TAKALKAR CLASSES BIBWEWADI

Total Marks: 50 Time: 60 Minutes

Chemistry Section A Solutions:

Q.1 At first, urea is synthesized in laboratory by

A) Traube B) Nollet
C) Kolbe D) Wohler
Q.5 The final product of methylation of ethyl
Solutions: Theory based amine is

A) Dimethyl ethyl amine

Q.2 In the acylation reaction the H-atom of an
amine is replaced by B) Methyl ethyl amine
C) 2-methyl-prop-2-ene
A) A carbonyl group
D) trimethyl ethyl ammonium salt
B) An alkyl group
Solutions: R–X finally forms quaternary ammonium salt.
C) An acetyl group
D) An imino group
Q.6
Solutions: In the acylation reaction H-atom of an amine is
replaced by an acetyl group (R-CO-). A)
B)
Q.3 Which of the following compounds will not C)
form a Schiff base on reaction with p- D)
nitrobenzaldehyde?
Solutions:

A) B)

C) D)

Solutions:

Q.4 Which of the following gives positive

Libermann nitroso test?

A) 2-butanamine
Q.7
B) N-ethyl-2-pentanamine
C) N-methylpiperidine
A) B) C) D)
D) N, N-dimethylcyclohexylamine

1/8
Solutions: Solutions:

Q.8

A)
B)
C)

D)
Q.12
Solutions:
A)

B)

Q.9

A) B)
C) D) C)

Solutions:

D)

Solutions:

Q.10

A) B)
C) D)
Solutions:

Q.13

A)
B)
C)
D)
Q.11
Solutions:

A) B)
C) D)

2/8
 Solutions: Solution:
Q.14 The Hinsberg reagent is benzene sulphonyl
chloride
A)
B)
C)
D)

Solutions:
Q.18 The end product in Hofmann’s exhaustive of
amines is

A) Primary amine
Q.15
B) Secondary amine
A) B) C) Tertiary amine
C) D) D) Quaternary ammonium halide

Solutions: Solutions: CH3CH2NH2 + CH3CH2I ⎯⎯⎯⎯ (CH3CH2) N + I −

− HI 4
Excess

Q.19 Which of the following conversions need the

reagent Sn/ HCl?

A) R – CO –NH2 → R –CH2 –NH2

Q.16
B) R – C ≡ N → R –CH2 –NH2
A) C) R – NO2 → R –NH2 + 2H2O
B)
D) R – CO –HN2 → R –NH2
C)
D) Solutions: R − NO ⎯⎯⎯⎯⎯⎯⎯
Sn / HCl
R − NH2 + 2H2O
2
Solutions:

Q.20 Identify Hinsberg reagent from following.

A) Benzene sulphonly chloride

B) Beynzyl chloride
C) Benzoyl chloride
D) Benzene diazonium chloride
Q.17 The Hinsberg reagent is: Solutions: Solution:
Benzene sulphonly chloride is Hinsberg
reagent.
A)
Q.21 Which of the following reactions does not match correctly
with
its name?
B)
A) R – NH2 + 3R – X → Hofmannexhaustivealkylation
B) R – CO – NH2 + Br2 + 4KOH → :Hofmanndegradation
LiA1H
C) R – CO – NH + 4[H] ⎯⎯⎯⎯⎯⎯⎯:Mendius
4
reduction
C) 2
⊕ ⊕ (i)moist Ag2o
D) R − CH2 − N − (R) 3 X ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯:Hofmannelimination
(ii) ∆ , − H2o

D)

3/8
Solutions: LiA1H4 Solutions: Solution:
R – CO – NH2 + 4[H] ⎯⎯⎯⎯⎯⎯⎯ R – CH2 – NH2
Mendius reduction (Incorrect)
By using Na/EtOH, it is known as Mendius
reduction. –NH2 group directly attached to benzene ring is
aromatic amine.
Q.22 What is the IUPAC name of (CH3) 2 – N–CH3?
Q.25 Which among the following reagents is used
A) 2, 2–Dimethylmethanamine to distinguish primary, secondary and
B) N – Methyldimethanamine tertiary amines according to solubility in
alkaline medium?
C) N, N–Dimethylmethanamine
D) Trimethylamine A) Benzene sulphonyl chloride
B) Ethylene glycol
Solutions:
C) Iodoform
D) Acetyl chloride
Solutions: Hinsberg reagent: Benzenesulfonyl chloride
(C6H5SO2Cl)
Q.23 Identify the amine that does not form alcohol
by the action of
NaNO2 and HCl.

A) (CH3) 3 – C –NH2
B) CH3 –CH2 –NH2

C)

D) (CH3) 2 –NH

Solutions: NaNO2 + HCl

R − NH2 ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯R – OH + N2 + H2O
Thus, (CH2) –NH → 2 ° amine, do not give
alcohol with NaNO2 & Q.26 The correct structure of
HCl. prop− 2 −en − 1 −amine is

A) CH3 –CH = CH–NH2

Q.24 Which one of the following is an aromatic
amine? B)

A) C)

D) H2C = CH–CH2 –NH2

B)
Solutions: 3 2 1
CH2 = CH–CH2 –NH2
prop− 2 −ene− 1 −amine
C)

D) C5H9 − NH2

4/8
Q.27 Identify compound X in the following reaction. Q.31 Identify the Gabriel phthalimide synthesis
reaction from the reactants and reagents
used in it.
LiAlH4
A) R – C ≡ N + ⎡⎢⎣ H⎤⎥⎦ ⎯⎯⎯⎯⎯⎯⎯ product
ether

A) (C2H5) 3 – N LiAlH4
B) R – CO –NH + ⎡⎢⎣ H⎤⎥⎦ ⎯⎯⎯⎯⎯⎯⎯ product
2 ether
B) C2H5 –NH2
Δ
(C2H5) –NH C) R – CO –NH2 + Br2 + 4NaOH (aq. )⎯⎯⎯ product
C) 2

D) CH3 –NH– C2H5

Solutions:
D)

Solutions: Gabriel phthalimide synthesis reaction

Q.28 Which among the following reactions represents
Carbylamines reaction?
Δ
A) R –NH2 + CHCl3 + 3KOH⎯⎯⎯R –NC + 3KCl + 3H2O
alc
(i) NaNO2 + HCl ⏐
⏐⏐
B) R –NH2
+ NHO 2
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ R – OH + N2⏐
⏐ + HCl
⏐⏐
(ii) H2O ⏐⏐
pyridine
C) R –NH2 + CH3COCl⎯⎯⎯⎯⎯⎯⎯R –NH–COCH3 + CHl
⎯⎯ +
D) R –NH + R – X → R NX + 2HX
2 4

Solutions: R –NH + CHCl + 3KOH⎯⎯⎯

Δ
R –NC + 3KCl + 3H2O
2 3 alc
Carbylamine reaction Q.32 How many isomers of C4H11N are tertiary
amines?
Q.29 Identify the reagent used for conversion of
A) One B) Two
aniline to phenol from following.
C) Three D) Four
A) NaNO2 / HCl /
Solutions:
B) LiAlH4
H2
C)
Ni
D) Co −naphthenate
Q.33 What is the molecular formula of p-
Solutions: NaNO2 / HCl is used for conversion of aniline to toluidine?
phenol.
A) C6H10N2 B) C7H9N
Q.30 How many moles of ethyl bromide is C) C10H14N2 D) C10H14N
required for formation of 1 mole
Solutions:
N, N − Di ethyl ethanamine from ethyl
amine?

A) 1 B) 2 C) 3 D) 4
Solutions:

5/8
Q.34 Which of the following amines on heating Q.38 Which among the following reagents is
with chloroform generate foul smelling called as Hinsberg’s reagent?
product?
A) Benzenesulphonyl chloride
A) Ethanamine B) Sodium nitroprusside
B) Ethyl methyl amine C) Chromyl chloride
C) Ethyl dimethyl amine D) Hydrazine
D) Diethylmethyl amine
Solutions: Solution. (A)
Solutions: It must be primary amine Ph − SO2 − Cl (Benzene sulphonyl chloride, Hinsberg
CHCl3 / KOH
CH3 –CH2 –NH2⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯CH3 –CH2 – N⎯
= C + KCl + H2O reagent.)
wurtzreaction
ethylisocyanide
Ethylamine (1 ° amine)
(foulsmellingproduct) Q.39 Aniline is treated with NaNO2 + HCl at low
temperature to form,
Q.35 What is molecular formula of
cyclohexylamine?

A) C6H8N B) C6H10N A) B)

C) C6H12N D) C6H13N

Solutions:

C) D)
cyclohexylamine
M.F. = C6H13N

Q.36 Identify the correct decreasing order of Solutions:

basic strength of compounds from following.

A) CH3NH2 > (CH3) 2NH > C6H5NH2 > NH3

B) (CH3) 2NH > CH3NH2 > NH3 > C6H5NH2
Q.40 (i) NaNO2 + HCl ,273K
C) CH3 > CH3NH2 > (CH3) 2NH > C6H5NH2 If, Aniline product.
(ii) H2O , Δ
D) C6H5NH2 > (CH3) 2NH > CH3NH2 > NH3 Identify the product of above reaction.
Solutions: ..
A) o-Nitroaniline
⇒ C6H5 − NH2 (de localization of ℓ .p )
Least basic B) m-Nitroaniline
⇒ R = CH3,2 ° > 1 ° > 3 ° > NH3 (As per NCERT) C) p-Nitroaniline
Thus correction Ans. is D) Phenol
(CH3) NH > CH3NH2 > NH3 > C6H5NH2
2
Solutions:

Q.37 Identify substrate ‘A’ in the following

conversion
∆
A + CH3I⎯⎯⎯C2H5 (CH3) 3+NI +
excess

A) C2H5NO2 B) C2H5CN
C) C2H5NH2 D) CH3CONH2

Solutions: CH3 − I + −
C2H5 − NH2⎯⎯⎯⎯⎯⎯⎯⎯C2H5 − (CH3) N I
∆Excess

6/8
Q.41 Identify product B in the following reaction. Q.45 Which of the following amines undergoes
acylation reaction?

A) Ethyldimethylamine
A) Chlorobenzene B) N-Methylaniline
B) Benzyl alcohol C) N-N-dimethylmethanamine
C) Benzenediazoniumchloride D) N-N-Dimethylaniline
D) Phenol
Solutions: Amine having acidic H undergoes acylation
Solutions:

Q.42 Which of the following compounds do not

develop intermolecular hydrogen bonding?

A) Cyclohexylamine
B) Allylamine Q.46 Identify correct decreasing order of
C) Trimethylamine solubilities of alcohols, alkanes and amines
D) Diphenylamine in water having comparable molar mass.

Solutions: A) alcohol > amine > alkane

B) alkane > amine > alcohol
C) amine > alcohol > alkane
D) alkane > alcohol > amine
Solutions: Sol. (A)
Q.43 Which isomers among the following has Salability ∝ H-bonding
alcohol from better H-bond than amine.
highest boiling point?
Therefore, Alcohol > amine > alkane
A) n-Butylamine
B) tert-Butylamine Q.47 Identify an aromatic, mixed, 3°amine from
following.
C) Ehyldimethylamine
D) Diethylamine
Solutions: Due to H-bonding n-butylamine has highest boiling
point. A)

Q.44 What is IUPAC name of allylamine?

B) (C2H5)3N
A) Propan-1-amine
C) (CH3)3C–NH2
B) Prop-2-en-1-amine
C) Prop-1-en-2-amine
D) Propan-2-amine
D)
Solutions:

7/8
Solutions: Mixed 3oamine means different type of alkyl radical
attacted to N-atom, Q.50 The product A formed in the following
reaction is

A)

Q.48 Identify ‘A’ in the following reaction

LiAH4
A⎯⎯⎯⎯⎯⎯Ethanamine
Ether
B)
A) C2H5CN B) CH3CONH2
C) C2H5CONH2 D) CH3NO2

Solutions: Sol. (B) C)

Q.49 Which from following statements is true D)

about CH3CH(NH2)CH2COOH molecule?

A) It is an example of amino acids.

Solutions:
B) It’s IUPAC name is 3-carboxy-2-amine
C) The amino group is located at C –2.
–NH2 group is considered as principal
D)
functional group for IUPAC naming.
Solutions: Sol. (C)

8/8