· methanol: -

NrEsrioans
Tr
Tn 35765.58
· =
=

Traz=
Fat <3=
·
0.7129

in

AH RTn
en(Pc)
10013)
=
-

8. 93 -

Tru

18.3141 (337.61
=

x 10092 (en (80.97) -

100 13)

0.93 -
8.6586
38183.9
=

fol
DAH @AHsat ③ AH

prase:
ANa
368
Tfrom 380-368
38 - 585

Ersatj038138183.91 Toad
4Hufr
*
stsat =
0.38

F
- 35513.48

ax=faepLdT RSTAtBTCTY.ATRCACTuTIECTITY EG-TRT]

· =

2for liquid: -

*
=
13.431, B =- 51,28x153, c=131013 x 106

[(13.4317 (368-300) 28x1833368"300T] *NO268-30031)

1H.
: =
c8.314) -

32080galf
=

sx=faepLdT RSEAtBTCTY.dT=RCACTurTIECTITY EG-TRT]

· =

2 for
vaper:
-

A
=
2.211, B = 12.216 x 183, C=-3.45x 106

SH2=18314)
(2.211 (500
+XI5 550023682) 3x10 2500-300
·
-

368) -

=752601956 5/mpl

Dtotal AH, tAHsat + DHz=35573.48 +

·

6208.891 49248.5666
+ 7526, 1956 =
Iol

g-D1=10010101mploazus.5666 fofoutrosoxooesre
·

=
1368 K5]s
-
1368 KW
 T=300K, P=3bar
potio
↑= GF??
Tz = 500K

jsat = 338.0K

AH, *H 2

TI368
T= 300K T

-> = 500K
AI'
lia -> gas

atconstant => 1H
pressure =
&

*
TH =
JCpdT=OABT +CTIDTAT Cliquid

30 G

R
=

[AF2-Ti) B (T2" -Ti

+ +
2 (E23-T) -3
(t#]
c8.314)
-

[13.431 (368-300) x56

+
5228x18" (3682-3004 +113328-308
-

6208.895/mol

*
Swap =

Srap)
838, 3An=Rin(1092Cencsd,TI

Eeouat bar, TruapFra3fOS:o

e

AHrap=183141
(337aifood-as)]fE36565.525 ol

=> DHy=JCpdT=OPABT+CTIDTAT g
368

= R [A2-Ti) B (T2" -Ti

+ +
3 (E23-T) - 3
(#1]

[2.211 (3500
c8.314)
=

-
368) +
4x187500?3689 +x56(5003-3389] = 1526.
Fo

:. DHE= DH + trap tHH= 6208.89 +36565.525+7526.

19=50388.605
M s(

g=ADH
1x10bmx,50300.605 =1397x1065Is= SW
=
 S
questione
2
#

DHan =
5A4f products -

244 +
reactants

aBtIwis
= -

ESSC-BYC
=2[=us000] = -

922205

DHan =
5A4f products -

244 +
reactants

5(xH+)
=

ep+ heCsHfINg -SCATM-4CDHfINHs

sT-241818] (90250]
4
41-16110)
·
+ -

=
-
455468 F

*
DHan =
E44f products -

244 f
reactants

2(DHf)
AHf-AHf-3AHfo
=
+
ANos

a -1741007 +
[90250) [-2853227
=

- -

3/331807
= -
71660 J

DHan =
5A4f products -

244 +
reactants

AHz
AH--AHf-Altacn
=

+
C2Hz

[2274807
=
+
[-635040] -
[,285830) -

1-548007
61980 J
=

DHan =
5A4f products -

244 +
reactants

2 [9H+]
4Hf-2Hf Ronan-2CDHfINa
=

Nash

=
29-425609) +0 -2(-2418187 -
210)

= -
367582 J

DHan =
5A4f products -

244 +
reactants

7 (DH + (DHf120
N 515HfNow
-

+ 12 8Cx4
f1NH
-
-

7(0)
=
+ 12) 241818)
-
-
57-16110) -
6,33180)
= -

2732016 5
DHan =
5A4f products -

244 +
reactants

Htel 18 14fo-AHfc2Hn
=

= -

32630 -=10) - 32510

=
-
15 5 145 J

DHan =
5A4f products -

244 +
reactants

BHfCHeLzCo AHfIng -DH-C2Hn

=
-

-
= 52638 -1241818) -
(227480)

=
38292 5
-

DHan =
5A4f products -

244 +
reactants

18Hf
-

2 +AHfp-2AHe. -AHfH e

4101
= + -

393509-27241818) -
(74520)

=
164647 5

DHan =
5A4f products -

244 +
reactants

BATHur
tAHtaOH
=

EDHTH -$Hton

=
1241818] 7,200665)-3101 -
F-393509)

=-
489695

DHan =
5A4f products -

244 +
reactants

sHfMustbH-cIO-tAIfo,
=

IPHfcbt
-
H

[2418187 (1085707 2187 52806607

=

+ - -

=
149728 I

DHan =
5A4f products -

244 +
reactants

2AHf +2AHff -3AHfo-zDHfh

=

29-2968307
=
+
2[-241818] -
310) - 2620630)

=-1836036 5
 DHan =
5A4f products -

244 +
reactants

NAE. +34Hf-2AHfy
=

-AH
S
F2988307
= + 3C01 -

25-2418187 -
[-20630)
=
287436 5

DHan =
5A4f products -

244 +
reactants

20H
f-bHf-AHfr
=

2
-

[90250]-0-0

180500 J
=

DHan =
5A4f products -

244 +
reactants

AHfcon+AHfcap-bitfcaco
=

9393509)
=

+
(.5350907 -

7-1206928]
178321 5
=>

DHan =
5A4f products -

244 +
reactants

sHf2SOn TAAf>
=

TAAfgOz

(313989)
=

-
(2858307 -

7395220)

-
=

1324395

DHan =
5A4f products -

244 +
reactants

=
AHf
AHfHe8 -AH-C2Hm
-

&Hs OH
=
7277590) -

[2858307 -
[S2510)

-
=

44370 J

DHan =
5A4f products -

244 +
reactants

AHfCHOH
=

-AHf AHECHICHO
-

[235180]-0-5-1661907
=

=
-
68910 5
DHan =
5A4f products -

244 +
reactants

AH+
=

+ 4H
H20
fCHy 2004 -

DHfo -3He
C2H 58 H

=
F2858307 + (-4845557-8-7-277690D
= -

492640 J

DHan =
5A4f products -

244 +
reactants

AlfH2 AHf
=
+ -

AHE
CHICH CH CH2 CH5 <H CH2

=>
o [104240]
+
-

540] =
109780

DHan =
5A4f products -

244 +
reactants

24Hf AH-
->

-AHuHic
+
4.
CHICHCHCH2

2COL
=
+
[1092407-51257907
=
235038 J

DHan =
5A4f products -

244 +
reactants

BiffHzg
=>
+ AHf
C2CHCHCH2
-[Alfo, -AHfc2HzCHCH2

= -
241818 +109240-. - - 548

= -
1,32038 5

DHan =
5A4f products -

244 +
reactants

5AHfn +6DHE-SAHfNy -4AHfw

=

5(0)
67-241818)
=

61902507
+

47461107
-
-

=
-

1807968 5

DHan =
5A4f products -

244 +
reactants

=
2AHf
BH++c2H2 -DHfN2
-

HCN

2(135100)
=

-
227480 -
8

42,720 5
=
DHan =
5A4f products -

244 +
reactants

AIf,t+DHfIgHjCH: CH -
=

AHfIgH5CeHt
O
->
+ 147360+-2942 D

117245 J
=

DHan =
5A4f products -

244 +
reactants

Biff +
AHf-AHfco -Alfa
=

go

110325 +8-F-285830]
= -
-
8

= 175305 5
 CHu +282 -> CO2 +2H20

·
what enters??

CHu = 1. =
1 m81

88 Ne = 2 x 103 =
2.6mol

Nz: 2.6
E9
ns =
x = 9078lud

En=13.381 mol

Prap: -

130°

at 30%, Prop=4.247 kPa

·
un=4 x 13.381 = 0.588
1810625-4.27)

·
that leaves??

CO2 :
Ims/

H20:2 + 0.588 = 2.588md/

O 2: 2.6 -
0.6 = 0.6m8/

N2 = 9.781 mol

d= 6H
AHeag DHp
·
= +

·
AH2ag=xH+co,FeDHEAug -

23Af-bHfcHu
-393509-24-2418187-8-7-745207 =-802625E
=>

new I

next
page ->
DHy a CO2 +9728
+2
->

2 mol8z + 8.6mc182 =2.6ms102

I mol BHu

: 9.78 mol N2.

= furnace
 &
AHP
-
↓
① C82 &H2G 82 ④ N2
⑤
R 8 S 9. 78 1
I 2.588

A 5.457 3.27 3. 639 3.28

B 10045x18- 1.45x153 D. 506x18

3
8 593x10-3

D -
1157x105 8 121x185 -
5.222x105 -
0.02 x 105

A:
GriAi =
nA,+.. . . .

MuAu

=
1(5.757) 2.588(3.47)
+

+ 0.5 (3.039) + 9.781(3.28) =

48.70244

B=GuiBi =
n, B,+..- + ruBy
1D025x153)
- + 2.588 (1.45x183) +
0.6 (0.50 6x183) + 9.781 (0.593x103)
10.90133x153
=

D =

GriDi=n,D,x.. +UyPu
17-1857x185) +
=

20588) 5.121 x 108) +0.370.227x185) + 9.781770.02 x105)

= -
0.5888x105

3Ap =

gTECsaT = R
CIABTDTT =
RLACTITI +

BCRTH-[E1]
[ch8.70znu)(17-3.15-353.157+ (12.90133x53) [72315383.154
est]
00314

(fi
=

05888NA

=
732196.3 I
o

:D=xtzag +
1Hp =-802625 +732196.3=-70428.7
5/md

x 101.3
18
port
·
partial pressure of Hr0 = = 18.77 kPa

2.588 + 0.6 +9.

7 81 + 1

I
·
Ambles of the
gases= 4thyt44=9.781 + 8.6 + 1 = 11.381 moles

Prop at 50° =12.341Pa

·: moles of
water
leavingthe heat exchanger-

mc=3
-1234 411369 = 1.5765

therefore the modes of water condense:

2.588- 1.57B5 =
1.0115 moles

Latent
·

heat at 50C

#H50 =
(2382.9) [18.015] =
42927.9 I
mos

is
se o ↓
48.7024
y
10.9013 x

&
hesi
MCAGEG8
a :

T2 =323.15K 43271.57 I
T. =
1773.15K

P =-723630-13421.57=-767051.54
:

E
&BS

2H2cg
->
"H
DT Orc9L
+
2C12cg(

*
AHran=
2Atta -

Enteactants

21-2418187-4(92307)
-
= = 1144 x1055

To = 298K

= 823K

- ↓
#2.A Oz
D2 H <I

I
2 1)-I 4) (m)
M

3.4 7 4. 442 3. 639 3.156

A

B 1.15 x 10- 8.089 x10' 0.506x10' 0.623x103

D 8. 121 x 105 8 344x105 -

0.227x105 0.151x105

*
=
EniAi=

&
Reactants:
SAini 4(3.156) 1(3.639)
=
-
+ =
16.263
[A+BT+CT"+DT" I reactants

SBini=4(8.323x153) + 1(0.503x154) =
2.998x10-
reactants

H =
S<Cp3dT=
RAELABTTCT"+DT"dT & Dini= 4(8.15 105, x
+ 7-0.227x185) = 37 700

RCACT2-T3 +E [im"T] eT1 +*]

=

18.314)
(16.263(298.15-823.15) [8x18)[298.15'-823.152)
=

Tz wt)
+ 3770

= -
78992. 617 J

*
Products:

*H =
S<Cp3dT=
RAELABT+CT"+DT"dT &
Ani = 2(4.442) +2(3.47) =
15.82

& Du5x15
Bini=228.08ax153)
I +2

=
RCACT2-T +E [in"+] e4ig3-T1 4] + 3.078x10
=

& Dini=-25.342x1853 +2(0121x105)

= 9388 8

18.31
(15.824) (823.15-298) 38x8 9823.15" -2981517
rist)
=

ausofes.5
x
-

=
75858.5 J

&=
D1f+DHp +$Hrxn=-78992.617 + 75808.5- D14MX185)

-112584,
=
117 F

·@Pmol
4x0-45=-117584 17x025=-13228028 M
=