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Ion Loss or Gain of Electrons Full Outer Shell: Formation of Ionic Bond How Ions Are Formed

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0% found this document useful (0 votes)
13 views

Ion Loss or Gain of Electrons Full Outer Shell: Formation of Ionic Bond How Ions Are Formed

Uploaded by

hanshika.k2010
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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FORMATION OF IONIC BOND

How Ions are formed

 An ion is an electrically charged atom or group of atoms formed by the loss or gain of
electrons
 This loss or gain of electrons takes place to obtain a full outer shell of electrons
 The electronic structure of ions of elements in Groups 1, 2, 6 and 7 will be the same as
that of a noble gas - such as helium, neon, and argon
 Negative ions are called anions and form when atoms gain electrons, meaning they have
more electrons than protons
 Positive ions are called cations and form when atoms lose electrons, meaning they have
more protons than electrons
 All metals lose electrons to other atoms to become positively charged ions
 All non-metals gain electrons from other atoms to become negatively charged ions

Formation of a cation

Formation of positively charged sodium ion


Formation of an Anion

Formation of negatively charged chloride ion

What is ionic bonding?

 Ionic compounds are formed when metal atoms react with non-metal atoms
 Metal atoms lose their outer electrons which the non-metal atoms gain to form positive
and negative ions
 The positive and negative ions are held together by strong electrostatic forces
of attraction between opposite charges
 This force of attraction is known as an ionic bond and they hold ionic compounds
together

Dot-and-cross diagrams

 Dot and cross diagrams are diagrams that show the arrangement of the outer-shell
electrons in an ionic or covalent compound or element
 The electrons are shown as dots and crosses
 In a dot and cross diagram:
o Only the outer electrons are shown
o The charge of the ion is spread evenly which is shown by using brackets
o The charge on each ion is written at the top right-hand corner
Formation of ionic bonding

 Sodium is a Group 1 metal so loses one outer electron to another atom to gain a full outer
shell of electrons
 A positive sodium ion with the charge 1+ is formed, Na+
 Chlorine is a Group 7 non-metal so gains one electron to have a full outer shell of
electrons
 A negative chloride ion with a charge of 1– is formed, Cl–
 The ions are then attracted to one another and held together by electrostatic forces
 The formula of the ionic compound is thus NaCl
 The large square brackets should encompass each atom and the charge should be in
superscript and on the right-hand side, outside the brackets

Diagram representing the format ion of the ionic bond in sodium chloride

Sodium loses one electron and chlorine gains an electron


Dot-and-cross diagram of sodium chloride

Lattice Structure:

The lattice is the symmetrical three-dimensional structural arrangements of atoms, ions or


molecules (constituent particle inside a crystalline solid as points

Properties of ionic compounds

 Ionic compounds are usually solid at room temperature


 They have high melting and boiling points
 Ionic compounds are good conductors of electricity in the molten state or in solution
 They are poor conductors in the solid state

Explaining the properties of ionic compounds

 Ionic compounds have high melting and boiling points


o They have giant structures
o There are strong electrostatic forces of attraction between oppositely charged ions
in all directions
o The forces need lots of energy to overcome them
 Ionic compounds are poor conductors in the solid state
o The ions are in fixed positions in the lattice
o They are therefore unable to move and carry a charge
 Ionic compounds are good conductors of electricity in the molten state or in solution
o When the ionic compound is melted or dissolved in water, the ions are able to
move and carry a charge
 The greater the charge on the ions, the stronger the electrostatic forces and the higher the
melting point will be
o For example, magnesium oxide consists of Mg 2+ and O2- so will have a higher
melting point than sodium chloride which contains the ions, Na + and Cl-

Diagram to show the electrical conductivity of ionic compounds

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