SIIT SAPRK REVISION CHEMISTRY

SIIT SPARK REVISION CHEMISTRY ASSIGNMENT

TOPIC: NOMENCLATURE
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O O

1. The IUPAC name for CH3 C CH2 CH2 C OH is ________.

1) 1-hydroxypentane-1, 4-dione 2) 4-oxopentanecarboxylic acid
3) 1-carboxybutan-3-one 4) 4-oxopentanoic acid
OCH 3
NO 2

2. The IUPAC name for

Cl

1) 1-Chloro-4-nitro-3-methoxybenzene
2) 1-Chloro-3-methoxy-4-nitrobenzene
3) 4-Chloro-2-methoxy-1-nitrobenzene
4) 1-Methoxy-2-nitro-5-chlorobenzene

3. The correct IUPAC name of the following alkane is

H3C CH2 CH CH2 CH2 CH CH2 CH3
CH CH2
CH3 CH3 CH3
1) 3,6–Diethyl–2–methyloctane 2)5–Isopropyl–3–ethyloctane
3) 3–Ethyl–6–isopropyloctane 4) 3–Isopropyl–6–ethyloctane

4. Which among the following molecular formula may contain two rings
and one double bond?
1) C3H6N2 2) C 4H6S2 3) C6H8Br2 4) C5H5Br

5. How many of the following compounds has 1, 2 and 3 hydrogen

atoms?
C2H 5 CH3 H3 C CH3

CH3
1)5 2) 2 3)3 4) 4

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6. Maximum number of carbon atoms present in the same plane in

CH3  CH  CH  C  CH
1) 9 2)4 3) 5 4) 3

7. The IUPAC name of the following compound is

N

1) N-Butyl-N-ethylpropanamine 2) N-ethyl-N-propylbutanamine
3) N-Butylhexanamine 4) N-propyl-N-ethylbutanamine

8. The IUPAC name of the following compound is

O
H3C CH2 CH C O CH3
C2H5
1) 2-Ethylmethylbutanoate 2) Methoxy-2-ethylbutanoate
3) Methyl-2-ethylbutanoate 4) 2-Ethyl-1-methoxybutanone

9. The IUPAC name of the following compound is

O
H3 C CH2 C
O
H3C CH2 CH2 C
O
1) Ethanoicpropanoicanhydride 2) Propanoicethanoicanhydride
3) Propanoicbutanoicanhydride 4) Butanoicpropanoicanhydride

10. The IUPAC name of the following compound is

HC CH2
H3C CH2 CH2 CH C CH
1) 3-Vinylhex-1-yne 2) 3-Ethylhex-1-ene
3) 3-Propylpent-4-yne-1-ene 4) 3-Propylpent-1-en-4-yne

11. The IUPAC name of this compound is

Cl OH
H3C CH2 C CH2 C CH3
H2C CH2 Br
1) 6-Bromo-4-chloro-2-hydroxyhexane
2) 6-Bromo-4-chloro-4-ethylhexan-2-ol

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3) 4-Chloro-4-bromoethylhexan-2-ol
4) 1-Bromo-3-chloro-3-ethylhexan-5-ol

12. 2-Methylhepta-1,6-diene is
1) CH2  CH  CH3  CH2  CH  CH2 2) H2C CH CH(CH2)2CH CH2
CH3
3)H2C C (CH 2)3CH2 CH3 4) H3C C (CH2)3CH CH2
CH3 CH2

CCl3 CCl3

13. The IUPAC name of

CCl3
1) 1,1,1-trichloro-2-ethyl-4,5-bis(trichloromethyl)octane
2) 3,4,5-tris(trichloromethyl)octane
3) 4,5,6-tris(trichloromethyl)octane
4) 7,7,7-trichloro-6-ethyl-4,5-bis(trichloromethyl)octane

COOH

14. The IUPAC name of

O
1) 5-ketobicycle[4.3.0] nonanecarboxylicacid
2) 6-ketobicyclo [4.3.0]nonane-2-carboxylicacid
3) 2-ketobicyclo [4.3.0] nonanoicacid
4) 2-ketobicyclo [4.3.0] nonane-7-carboxylicacid

CONH2

15. The IUPAC name of

COOCH3
1) 4-Methoxycarbonylcyclohexanamide
2) Methyl-4-carbamoylcyclohexanoate
3) 4-Methyl-carbanylcyclohexanamide
4) Methyl-4-carbamoylcyclohexanecarboxylate

16. The number of hybrid orbitals and pure orbitals are involved in bond
formation of CH2  C  C  CH3 respectively
1) 6 and 12 2) 12 and 10 3) 10 and 10 4) 12 and 6
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CN

17. Degree of unsaturation in given compound is

1) 5 2) 6 3) 7 4) 4

18. Which of the following compounds contains same set of hybridized

atoms?
1) H2 C CH C CH 2)
NO
O
C H

3) H2C C C CH2 4)

19. Among the following compound, which has non-zero dipole moment?
NO 2

Cl H Cl Cl
1) 2) C C 3) 4) C C
H Cl NO 2 H H

20. The number of different functional groups present in a given compound

O
O C H

OH
NH2

COOH NH2
1) 6 2) 4 3) 5 4) 7

Br
21. The IUPAC name of

Cl
1) 1-bromo-3-chlorocyclohex-2-ene
2) 2-bromo-6-chlorocyclohex-1-ene

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3) 3-bromo-1-chlorocyclohex-1-ene
4) 1-bromo-6-chlorocylcohexene

22. The IUPAC name of

HOOC COOH

COOH
1) Propane-1,2,3-tricarboxylicacid
2) butane-1, 2, 3-tricarboxylicacid
3) 3-carboxyethylpentanedioicacid
4) 3-carboxymethylhexanedioicacid

O
O C

23. The IUPAC name of

1) Cyclohexylbenzoate 2) Cyclohexylbenzenecarboxylate
3) Cyclohexylphenylmethanoate 4) Phenylcyclohexanecarboxylate

24. Which of the following is correct

CH3
1) Vinyl P) H3 C CH CH2
2) Allyl Q) CH2  CH  CH2 
3) Secondary butyl R) CH3  CH2  C H  CH3
|

4) Isobutyl S) CH2  CH 
1) 1-P;2-Q;3-R;4-S 2) 1-S;2-Q;3-R;4-P
3) 1-S;2-R;3-Q;4-P 4) 1-Q;2-S;3-R;4-P

25. The IUPAC name of the following compound

1) 3-cyclopentylpentane 2) 1-pentylcyclopentane
3) 1-cyclopentyl-1-ethylpropane 4) (1-ethylpropyl) cyclopentane

26. The total number of homocyclic structural isomers possible for the
formula C4H9N
1) 3 2) 4 3) 2 4) 5

27. Which of the following set does not represent functional isomers?
COOCH 3
1) 2) COOH

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O OH
OH O
3) 4)

28. The IUPAC name of

1) 3-Vinyloct-1-en-7-yne
2) 3-Vinyloct-7-yne-1-ene
3) 3(penta-4-yne-1-yl) penta-1, 3-diene
4) 3(pent-1-yne-5yl) penta-1,3-diene
29. Which of the following set is not represent positional isomerism
1) CH3CH2CH  CH3  CH2CH3 CH3CH2CH2CH  CH3  CH3
O CH3
O
2) CH3
NH2

3)
NH2
O

4) H H
O

30. Which is the correct IUPAC names of the following compound?

HC(CH 3 )2
H3 C CH2 CH2 CH CH CH2 CH2 CH2 CH2 CH3
H3 C CH CH2 CH3
1) 5-Butyl-4-isopropyldecane
2) 5-Ethyl-4-propyldecane
3) 5-sec-Butyl-4-isopropyldecane
4) 5(1-methylpropyl)-4(1-methylethyl)decane

1) 4 2) 3 3) 1 4) 4 5) 3 6) 3 7) 2 8) 3 9) 4 10) 4
11) 2 12) 4 13) 2 14) 4 15) 4 16) 3 17) 3 18) 4 19) 4 20) 2
21) 3 22) 4 23) 4 24) 2 25) 4 26) 4 27) 4 28) 1 29) 4 30) 3

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