BASARA GNANA SARASWATHI CAMPUS KAKATIYA HILLS

Sec: Star SC Thermodynamics & Thermochemistry Date: 06-11-2020

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SINGLE ANSWER TYPE
1. Select the correct statement at all conditions
A) Total number of moles in a closed system at new equilibrium is less than the old
equilibrium if some amount of a substance is removed from a system.
B) In exothermic reaction, concentration of products dominate that of reactant
C) Change in Entropy of a reversible reaction is zero
D) A B and C are incorrect statements
2. Which of the following properties are characteristic of an ideal solution?
(i)   mix G T,P is negative (ii)   mixST,P is positive
(iii)   mix V T,P is positive (iv)   mix H T,P is negative
A) (i) and (iv) B) (i) and (ii) C) (i) and (iii) D) (iii) and (iv)
3. Although graphite is thermodynamically more stable than diamond at 25C and 1
atmosphere, a diamond will not transform into graphite, even over a period of
thousands of years. Which of the following correctly explains this observation?
A) G for the reaction C (diamond)  C (graphite) is greater than zero
B) H for the reaction C (diamond)  C (graphite) is greater than zero
C) S for the reaction C (diamond)  C (graphite) is less than zero
D) The reaction C (diamond)  C (graphite) is not observed because it has a large
activation energy
4. Calculate r (ratio of C P and CV ) for triatomic linear gas at high temperature. Assume
that the contribution of vibrational degree of freedom is 75%
A) 1.222 B) 1.121 C) 1.18 D) 1.33
 5 
5. 0.5 mole each of two ideal gases A  Cv ,m  R  and B Cv ,m  3R  are taken in a
 2 
container and expanded reversibly and adiabatically. During this process temperature
of gaseous mixture decreased from 350K to 250K. Find  H (in cal/mole) for the
process
A) -200 B) -275 C) -750 D) -150
6. Ice-water mass ratio is maintained as 1:1 in a given system containing water in
equilibrium with ice at constant pressure. Molar heat capacity of such a system is____
A) zero B) Infinity C) 4.182 J/k/mole D) 75.48 J/k/mole
7. The enthalpy of neutralisation of a weak monoacidic base(1M) with strong acid is
–56.9 KJ/mol. If the enthalpy of ionisation of weak monoacidic base is 1.8 KJ/mol, the
percentage ionisation of weak base in its molar solution is [Given that
∆Hneutralisation of strong acid and strong base = –57.3 KJ/mol]
A) 100/3 B) 200/9 C) 25% D) 700 / 9
8. Two moles of an ideal gas (   3 / 2 ) is made to expand reversibly and adiabatically to
4 times its initial volume. The change in entropy of the system during expansion is :
(Given : R = 2 cal/K/mole, log10 2 = 0.3, log10 3 = 0.48)
A) 5.6 cal/k B) 11.2 cal/k C) 2.8 cal/k D) 0
9. In the following PV diagrams for a cyclic process, the heat absorbed is maximum for :

A) B) C) D)

10. If an endothermic reaction is non-spontaneous at freezing point of water and becomes

feasible at its boiling point, then
A)  H is –ve,  S is +ve B)  H and ,  S both are +ve
C)  H and,  S both –ve D)  H is +ve,  S is –ve
11. Ethyl chloride is prepared by reaction of ethylene with hydrogen chloride as:
C2H4 g  HCl g  C2H5Cl g;
H  72.3kJ , at 298K
What is the value of U (in kj) if 70g of ethylene and 73g of HCl are allowed to react?
A) -69.8 B) -180.75 C) -174.5 D) -139.6
12. A coffee cup calorimeter initially contains 125g of water, at a temperature of 24.20C .
8 g of ammonium nitrate (NH4 NO3), also at 24.20C , is added to the water, and
the final temperature is 18.20C.What is the heat of solution of ammonium nitrate in
kJ/ mol ?
The specific heat capacity of the solution is 4.2 J /0 C g.
A) 33.51 kJ/mol B) 39.5 kJ/mol
C) 32.2 kJ/ mol D) 37.3 kJ/mol
MULTIPLE ANSWER TYPE
13. For which process does U  0 holds true for ideal gas
A) Cyclic process B) Isothermal process
C) Isochoric process D) Adiabatic process
14. Which of the following statements is/are true
0
A) for substance Svap  S 0fusion in general
B) grater amount of heat will be required to dissociate NH 3 gas into N 2 and H 2 at
constant pressure condition as compared to constant volume condition at same
temperature
C) The reaction having rate law, r  k  A  B  will follow first order kinetics if G is
2

negative and third order kinetics if G is positive

D) Graphite being standard allotrope of carbon, graphite has less standard entropy
Sm0  than diamond.
15. Which of the following must be spontaneous, all temperatures
A) H sys  ve ; S sys  ve B) H sys  ve ; S sys  ve
C) H sys  ve ; S sys  ve D) H sys  ve ; S sys  ve
16. The standard enthalpy and entropy changes for a reaction in equilibrium for the
forward direction are given below
at 300K, H 0  41.16KJ /mole; S 0  4.24 102 KJ /mole
at 1200K, H 0  32.93KJ /mole; S 0  2.96 102 KJ /mole
Identify correct statements
A) The reaction will proceed in the forward direction at 300K
B) The reaction will proceed in forward direction at 300K and 1200K
C) The reaction will proceed in to reverse direction at 1200K, spontaneously
D) The reaction will proceed in forward direction at 1200K and backward direction at
300K.
17. If H f 0CH 3OH  l   230 KJ / mole ; H f 0 H 2O  l   285 KJ / mole
H f 0CO2  g   390 KJ / mole ; S m0 CH 3OH  l   130 J / K / mole
S m0 CO2  g   210 J / K / mole ; S m0 H 2O  l   110 J / K / mole
1
Sm0 H 2  g   130 J / K / mole ;  105 / columb
F
All data at 300K
Then which of the following information is correct about
Direct methanol fuel cell at 300K. If methanol liquid is used as fuel here
A) H 0 reaction=-730 KJ/mole of O2 consumed
B) S 0 reaction=-9J/K/mole of CH 3OH consumed
C) E 0 cell =1.21 volts approx
D) G 0 cell =-727.3KJ/mole of CO2 produced
18 Select the correct statements :
A) The entropy of an isolated system can never decrease.
B) For a chemical system in thermodynamic equilibrium at standard conditions,
standard Gibb's energy change (∆Gº) T, P is equal to zero.
C) If the isoentropic process for an ideal gas is reversible, it must be adiabatic.
D) A process occurs in such a direction as to cause an increase in the entropy of the
universe.
19. Among the following, the extensive property is (properties are) :
A) molarity B) entropy C) resistance D) heat capacity
20. A liquid which is confined inside an adiabatic piston is suddenly taken from state 1 to
state 2 by a single stage process. If the piston comes to rest at point 2 as shown. Then
identify correct option(s)

A)W= – 3P0V0 B)  U = – 3 P0V0

C)  H = –P0 V0 D) q = 0
21. During winters, moisture condenses in the form of dew and can be seen on plant
leaves and grass. The entropy of the system in such cases decreases as liquids possess
lesser disorder as compared to gases. With reference to the second law, which
statement is not correct, for the above process?
 A) The randomness of the universe decreases
B) The randomness of the surroundings decreases
C) Increase is randomness of surroundings equals the decrease in randomness of
system
D) The increase in randomness of the surroundings is greater as compared to the
decrease in randomness of the system.
22. If for reaction
N2 (g) + 3H2 (g)   2NH3 (g) ∆H1º = – 40 kJ/mole, at temperature 300 K and if
specific heat capacities of different species are sP , N 2 = 1 J/gmºC, s P , H 2 = 10
J/gmºC and sP , NH 3 = 2 J/gm ºC. Then ∆H2º at 400 K for the same reaction will be
(assume heat capacities to be constant in given temperature range)
A) – 38 kJ/mole B) – 28 kJ/mole
C) – 42.0 kJ/mole D) – 27.3 kJ/mole
23. Consider the reactions
(i) S (rhombic) + 3/2 O2(g)  SO3(g),  H1
(ii) S (monoclinic) + 3/2O2(g)  SO3(g),  H2
(iii) S (rhombic) + O3(g)  SO3(g),  H3
(iv) S (monoclinic) + O3(g)  SO3(g),  H4
then identify true relation(s)
A) ∆H1 < ∆H 2 < ∆H4 (magnitude only) B) ∆H 1 < ∆H3 < ∆H 4 (magnitude
only)
C) ∆H 1 < ∆H2 = ∆H 3 < ∆H4 (magnitude only) D) ∆H1 + ∆H 4 = ∆H2 + ∆H 3
24. The normal boiling point of a liquid `X` is 400 K. Which of the following statement is
true about the process X (l)   X(g)?
A) at 400 K and 1 atm pressure ∆G = 0
B) at 400 K and 2 atm pressure ∆G = + ve
C) at 400 K and 0.1 atm presure ∆G = – ve
D) at 410 K and 1 atm pressure ∆G = + ve
25. Which of the following have zero standard enthalpy of formation
A) Cdiamond B) Br2(g) C) Pwhite D) SRhombic
INTEGER ANSWER TYPE
26. Certain amount of gas confined in a piston-filled cylinder is heated from 27 0 C to
127 0 C keeping its pressure constant and gas expanded against constant pressure
doing 4.157kJ of work on surroundings find the number of moles of gas present in
cylinder.
27. Number of extensive physical properties is
density, viscosity, emf of drycell, surface tension, molarity, dipolemoment, molar heat
capacity, refractive index, vapour pressure, molar entropy change.
28. If H 0f  MgCl , s  is -125 KJ/mole, H 0f  MgCl2, s  is -642 KJ/mole the enthalpy of
disproportionation of MgCl is -49X to form one mole each of MgCl 2 and other
feasible product. When X is ____
29. If the magnitude of difference in enthalpy of combustion (∆H r) and internal energy of
combustion (∆U r) of solid benzoic acid (C6H5COOH) at 300K is expressed as
p × 102 cal, then the value of p is : (Gas constant R = 2 cal mol–1K–1)
30. Certain amount of a gas ( γ = 1.5) taken in a container and allowed to expand
reversibly and adiabatically from 49 L to 64 L, starting from an initial temperature of
47ºC. Find the final temperature of gas in ºC.
31. One mole of a substance is cooled at the rate of 0.04 kJ/min as shown in the graph. AB
represents cooling of liquid, BC represents conversion of liquid to solid, CD
represents cooling of solid. The entropy of fusion is ………J/mol/K.
A
800
Temp. in K

B C
400

100 D

5 10 40 50

Time in minutes

PASSAGE-1
It is observed that when acid and bases react, some energy is released due to
neutralization reaction, while in case of strong acids and bases, the energy released is
greater, in attributed to energy required for ionization. From above information and
given data answer the following questions
 H (neutralization of SA with SB) = -57.5 kJ/equivalent
 H ionization of NH 4OH = 10kJ/mole
 H ionization of H 2C 2O 4 = 20kJ/mole
32. What will be the energy released when 500ml of 0.1M H 2SO 4 solution reacts with
1 litre of 0.1M NH 4OH solution if base is 30% ionized is given solution.
A) 5.75kJ B) 4.75kJ C) 5.05kJ D) 5.45kJ
33. What will be the final temperature attained if all the heat released in neutralization of
1 litre of 0.2M NH 4OH with 2 litre of 0.1M HCl increases the temperature of final
1
solution having density 0.95 g/ml and specific heat capacity = J/gram, if original
3
temperature was 27 0 C . Assume weak base was initially completely unionized
A) 310 0 C B) 300K C) 310K D) 290K
PASSAGE-2
An ideal gas whose adiabatic exponent equals  is expanded according to the
P  V , where  is a constant. The initial volume of the gas is equal to V0 . As a
result of expansion, the volume increases 4 times.
34. What is the in the increment of the internal energy of the gas?
15V02 V02 15V02 15    1 V02
A) B) C) D)
 1  1 2 2    1
35. What is the molar heat capacity of the gas in the process?
 R    1 V02 R    1 15    1 V02
A) B) C) D)
2    1  1 2    1 2    1
PASSAGE-3
The standard molar enthalpies of IF3 (g) and IF5 (g) are –470 kJ and – 847 kJ,
respectively. Valence shell electron-pair repulsion theory predicts that IF5 (g) is
square pyramidal in shape in which all I–F bonds are equivalent while IF3 (g) is
T-shaped (based on trigonal-bipyramidal geometry) in which I–F bonds are of
different lengths. It is observed that the axial I–F bonds in IF3 are equivalent to the I–
F bonds in IF5.. Some other informations given are:
I2 (s)  I2 (g) ;  H = 62 kJ
F2 (g)  2F (g) ;  H = 155 kJ
I2 (g)  2 I (g) ;  H = 149 kJ
36. Calculate the equatorial I–F bond strength (in kJ/mol) in IF3
A) 150 kj/mol B) 272 kj/mol C) 200kj/mol D) 172 kj/mol
37. i) I2 (s)  2I (g)
ii) F2 (g)  2F (g)
iii) I2 (g)  2 I (g)
iv) BF3 g   B g   3F g 
Out of above four which represents enthalphy of atomization
A) ii, iii, iv B) i, ii C) i, ii, iii D) all
MATRIX MATCHING ANSWER TYPE
38. 5 mole of an ideal gas is filled in container A, fitted with a massless, frictionless
piston. With this container A two more empty containers B and C are connected
through the stop cocks as shown. Stop cock I is opened for considerable time and then
closed. Thereafter, stop cock II is opened for considerable time and then closed.

Column I Column II
(A) Number of moles of gas in container B are (P) 4/5
(B) Number of moles of gas in container C are (Q) 1/2
(C) The ratio of height of piston after closing stop cock II and (R) 1/3
before opening the stop cock I is
(D) The ratio of temperature of gas in container C and (S) 2/3
that in container B is
A) A-Q;B- S;C- P;D- R B) A-R;B- S;C- Q;D- P
C) A-S;B- R;C- P;D- Q D) A-R;B- S;C- P;D- Q
39. Match the column
Column I Column II
A) 2HCl  g   H 2  g   Cl2  g  P) H   ve, S   ve
B) 2O3  g   3O2  g  Q) H  ve, S   ve
C) MgCO3  g   MgO  s  CO2  g  R) H  ve, S  ve
D) 2NO2  g   N2O4  g  S)  H   ve,  S  0
A) A-S;B-Q; C-P; D-R B) A-Q;B-S; C-P; D-R
C) A-S;B-Q; C-R; D-P D) A-R;B-Q; C-P; D-S

KEY
1 2 3 4 5 6 7 8 9 10
D B D C C B D D B B
11 12 13 14 15 16 17 18 19 20
D A AB AB B AC BCD ABCD BCD ABCD
21 22 23 24 25 26 27 28 29 30
ABC C ABD ABC CD 5 0 8 3 7
31 32 33 34 35 36 37 38 39
3 C C A A B A D A