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At the anode of an acid electrolyte fuel cell the hydrogen gas ionizes,
releasing electrons and creating H+ ions (or protons).
2H2→4H+ + 4e-
This reaction releases energy. At the cathode, oxygen reacts with electrons
taken from the electrode, and H+ ions from the electrolyte, to form water.
O2 + 4e- +4h- →2H2O
Clearly, for both these reactions to proceed continuously, electrons
produced at the anode must pass through an electrical circuit to the
cathode.
Also, H+ ions must pass through the electrolyte.
An acid is a fluid with free H+ ions, and so serves this purpose very well.
Certain polymers can also be made to contain mobile H+ ions.
description of vehicle movement
-The vehicle motion can be completely determined by analyzing the forces
acting on it in the direction of motion. The forces acting on a vehicle,
moving up a grade, are shown in Figure.
-The tractive force (Ft) in the contact area between the tires of the driven
wheels and the road surface propels the vehicle forward.
-The tractive force (Ft) is produced by the power plant and transferred to
the driving wheels via the transmission and the final drive.
-When the vehicle moves, it encounters a resistive force that tries to retard
its motion. The resistive forces are
-Rolling resistance
-Aerodynamic drag
-Grading resistance
-Acceleration resistance
Rolling resistance
-The rolling resistance of tires on hard surfaces is due to hysteresis in the
tire material.
-a tire at a standstill. On this tire, a force (P) acts at its center. The pressure
in the contact area between the tire and the ground is distributed
symmetrically to the center line, and the resulting reaction force (Pz) is
aligned along P.
-When the tire rolls, the leading half of the contact area is loading and the
trailing half is unloading.
-Thus, the pressure on the leading half is greater than the pressure on the
trailing half.
-This phenomenon results in the ground reaction force shifting forward.
-The shift in the ground reaction force creates a moment that opposes
rolling of the wheels.
-The moment produced by forward shift of the resultant ground reaction
force is called rolling resistance moment and can expressed as
Tr=Pa=Mga
Tr=rolling resis,P=normal load acting on centre of rolling wheel
M=mass of vehicle g ,a=deformation of tyre
-To keeps the wheel rolling, a force Fr, acting on the centre of the wheel is
required to balance this rolling resistant moment. This force is expressed as
Fr=Tr/rdyn=Pa/rdyn=pfr
When a vehicle is moving up a gradient, the normal force (P), in equation is
replaced by the component that is perpendicular to the road surface.
Hence, equation is rewritten as Fr=pfrcosa=Mgfrcosa
Grading resistance
Fg=Mgsina
Acceleration resistance
Fa=(lam)Mdv/dt
lam=rotational inertia constant
Aerodynamic drag
-A vehicle traveling at a particular speed in air encounters a force resisting
its motion. This force is known as aerodynamic drag. The main causes of
aerodynamic drag are:
Shape drag
-The shape drag is due to the shape of the vehicle.
- The forward motion of the vehicle pushes the air in front of it.
- However, the air cannot instantaneously move out of the way and its
pressure is thus increased. This results in high air pressure in the front of
the vehicle.
-The air behind the vehicle cannot instantaneously fill the space left by the
forward motion of the vehicle. This creates a zone of low air pressure.
-Hence, the motion of the vehicle creates two zones of pressure.
-The high pressure zone in the front of the vehicle opposes its movement
by pushing. On the other hand, the low pressure zone developed at the rear
of the vehicle opposes its motion by pulling it backwards.
Skin effect
-The air close to the skin of the vehicle moves almost at the speed of the
vehicle while the air away from the vehicle remains still.
-Between these two layers (the air layer moving at the vehicle speed and
the static layer) the molecules move at a wide range of speeds.
-The difference in speed between two air molecules produces friction.
-This friction results in the second component of aerodynamic drag and it is
known as skin effect.
Fw=1/2pAfCdv^2
p=density of air
Af=vehicle frontal area
v=vehicle speed
Cd=drag coff
Total driving resistance
The traction force (Ft) required at the drive wheels is made up of the driving
resistance forces and is defined as Fresistance=Fr+Fw+Fg+Fa
Substituting the values of all the forces in above equation, gives
mathematical model
Fresistance=Mgf(r)cosa + ½(p)A(f)C(d)v^2+Mgsina+(lam)Mdv/dt
The above equation may be used to calculate the power required (Preq):
Preq=Fresistance*v
challenges:
1.Higher Weight: Hybrids often weigh more than conventional vehicles due
to components like batteries, electric motors, and supporting systems.
While their fuel-driven energy sources are smaller and lighter, the added
weight from these components can diminish efficiency, depending on the
storage mechanism and performance needs.
2.Electrical Losses: Energy losses occur due to bidirectional energy flows
within hybrid drivetrains. Electric motors, like internal combustion engines
(ICEs), are less efficient at low speeds and light loads, common in city
driving. Without careful component design and control strategies, these
losses can erode the theoretical efficiency gains.