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ADE-2

ADE-2

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Mr. RAVI KUMAR I
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12 views

ADE-2

ADE-2

Uploaded by

Mr. RAVI KUMAR I
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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The absence of electrons in covalent bond is represented by a small circle usually referred to as

hole which is of positive charge. Even a hole serves as carrier of electricity in a manner similar to that
of free electron.

The mechanism by which a hole contributes to conductivity is explained as follows:

When a bond is in complete so that a hole exists, it is relatively easy for a valance electron in
the neighboring atom to leave its covalent bond to fill this hole. An electron moving from a bond to fill
a hole moves in a direction opposite to that of the electron. This hole, in its new position may now be
filled by an electron from another covalent bond and the hole will correspondingly move one more
step in the direction opposite to the motion of electron. Here we have a mechanism for conduction of
electricity which does not involve free electrons. This phenomenon is illustrated in fig1.3

Electron movement

Hole movement

Fig. 1.3a

Fig. 1.3b Fig. 1.3c


Fig 1.3a show that there is a hole at ion 6.Imagine that an electron from ion 5 moves into the
hole at ion 6 so that the configuration of 1.3b results. If we compare both fig1.3a &fig 1.3b, it appears
as if the hole has moved towards the left from ion6 to ion 5. Further if we compare fig 1.3b and fig
1.3c, the hole moves from ion5 to ion 4. This discussion indicates the motion of hole is in a direction
opposite to that of motion of electron. Hence we consider holes as physical entities whose movement
constitutes flow of current.

In a pure semiconductor, the number of holes is equal to the number of free electrons.

1.0.2 EXTRINSIC SEMICONDUCTOR

Intrinsic semiconductor has very limited applications as they conduct very small amounts of
current at room temperature. The current conduction capability of intrinsic semiconductor can be
increased significantly by adding a small amounts impurity to the intrinsic semiconductor. By adding
impurities it becomes impure or extrinsic semiconductor. This process of adding impurities is called as
doping. The amount of impurity added is 1 part in 106 atoms.

N type semiconductor: If the added impurity is a pentavalent atom then the resultant semiconductor
is called N-type semiconductor. Examples of pentavalent impurities are Phosphorus, Arsenic, Bismuth,
Antimony etc.

A pentavalent impurity has five valance electrons. Fig 1.4a shows the crystal structure of N-type
semiconductor material where four out of five valance electrons of the impurity atom(antimony) forms
covalent bond with the four intrinsic semiconductor atoms. The fifth electron is loosely bound to the
impurity atom. This loosely bound electron can be easily

Fifth valance electron of SB

CB
Ec
Ed
B
Donor energy level B
Ev
B VB

Fig. 1.4a crystal structure of N type SC Fig. 1.4bEnergy band diagram of N type
SC
Excited from the valance band to the conduction band by the application of electric field or increasing
the thermal energy. The energy required to detach the fifth electron form the impurity atom is very
small of the order of 0.01ev for Ge and 0.05 eV for Si.

The effect of doping creates a discrete energy level called donor energy level in the forbidden band
gap with energy level Ed slightly less than the conduction band (fig 1.4b). The difference between the
energy levels of the conducting band and the donor energy level is the energy required to free the fifth
valance electron (0.01 eV for Ge and 0.05 eV for Si). At room temperature almost all the fifth electrons
from the donor impurity atom are raised to conduction band and hence the number of electrons in the
conduction band increases significantly. Thus every antimony atom contributes to one conduction
electron without creating a hole.

In the N-type sc the no. of electrons increases and the no. of holes decreases compared to those
available in an intrinsic sc. The reason for decrease in the no. of holes is that the larger no. of electrons
present increases the recombination of electrons with holes. Thus current in N type sc is dominated by
electrons which are referred to as majority carriers. Holes are the minority carriers in N type sc

P type semiconductor: If the added impurity is a trivalent atom then the resultant semiconductor is
called P-type semiconductor. Examples of trivalent impurities are Boron, Gallium , indium etc.

The crystal structure of p type sc is shown in the fig1.5a. The three valance electrons of the
impurity (boon) forms three covalent bonds with the neighboring atoms and a vacancy exists in the
fourth bond giving rise to the holes. The hole is ready to accept an electron from the neighboring
atoms. Each trivalent atom contributes to one hole generation and thus introduces a large no. of holes
in the valance band. At the same time the no. electrons are decreased compared to those available in
intrinsic sc because of increased recombination due to creation of additional holes.

hole

Fig. 1.5a crystal structure of P type sc

Thus in P type sc , holes are majority carriers and electrons are minority carriers. Since each
trivalent impurity atoms are capable accepting an electron, these are called as acceptor atoms. The
following fig 1.5b shows the pictorial representation of P type sc

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