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Boiling is the process by which a substance changes from a liquid to a gas at the
different boiling temperature of the substances
The temperature at which a liquid is called its boiling point
What happens to the particles of a liquid that is heated until its boils
Heat energy is absorbed by the particles of the liquid , the heat energy is converted
into kinetic energy . the particles start to move faster as the temperature rises
When temperature is high enough energy to overcome the forces of attraction
holding them together
The particles are now spread fart apart thus the substance is now a gas . the
particles move about rapidly in any direction
Boiling Evaporation
Occurs only at boiling temperature Occurs at temperatures below boiling
point
Occurs throughout the liquid Occurs only at the surface of the liquid
Occurs rapidly Occurs slowly
Fractional distillation
Is used to separate a mixture of miscible liquids with different boiling points
Fractionating column is attached to the round bottom flask and condenser
Many beads are placed in the fractionating column provided a large surface area for
vapour to condense on
The liquid with the lowest boiling point will distil first
Vapour rises up the column as the solution is heated
The higher boiling point vapour condenses on the fractionating column and falls back
into the flask
The lower boiling point distils over first
The thermometer will show a constant temperature of the vapour
In the condenser , the vapour cools and condenses , the liquid flows down inside the
condenser and into the receiver
The liquid is than collected as the distillate in the receiver
When 1 has been distilled over , the temperature rises to the next vapours
temperature and the water distils will be collected separately
Chromatography
.is the method of separating two or more components that dissolve in the same
solvent
Used to separate the components in a sample , identify the components present
Identify substances
Determine if the sample is pure
Mixture Compound
Separation Can be separated by physical Can be broken down into its
properties elements or simpler
compounds by chemical
process
Properties Chemical properties are the same Physical and chemical
as its components properties are different from its
elements
Energy change No chemical reaction A chemical reaction takes place
Composition Can be mixed in any ratio Combined in a fixed ratio
Chp 5 – atoms
Protons
Has a relative charge of +1
Has a relative mass of 1
Tightly packed in the centre of an atom to form the nucleus
Neutron
Has a relative charge of 0
Has a relative mass of 1
Tightly packed in the centre of an atom to form the nucleus
Electron
Has a relative charge of -1
Has a relative mass of 1/1840
Moves rapidly around the nucleus
The number of electrons is the same as the number of protons , thus the negative
charges cancel out the positive charge leading the atom to be electrically neutral
The proton number is also called the atomic number
From the proton number the no of electrons can be determined
The nucleon no of an atom is the total number of protons and neutrons in the atom
Mass no = nucleon no
When representing , nucleon no on top left and the proton no left bottom and the
symbol on the right
Isotopes
Isotopes are atoms of the same element with the same number of protons and
electrons but with different number of neutrons
Ionic compound are soluble in water , as water weakens the forces of attraction
between the ions . as a result , the ions are pulled from the lattice structure and the
compound dissolves to form an aqueous solution
Insoluble in water there is no water present leading the ionic compounds to remain
tightly held in the lattice structure
Ionic compound conduct electricity when molten or in aqueous solution
When an ionic compound is molten or dissolved in water it can conduct electricity as
the free-moving ions or electrons in order to conduct electricity , when the ions are
molten or dissolved the cations and anions are free to move and are available to
conduct electricity
Ionic compounds do not conduct electricity in the solid state as there are no-free
moving ions to conduct electricity in the solid state since the ions are held in place in
the lattice structure
Types of oxide
Acidic oxides
1. Non-metal
2. Most acidic oxides dissolve in water to form acidic
3. Acidic oxides do not react with acids . however , they react with alkalis to
form a salt and water
Basic oxides
1. Metal
2. Most basic oxides are insoluble in water
3. A few oxides such as sodium oxide dissolve readily in water to form alkalis
4. Basic oxide are solid at room temperature , react with acids to form a salt and
water
Amphoteric oxide
1. Metallic oxide that reacts with both acids and bases to form salts and water
2. Zinc and example behaves as a basic oxide and acidic oxide as salt and water
are formed
Neutral oxide
1. Some non-metals form oxides that show neither basic nor acidic
properties and they are insoluble in water
2. Examples are water , carbon monoxide and nitric oxide
Chp 10 – salts
10.1
Salts contain ionic compounds – containing cation and anion
Salts can be made by reacting acids with metals , carbonates , bases or alkalis
Reactants Products
Acids + metal Salt + hydrogen
Acid + carbonate Salt + water + carbon dioxide
Acid + base / alkali (neutralisation) Salt + water
During the reaction, one or more hydrogen ions of acids is replaced by a metal ion or
an ammonium ion
Water of crystallisation
Salts containing water of crystallisation are hydrated salts
When hydrated salts are heated, the water of crystallisation is given out
Salts that do not contain water of crystallisation are anhydrous salts
Name of salt Formula for anhydrous salt Formula for hydrous salts
Copper (ll) sulfate
Magnesium sulfate
Sodium carbonate
Zinc sulfate
Method 2 – titration
- All starting materials used are soluble ( the volume of each starting materials
must be exact as the excess cannot be removed from the salt solution by
filtration and the salt produced will be impure )
- To determine exact volumes of reactants use titration
- Titration is using a burette by rinsing it with water and alkali (sodium hydroxide) .
Than using a pipette measure the volume of acid using a suction . Put the
measured acid into a conical flask adding 2 drops of methyl orange and placed a
white tile under the flask. Using a retort stand put a burette filled with sodium
hydroxide. slowly drip alkali into the conical flask with acid slowly swirl until its
orange ( neutralisation has occurred )
- Involves mixing 2 solutions to form an insoluble solid that separates out from
the reaction mixture
- To produce the insoluble salt , mix solution containing the cation of the salt with
solution containing the anion of the salt
- Preparing barium chloride n magnesium sulphate
1. Pour barium nitrate solution into a beaker , add solution sulphate solution in
excess and stir until no more precipitation forms
2. Filter to collect the precipitate as residue
3. Wash the precipitate with a little distilled water to remove soluble
impurities
4. Allow the precipitate to dry on a piece of filter paper
Identifying gases
Chp 11 – metals
1. metals are characterised by normally being shiny , strong solids with high melting
points , which are goods conductors of heat and electricity
2. metals have high densities , melting points and boiling points as the atoms are
packed tightly in layers and held together by strong metallic bonds requiring a large amount
of energy is required to break these bonds
3. metals are malleable and ductile because their atoms are of the same size and are
closely packed in neat layers . when a force is applied , the layer slide easily over one
another
Alloys
Potassium Please
Sodium Send
Calcium Camels
Magnesium Monkeys
Zinc Zebra
Iron In
Lead Large
Hydrogen Heavy
Copper Crates
Silver Soon
Reactions of metals with cold water
Sodium Reacts violently hydrogen gas may catch fire and explode
Zinc Reacts readily when hot its yellow and when its cold its white
Conclusion
Extracting metals
The methods
1. Heating the compound/ore with carbon
2. Electrolysis – using electricity to decompose the molten metals
compound/ore to the metal
rusting
Recycling metals
1. physical properties
- non-metals that exist diatomic covalent molecules
- low melting point n boiling point
- they r coloured
2. physical properties of halogens going down
- melting points n boiling points increases
- colours become darker
3. chemical properties
- halogens r reactive non-metals
- halogens react w most metals to form salts halides
- halogens undergo displacement reactions w halide solutions
4. reactivity order
- decreases down the group because the size of the tom
increases down the group making it more difficult for the
nucleus to attract one more electron
group 0 elements – noble gases
1. properties of noble gases
- no-metals
- monatomic
- colourless gases room temperature
- low melting n boiling points
- insoluble water
2. why r noble gases unreactive
- they either have 2 or 8 valence electrons . their full structure
makes them unreactive , they don’t lose , gin or share
electron
chp 13 air
composition of air
1. oxides of nitrogen
– found in engines or chemical factories where temperature r high n
nitrogen n oxygen combine
- during thunderstorms , het energy released by lightning causes
nitrogen n oxygen in the air to react to form oxides like nitrogen
monoxide n nitrogen dioxide
- methane is produced when plant n animal decay , sheep n cow give off
methane due to the digestion of food , from the decay of rubbish in landfills
- ozone is formed when nitrogen dioxide in the air reacts with unburnt
hydrocarbons in the presence of sunlight
acid rain
1. form when acidic air pollutants ( sulfur dioxide n nitrogen dioxide ) react with water
in the atmosphere
2. the Ph. Value of unpolluted water is slightly below 7 due to carbon dioxide in the ir
dissolving in rainwater to form carbonic acid which is weak acid
3. acid rain ph. value of less than 4
what r the effects of acid rain on buildings , plant n aquatic life
- sulfur dioxide n oxide of nitrogen r released into the atmosphere n react w water to
form acid rain
- acid rain reacts with metals n carbonates n damage them
- leeches nutrients from soil n cause plants to wither n die n the PH value is to acidic
n will kill is fish
all organic compounds contain the element carbon n most contain hydrogen
Only hydrogen n carbon r called hydrocarbons
Organic compounds contain other elements such as oxygen , chlorine n nitrogen
Homologous series is a family of organic compounds with same functional group n
similar chemical properties
Functional group is an atom or group of atom that gives a molecule its
characteristics properties
Alkanes – do not have functional group , there r only C-C n C-H bonds
Alkenes – C=C , carbon-carbon double bond
General characteristics of homologous series
Organic compounds in the same homologous series have the following characteristics