mcqs
mcqs
14. If all the domains of a substance are oriented in the same direction of an applied
magnetic field, then the substance is;
a) Ferrimagnetic substance b) Antiferromagnetic substance
c) Diamagnetic substance d) Ferromagnetic substance
15. A unit cell which has particles at corners and centres of two opposite faces is called:
a) end-centred b) face centred c) body centred d) primitive
16. In two-dimensional hexagonal close packed arrangement of particles, the co-ordination
number is;
a) Two b) Four c) Six d) Twelve
17. Among the following solids, an example for an Amorphous solid is;
a) Sodium Chloride b) Quartz c) glass d) Zinc Chloride
18. When a solid is cut with sharp edged tool, it forms two pieces with irregular surfaces
then the solid is;
a) Amorphous solid b) Crystalline solid c) Conductor d) Semi-conductor
19. Among the following, the one which is not a type of a crystalline solid;
a) Network solids b) Metallic solids c) Ionic solids d) Pseudo solids
20. n-type semiconductor is obtained when Silicon is doped with
a) divalent atom b) trivalent atom c) tetravalent atom d) pentavalent atom
concentration
d) Both a) and b) above
FILL IN THE BLANKS
1. Alloy of copper and gold is an example for solid dissolved in______________ (solid).
2. If solute is present in trace amounts, then concentration is expressed in
__________(ppm).
3. The maximum amount of a solute that can be dissolved in a given amount of solvent at
a given temperature is called ___________________ (solubility).
4. p = KH x is the mathematical form of _____________ law (Henry’s law).
5. The plot of vapour pressure of a liquid and mole fraction is linear for an _________
solution (ideal).
6. Colligative properties do not depend upon the nature of ____________ (solute).
7. _____________ is an example for a synthetic semipermeable membrane.
8. At a given temperature osmotic pressure of a solution proportional to the ___________
(molarity)
9. Abnormal molar mass of solute is due to association or __________ of its
particles(dissociation).
10. Low oxygen level in blood in high altitude regions causes _______(anoxia).
Solution-Answer key
1 2 3 4 5 6 7 8 9 10
B A B A B C B A B C
11 12 13 14 15 16 17 18 19 20
B C A B B A A D C D
Electrochemistry-Answer key
1 2 3 4 5 6 7 8 9 10
A B C C D A A D C b
11 12 13 14 15 16 17 18
D D A B D A C A
6
𝑎𝑐𝑖𝑑 𝐻 +
CH3COOC2H5(l) + H2O(l) → CH3COOH(l) + C2H5OH(l), rate=k [ester] [H2O],
What is the overall order of the reaction if water is present in large excess?
a) Zero b) One c) Two d) Three
13. The Arrhenius equation accounts for the rate of a chemical reaction in terms of
the;
a) concentration of reactants b) activation energy
c) physical states of the reactants d) order of reaction
14. For a chemical reaction, for a 10 degree rise in temperature, the rate
constant(k);
𝑘
a) Becomes 2 b) Remains same c) Becomes 10.k d) Almost doubles
15. While studying the decomposition of ammonia on
hot platinum surface, according to the equation,
2NH3(g) → N2(g) + 3H2(g), it is observed that a plot
of its concentration versus time is as given below, which
of the following statement is CORRECT?
a) Slope of the line is -k b) Order of the reaction is 1.
c) Unit of k is s-1 d) Rate is proportional to [R]o
1
16. For Arrhenius equation, the plot of ln k versus 𝑇 is a straight line with slope
equals to;
𝐸𝑎
a) −𝐸𝑎 𝑥 𝑅 b) Ea x 2.303 x R c) − d) 𝐸𝑎 2.303𝑅
𝑅
17. With respect to a catalyst, which of the following is correct?
(A)It is required in large amounts,
(B) it reduces activation energy,
(C) it provides a different pathway for a reaction
a) All are correct b) Only A c) Only B d) Both B and C
Kinetics-Answer key
1 2 3 4 5 6 7 8 9 10
D C D C C D B C A A
11 12 13 14 15 16 17
C B B D A C D
4. Which of the following is not correct regarding the physical adsorption of a gas
on the solid surface?
a) On increasing surface area, extent of adsorption increases
b) Easily liquifiable gases are easily adsorbed
c) Adsorption is more for specific substance
d) It is a reversible
5. Which of the following is not correct regarding chemisorption?
a) Requires high energy of activation
b) Multilayer adsorption
c) High enthalpy of adsorption
d) Irreversible
1
𝑥
6. In Freundlich adsorption isotherm 𝑚 = 𝑘𝑝𝑛 , the value of n at low pressure is;
a) More than one b) Less than one
c) Equal to one d) From zero to one
7. The catalyst remains unchanged at the end of the reaction in;
a) Quality b) Chemical composition
c) Quality and chemical composition d) Chemical composition and quantity.
8. A finely divided state of the catalyst is more effective as in this state;
a) More surface area is available b) More energy is stored in the catalyst
c) Catalyst shows variable oxidation state d) More enthalpy of adsorption.
9. One of the following is an example of heterogeneous catalysis.
a) Formation of SO3 in lead chamber process
b) Formation of SO3 in contact process
c) Acid hydrolysis of ester
d) Acid hydrolysis of sucrose
10. According to adsorption theory of catalysis, which of the following is WRONG?
a) The concentration of the reactant molecules on the surface of the catalyst
becomes high
b) Desorption of products is very difficult
c) Adsorption produces heat which increases the speed of the reaction
d) Adsorption lowers the action energy of the reaction.
11. Which shape selective catalyst is used to convert alcohol to gasoline?
a) Trypsin b) Calgon c) ZSM-5 d) Zeigler-Natta catalyst.
12. The size of the colloidal particle is;
a) 10-9– 10-6m b) 10-9 – 10 –12m c) 10-3– 10-9m d) 10-3–10-6 m
13. When a small amount of FeCl3 is added to a freshly prepared Fe(OH)3, A reddish
brown colloidal solution is obtained. This phenomenon is known as;
a) Dialysis b) Peptization c) Protection d) Dissolution
14. Which of the following sols, can be prepared by Bredig’s arc method?
a) As2S3 b) Fe(OH)3 c) Sulphur sol d) Gold sol
15. At high concentration of soap in water, soap behaves as………….colloid;
a) Molecular b) Associated c) Macromolecular d) Lyophilic
9
1 2 3 4 5 6 7 8 9 10
B A D C B A D A D B
11 12 13 14 15 16 17 18 19 20
C A B D B A A B A D
1. Excess Xenon reacts with F2 at 673K and 1bar pressure to give _________(XeF 2)
2. XeF6 + 3H2O → _________ + 6HF (XeO3)
3. XeF6 + 2H2O → _________ + 4HF (XeO2F2)
4. XeF6 + H2O → _________ + 2HF (XeOF4)
5. First ionization enthalpy of ________ is nearly same as that of Xe. (O2)
6. Xe reacts with PtF6 to give ___________ (Xe⁺PtF6⁻)
7. Xe + 2F2 →_______ at 873K, 7 bar, (XeF4)
p-Block elements (group 18 only) - Answer key
1 2 3 4 5 6
A C D B D B
1 2 3 4 5 6 7 8 9 10
C D B C C D B B A C
11 12 13 14 15 16 17 18 19 20
A A C A D B B A A d
15. Which of the following cannot be used to oxidize primary alcohol to aldehyde;
a) CrO3 in anhydrous medium b) PCC
c) Acidified KMnO4 d) Cu at 300° C
16. The IUPAC name of picric acid is;
a) m-Nitrobenzoic acid b) 2, 4, 6-Trinitrophenol
c) 2, 4, 6-Tribromophenol d) p-Nitrophenol
17. The best reagent to convert CH3─CH═CH─CH2OH into CH3─CH═CH─CHO is;
a) Acidic permanganate b) Acidic dichromate
c) CrO3 in glacial acetic acid d) Pyridinium chlorochromate
18. Tertiary butyl alcohol gives tertiary butyl chloride on treatment with;
a) Conc. HCl / anhydrous ZnCl2 b) alc. KCN
c) alc.NH3 d) Cl2
19. Conversion of phenol to salicylic acid and to salicylaldehyde are known as
(respectively);
a) Reimer-Tiemann reaction and Kolbe's reaction
b) Williamson's synthesis and hydroboration-oxidation
c) Kolbe's reaction and Williamson's synthesis
d) Kolbe's reaction and Reimer-Tiemann reaction
20. Phenol is treated with dilute HNO3 at low temperature and the products are
separated by;
a) simple distillation b) sublimation
c) steam distillation d) reduced pressure distillation –
1 2 3 4 5 6 7 8 9 10
C A B C A B B C B C
11 12 13 14 15 16 17 18 19 20
B D A C C B D A D C
1 2 3 4 5 6 7 8 9 10
C B C B D C B B D A
11 12 13 14 15 16 17 18 19 20
C A C D A B B B C D
13. AMINES & DIAZONIUM SALTS (Question no.14)
1. The state of hybridization of orbitals of N atom in amines is;
a) sp2 b) sp3 c) sp d) dsp2
2. The IUPAC name of an amine (H3C)2N─CH2─CH3
a) N,N-Dimethylethanamine b) 1,1-Dimethylethanamine
c) N-Dimethylethanamine d) N-Ethyl-N-methylmethanamine
+ ─
3. For the conversion of A R4N X , three moles of R─X is required. Then the
reactant A is;
a) R─N─R b) R3N c) R─NH2 d) Ar─NH2
4. During the catalytic hydrogenation of nitriles to amines, the product
obtained is;
a) only 10 amine b) only 20 amine
c) only 30 amine d) mixture of 10, 20, 30 amines
5. The only amine that can be synthesised by the Gabriel- pthalimide synthesis
is;
a) only aromatic 10 amine b) only aliphatic 10 amine
c) both aromatic and aliphatic 10 amines d) all types of aliphatic amines
6. In the Hoffmann bromamide degradation reaction of benzamide, the amine
produced is;
a) Methanamine b) Ethanamine c) Propanamine d) Aniline
7. Among the following amines, the one with highest boiling point is;
a) CH3NH2 b) (CH3)2N-C2H5
c) C2H5─NH─C2H5 d) n-C4H9─NH2
8. Among the isomeric amines, the correct decreasing order of boiling point is;
a) 20 > 10 > 30 b) 30 > 20 > 10 c) 10 > 20 > 30 d) 30 > 10 > 20
20
1 2 3 4 5 6 7 8 9 10
B A C A B D D C B C
11 12 13 14 15 16 17 18 19 20
A B C D B C B C B A
14. Among the given statements, the incorrect one with respect to DNA is;
a) It acts as genetic material
b) pentose sugar present is β-D-2-Deoxyribose
c) It has double stranded helical structure
d) It synthesizes the required protein
15. The correct Pyranose (Haworth) structure of β-D(+)-Glucopyranose is;
16. Night blindness is caused due to the deficiency of;
a) Vitamin K b) Vitamin E c) Vitamin B12 d) Vitamin A
17. In a polynucleotide chain, the nucleotide units are joined together through;
a) Glycosidic Linkage b) Phosphodiester Linkage
c) Peptide Linkage d) Covalent Bond 18. In the following
18. hormones, the one which is not a sex hormone is;
a) Testosterone b) Progesterone c) Thyroxine d) Estradiol
19. The enzyme which catalyses the oxidation of one substrate with
simultaneous reduction of another substrate is;
a) Oxidoreductase b) Invertase c) Maltase d) Lactase
20. The correct structure of an optically inactive amino acid, Glycine is; -
Biomolecules-Key Answers: -
1 2 3 4 5 6 7 8 9 10
B C A B A C C A C D
11 12 13 14 15 16 17 18 19 20
C B A D B D B C A B
FILL IN THE BLANKS BY CHOSING THE APPROPRIATE WORD FROM THOSE GIVEN IN
THE BRACKETS SET-I
[ Swarts , Helium, most probable kinetic energy, paracetamol, p= KH.x]
1. Mathematical form of Henry’s law is _____________.
2. Kinetic energy of maximum fraction of molecules is ___________ .
3. Balloons are filled with _______ for meteorological studies.
4. CH3Br + AgF → CH3-F + AgBr, this is___________ reaction
5. An analgesic which is also antipyretic is ___________.
SET-II
[ collision frequency, XeO2F2, polar, cationic, ideal solution]
1. Solute-solute, solvent-solvent and solute-solvent interactions are same in
__________.
2. Number of collisions per second per unit volume is called ___________.
3. XeF6 + 2H2O → _________ + 4 HF
4. SN1 reaction is favoured by __________ solvents.
5. Cetyl trimethyl ammonium bromide is a __________ detergent.
SET-III
[increases, radon, 2-butene, pseudo, ofloxacin]
1. When glucose is dissolved in water, the boiling point of water ________.
2. Acid hydrolysis of sucrose is a ___________ first order reaction.
3. A radioactive element of group 18 is ____________.
24