Answering Solubility Lab Questions
Answering Solubility Lab Questions
Note the following: The lines on the solubility curve indicate a saturated solution - a solution
that has the maximum amount of solute dissolved in 100 g of water.
Any amount below the line for a particular substance shows an unsaturated solution, and
anything above the line shows a supersaturated solution.
Answers:
1. 50g
2. NaCl (less mass is dissolved at 10oC)
3. Supersaturated (located over the line)
4. NH3
LAB QUESTIONS:
1. At what temperature does a saturated solution containing 10 g of potassium nitrate first form crystals as it is cooled at 35oC. -
2. Solubility at 90C
3. Minimum mass of water required to dissolve 30g KNO3 at 60.
4. Mass of KNO3 that must be added to resaturate a solution containing 200g of water.
5. Predict the solubility of potassium nitrate at 100oC and at room temperature.
6. Calculate the mass of crystals which fall out of a saturated solution of potassium nitrate in 100 g of water when it is cooled from 60°C to 40°C.
The graph typically shows the solubility trend increasing with temperature.
STEPS:
1. At what temperature does a saturated solution containing 50 g of potassium nitrate first form crystals as it is cooled at 35°C?
- Find the solubility of KNO₃ at 35°C from the solubility graph. To do this, find 10g on the y-axis of the graph (which represents the solubility in 50g of KNO₃ per 100g of
water).
- Move horizontally with dashed lines, until you intersect the solubility curve, then drop down to the x-axis to find the corresponding temperature. This is the temperature at
which crystals will first start to form.
Solubility
- Find the solubility(y axis) of KNO₃ at 38°C (x axis)from the graph. Put this value in the equation.
- Mass of solute(potassium nitrate ) given is 30g. Put this value in the equation.
- Solve for the mass of water. eg:
Solubility at 38oC
4. Predict the solubility of potassium nitrate at 55°C and at room temperature:
● For 100°C, the estimate by extending the solubility curve of the graph doesn’t explicitly show 100°C.
● For room temperature (approximately 25°C), locate 25°C on the x-axis and read the solubility value from the curve.
5. Calculate the mass of crystals that fall out of a saturated solution of KNO₃ in 100g of water when cooled from 60°C to 40°C.
Find the solubility of KNO₃ at both 60°C and 40°C from the graph.
Subtract the solubility at 40°C from the solubility at 60°C to find the difference in dissolved KNO₃ between the two temperatures.
This difference represents the mass of KNO₃ crystals that will fall out of the solution upon cooling. This difference is the mass of KNO₃ that will crystallize out per 100g of water.
Example calculation: If the solubility at 60°C is 110g per 100g water and at 40°C is 80g per 100g water, the mass of crystals that fall out would be: