60-Numerical Problems -Chemistry PRINTOUT
60-Numerical Problems -Chemistry PRINTOUT
4. If the density of some lake water is 1.25 g mL−1 and contains 92 g of Na+ ions per kg of water, calculate the
molarity of Na+ ions in the lake.
5. Calculate the freezing point of a solution containing 60g of Glucose (Molar Mass =180 g Mol−1) In 250 g of
water.
6. Calculate the freezing point of a solution containing 60 g of glucose (Molar mass = 180 g mol-1) in 250 g of
water. (Kf of water = 1.86 K kg mol-1)
7. Calculate the mass of compound (molar mass = 256 g mol-1) to be dissolved in 75 g of benzene to lower its
freezing point by 0.48 K(Kf= 5.12 K kg mol-1.
8. 18 g of glucose, C6H12O6, is dissolved in 1 kg of water in a saucepan.At what temperature will water boil
at 1.013 bar?
Kb for water is 0.52 K kg mol−1
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11. The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the
composition of the liquid mixture if total vapour pressure is 600 mm Hg. Also find the composition of the vapour
phase.
12. A 0.01 m aqueous solution of AlCl3 freezes at −0.068C. Calculate the percentage of dissociation. [Given :
Kf for Water =1.86 K kg mol−1
13. The freezing point of a solution containing of benzoic acid in of benzene is
depressed by . What is the percentage association of benzoic acid if it forms a dimer in solution ?
( for benzene )
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19. What mass of NaCl (molar mass = 58.5 g mol–1) must be dissolved in 65 g of water to lower the freezing point
by 7.5°C? The freezing point depression constant, Kf , for water is 1.86 K kg mol–1. Assume van’t Hoff factor
for NaCl is 1.87.
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