Get Principles of Heating Ventilating and Air Conditioning 8th Edition Ronald Hunter Howell Free All Chapters
Get Principles of Heating Ventilating and Air Conditioning 8th Edition Ronald Hunter Howell Free All Chapters
https://ebookultra.com
https://ebookultra.com/download/principles-of-
heating-ventilating-and-air-conditioning-8th-
edition-ronald-hunter-howell/
https://ebookultra.com/download/audel-air-conditioning-home-and-
commercial-rex-miller/
ebookultra.com
https://ebookultra.com/download/refrigeration-and-air-
conditioning-1st-edition-ramesh-chandra-arora/
ebookultra.com
https://ebookultra.com/download/refrigeration-and-air-
conditioning-3rd-edition-c-p-arora/
ebookultra.com
https://ebookultra.com/download/principles-of-fourier-analysis-1st-
edition-kenneth-b-howell/
ebookultra.com
Principles and practices of commercial construction 8th ed
Edition Andres
https://ebookultra.com/download/principles-and-practices-of-
commercial-construction-8th-ed-edition-andres/
ebookultra.com
https://ebookultra.com/download/principles-of-economics-8th-edition-n-
gregory-mankiw/
ebookultra.com
https://ebookultra.com/download/principles-of-air-quality-
management-2nd-ed-edition-roger-d-griffin/
ebookultra.com
https://ebookultra.com/download/hematology-basic-principles-and-
practice-5th-edition-ronald-hoffman-md/
ebookultra.com
https://ebookultra.com/download/b-17-flying-fortress-units-of-the-8th-
air-force-part-2-martin-bowman/
ebookultra.com
Principles of Heating Ventilating and Air Conditioning
8th Edition Ronald Hunter Howell Digital Instant
Download
Author(s): Ronald Hunter Howell
ISBN(s): 9781939200730, 1939200733
Edition: 8
File Details: PDF, 27.33 MB
Year: 2017
Language: english
Principles of Heating, Ventilating, and Air Conditioning is a textbook based on the 2017 ASHRAE
Principles of HVAC
Handbook—Fundamentals. It contains the most current ASHRAE procedures and definitive, yet
easy to understand, treatment of building HVAC systems, from basic principles through design and
operation. Principles
of Heating
It is suitable both as a textbook and as a reference book for undergraduate engineering courses in
the field of air conditioning, heating, and ventilation; for similar courses at technical and vocational
schools; for continuing education and refresher short courses for engineers; and for adult education
courses for professionals other than engineers, especially when combined with ASHRAE Handbook—
Fundamentals.
The material is divided into three major sections: general concepts, Chapters 1–10; air-conditioning
Ventilating
and
systems, Chapters 11–16; and HVAC&R equipment, Chapters 17–20. There are several significant
changes in this revised edition. Chapter 4 has new values for climatic design information. Chapter 7
has been extensively revised with new design data. In addition, the chapters on system design and
equipment have been significantly revised to reflect recent changes and concepts in modern heating
and air-conditioning system practices.
This book includes access to a website containing the Radiant Time Series (RTS) Method Load
Air Conditioning
Calculation Spreadsheets, which are intended as an educational tool both for the student and for
the experienced engineer wishing to explore the RTS method. These spreadsheets allow the user to
perform RTS cooling load calculations for lights, people, equipment, walls/roofs, and fenestration
components using design day weather profiles for any month. Cooling and heating loads can be 8th Edition
calculated for individual rooms or block load zones. Twelve-month cooling calculations can be done
to determine the month and time of peak cooling load for each room or block load zone. In addition,
room/zone worksheets can be copied and modified within the spreadsheet to analyze as many rooms
or zones as desired; the number of rooms/zones is limited only by the available computer memory.
8th Edition
Based on the 2017 ASHRAE Handbook—Fundamentals
Ronald H. Howell
ASHRAE
1791 Tullie Circle
Atlanta, GA 30329-2305
404-636-8400 (worldwide)
Product
9 Code:200730
781939 90567 7/17
www.ashrae.org
Ronald H. Howell, PhD, PE, Fellow ASHRAE, retired as professor and chair of mechanical engineering at the Univer-
sity of South Florida and is also professor emeritus of the University of Missouri-Rolla. For 45 years he taught courses
in refrigeration, heating and air conditioning, thermal analysis, and related areas. He has been the principal or co-prin-
cipal investigator of 12 ASHRAE-funded research projects. His industrial and consulting engineering experience ranges
from ventilation and condensation problems to the development and implementation of a complete air curtain test
program.
The following authors contributed significantly to the textbook Principles of Heating, Ventilation, and Air Conditioning.
They recently passed away and were not part of the 2017 revisions.
William J. Coad, PE, Fellow ASHRAE, was ASHRAE president in 2001-2002. He was employed with McClure Engi-
neering Associates, St. Louis, Mo., for 45 years. He was also president of Coad Engineering Enterprises. He served as
a consultant to the Missouri state government and was a lecturer in mechanical engineering for 12 years and an affiliate
professor in the graduate program for 17 years at Washington University, St. Louis. He was the author of Energy Engi-
neering and Management for Building Systems (Van Nostrand Reinhold). Mr. Coad passed away in August 2014.
Harry J. Sauer, Jr., PhD, PE, Fellow ASHRAE, was a professor of mechanical and aerospace engineering at the Univer-
sity of Missouri-Rolla. He taught courses in air conditioning, refrigeration, environmental quality analysis and control,
and related areas. His research ranged from experimental boiling/condensing heat transfer and energy recovery equip-
ment for HVAC systems to computer simulations of building energy use and actual monitoring of residential energy use.
He served as an advisor to the Missouri state government and has conducted energy auditor training programs for the
US Department of Energy. Dr. Sauer passed away in June 2008.
PRINCIPLES
OF HEATING
VENTILATING
AND
AIR CONDITIONING
8th Edition
Ronald H. Howell
Atlanta
ISBN 978-1-939200-73-0 (hardback)
978-1-939200-74-7 (PDF)
ASHRAE is a registered trademark in the U.S. Patent and Trademark Office, owned by the American Society of Heating, Refriger-
ating and Air-Conditioning Engineers, Inc.
ASHRAE has compiled this publication with care, but ASHRAE has not investigated, and ASHRAE expressly disclaims any duty
to investigate, any product, service, process, procedure, design, or the like that may be described herein. The appearance of any
technical data or editorial material in this publication does not constitute endorsement, warranty, or guaranty by ASHRAE of any
product, service, process, procedure, design, or the like. ASHRAE does not warrant that the information in the publication is free
of errors, and ASHRAE does not necessarily agree with any statement or opinion in this publication. The entire risk of the use of
any information in this publication is assumed by the user.
No part of this publication may be reproduced without permission in writing from ASHRAE, except by a reviewer who may quote
brief passages or reproduce illustrations in a review with appropriate credit, nor may any part of this publication be reproduced,
stored in a retrieval system, or transmitted in any way or by any means—electronic, photocopying, recording, or other—without
permission in writing from ASHRAE. Requests for permission should be submitted at www.ashrae.org/permissions.
Index 593
This book includes access to a website containing the Radiant Time Series (RTS) Method Load
Calculation Spreadsheets. See www.ashrae.org/PHVAC8.
PREFACE
Principles of Heating, Ventilating, and Air Conditioning, a textbook based on the 2017 ASHRAE
Handbook—Fundamentals, should provide an attractive text for air-conditioning courses at engi-
neering colleges and technical institutes. The text has been developed to give broad and current cov-
erage of the heating, ventilation, and air-conditioning field when combined with the 2017 ASHRAE
Handbook—Fundamentals.
The book should prove most suitable as a textbook and subsequent reference book for (a) under-
graduate engineering courses in the general field of HVAC, (b) similar courses at technical institutes,
(c) continuing education and refresher short courses for engineers, and (d) adult education courses
for nonengineers. It contains more material than can normally be covered in a one-semester course.
However, several different single-semester or shorter courses can be easily planned by merely elim-
inating the chapters and/or parts that are least applicable to the objectives of the particular course.
This text will also readily aid in self-instruction of the 2017 ASHRAE Handbook—Fundamentals by
engineers wishing to develop their competence in the HVAC&R field.
Although numerous references are made to the other ASHRAE Handbook volumes, sufficient
material has been included from these to make this text complete enough for various courses in the
HVAC&R field. The material covered for various audiences in regular university courses, technical
institute courses, and short courses can and will vary greatly. This textbook needed to be complete
to satisfy all of these anticipated uses and needs. Toward this end, the following major sections are
included:
Part I General Concepts, Chapters 1–10
Part II Air-Conditioning Systems, Chapters 11–16
Part III HVAC&R Equipment, Chapters 17–20
Although the 2017 ASHRAE Handbook—Fundamentals is published in an SI edition, which uses
international units, and an inch-pound (I-P) edition, this single version of Principles of Heating, Ven-
tilating, and Air Conditioning is designed to serve the I-P edition with some SI interspersed through-
out.
There are several significant changes in this edition. Chapter 4 has new values for climatic design
information. Chapter 7 has been extensively revised with new design data. These changes make Prin-
ciples compatible with the 2017 ASHRAE Handbook—Fundamentals. In addition, the chapters on
system design and equipment have been significantly revised to reflect recent changes and concepts
in contemporary heating and air-conditioning system practices. Also, the Solutions Manual has been
extensively edited.
A particular point of confusion must be pointed out. Because this book was developed to be used
with the ASHRAE Handbook’s Fundamentals volume, a number of tables and figures have been
reproduced in the original form, complete with references to material elsewhere in Fundamentals
(not in this book). Thus, if the subheading in the table or figure indicates that it is a Fundamentals
table or figure, then all references to other locations, equations, tables, etc., refer to those in Funda-
mentals, not in Principles.
Dr. Harry Sauer, Jr., one of the co-authors of this textbook, passed away in June 2008. Likewise,
William J. Coad was also a co-author of this textbook and passed away in August 2014. Both Dr.
Sauer and Mr. Coad made significant contributions to the book.
BACKGROUND
This chapter provides a brief background on the heating, ventilating, air-conditioning, and refrigeration (HVAC&R)
field and industry, including the early history and some significant developments. An introduction to a few basic concepts
is included along with suggestions for further reading.
11. Ventilation requirements for the structure. Does it Committee. These excerpts provide a synopsis of the history
require 100% outdoor air, a given number of CFM per of environmental control.
person, or a given number of CFM per square foot of Obviously, the earliest form of heating was the open fire.
floor area? The addition of a chimney to carry away combustion
12. Local and/or national codes relating to ventilation, byproducts was the first important step in the evolution of
gas, and/or electric piping. heating systems. By the time of the Romans, there was suf-
13. Outside design temperatures and wind velocities for ficient knowledge of ventilation to allow for the installation
the location. of ventilating and panel heating in baths. Leonardo da Vinci
14. The environmental conditions that are maintained. had invented a ventilating fan by the end of the 15th century.
Will fluctuations of these conditions with load be detri- Robert Boyle’s law was established in 1659; John Dalton’s
mental to the purpose served by the structure? in 1800. In 1775, Dr. William Cullen made ice by pumping
15. The heating and cooling loads (also consider the mois- a vacuum in a vessel of water. A few years later, Benjamin
ture load, air contaminants, and noise). Franklin wrote his treatise on Pennsylvania fireplaces,
16. The type of heating and cooling system to be used in detailing their construction, installation, and operation.
the structure. Is it forced air, circulated water, or direct Although warming and ventilating techniques had greatly
expansion? Will it be a multizone, single zone, reheat, improved by the 19th century, manufacturers were unable to
variable air volume, or another type of system? What exploit these techniques because
method of control will be used? Will a dedicated out-
door air system be considered? • Data available on such subjects as transmission coeffi-
17. The heating and cooling equipment size that will cients, air and water friction in pipes, and brine and ammo-
maintain the inside design conditions for the selected nia properties were sparse and unreliable.
outside design condition. Electric heat or fossil fuel? • Neither set design conditions nor reliable psychrometric
Mechanical vapor compression or absorption chiller? charts existed.
18. The advantages and disadvantages of oversizing and • A definitive rational theory that would permit perfor-
undersizing the equipment as applied to the structure. mance calculation and prediction of results had not yet
Survey any economic tradeoffs to be made. Should a been developed.
different type of unit be installed in order to reduce • Little was known about physical, thermodynamic, and
operating costs? Should a more sophisticated control fluid dynamic properties of air, water, brines, and refrig-
system be used to give more exact control of humidity erants.
and temperature or should an on-off cycle be used? Fuel • No authoritative information existed on heat transmission
economy as related to design will become an even more involving combustion, conduction, convection, radiation,
important factor in system selection and operation. evaporation, and condensation.
19. What is the estimated annual energy usage? • No credible performance information for manufactured
In general, no absolute rules dictate correct selections or equipment was available.
specifications for each of the above items, so only engineer- Thanks to Thomas Edison, the first electric power plant
ing estimates or educated guesses can be made. However, opened in New York in 1882, making it possible for the first
estimates must be based on sound fundamental principles time to have an inexpensive source of energy for residential
and concepts. This book presents a basic philosophy of envi- and commercial buildings.
ronmental control as well as the basic concepts of design.
These ideas relate directly to the ASHRAE Handbook series: 1.1.1 Furnaces
2014 Refrigeration, 2015 HVAC Applications, 2016 HVAC By 1894, the year the American Society of Heating and
Systems and Equipment, and most directly to 2017 Funda- Ventilating Engineers (ASH&VE) was born, central heating
mentals. was fairly well developed. The basic heat sources were
warm air furnaces and boilers. The combustion chambers of
1.2 Historical Notes the first warm air furnaces were made of cast iron. Circula-
tion in a gravity warm air furnace system is caused by the
Knowing something of the past helps in understanding difference in air density in the many parts of the system. As
current design criteria and trends. As in other fields of tech- the force of combustion is small, the system was designed to
nology, the accomplishments and failures of the past affect allow air to circulate freely. The addition of fans (circa 1899)
current and future design concepts. The following para- to furnace systems provided a mechanical means of air cir-
graphs consist mainly of edited excerpts from ASHRAE culation. Other additions to the modern furnace include
Journal articles: “A History of Heating” by John W. James, cooling systems, humidification apparatuses, air distribu-
“The History of Refrigeration” by Willis R. Woolrich, and tors, and air filters. Another important step for the modern
“Milestones in Air Conditioning” by Walter A. Grant, with heating industry was the conversion of furnaces from coal to
additional information obtained from ASHRAE’s Historical oil and gas, and from manual to automatic firing.
Chapter 1| Background 3
Figure 1-1 depicts ASHRAE’s history. ASHRAE cele- wet-bulb, and dew-point temperatures of air, as well as its sen-
brated its Centennial Year during society year 1994-1995. In sible, latent, and total heat load, and set forth the theory of adi-
commemoration of the centennial, two books on the history of abatic saturation. The formulas and psychrometric chart
ASHRAE and of the HVAC industry were published, Pro- presented in this paper became the basis for all fundamental
claiming the Truth and Heat and Cold: Mastering the Great calculations used by the air-conditioning industry.
Indoors. By 1922, Carrier’s centrifugal refrigeration machine,
together with the development of nonhazardous, low-pressure
1.1.6 Willis H. Carrier
refrigerants, made water chilling for large and medium-size
Willis H. Carrier (1876-1950) has often been referred to as commercial and industrial applications both economical and
the “Father of Air Conditioning.” His analytical and practical practical. A conduit induction system for multiroom build-
accomplishments contributed greatly to the development of ings, was invented in 1937 by Carrier and his associate, Car-
the refrigeration industry. lyle Ashley.
Carrier graduated from Cornell University in 1901 and was
employed by the Buffalo Forge Company. He realized that 1.1.7 Comfort Cooling
satisfactory refrigeration could not be installed due to the Although comfort air-cooling systems had been built as of
inaccurate data that were available. By 1902, he developed the 1890s, no real progress was made in mechanical air cool-
formulas to optimize forced-draft boiler fans, conducted tests ing until after the turn of the century. At that time, several sci-
and developed multirating performance tables on indirect entifically designed air-conditioning plants were installed in
pipe coil heaters, and set up the first research laboratory in the buildings. One such installation included a theater in
heating and ventilating industry. Cologne, Germany. In 1902, Alfred Wolff designed a 400-ton
In 1902, Carrier was asked to solve the problem faced by system for the New York Stock Exchange. Installed in 1902,
the lithographic industry of poor color register caused by this system was in operation for 20 years. The Boston Float-
weather changes. Carrier’s solution was to design, test, and ing Hospital, in 1908, was the first hospital to be equipped
install at the Sackett-Wilhelms Lithographing Company of with modern air conditioning. Mechanical air cooling was
Brooklyn a scientifically engineered, year-round air-condi- installed in a Texas church in 1914. In 1922, Grauman’s Met-
tioning system that provided heating, cooling, humidifying, ropolitan Theater, the first air-conditioned movie theater,
and dehumidifying. opened in Los Angeles. The first office building designed
By 1904, Carrier had adapted atomizing nozzles and devel- with and built for comfort air-conditioning specifications was
oped eliminators for air washers to control dew-point tem- the Milam Building, in San Antonio, Texas, which was com-
perature by heating or cooling a system’s recirculated water. pleted in 1928. Also in 1928, the Chamber of the House of
Soon after this development, over 200 industries were using Representatives became air conditioned. The Senate became
year-round air conditioning. air conditioned the following year and in 1930, the White
At the 1911 ASME meeting, Carrier presented his paper, House and the Executive Office Building were air-condi-
“Rational Psychrometric Formulae,” which related dry-bulb, tioned.
The system of air bypass control, invented in 1924 by L.
Logan Lewis, solved the difficult problem of humidity control
under varying load. By the end of the 1920s, the first room air
conditioner was introduced by Frigidaire. Other important
inventions of the 1920s include lightweight extended surface
coils and the first unit heater and cold diffuser.
Thomas Midgley, Jr. developed the halocarbon refrigerants
in 1930. These refrigerants were found to be safe and eco-
nomical for the small reciprocating compressors used in com-
mercial and residential markets. Manufacturers were soon
producing mass market room air conditioners that used
Refrigerant 12.
Fluorinated refrigerants were also applied to centrifugal
compression, which required only half the number of impel-
lers for the same head as chlorinated hydrocarbons. Space and
materials were saved when pressure-formed extended-surface
tubes in shell-and-tube exchangers were introduced by Walter
Jones. This invention was an important advance for centrifu-
gal and reciprocating equipment.
Other achievements of the 1930s included
• The first residential lithium bromide absorption machine
Fig. 1-1 Background of ASHRAE was introduced in 1931 by Servel.
Chapter 1| Background 5
• In 1931, Carrier marketed steam ejector cooling units for designs rapidly became the most popular type of HVAC
railroad passenger cars. system for offices, hospitals, and some school buildings.
• As of the mid-1930s, General Electric introduced the heat Although energy-efficient, VAV systems proved to have their
pump; the electrostatic air cleaner was put out by Westing- own set of problems related to indoor air quality (IAQ), sick
house; Charles Neeson of Airtemp invented the high-speed building syndrome (SBS), and building related illness (BRI).
radial compressor; and W.B. Connor discovered that odors Solutions to these problems are only now being realized.
could be removed by using activated carbon. In 1987, the United Nations Montreal Protocol for protect-
ing the earth’s ozone layer was signed, establishing the phase-
With the end of World War II, air-conditioning technology
out schedule for the production of chlorofluorocarbon (CFC)
advanced rapidly. Among the advances were air-source heat
and hydrochlorofluorocarbon (HCFC) refrigerants. Contem-
pumps, large lithium-bromide water chillers, automobile air
porary buildings and their air-conditioning equipment must
conditioners, rooftop heating and cooling units, small, out-
now provide improved indoor air quality as well as comfort,
door-installed ammonia absorption chillers, air purifiers, a
while consuming less energy and using alternative refriger-
vapor cycle aircraft cabin cooling unit, and a large-capacity
ants.
Lysholm rotary compressor.
Improvements on and expansions of products that already
existed include 1.3 Building Energy Use
• Dual-duct central systems for office buildings Energy is generally used in buildings to perform functions
• Change from open to hermetic compressors from the small- of heating, lighting, mechanical drives, cooling, and special
est reciprocating units to large-capacity centrifugals applications. A typical breakdown of the relative energy use
• Resurgence of electric heating in all kinds of applications in a commercial building is given as Figure 1-2.
• Use of heat pumps to reclaim heat in large buildings Energy is available in limited forms, such as electricity,
• Application of electrostatic cleaners to residences fossil fuels, and solar energy, and these energy forms must be
• Self-contained variable volume air terminals for multiple converted within a building to serve the end use of the various
interior rooms functions. A degradation of energy is associated with any con-
• Increasing use of total energy systems for large buildings version process. In energy conservation efforts, two avenues
and clusters of buildings of approach were taken: (1) reducing the amount of use and/or
• Larger sizes of centrifugals, now over 5000 tons in a single (2) reducing conversion losses. For example, the furnace that
unit heats a building produces unusable and toxic flue gas that
• Central heating and cooling plants for shopping centers, must be vented to the outside and in this process some of the
colleges, and apartment and office building complexes energy is lost. Table 1-1 presents typical values for building
In the late 1940s and into the early 1950s, development heat losses and gains at design conditions for a mid-America
work continued on unitary heat pumps for residential and climate. Actual values will vary significantly with climate and
small commercial installations. These factory-engineered and building construction.
assembled units, like conventional domestic boilers, could be The projected total U.S. energy consumption by end-user
easily and cheaply installed in the home or small commercial sector: transportation, industrial, commercial, and residential
businesses by engineers. In 1952, heat pumps were placed on is shown in Figure 1-3. The per capita energy consumption for
the market for mass consumption. Early heat pumps lacked the U.S. and the world is shown in Figure 1-4, showing that in
the durability needed to withstand winter temperatures. Low 2007 the U.S. consumption was the same as in 1965. This has
winter temperatures placed severe stress on the components
of these heat pumps (compressors, outdoor fans, reversing
valves, and control hardware). Improvements in the design of
heat pumps has continued, resulting in more-reliable com-
pressors and lubricating systems, improved reversing valves,
and refined control systems.
In the 1950s came the rooftop unit for commercial build-
ings. Multizone packaged rooftop units were popular during
the 1960s; however, most were very energy inefficient and
lost favor during the 1970s. Beginning with the oil embargo of
1973, the air-conditioning field could no longer conduct
“business as usual,” with concern mainly for the initial cost of
the building and its conditioning equipment. The use of crude
rules of thumb, which significantly oversized equipment and
wasted energy, was largely replaced with reliance upon more
scientifically sound, and often computer-assisted, design,
sizing, and selection procedures. Variable air volume (VAV) Fig. 1-2 Energy Use in a Commercial Building
6 Principles of HVAC, 8th Edition
been achieved through application of energy conservation ponent, system, or subsystem within a building; and (3) build-
principles as well as increased energy costs and changes in the ing energy, which considers the performance of the building
economy. as a whole. In this last type, a design goal is set for the annual
The efficient use of energy in buildings can be achieved by energy requirements of the entire building on basis such as
implementing (1) optimum energy designs, (2) well-devel- Btu/ft2 per year (GJ/m2 per year). Any combination of mate-
oped energy use policies, and (3) dedicated management rials, systems, and operating procedures can be applied, as
backed up by a properly trained and motivated operating staff. long as design energy usage does not exceed the building’s
Optimum energy conservation is attained when the least annual energy budget goal. “Standard 90.1-2013 User’s Man-
amount of energy is used to achieve a desired result. If this is ual” is extremely helpful in understanding and applying the
not fully realizable, the next best method is to move excess requirements of ASHRAE Standard 90.1
energy from where it is not wanted to where it can be used or This approach allows greater flexibility while promoting
stored for future use, which generally results in a minimum the goals of energy efficiency. It also allows and encourages
expenditure of new energy. A system should be designed so the use of innovative techniques and the development of new
that it cannot heat and cool the same locations simultaneously. methods for saving energy. Means for its implementation are
ASHRAE Standard 90.1-2013, “Energy Standard for still being developed. They are different for new and for exist-
Buildings Except Low-Rise Residential Buildings,” and the ing buildings; in both cases, an accurate data base is required
100-2015 series standards, “Energy Conservation in Existing as well as an accurate, verifiable means of measuring con-
Buildings,” provide minimum guidelines for energy conser- sumption.
vation design and operation. They incorporate these types of As energy prices have risen, more sophisticated schemes
energy standards: (1) prescriptive, which specifies the mate- for reducing energy consumption have been conceived.
rials and methods for design and construction of buildings; (2) Included in such schemes are cogeneration, energy manage-
system performance, which sets requirements for each com- ment systems (EMS), direct digital control (DDS), daylight-
ing, closed water-loop heat pumps, variable air volume (VAV)
Table 1-1 Typical Building Design Heat Losses or Gains
systems, variable frequency drives, thermal storage, dessicant
Air Conditioning Heating dehumidication, and heat recovery in commercial and institu-
Building Type ft2/ton m2/kW Btu/h·ft3 W/m3 tional buildings and industrial plants.
Apartment 450 12 4.5 45 As detailed in a 1992 Department of Energy Report,
Bank 250 7 3.0 30 “Commercial Buildings Consumption and Expenditures,
Department Store 250 7 1.0 10 1989,” more than seventy percent of the commercial-indus-
Dormitories 450 12 4.5 45 trial-institutional (C-I-I) buildings recently built in the United
House 700 18 3.0 30 States made use of energy conservation measures for heating
Medical Center 300 8 4.5 45
and cooling.
Night Club 250 7 3.0 30
The type of building and its use strongly affects the energy
Office Interior 350 9 3.0 30
Exterior 275 7 3.0 30
use as shown in Table 1-2.
Post Office 250 7 3.0 30 Heating and air-conditioning systems that are simple in
Restaurant 250 7 3.0 30 design and of the proper size for a given building generally
Schools 275 7 3.0 30 have relatively low maintenance and operating costs. For opti-
Shopping Center 250 7 3.0 30 mum results, as much inherent thermal control as is econom-
ically possible should be built into the basic structure. Such
control might include materials with high thermal properties, the use of 2.5 gpm/ton for determining the water flow rate
insulation, and multiple or special glazing and shading through the cooling coil and chiller unit, using 1.2 cfm/sq ft of
devices. The relationship between the shape, orientation, and gross floor area for estimating the required conditioned air-
air-conditioning requirement of a building should also be con- flow rate for comfort cooling, and the estimation of 0.6
sidered. Since the exterior load may vary from 30 to 60% of kW/ton as the power requirement for air conditioning. Table
the total air-conditioning load when the fenestration (light 1-3 provides very approximate data related to the cost of
transmitting) area ranges from 25 to 75% of the floor area, it HVAC equipment and systems.
may be desirable to minimize the perimeter area. For exam- Table 1.4 provides approximate energy costs for commer-
ple, a rectangular building with a 4-to-1 aspect ratio requires cial consumers in the United States for 2015. Keep in mind
substantially more refrigeration than a square building with that these energy costs are very volatile at this time.
the same floor area. Table 1.5 gives approximate total building costs for offices
When a structure is characterized by several exposures and and medical offices averaged for twenty U.S. locations in 2007.
multipurpose use, especially with wide load swings and non- The material presented in this book will enable the reader
coincident energy use in certain areas, multiunit or unitary to validate appropriate rules as well as to improve upon these
systems may be considered for such areas, but not necessarily approximations for the final design.
for the entire building. The benefits of transferring heat
absorbed by cooling from one area to other areas, processes, 1.5 Sustainability and Green Buildings
or services that require heat may enhance the selection of such
systems. The following discussion concerning sustainable design
Buildings in the US consume significant quantities of and green buildings has been extracted from Chapters 34 and
energy each year. According to the US Department of Energy 35 of the 2017 ASHRAE Handbook—Fundamentals.
(DOE), buildings account for 36% of all the energy used in the Pollution, toxic waste creation, waste disposal, global cli-
US, and 66% of all the electricity used. Beyond economics, mate change, ozone depletion, deforestation, and resource
energy use in the buildings sector has significant implications depletion are recognized as results of uncontrolled technolog-
for our environment. Emissions related to building energy use ical and population growth. Without mitigation, current
account for 35% of carbon dioxide emissions, 47% of sulfur trends will adversely affect the ability of the earth’s ecosystem
dioxide emissions, and 22% of nitrogen oxide emissions. to regenerate and remain viable for future generations.
The built environment contributes significantly to these
1.4 Conceptualizing an HVAC System effects, accounting for one-sixth of the world’s fresh water
use, one-quarter of its wood harvest, and two-fifths of its
An important tool for the HVAC design engineer is the material and energy flows. Air quality, transportation pat-
ability to develop a quick overview or “concept” of the mag- terns, and watersheds are also affected. The resources
nitude of the project at hand. Toward this goal, the industry required to serve this sector are considerable and many of
has developed a number of “rules of thumb,” some more accu- them are diminishing.
rate than others. As handy as they might be, these approxima-
Table 1-3 Capital Cost Estimating Factors
tions must be treated as just that—approximations. Don’t use
them as “rules of dumb.” Cooling Systems
• $1675/installed ton of cooling
Tables 1-1 and 1-2 are examples of such rules-of-thumb,
Heating Systems
providing data for a quick estimate of heating and cooling • $2.92/cfm of installed heating
equipment sizes and of building energy use, requiring knowl- Fans/Ducting/Coils/Dampers/Filters
edge only of the size and intended use of the building. Other • $7.84/cfm all-system
rules-of-thumb include using a face velocity of 500 fpm in
determining the face area for a cooling coil, the use of Table 1-4 Approximate Energy Costs
to Commercial Consumers (2015)
400 cfm/ton for estimating the required cooling airflow rate,
Electricity ($/kWh) 0.090
Table 1-2 Annual Energy Use Per Unit Floor Area Natural Gas ($/therm) 0.84
LPG ($/gal) 2.95
Building Type Annual Energy Use kWh/ft2
No. 2 Fuel Oil ($/gas) 3.46
Assembly 18.7
Education 25.5
Table 1-5 Approximate Total Building Costs ($/sq. ft.)
Food Sales 51.5
(Adapted from RSMeans Costs Comparisons 2007)
Health Care 64.0
Lodging 38.8 2–4-Story 5–10-Story 11–20-Story Medical
Mercantile 24.8 Office Office Office Office
Office 30.5 Building Building Building Building
Warehouse 16.9 High 194 181 167 219
Vacant 6.9 Average 149 130 121 169
All Buildings 26.7 Low 117 110 98 132
8 Principles of HVAC, 8th Edition
Recognition of how the building industry affects the envi- • Installed lighting (overall) 0.8 W/ft2
ronment is changing the approach to design, construction, • Space sensible cooling 15 Btu/h·ft2
operation, maintenance, reuse, and demolition of buildings
• Space heating load 10 Btu/h·ft2
and focusing on environmental and long-term economic con-
sequences. Although this sustainable design ethic—sustain- • Electric power (overall) 3 W/ft2
ability—covers things beyond the HVAC industry alone, • Thermal power (overall) 20 Btu/h·ft2
efficient use of energy resources is certainly a key element of • Hydronic system head 70 ft of water
any sustainable design and is very much under the control of • Water chiller (water-cooled) 0.5 kW/ton
the HVAC designer. • Chilled-water system auxiliaries 0.15 kW/ton
Research over the years has shown that new commercial • Unitary air-conditioning systems 1.0 kW/ton
construction can reduce annual energy consumption by about • Annual electric energy 15 kWh/ft2·yr
50% using integrated design procedures and energy conserva-
• Annual thermal energy 5 Btu/ft2·yr·°F·day
tion techniques. In the past few years several programs pro-
moting energy efficiency in building design and operation These goals, however, may not be realistic for all projects.
have been developed. One of these is Energy Star Label As the building and systems are designed, all decisions
(www.energystar.gov) and another one, which is becoming become interactive as the result of each subsystem’s power or
well known, is Leadership in Energy and Environmental energy performance being continually compared to the “bud-
Design (LEED) (www.usgbc.org/leed). get.”
In 1999 the Environmental Protection Agency of the US Energy efficiency should be considered at the beginning
government introduced the Energy Star Label for buildings. of building design because energy-efficient features are most
This is a set of performance standards that compare a build- easily and effectively incorporated at that time. Active par-
ing’s adjusted energy use to that of similar buildings nation- ticipation of all members of the design team (including
wide. The buildings that perform in the top 25%, while owner, architect, engineer, and often the contractor) should
conforming to standards for temperature, humidity, illumina- be sought early. Consider building attributes such as building
tion, outdoor air requirements, and air cleanliness, earn the function, form, orientation, window/wall ratio, and HVAC
Energy Star Label. system types early because each has major energy implica-
LEED is a voluntary points-based national standard for tions.
developing a high-performance building using an integrated
design process. LEED evaluates “greenness” in five catego-
ries: sustainable sites, water efficiency, energy and atmo-
1.6 Problems
sphere, materials and resources, and the indoor air
environmental quality. 1.1 Estimate whether ice will form on a clear night when
In the energy and atmosphere category, building systems ambient air temperature is 45°F (7.2°C), if the water is placed
commissioning and minimum energy usages are necessary in a shallow pan in a sheltered location where the convective
requirements. The latter requires meeting the requirements heat transfer coefficient is 0.5 Btu/h·ft2 ·°F [2.8 W/(m2 ·K)].
ANSI/ASHRAE/IESNA Standard 90.1-2013, Energy Standard 1.2 Obtain a sketch or drawing of Gorrie’s refrigeration
for Buildings Except Low-Rise Residential Buildings, or the machine and describe its operation.
local energy code, whichever is more stringent. 1.3 Plot the history of the annual energy use per square foot
Basically LEED defines what makes a building “green” of floor space for nonresidential buildings and predict the
while the Energy Star Label is concerned only with energy values for the years 2014 and 2015.
performance. Both of these programs require adherence to 1.4 Estimate the size of cooling and heating equipment that
ASHRAE standards. Chapter 35 of the 2017 ASHRAE Hand- is needed for a new bank building in middle America that is
book—Fundamentals provides guidance in achieving sustain- 140 ft by 220 ft by 12 ft high (42.7 m by 67 m by 3.7 m high).
able designs. [Answer: 123 tons cooling, 11,109,000 Btu/h heating]
The basic approach to energy-efficient design is reducing 1.5 Estimate the size of heating and cooling equipment that
loads (power), improving transport systems, and providing will be needed for a residence in middle America that is 28 ft
efficient components and “intelligent” controls. Important by 78 ft by 8 ft high (8.5 m by 23.8 m by 2.4 m high).
design concepts include understanding the relationship 1.6 Estimate the initial cost of the complete HVAC system
between energy and power, maintaining simplicity, using self- (heating, cooling, and air moving) for an office building,
imposed budgets, and applying energy-smart design prac- 40 ft by 150 ft by 10 ft high (12.2 m by 45.7 m by 3.1 m high).
tices. 1.7 Estimate the annual operating cost for the building in
Just as an engineer must work to a cost budget with most Problem 1.6 if it is all-electric. [Answer: $14,640]
designs, self-imposed power budgets can be similarly helpful 1.8 Conceptualize, as completely as possible, using infor-
in achieving energy-efficient design. For example, the follow- mation only from Sections 1.3, 1.4, and 1.5, the building of
ing are possible goals for mid-rise to high-rise office buildings Project 8 Two-Story Building, Appendix B, Systems Design
in a typical midwestern or northeastern temperature climate: Problems.
Chapter 1| Background 9
2.1 Fundamental Concepts and making it available, as entropy will have reached its maxi-
Principles mum value.
Like all sciences, the basis of thermodynamics is experi-
2.1.1 Thermodynamics mental observation. Findings from these experimental obser-
vations have been formalized into basic laws. In the sections
Thermodynamics is the science devoted to the study of that follow, these laws and their related thermodynamic prop-
energy, its transformations, and its relation to status of matter. erties will be presented and applied to various examples.
Since every engineering operation involves an interaction These examples should give the student an understanding of
between energy and materials, the principles of thermody- the basic concepts and an ability to apply these fundamentals
namics can be found in all engineering activities. to thermodynamic problems. It is not necessary to memorize
Thermodynamics may be considered the description of the numerous equations, for problems are best solved by applying
behavior of matter in equilibrium and its changes from one the definitions and laws of thermodynamics.
equilibrium state to another. The important concepts of ther- Thermodynamic reasoning is always from the general law
modynamics are energy and entropy; the two major principles to the specific case; that is, the reasoning is deductive rather
of thermodynamics are called the first and second laws of than inductive. To illustrate the elements of thermodynamic
thermodynamics. The first law of thermodynamics deals with reasoning, the analytical processes may be divided into two
energy. The idea of energy represents the attempt to find an steps:
invariant in the physical universe, something that remains
constant in the midst of change. The second law of thermody- 1. The idealization or substitution of an analytical model for
namics explains the concept of entropy; e.g., every naturally a real system. This step is taken in all engineering sciences.
occurring transformation of energy is accompanied some- Therefore, skill in making idealizations is an essential part
where by a loss in the availability of energy for future perfor- of the engineering art.
mance of work. 2. The second step, unique to thermodynamics, is the
The German physicist, Rudolf Clausius (1822–1888), deductive reasoning from the first and second laws of
devised the concept of entropy to quantitatively describe the thermodynamics.
loss of available energy in all naturally occurring transforma- These steps involve (a) an energy balance, (b) a suitable
tions. Although the natural tendency is for heat to flow from properties relation, and (c) accounting for entropy changes.
a hot to a colder body with which it is in contact, correspond-
ing to an increase in entropy, it is possible to make heat flow 2.1.2 System and Surroundings
from a colder body to a hot body, as is done every day in a Most applications of thermodynamics require the defini-
refrigerator. However, this does not take place naturally or tion of a system and its surroundings. A system can be an
without effort exerted somewhere. object, any quantity of matter, or any region of space selected
According to the fundamental principles of thermodynam- for study and set apart (mentally) from everything else, which
ics, the energy of the world stays constant and the entropy of then becomes the surroundings. The systems of interest in
the world increases without limit. If the essence of the first thermodynamics are finite, and the point of view taken is mac-
principle in everyday life is that one cannot get something for roscopic rather than microscopic. No account is taken of the
nothing, the second principle emphasizes that every time one detailed structure of matter, and only the coarse characteris-
does get something, the opportunity to get that something in tics of the system, such as its temperature and pressure, are
the future is reduced by a measurable amount, until ulti- regarded as thermodynamic coordinates.
mately, there will be no more “getting.” This “heat death,” Everything external to the system is the surroundings, and
envisioned by Clausius, will be a time when the universe the system is separated from the surroundings by the system
reaches a level temperature; and though the total amount of boundaries. These boundaries may be either movable or fixed;
energy will be the same as ever, there will be no means of either real or imaginary.
12 Principles of HVAC, 8th Edition
2.1.3 Properties and State Thus the value of the integral depends solely on the initial
and final states. Likewise, the change in the value of a prop-
A property of a system is any observable characteristic of
erty depends only on the end states. Hence the differential
the system. The more common thermodynamic properties are
change dY in a property Y is an exact differential. Throughout
temperature, pressure, specific volume or density, internal
this text, the infinitesimal variation of a property will be iden-
energy, enthalpy, and entropy.
tified by the differential symbol d preceding the property sym-
The state of a system is its condition or configuration bol. For example, the infinitesimal change in the pressure p of
described in sufficient detail so that one state may be distin- a system is given by dp. The finite change in a property is
guished from all other states. A listing of a sufficient number denoted by the symbol (capital delta), for example, p. The
of independent properties constitutes a complete definition of change in a property value Y always represents the final
the state of a system. value minus the initial value. This convention must be kept in
The state may be identified or described by observable, mind.
macroscopic properties such as temperature, pressure, and The symbol is used instead of the usual differential oper-
density. Each property of a substance in a given state has only ator d as a reminder that some quantities depend on the pro-
one value; this property always has the same value for a given cess and are not a property of the system. Q represents only
state, regardless of how the substance arrived at that state. In a small quantity of heat, not a differential. m represents only
fact, a property can be defined as any quantity that depends on a small quantity of matter.
the state of the system and is independent of the path (i.e., the The same qualifications for hold in the case of thermo-
prior history) by which the system arrived at that given state. dynamic work. As there is no exact differential dW, small
Conversely, the state is specified or described by its properties. quantities of W similar in magnitude to differentials are
The state of a macroscopic system is the condition of the expressed as W.
system as characterized by the values of its properties. This
chapter directs attention to equilibrium states, with equilib- 2.1.4 Processes and Cycles
rium used in its generally accepted context—the equality of A process is a change in state which can be defined as any
forces, or the state of balance. In future discussion, the term change in the properties of a system. A process is described in
state refers to an equilibrium state unless otherwise noted. part by the series of states passed through by the system.
The concept of equilibrium is important, as it is only in an Often, but not always, some interaction between the system
equilibrium state that thermodynamic properties have mean- and surroundings occurs during a process; the specification of
ing. A system is in thermodynamic equilibrium if it is incapa- this interaction completes the description of the process.
ble of finite, spontaneous change to another state without a Describing a process typically involves specifying the ini-
finite change in the state of the surroundings. tial and final equilibrium states, the path (if identifiable), and
Included in the many types of equilibria are thermal, the interactions which take place across the boundaries of the
mechanical, and chemical. A system in thermal equilibrium is system during the process. The following terms define special
at the same temperature as the surroundings and the tempera- processes:
ture is the same throughout. A system in mechanical equilib- isobaric or constant pressure—process wherein the pressure
rium has no part accelerating ( F = 0) and the pressure within does not change;
the system is the same as in the surroundings. A system in
isothermal—process that occurs at constant temperature;
chemical equilibrium does not tend to undergo a chemical
reaction; the matter in the system is said to be inert. isometric—process with constant volume;
Any property of a thermodynamic system has a fixed value adiabatic—process in which no heat is transferred to or from
in a given equilibrium state, regardless of how the system the system;
arrives at that state. Therefore, the change that occurs in the
isentropic—process with no change in entropy.
value of a property when a system is altered from one equilib-
rium state to another is always the same. This is true regard- A cycle is a process, or more frequently, a series of pro-
less of the method used to bring about a change between the cesses wherein the initial and final states of the system are
two end states. The converse of this statement is equally true. identical. Therefore, at the conclusion of a cycle, all the prop-
If a measured quantity always has the same value between two erties have the same value they had at the beginning.
given states, that quantity is a measure of the change in a prop-
erty. This latter assertion is useful in connection with the con- 2.1.5 Reversibility
servation of energy principle introduced in the next section. All naturally occurring changes or processes are irrevers-
The uniqueness of a property value for a given state can be ible. Like a clock, they tend to run down and cannot rewind
described mathematically in the following manner. The inte- themselves without other changes in the surroundings occur-
gral of an exact differential dY is given by ring. Familiar examples are the transfer of heat with a finite
temperature difference, the mixing of two gases, a waterfall,
and a chemical reaction. All of the above changes can be
1 dY = Y 2 – Y 1 = Y
2
reversed, however. Heat can be transferred from a region of
Chapter 2 | Thermodynamics and Psychrometrics 13
low temperature to one of higher temperature; gas can be sep- conservation of mass and conservation of energy are treated
arated into its components; water can be forced to flow uphill. as separate laws in basic thermodynamics.
The important point is that these things can be done only at the The mass rate of flow of a fluid passing through a cross-
expense of some other system, which itself becomes run down. sectional area A is
A process is reversible if its direction can be reversed at
any stage by an infinitesimal change in external conditions. If m = AV v (2-1)
a connected series of equilibrium states is considered, each where V is the average velocity of the fluid in a direction nor-
representing only an infinitesimal displacement from the mal to the plane of the area A, and v is the specific volume of
adjacent one, but with the overall result a finite change, then the fluid. For steady flow with fluid entering a system at a sec-
a reversible process exists. tion 1 and leaving at a section 2,
All actual processes can be made to approach a reversible
process by a suitable choice of conditions; but like the absolute m1 = m2 = A1 V 1 v1 = A2 V 2 v2 (2-1a)
zero of temperature, the strictly reversible process is only a
concept that aids in the analysis of problems. The approach of This is the continuity equation of steady flow. It can readily
actual processes to this ideal limit can be made almost as close be extended to any number of system inlets and outlets and is
as is desired. However, the closeness of approach is generally used in nearly all energy analyses.
limited by economic factors rather than physical ones. The
truly reversible process would require an infinite time for com- 2.2 Properties of a Substance
pletion. The sole reason for the concept of the reversible pro-
cess is to establish a standard for the comparison of actual
2.2.1 Specific Volume and Density
processes. The reversible process is one that gives the maxi-
mum accomplishment, i.e., yields the greatest amount of work The specific volume of a substance v is the volume per unit
or requires the least amount of work to bring about a given mass. The density of a substance is the mass per unit vol-
change. It gives the maximum efficiency toward which to ume, and is therefore the reciprocal of the specific volume.
strive, but which will never be equalled. The reversible process Specific volume and density are intensive properties in that
is the standard for judging the efficiency of an actual process. they are independent of the size of the system.
Since the reversible process represents a succession of 2.2.2 Pressure
equilibrium states, each only a differential step from its neigh- When dealing with liquids and gases, we ordinarily speak
bor, the reversible process can be represented as a continuous of pressure; in solids we speak of stresses. The pressure in a
line on a state diagram (p-v, T-s, etc.). The irreversible process fluid at rest at a given point is the same in all directions. Pres-
cannot be so represented. The terminal states and general sure is defined as the normal component of force per unit area.
direction of change can be noted, but the complete path of Absolute pressure is the quantity of interest in most ther-
change is an indeterminate, irreversible process and cannot be modynamic investigations. Most pressure and vacuum gages,
drawn as a line on a thermodynamic diagram. however, read the difference between absolute pressure and
Irreversibilities always lower the efficiencies of processes. the atmospheric pressure existing at the gage (Figure 2-1).
Their effect is identical to that of friction, which is one cause
of irreversibility. Conversely, no process more efficient than a 2.2.3 Temperature
reversible process can be imagined. The reversible process Because temperature is difficult to define, equality of tem-
represents a standard of perfection that cannot be exceeded perature is defined instead. Two bodies have equality of tem-
because perature if no change in any observable property occurs
when they are in thermal communication.
1. It places an upper limit on the work that may be obtained
The zeroth law of thermodynamics states that when two
for a given work-producing process;
bodies have equality of temperature with a third body, they in
2. It places a lower limit on the work input for a given work-
turn have equality of temperature with each other. Since this
requiring process.
fact is not derivable from other laws, and since in the logical
2.1.6 Conservation of Mass presentation of thermodynamics it precedes the first and sec-
From relativistic considerations, mass m and energy E are ond laws of thermodynamics, it has been called the zeroth
related by the well-known equation: law of thermodynamics. This law is the basis of temperature
measurement. Every time a body has equality of temperature
2 with a thermometer, it is said that the body has the tempera-
E = mc
ture read on the thermometer. The problem remains, how-
where c = velocity of light. ever, of relating temperatures that might be read on different
This equation shows that the mass of a system does change thermometers, or that are obtained when different
when its energy changes. However, for other than nuclear temperature-measuring devices are used, such as thermocou-
reactions, the change is quite small and even the most accurate ples and resistance thermometers. The need for a standard
chemical balance cannot detect the change in mass. Thus, scale for temperature measurements is apparent.
14 Principles of HVAC, 8th Edition
2.2.5 Enthalpy
In analyzing specific types of processes, certain combina-
tions of thermodynamic properties, which are therefore also
properties of the substance undergoing the change of state, are
frequently encountered. One such combination is U + pV. It is
convenient to define a new extensive property, called enthalpy:
H = U + pV
or, per unit mass
h = u + pv (2-2)
As in the case of internal energy, specific enthalpy can be
referred to as h, and total enthalpy H. However, both may be
called enthalpy, since the context makes it clear which is
meant.
2.2.6 Entropy
Entropy S is a measure of the molecular disorder or of the
probability of a given state. The more disordered a system, the
Fig. 2-1 Terms Used in Pressure Measurement greater is its entropy; conversely, an orderly or unmixed con-
figuration is one of low entropy.
Fahrenheit and Celsius are two commonly used tempera- By applying the theory of probability to molecular sys-
ture measuring scales. The Celsius scale was formerly called tems, Boltzmann showed a simple relationship between the
the Centigrade scale. entropy of a given system of molecules and the probability of
In this text, the abbreviations °F and °C denote the Fahren- its occurrence. This relationship is given as
heit and Celsius scales, respectively. The symbols t and T are S = k lnW
both used in the literature for temperature on all temperature
scales. Unfortunately, little uniformity exists with nomencla- where k is the Boltzmann constant and W is the thermody-
ture in engineering. namic probability.
The absolute scale related to the Celsius scale is referred to Since entropy is the property used in quantifying the Sec-
as the Kelvin scale and is designated K. For SI units, the ond Law of Thermodynamics, additional discussion from a
degree sign is not used with the Kelvin scale. The relation classical thermodynamic viewpoint will be presented when
between the SI temperature scales is the Second Law is discussed.
be established for these primary dimensions, with each scale In this book, all equations that derive from Newton’s law
divided into specific units of size. The internationally carry the constant gc.
accepted base units for the six quantities are as follows:
2.2.9 Pure Substance
length metre (m) A pure substance is one that has a homogeneous and
mass kilogram (kg) invariable chemical composition. It may exist in more than
time second (s) one phase, but the chemical composition is the same in all
electric current ampere (A) phases. Thus, liquid water, a mixture of liquid water and water
thermodynamic temperature kelvin (K) vapor (steam), or a mixture of ice and liquid water are all pure
amount of substance mole (mol) substances, for every phase has the same chemical composi-
tion. On the other hand, a mixture of liquid air and gaseous air
Each of these has a precise definition according to interna- is not a pure substance, since the composition of the liquid
tional agreement. They form the basis for the SI from the phase is different from that of the vapor phase.
French document, Le Système International d’Unités (SI ), or Sometimes a mixture of gases is considered a pure sub-
International System of Units. stance as long as there is no change of phase. Strictly speak-
The mass of a system is often given by stating the number ing, this is not true. A mixture of gases, such as air, exhibits
of moles it contains. A mole is the mass of a chemical species some of the characteristics of a pure substance as long as there
equal numerically to its molecular mass. Thus, a kilogram is no change of phase.
mole of oxygen (O2) contains 32 kilograms. In addition, the Consider as a system that water is contained in the piston-
number of molecules in a kilogram mole is the same for all cylinder arrangement of Figure 2-2. Suppose that the piston
substances. This is also true for a gram mole, and in this case maintains a pressure of 14.7 lbf /in. (101.3 kPa) in the cylinder
the number of molecules is Avogadro’s number, equal to containing H2O, and that the initial temperature is 59°F
6.0225 1023 molecules. (15°C). As heat is transferred to the water, the temperature
Many derived units are important in thermodynamics. increases appreciably, the specific volume increases slightly,
Examples are force, pressure, and density. Force is deter- and the pressure remains constant. When the temperature
mined through Newton’s second law of motion, F = ma, and reaches 212°F (100°C), additional heat transfer results in a
has the basic unit (kg·m)/s2. The SI unit for this composite set change of phase. That is, some of the liquid becomes vapor,
is the newton (N). Pressure is defined as force per unit area and during this process both the temperature and pressure
(N/m2), called the pascal (Pa); and density is mass per unit remain constant, while the specific volume increases consid-
volume (kg/m3). erably. When the last drop of liquid has vaporized, further
The US customary engineering system of units also recog- heat transfer results in an increase in both temperature and
nizes the second as the basic unit of time, and the ampere as specific volume of the vapor.
the unit of current. However, absolute temperature is mea- Saturation temperature designates the temperature at
sured in degrees Rankine (°R). The foot (ft) is the usual unit which vaporization takes place at a given pressure; this pres-
of length and the pound mass (lbm) is the unit of mass. The sure is called the saturation pressure for the given tempera-
molar unit is the pound mole. ASHRAE calls this system the ture. Thus for water at 212°F (100°C), the saturation pressure
inch-pound (I-P) unit system. is 14.7 lbf /in.2 (101.3 kPa), and for water at 14.7 lbf /in.2
The unit of force, the pound force (lbf), is defined without (101.3 kPa), the saturation temperature is 212°F (100°C).
reference to Newton’s second law, so this law must be written If a substance exists as liquid at the saturation temperature
to include a dimensional proportionality constant: and pressure, it is called saturated liquid. If the temperature of
the liquid is lower than the saturation temperature for the
F = ma/gc existing pressure, it is called a subcooled liquid (implying that
the temperature is lower than the saturation temperature for
where gc is the proportionality constant. In the I-P system, the the given pressure) or a compressed liquid (implying that the
proportionality constant is pressure is greater than the saturation pressure for the given
gc = 32.174 (lbm/lbf)(ft/s2) temperature).
When a substance exists as part liquid and part vapor at the
The unit of density is lbm/ft3, and the unit of pressure is lbf /ft2 saturation temperature, its quality is defined as the ratio of the
or lbf /in2, often written psi. Pressure gages usually measure mass of vapor to the total mass. The quality may be consid-
pressure relative to atmospheric pressure. The term absolute ered as an intensive property, and it has the symbol x. Quality
pressure is often used to distinguish thermodynamic (actual) has meaning only when the substance is in a saturated state,
pressure (psia) from gage (relative) pressure (psig). i.e., at saturation pressure and temperature.
In SI units, the proportionality constant gc in Newton’s law If a substance exists as vapor at the saturation temperature,
is unity or it is called saturated vapor. (Sometimes the term dry saturated
vapor is used to emphasize that the quality is 100%.) When the
gc = 1 (kg/N)(m/s2) vapor is at a temperature greater than the saturation tempera-
16 Principles of HVAC, 8th Edition
The specific volume of a substance having a given quality The relation between the internal energy u and the tem-
can be found by using the definition of quality. Quality is perature can be established by using the definition of con-
defined as the ratio of the mass of vapor to total mass of liquid stant-volume specific heat given by
plus vapor when a substance is in a saturation state. Consider
a mass of 1 kg having a quality x. The specific volume is the c v = u T v
sum of the volume of the liquid and the volume of the vapor.
Since the internal energy of an ideal gas is not a function of
The volume of the liquid is (1 – x)vf , and the volume of the
volume, an ideal gas can be written as
vapor is xvg. Therefore, the specific volume v is
cv = du/dT
v = xvg + (1 – x)vf (2-5)
du = cv dt (2-10)
Since vf + vfg = vg, Equation 2-5 can also be written in the
following form: This equation is always valid for an ideal gas regardless of the
kind of process considered.
v = vf + xvfg (2-6) From the definition of enthalpy and the equation of state of
The same procedure is followed for determining the an ideal gas, it follows that
enthalpy and the entropy for quality conditions: h = u + pv = u + RT
h = xhg + (1 – x)hf (2-7) Since R is a constant and u is a function of temperature only,
the enthalpy h of an ideal gas is also a function of temperature
s = xsg + (1 – x)sf (2-8) only.
Internal energy can then be obtained from the definition of The relation between enthalpy and temperature is found
enthalpy as u = h – pv. from the constant pressure specific heat as defined by
If the substance is a compressed or subcooled liquid, the c p = h T p
thermodynamic properties of specific volume, enthalpy, inter-
nal energy, and entropy are strongly temperature dependent Since the enthalpy of an ideal gas is a function of the tempera-
(rather than pressure dependent). If compressed liquid tables ture only, and is independent of the pressure, it follows that
are unavailable, they may be approximated by the correspond-
cp = dh/dT
ing values for saturated liquid (vf , hf , uf , and sf ) at the existing
temperature. dh = cp dT (2-11)
In the superheat region, thermodynamic properties must be
obtained from superheat tables or a plot of the thermodynamic This equation is always valid for an ideal gas regardless of the
properties, called a Mollier diagram (Figure 2-4). kind of process considered.
The thermodynamic and transport properties of the refrig- Entropy, however, remains a function of both temperature
erants used in vapor compression systems are found in simi- and pressure, and is given by the equation
lar tables typified by Table 2-2, which is a section of the R- ds = cp(dT/T ) − R(dp/p) (2-12)
134a property tables from Chapter 30 of the 2017 ASHRAE
Handbook—Fundamentals. However, for these refrigerants where cp is frequently treated as being constant.
the common Mollier plot is the p-h diagram as illustrated in The ratio of heat capacities is often denoted by
Figure 2-5. k = cp/cv (2-13)
For fluids used in absorption refrigeration systems, the
thermodynamic properties are commonly found on a different and is a useful quantity in calculations for ideal gases. Ideal
type of plot—the enthalpy-concentration diagram, as illus- gas values for some common gases are listed in Table 2-3.
trated in Figure 2-6 for aqua-ammonia and in Figure 2-7 for No real gas exactly satisfies these equations over any finite
lithium-bromide/water. range of temperature and pressure. However, all real gases
approach ideal behavior at low pressures, and in the limit as
2.2.11 Property Equations for Ideal Gases p 0 do in fact meet the above requirements.
An ideal gas is defined as a gas at sufficiently low density Thus, in solving problems, ideal behavior is assumed in
so that intermolecular forces are negligible. As a result, an two cases. First, at very low pressures, ideal gas behavior can
ideal gas has the equation of state be assumed with good accuracy, regardless of the tempera-
pv = RT (2-9) ture. Second, at temperatures that are double the critical tem-
perature or above (the critical temperature of nitrogen is
For an ideal gas, the internal energy is a function of tem- 126 K), ideal gas behavior can be assumed with good accu-
perature only, which means that regardless of the pressure, an racy to pressures of at least 1000 lbf /in2 (7000 kPa). In the
ideal gas at a given temperature has a certain definite specific superheated vapor region, when the temperature is less than
internal energy u. twice the critical temperature and the pressure is above a very
Chapter 2 | Thermodynamics and Psychrometrics 23
Table 2-2 Refrigerant 134a Properties of Saturated Liquid and Saturated Vapor
(Table Refrigerant 134a, Chapter 30, 2017 ASHRAE Handbook—Fundamentals)
Enthalpy, Entropy, Specific Heat cp, Vel. of Sound, Viscosity, Thermal Cond.,
Pres- Density, Volume, Surface
Btu/lb Btu/lb·°F Btu/lb·°F cp/cv ft/s lbm/ft·h Btu/h·ft·°F
Temp.,* sure, lb/ft3 ft3/lb Tension, Temp.,*
°F psia Liquid Vapor Liquid Vapor Liquid Vapor Liquid Vapor Vapor Liquid Vapor Liquid Vapor Liquid Vapor dyne/cm °F
–153.94a 0.057 99.33 568.59 –32.992 80.362 –0.09154 0.27923 0.2829 0.1399 1.1637 3674. 416.0 5.262 0.0156 0.0840 0.00178 28.07 –153.94
–150.00 0.072 98.97 452.12 –31.878 80.907 –0.08791 0.27629 0.2830 0.1411 1.1623 3638. 418.3 4.790 0.0159 0.0832 0.00188 27.69 –150.00
–140.00 0.129 98.05 260.63 –29.046 82.304 –0.07891 0.26941 0.2834 0.1443 1.1589 3545. 424.2 3.880 0.0164 0.0813 0.00214 26.74 –140.00
–130.00 0.221 97.13 156.50 –26.208 83.725 –0.07017 0.26329 0.2842 0.1475 1.1559 3452. 429.9 3.238 0.0170 0.0794 0.00240 25.79 –130.00
–120.00 0.365 96.20 97.481 –23.360 85.168 –0.06166 0.25784 0.2853 0.1508 1.1532 3360. 435.5 2.762 0.0176 0.0775 0.00265 24.85 –120.00
–110.00 0.583 95.27 62.763 –20.500 86.629 –0.05337 0.25300 0.2866 0.1540 1.1509 3269. 440.8 2.396 0.0182 0.0757 0.00291 23.92 –110.00
–100.00 0.903 94.33 41.637 –17.626 88.107 –0.04527 0.24871 0.2881 0.1573 1.1490 3178. 446.0 2.105 0.0187 0.0739 0.00317 22.99 –100.00
–90.00 1.359 93.38 28.381 –14.736 89.599 –0.03734 0.24490 0.2898 0.1607 1.1475 3087. 450.9 1.869 0.0193 0.0722 0.00343 22.07 –90.00
–80.00 1.993 92.42 19.825 –11.829 91.103 –0.02959 0.24152 0.2916 0.1641 1.1465 2998. 455.6 1.673 0.0199 0.0705 0.00369 21.16 –80.00
–75.00 2.392 91.94 16.711 –10.368 91.858 –0.02577 0.23998 0.2925 0.1658 1.1462 2954. 457.8 1.587 0.0201 0.0696 0.00382 20.71 –75.00
–70.00 2.854 91.46 14.161 –8.903 92.614 –0.02198 0.23854 0.2935 0.1676 1.1460 2909. 460.0 1.509 0.0204 0.0688 0.00395 20.26 –70.00
–65.00 3.389 90.97 12.060 –7.432 93.372 –0.01824 0.23718 0.2945 0.1694 1.1459 2866. 462.1 1.436 0.0207 0.0680 0.00408 19.81 –65.00
–60.00 4.002 90.49 10.321 –5.957 94.131 –0.01452 0.23590 0.2955 0.1713 1.1460 2822. 464.1 1.369 0.0210 0.0671 0.00420 19.36 –60.00
–55.00 4.703 90.00 8.8733 –4.476 94.890 –0.01085 0.23470 0.2965 0.1731 1.1462 2778. 466.0 1.306 0.0212 0.0663 0.00433 18.92 –55.00
–50.00 5.501 89.50 7.6621 –2.989 95.650 –0.00720 0.23358 0.2976 0.1751 1.1466 2735. 467.8 1.248 0.0215 0.0655 0.00446 18.47 –50.00
–45.00 6.406 89.00 6.6438 –1.498 96.409 –0.00358 0.23252 0.2987 0.1770 1.1471 2691. 469.6 1.193 0.0218 0.0647 0.00460 18.03 –45.00
–40.00 7.427 88.50 5.7839 0.000 97.167 0.00000 0.23153 0.2999 0.1790 1.1478 2648. 471.2 1.142 0.0221 0.0639 0.00473 17.60 –40.00
–35.00 8.576 88.00 5.0544 1.503 97.924 0.00356 0.23060 0.3010 0.1811 1.1486 2605. 472.8 1.095 0.0223 0.0632 0.00486 17.16 –35.00
–30.00 9.862 87.49 4.4330 3.013 98.679 0.00708 0.22973 0.3022 0.1832 1.1496 2563. 474.2 1.050 0.0226 0.0624 0.00499 16.73 –30.00
–25.00 11.299 86.98 3.9014 4.529 99.433 0.01058 0.22892 0.3035 0.1853 1.1508 2520. 475.6 1.007 0.0229 0.0616 0.00512 16.30 –25.00
–20.00 12.898 86.47 3.4449 6.051 100.184 0.01406 0.22816 0.3047 0.1875 1.1521 2477. 476.8 0.968 0.0231 0.0608 0.00525 15.87 –20.00
–15.00 14.671 85.95 3.0514 7.580 100.932 0.01751 0.22744 0.3060 0.1898 1.1537 2435. 477.9 0.930 0.0234 0.0601 0.00538 15.44 –15.00
–14.93b 14.696 85.94 3.0465 7.600 100.942 0.01755 0.22743 0.3061 0.1898 1.1537 2434. 477.9 0.929 0.0234 0.0601 0.00538 15.44 –14.93
–10.00 16.632 85.43 2.7109 9.115 101.677 0.02093 0.22678 0.3074 0.1921 1.1554 2393. 478.9 0.894 0.0237 0.0593 0.00552 15.02 –10.00
–5.00 18.794 84.90 2.4154 10.657 102.419 0.02433 0.22615 0.3088 0.1945 1.1573 2350. 479.8 0.860 0.0240 0.0586 0.00565 14.60 –5.00
0.00 21.171 84.37 2.1579 12.207 103.156 0.02771 0.22557 0.3102 0.1969 1.1595 2308. 480.5 0.828 0.0242 0.0578 0.00578 14.18 0.00
5.00 23.777 83.83 1.9330 13.764 103.889 0.03107 0.22502 0.3117 0.1995 1.1619 2266. 481.1 0.798 0.0245 0.0571 0.00592 13.76 5.00
10.00 26.628 83.29 1.7357 15.328 104.617 0.03440 0.22451 0.3132 0.2021 1.1645 2224. 481.6 0.769 0.0248 0.0564 0.00605 13.35 10.00
15.00 29.739 82.74 1.5623 16.901 105.339 0.03772 0.22403 0.3147 0.2047 1.1674 2182. 482.0 0.741 0.0250 0.0556 0.00619 12.94 15.00
20.00 33.124 82.19 1.4094 18.481 106.056 0.04101 0.22359 0.3164 0.2075 1.1705 2140. 482.2 0.715 0.0253 0.0549 0.00632 12.53 20.00
25.00 36.800 81.63 1.2742 20.070 106.767 0.04429 0.22317 0.3181 0.2103 1.1740 2098. 482.2 0.689 0.0256 0.0542 0.00646 12.12 25.00
30.00 40.784 81.06 1.1543 21.667 107.471 0.04755 0.22278 0.3198 0.2132 1.1777 2056. 482.2 0.665 0.0258 0.0535 0.00660 11.72 30.00
35.00 45.092 80.49 1.0478 23.274 108.167 0.05079 0.22241 0.3216 0.2163 1.1818 2014. 481.9 0.642 0.0261 0.0528 0.00674 11.32 35.00
40.00 49.741 79.90 0.9528 24.890 108.856 0.05402 0.22207 0.3235 0.2194 1.1862 1973. 481.5 0.620 0.0264 0.0521 0.00688 10.92 40.00
45.00 54.749 79.32 0.8680 26.515 109.537 0.05724 0.22174 0.3255 0.2226 1.1910 1931. 481.0 0.598 0.0267 0.0514 0.00703 10.53 45.00
50.00 60.134 78.72 0.7920 28.150 110.209 0.06044 0.22144 0.3275 0.2260 1.1961 1889. 480.3 0.578 0.0270 0.0507 0.00717 10.14 50.00
55.00 65.913 78.11 0.7238 29.796 110.871 0.06362 0.22115 0.3297 0.2294 1.2018 1847. 479.4 0.558 0.0273 0.0500 0.00732 9.75 55.00
60.00 72.105 77.50 0.6625 31.452 111.524 0.06680 0.22088 0.3319 0.2331 1.2079 1805. 478.3 0.539 0.0275 0.0493 0.00747 9.36 60.00
65.00 78.729 76.87 0.6072 33.120 112.165 0.06996 0.22062 0.3343 0.2368 1.2145 1763. 477.0 0.520 0.0278 0.0486 0.00762 8.98 65.00
70.00 85.805 76.24 0.5572 34.799 112.796 0.07311 0.22037 0.3368 0.2408 1.2217 1721. 475.6 0.503 0.0281 0.0479 0.00777 8.60 70.00
75.00 93.351 75.59 0.5120 36.491 113.414 0.07626 0.22013 0.3394 0.2449 1.2296 1679. 474.0 0.485 0.0284 0.0472 0.00793 8.23 75.00
80.00 101.39 74.94 0.4710 38.195 114.019 0.07939 0.21989 0.3422 0.2492 1.2382 1636. 472.2 0.469 0.0287 0.0465 0.00809 7.86 80.00
85.00 109.93 74.27 0.4338 39.913 114.610 0.08252 0.21966 0.3451 0.2537 1.2475 1594. 470.1 0.453 0.0291 0.0458 0.00825 7.49 85.00
90.00 119.01 73.58 0.3999 41.645 115.186 0.08565 0.21944 0.3482 0.2585 1.2578 1551. 467.9 0.437 0.0294 0.0451 0.00842 7.13 90.00
95.00 128.65 72.88 0.3690 43.392 115.746 0.08877 0.21921 0.3515 0.2636 1.2690 1509. 465.4 0.422 0.0297 0.0444 0.00860 6.77 95.00
100.00 138.85 72.17 0.3407 45.155 116.289 0.09188 0.21898 0.3551 0.2690 1.2813 1466. 462.7 0.407 0.0301 0.0437 0.00878 6.41 100.00
105.00 149.65 71.44 0.3148 46.934 116.813 0.09500 0.21875 0.3589 0.2747 1.2950 1423. 459.8 0.393 0.0304 0.0431 0.00897 6.06 105.00
110.00 161.07 70.69 0.2911 48.731 117.317 0.09811 0.21851 0.3630 0.2809 1.3101 1380. 456.7 0.378 0.0308 0.0424 0.00916 5.71 110.00
115.00 173.14 69.93 0.2693 50.546 117.799 0.10123 0.21826 0.3675 0.2875 1.3268 1337. 453.2 0.365 0.0312 0.0417 0.00936 5.36 115.00
120.00 185.86 69.14 0.2493 52.382 118.258 0.10435 0.21800 0.3723 0.2948 1.3456 1294. 449.6 0.351 0.0316 0.0410 0.00958 5.03 120.00
125.00 199.28 68.32 0.2308 54.239 118.690 0.10748 0.21772 0.3775 0.3026 1.3666 1250. 445.6 0.338 0.0320 0.0403 0.00981 4.69 125.00
130.00 213.41 67.49 0.2137 56.119 119.095 0.11062 0.21742 0.3833 0.3112 1.3903 1206. 441.4 0.325 0.0324 0.0396 0.01005 4.36 130.00
135.00 228.28 66.62 0.1980 58.023 119.468 0.11376 0.21709 0.3897 0.3208 1.4173 1162. 436.8 0.313 0.0329 0.0389 0.01031 4.04 135.00
140.00 243.92 65.73 0.1833 59.954 119.807 0.11692 0.21673 0.3968 0.3315 1.4481 1117. 432.0 0.301 0.0334 0.0382 0.01058 3.72 140.00
145.00 260.36 64.80 0.1697 61.915 120.108 0.12010 0.21634 0.4048 0.3435 1.4837 1072. 426.8 0.288 0.0339 0.0375 0.01089 3.40 145.00
150.00 277.61 63.83 0.1571 63.908 120.366 0.12330 0.21591 0.4138 0.3571 1.5250 1027. 421.2 0.276 0.0344 0.0368 0.01122 3.09 150.00
155.00 295.73 62.82 0.1453 65.936 120.576 0.12653 0.21542 0.4242 0.3729 1.5738 980. 415.3 0.264 0.0350 0.0361 0.01158 2.79 155.00
160.00 314.73 61.76 0.1343 68.005 120.731 0.12979 0.21488 0.4362 0.3914 1.6318 934. 409.1 0.253 0.0357 0.0354 0.01199 2.50 160.00
165.00 334.65 60.65 0.1239 70.118 120.823 0.13309 0.21426 0.4504 0.4133 1.7022 886. 402.4 0.241 0.0364 0.0346 0.01245 2.21 165.00
170.00 355.53 59.47 0.1142 72.283 120.842 0.13644 0.21356 0.4675 0.4400 1.7889 837. 395.3 0.229 0.0372 0.0339 0.01297 1.93 170.00
175.00 377.41 58.21 0.1051 74.509 120.773 0.13985 0.21274 0.4887 0.4733 1.8984 786. 387.7 0.218 0.0381 0.0332 0.01358 1.66 175.00
180.00 400.34 56.86 0.0964 76.807 120.598 0.14334 0.21180 0.5156 0.5159 2.0405 734. 379.6 0.206 0.0391 0.0325 0.01430 1.39 180.00
185.00 424.36 55.38 0.0881 79.193 120.294 0.14693 0.21069 0.5512 0.5729 2.2321 680. 371.0 0.194 0.0403 0.0318 0.01516 1.14 185.00
190.00 449.52 53.76 0.0801 81.692 119.822 0.15066 0.20935 0.6012 0.6532 2.5041 624. 361.8 0.182 0.0417 0.0311 0.01623 0.90 190.00
195.00 475.91 51.91 0.0724 84.343 119.123 0.15459 0.20771 0.6768 0.7751 2.9192 565. 352.0 0.169 0.0435 0.0304 0.01760 0.67 195.00
200.00 503.59 49.76 0.0647 87.214 118.097 0.15880 0.20562 0.8062 0.9835 3.6309 502. 341.3 0.155 0.0457 0.0300 0.01949 0.45 200.00
205.00 532.68 47.08 0.0567 90.454 116.526 0.16353 0.20275 1.083 1.425 5.136 436. 329.4 0.140 0.0489 0.0300 0.02240 0.26 205.00
210.00 563.35 43.20 0.0477 94.530 113.746 0.16945 0.19814 2.113 3.008 10.512 363. 315.5 0.120 0.0543 0.0316 0.02848 0.09 210.00
213.91c 588.75 31.96 0.0313 103.894 103.894 0.18320 0.18320 • • 0. 0.0 – – • • 0.00 213.91
*Temperatures are on the ITS-90 scale a = triple point b = normal boiling point c = critical point
Chapter 2 | Thermodynamics and Psychrometrics 25
low value (e.g., atmospheric pressure), the deviation from of the mixture, then the volume of each component is also
ideal gas behavior may be considerable. In this region, tables Vm, or
of thermodynamic properties or charts for a particular sub-
stance should be used. Vm = Va = Vb = Vc (2-15)
2.2.12 Mixtures However, the volume of a mixture of ideal gases equals the
A large number of thermodynamic problems involve mix- sum of the volumes of its constituents if each existed alone at
tures of different pure substances. A pure substance is a sub- the temperature and pressure of the mixture. This property is
stance which is homogeneous and unchanging in chemical known as Amagat’s law, Leduc’s law, or the law of additive
composition. Homogeneous mixtures of gases that do not volumes. Like Dalton’s law, it is strictly true only for ideal
react with each other are therefore pure substances, and the gases, but holds approximately for real-gas mixtures, even
properties of such mixtures can be determined, correlated, those in some ranges of pressure and temperature where
and either tabulated or fitted by equations just like the prop- pv = RT is inaccurate. When the temperature of a real-gas
erties of any other pure substance. This work has been done mixture is well above the critical temperatures of all its con-
for common mixtures such as air and certain combustion stituents, the additive volume law is usually more accurate
products, but, as an unlimited number of mixtures is possible, than the additive pressure law.
properties of all of them cannot be determined experimentally For ideal-gas mixtures, volumetric analyses are frequently
and tabulated. Thus, it is important to be able to calculate the used. The volume fraction is defined as
properties of any mixture from the properties of its constitu-
ents. Such calculations are discussed in this section, first for
V a p m T m
gas mixtures and then for gas-vapor mixtures. Volume fraction of A = -----------------------------
-
Vm
Since individual gases can often be approximated as ideal
gases, the study of mixtures of ideal gases and their properties Volume of A existing alone at p m T m
is of considerable importance. Each constituent gas in a mix- = -------------------------------------------------------------------------------------------
-
Volume of mixture at p m T m
ture has its own pressure called the partial pressure of the
particular gas. The Gibbs-Dalton law states that in a mixture Note that in a gas mixture, each constituent occupies the
of ideal gases, the pressure of the mixture is equal to the sum total volume; thus volume fraction is not defined as the ratio
of the partial pressures of the individual constituent gases. In of a constituent volume to the mixture volume because this
equation form ratio is always unity.
pm = pa + pb + pc (2-14) Avogadro’s law goes on to state, equal volumes of ideal
gases held under exactly the same temperature and pressure
pa = pm (na /nm), pb = pm (nb /nm), pc = (nc /nm) have equal numbers of molecules. If Tm is the temperature of
the mixture,
where pm is the total pressure of the mixture of gases a, b, and
c, and pa, pb, and pc are the partial pressures. In a mixture of Tm = Ta = Tb = Tc (2-16)
ideal gases, the partial pressure of each constituent equals the
pressure that constituent would exert if it existed alone at the for the temperature relationship.
temperature and volume of the mixture. The analysis of a gas mixture based on mass is called a
Generally, in gas mixtures, each constituent gas behaves as gravimetric analysis. It is based on the fact that the mass of
though the other gases were not present; each gas occupies the a mixture equals the sum of the masses of its constituents:
total volume of the mixture at the temperature of the mixture
and the partial pressure of the gas. Thus, if Vm is the volume mm = ma + mb + mc (2-17)
30 Principles of HVAC, 8th Edition
where the subscript m refers to the mixture and the subscripts Psychrometrics is the science involving thermodynamic
a, b, and c refer to individual constituents of the mixture. The properties of moist air and the effect of atmospheric moisture
ratio ma/mm is called the mass fraction of constituent a. on materials and human comfort. As it applies in this text, the
The total number of moles in a mixture is defined as the definition is broadened to include the method of controlling
sum of the number of moles of its constituents: the thermal properties of moist air.
When moist air is considered to be a mixture of indepen-
nm = na + nb + nc (2-18)
dent, perfect gases, dry air, and water vapor, each is assumed
The mole fraction x is defined as n/nm , and to obey the perfect gas equation of state:
where Mm is called the apparent (or average) molecular Water vapor: pwV = nwRT
weight of the mixture. The second part of the Gibbs-Dalton
where
law can be taken as a basic definition:
pa = partial pressure of dry air
Um = Ua + Ub + Uc (2-20) pw = partial pressure of water vapor
Hm = Ha + Hb + Hc (2-21) V= total mixture volume
na = number of moles of dry air
Sm = Sa + Sb + Sc (2-22) nw = number of moles of water vapor
R= universal gas constant
Remember that the constituent entropies here must be
(8.31441 J/g-mol·K or 1545.32 ft·lbf / lb·mol·°R)
evaluated at the temperature and volume of the mixture or at
T = absolute temperature
the mixture temperature and the constituent partial pressures.
The entropy of any constituent at the volume and temperature The mixture also obeys the perfect gas equation:
of the mixture (and hence at its partial pressure) is greater than
its entropy when existing at the pressure and temperature of pV = nRT or (pa + pw)V = (na + nw)RT
the mixture (and hence at its partial volume). Dry-bulb temperature t is the temperature of air as regis-
Consider the constituents as perfect gases: tered by an ordinary thermometer.
Rm = (maRa + mbRb + mcRc)/mm (2-23) Thermodynamic wet-bulb temperature t* is the tempera-
ture at which water (liquid or solid), by evaporating into moist
cvm = (macva + mbcvb + mccvc)/mm (2-24) air at a given dry-bulb temperature t and humidity ratio W, can
bring the air to saturation adiabatically at the same temperature
cpm = (macpa + mbcpb + mccpc)/mm (2-25) t*, while the pressure p is maintained constant. Figure 2-8 may
2.2.13 Psychrometrics: Moist Air Properties be used as a schematic representation of the adiabatic saturation
process, where the leaving air is saturated and at a temperature
Consider a simplification of the problem involving a mix-
equal to that of the injected water. A device used in place of the
ture of ideal gases that is in contact with a solid or liquid phase
adiabatic saturator is the psychrometer.
of one of the components. The most familiar example is a
The psychrometer consists of two thermometers or other
mixture of air and water vapor in contact with liquid water or
temperature-sensing elements, one of which has a wetted cotton
ice, such as the problems encountered in air conditioning or
wick covering the bulb (Figure 2-9). When the wet bulb is
drying. This, and a number of similar problems can be ana-
placed in an airstream, water may evaporate from the wick. The
lyzed simply and with considerable accuracy if the following
equilibrium temperature the water eventually reaches is called
assumptions are made:
the wet-bulb temperature. This process is not one of adiabatic
1. The solid or liquid phase contains no dissolved gases. saturation which defines the thermodynamic wet-bulb tempera-
2. The gaseous phase can be treated as a mixture of ideal
gases.
3. When the mixture and the condensed phase are at a given
pressure and temperature, the equilibrium between the
condensed phase and its vapor is not influenced by the
presence of the other component. This means that when
equilibrium is achieved, the partial pressure of the vapor
equals the saturation pressure corresponding to the tem-
perature of the mixture.
If the vapor is at the saturation pressure and temperature,
the mixture is referred to as a saturated mixture. For an air-
water vapor mixture, the term saturated air is used. Fig. 2-8 Adiabatic Saturator
Chapter 2 | Thermodynamics and Psychrometrics 31
ture, but is one of simultaneous heat and mass transfer from the Degree of saturation is the ratio of the actual humidity
wet-bulb thermometer. Fortunately, the corrections applied to ratio W to the humidity ratio Ws of saturated air at the same
wet-bulb thermometer readings to obtain the thermodynamic temperature and pressure.
wet-bulb temperature are usually small.
Humidity ratio W of a given moist air sample is defined as W
= ------- (2-28)
the ratio of the mass of water vapor to the mass of dry air con- Ws
tained in the sample: t, p
where ha is the specific enthalpy for dry air and hg is the spe- ture. Approximately
cific enthalpy for water vapor at the temperature of the mix-
32 Principles of HVAC, 8th Edition
Table 2-4 Thermodynamic Properties of Moist Air at Standard Atmospheric Pressure, 14.696 psia
(Table 2, Chapter 1, 2017 ASHRAE Handbook—Fundamentals)
Temp., °F Specific Volume, ft3/lbda Specific Enthalpy, Btu/lbda Specific Entropy, Btu/lbda·°F Temp., °F
Humidity Ratio
t Ws , lbw / lbda vda vas vs hda has hs sda ss t
–80 0.0000049 9.553 0.000 9.553 –19.221 0.005 –19.215 –0.04594 –0.04592 –80
–79 0.0000053 9.579 0.000 9.579 –18.980 0.005 –18.975 –0.04531 –0.04529 –79
–78 0.0000057 9.604 0.000 9.604 –18.740 0.006 –18.734 –0.04468 –0.04466 –78
–77 0.0000062 9.629 0.000 9.629 –18.500 0.007 –18.493 –0.04405 –0.04403 –77
–76 0.0000067 9.655 0.000 9.655 –18.259 0.007 –18.252 –0.04342 –0.04340 –76
–75 0.0000072 9.680 0.000 9.680 –18.019 0.007 –18.011 –0.04279 –0.04277 –75
–74 0.0000078 9.705 0.000 9.705 –17.778 0.008 –17.770 –0.04217 –0.04215 –74
–73 0.0000084 9.731 0.000 9.731 –17.538 0.009 –17.529 –0.04155 –0.04152 –73
–72 0.0000090 9.756 0.000 9.756 –17.298 0.010 –17.288 –0.04093 –0.04090 –72
–71 0.0000097 9.781 0.000 9.782 –17.057 0.010 –17.047 –0.04031 –0.04028 –71
–70 0.0000104 9.807 0.000 9.807 –16.806 0.011 –16.817 –0.03969 –0.03966 –70
–69 0.0000112 9.832 0.000 9.832 –16.577 0.012 –16.565 –0.03907 –0.03904 –69
–68 0.0000120 9.857 0.000 9.858 –16.336 0.013 –16.324 –0.03846 –0.03843 –68
–67 0.0000129 9.883 0.000 9.883 –16.096 0.013 –16.083 –0.03785 –0.03781 –67
–66 0.0000139 9.908 0.000 9.908 –15.856 0.015 –15.841 –0.03724 –0.03720 –66
–65 0.0000149 9.933 0.000 9.934 –15.616 0.015 –15.600 –0.03663 –0.03659 –65
–64 0.0000160 9.959 0.000 9.959 –15.375 0.017 –15.359 –0.03602 –0.03597 –64
–63 0.0000172 9.984 0.000 9.984 –15.117 0.018 –15.135 –0.03541 –0.03536 –63
–62 0.0000184 10.009 0.000 10.010 –14.895 0.019 –14.876 –0.03481 –0.03476 –62
–61 0.0000198 10.035 0.000 10.035 –14.654 0.021 –14.634 –0.03420 –0.03415 –61
–60 0.0000212 10.060 0.000 10.060 –14.414 0.022 –14.392 –0.03360 –0.03354 –60
–59 0.0000227 10.085 0.000 10.086 –14.174 0.024 –14.150 –0.03300 –0.03294 –59
–58 0.0000243 10.111 0.000 10.111 –13.933 0.025 –13.908 –0.03240 –0.03233 –58
–57 0.0000260 10.136 0.000 10.137 –13.693 0.027 –13.666 –0.03180 –0.03173 –57
–56 0.0000279 10.161 0.000 10.162 –13.453 0.029 –13.424 –0.03121 –0.03113 –56
–55 0.0000298 10.187 0.000 10.187 –13.213 0.031 –13.182 –0.03061 –0.03053 –55
–54 0.0000319 10.212 0.001 10.213 –12.972 0.033 –12.939 –0.03002 –0.02993 –54
–53 0.0000341 10.237 0.001 10.238 –12.732 0.035 –12.697 –0.02943 –0.02934 –53
–52 0.0000365 10.263 0.001 10.263 –12.492 0.038 –12.454 –0.02884 –0.02874 –52
–51 0.0000390 10.288 0.001 10.289 –12.251 0.041 –12.211 –0.02825 –0.02814 –51
–50 0.0000416 10.313 0.001 10.314 –12.011 0.043 –11.968 –0.02766 –0.02755 –50
–49 0.0000445 10.339 0.001 10.340 –11.771 0.046 –11.725 –0.02708 –0.02696 –49
–48 0.0000475 10.364 0.001 10.365 –11.531 0.050 –11.481 –0.02649 –0.02636 –48
–47 0.0000507 10.389 0.001 10.390 –11.290 0.053 –11.237 –0.02591 –0.02577 –47
–46 0.0000541 10.415 0.001 10.416 –11.050 0.056 –10.994 –0.02533 –0.02518 –46
–45 0.0000577 10.440 0.001 10.441 –10.810 0.060 –10.750 –0.02475 –0.02459 –45
–44 0.0000615 10.465 0.001 10.466 –10.570 0.064 –10.505 –0.02417 –0.02400 –44
–43 0.0000656 10.491 0.001 10.492 –10.329 0.068 –10.261 –0.02359 –0.02342 –43
–42 0.0000699 10.516 0.001 10.517 –10.089 0.073 –10.016 –0.02302 –0.02283 –42
–41 0.0000744 10.541 0.001 10.543 –9.849 0.078 –9.771 –0.02244 –0.02224 –41
–40 0.0000793 10.567 0.001 10.568 –9.609 0.083 –9.526 –0.02187 –0.02166 –40
–39 0.0000844 10.592 0.001 10.593 –9.368 0.088 –9.280 –0.02130 –0.02107 –39
–38 0.0000898 10.617 0.002 10.619 –9.128 0.094 –9.034 –0.02073 –0.02049 –38
–37 0.0000956 10.643 0.002 10.644 –8.888 0.100 –8.788 –0.02016 –0.01991 –37
–36 0.0001017 10.668 0.002 10.670 –8.648 0.106 –8.541 –0.01959 –0.01932 –36
–35 0.0001081 10.693 0.002 10.695 –8.407 0.113 –8.294 –0.01902 –0.01874 –35
–34 0.0001150 10.719 0.002 10.721 –8.167 0.120 –8.047 –0.01846 –0.01816 –34
–33 0.0001222 10.744 0.002 10.746 –7.927 0.128 –7.799 –0.01790 –0.01758 –33
–32 0.0001298 10.769 0.002 10.772 –7.687 0.136 –7.551 –0.01733 –0.01699 –32
–31 0.0001379 10.795 0.002 10.797 –7.447 0.145 –7.302 –0.01677 –0.01641 –31
–30 0.0001465 10.820 0.003 10.822 –7.206 0.154 –7.053 –0.01621 –0.01583 –30
–29 0.0001555 10.845 0.003 10.848 –6.966 0.163 –6.803 –0.01565 –0.01525 –29
–28 0.0001650 10.871 0.003 10.873 –6.726 0.173 –6.553 –0.01510 –0.01467 –28
–27 0.0001751 10.896 0.003 10.899 –6.486 0.184 –6.302 –0.01454 –0.01409 –27
–26 0.0001858 10.921 0.003 10.924 –6.245 0.195 –6.051 –0.01399 –0.01351 –26
–25 0.0001970 10.947 0.003 10.950 –6.005 0.207 –5.798 –0.01343 –0.01293 –25
–24 0.0002088 10.972 0.004 10.976 –5.765 0.220 –5.545 –0.01288 –0.01235 –24
–23 0.0002214 10.997 0.004 11.001 –5.525 0.233 –5.292 –0.01233 –0.01176 –23
–22 0.0002346 11.022 0.004 11.027 –5.284 0.247 –5.038 –0.01178 –0.01118 –22
–21 0.0002485 11.048 0.004 11.052 –5.044 0.261 –4.783 –0.01123 –0.01060 –21
–20 0.0002632 11.073 0.005 11.078 –4.804 0.277 –4.527 –0.01069 –0.01002 –20
–19 0.0002786 11.098 0.005 11.103 –4.564 0.293 –4.271 –0.01014 –0.00943 –19
–18 0.0002950 11.124 0.005 11.129 –4.324 0.311 –4.013 –0.00960 –0.00885 –18
–17 0.0003121 11.149 0.006 11.155 –4.084 0.329 –3.754 –0.00905 –0.00826 –17
–16 0.0003303 11.174 0.006 11.180 –3.843 0.348 –3.495 –0.00851 –0.00768 –16
–15 0.0003493 11.200 0.006 11.206 –3.603 0.368 –3.235 –0.00797 –0.00709 –15
–14 0.0003694 11.225 0.007 11.232 –3.363 0.390 –2.973 –0.00743 –0.00650 –14
–13 0.0003905 11.250 0.007 11.257 –3.123 0.412 –2.710 –0.00689 –0.00591 –13
–12 0.0004128 11.276 0.007 11.283 –2.882 0.436 –2.447 –0.00635 –0.00532 –12
–11 0.0004362 11.301 0.008 11.309 –2.642 0.460 –2.182 –0.00582 –0.00473 –11
Exploring the Variety of Random
Documents with Different Content
further information. The London Horticultural Society mentioned the
variety as long ago as in 1831. Another Mr. Pond, a nurseryman in
Massachusetts, grew a variety very similar in appearance to the
English plum and permitted his name to be given it to the great
confusion of the nomenclature of the two. The Hungarian prune of
the Pacific Coast is Pond, why so-called does not appear; with this as
with several other plums the Pacific Coast fruit-growers persist in
using a name known to have been wrongly applied to an old and
well-known variety elsewhere called rightly. Oswego, a supposed
seedling grown in Oswego, New York, is identical with the Pond as
tested by this Experiment Station and by local growers. The
American Pomological Society placed this fruit on its catalog list in
1856.
POOLE PRIDE
Prunus munsoniana
1. Am. Pom. Soc. Rpt. 108. 1885. 2. Cornell Sta. Bul. 38:50. 1892. 3.
Ia. Hort. Soc. Rpt. 334. 1894. 4. Wis. Sta. Bul. 63:24, 53. 1897. 5. Ibid.
87:15. 1901. 6. Waugh Plum Cult. 186. 1901. 7. Budd-Hansen Am. Hort.
Man. 299. 1903. 8. Ohio Sta. Bul. 162:245 fig., 256, 257. 1905.
Kroh 1, 6. Kroh 3, 7. Poole 2, 7. Poole 6. Poole’s Pride 3, 4, 5. Poole’s
Pride 2, 6, 7.
POTTAWATTAMIE
POTTAWATTAMIE
Prunus munsoniana
1. Ia. Hort. Soc. Rpt. 287. 1887. 2. Pop. Gard. 3:27 fig. 1887. 3. Cornell
Sta. Bul. 38:64. 86. 1892. 4. Mich Sta. Bul. 123:20. 1895. 5. Ia. Sta. Bul.
31:346. 1895. 6. Wis. Sta. Bul. 63:53. 1897. 7. Am. Pom. Soc. Cat. 25.
1897. 8. Ohio Sta. Bul. 113:156. 1899. 9. Ia. Sta. Bul. 46:287. 1900. 10.
Waugh Plum Cult. 199 fig. 1901. 11. Ga. Sta. Bul. 67:279. 1904.
PURPLE GAGE
Prunus domestica
1. Pom. Mag. 3:129, Pl. 1830. 2. Lond. Hort. Soc. Cat. 152, 153. 1831.
3. Downing Fr. Trees Am. 308 fig. 127. 1845. 4. Poiteau Pom. Franc. 1.
1846. 5. Thomas Am. Fruit Cult. 339. 1849. 6. Am. Pom. Soc. Cat. 54.
1852. 7. Ann. Pom. Belge 3:71, Pl. 1855. 8. Thompson Gard. Ass’t 519,
Pl. 1. 1859. 9. Hogg Fruit Man. 377. 1866. 10. Pom. France 7: No. 9.
1871. 11. Mas Le Verger 6:3 fig. 2. 1866-73. 12. Cat. Cong. Pom. France
367. 1887. 13. Mathieu Nom. Pom. 452. 1889. 14. Guide Prat. 155, 364.
1895.
Blaue Reine-Claude 10, 11, 13 incor., 14. Die Violette Königin Claudia
13. Die Violette Königin Claudie 1. Die Violette Köning Claudie 3. Die
Violette oder blaue Renoclode 10, 14. Die Violette oder Blaue Reneclode
11, 13. Purple Gage 2, 8, 10, 11, 12, 13, 14. Prune Reine Claude Violette
4, 10. Reine-Claude Alex. Dumas 14. Reine-Claude Violette 2, 7, 8, 11, 12,
14. Reine-Claude Violette 1, 3, 5, 9, 13. Violet Queen Claude 3, 5. Violet
Gage 8, 9, 10, 12, 13, 14. Violette Reine-Claude 13. Violet Gage 2. Violette
Queen Claude 13. Violet oder Blaue Reneclode 13.
QUACKENBOSS
QUACKENBOSS
Prunus domestica
1. Downing Fr. Trees Am. 393. 1857. 2. Cultivator 6:269 fig. 1858. 3.
Thomas Am. Fruit Cult. 345. 1867. 4. Downing Fr. Trees Am. 941. 1869.
5. Am. Pom. Soc. Cat. 24. 1871. 6. Mas. Pom. Gen. 2:151, fig. 76. 1873.
7. Barry Fr. Garden 415. 1883. 8. Mich. Sta. Bul. 103:34, fig. 6. 1894. 9.
Ont. Fr. Exp. Sta. Rpt. 52. 1895. 10. Cornell Sta. Bul. 131:191, fig. 40 II.
1897. 11. Waugh Plum Cult. 119. 1901. 12. Va. Sta. Bul. 134:44. 1902.
Quackenbos 9, 12.
RED APRICOT
Prunus domestica
1. Knoop Fructologie 2:52, 54. 1771. 2. Kraft Pom. Aust. 2:27, Tab. 172
fig. 1. 1796. 3. Prince Pom. Man. 2:72. 1832. 4. Poiteau Pom. Franc. 1.
1846. 5. Goodrich N. Fr. Cult. 83. 1849. 6. Mas Pom. Gen. 2:127, fig. 64.
1873. 7. Hogg Fruit Man. 720. 1884. 8. Mathieu Nom. Pom. 447. 1889. 9.
Lucas Vollst. Hand. Obst. 474. 1894.
Abricot Rouge 1. Abricote Rouge 3. Apricot Plum 5. Abricotée Rouge 6.
Abricot Rouge 6, 7, 8. Abricotée Rouge 7, 8. Die Aprikosenpflaume 2.
Fürstenzeller Pflaume 8. Fürstenzeller Reine-Claude 6. Prune d’Abricot
Rouge 1, 8. Prune d’Abricos 2. Prune d’Abricot rouge 1. Prune Abricotée
Rouge 4. Red Apricot Plum 3. Rothe Aprikosenpflaume 6. Red Apricot 6, 8.
Rote Aprikosenpflaume 8. Rote Aprikosenzwetsche 9.
RED DATE
Prunus domestica
1. Parkinson Par. Ter. 576. 1629. 2. Rea Flora 208. 1676. 3. Ray Hist.
Plant. 2:1529. 1688. 4. Kraft Pom. Aust. 2:43, Tab. 196 fig. 2. 1796. 5.
Lond. Hort. Soc. Cat. 147. 1831. 6. Mathieu Nom. Pom. 447. 1889.
A Fleur Double 5. Dattel Pflaume 6. Dattel Zwetsche 6. Die grosse rothe
Feigenpflaume 4. Figue Grose Rouge 5. Figue Grosse Rouge 6. Früh
Zwetsche 6. Grosse Rote Feigen Pflaume 6. Lange Violette Dattel
Zwetsche 6. Lange Violette Dattel Pflaume 6. Prune figue grosse rouge 4.
Prune d’Autriche 6. Prune Figue 6. Prune Datte 6. Purpur Pflaume 6. Red
Date-plum 3. Rote. Dattelzwetsche 6. Rote Feigen Pflaume 6. Turkische
Zwetsche 6. Ungarische Zwetsche 6. Wilmot’s Russian 5. Zucker Zwetsche
6.
RED DIAPER
Prunus domestica
1. Quintinye Com. Gard. 67, 68, 69. 1699. 2. Miller Gard. Kal. 184.
1734. 3. Knoop Fructologie 2:57. 1761. 4. Duhamel Trait. Arb. Fr. 2:102,
Pl. XX fig. 12. 1768. 5. Kraft Pom. Aust. 2:36, Tab. 185 fig. 2. 1796. 6.
Willichs Dom. Enc. 300. 1803. 7. Pom. Mag. 1:6, Pl. 1828. 8. Prince Pom.
Man. 2:69, 90. 1832. 9. Downing Fr. Trees Am. 298. 1845. 10. Floy-
Lindley Guide Orch. Gard. 285, 287, 288, 383. 1846. 11. Poiteau Pom.
Franc. 1:1846. 12. Horticulturist 3:29. 1848. 13. Thomas Am. Fruit Cult.
335, fig. 261. 1849. 14. Horticulturist 4:195. 1849. 15. Ann. Pom. Belge
75 Pl. 1853. 16. Bridgeman Gard. Ass’t 128, 129, 130. 1857. 17. Pom.
France 7: No. 10. 1871. 18. Mas Pom. Gen. 2:135, fig. 68. 1873. 19. Le
Bon Jard. 339. 1882. 20. Hogg Fruit Man. 697. 1884. 21. Cat. Cong. Pom.
France 345. 1887. 22. Mathieu Nom. Pom. 447. 1889. 23. Guide Prat.
158, 365. 1895.
Amalia Pflaume 22, 23. Bunte Herzformige Pflaume 17, 22. Cyprische
Pflaume 22, 23. Diaprée de Roche Corbon 22. Dame Aubert Rouge 22, 23.
Diademe Imperial 22. De Chypre 23. Diademe Imperiale 23. Diaper 1, 10.
Die Blutfarbige Pflaume 5. Diaprée Rouge 3, 4, 9, 17, 18, 19, 20, 21.
Diaprée Rouge 5, 8, 10, 13, 16, 18, 22. Diapre Rouge 8, 22, 23. Die Rothe
Eierpflaume 14. Diaper Rouge 16. Diaper 17, 20, 22. Die Blutfarbege
Pflaume 17. Diaprea rubra 17. Diademe 19. De Briancon 21. Gluhende
Kohle 22. Hoheits Pflaume 22, 23. Imperial Diadem 8, 9, 13, 20, 22.
Imperial Diadem 10, 16. Imperial Diademe 17, 21. Imperatrice 19. La
Roche-Corbon 22. La Courbon 17. Mimms 10, 16. Mimms 9, 13, 17, 20.
Mimms Plum 10, 16, 22. Mimms Plum 7, 8. Mimms Pflaume 22. Matchless
22. Prune Diaprée Rouge 11. Prune Imperatrice 15. Prune Diademe 15.
Prune de Briancon 17. Prune de Chypre 22. Prinzessin Pflaume 22, 23.
Roche-Carbon 22. Rote Diaprée 22. Rouge Corbon 22. Rote Eier Pflaume
22. Rote Cyprische Pflaume 22. Rote Marunke 22. Rote Osterei 22. Rote
Masche 22. Rote Ross Pflaume 22. Rothe Eierpflaume 23. Rothe Marunke
23. Roche Corbon 1. Roche Courbon 2. Roche Corbon 4, 5, 8, 9, 10, 16,
17, 18, 20, 21, 22. Roch-courbon 6. Red Diaper 6, 10, 16, 17, 20, 21, 22.
Roche Courbon 8. Red Egg Plum 14. Reine de Chypre 14. Red Imperial 16.
Rothe Diaprée 17. Rothe Violen Pflaume 17. Red Diaper Plum 17. Rothe
Eierpflaume 17. Rothe Süsse Pflaume 17. Rothe Diapre 18. Virginische
Pflaume 17.
RED JUNE
Prunus triflora
1. Am. Pom. Soc. Rpt. 106. 1891. 2. Cornell Sta. Bul. 62:28. 1894. 3.
Ga. Hort. Soc. Rpt. 95. 1895. 4. Cornell Sta. Bul. 106:60. 1896. 5. Ala.
Col. Sta. Bul. 85:444. 1897. 6. Cornell Sta. Bul. 139:45. 1897. 7. Rural N.
Y. 56:615. 1897. 8. Am. Pom. Soc. Cat. 26. 1897. 9. Mich. Sta. Bul.
169:242, 243, 249, 250. 1899. 10. Cornell Sta. Bul. 175:136. 1899. 11.
U. S. D. A. Rpt. 386. 1901. 12. Waugh Plum Cult. 140. 1901. 13. Budd-
Hansen Am. Hort. Man. 324. 1903. 14. Can. Exp. Farm Bul. 43:37. 1903.
15. Mass. Sta. Ann. Rpt. 17:160. 1905. 16. Md. Hort. Soc. Rpt. 85. 1905.
17. Ga. Sta. Bul. 68:5, 32. 1905.
Botan 14. Hytankayo 11. Long Fruit 3. Nagate no Botankyo 10, 11, 17.
Red Nagate 1, 2, 3, 6, 9. Red Nagate 4, 5, 11, 12, 13, 17. Red June 2, 3.
Shiro Smomo 2, 4, 7, 11, 12, 14. Shiro Smomo 9.
1. Parkinson Par. Ter. 576, 577. 1629. 2. Rea Flora 208. 1676. 3.
Langley Pomona 92, Pl. XX fig. V. 1729. 4. Duhamel Trait. Arb. Fr. 2:98,
Pl. XV. 1768. 5. Kraft Pom. Aust. 2:31, Tab. 178 fig. 1. 1796. 6. Willichs
Dom. Enc. 4:300. 1803. 7. Prince Pom. Man. 2:59. 1832. 8. Hoffy Orch.
Com. fig. 1841. 9. Floy-Lindley Guide Orch. Gard. 292. 1846. 10.
Horticulturist 4:194. 1849. 11. Ann. Pom. Belge 99, Pl. 1853. 12. Elliott
Fr. Book 428, 429. 1854. 13. Noisette Man. Comp. Jard. 2:499. 1860. 14.
Downing Fr. Trees Am. 943. 1869. 15. Mas Pom. Gen. 2:139, fig. 70.
1873. 16. Hogg Fruit Man. 721. 1884. 17. Am. Pom. Soc. Rpt. 61. 1887.
18. Mathieu Nom. Pom. 445, 448. 1889. 19. Ia. Hort. Soc. Rpt. 87. 1890.
20. Guide Prat. 158, 358. 1895.
Askew’s Purple Egg 12, 14, 16, 18. Blaue Kaiserpflaume 15, 18, 20
incor. Blaue Eier Pflaume 18 incor. Bockshoden 18, 20. Bocksdutten 18,
20. Bonum Magnum 18 incor., 20. Blue Imperatrice 7 incor., 8. Copper
Plum 8. Die Kaiserliche veilchenfarbige Pflaume 5. Die Rothe
Kaiserpflaume 10. Dame Aubert 13. Dame Aubert Violette 14, 16, 18, 20.
Die Rothe Eierpflaume 14. Dame Aubert Rouge 17. Dame Aubert Rouge
19. D’Oeuf Violette 20. Early Forcing 12. Florence 12, 14, 16, 18, 20.
Frühe Treib Zwetsche 18. Frühe Treibzwetsche 20. Great Imperial Plum
18, 20. Grosse Früh Zwetsche 18 incor. Grosse Ungarische Zwetsche 18
incor. Imperiall 1. Imperial 3, 6. Impériale Violette 5, 7, 8, 9, 10, 14, 16,
18, 20. Impériale Violette 4, 15, 20. Imperial Violet 7. Impériale 7, 14, 16,
18, 20. Imperiall 9. Imperial 9, 14, 18. Impériale Rouge 10, 14, 16, 18.
Imperial Rouge 12, 18. Imperial Violet 14, 18. Impériale Hâtive 18, 20.
Impériale rouge 20. Large Orlean 7. Mogul Rouge 16, 18. Oeuf Rouge 16,
18. Prune d’Oeuf Violette 18. Prinzessinpflaume 15. Prune-figue 13. Prune
Impériale Violette 11. Prune d’oeuf 7, 14, 18. Purple Egg 7, 12, 14, 16, 18.
Prune-oeuf 7. Purple Magnum Bonum 12, 14, 18. Red Magnum Bonum 8,
12, 20. Red Magnum 6. Red Imperiale 7, 8, 12, 14, 16, 18, 20. Red
Bonum Magnum 3, 7, 18, 20. Red Egg Plum 10. Red Egg 12. Red Imperial
12. Red Egg 14, 16, 18. Red Aubert 17. Rote Eier Pflaume 18. Rote
Kaiserpflaume 18. Rote Kaiser Zwetsche 18. 116 Riga 19. Rothe
Kaiserpflaume 20. Rothe Kaiserzwetsche 20. Shepler ?14, ?18. Sainte-
Catherine (Belgien) 18, 20. The Imperial Plum 2. Violette oder Blaue
Kaiserpflaume 15.
REINE CLAUDE
Prunus domestica
1. Quintinye Com. Gard. 67, 68, 69. 1699. 2. Langley Pomona 93, Pl.
XXIII fig. 7. 1729. 3. Duhamel Trait. Arb. Fr. 2:89, Pl. XI. 1768. 4. Knoop
Fructologie 2:62. 1771. 5. Kraft Pom. Aust. 28, Tab. 173 fig. 2, 41, Tab.
193 fig. 2. 1796. 6. Forsyth Treat. Fr. Trees 20. 1803. 7. Miller Gard. Dict.
3. 1807. 8. Coxe Cult. Fr. Trees 237, fig. 14. 1817. 9. Phillips Com. Orch.
306. 1831. 10. Lond. Hort. Soc. Cat. 147, 148. 1831. 11. Prince Pom.
Man. 2:48. 1832. 12. Gallesio Pom. Ital., Pl. 1839. 13. Downing Fr. Trees
Am. 276 fig. 106. 1845. 14. Floy-Lindley Guide Orch. Gard. 283, 382, 419.
1846. 15. Poiteau Pom. Franc. 1:1846. 16. Horticulturist 2:178, 179, fig.
30, 291. 1847. 17. Thomas Am. Fruit Cult. 326 fig. 253, 329. 1849. 18.
Hovey Fr. Am. 2:69, Pl. 1851. 19. Am. Pom. Soc. Cat. 54. 1852. 20. Elliott
Fr. Book 410. 1854. 21. Thompson Gard. Ass’t 517. 1859. 22. Downing Fr.
Trees Am. 917. 1869. 23. Mas Le Verger 6:55, fig. 28. 1866-73. 24. Pom.
France 7: No. 5. 1871. 25. Oberdieck Deut. Obst. Sort. 434. 1881. 26.
Lauche Deut. Pom. 20, Pl. IV 20. 1882. 27. Hogg Fruit Man. 703. 1884.
28. Mathieu Nom. Pom. 433. 1889. 29. Guide Prat. 154, 363. 1895. 30.
Bailey Sur. Unlike 176, 243. 1896. 31. Cornell Sta. Bul. 131:186. 1897.
32. Botanical Gazette 26:423. 1898. 33. Gard. Chron. 3rd Ser. 24:465.
1898. 34. Waugh Plum Cult. 22, 106, 107 fig. 1901.
Abricot Verd 5, 9. Abricot Vert 3, 7, 10, 11, 13, 14, 21, 22, 23, 24, 27,
28, 29. Abricotée Sageret ?22, 28. Aloise’s Green Gage 22, 24, 27, ?28,
29. Blanche Grosse Espece 10. Bonne Verte 5. Bradford Gage 13, 20, 21,
22, 28, 29. Bradford Green Gage 27, 28. Bradford Queen Gage 24, ?29.
Brugnon Green Gage 10, 18, 21, 22, 24, 27, 28, 29. Brugnon Gage 20, 22,
28, 29. Bruyn Gage 13, 17, 18 incor., 20, 22, 28, 29. Burgnon Gage 13,
24. Cant’s Late Green Gage 22, 28. Claudia 12. Damas Gris 24, 28, 29.
Damas Verd 9. Damas Vert 7, 10, 13, 18, 21, 22, 24, 27, 28, 29. Dauphine
5, 7, 10, 11, 13, 14, 18, 21, 22, 23, 24, 27, 28, 29. Die grosse Königin
Claudiapflaume, die grüne Abrikose 5. Die Königin Klaudia 5. Dauphine 3.
Dauphiny 6. Drap d’Or of some 10, 18, 28, 29. Echte Grosse Reine-Claude
28, 29. Gage Verte 28, 29. Great Green Damask 22, 27, 28. Great Green
Damaski 24, 29. Great Queen Claudia 11. Green Gage 2, 6, 8, 10, 11, 13,
14, 17, 18, 19, 20, 21, 22, 27, 30, 31, 33, 34. Green Spanish 14, 18. Gros
Damas Vert 11, 22, 28, 29. Grosse Königin Claudiapflaume 5. Green Gage
7, 9, 23, 24, 28, 29, 32, 34. Goring’s Golden Gage 22, 24, 27, 28, 29.
Grosse Reine 10, 13, 18, 20, 21, 22, 24, 27, 28, 29. Grosse Grüne Reine-
Claude 25, 28. Grosse Reine-Claude 7, 25, 26, 28. Grosse Reine-Claude 3,
5, 10, 11, 13, 14, 18, 20, 21, 22, 23, 24, 25, 29. Gros Reine-Claude 14.
Grüne Aprikose 5, 28, 29. Grüne Abrikose 5. Grüne Reineclaude 25. Gute
Grüne 28, 29. Huling’s Reine-Claudia 22, 28. Huling’s Reine Claude 11. Ida
Gage 22. Ida Green Gage 16. Ida Green Gage 20, 22, 24, 27, 28, 29.
Isleworth Green Gage 13, 18, 20, 21, 22, 24, 27, 28, 29. Isleworth Green
Gage 10. King of Plums 20. Königin Claudia 28, 29. Königin Klaudia 5.
Large Queen Claude 11. La Grosse Reine-Claude 11. Large Queen Claudia
6. Large green claudia 11. Livingston Manor 22, 28. Louis Brun ?22, ?28.
Mammola 12. Mirabelle Vert Double 22, 24, 27, 28, 29. Murray’s Reine
Claudia 22, 28. Murray’s Reine Claude 11, 14, 22, 27. Prune de Reine
Claude 15. Prunus Domestica Cereola 32. Prunus Domestica var. cereola
33. Prunus Domestica var. Claudiana 32. Queen Claude 2. Queen Claudia
11, 22, 24, 27, 28, 29. Reine-Claude Ancienne 23, 24, 28, 27. Reine-
Claude Blanche Grosse Espece 10. Reineclaude d’oree 29. Reine-Claude
Blanche La Grosse 11, 22. Reine-Claude 8, 10, 11, 13, 17, 18, 20, 21, 22,
27, 28, 33. Reine Claud 1. Reine-Claudia 2. Reine-Claude Blanche 10.
Reine-Claude Dorée 22, 23, 24, 25, 28, 29. Reine-Claude Dore 18, 22.
Reine-Claude Grosse 27, 28. Reine-Claude Verde Perdrigon 5. Reine-
Claude Verte 23, 29. Rensselaer Gage 20, 22. Rensselvar Gage 24, 29.
Rensselaar Gage 27, 28. Reine-Claude Verte Tiquetée 28, 29. Reine-
Claudia Blanche La Grosso 22, 28. Royal Green Gage 28, 29. Schuyler
Gage 20, incor. 22, 24, 27. Schuyler’s Gage ?13, 20, 28, 29. Sucrin Vert
10, 11, 13, 18, 21, 22, 24, 27, 28, 29. Sultaneck Erik ?28, 29. Susina
Regina 12. Triomphe Garcon 24, 28, 29. Triomphe Valet 24, 28, 29.
Trompe Garcon 22, 27, 28, 29. Tromp-Valet 7. Trompe Valet 22, 27, 28,
29. Verdacia 27, 28. Verdacchia rotonda 12. Verdoch 27, 32, 34. Verdochia
32. Verdochio 22, 24, 27, 28, 29. Verducia 22. Verte Bonne 3, 7, 9, 10, 11,
14, 18, 21, 22, 23, 24, 28, 29. Vert Bonne 13, 22, 27. Verte d’Espagne 23,
28, 29. Verte Tiquetée 22, 24, 27, 28, 29. Vilmot’s Green Gage 29. Vilmot’s
Late Green Gage 29. Wilmot’s Green Gage 10, 11, 18, 20, 21, 22, 24, 27,
28. Wilmot’s Late Green Gage 11, 18, 20, 21, 22. Wilmot’s Late Green
Gage 10, 13, 18, 20, 21, 22, 28, 29. Wilmot’s New Green Gage 10, 11, 13,
18, 20, 22, 28, 29. Waterloo 20.
ROBINSON
ROBINSON
Prunus munsoniana
1. Ind. Hort. Soc. Rpt. 134. 1883. 2. Am. Pom. Soc. Rpt. 151. 1891. 3.
Cornell Sta. Bul. 38:64, 86. 1892. 4. Me. Sta. An. Rpt. 12:67. 1896. 5.
Am. Pom. Soc. Rpt. 89. 1897. 6. Wis. Hort. Soc. Rpt. 137. 1899. 7. Wis.
Sta. Bul. 87:15. 1901. 8. Waugh Plum Cult. 199. 1901. 9. Kan. Sta. Bul.
101:131. 1901. 10. Ga. Sta. Bul. 67:280. 1904. 11. Ohio Sta. Bul.
162:256, 257. 1905.
Robinson has long been one of the best known of its species
though it is probably inferior in fruit-characters at least to several
other Munsoniana sorts. The plums are attractive in coloring but
small in size and comparatively low in quality. The trees are
capricious in growth and not as hardy as some others of the species
but where they can be grown are always productive. The variety is
rated by some authors among those that need cross-pollination to
insure large crops. Robinson may be worth growing in the South and
in the States of the Plains but it cannot be recommended for any
purpose in New York.
This variety is a seedling grown by a Mr. Pickett of Putnam County,
Indiana, from a seed brought with him from North Carolina about
1835. In 1879, Dr. J. H. Robinson read a paper before the Indiana
Horticultural Society on Chicasaw plums, and gave a very flattering
description of this plum, which he had been growing since 1872.
Later it was named by the Putnam County Horticultural Society in
honor of Dr. Robinson. This name was used as a synonym of Miner
by Downing in 1869 but at the present time that usage has almost
disappeared in plum literature.
ROLLINGSTONE
Prunus americana
ROYAL TOURS
Prunus domestica
1. Duhamel Trait. Arb. Fr. 2:81, Pl. XX fig. 8. 1768. 2. Kraft Pom. Aust.
2:35, Tab. 184 fig. 2. 1796. 3. Downing Fr. Trees Am. 313. 1845. 4. Elliott
Fr. Book 423. 1854. 5. Mas Le Verger 6:53, fig. 27. 1866-73. 6. Lange
Allgem. Garten. 2:420. 1879. 7. Le Bon Jard. 2:341. 1882. 8. Cat. Cong.
Pom. France 368. 1887. 9. Mathieu Nom. Pom. 438. 1889. 10. Guide Prat.
160, 365. 1895. 11. Waugh Plum Cult. 120, 121. 1901.
Damas de Tours 7. Die königliche Pflaume von Tours 2. Diel’s
Königspflaume 9 incor. Diels Königpflaume 10. Frühe Herrn Pflaume 9
incor., 10. Kings plum of Tours 6. Königspflaume von Tours 5, 10.
Königspflaume von Tours 9. Königliche Pflaume von Tours 9, 10. Königs
Pflaume 9 incor., 10. Königliche Grosse Pflaume 9, 10. Königin von Tours
9, 10. Moroccopflaume 10. Morocco 9 incor. Prune Royale de Tours 5, 9.
Rothe Königspflaume 10. Roi 10. Royale 8, 10. Royale de Tours 1, 3, 5, 7,
8, 10. Royale de Tours 2, 4, 9, 10, 11. Royal Tours 3, 4, 9. Royal of Tours
4. Royal red Plum 8, 10. Worth 11.
Tree strong, vigorous; branches thick, short, smooth; fruit early mid-
season; of medium size, irregularly roundish, swollen on one side, dark
reddish-purple covered with thick bloom; cavity deep; suture prominent;
stem short, thick; skin thick, firm; dots conspicuous; flesh greenish-yellow,
firm, sweet; very good; stone large, oblong, rough, clinging.
RUTLAND PLUMCOT
Prunus triflora × Prunus armeniaca
1. Burbank Cat. 13 fig. 1901. 2. De Vries Pl. Br. 218. 1907. 3. Fancher
Creek Nur. Cat. 10 fig. 1909.
Plumcot 1, 2.
SAINT CATHERINE
Prunus domestica
1. Quintinye Com. Gard. 67, 68, 69. 1699. 2. Langley Pomona 94, Pl. 24
fig. 6. 1729. 3. Miller Gard. Dict. 3. 1754. 4. Duhamel Trait. Arb. Fr. 2:97,
Pl. XX fig. 5, 109, Pl. XIX. 1768. 5. Knoop Fructologie 2:55. 1771. 6.
Lond. Hort. Soc. Cat. 153. 1831. 7. Prince Pom. Man. 2:76, 103. 1832. 8.
Kenrick Am. Orch. 267. 1832. 9. Gallesio Pom. Ital. 2: Pl. 1839. 10.
Downing Fr. Trees Am. 283 fig. 112. 1845. 11. Floy-Lindley Guide Orch.
Gard. 298, 383. 1846. 12. Poiteau Pom. Franc. 1:1846. 13. U. S. Pat. Off.
Rpt. XXX. 1854. 14. Ann. Pom. Belge 65, Pl. 1855. 15. Thompson Gard.
Ass’t 520. 1859. 16. Am. Pom. Soc. Cat. 86. 1862. 17. Pom. France 7:
No. 23. 1871. 18. Mas Le Verger 6:89, fig, 45. 1866-73. 19. Hogg Fruit
Man. 724. 1884. 20. Mathieu Nom. Pom. 431. 1889. 21. Wickson Cal.
Fruits 356 fig. 1891. 22. Guide Prat. 161, 365. 1895. 23. Oregon Sta. Bul.
45:33 fig. 1897.
Bricet 7. Bricette 4, 7, 12. Bricette 7, 19. Brisette 20, 22. Catherine
(Prune de Ste.) 5. Catharinenpflaume 18, 20, 21. De Sainte-Catherine 22.
Gelbe Catharinenpflaume 20. Gelbe Catharinenpflaume 18, 22. Gelbe
Katharinenpflaume 17, 22. Gute Kathe 20. Mirabelle Tardive 7. Petite
Bricette 7. Pruneau de Tours 18. Prune de Sainte Catherine 7, 17, 20.
Prune Sainte Catherine 13. Prune Sainte-Catherine 18. Prune Sainte-
Catherine Jaune 18. Prunier Sainte-Catherine 14. Pruneaux de Tours 13.
St. Catharine 1, 2, 7, 8, 16, 19, 23. Saint Catherine 7. Sainte Catherine 11,
20. Sainte-Catharine 3, 4, 12, 17, 18, 22. Sainte-Catherine de Tours 17,
20, 22. Sainte-Catherine jaune 20, 21. Sainte-Catherine ordinaire 17, 20,
22. St. Katharine 1. Späte Mirabelle 20 incor., 22. Susina Di Santa Caterina
9. Torlo d’Ovo 9. Torlo d’Uovo 9. Yellow St. Catharine 7.
This plum is grown only on the Pacific Coast in America and even
there is to be found but locally and is now passing from cultivation.
It is, however, one of the well-known sorts in Europe, especially in
France where it is used for prune-making. It appears to be of the
Reine Claude group in which group America has so many plums of
surpassing merit that this one has no place on this side of the
Atlantic. It is included in The Plums of New York largely because of
its historic interest and because there seems to be no complete
description of it made from trees and fruits grown on this continent.
The origin of this old plum is unknown. It was first mentioned by
Quintinye in 1699. Wherever it originated, it is now grown most
extensively in France and is known to commerce as the Prune of
Tours. The people in Northern Italy cultivate it under the name Torlo
d’Ovo (References, 9). The Belgians have used Saint Catherine
incorrectly for the Imperiale Violette (References, 14). In America,
according to Kenrick, it was not uncommon around Boston in 1832
but it evidently did not receive much recognition, for the United
States Patent Office reimported it from France in 1854 and
distributed it in the northeastern part of this country. The American
Pomological Society added it to its fruit catalog list in 1862 and
dropped it in 1899.