to slightly yellow plates and powder.

Boiling Point: 309°C (588°F)
Odor: Characteristic odor.
Melting Point: 131 - 133°C (268 - 271°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: ca. 60g/100ml water @ 20°C (68°F).
Vapor Density (Air=1): 4.4
Density: 1.45
Vapor Pressure (mm Hg): 10 @ 167.7°C (334°F)
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.

Explosion: Not considered to be an explosion hazard.

Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage. Darkens on exposure to air or light.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxygen, oxidizing agents, alkalis, ammonia, iodine, iron and lead salts, and phenol.
Conditions to Avoid: Air, heat, and light.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
WARNING! HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. CAUSES
IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS THE RESPIRATORY
SYSTEM, LIVER, KIDNEYS, EYES, SKIN AND BLOOD.

Potential Health Effects

Inhalation:
Irritant. May be absorbed through the lungs. Can cause coughing, sneezing or difficulty in breathing.

Ingestion:
Toxic substance. Ingestion can lead to severe gastrointensinal irritation, vomiting, and diarrhea. Pyrogallic acid
absorbed through the alimentary canal can cause damage to the liver and kidneys, produce methemoglobinemia,
circulatory collapse and death.

Skin Contact:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0464
Irritant. Causes redness and soreness. Pyrogallic acid is readily absorbed through the skin and severe or fatal
poisoning can occur.

Eye Contact: Causes irritation with redness and pain.

Chronic Exposure: Accumulation of pyrogallic acid in the system affects the kidneys and liver.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be
more susceptible to the effects of the substance.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a
physician.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Call a physician immediately.

Skin Contact:
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing
and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn.
For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Handling and Storage:
Store in a cool, dry, ventilated area away from sources of heat or ignition. Isolate from oxidizing materials. Protect
from direct sunlight. Containers of this material may be hazardous when empty since they retain product residues
(dust, solids); observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as
specified in Section 8.

Spills:
Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce
airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a
closed container.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0465

Material Safety Data Sheet

City University of Hong Kong

MSDS SAFRANINE O 0465

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : SAFRANINE O

Chinese Name:
Synonyms: CI 50240; basic red 2
CAS No: 477-73-6
Molecular Weight: 350.85
Chemical Formula: C20H19N4Cl

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Dark rusty crystals or dark green powder.

Boiling Point: No information found.
Odor: Odorless.
Melting Point: No information found.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Soluble in water.
Vapor Density (Air=1): No information found.
Specific Gravity: No information found.
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products:
May produce carbon monoxide, carbon dioxide, nitrogen oxides and hydrogen chloride when heated to
decomposition.

Hazardous Polymerization: Will not occur.

Incompatibilities: No information found.
Conditions to Avoid: No information found.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview: Warning! Causes irritation to eyes and skin.

Potential Health Effects
Information on the human health effects from exposure to this substance is limited.
Inhalation: No information found, but compound should be handled as a potential health hazard.
Ingestion: No information found, but compound should be handled as a potential health hazard.
Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain.
Eye Contact: Causes irritation, redness, and pain.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0465

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Get medical attention.

Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get
medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn.
For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

Other Control Measures:

There is insufficient data in the published literature to assign complete numerical SAF-T-DATA* ratings and
laboratory protective equipment for this product. Special precautions must be used in storage, use and handling.
Protective equipment for laboratory bench use should be chosen using professional judgment based on the size and
type of reaction or test to be conducted and the available ventilation, with overriding consideration to minimize
contact with the chemical.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers
of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings
and precautions listed for the product.

========================================================================

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0466

Material Safety Data Sheet

City University of Hong Kong

MSDS Silica Gel G 0466

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : Silica Gel G / HR

Chinese Name:
Synonyms: None
CAS No: 7631-86-9
Molecular Weight: Not available.
Chemical Formula: Not available.

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White amorphous powder.

Boiling Point: No information found.
Odor: Odorless.
Melting Point: No information found.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Negligible (< 0.1%)
Vapor Density (Air=1): No information found.
Specific Gravity: No information found.
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information: Use protective clothing and breathing equipment appropriate for the surrounding fire.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Oxides of carbon and silicon may be formed when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities:
Reacts with hydrogen fluoride, fluorine, oxygen difluoride, chlorine trifluoride, strong acids, strong bases, and
oxidizers.

Conditions to Avoid: Moisture, extreme heat, and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview: Caution! May cause irritation to skin, eyes, and respiratory tract.
Potential Health Effects
This product contains synthetic amorphous silica, not to be confused with crystalline silica such as quartz,
cristobalite or tridymite or with diatomaceous earth or other naturally occurring forms of amorphous silica that
frequently contain crystalline forms.

Inhalation:
May cause dryness and irritation to mucous membranes, nose, and throat. Symptoms may include coughing, sore
throat, and wheezing.

Ingestion: No adverse effects expected.

Skin Contact: May cause irritation with dryness and abrasion.
Eye Contact: May cause irritation, redness and pain.
Chronic Exposure:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0466
Repeated exposure may cause symptoms similar to those listed for acute effects. Synthetic amorphous silica does
not produce silicosis.

Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice.
Skin Contact:
Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and
shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation
develops.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally.
Get medical attention if irritation persists.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

Silica (synthetic, amorphous):
- OSHA Permissible Exposure Limit (PEL) -
80/(%SiO2) mg/m3 (TWA) for amorphous silica, including natural diatomaceous earth.
- ACGIH Threshold Limit Value (TLV) -
10 mg/m3 (TWA) for amorphous precipitated silica and amorphous silica gel.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit
or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever
is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use
concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Handling and Storage:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. When
pouring into a container of flammable liquid, ground both containers electrically to prevent a static electric spark.
Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe
all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0467

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM BENZOATE 0467

========================================================================
PRODUCT INFORMATION
========================================================================

Product name(s) : SODIUM BENZOATE

Chinese Name:
Synonyms: Benzoic Acid, sodium salt; Benzoate of soda; Sodium benzoic acid; Antimol
CAS No: 532-32-1
Molecular Weight: 144
Chemical Formula: C7H5NaO2

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White granules or crystalline powder.

Boiling Point: Not applicable.
Odor: Odorless.
Melting Point: > 300°C (> 572°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Soluble in water. (1 gm/2 ml water)
Vapor Density (Air=1): No information found.
Density: 1.44
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust
explosion hazard.

Fire Extinguishing Media:

Use any means suitable for extinguishing surrounding fire. Water spray can be used to extinguish fires and cool fire-
exposed containers.

Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products:
Thermal decomposition may produce carbon dioxide, carbon monoxide, and/or benzoic acid.

Hazardous Polymerization: This substance does not polymerize.

Incompatibilities: Acids, ferric salts, strong oxidizers.
Conditions to Avoid: No information found.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Caution! May be harmful if swallowed or inhaled. May cause irritation to skin, eyes, and respiratory tract. May form
combustible dust concentrations in air.

Potential Health Effects

Inhalation: May cause irritation to the respiratory tract. Symptoms may include coughing and shortness of breath.
Ingestion: Large oral doses may cause irritation to the gastrointestinal tract.
Skin Contact: May cause irritation with redness and pain.
Eye Contact: May cause irritation, redness and pain.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0467
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Get medical attention.

Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash
clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally.
Get medical attention if irritation persists.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn.
For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Handling and Storage:
Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away from
sources of heat, moisture and incompatibilities. Avoid dust formation and control ignition sources. Employ
grounding, venting and explosion relief provisions in accord with accepted engineering practices in any process
capable of generating dust and/or static electricity. Empty only into inert or non-flammable atmosphere. Emptying
contents into a non-inert atmosphere where flammable vapors may be present could cause a flash fire or explosion
due to electrostatic discharge. Containers of this material may be hazardous when empty since they retain product
residues (dust, solids); observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0468

Material Safety Data Sheet

City University of Hong Kong

MSDS Sodium Bromide 0468

========================================================================
PRODUCT INFORMATION
========================================================================

CHEMICAL NAME: Sodium Bromide

Chinese Name:
CAS NO.: 7647-15-6
CHEMICAL FORMULA: NaBr
CHEMICAL FAMILY: Metal Bromide

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

APPEARANCE/ODOR: White crystalline or granular solid/ordorless.

BOILING POINT: 1390°C/2534°F.
VAPOR PRESSURE: Not applicable.
SOLUBILITY IN WATER: 733 g/l at 20°C/60F.
SPECIFIC GRAVITY: 3.2

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
EVAPORATION RATE: Not applicable.
PERCENT VOLATILE: 0.00
MOLECULAR WEIGHT: 102.9 g
MELTING POINT: 755°C/1391°F
pH: 5.5 to 8 for 5% sol.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

FLASH POINT(METHOD): Non-combustible.

FLAMMABLE LIMITS: Not applicable.
EXTINGUISHING MEDIA: Non-combustible material. Use extinguishing method appropriate for surrounding fire.
SPECIAL FIRE FIGHTING PROCEDURES: Avoid breathing fumes.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS: Includes bromine.
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known.

========================================================================
REACTIVITY DATA
========================================================================

STABILITY: Stable.
CONDITIONS TO AVOID: Product is hygroscopic -- avoid contact with water and moist air.
MATERIALS TO AVOID: Strong acids, bases, oxidizing agents, alkaloidal, and heavy metal salts.
HAZARDOUS POLYMERIZATION: Will not occur.

========================================================================
HEALTH HAZARD DATA
========================================================================

INHALATION: Not expected to be a primary route of exposure.

EYE CONTACT: May cause eye irritation.
SKIN CONTACT: Prolonged or repeated exposure may cause skin irritation.
INGESTION: Not expected to be acutely toxic.
CHRONIC EFFECTS OF OVEREXPOSURE: None known.

========================================================================
FIRST AID MEASURES
========================================================================

INHALATION: If inhaled, remove to fresh air.

EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
SKIN CONTACT: Wash contaminated areas with soap and water.
INGESTION: Give two glasses of water. Do not induce vomiting. Get medical attention.

========================================================================
PREVENTATIVE MEASURES
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0468

EXPOSURE LIMITS: Not established by OSHA/ACGIH.

EYE PROTECTION: Chemical goggles and face shield.
PROTECTIVE GLOVES: Resistant to chemical penetration.
RESPIRATORY PROTECTION: None under normal conditions.
LOCAL EXHAUST VENTILATION: Not required.
MECHANICAL VENTILATION: Recommended.
OTHER:
If repeated or prolonged skin contact or contamination of clothing is likely, protective clothing should be worn.
STORAGE REQUIREMENTS: Store in well-ventilated, cool, dry area. Close container when not in use.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

SPILLS OR LEAKS: Sweep or shovel spills into appropriate container for disposal.
DISPOSAL METHODS:
To the best of Albemarle's knowledge, this product is not regulated by CERCLA/RCRA as a hazardous waste or
material. However, this product has not been tested for the toxicity characteristic via the Toxicity Characteristic
Leaching Procedure. Therefore, it may be disposed of as an industrial waste in a manner acceptable to good waste
management practice and in compliance with applicable local, state and federal regulations.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0470

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM ACETATE ANHYDROUS 0470

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : SODIUM ACETATE ANHYDROUS

Chinese Name:
Synonyms: Sodium acetate anhydrous; Acetic acid, sodium salt
CAS No: 127-09-3
Molecular Weight: 82.03
Chemical Formula: CH3COONa

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White hygroscopic crystals.

Boiling Point: Not applicable.
Odor: Odorless.
Melting Point: 324°C (615°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: 119 g/100 g cold water
Vapor Density (Air=1): No information found.
Density: 1.53
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Autoignition temperature: 611°C (1132°F)
Combustible. May pose a fire hazard when exposed to elevated temperatures or by contact with an ignition source.

Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust
explosion hazard.

Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage. Hygroscopic powder.
Hazardous Decomposition Products: Emits fumes of acetic acid upon heating and on contact with strong acids.
Hazardous Polymerization: Will not occur.
Incompatibilities: Nitric acid, fluoride, potassium nitrate, strong oxidizers and diketene.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview: Caution! May cause irritation to skin, eyes, and respiratory tract.
Potential Health Effects
Inhalation:
May cause irritation to the respiratory tract. Symptoms may include coughing, sore throat, labored breathing, and
chest pain.

Ingestion: Large doses may produce abdominal pain, nausea, and vomiting.
Skin Contact: May cause irritation with redness and pain.
Eye Contact: May cause irritation, redness and pain.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0470

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash
clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally.
Get medical attention if irritation persists.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

- OSHA Permissible Exposure Limit (PEL): 15 mg/m3 total dust, 5 mg/m3 respirable fraction for nuisance dusts.
- ACGIH Threshold Limit Value (TLV):
10 mg/m3 total dust containing no asbestos and < 1% crystalline silica for Particulates Not Otherwise Classified
(PNOC).

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit
or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever
is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use
concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Handling and Storage:
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from any source of heat or ignition. Containers of this material may be hazardous when empty since they retain
product residues (dust, solids); observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as
specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking
tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for
recovery or disposal and place in a closed container. Small amounts of residue may be flushed to sewer with plenty
of water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0472

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM BISULFITE 0472

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : SODIUM BISULFITE

Chinese Name:
Synonyms: Sodium acid sulfite; Sulfurous acid, monosodium salt; Sodium hydrogen sulfite, solid
CAS No: 7631-90-5
Molecular Weight: 104.06
Chemical Formula: Usually a mixture of NaHSO3 (sodium bisulfite) and Na2S2O5 (sodium metabisulfite)

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Coarse white granules.

Boiling Point: Not applicable.
Odor: Slight odor of sulfur dioxide.
Melting Point: 150°C (302°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Very soluble in water, insoluble in alcohol.
Vapor Density (Air=1): No information found.
Specific Gravity: 1.48
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): No information found.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire. Do not allow water runoff to enter sewers or waterways.

Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability:
Strength diminishes somewhat with age. Gradually decomposes in air to sulfate, generating sulfurous acid gas.
Contact with moisture (water, wet ice, etc.), Will release toxic sulfur dioxide gas.

Hazardous Decomposition Products: Burning may produce sulfur oxides.

Hazardous Polymerization: Will not occur.
Incompatibilities: Water, acids, alkalis, sodium nitrite, oxidizers, aluminum powder.
Conditions to Avoid: Moisture, heat, flames, ignition sources and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Warning! Harmful if swallowed or inhaled. May cause allergic respiratory reaction. Causes irritation to skin, eyes
and respiratory tract. Reacts with acids and water releasing toxic sulfur dioxide gas.

Potential Health Effects

Inhalation:
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. May cause allergic
reaction in sensitive individuals.

Ingestion:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0472
May cause gastric irritation by the liberation of sulfurous acid. An asthmatic reaction may occur after ingestion.
Large doses may result in nausea, vomiting, diarrhea, abdominal pains, circulatory disturbance, and central nervous
system depression. Estimated fatal dose is 10 gm.

Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain.
Eye Contact:
Causes irritation, redness, and pain. Contact may cause irreversible eye damage. Symptoms may include stinging,
tearing, redness, swelling, corneal damage and blindness.

Chronic Exposure: No information found.

Aggravation of Pre-existing Conditions:
Some individuals are said to be dangerously sensitive to minute amounts of sulfites in foods. Symptoms may include
broncho constriction, shock, gastrointestinal disturbances, angio edema, flushing, and tingling sensations. Once
allergy develops, future exposures can cause asthma attacks with shortness of breath, wheezing, and cough.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Get medical attention.

Skin Contact:
Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes.
Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean
shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

-ACGIH Threshold Limit Value (TLV):
5mg/m3 (TWA) for sodium bisulfite & for sodium metabisulfite, A4 Not classifiable as a human carcinogen.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a half-face respirator with an acid gas cartridge may be worn for up to ten times
the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator
supplier, whichever is lowest. A full-face piece respirator with an acid gas cartridge may be worn up to 50 times the
exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator
supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-
facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in
oxygen-deficient atmospheres.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away from
sources of heat, moisture and incompatibilities. Releases toxic sulfur dioxide gas when in contact with water, ice.
Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe
all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust.
Cautiously spray residue with plenty of water, providing ventilation to clear sulfur dioxide fumes generated from
water contact. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of
reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0473

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM IODIDE 0473

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name(S) : Sodium Iodide

Chinese Name:
Synonyms: Sodium iodine; Sodium monoiodide
CAS No: 7681-82-5
Molecular Weight: 149.89
Chemical Formula: NaI

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White granular or colorless crystals

Boiling Point: 1300°C (2372°F)
Odor: Odorless.
Melting Point: 651°C (1204°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: 184 g/l00 ml water @ 25°C
Vapor Density (Air=1): No information found.
Specific Gravity: 3.67
Vapor Pressure (mm Hg): 1 @ 767°C (1413°F)
pH: 8 - 9.5
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability:
Stable under ordinary conditions of use and storage. Absorbs up to 5% moisture on exposure to air and becomes
brown due to liberation of iodine.

Hazardous Decomposition Products:

When heated to decomposition it emits toxic fumes of iodine and sodium oxide.

Hazardous Polymerization: Will not occur.

Incompatibilities:
Alkali metals, chloral hydrate, acids tartaric acid, potassium chlorate, metallic salts, iodine. Reacts violently with
bromide trifluoride, perchloric acid, and oxidants.

Conditions to Avoid: Light and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Warning! Harmful if swallowed or inhaled. Causes irritation to skin, eyes and respiratory tract. Chronic exposure
may produce iodism

Potential Health Effects

Inhalation:
Inhalation of dust may cause coughing, choking, with variable symptoms of headache, dizziness, and weakness. May
cause lung edema.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0473
Ingestion:
Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea.

Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain.
Eye Contact: Causes irritation, redness, and pain.
Chronic Exposure:
A mild toxic syndrome "iodism" may result from chronic iodide overdoses. May cause salivation, sneezing,
conjunctivitis, headache, fever, laryngitis, bronchitis, stomatitis, and parotitis (iodine mumps). Prolonged or
repeated skin exposure may cause skin rashes.

Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Get medical attention.

Skin Contact:
Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes.
Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean
shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn.
For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from incompatible substances. Protect from light. Containers of this material may be hazardous when empty since
they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust.
Small amounts of residue may be flushed to sewer with plenty of water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0474

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM PEROXIDE 0474

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : SODIUM PEROXIDE

Chinese Name:
Synonyms: Disodium dioxide; disodium peroxide
CAS No: 1313-60-6
Molecular Weight: 77.98
Chemical Formula: Na2O2

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White to pale yellow granules.

Boiling Point: 657°C (1215°F)
Odor: Odorless.
Melting Point: 460°C (860°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Reacts violently in water.
Vapor Density (Air=1): No information found.
Density: 2.81
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles
may cause ignition.

Explosion:
Contact with combustible, organic, or oxidizable substances may cause extremely violent combustion. May react
explosively in contact with large amounts of water.

Fire Extinguishing Media:

Dry chemical or pulverized dolomite. DO NOT USE WATER, CARBON DIOXIDE, HALOCARBON or Wet
Chemical Extinguishers.

Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage. Water reactive.
Hazardous Decomposition Products:
Emits oxygen when heated to decomposition which may increase a fire hazard. Toxic oxides of sodium and metallic
sodium fumes may also be released.

Hazardous Polymerization: Will not occur.

Incompatibilities:
Moisture, organic and oxidizable substances, acetic acid, acetic anhydride, aluminum, aluminum plus carbon
dioxide, ammonium persulfate, aniline, antimony, arsenic, benzene, boron nitride, calcium carbide, charcoal,
dextrose plus potassium nitrate, diethyl ether, glycerine, hexamethylenetetramine, hydrogen sulfide, magnesium,
magnesium plus carbon dioxide, manganese dioxide, organic matter, phosphorus, potassium selenium
monochloride, silver chloride plus charcoal, sodium, sulfur monochloride, tin, and zinc, reducing agents.

Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0474

Emergency Overview
Danger! Corrosive. Strong oxidizer. Contact with other material may cause fire. Causes severe burns to every area
of contact. Harmful if swallowed or inhaled.

Potential Health Effects

Inhalation:
Extremely destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms may include
burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.

Ingestion:
Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach. Can cause sore throat, vomiting,
diarrhea.

Skin Contact: Corrosive. Symptoms of redness, pain, and severe burn can occur.
Eye Contact: Corrosive. Contact can cause blurred vision, redness, pain and severe tissue burns.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.

Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an
unconscious person. Get medical attention immediately.

Skin Contact:
Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse.
Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn.
For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Protect
from moisture. Separate from combustible, organic, or any other readily oxidizable materials. Containers of this
material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and
precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Clean-up personnel should wear protective clothing and respiratory equipment suitable for toxic or corrosive fluids
or vapors. Do not save for reclamation. Cover with double volume of sand-soda ash mixture (90%-10%). Mix
thoroughly and break up any lumps of peroxide. As an alternate, with a plastic scoop, add mixture slowly to a large
amount of water with stirring. Neutralize with dilute sulfuric acid. When settled decant the sulfate solution into the
drain with excess water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0476

Material Safety Data Sheet

City University of Hong Kong

MSDS SODIUM SULFITE 0476

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : SODIUM SULFITE

Chinese Name:
Synonyms: Sodium sulfite anhydrous; disodium sulfite; sulfurous acid, disodium salt; exsiccated sodium sulfite
CAS No: 7757-83-7
Molecular Weight: 126.04
Chemical Formula: Na2SO3

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White crystals.

Boiling Point: Not applicable.
Odor: Odorless.
Melting Point: No information found.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Soluble in ca. 3.2 parts water.
Vapor Density (Air=1): No information found.
Specific Gravity: 2.6 @ 15.4°C (60°F)
Vapor Pressure (mm Hg): No information found.
pH: ca. 9
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Not considered to be a fire hazard. If involved in a fire, can emit toxic fumes and irritating and corrosive gases.

Explosion: Not considered to be an explosion hazard.

Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability:
Stable under ordinary conditions of use and storage. Heat and moisture contribute to instability. May air-oxidize.

Hazardous Decomposition Products: Burning may produce sulfur oxides.

Hazardous Polymerization: Will not occur.
Incompatibilities: Acids, strong oxidizers, high temperatures.
Conditions to Avoid: Heat and moisture.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Warning! Harmful if swallowed. May cause allergic reaction and breathing difficulties. May cause irritation to skin,
eyes, and respiratory tract.

Potential Health Effects

Although only moderately toxic in large amounts, sulfites can pose risk to some asthmatics producing central
nervous system depression, bronchoconstriction and anaphylaxis.

Inhalation:
Inhalation of dust may cause irritation to the mucous membranes of the upper respiratory tract. Use of
bronchodilators preserved with sulfites can cause allergic reactions.

Ingestion:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0476
May cause gastric irritation by the liberation of sulfurous acid. Large doses may result in circulatory disturbances,
diarrhea, and central nervous system depression. Estimated fatal dose is 10g to 0.5 - > 5g/kg.

Skin Contact: May cause irritation.

Eye Contact: May cause irritation, redness and pain.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions:
Some individuals are said to be dangerously sensitive to minute amounts of sulfites in foods and some
bronchodilator medicines preserved with sulfites. Symptoms may include broncho constriction, shock,
gastrointestinal disturbances, angio edema, flushing, and tingling sensations.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Call a physician immediately.

Skin Contact:
Remove any contaminated clothing. Wash skin with soap and water for at least 15 minutes. Get medical attention if
irritation develops or persists.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

-ACGIH Threshold Limit Value (TLV):
5mg/m3 (TWA) for sodium bisulfite & for sodium metabisulfite, A4 Not classifiable as a human carcinogen.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit
or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever
is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use
concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away from
sources of heat, moisture and incompatibilities. Containers of this material may be hazardous when empty since
they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0478

Material Safety Data Sheet

City University of Hong Kong

MSDS SUCROSE 0478

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : SUCROSE

Chinese Name:
Synonyms: alpha-D-glucopyranosyl-beta-D-fructofuranoside; sugar
CAS No: 57-50-1
Molecular Weight: 342.3
Chemical Formula: C12H22O11

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Monoclinic sphenoidal crystals.

Boiling Point: Not applicable.
Odor: Characteristic caramel.
Melting Point: 160 - 186°C (320 - 367°F)

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: 1 gm/0.5 ml water
Vapor Density (Air=1): No information found.
Density: 1.59
Vapor Pressure (mm Hg): No information found.
pH: Solutions are neutral to litmus.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust
explosion hazard. Minimum explosible concentration in air: 0.045 g/l.

Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizers, sulfuric acid and nitric acid.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Caution! May form combustible dust concentrations in air. Nuisance dust. High concentrations may irritate eyes and
respiratory tract.

Potential Health Effects

Inhalation:
Not expected to be a health hazard. Nuisance dust. Inhalation of high concentrations may cause coughing and upper
respiratory tract irritation.

Ingestion: Extremely large oral dosages may produce gastrointestinal disturbances.

Skin Contact: No adverse effects expected.
Eye Contact: No adverse effects expected but dust may cause mechanical irritation.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0478

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact: Not expected to require first aid measures.
Eye Contact: Wash thoroughly with running water. Get medical advice if irritation develops.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

-OSHA Permissible Exposure Limit (PEL): 15 mg/m3 total dust, 5 mg/m3 respirable fraction
-ACGIH Threshold Limit Value (TLV): 10 mg/m3 total dust containing no asbestos and < 1% crystalline silica

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit
or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever
is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use
concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection: Safety glasses.
Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from any source of heat or ignition. Containers of this material may be hazardous when empty since they retain
product residues (dust, solids); observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as
specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking
tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for
recovery or disposal and place in a closed container.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0479

Material Safety Data Sheet

City University of Hong Kong

MSDS SUDAN III 0479

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : SUDAN III

Chinese Name: III
Synonyms:
Oil red; oil scarlet; CI 26100; Solvent Red 23; Sudan Red III; 2-naphthalenol, 1-((4-phenylazo) phenyl)azo-

CAS No: 85-86-9

Molecular Weight: 352.42
Chemical Formula: C22H16N4O

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Reddish-brown powder.

Boiling Point: No information found.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odor: No information found.
Melting Point: 199°C (390°F) Decomposes.
Solubility: Insoluble in water.
Vapor Density (Air=1): No information found.
Specific Gravity: No information found.
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.

Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust
explosion hazard.

Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the
chemical substance and ensure prompt removal from skin, eyes and clothing.

Potential Health Effects

Inhalation: No adverse health effects expected from inhalation.
Ingestion: Large doses may cause gastro-intestinal upset.
Skin Contact: No adverse effects expected.
Eye Contact: No adverse effects expected.
Chronic Exposure: No information found.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0479
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Not expected to require first aid measures. Remove to fresh air. Get medical attention for any breathing difficulty.

Ingestion: If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact: Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact: Wash thoroughly with running water. Get medical advice if irritation develops.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System: Not expected to require any special ventilation.
Personal Respirators (NIOSH Approved): Not expected to require personal respirator usage.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles.
Other Control Measures:
There is insufficient data in the published literature to assign complete numerical SAF-T-DATA* ratings and
laboratory protective equipment for this product. Special precautions must be used in storage, use and handling.
Protective equipment for laboratory bench use should be chosen using professional judgment based on the size and
type of reaction or test to be conducted and the available ventilation, with overriding consideration to minimize
contact with the chemical.

Handling and Storage:

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from incompatible substances. Containers of this material may be hazardous when empty since they retain product
residues (dust, solids); observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as
specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking
tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for
recovery or disposal and place in a closed container.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0481

Material Safety Data Sheet

City University of Hong Kong

MSDS THYMOL BLUE 0481

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : THYMOL BLUE

Chinese Name:
Synonyms:
Phenol, 4,4'-(3H-2,1-benzoxathiol-3-ylidene)bis(5-methyl-2 (1-methylethyl)-, S,S-dioxide; Thymolsulfonpthalein

CAS No: 76-61-9

Molecular Weight: 466.60
Chemical Formula: C27H30O5S

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Brownish-green powder.

Boiling Point: Not applicable.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Odor: Characteristic odor.
Melting Point: 221 - 224°C (430 - 435°F)
Solubility: Insoluble in water.
Vapor Density (Air=1): No information found.
Specific Gravity: No information found.
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.

Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust
explosion hazard.

Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, sulfur oxides.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers.
Conditions to Avoid: Dusting and incompatibles.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview: Caution! May cause irritation to skin, eyes, and respiratory tract.
Potential Health Effects
Specific hazard information about this compound was not found. However,
composition and structure suggest that the compound can be harmful.

Inhalation:
May cause irritation to the respiratory tract. Symptoms may include coughing, sore throat, labored breathing, and
chest pain.

Ingestion:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0481
The toxic effects of this substance have not been thoroughly investigated. Oral doses may have toxic effects.

Skin Contact: May cause irritation with redness and pain.

Eye Contact: May cause irritation, redness and pain.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical
attention.

Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Call a physician if irritation develops.

Eye Contact:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Call a physician if irritation persists.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

- OSHA Permissible Exposure Limit (PEL): 15 mg/m3 total dust, 5 mg/m3 respirable fraction for nuisance dusts.
- ACGIH Threshold Limit Value (TLV):
10 mg/m3 total dust containing no asbestos and < 1% crystalline silica for Particulates Not Otherwise Classified
(PNOC).

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit
or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever
is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use
concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away from
sources of heat, moisture and incompatibilities. Containers of this material may be hazardous when empty since
they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as
specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking
tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for
recovery or disposal and place in a closed container.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0483

Material Safety Data Sheet

City University of Hong Kong

MSDS TRIMETHYLAMINE 0483

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : TRIMETHYLAMINE

Chinese Name:
Synonyms: Methanamine, N, N-dimethyl; TMA solution
CAS No: 75-50-3
Molecular Weight: 59.11
Chemical Formula: C3H9N

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Clear, colorless liquid.

Boiling Point: 43°C (109°F)
Odor: Pungent odor.
Melting Point: 6°C (43°F) Freezes

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Completely soluble in water.
Vapor Density (Air=1): 2.0
Specific Gravity: 0.93
Vapor Pressure (mm Hg): 340 @ 25°C (77°F)
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): No information found.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
Flash point: 6°C (43°F)
Autoignition temperature: 190°C (374°F)
Flammable limits in air % by volume: LEL: 2.0; UEL: 11.6
Flammable Liquid

Explosion: Above the flash point, explosive vapor-air mixtures may be formed.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode. Vapors can flow along surfaces to
distant ignition source and flash back.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage. Decomposed by mercury.
Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides.
Hazardous Polymerization: Will not occur.
Incompatibilities:
Oxidizers may react explosively with mercury; may react with nitrosating agents such as sodium nitrite, to form N-
Nitrosodimethylamine, an OSHA regulated carcinogen.

Conditions to Avoid: No information found.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Warning! Flammable liquid. Harmful if swallowed or inhaled. Causes severe eye irritation and skin irritation. Causes
respiratory tract irritation.

Potential Health Effects

Inhalation:

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0483
Vapors are irritating to the nose, throat, lungs, and may cause coughing, sneezing and shortness of breath. Prolonged
exposure to high vapor concentrations may cause respiratory tract problems.

Ingestion: Harmful if swallowed. Corrosive nature of liquid causes tissue damage.

Skin Contact: Highly irritating to the skin. May cause frostbite, burns, and necrosis.
Eye Contact:
Vapors are irritating to the eyes. The liquid is highly irritating and may cause intense pain, severe corneal damage,
and permanent corneal opacity.

Chronic Exposure: Chronic exposure may cause dermatitis, conjunctivitis, and lung problems.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible
to the effects of the substance.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a
physician.

Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person.

Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Call a physician, immediately. Wash clothing before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

-OSHA Permissible Exposure Limit (PEL): 10 ppm (TWA), 15 ppm (STEL)
-ACGIH Threshold Limit Value (TLV): 5 ppm (TWA), 15 ppm (STEL)

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 If the TLV is exceeded a full facepiece chemical cartridge respirator may be worn up to the maximum use
concentration specified by the respirator supplier. Alternatively, a supplied air full facepiece respirator or airlined
hood may be worn.

Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.

Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and
quick-drench facilities in work area.

Handling and Storage:

Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire
hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be
bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use
non-sparking type tools and equipment, including explosion proof ventilation. Containers of this material may be
hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed
for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as
specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and
recover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an appropriate container or
absorb with an inert material (e. G., Vermiculite, dry sand, earth), and place in a chemical waste container. Do not
use combustible materials, such as saw dust. Do not flush to sewer!

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0484

Material Safety Data Sheet

City University of Hong Kong

MSDS BENEDICT SOLUTION 0484

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : BENEDICT SOLUTION

Chinese Name:
Synonyms: Sugar indicator
CAS No: Not applicable to mixtures.
Molecular Weight: Not applicable to mixtures.
Chemical Formula: Not applicable. (ca. 75% water)

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: Clear, blue liquid.

Boiling Point: No information found.
Odor: Characteristic odor.
Melting Point: No information found.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Miscible in water.
Vapor Density (Air=1): No information found.
Specific Gravity: No information found.
Vapor Pressure (mm Hg): No information found.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): No information found.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire: Not considered to be a fire hazard.

Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities:
Acids, bases, reducing or oxidizing agents, phosphorous pentoxide, zinc, lithium, calcium hydroxide.

Conditions to Avoid: No information found.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
Danger! May cause eye burns. Harmful if swallowed or inhaled. Causes irritation to skin and respiratory tract.

Potential Health Effects

Inhalation:
Inhalation of mist may be irritating to respiratory tract. Symptoms associated with overexposure to sodium
carbonate may include coughing, labored breathing and sore throat.

Ingestion:
Symptoms associated with ingestion of this solution are not expected to be severe. Ingestion of sodium carbonate
may be corrosive to the gastro-intestinal tract where symptoms may include abdominal pain, diarrhea and collapse.

Skin Contact: Solution can be an irritant to the skin.

Eye Contact:
Solution is irritating to the eyes. Contact with sodium carbonate may cause conjunctival edema and corrosion.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0484

Chronic Exposure: No information found.

Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible
to the effects of the substance.

========================================================================
FIRST AID MEASURES
========================================================================

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.

Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an
unconscious person. Get medical attention immediately.

Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits: None established.

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation,
A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

For conditions of use where limited exposure to fumes is apparent, a half mask chemical cartridge respirator may be
worn. For emergencies, use a self-contained breathing apparatus or supplied air.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and
quick-drench facilities in work area.

Handling and Storage:

Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away from
sources of heat, moisture and incompatibilities.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Contain
and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e. G.,
Vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as
saw dust. Do not flush to sewer!

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0487

Material Safety Data Sheet

City University of Hong Kong

MSDS CASEIN 0487

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical name(s) : CASEIN

Chinese Name:
Synonyms: Milk protein
CAS No: 9000-71-9
Molecular Weight: Not applicable.
Chemical Formula: Not applicable.

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance: White to off-white powder or granules.

Boiling Point: No information found.
Odor: Faint characteristic odor.
Melting Point: No information found.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Solubility: Negligible (< 0.1%)
Vapor Density (Air=1): Not applicable.
Specific Gravity: 1.25
Vapor Pressure (mm Hg): Not applicable.
pH: No information found.
Evaporation Rate (BuAc=1): No information found.
% Volatiles by volume @ 21°C (70°F): 10

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Fire:
As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.

Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust
explosion hazard. Minimum ignition temperature, dust cloud: 460°C.

Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information:
Use protective clothing and breathing equipment appropriate for the surrounding fire.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: No information found.
Conditions to Avoid: Moisture.

========================================================================
HEALTH HAZARD DATA
========================================================================

Emergency Overview
As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the
chemical substance and ensure prompt removal from skin, eyes and clothing.

Potential Health Effects

Inhalation: No adverse health effects expected from inhalation.
Ingestion: Not expected to be a health hazard via ingestion.
Skin Contact: Not expected to be a health hazard from skin exposure.
Eye Contact: Not expected to be a health hazard.
Chronic Exposure: No adverse health effects expected.
Aggravation of Pre-existing Conditions: No information found.

========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0487

FIRST AID MEASURES

========================================================================

Inhalation:
Not expected to require first aid measures. Remove to fresh air. Get medical attention for any breathing difficulty.

Ingestion:
Not expected to require first aid measures. If large amounts were swallowed, give water to drink and get medical
advice.

Skin Contact:
Not expected to require first aid measures. Wash exposed area with soap and water. Get medical advice if irritation
develops.

Eye Contact:
Not expected to require first aid measures. Wash thoroughly with running water. Get medical advice if irritation
develops.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Airborne Exposure Limits:

- OSHA Permissible Exposure Limit (PEL): 15 mg/m3 total dust, 5 mg/m3 respirable fraction for nuisance dusts.
- ACGIH Threshold Limit Value (TLV):
10 mg/m3 total dust containing no asbestos and < 1% crystalline silica for Particulates Not Otherwise Classified
(PNOC).

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details.

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit
or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever
is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use
concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-
supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing.

Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain
eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers
of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings
and precautions listed for the product.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills:
Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust
dispersal.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0491

Material Safety Data Sheet

City University of Hong Kong

MSDS OXALIC ACID 0491

========================================================================
PRODUCT INFORMATION
========================================================================

CHEMICAL NAME: Oxalic Acid

Chinese Name:
SYNONYMS(S): Ethanedioic Acid, Dicarboxylic acid.
CHEMICAL FAMILY: Dicarboxylic acids
MOLECULAR FORMULA: (COOH) 2.2H2O
PRODUCT USE:
Metal cleaning, textile cleaning, anti-corrosion coating, chemical intermediate and catalyst.
CAS.: 144-62-7

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

PHYSICAL STATE: Solid.

ODOUR AND APPEARANCE: Odourless, colorless crystals.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
ODOUR THRESHOLD: Not applicable. Odourless.
SPECIFIC GRAVITY: 1.9 @ 17°C
VAPOR PRESSURE: 0.001mmHg @ 20°C
VAPOR DENSITY: 4.4 (air = 1)
% VOLATILES BY VOLUME: Not applicable.
BULK DENSITY: Not applicable.
EVAPORATION RATE: Not applicable.
SOLUBILITY IN WATER: 83.4 g/l
BOILING POINT: 149-160°C
MELTING POINT:190°C
pH: 1.3 (.1 M solution in water).
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

CONDITIONS OF FLAMMABILITY: Not applicable.

MEANS OF EXTINCTION: Water spray, dry chemical, alcohol foam or CO2
FLASH POINT AND METHOD OF DETERMINATION:
This material does not have a flash point but is readily ignited.

UPPER FLAMMABLE LIMIT: Not applicable.

LOWER FLAMMABLE LIMIT: Not applicable.
AUTO IGNITION TEMPERATURE: Not available.
SPECIAL FIRE FIGHTING PROCEDURES:
Wear complete face mask and self contained breathing apparatus. Use water to keep fire exposed containers cool.
Water may be used to flush spills away from fire.

FIRE AND EXPLOSION HAZARDS:

If molten, water or foam may cause frothing. In a fire oxalic acid breaks down into carbon monoxide, carbon dioxide
and formic acid. Fumes may be highly toxic and irritating.

========================================================================
REACTIVITY DATA
========================================================================

STABILITY: Normally stable.

CONDITIONS CONTRIBUTING TO THE FOLLOWING INSTABILITY:
Heat or ultra-violet light contribute to instability. Sublimes at 150°C (melting point).
INCOMPATIBILITY:
Furfuryl alcohol, silver, alkalies, chlorites, oxidizing agents, iron and iron compounds.
HAZARDOUS REACTIONS/DECOMPOSITIONS:
In a fire oxalic acid breaks down into carbon monoxide, carbon dioxide, and formic acid. Fumes may be highly toxic
and irritating.

HAZARDOUS POLYMERIZATION: Will not occur.

========================================================================
HEALTH HAZARD DATA
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0491

INHALATION:
Oxalic acid can cause irritation of the nose and throat, and shortness of breath. When inhaled it is readily absorbed
into the body and may cause headache and nausea.

EYE CONTACT:
Severe eye irritant. Can cause redness, pain and damage to the cornea. Prolonged exposure can cause irreversible
eye damage.

SKIN CONTACT: Corrosive. Can cause skin irritation after prolonged exposure.
INGESTION:
Can cause severe poisoning or death depending on concentration and amount ingested. Can cause burns to the throat
and stomach. A delayed effect of ingestion is kidney damage, possibly leading to renal failure.

CHRONIC EXPOSURE EFFECTS:

Chronic exposure to oxalic acid by ingestion, skin absorption and inhalation, is linked to stone formation in the
kidney and urinary tract. Overexposure also leads to chronic respiratory tract irritation. Overexposure can also lead
to ulcers of the skin, discoloration and possibly gangrene.

EXPOSURE LIMITS: (TLV-TWA) 1 mg/m3; Short term;(TLV-STEL) 2 mg/m3

IRRITANCY: Not available.
CARCINOGENICITY: Not available.
REPRODUCTIVE TOXICITY: Not available. MUTAGENICITY: Not available.
SENSITIZATION TO PRODUCT: Not available.
ANIMAL TOXICITY DATA: LD50 (oral, rat) 375 mg/kg
NAME OF TOXICOLOGICALLY SYNERGISTIC PRODUCTS: Not available.
OTHER HEALTH EFFECTS:
Could effect the production of milk and bone growth in breastfeeding animals or animals in gestation.

========================================================================
FIRST AID MEASURES
========================================================================

INHALATION:
Remove from contaminated area to fresh air. If breathing has stopped begin artificial respiration. Obtain medical
attention immediately.

EYE CONTACT:
Flush the contaminated eye(s) with lukewarm water for at least 20 minutes while holding eyelid(s) open. Obtain
medical attention immediately.

SKIN CONTACT:
Remove contaminated clothing. Wash skin with water for at least 20 minutes. Obtain medical attention immediately.

INGESTION:
DO NOT induce vomiting. Give large quantities of water or milk. If vomiting occurs naturally readminister water or
milk.

========================================================================

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
PREVENTATIVE MEASURES
========================================================================

RESPIRATORY PROTECTION:
If over TLV wear dust/mist respirator with chemical goggles. Alternatively, supplied air full facepiece respirator or
air lined hood. Consult respirator supplier for limitations.

EYE/FACE PROTECTION:
Chemical safety goggles and/or full face shield. Contact lens should not be worn. Maintain eyewash fountain and
quick drench facilities in work areas.

SKIN PROTECTION:
Wear impervious, protective clothing including boots, gloves, lab coat, apron or coveralls to prevent skin contact.
Maintain a safety shower in the working area.

ENGINEERING CONTROLS:
Local exhaust ventilation preferred because emissions of contaminants can be controlled at source.

RESPIRATORY CONTROLS: Not applicable.

MATERIALS FOR PROTECTIVE CLOTHING: Natural rubber, neoprene, nitrile or polyethylene.
PRECAUTIONS:
Prepare emergency action plan in advance. Ensure workers are knowledgeable in the safe handling of this product.

STORAGE REQUIREMENTS:
Store sealed container in dry, well-ventilated area away from heat and incompatibles.

SPECIAL SHIPPING REQUIREMENTS: Not applicable.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

STEPS IN THE EVENT OF A SPILL OR LEAK:

Cover with soda ash or sodium bicarbonate to neutralize. Sweep into sealed container. Wear protective clothing.
Prevent material from entering sewers or waterways. CLEANUP - Cover with soda ash or sodium bicarbonate to
neutralize. Sweep into sealed container. Flush area with water.

WASTE DISPOSAL:
Dispose according to local, provincial and federal laws. DO NOT flush down sewer. Dissolve in a flammable solvent
and burn or soak in paper and burn.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0499

Material Safety Data Sheet

City University of Hong Kong

MSDS Iron, metal 0499

========================================================================
PRODUCT INFORMATION
========================================================================

Chemical Name and Synonyms: Iron, metal

Chinese Name:
Chemical Family: Metal
Chemical Formula: Fe
Product Use: Laboratory reagent
CAS No.7439-89-6

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Physical State: Solid

Odour and Appearance: Fine grey filings, shavings or powder, odourless
Odour Threshold (ppm): Not applicable
Vapour Pressure (mm Hg): Not available

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapour Density (Air = 1): Not available
Evaporation Rate: Not available
Boiling Point (°C): 2750°C
Melting Point (°C): 1535°C
pH: Not available
Specific Gravity: 7.87
Coefficient of Water/Oil distribution: Not available

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Flammability:
Flammable solid. In powder form, can burn in air or react with oxidizers,
and is capable of creating a dust explosion under certain conditions.

Extinguishing Media:
Dry chemical powder. DO NOT USE WATER. FIrefighters must wear protective
equipment and clothing sufficient to prevent inhalation of mists or
fumes, and contact with skin, eyes, and clothing.

Flash Point (Method Used): Not available

Autoignition Temperature: Not available
Upper Flammable Limit (% by volume): Not available
Lower Flammable Limit (% by volume): Not available
Hazardous Combustion Products: Toxic iron oxide fumes
Sensitivity to Impact: None
Sensitivity to Static discharge: As dust, may be ignited by static discharge under certain conditions.

========================================================================
REACTIVITY DATA
========================================================================

Chemical Stability:
Stable to temperature of 700°C. Stable in dry air; readily oxidizes in moist air, forming rust. Ultrafine (5 microns)
powder is very unstable and can ignite spontaneously in air.

Incompatibility with other substances:

Avoid acids, moisture, oxygen. Reacts violently with strong oxidizing agents, halogens, phosphorus, polystyrene.
Reaction with water can produce flammable/explosive hydrogen gas.

Reactivity: Avoid incompatible materials. Moisture, generation of dust, ignition sources.

Hazardous Decomposition Products: Toxic iron oxide fumes.

========================================================================
HEALTH HAZARD DATA
========================================================================

Toxicological Data:
LD50: (oral, rat) 30 g/kg

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0499
LC50: Not available

Effects of Acute Exposure to Product:

Inhaled: Inhalation of dust is irritating and may be harmful.
In contact with skin: May irritate.
In contact with eyes: May cause mechanical irritation.
Ingested:
May be harmful. Severe overdose may have corrosive effect on gastrointestinal system, with necrosis, perforation
and stricture. Symptoms of abdominal pain, nausea, vomiting, diarrhea may be delayed several hours. Metabolic
acidosis may occur several days after an apparent recovery, and can lead to convulsions and coma.

Effects of Chronic Exposure to Product:

Long term inhalation can cause siderosis, a benign pneumoconiosis. Long-term exposure may cause effects to the
liver, gastointestinal system, blood and cardiovascular system.

Carcinogenicity:
Not listed as a human carcinogen. Tumorigenic by RTECS (4565500) criteria
Teratogenicity: No information available
Reproductive Effects: No information available
Mutagenicity: No information available
Synergistic Products: None known

========================================================================
FIRST AID MEASURES
========================================================================

Eyes:
Flush thoroughly with water for at least fifteen (15) minutes, holding eyelids open while flushing. Get medical
advice if irritation develops.

Skin:
Remove contaminated clothing. Wash skin with plenty of water for at least fifteen (15) minutes. If irritation
develops seek medical attention.

Inhalation:
Remove to fresh air. Give oxygen and get medical attention for any breathing difficulty.

Ingestion:
If victim is alert and not convulsing, rinse mouth thoroughly with water and give 2 to 4 glasses of water to drink. Do
not induce vomiting. Seek medical attention.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Engineering Controls: Local exhaust recommended

Respiratory Protection:
Dust mask. NIOSH/MSHA approved air-purifying respirator or self-contained breathing apparatus for high or
unknown exposures, or for fire or spill conditions.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Eye Protection: Chemical safety goggles.
Skin Protection: Rubber gloves. Other protective clothing as required to limit contact.
Other Personal Protective Equipment: Safety shower and eye-wash fountain in work area.
Handling Procedures and Equipment:
Flammable solid. Workers using this product should be thoroughly trained in its hazards and its safe use. Keep away
from flames and other ignition sources. Use non-sparking tools. Follow routine safe handling procedures. Avoid
generating dust.

Storage Requirements:
Moisture sensitive. Store in suitable, labelled containers, in a cool, dry, well-ventilated area, out of direct sunlight.
Keep containers tightly closed when not in use and when empty. Protect from damage.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Leak and Spill Procedure:

Eliminate all sources of ignition. Cleanup personnel should wear protective equipment and clothing sufficient to
prevent inhalation of dust and particles and contact with skin, eyes and clothing. Mix with inert substance and
transfer carefully into container for removal by disposal company. Wash site of spillage thoroughly with water and
detergent. Use non-sparking tools.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0501

Material Safety Data Sheet

City University of Hong Kong

MSDS AMYLASE 0501

========================================================================
PRODUCT INFORMATION
========================================================================

NAME: AMYLASE REAGENT

Chinese Name:
CAS: NONE

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: LIQUID.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Extinguishing Media: Water spray. carbon dioxide, dry chemical powder or appropriate foam.
Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

========================================================================
REACTIVITY DATA
========================================================================

Stability: STABLE.
Hazardous Combustion Or Decomposition Products: Nature of decomposition products not known.
Hazardous Polymerization: Will not occur.

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May be harmful by inhalation, ingestion, or skin absorption.
May cause irritation.
Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals.
The toxicological properties have not been thoroughly investigated.

========================================================================
FIRST AID MEASURES
========================================================================

If swallowed, wash out mouth with water provided person is conscious. Call a physician.
In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing
and shoes. Call a physician.
If inhaled, remove to fresh air. If breathing becomes difficult, call a physician.
In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing
by separating the eyelids with fingers. Call a physician.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant gloves, safety goggles, other protective
clothing.
Mechanical exhaust.
Store in a cool dry place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear protective equipment.

Absorb on sand or vermiculite and place in closed containers for disposal.
Ventilate area and wash spill site after material pickup is complete.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0501

Disposal Considerations :
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state and local environmental regulations.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0504

Material Safety Data Sheet

City University of Hong Kong

MSDS CALCIUM HYPOCHLORITE 0504

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Calcium Hypochlorite

Chinese Name:
CAS #:none
Synonyms:
B-k powder * bleaching powder * calcium chlorohydrochlorite * calcium hypochlorite * calcium oxychloride *
caporit * chemichlor g * chloride of lime * chlorinated lime * chlorolime chemical * hth * hth (bleaching agent) *
hy-chlor * lime chloride * lo-bax * losantin * perchloron * pittchlor * pittcide * pittclor * sentry * solvox ks * t-
eusol *

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Melting point: 100°C

Specific gravity: 2.35

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Special Firefighting Procedures:

Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Unusual Fire And Explosions Hazards:

Contact with other material may cause fire. Emits toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Strong reducing agents strong acids

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
If swallowed calcium hypochlorite can produce nausea, vomiting, delirium, coma, respiratory collapse, holes in the
esophogus and stomach. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis,
shortness of breath, headache, nausea and vomiting. To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated. Harmful if swallowed, inhaled, or absorbed through
skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract,
eyes and skin.

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact, immediately flush eyes or skin with copious amounts of water for at least 15 minutes while
removing contaminated clothing and shoes.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
Assure adequate flushing of the eyes by separating the eyelids with fingers.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant

Gloves, safety goggles, other protective clothing.
Safety shower and eye bath.
Use only in a chemical fume hood.
Avoid breathing dust.
Do not get in eyes, on skin, on clothing.
Avoid prolonged or repeated exposure.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0504
Wash thoroughly after handling.
Wash contaminated clothing before reuse.
Discard contaminated shoes.
Severe irritant.
Keep tightly closed.
Keep away from combustible materials, heat, sparks, and open flame.
Store in a cool dry place.
Avoid contact with acid.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Evacuate area.
Shut off all sources of ignition.
Wear self-contained breathing apparatus, rubber boots and heavy
Rubber gloves.
Cover with dry-lime, sand, or soda ash. Place in covered containers
Using non-sparking tools and transport outdoors.

Disposal Considerations:
Cautiously acidify a 3% solution or a suspension of the material to pH 2 with sulfuric acid. Gradually add a 50%
excess of aqueous sodium bisulfite with stirring at room temperature. An increase in temperature indicates that a
reaction is taking place. If no reaction is observed on the addition of about 10% of the sodium bisulfite solution
initiate it by cautiously adding more acid. If manganese, chromium, or molybdenum are present adjust the pH of the
solution to 7 and treat with sulfide to precipitate for burial as hazardous waste. Destroy excess sulfide, neutralize
and flush the solution down the drain. Observe all federal, state and local environmental regulations.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0505

Material Safety Data Sheet

City University of Hong Kong

MSDS BUFFER TABLETS pH 7.0 0505

========================================================================
PRODUCT INFORMATION
========================================================================

Name: buffer tablets pH 7.0 package with 50 pieces

Chinese Name:
CAS #:None

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Solid.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Extinguishing Media:
Noncombustible. Use extinguishing media appropriate to surrounding fire conditions.

Special Firefighting Procedures:

Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Unusual Fire And Explosions Hazards: Emits toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Strong Acids

Hazardous Combustion Or Decomposition Products: Nature of decomposition products not known.

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May be harmful by inhalation, ingestion, or skin absorption.
Causes eye and skin irritation.
Material is irritating to mucous membranes and upper respiratory tract.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated.

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.
In case of contact, immediately wash skin with soap and copious amounts of water.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
If swallowed, wash out mouth with water provided person is conscious. Call a physician. Wash contaminated
clothing before reuse.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant

Gloves, safety goggles, other protective clothing.
Safety shower and eye bath.
Mechanical exhaust required.
Do not breathe dust.
Avoid contact with eyes, skin and clothing.
Avoid prolonged or repeated exposure.
Wash thoroughly after handling.
Irritant.
Keep tightly closed.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0505
Hygroscopic
Store in a cool dry place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. Sweep up, place in a bag and hold for
waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0506

Material Safety Data Sheet

City University of Hong Kong

MSDS BUTYRALDEHYDE 0506

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Butyraldehyde
Chinese Name:
CAS #: 123-72-8
Molecular formula: C4H8O
Synonyms:
Aldehyde butyrique (French) * aldeide butirrica (Italian) * butal * butaldehyde * butalyde * butanal * n-butanal
(Czech) * butanaldehyde * butyl aldehyde * n-butyl aldehyde * butyral * butyraldehyd (German) * n-butyraldehyde *
butyric aldehyde * nci-c56291 *

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Boiling Point: 75°C

Melting Point: -96°C

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Flashpoint 12°F (-11°C)
Explosion Limits In Air:
Upper 11.8 %
Lower 2 %
Vapor Pressure: 90 mmHg
Specific Gravity: 0.8 g
Vapor Density: 2.5 g/l

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Extinguishing Media:
Carbon dioxide, dry chemical powder or appropriate foam. Water may be effective for cooling, but may not effect
extinguishment.

Special Firefighting Procedures:

Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Use water
spray to cool fire-exposed containers.

Unusual Fire And Explosions Hazards:

Extremely flammable. Vapor may travel considerable distance to source of ignition and flash back. Container
explosion may occur under fire conditions. Forms explosive mixtures in air.

========================================================================
REACTIVITY DATA
========================================================================

Conditions To Avoid: Protect from light.

Incompatibilities: Oxidizing agents, strong bases, strong reducing agents, strong acids
Hazardous Combustion Or Decomposition Products: Carbon monoxide, carbon dioxide
Hazardous Polymerization: May undergo autopolymerization.

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
Harmful if swallowed, inhaled, or absorbed through skin.
Material is extremely destructive to tissue of the mucous membranes
And upper respiratory tract, eyes and skin.
Inhalation may result in spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis and
pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness
of breath, headache, nausea and vomiting.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated. Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals.

========================================================================
FIRST AID MEASURES
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0506

In case of contact, immediately flush eyes or skin with copious amounts of water for at least 15 minutes while
removing contaminated clothing and shoes.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant

Gloves, safety goggles, other protective clothing.
Use only in a chemical fume hood.
Safety shower and eye bath.
Use nonsparking tools.
Do not breathe vapor.
Do not get in eyes, on skin, on clothing.
Avoid prolonged or repeated exposure.
Wash thoroughly after handling.
Remove and wash contaminated clothing promptly.
Keep tightly closed.
Keep away from heat, sparks, and open flame.
Store in a cool dry place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Evacuate Area:
Shut off all sources of ignition.
Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves.

Disposal Considerations:
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this
material is highly flammable.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0508

Material Safety Data Sheet

City University of Hong Kong

MSDS CANADA BALSAM 0508

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Canada Balsam

Chinese Name:
CAS #: 8007-47-4
Synonyms: Balsam Of Fir * Canadian Balsam * Fir Balsam Absolute *

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Melting Point: 93 - 98°C

Flashpoint 118°F(48°C)
Specific Gravity: 0,99

========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
FIRE AND EXPLOSION DATA
========================================================================

Extinguishing Media: Water spray. Carbon dioxide, dry chemical powder or appropriate foam.
Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Unusual Fire And Explosions Hazards: Combustible liquid. Emits toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable.
Incompatibilities: Sensitive to air, sensitive to moisture, strong oxidizing agents
Hazardous Combustion Or Decomposition Products: Carbon monoxide, carbon dioxide
Hazardous Polymerization: Will not occur.

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May cause skin irritation.
May cause eye irritation.
Material may be irritating to mucous membranes and upper respiratory tract.
May be harmful by inhalation, ingestion, or skin absorption.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated.

========================================================================
FIRST AID MEASURES
========================================================================

If swallowed, wash out mouth with water provided person is conscious. Call a physician.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
In case of contact, immediately wash skin with soap and copious amounts of water.
In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Safety shower and eye bath.

Mechanical exhaust required.
Wash contaminated clothing before reuse.
Wash thoroughly after handling.
Avoid breathing vapor.
Avoid contact with eyes, skin and clothing.
Avoid prolonged or repeated exposure.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0508
NIOSH/MSHA-approved respirator.
Compatible chemical-resistant gloves.
Chemical safety goggles.
Keep tightly closed.
Keep away from heat and open flame.
Store in a cool dry place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves. Cover with dry-lime, sand, or soda
ash. Place in covered containers using non-sparking tools and transport outdoors. Ventilate area and wash spill site
after material pickup is complete. Evacuate area.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0511

Material Safety Data Sheet

City University of Hong Kong

MSDS COPPER NITRATE 0511

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Copper Nitrate

Chinese Name:
CAS #: 10031-43-3
Synonyms:
Copper dinitrate trihydrate * copper nitrate trihydrate * copper (ii) nitrate trihydrate * cupric nitrate trihydrate *
gerhardite * nitric acid, copper (2+) salt, trihydrate *

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Solid.

Melting Point: 114°C
Solubility:
Water -Soluble

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 Ether -Soluble
Ethyl Acetate: Soluble
Dioxane: Soluble
Specific Gravity: 2.320

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Extinguishing Media: Carbon dioxide, dry chemical powder or appropriate foam.

Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Oxidizer.

Unusual Fire And Explosions Hazards: May accelerate combustion.

Contact With Other Material May Cause Fire.: Emits toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable.
Incompatibilities:
Reducing agents, organic materials, finely powdered metals, heat, moisture

Hazardous Combustion Or Decomposition Products: Toxic fumes of: nitrogen oxides

Hazardous Polymerization: Will not occur.

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
Harmful if swallowed, inhaled, or absorbed through skin. Material is extremely destructive to tissue of the mucous
membranes and upper respiratory tract, eyes and skin.

Inhalation may result in spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis and
pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness
of breath, headache, nausea and vomiting.

Target Organ(S): Blood, kidneys, liver, central nervous system, vascular system
Additional Information:
Chronic copper poisoning is typified by hepatic cirrhosis, brain damage and demyelination, kidney defects, and
copper deposition in the cornea as exemplified by humans with wilson's disease. It has also been reported that
copper poisoning has lead to hemolytic anemia and accelerates arteriosclerosis.

========================================================================
FIRST AID MEASURES
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0511
In case of contact, immediately flush eyes or skin with copious amounts of water for at least 15 minutes while
removing contaminated clothing and shoes. Assure adequate flushing of the eyes by separating the eyelids with
fingers.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
If swallowed, wash out mouth with water provided person is conscious. Call a physician immediately. Remove and
wash contaminated clothing promptly.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant

Gloves, safety goggles, other protective clothing.
Use only in a chemical fume hood.
Faceshield (8-inch minimum).
Safety shower and eye bath.
Do not breathe dust.
Do not get in eyes, on skin, on clothing.
Wash thoroughly after handling.
Corrosive.
Harmful solid.
Keep tightly closed.
Do not store near, nor allow contact with, clothing and other
Combustible material.
Store in a cool dry place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Evacuate area.
Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves.
Use nonsparking tools.
Sweep up, place in a bag and hold for waste disposal.
Avoid raising dust.
Ventilate area and wash spill site after material pickup is complete.

Disposal Considerations:
The material should be dissolved in 1) water; 2) acid solution or 3) oxidized to a water-soluble state. Precipitate the
material as the sulfide, adjusting the pH of the solution to 7 to complete pre- cipitation. Filter the insolubles and
dispose of them in a hazardous- waste site. Destroy any excess sulfide with sodium hypochlorite. Neutralize the
solution before flushing down the drain. Observe all federal, state and local environmental regulations.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0516

Material Safety Data Sheet

City University of Hong Kong

MSDS D(+)-GLUCOSE MONOHYDRATE 0516

========================================================================
PRODUCT INFORMATION
========================================================================

NAME: D(+)-GLUCOSE MONOHYDRATE FOR MICROBIOLOGY*

Chinese Name:
CAS #: 5996-10-1
Molecular formula: C6H12O6.H2O

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Solid.

Solubility: Water -Soluble , Ethanol -Soluble

========================================================================
FIRE AND EXPLOSION DATA

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================

Extinguishing Media: Water spray. Carbon dioxide, dry chemical powder or appropriate foam.
Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Unusual Fire And Explosions Hazards: Emits toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Strong Oxidizing Agents

Hazardous Combustion Or Decomposition Products: Toxic fumes of: carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May be harmful by inhalation, ingestion, or skin absorption.
May cause eye irritation.
May cause skin irritation.
Material may be irritating to mucous membranes and upper respiratory tract.
To the best of our knowledge, the chemical, physical, and
Toxicological properties have not been thoroughly investigated.

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.
In case of contact, immediately wash skin with soap and copious amounts of water.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
If swallowed, wash out mouth with water provided person is conscious. Call a physician. Wash contaminated
clothing before reuse.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Chemical safety goggles.

Compatible chemical-resistant gloves.
NIOSH/MSHA-approved respirator.
Safety shower and eye bath.
Mechanical exhaust required.
Avoid inhalation.
Avoid contact with eyes, skin and clothing.
Avoid prolonged or repeated exposure.
Wash thoroughly after handling.
Keep tightly closed.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0516
Store in a cool dry place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves.
Sweep up, place in a bag and hold for waste disposal.
Avoid raising dust.
Ventilate area and wash spill site after material pickup is complete.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0519

Material Safety Data Sheet

City University of Hong Kong

MSDS FERROUS SULFIDE 0519

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Ferrous Sulfide

Chinese Name:
CAS #: 1317-37-9
Molecular formula: FeS

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Black-grey chunks

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Extinguishing Media: Water spray. Carbon dioxide, dry chemical powder or appropriate foam.
Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Unusual Fire And Explosions Hazards: Emits toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Strong oxidizing agents, moisture sensitive, air sensitive, strong acids
Hazardous Combustion Or Decomposition Products: Sulfur oxides, hydrogen sulfide gas

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May be harmful by inhalation, ingestion, or skin absorption.
May cause irritation.
To the best of our knowledge, the chemical, physical, and
Toxicological properties have not been thoroughly investigated.

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes. Flush skin with
water.
If inhaled, remove to fresh air.
If swallowed, wash out mouth with water provided person is conscious. Call a physician.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Chemical safety goggles.

Compatible chemical-resistant gloves.
Mechanical exhaust required.
Safety shower and eye bath.
Wear dust mask.
Avoid breathing dust.
Avoid contact with eyes, skin and clothing.
Wash thoroughly after handling.
Keep tightly closed.
Air and moisture sensitive
Store under nitrogen.
Store in a cool dry place.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0519
Handling And Storage:
Moist material oxidizes exothermically in air reaching ignition temperature. Exothermic reaction with lithium
initiates at 260°C and rapidly rises to 960°C.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves.
Sweep up, place in a bag and hold for waste disposal.
Avoid raising dust.
Ventilate area and wash spill site after material pickup is complete.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0520

Material Safety Data Sheet

City University of Hong Kong

MSDS LEAD(II) BROMIDE 0520

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Lead(II) Bromide

Chinese Name:
CAS #: 10031-22-8
Molecular formula: PbBr 2

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Boiling Point: 892°C

Melting Point: 373°C
Specific Gravity: 6.66

========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
FIRE AND EXPLOSION DATA
========================================================================

Extinguishing Media: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions.
Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Unusual Fire And Explosions Hazards: Emits toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Strong oxidizing agents

Hazardous Combustion Or Decomposition Products: Hydrogen bromide gas, lead/lead oxides

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May cause skin irritation.
May cause eye irritation.
Harmful if swallowed, inhaled, or absorbed through skin.
Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have
teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to
organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development
and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous and
digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular
dysfunction, possible paralysis and encephalopathy can result. Additional symptoms of overexposure include: joint
and muscle pain, weakness of the extensor muscles (frequently the hand and wrist), headache, dizziness, abdominal
pain, diarrhea, constipation, nausea, vomiting, blue line on the gums, insomnia and metallic taste. High body levels
produce increased cerebrospinal pressure, brain damage, stupor leading to coma and often death.

Chronic Effects:
May cause reproductive disorders.
Target Organ(S):
Blood, kidneys, nerves, female reproductive system, male reproductive system

========================================================================
FIRST AID MEASURES
========================================================================

If swallowed, wash out mouth with water provided person is conscious. Call a physician.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
In case of contact, immediately wash skin with soap and copious amounts of water.
In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.

========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0520

PREVENTATIVE MEASURES
========================================================================

Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant

Gloves, safety goggles, other protective clothing.
Safety shower and eye bath.
Mechanical exhaust required.
Do not breathe dust.
Avoid contact with eyes, skin and clothing.
Avoid prolonged or repeated exposure.
Wash thoroughly after handling.
Harmful dust.
Keep tightly closed.
Store in a cool dry place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves.
Sweep up, place in a bag and hold for waste disposal.
Avoid raising dust.
Ventilate area and wash spill site after material pickup is complete.

Disposal Considerations:
The material should be dissolved in 1) water; 2) acid solution or 3) oxidized to a water-soluble state. Precipitate the
material as the sulfide, adjusting the pH of the solution to 7 to complete precipitation. Filter the insolubles and
dispose of them in a hazardous- waste site. Destroy any excess sulfide with sodium hypochlorite. Neutralize the
solution before flushing down the drain. Observe all federal, state and local environmental regulations.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0524

Material Safety Data Sheet

City University of Hong Kong

MSDS POTASSIUM 0524

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Potassium, Chunks, In Mineral Oil, 98%

Chinese Name:
CAS #: 7440-09-7
Molecular formula: K
Additional Information: Contains mineral oil, chemical abstracts registry number 8012-95-1.

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Grey-black sticks

Melting Point: 64°C
Vapor Pressure: 0.09mm 260°C

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Extinguishing Media:
Use approved class d extinguishers or smother with dry sand, dry ground limestone or dry clay. Do not use water.
Do not use carbon dioxide extinguisher on this material.

Special Firefighting Procedures:

Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Flammable
solid.

Unusual Fire And Explosions Hazards:

Material readily reacts with water generating flammable and/or explosive hydrogen gas.

Emits Toxic Fumes Under Fire Conditions.: Catches fire if exposed to air.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Oxidizing agents, Teflon, chlorinated solvents, carbon monoxide, carbon dioxide,
Reacts Violently With: Water, acids, air sensitive
Hazardous Combustion Or Decomposition Products: Nature of decomposition products not known.

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
Harmful if inhaled or swallowed.
Causes burns.
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes and skin.

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact, immediately flush eyes or skin with copious amounts of water for at least 15 minutes while
removing contaminated clothing and shoes.
Assure adequate flushing of the eyes by separating the eyelids with fingers.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
If swallowed, wash out mouth with water provided person is conscious. Call a physician immediately. Discard
contaminated clothing and shoes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0524
NIOSH/MSHA-approved respirator.
Chemical safety goggles.
Wear heavy rubber gloves.
Rubber apron.
Faceshield (8-inch minimum).
Use nonsparking tools.
Use only in a chemical fume hood.
Avoid contact and inhalation.
Wash thoroughly after handling.
Corrosive.
Keep away from combustible materials, heat, sparks, and open flame.
Reacts violently with water.
Container should be opened only by a technically qualified person.

Handling And Storage:

Potassium readily forms hazardous oxides at room temperature even under oil, storage should be under argon or
oxygen free solvents (kerosene or toluene) once the material has been opened. Do not attempt to cut the material if
the surface is other than silver or black in appearance because a potentially explosive condition could exist.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Evacuate area.
Shut off all sources of ignition.
Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves.
Cover with dry-lime, sand, or soda ash. Place in covered containers using non-sparking tools and transport outdoors.
Ventilate area and wash spill site after material pickup is complete.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0525

Material Safety Data Sheet

City University of Hong Kong

MSDS SILICON POWDER 0525

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Silicon Powder

Chinese Name:
CAS #: 7440-21-3
Synonyms: Defoamer s-10 * polyeristalline silicon powder * silicon (ACGIN:OSHA) *

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Grey powder

Specific gravity: 2.330

========================================================================
FIRE AND EXPLOSION DATA

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================

Extinguishing Media: Dry chemical powder. Do not use water.

Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Unusual Fire And Explosions Hazards:

This material, like most materials in powder form, is capable of creating a dust explosion. Flammable solid. Emits
toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable.
Incompatibilities:
Reacts Violently With:
Alkali carbonates, oxidizing agents, (aluminum and lead azide), calcium, cesium chloride, cobalt diflouride,
elemental flourine, iodine pentafluoride, manganese trifluoride, rubidium chloride, flourine nitrate, silver fluoride,
and sodium-potassium alloy. Material readily reacts with water generating flammable and/or explosive hydrogen gas.

Hazardous Combustion Or Decomposition Products: Nature of decomposition products not known.

Hazardous Polymerization: Will not occur.

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
Material is irritating to mucous membranes and upper respiratory tract.
May be harmful by inhalation, ingestion, or skin absorption.
Causes eye and skin irritation.
To the best of our knowledge, the chemical, physical, and
Toxicological properties have not been thoroughly investigated.

========================================================================
FIRST AID MEASURES
========================================================================

If swallowed, wash out mouth with water provided person is conscious. Call a physician.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
In case of contact, immediately wash skin with soap and copious amounts of water.
Contamination of the eyes should be treated by immediate and prolonged irrigation with copious amounts of water.

========================================================================
PREVENTATIVE MEASURES
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0525
NIOSH/MSHA-approved respirator.
Compatible chemical-resistant gloves.
Chemical safety goggles.
Safety shower and eye bath.
Mechanical exhaust required.
Use nonsparking tools.
Avoid breathing dust.
Avoid contact with eyes, skin and clothing.
Avoid prolonged or repeated exposure.
Wash thoroughly after handling.
Discard contaminated clothing and shoes.
Keep tightly closed.
Store in a cool dry place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Evacuate area.
Shut off all sources of ignition.
Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves.
Cover with dry-lime, sand, or soda ash. Place in covered containers using non-sparking tools and transport outdoors.
Ventilate area and wash spill site after material pickup is complete.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0526

Material Safety Data Sheet

City University of Hong Kong

MSDS TIN, FOIL 0526

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Tin, Foil, 1.0mm Thick, 99.9%

Chinese Name:
CAS #: 7440-31-5
Molecular formula: Sn
Synonyms: Silver matt powder * tin (ACGIN:OSHA) * tin (alpha) * tin flake * tin powder * zinn (German) *

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Shiny silver foil

Melting Point: 231.9°C
Specific Gravity: 7.310

========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
FIRE AND EXPLOSION DATA
========================================================================

Extinguishing Media: Use extinguishing media appropriate to surrounding fire conditions.

Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Unusual Fire And Explosions Hazards: Emits toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Strong oxidizing agents, sulfur, strong bases, halogens

Hazardous Combustion Or Decomposition Products: Nature of decomposition products not known.

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May cause skin irritation.
May cause eye irritation.
May be harmful by inhalation, ingestion, or skin absorption.

========================================================================
FIRST AID MEASURES
========================================================================

If inhaled, remove to fresh air. Flush skin with water.

In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.

========================================================================
PREVENTATIVE MEASURES
========================================================================

NIOSH/MSHA-approved respirator.
Compatible chemical-resistant gloves.
Chemical safety goggles.
Safety shower and eye bath.
Mechanical exhaust required.
Avoid contact and inhalation.
Wash thoroughly after handling.
Keep container closed.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0526

Wear protective equipment.

Sweep up, place in a bag and hold for waste disposal.
Ventilate area and wash spill site after material pickup is complete.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0528

Material Safety Data Sheet

City University of Hong Kong

MSDS UREASE 0528

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Urease From Jack Beans, Powder,

Chinese Name:
CAS #: 9002-13-5
Synonyms: Jack bean urease *

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Solid.

Solubility: Water -soluble

========================================================================
FIRE AND EXPLOSION DATA

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================

Extinguishing Media: Carbon dioxide, dry chemical powder or appropriate foam. Water spray.
Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable.
Conditions To Avoid: Inhibited by heavy metal ions.
Hazardous Combustion Or Decomposition Products: Nature of decomposition products not known.
Hazardous Polymerization: Will not occur.

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May be harmful by inhalation, ingestion, or skin absorption.
May cause irritation.
Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals.

========================================================================
FIRST AID MEASURES
========================================================================

If swallowed, wash out mouth with water provided person is conscious. Call a physician.
In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing
and shoes. Call a physician.
If inhaled, remove to fresh air. If breathing becomes difficult, call a physician.
In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing
by separating the eyelids with fingers. Call a physician.

========================================================================
PREVENTATIVE MEASURES
========================================================================

NIOSH/MSHA-approved respirator.
Mechanical exhaust.
Compatible chemical-resistant gloves.
Chemical safety goggles.
Store in a cool dry place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0528
Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves.
Sweep up, place in a bag and hold for waste disposal.
Ventilate area and wash spill site after material pickup is complete. Avoid raising dust.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0530

Material Safety Data Sheet

City University of Hong Kong

MSDS DETTOL 0530

========================================================================
PRODUCT INFORMATION
========================================================================

Name: 4-Chloro-3,5-Dimethylphenol
Chinese Name:
CAS #: 88-04-0
Molecular formula: C8H9ClO
Synonyms:
Benzytol * 4-chloro-3,5-dimethylphenol * 2-chloro-5-hydroxy-1,3- dimethylbenzene * 4-chloro-1-hydroxy-3,5-
dimethylbenzene * 2-chloro-5- hydroxy-m-xylene * chloro-xylenol * p-chloro-m-xylenol * 2-chloro-m- xylenol *
4-chloro-3,5-xylenol * desson * dettol * espadol * husept extra * nipacide mx * ottasept * ottasept extra * pcmx *
phenol, 4- chloro-3,5-dimethyl- * rba 777 *

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Solid.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Melting Point: 114 To 116°C

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Extinguishing Media: Water spray. Carbon dioxide, dry chemical powder or appropriate foam.
Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Unusual Fire And Explosions Hazards: Emits toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Strong oxidizing agents, strong bases

Hazardous Combustion Or Decomposition Products:
Toxic fumes of: carbon monoxide, carbon dioxide, hydrogen chloride gas

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
Harmful if swallowed.
May be harmful if inhaled.
May be harmful if absorbed through the skin.
Causes eye and skin irritation.
Material is irritating to mucous membranes and upper respiratory tract.
Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of
tissue.

Prolonged Contact Can Cause:

Damage to the eyes
Severe irritation or burns.
Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated.

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.
In case of contact, immediately wash skin with soap and copious amounts of water.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
If swallowed, wash out mouth with water provided person is conscious. Call a physician. Wash contaminated
clothing before reuse.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0530
========================================================================
PREVENTATIVE MEASURES
========================================================================

Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant gloves, safety goggles, other protective
clothing.
Mechanical exhaust required.
Safety shower and eye bath.
Do not breathe dust.
Do not get in eyes, on skin, on clothing.
Avoid prolonged or repeated exposure.
Wash thoroughly after handling.
Harmful solid.
Irritant.
Keep tightly closed.
Store in a cool dry place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves.
Sweep up, place in a bag and hold for waste disposal.
Avoid raising dust.
Ventilate area and wash spill site after material pickup is complete.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0533

Material Safety Data Sheet

City University of Hong Kong

MSDS LACMOID 0533

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Lacmoid
Chinese Name:
CAS #: 33869-21-5

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Black powder

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Extinguishing Media: Water spray. Carbon dioxide, dry chemical powder or appropriate foam.
Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Strong oxidizing agents

Hazardous Combustion Or Decomposition Products:
Toxic fumes of: carbon monoxide, carbon dioxide nitrogen oxides

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May be harmful by inhalation, ingestion, or skin absorption.
Causes eye and skin irritation.
Material is irritating to mucous membranes and upper respiratory tract.
To the best of our knowledge, the chemical, physical, and
Toxicological properties have not been thoroughly investigated.

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.
In case of contact, immediately wash skin with soap and copious amounts of water.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
If swallowed, wash out mouth with water provided person is conscious. Call a physician. Wash contaminated
clothing before reuse.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Chemical safety goggles.

Rubber gloves.
NIOSH/MSHA-approved respirator.
Safety shower and eye bath.
Mechanical exhaust required.
Avoid contact and inhalation.
Do not get in eyes, on skin, on clothing.
Wash thoroughly after handling.
Irritant.
Keep tightly closed.
Store in a cool dry place.

========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0533

ENVIRONMENTAL PROTECTION DATA

========================================================================

Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves.
Sweep up, place in a bag and hold for waste disposal.
Avoid raising dust.
Ventilate area and wash spill site after material pickup is complete.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0535

Material Safety Data Sheet

City University of Hong Kong

MSDS LEAD(IV) ACETATE 0535

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Lead(IV) Acetate, 95%

Chinese Name:
CAS #: 546-67-8
Molecular formula: Pb(O2C2H3)4
Synonyms: Lead acetate * lead tetraacetate * plumbic acetate *

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: White to off-white crystalline powder

========================================================================
FIRE AND EXPLOSION DATA

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================

Extinguishing Media: Water spray. Carbon dioxide, dry chemical powder or appropriate foam.
Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Oxidizer.

Unusual Fire And Explosions Hazards:

Emits toxic fumes under fire conditions. Contact with other material may cause fire.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Alcohols, strong acids, strong reducing agents, air sensitive, moisture sensitive
Hazardous Combustion Or Decomposition Products:
Toxic fumes of: carbon monoxide, carbon dioxide, lead/lead oxides

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
Harmful if swallowed, inhaled, or absorbed through skin.
Causes eye and skin irritation.
Material is irritating to mucous membranes and upper respiratory tract.

Chronic Effects:
Carcinogen.
May cause reproductive disorders.
Target organ(s):
Peripheral nervous system, central nervous system, female reproductive system, male reproductive system, blood,
kidneys

Additional Information:
Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have
teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to
organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development
and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous and
digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular
dysfunction, possible paralysis and encephalopathy can result. Additional symptoms of overexposure include: joint
and muscle pain, weakness of the extensor muscles (frequently the hand and wrist), headache, dizziness, abdominal
pain, diarrhea, constipation, nausea, vomiting, blue line on the gums, insomnia and metallic taste. High body levels
produce increased cerebrospinal pressure, brain damage, stupor leading to coma and often death.

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact, immediately flush eyes or skin with copious amounts of water for at least 15 minutes while
removing contaminated clothing and shoes.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0535
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
If swallowed, wash out mouth with water provided person is conscious. Call a physician. Wash contaminated
clothing before reuse.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant

Gloves, safety goggles, other protective clothing.
Safety shower and eye bath.
Use only in a chemical fume hood.
Do not breathe dust.
Do not get in eyes, on skin, on clothing.
Avoid prolonged or repeated exposure.
Readily absorbed through skin.
Wash thoroughly after handling.
Toxic.
Irritant.
Carcinogen.
Reproductive hazard.
Keep tightly closed.
Air and moisture sensitive
Do not store near, nor allow contact with, clothing and other
Combustible material.
Store under nitrogen.
Refrigerate.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Evacuate area.
Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves.
Sweep up, place in a bag and hold for waste disposal.
Avoid raising dust.
Ventilate area and wash spill site after material pickup is complete.

Disposal Considerations :
The material should be dissolved in 1) water; 2) acid solution or 3) oxidized to a water-soluble state. Precipitate the
material as the sulfide, adjusting the pH of the solution to 7 to complete precipitation. Filter the insolubles and
dispose of them in a hazardous- waste site. Destroy any excess sulfide with sodium hypochlorite. Neutralize the
solution before flushing down the drain. Observe all federal, state and local environmental regulations.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0536

Material Safety Data Sheet

City University of Hong Kong

MSDS LEAD OXIDE, RED 0536

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Lead Oxide, Red, Powder, 1-2micron, 99%

Chinese Name:
CAS #: 1314-41-6
Molecular formula: Pb3O4
Synonyms:
C.I. 77578 * C.I. pigment red 105 * gold satinobre * heuconin 5 * lead orthoplumbate * lead oxide (Pb3O4) * lead
oxide (3:4) * lead oxide red * lead tetraoxide * lead tetroxide * mennige * mineral orange * mineral red * minium *
minium non-setting rl 95 * orange lead * Paris red * pigment red 105 * plumboplumbic oxide * red lead * red lead
oxide * sandix * saturn red * trilead tetraoxide * trilead tetroxide *

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Orange powder

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Extinguishing Media: Water spray.

Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Oxidizer.

Unusual Fire And Explosions Hazards:

Contact with other material may cause fire. Emits toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Strong reducing agents

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May be harmful by inhalation, ingestion, or skin absorption.
Causes eye and skin irritation.
Material is irritating to mucous membranes and upper respiratory tract.
Chronic Effects:
May cause reproductive disorders.
Target organ(s): Blood, kidneys, nerves, female reproductive system, male reproductive system

Additional Information:
Lead salts have been reported to cross the placenta and to induce embryo- and feto- mortality. They also have
teratogenic effect in some animal species. No teratogenic effects have been reported with exposure to
organometallic lead compounds. Adverse effects of lead on human reproduction, embryonic and fetal development
and postnatal (e.g., mental) development have been reported. Excessive exposure can affect blood, nervous and
digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If left untreated, neuromuscular
dysfunction, possible paralysis and encephalopathy can result. Additional symptoms of overexposure include: joint
and muscle pain, weakness of the extensor muscles (frequently the hand and wrist), headache, dizziness, abdominal
pain, diarrhea, constipation, nausea, vomiting, blue line on the gums, insomnia and metallic taste. High body levels
produce increased cerebrospinal pressure, brain damage, stupor leading to coma and often death.

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact, immediately flush eyes or skin with copious amounts of water for at least 15 minutes while
removing contaminated clothing and shoes.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0536
If swallowed, wash out mouth with water provided person is conscious. Call a physician. Wash contaminated
clothing before reuse.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant gloves, safety goggles, other protective
clothing.
Use only in a chemical fume hood.
Safety shower and eye bath.
Avoid breathing dust.
Do not get in eyes, on skin, on clothing.
Avoid prolonged or repeated exposure.
Wash thoroughly after handling.
Irritant.
Harmful dust.
Reproductive hazard.
Keep tightly closed.
Keep away from combustible materials, heat, sparks, and open flame.
Store in a cool dry place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Evacuate area.
Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves.
Cover with dry lime or soda ash, pick up, keep in a closed container and hold for waste disposal.
Ventilate area and wash spill site after material pickup is complete.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0537

Material Safety Data Sheet

City University of Hong Kong

MSDS LEISHMAN'S STAIN 0537

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Leishman's Stain

Chinese Name:
CAS #: 12627-53-1

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Green powder

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Extinguishing Media: Water spray. Carbon dioxide, dry chemical powder or appropriate foam.
Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable.
Incompatibilities: Oxidizing agents
Hazardous Combustion Or Decomposition Products: Nature of decomposition products not known.
Hazardous Polymerization: Will not occur.

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May be harmful by inhalation, ingestion, or skin absorption.
May cause irritation.
The toxicological properties have not been thoroughly investigated.

========================================================================
FIRST AID MEASURES
========================================================================

If swallowed, wash out mouth with water provided person is conscious. Call a physician.
In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing
and shoes. Call a physician.
If inhaled, remove to fresh air. If breathing becomes difficult, call a physician.
In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing
by separating the eyelids with fingers. Call a physician.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant gloves, safety goggles, other protective
clothing.
Mechanical exhaust required.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear protective equipment.

Sweep up, place in a bag and hold for waste disposal.
Avoid raising dust.
Ventilate area and wash spill site after material pickup is complete.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0540

Material Safety Data Sheet

City University of Hong Kong

MSDS MANGANESE(II) SULFATE HYDRATE 0540

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Manganese(II) Sulfate Hydrate, 99.99+%

Chinese Name:
CAS #: 15244-36-7
Molecular formula: MNO4S
Synonyms:
Manganese sulfate (1:1) * manganese (2+) sulfate (1:1) * manganese sulphate * manganous sulfate * man-gro *
NCI c61143 * sorba-spray mn * sulfuric acid, manganese (ii) salt (1:1) (8ci) *

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Pink crystalline powder and chunks

Specific Gravity: 2.090

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================
FIRE AND EXPLOSION DATA
========================================================================

Extinguishing Media: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions.
Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Unusual Fire And Explosions Hazards: Emits toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Strong acids

Hazardous Combustion Or Decomposition Products: Sulfur oxides

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
Men exposed to manganese dusts showed a decrease in fertility. Chronic manganese poisoning primarily involves
the central nervous system. Early symptoms include languor, sleepiness and weakness in the legs. A stolid mask-like
appearance of the face, emotional disturbances such as uncontrollable laughter and a spastic gait with tendency to
fall in walking are findings in more advanced cases. High incidence of pneumonia has been found in workers
exposed to the dust or fume of some manganese compounds.
Material is irritating to mucous membranes and upper respiratory tract.
Harmful if swallowed, inhaled, or absorbed through skin.
Causes eye and skin irritation.

Chronic Effects: Target organ(s): Central nervous system, Lungs

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact, immediately flush eyes or skin with copious amounts of water for at least 15 minutes while
removing contaminated clothing and shoes.
If swallowed, wash out mouth with water provided person is conscious. Call a physician.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
Assure adequate flushing of the eyes by separating the eyelids with fingers.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant gloves, safety goggles, other protective
clothing.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0540
Safety shower and eye bath.
Use only in a chemical fume hood.
Do not breathe dust.
Do not get in eyes, on skin, on clothing.
Avoid prolonged or repeated exposure.
Wash thoroughly after handling.
Wash contaminated clothing before reuse.
Irritant.
Keep tightly closed.
Refrigerate.
Hygroscopic

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves.
Sweep up, place in a bag and hold for waste disposal.
Avoid raising dust.
Ventilate area and wash spill site after material pickup is complete.

Disposal Considerations:
The material should be dissolved in 1) water; 2) acid solution or 3) oxidized to a water-soluble state. Precipitate the
material as the sulfide, adjusting the pH of the solution to 7 to complete precipitation. Filter the insolubles and
dispose of them in a hazardous- waste site. Destroy any excess sulfide with sodium hypochlorite. Neutralize the
solution before flushing down the drain. Observe all federal, state and local environmental regulations.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0543

Material Safety Data Sheet

City University of Hong Kong

MSDS METHYL 2-METHYLPENTANOATE 0543

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Methyl 2-Methylpentanoate, 98+%

Chinese Name:
CAS #: 2177-77-7
Molecular formula: C7H14O2

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Boiling Point: 45°C/.2mm.

Flashpoint: 85°F( 29.44°C)
Specific Gravity: 0.878

========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
FIRE AND EXPLOSION DATA
========================================================================

Extinguishing Media: Carbon dioxide, dry chemical powder or appropriate foam.

Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Flammable
liquid.

Unusual Fire And Explosions Hazards:

Vapor may travel considerable distance to source of ignition and flash back. Emits toxic fumes under fire
conditions.

========================================================================
REACTIVITY DATA
========================================================================

Incompatibilities: Strong oxidizing agents

Hazardous Combustion Or Decomposition Products: Toxic fumes of: carbon monoxide, carbon dioxide

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May be harmful by inhalation, ingestion, or skin absorption.
May cause eye irritation.
May cause skin irritation.
Material may be irritating to mucous membranes and upper respiratory tract.
Prolonged or repeated exposure to skin causes defatting and dermatitis.

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.
In case of contact, immediately wash skin with soap and copious amounts of water.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
If swallowed, wash out mouth with water provided person is conscious. Call a physician.
Remove and wash contaminated clothing promptly.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant gloves, safety goggles, other protective
clothing.
Safety shower and eye bath.
Mechanical exhaust required.
Use nonsparking tools.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0543
Do not breathe vapor.
Do not get in eyes, on skin, on clothing.
Avoid prolonged or repeated exposure.
Wash thoroughly after handling.
Keep tightly closed.
Keep away from heat, sparks, and open flame.
Store in a cool dry place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Evacuate area.
Shut off all sources of ignition.
Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves.
Cover with dry-lime, sand, or soda ash. Place in covered containers using non-sparking tools and transport outdoors.
Ventilate area and wash spill site after material pickup is complete.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0546

Material Safety Data Sheet

City University of Hong Kong

MSDS PEPTONE 0546

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Peptone Yeast Extract Iron Citrate Agar, F Or Microbiology*

Chinese Name:
CAS #:NONE

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Solid.

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Extinguishing Media: Water spray. Carbon dioxide, dry chemical powder or appropriate foam.
Special Firefighting Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Unusual Fire And Explosions Hazards: Emits toxic fumes under fire conditions.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Stable.
Incompatibilities: Strong oxidizing agents, protect from moisture.
Hazardous Combustion Or Decomposition Products: Nature of decomposition products not known.
Hazardous Polymerization: Will not occur.

========================================================================
HEALTH HAZARD DATA
========================================================================

Acute Effects:
May be harmful by inhalation, ingestion, or skin absorption.
May cause eye irritation.
May cause skin irritation.
Material may be irritating to mucous membranes and upper respiratory tract.

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.
In case of contact, immediately wash skin with soap and copious amounts of water.
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
If swallowed, wash out mouth with water provided person is conscious. Call a physician.
Wash contaminated clothing before reuse.

========================================================================
PREVENTATIVE MEASURES
========================================================================

Chemical safety goggles.

Compatible chemical-resistant gloves.
NIOSH/MSHA-approved respirator.
Safety shower and eye bath.
Mechanical exhaust required.
Avoid inhalation.
Avoid contact with eyes, skin and clothing.
Avoid prolonged or repeated exposure.
Wash thoroughly after handling.
Keep tightly closed.
Store in a cool dry place.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0546

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves.
Sweep up, place in a bag and hold for waste disposal. Avoid raising dust.
Ventilate area and wash spill site after material pickup is complete.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0552

Material Safety Data Sheet

City University of Hong Kong

MSDS VASELINE 0552

========================================================================
PRODUCT INFORMATION
========================================================================

Name: Vaseline, White

Chinese Name:
CAS #:NONE

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Form – paste, Color - colorless , Odor - odorless

Flashpoint: 419°F (215°C)
Solubility: Water -insoluble

========================================================================
FIRE AND EXPLOSION DATA

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================

Extinguishing Media: Water spray. Carbon dioxide, dry chemical powder or appropriate foam.
Hazardous Polymerization: Will not occur.

========================================================================
REACTIVITY DATA
========================================================================

Hazardous Combustion Or Decomposition Products: Thermally stable up to 300°C

========================================================================
HEALTH HAZARD DATA
========================================================================

Data not available

========================================================================
FIRST AID MEASURES
========================================================================

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If necessary

========================================================================
PREVENTATIVE MEASURES
========================================================================

Chemical safety goggles.

Keep container tightly closed.
Keep container in a well-ventilated place.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Place in appropriate container.

Wash spill site with soap solution.
Flush spill area with copious amounts of water.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0554

Material Safety Data Sheet

City University of Hong Kong

MSDS Aceto-Orcein 0554

========================================================================
PRODUCT INFORMATION
========================================================================

MSDS Name: Aceto-Orcein Solution

Synonyms: None
Ingredient:
Chemical Name CAS#
Acetic acid 64-19-7
Orcein 1400-62-0

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Physical State: Liquid

Appearance: violet
Odor: Vinegar-like odor.
pH: Acidic.

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Vapor Pressure: 11 mm Hg
Vapor Density: 2.07
Evaporation Rate: 0.97 (n-Butyl Acetate=1)
Viscosity: Not available.
Boiling Point: 108°C
Freezing/Melting Point: 0°C
Autoignition Temperature: 800°F ( 426.67°C)
Flash Point: Not applicable.
NFPA Rating: Not published.
Explosion Limits, Lower: 5.4, Upper: 16
Decomposition Temperature: Not available.
Solubility: Soluble in water.
Specific Gravity/Density: 1.025
Molecular Formula: Mixture
Molecular Weight: 0

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or
equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Reacts with most metals to form highly flammable hydrogen gas which can form
explosive mixtures with air.

Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.

========================================================================
REACTIVITY DATA
========================================================================

Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.

Conditions to Avoid: Incompatible materials, ignition sources, excess heat.

Incompatibilities with Other Materials:
Acetaldehyde;2-aminoethanol;ammonium nitrate; bromine pentafluoride; chlorine trifluoride; chlorosulfonic acid;
chromic acid; chromic anhydride+acetic anhydride; diallyl methyl carbinol+ozone; ethylene diamine; ethylamine;
hydrogen peroxide; nitric acid; nitric acid+acetone; oleum; perchloric acid; permanganates; phosphorus isocyanate;
phosphorus trichloride; potassium hydroxide; potassium-t-butoxide; sodium perioxide;xylene.

Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.

Hazardous Polymerization: Will not occur.

========================================================================
HEALTH HAZARD DATA
========================================================================

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0554
Danger! Causes digestive tract burns. Causes respiratory tract burns. May be harmful if absorbed through the skin.
Corrosive. Causes eye and skin burns.

Target Organs: None.

Potential Health Effects
Eye:
Causes eye burns. Contact with liquid or vapor causes severe burns and possible irreversible eye damage.

Skin:
Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to
this material. May be harmful if absorbed through the skin.

Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. Causes severe
pain, nausea, vomiting, diarrhea, and shock.

Inhalation: Effects may be delayed. Causes chemical burns to the respiratory tract.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated inhalation may cause chronic bronchitis.
Repeated exposure may cause erosion of teeth.

========================================================================
FIRST AID MEASURES
========================================================================

Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30
minutes).

Skin:
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.

Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by
mouth to an unconscious person. Get medical aid immediately.

Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen.
DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a
suitable mechanical device such as a bag and a mask.

Notes to Physician: Treat symptomatically and

Antidote: None reported.

========================================================================
PREVENTATIVE MEASURES

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
========================================================================

Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use
adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.

Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection
regulations in 29 CFR 1910.133 or European Standard EN166.

Skin: Wear appropriate protective gloves to prevent skin exposure.

Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator when necessary.

Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin,
or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes.

Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
Store in a suitable container in a dry area above the substance's freezing point.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Spills/Leaks:
Absorb spill with inert material, (e.g., Dry sand or earth), then place into a chemical waste container. Avoid runoff
into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Provide ventilation.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0563

Material Safety Data Sheet

City University of Hong Kong

MSDS ALBUSTIX 0563

========================================================================
PRODUCT INFORMATION
========================================================================

Part Number/Trade Name: Albustix

========================================================================
RISK SYMBOL
========================================================================

========================================================================
PHYSICAL DATA
========================================================================

Appearance And Odor: Small square paper pad fastened to plastic strip.
Solubility In Water: Not soluble
pH: N/A

========================================================================
FIRE AND EXPLOSION DATA
========================================================================

City University of Hong Kong 1

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
Flash Point: None
Lower Explosive Limit: N/A
Extinguishing Media: Use whatever is required for surrounding area.
Special Fire Fighting Proc: Use NIOSH approved SCBA & full protective equipment (fp n).
Unusual Fire And Expl Hazrds: None identified.

========================================================================
REACTIVITY DATA
========================================================================

Stability: Yes
Cond To Avoid (Stability):
This product is stable as sold if used as directed. There are no specific conditions to avoid.

Materials To Avoid: None specified by manufacturer.

Hazardous Decomp Products: None specified by manufacturer.
Hazardous Poly Occur: No
Conditions To Avoid (Poly): Not relevant

========================================================================
HEALTH HAZARD DATA
========================================================================

LD50-LC50 Mixture: None specified by manufacturer.

Route Of Entry - Inhalation: No
Route Of Entry - Skin: No
Route Of Entry - Ingestion: Yes
Health Haz Acute And Chronic:
This product is not considered to be a critical hazard to man or environment.
Acute: Inhalation, skin contact and eye contact: should not cause any health concerns.
Ingestion: If ingestion should occur patient may feel uncomfortable. Treat as indicated.
Chronic: No chronic effects of overexposure are currently known.

Carcinogenicity - NTP: No
Carcinogenicity - IARC: No
Carcinogenicity - OSHA: No
Explanation Carcinogenicity: Not relevant
Med Cond Aggravated By Exp: None specified by manufacturer.

========================================================================
FIRST AID MEASURES
========================================================================

Emergency/First Aid Proc:

Inhal: Remove to fresh air. Support breathing(give o*2/artf resp) (fp n). Eyes: Immediately flush w/potable water for a
minimum of 15 minutes, seek assistance from md (fp n).
Skin: Flush w/copious amounts of water. Call md (fp n).
Ingest: Have patient drink 2-8 oz glasses of water or milk to dilute & contact md for further care.

The above information is believed to be accurate to the best of our knowledge.

No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.
 M.S.D.S. 0563

========================================================================
PREVENTATIVE MEASURES
========================================================================

Respiratory Protection:
NIOSH approved respirator appropriate for exposure of concern (fp n). There is no respiratory protection required.

Ventilation: Use general room ventilation.

Protective Gloves: Impervious gloves (fp n).
Eye Protection: Ansi approved chem workers goggs (fp n).
Other Protective Equipment: Eye wash fountain & deluge shower which meet ANSI design criteria (fp n).
Work Hygienic Practices: None specified by manufacturer.
Suppl. Safety & Health Data: None specified by manufacturer.
Precautions-Handling/Storing: Store at temperature & conditions as indicated on product labels.
Other Precautions: See product label or package insert for instructions on handling strips during test use.

========================================================================
ENVIRONMENTAL PROTECTION DATA
========================================================================

Steps If Matl Released/Spill:

Sweep up or pick up & place in a disposable container. Ecological effects of product strips have not been
determined.

City University of Hong Kong 3

The above information is believed to be accurate to the best of our knowledge.
No responsibilities or liabilities are assumed or implied by CITY U for their inaccuracies.