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Gaseous Assignment

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4 views

Gaseous Assignment

Czzufuxffzfuzfuufzu

Uploaded by

yuvrajkumarbhagat
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Class home work

1 A sample of a gas occupies 10 litre under a pressure of


atmosphere. What will be its volume if the pressure is increased
to 2 atmosphere? Assume that the temperature of the gas
sample does not change.

2 A sample of a gas occupies 600 mL at 27°C and 1 atm. What


will be the volume at 127°C if the pressure is kept constant.

3 A gas cylinder containing cooking gas can withstand a


pressure of 14.9 atmosphere. The pressure gauge of the
cylinder indicates 12 atmosphere at 27°C. Due to a sudden fire
in the building, the temperature starts rising. At what
temperature will the cylinder explode?

4 A 1000 mL sample of a gas at -73°C and 2 atmosphere is


heated to123°C and the pressure is reduced to 0.5
atmosphere.What will be the final volume?

5 3.7 g o f a gas at 25°C occupied the same volume as 0.184 g


of hydrogen at 17°C and at the same pressure. What is the
molecular mass of the gas?

6 What is the pressure of HCl gas at -40°C if its density is


8.0 kg m-3 ?

7 A sample of a gas occupies a volume of 512 mL at 20°C and


74 cm of Hg as pressure. What volume would this gas occupy
at STP?
8 The density ofa gas is 0.259 g/L at 400 K and 190 torr: Find its
molar mass.

9 The density of phosphorus vapour at 310°C and 775 torr is 2.64


g dm-3. What is the molecular formula of phosphorus?

10 What percentage of a sample of nitrogen must be allowed to


escape if its temperature, pressure and volume are changed
from 220°C, 3.0 atm and 1.65L to 110°C, 0.7atm and 1.0L
respectively?

11 The density of oxygen is 1.43 g/L. Determine the denstty of


oxygen at 17°C and 800 torr

12 Oxygen is present in a one litre flask at a pressure of 7.6x


10-10 mm of Hg. Calculate the number of oxygen molecules in
the flask at at 0°C.

13 An open flask contains air at 27°C. Calculate the temperature at


which it should be heated so that 1/3 rd of air measured at 27°C
escapes out.

14 A mixture of CO and CO2 is found to have a density of 1.5 gL-1


at 30°C and 730 torr. What is the composition of the mixture?

15 2.5 L of a sample of a gas at 27°C and 1 bar pressure is


compressed to a volume of 500 mL keepipg the temperature
constant, the percentage increase in the pressure is:
(a) 100% (b) 400% (c) 500% (d) 80%
16 A certain quantity o f a gas occupies 100 mL when collected
over water at 15°C and 750 mm pressure. It occupies 91.9 mL
in dry state at NTP Find the aqueous vapour pressure at 15°C

17 Which of the following gases will have density of 1.8 g/L at 760
torr pressure and 27°C ?

18 The vapour of phosphine gas at 27°C and 3 bar pressure has


density:
(a) 4.09 g /mL (c) 2.04 g /L (b) 4.14 g/L (d) 2.04 g/ L

19 A 10litre flask contains 0.2 mole of methane, 0.3 mole of


hydrogen and 0.4 mole of nitrogen at 25°C. What is the partial
pressure of each, component and what is the pressure inside
the flask?

20 1.22 g of a gas measured over water at 15°C and a pressure


of 775 mm of mercury occupied 900 mL. Calculate the volume
of dry gas at NTP Vapour pressure of water at 15°C is 14mm.

21 1500 mL flask contains 400 mg O2 and 60mg H2 at 100°C


(a) What is the total pressure in the flask?
(b) If the mixture is permitted to react to form water vapour at
100°C, what will be left and what will be their partial
pressures?
22 Find the total pressure exerted by 1.6 g methane and 2.2 g
CO2 contained in a four litre flask at 27°C

23 20 dm3 o f S02 diffuse through a porous partition in 60 s.


What volume ofO2 will diffuse under similar conditions in
30s?

24 50 volume o f hydrogen take 20 minute to diffuse out ofa


vessel. How long will 40 volume ofoxygen take to diffuse
outfrom the same vessel under the same conditions?

25 Calculate the relative rates of diffusion of 235UF6 and 238UF6


in the gaseous state (At. mass of F- 19).

26 180 mL o f a hydrocarbon diffuses through a porous


membrane in 15 minutes while 120 mL of SO2 under identical
conditions diffuses in 20 minutes. What is the molecular
mass of the hydrocarbon?

27 The reaction between gaseous NH3 and HBr produces a white


solid NH4Br. Suppose a small quantity of gaseous NH3 and
gaseous HBr are introduced simultaneously into opposite ends
of an open tube which is one metre long. Calculate the
distance of white solid formed from the end which was used to
introduce NH3

28 The ratio of velocities of diffusion of gases A and B is 1:4. If the


ratio of their masses present in the mixture is 2: 3, calculate
the ratio of their mole fractions.
29 100 cm of NH3 diffuses through a pill hole in 32.5 second.
How much time will 60 cc o f N2 take to diffuse under the
same conditions

30 A gas with molecular fonnula CnH2n + 2 diffuses through a


porous plug at a rate 1/6th of the rate of diffusion of hydrogen
gas under similar conditions. The formula of the gas is:

31 Under similar conditions which of the following gases will


diffuse four times as quickly as oxygen?
1. He 2. H2 3.N2 4. D2

32 The rate of diffusion of hydrogen and deuterium are in the


ratio:
(a)1 : 1 (b) 1.414 : 1 (c) 4 : 1 (d) 1 : 4

33 The time taken for effusion of 64 mL of oxygen will be same as


the time taken for the effusion of which of the following gases
under identical condition’s?
1. 64mL of H2 2. 100 mL of N2
3. 64 mL of CO2 4. 45.24 mL of SO2

34 Calculate the kinetic energy in joule of 8.00 g of methane at


27°C

35 Calculate the average and total kinetic energy of 0.5 mole of


an Ideal gas at 0°C.

36 Calculate the pressure exerted by 10^23 gas molecules each


of the mass 10^-22 g in a container of volume 1L the rms
speed is 10^5 cm/s.
37 Calculate the root mean square speed of an oxygen molecule
at 288 K in SI units.

38 Calculate the root mean square speed of hydrogen molecule


at STP

39 Oxygen at 1 atmosphere and 0°C has a density of 1.4299 g/L.


Find the rms speed of oxygen molecule.

40 At what temperature will hydrogen molecules have the Same


root mean square speed as nitrogen molecule at
molecules at 27°C?

41 Calculate the root mean square, average and most probable


speed o foxygen at 27°C

42 Calculate the average kinetic energy per mole of CO2 gas at


27°C in different units (Joules, calories, ergs).

At what temperature is the root mean square speed of N2 gas


43 equal to that of propane gas at STP?
(a) 173.7°C (b) 173.7 K (c) 273 K (d) -40°C

44 At what temperature is the kinetic energy of a gas molecule


half of its value at 327°C?

45 At what temperature is the rms speed of H2 molecules the


same as that of oxygen molecules at 1327°C?
The root mean square speed of molecules of nitrogen gas is v
46 at a certain temperature. When the temperature is doubled, the
molecules dissociate into individual atoms. The new rms speed
of atom is:

The translational kinetic energy of an ideal gas depends only


47
on its:

1. pressure
2. Force
3. Temperature
4. molar mass

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