FINAL JEE(Advanced) EXAMINATION – 2023

(Held On Sunday 04th June, 2023)

PAPER-1 TEST PAPER
CHEMISTRY
SECTION-1 : (Maximum Marks : 12)
 This section contains THREE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 ONLY if (all) the correct option(s) is(are) chosen;

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Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it
is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to
correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 marks;
choosing ONLY (B) will get +1 marks;
choosing ONLY (D) will get +1 marks;
choosing no option (i.e. the question is unanswered) will get 0 marks; and
choosing any other combination of options will get –2 marks.

1. The correct statement(s) related to processes involved in the extraction of metals is(are)
(A) Roasting of Malachite produces Cuprite.
(B) Calcination of Calamine produces Zincite.
(C) Copper pyrites is heated with silica in a reverberatory furnace to remove iron.
(D) Impure silver is treated with aqueous KCN in the presence of oxygen followed by reduction
with zinc metal.

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2. In the following reactions, P, Q, R, and S are the major products.

CH3CH2CH(CH3 )CH2CN 
(i) PhMgBr, then H3O
(ii) PhMgBr, then H O
P
2

O
|| (i) anhyd. AlCl3
Ph – H + CH3CCl (ii) PhMgBr, then H2O
Q

O
|| 1
(i) (PhCH ) Cd
2 22
CH3CH2CCl R
(ii) PhMgBr, then H O
2

 i  PhMgBr, then H 2O

PhCH2CHO 
(ii) CrO3 , dil.H 2SO4
(iii) HCN
S
(iv) H2SO4 , 

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The correct statement(s) about P, Q, R, and S is(are)
(A) Both P and Q have asymmetric carbon(s).
(B) Both Q and R have asymmetric carbon(s).
(C) Both P and R have asymmetric carbon(s).
(D) P has asymmetric carbon(s), S does not have any asymmetric carbon.

3. Consider the following reaction scheme and choose the correct option(s) for the major products Q,
R and S.
Styrene (i) B2H6
(ii) NaOH, H O , H O
 P 
(i) CrO3 , H2SO4
(ii) Cl , Re d Phosphorus
Q
2 2 2 2
(iii) H2O

P 
(i)SOCl2
(ii) NaCN
 R 
conc.H 2SO4
S
(iii) H3O , 

O O
Cl COOH Cl COOH COOH
NH2 NH2

(A) (B)
O
SO3H
Q R S Q R S

O O
O O
Cl COOH Cl
NH2 NH2

(C) (D)
O
SO3H
Q R S Q R S

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 SECTION-2 : (Maximum Marks : 12)
 This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the
correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.

4. In the scheme given below, X and Y, respectively, are

Metal halide 
aq. NaOH
 White precipitate (P) + Filtrate (Q)

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aq.H2SO4
PbO  excess 
P 
2
heat
 X (a coloured species in solution)
MnO OH 2 ,
Conc.H 2SO4
Q 
warm
Y (gives blue-coloration with KI-starch paper)

(A) CrO42– and Br2 (B) MnO42– and Cl2

(C) MnO4– and Cl2 (D) MnSO4 and HOCl

5. Plotting 1/Λm against cΛm for aqueous solutions of a monobasic weak acid (HX) resulted in a
straight line with y-axis intercept of P and slope of S. The ratio P ⁄ S is
[Λm = molar conductivity
m = limiting molar conductivity
c = molar concentration
Ka = dissociation constant of HX]
(A) Ka m (B) Ka m / 2 (C) 2 Ka m (D) 1 / (Ka m )

6. On decreasing the 𝑝H from 7 to 2, the solubility of a sparingly soluble salt (MX) of a weak acid
(HX) increased from 10−4 mol L−1 to 10−3 mol L−1. The 𝑝Ka of HX is:
(A) 3 (B) 4 (C) 5 (D) 2

7. In the given reaction scheme, P is a phenyl alkyl ether, Q is an aromatic compound; R and S are the
major products.
(i) NaOH
(ii) CO2 (i)  CH CO  O
P  Q
HI
 R 
3
 S
2
(iii) H3O  (ii) H3O

The correct statement about S is

(A) It primarily inhibits noradrenaline degrading enzymes.
(B) It inhibits the synthesis of prostaglandin.
(C) It is a narcotic drug.
(D) It is ortho-acetylbenzoic acid.
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 SECTION-3 : (Maximum Marks : 24)
 This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the
on-screen virtual numeric keypad in the place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 ONLY If the correct integer is entered;
Zero Marks : 0 In all other cases.

8. The stoichiometric reaction of 516 g of dimethyldichlorosilane with water results in a tetrameric

cyclic product X in 75% yield. The weight (in g) of X obtained is___.
[Use, molar mass (g mol−1): H = 1, C = 12, O = 16, Si = 28, Cl = 35.5]

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9. A gas has a compressibility factor of 0.5 and a molar volume of 0.4 dm3 mol−1 at a temperature of
800 K and pressure x atm. If it shows ideal gas behaviour at the same temperature and pressure, the
molar volume will be y dm3 mol−1. The value of 𝐱/𝐲 is ___.
[Use: Gas constant, R = 8 × 10−2 L atm K−1 mol−1]

10. The plot of log kf versus 1 for a reversible reaction A (g) P (g) is shown.
T

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log kf

0.002 1 –1
(K )
T

Pre-exponential factors for the forward and backward reactions are 1015 s−1 and 1011 s−1,
respectively. If the value of log K for the reaction at 500 K is 6, the value of | log kb | at 250 K is
______.
[K = equilibrium constant of the reaction
kf = rate constant of forward reaction
kb = rate constant of backward reaction]

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11. One mole of an ideal monoatomic gas undergoes two reversible processes (A  B and B  C) as
shown in the given figure :

A
600 V1, T1

Temperature (K)
V2, T2 V3, T2
60
B C

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Volume (m3)

A  B is an adiabatic process. If the total heat absorbed in the entire process (A  B and B  C)
is RT2 ln 10, the value of 2 log V3 is _________.

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[Use, molar heat capacity of the gas at constant pressure, Cp,m = R]
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12. In a one-litre flask, 6 moles of A undergoes the reaction A (g) P (g). The progress of product
formation at two temperatures (in Kelvin), T1 and T2, is shown in the figure:
[P] (mol L–1)

4 T1

2 T2

Time (h)

If T1 = 2T2 and (G 2  G1 ) = RT2 ln x, then the value of x is ______.

[ G1 and G 2 are standard Gibb’s free energy change for the reaction at temperatures T1 and T2,
respectively.]

13. The total number of sp2 hybridised carbon atoms in the major product P (a non-heterocyclic
compound) of the following reaction is _______.
NC CN (i) LiAlH4 (excess), then H2O
P
NC CN (ii) Acetophenone (excess)

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 SECTION-4 : (Maximum Marks : 12)
 This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (P), (Q), (R) and (S) and List-II has Five entries (1), (2), (3), (4) and (5).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY
ONE of these four options satisfies the condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.

14. Match the reactions (in the given stoichiometry of the reactants) in List-I with one of their products
given in List-II and choose the correct option.
List-I List-II

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(P) P2O3 + 3H2O  (1) P(O)(OCH3)Cl2
(Q) P4 + 3NaOH + 3H2O  (2) H3PO3
(R) PCl5 + CH3COOH  (3) PH3
(S) H3PO2 + 2H2O + 4AgNO3  (4) POCl3
(5) H3PO4
(A) P  2; Q  3; R  1; S  5 (B) P  3; Q  5; R  4; S  2
(C) P  5; Q  2; R  1; S  3 (D) P  2; Q  3; R  4; S  5

15. Match the electronic configurations in List-I with appropriate metal complex ions in List-II and
choose the correct option.
[Atomic Number: Fe = 26, Mn = 25, Co = 27]
List-I List-II
(P) t 62ge0g (1) [Fe(H2O)6]2+

(Q) t 32ge2g (2) [Mn(H2O)6]2+

(R) e 2 t 32 (3) [Co(NH3)6]3+

(S) 4 2
t 2g eg (4) [FeCl4]–

(5) [CoCl4]2–
(A) P  1; Q  4; R  2; S  3 (B) P  1; Q  2; R  4; S  5
(C) P  3; Q  2; R 5; S  1 (D) P  3; Q  2; R  4; S  1

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16. Match the reactions in List-I with the features of their products in List-II and choose the correct
option.
List-I List-II
(P) (-)-1-Bromo-2-ethylpentane aq. NaOH (1) Inversion of configuration
(single enantiomer) SN2 reaction

(Q) (-)-2-Bromopentane aq. NaOH (2) Retention of configuration

(single enantiomer) SN2 reaction
(R) (-)-3-Bromo-3-methylhexane aq. NaOH (3) Mixture of enantiomers
(single enantiomer) SN1 reaction
(S) (4) Mixture of structural isomers
aq. NaOH
Me H Me Br

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SN1 reaction
(Single enantiomer)
(5) Mixture of diastereomers
(A) P  1; Q  2; R  5; S  3 (B) P  2; Q  1; R  3; S  5
(C) P  1; Q  2; R 5; S  4 (D) P  2; Q 4; R  3; S  5

17. The major products obtained from the reactions in List-II are the reactants for the named reactions
mentioned in List-I. Match List-I with List-II and choose the correct option.
List-I List-II
(P) Etard reaction (1) Zn Hg, HCl
Acetophenone 
(Q) Gattermann reaction (2) (i) KMnO4 ,KOH, 
Toluene  
(ii) SOCl2
(R) Gattermann-Koch reaction (3) Benzene CH3Cl
 
anhyd. AlCl3
(S) Rosenmund reduction (4) NaNO2 /HCl
Aniline  
273278 K
(5) Phenol  Zn, 
(A) P  2; Q  4; R  1; S  3
(B) P  1; Q  3; R  5; S  2
(C) P  3; Q  2; R  1; S  4
(D) P  3; Q  4; R  5; S  2