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ALL INDIA TEST SERIES

JEE (Advanced)-2024
CONCEPT RECAPITULATION TEST – III
PAPER –2
TEST DATE: 01-05-2024

ANSWERS, HINTS & SOLUTIONS

Physics PART – I

SECTION – A

1. C
Sol. tan   2

E

d tan

p d

1 P
Enet  1  3cos 2 
4 0 d3 sec 3 
1 P 2

4 0 d3  3 3
1 2P v2
Now e    m
4 0 3 3d3 d 2
2eP eP
 v 
12 3  0 md2 6 3 0 md2

2. D
v2
Sol. Acceleration of cm of cylinder 
5R
Acceleration of point P =
2
v v2
 R  
 R  5R
4v 2
 
5R

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

3. A
K K
Sol. v F  2
x x
Conservation of mech. energy
4K 4K 1
  mv 2
5R 7R 2
16K
 mv 2 
35R
K mv 2
Now N 2

 7R / 4  R
192K
 N
245R 2
4. D
2
H R h0 H
Sol. R2   h0 
4 2 2
H 2R2 gH
Now  
2 2g R
5. BC
Sol. Before t = 0,
Q;  CE  4C
E
i0  through inductor    1A
R
After t = 0
Qi2 1 2 Qmax 2
 Li0   Qmax  2 5C
2C 2 2C
Q2 1 2
Similarly max  Limax  imax  5A
2C 2
6. CD
R
Sol. B executes SHM with time period T = 2 both have same time period
g

When A reaches position of B, angle turned = At that time B will be at half of amplitude, that is
3
1 R
 3 from O1.
2 2
2 2
g2 2
 3R   3R  3
Speed v  w A  y        gR
R  2   4  4
3R g 3gR
When B reaches O1 its speed is . 
2 R 2
2
 3gR  2 7
Relative speed 
 2 
   gR  
4
gR
 
7. BCD
N0
Sol.  N0 et1
5

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

ln5
 t1  sec

ln2 ln 2
 
t1/2 2
2ln5
thus t1   2log2 5 sec
ln2
At t 2 , population of NA is 0.1 No
No
 No e t 2
10
ln10
 t2   2log2 10 sec

Now t 2  t1  2log2 10  2log2 5  2 sec

SECTION – B

8. 13
A2 3A
Sol. Speed before =  A 2  
4 2

A/2

A’

After = 3A
13A
Now amplitude A ' 
2
1
cos     t
13
T  1 
t cos 1  
2  13 
9. 4
Q  q q dq
Sol.    3R  0
C 2C dt
dq
i
dt

(Q – q) q

(Q – q) q

3R

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

t
2Q   
q  1  e 2RC 
3  
Q
Put q , t  4R Cn2
2
10. 9
Sol. Conservation of mech, energy
L m L 1 mL2 2 9g
mg  g   
2 2 4 2 3 4L
11. 3
Sol. Path is cycloidal
Maximum depth = 2R
m2g
R 2 2
qB
12. 5
Sol. Glass slab give constant shift.
13. 9
Sol. Critical damping
b2  4mk
b2
k  0.09N / m
4m
SECTION – C
14. 10.00
Sol. PB A  PA  A  mass(AB)  a

B A
L L 
 L3g  Lg A  3 A   Aa
 2 2 
 2Lg  2La
 a  g  10m / s 2
15. 150.00
Sol. Just after system is stopped acceleration of liquid of tube = ao.

3mg mg

ao

A B m =AL

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

2mg g
a0  
6m 3
3m
PA  A  mg   a0
2
3m g 3mg
 PA  A  mg   
2 3 2
3 3
 PA   Lg   102  101  10  150N / m 2
2 2

16. 12.00
 
Sol. 
PQ 3
V wave
x = 2m x = 4m

3A
 P Q
2

2 
 2 
 3
   12m

17. 49.00
Sol. x = 3.5 m (let point is ‘R’)

30o

P Q

2 1 
RQ    rod
12 2 12
Maximum power transfer at mean position. Time to cross mean position for R is
  
  
12 3  49
t  2   second.
10 24

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

Chemistry PART – II

SECTION – A

18. B
Sol. BrO3  4H  4e  BrO   2H2 O E0  0.54 V
1
BrO  2H  e  Br2  H2 O Eo  0.45 V
2
1
Then Eo for BrO3  6H  5e   Br2  3H2 O
2
5FE 0  4F  0.54   F  0.45 
is
E0  0.52V

19. B
1
Sol.  B(g) from graph n 
nA (g) 
2
A
Here  constant
time
It is zero order reaction

20. C
Sol.  v  a z  b
v  az  ab, ab  1, a  tan 45o
v  51  1, v  2500 Hz

21. D
Sol. (Reimer – Tiemann’s reaction)

22. ACD
2
Sol. cis form of Pt Cl2  NH3  4  have super imposable mirror image B is true
a
M
Square planar have super imposable mirror image but d b is optically active.
c
23. BCD
Cl

Sol. (A) will not release Cl– (B) CH3  C  CAg is white ppt
(C) gives CHI3 (yellow ppt.)
(D) ppt of NaCl formed

24. ABD
Sol. Due to tautomerization.

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

SECTION – B

25. 2
Sol. It will form buffer solution
Let V ml of KCN is added, the total volume = V + 10 ml
20 5V
HCN  , KCN 
V  10 V  10
KCN
pH  pk a  log
HCN
5V
9  9.3  log
20
 V  2m 

26. 5
Sol. PbS, Ag2S, NiS, CuS, CoS are black coloured solid.

27. 9
Sol. C  C  C  C, C  C  C  C, C  C  C  C, CC  CC

, , , ,

28. 4
Sol. O OH OH

A= , B= , C=

O OH OH

29. 3
Sol. (vi), (vii) and (viii) have non-superimposable mirror image.
30. 6
Sol. OH
CHO
CHO
OH

(A) (B) (C)

SECTION – C
31. 1.26
Sol. T3(aq)

 2e   T (aq)

E0  ?
T (aq)  e  T (s) G10  F(0.336)  0.336F
T3(aq)

 3e   T (s) G20  3F 0.728 
T3(aq)

 2e   T (aq) G0  3FE0
G0  G02  G10
2FE0  3F  0.278  0.336F
2.52
 2.184F  0.336F E0   1.26V
2

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

32. 26.96
Sol. From eq.
I2 s  2e  
 2Iaq Go  2F  0.54 
I2 s  Iaq  I3aq Go  RT ln  0.459 
 for I3 aq  2e   3Iaq Go  106.1 kJ mol1
The reaction T (aq)  I3(aq)
 
 I(aq)  TI4(aq)

can be formed by following reactions:
T (aq) 
 T3(aq)

 2e  E0  1.26 V; G10  243.1kJ mol1

I3(aq)  2e   3I(aq)

G20  106.1kJ mol1
T3(aq)
 
 4I(aq)  TI4(aq)

K f  1035.7 ; G30  203.8kJ mol1
The net free energy change for the reaction
T (aq)  I3(aq)
 
 I(aq)  TI4(aq)


0
GRx  G10  G20  G30
 66.8kJmol1
0
GRx  RT lnK eq
G0Rx 66.8  103
lnK eq     26.96
RT 8.314  298

33. 92.92
Sol. 2PbS  3O2  2PbO  2SO 2
PV
Moles of PbS = moles of SO2 =  2.706  103 (only from two-third of the sample)
RT
3
So total nPbS  2.706  103  4.06  103
2
Mass of PbS  4.06  10 3  239.2  0.971 g,
WPbS
% purity   100  92.92
Wgelena

34. 2.90
Sol. Total mass of lead produced = 0.8663 g
0.8663
Total mole of lead 
207.2
 nPb  nPbS   4.18  103 nPb   nPb  nPbS   nPbS 
 4.18  10 3  4.06  10 3
 0.12  103
nPb 0.12  10 3
So % elemental lead    100
nPb  nPbS 4.18  10 3
 2.8  2.9%

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

Mathematics PART – III

SECTION – A

35. A
z1
Sol. z
z2
y

A(z1)

B(z2)

x
O

 z 2  2z  2  0
 z  1 i
z1
  1 i
z2
 z1  z 2  z 2i
 z1  z 2   z 2i
 z1  z2 is perpendicular to z2 and z1  z2  z 2

36. C
Sol. Pn  n  2C3 ;Qn  n C3  n  n  n  4  
n
C1  n  4 C2
or Qn 
3
Pn  Qn  6
 n  10

37. D
1
Sol. f '(x)    cos  x   C
x
1 1
f '(2)     C     C  0
2 2
f(x)  ln x  sin  x   C'
f(1)  C'  0
f(x)  ln x  sin  x ]

38. C
Sol. y 2  4ax,4a  2p  0

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

at12 ,2at1

A  x1, y1 

B  x2 , y2 

at 22 ,2at 2

x1  at12 , y1  2at1
x 2  at12 , y 2  2at 2
and t1t 2  1
4a2 t1t 2
Ratio   4
a2 t12 t 22

39. CD
Sol. P  E1   1  P (unit’s place in both is 1, 2, 3, 4, 6, 7, 8, 9)
2
 4 9
P(E1  0 or 5)  1    
5 25
P(E2 : 5)  P 1 3 5 7 9   P 1 3 7 9  for 2 numbers
1 4 25  16 9
   
4 25 100 100
P(E 2 ) 9 9 25 1
   
P(E1 ) 100 100 9 4
P(E1 )  4P(E2 )
 (A) is not correct.
 E  P  E 2  E1  P E2  9 25 1
P 2      
E
 1 P  E1  P  E1  100 9 4
 (C)
 E  P  E1  E2  P E1 
P 1    1
 E2  P  E2  P  E2 
 D 

40. ABCD
Sol. Use R1  R1  R2 and R2  R2  R3 and expand to get D  2 1  sin 4   0
n n 
    1
4 8
 Independent of A
 (A),(B),(C),(D)
41. AC
 x  2 1  x  0
 x3 if x 1
Sol. f(x)   2 ; g(x)   x 0  x 1
x if x 1
 x  2 2  x  3

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

 (A),(C)
Also g(x) be continuous at x  I
2
g(n)  n2 ; g n   n2 ; g  n    n  1  1
2
For continuity n2   n  1  1
 n 1
 g(x) is continuous only at one integer x = 1.

SECTION – B

42. 9
 
Sol. Equation of plane P (with usual n1 which n to n and AB
n1  n  AB   i  j  3k    i  3j  k   2i  j  k
 Equation of plane
P1 : 2  x  1  1 y  2   1 z  0   0
 P1 : 2x  y  z  4
Also, P2 :  x  y  z  5
Q
n1  n2
B P1
P
A
L (1, 1, 1)

P2

Line PQ is parallel to vector

i j k i j k
n1  n2  2 1 1  1 0 0  k  j
1 1 1 1 1 1
x 1 y  6 z 0
 Equation PQ :   
0 1 1
(Contained P1 and P2 in symmetric form)
Let B  1, 6  ,   be any point on line PQ

So, AB  2iˆ   5    ˆj     1 kˆ
  
Now, AB  n1  n2  0
 0  5     1 0
 3
 B   1,3,3 
x 1 y  3 z 3
So, equation of line L is  
1 1 1 3 1 3
x 1 y  3 z 3
i.e.,  
1 1 1
 2y1  z1 6  3 
Hence   9
 bc 1 

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

43. 5
1
50 100
Sol. J  1  x 
0
x100 dx

1 1
 x101  99 x 101
  (1  x 50 )100
101
  100 1  x
 50
   50x  10149
dx
 0 0
1
5000 99
0
101 0
1  x 50  1  1  x  x 50 100
dx

1 1
5000  99 100 
   1 x
101  0
50
 
x100 dx   1  x 50  x100 dx 
0 
5000 500
J J I
101 101
5101 5000
J I
101 101
I 5101 m
  
J 5000 n
m  1  n 5101  1  5000
  5
20 20

44. 4
Sol. f(x)  ln 1  x 2   tan1 x
g(f(x))  x
g'(f(x))f '(x)  1
1 f "(x)
 g'(f(x))   g"(f(x))f '(x)  
f '(x) (f '(x))2
f "(x)
 g"(f(x))  
(f '(x))3
f(x)  ln 2e  /4  

 ln 1  x 2 tan1 x 

 ln 2 
4

 ln 1  x 2  tan1 x 
 x 1
f "(1)
g"(ln(2e  / 4 )) 
(f '(1))3
1 2x 2x  1
f '(x)  2
 2

1 x 1 x 1 x2
3
 f '(1) 
2

f "(x) 

1  x 2 2   2x  1  2x 
2
1 x2  


2 1  x  x2 
2 2
1  x 

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

1
 f "(1) 
2
2 4
 g"(ln2e  /4 ))  
27 27
 27  g"(ln(2e / 4 ))  4

45. 32
 3 
Sol. We have, an  tan1  2 
 9n  3n  1 
 3 
 tan1 
 1   3n  2  3n  1 
 
 3n  2  3n  1 
 tan1 
 1   3n  2  3n  1 
 
1 1
 tan  3n  2   tan  3n  1
 Sum of first 10 terms
10 10


  ar   tan1  3r  2   tan1  3r  1
r 1 r 1

    
 tan1 5  tan1 2  t tan1 8  tan1 5  ......  tan 1 32  tan 1 29 
 32  2 
 tan1 32  tan1 2  tan1  
 1  32.2 
30  6   13  m
 tan1  tan1    cot 1    cot 1  
65  13   6  n
 m  13 and n  6
Hence,  2m  n   32

46. 816
2
Sol. f(x)  a0  a1 1  x   a2 1  x   ....
2
f '(x)  a1  2a2 1  x   3a3 1  x   ...
f "(x)  2a2  6a3 1  x   ...
f "( 1)  2a2  Note 
Now, f(x)  1  x  x 2  x 3  ....  x16  x17
f '(x)  1  2x  3x 2  ...  16x15  17x16
f "(x)]x 1  1 2  2  3  3  4  ....  16  17
16
  r  r  1   r 2   r
r 1

16.17.33 16.17 16.17

   11  1
6 2 2
f "  1  16.17.6
2a 2  16.17.6
a2  16.51  816

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

47. 10
2
Sol. Suppose roots be a 2 ,  a  1 , where   N
2
So, the equation is  x  a2   x   a  1   0
 
2 2
Given, a2  a  1  1   a  1  a2
 a  a  1  1   2a  1  As a  N
2
 a  a  1  2a  1
 a2  a  2  0
  a  2  a  1  0
 a  2 or  1
(Reject, a  1 as a  N )
Hence, roots are 4 and 9.
4 0
f(x)  x 2  cx  1

Let f(x)  x 2  cx  1
17
So, f(4)  0  17    4c  0  c  ...(i)
4
82
and f(9)  0  82  9c  0  c  ...(ii)
9
82
 Eqns. (i)  (ii) gives c 
9
 Hence, minimum integral value of c = 10.

SECTION – C

48. 17.00
f(x) x2  x  1 2 1  2x  1 
Sol.  x3  1dx  ln x  1  3 tan  3   C
Differentiating both sides, we get
x  1  x  1 2x  1   x  x  1  1 2
2
f(x) 1 2
   
x3  1 x 2  x  1  x  1
2
3  2x  1 
2
3
1  
 3 
2x 2  x  1  x 2  x  1 4 3
  
3
x 1 2
3 3  4x  4x  1  
2
x  2x  2 1
 3
 2
x 1 x  x 1
 
f(x)  x 2  2x  2   x  1  x 2  x  3
5
 f(5)  5  5  3  17

49. 3.00
1  6cosec x
Sol. I d  sin x 
6  f(sin x)

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AITS-CRT-III (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024

6
1
 sin x d  sin x 
2
6  sin x  sin x  3
6
1
sin x d  sin x 
 Put sin x  t 
sin2 x  sin x  3
6 1 6
 2
 3
 2 t dt   t t dt
t t3 1 3
1  2
t t
 1 3  1 3 
 ln  1   2   K  ln  1   2 K
 t t   sin x sin x
 1 3 
 g(x)  ln  1   2 
 sin x sin x 
 1 3 
 g(x)  ln  1   2 
 sin t sin t
Now, lim g(t)  ln3
t  /2

50. 4.00

1 1 t2
Sol. f(t)   k
 
k 0  t  2 1 t 1
1
 2
t 
f(0)  2
2 3 4 5
S  1  2  3  4  ......
2 2 2 2
S 1 2 3
    ......
2 2 22 23
S 1 1 1
 1   2  3  .....
2 2 2 2
S 1
 
2 1
1
2
S4

51. 1.00
k2
Sol. f(k) 
k  1
f(k) 1

k  k  2  k  k  1
 
f(k) 1 1 
 k k  1    k  k  1   1
k 1 k 1

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