SILVER JUBILEE MATRIC HR SEC SCHOOL

MAYILADUTHURAI , MAYILADUTHURAI - 609001

BASIC CONCEPTS OF CHEMISTRY AND CHEMICAL CALCULATIONS
CHEMISTRY
Total Marks: 100 Marks Class: 11
Duration: 1 Hrs 40 Min
ONE MARKS
Answer all the questions 100 X 1 = 100
1. 40 ml of methane is completely burnt using 80 ml of oxygen at room temperature The volume of gas left after cooling to room
temperature is
a) 40 ml CO2 gas b) 40 ml CO2 gas and 80 ml H2Ogas
c) 60 ml CO2 gas and 60 ml H2O gas d) 120 ml CO2 gas
2. An element X has the following isotopic composition 200X = 90%, 199X = 8% and 202X =2%. The weighted average atomic
mass of the element X is closed to
a) 201 u b) 202 u c) 199 u d) 200 u
3. 23
Assertion : Two mole of glucose contains 12.044 × 10 molecules of glucose
Reason : Total number of entities present in one mole of any substance is equal to 6.02 × 1022
a) both assertion and reason are true and the reason is the b) both assertion and reason are true but reason is not the
correct explanation of assertion correct explanation of assertion
c) assertion is true but reason is false d) both assertion and reason are false
4. Carbon forms two oxides, namely carbon monoxide and carbon dioxide. The equivalent mass of which element remains
constant?
a) Carbon b) oxygen
c) both carbon and oxygen d) neither carbon nor oxygen
5. The equivalent mass of a trivalent metal element is 9 g eq-1 the molar mass of its anhydrous oxide is
a) 102 g b) 27 g c) 270 g d) 78 g
6. The number of water molecules in a drop of water weighing 0.018 g is
a) 6.022 × 1026 b) 6.022 × 1023
c) 6.022 × 10 20 d) 9.9 × 1022
7. 1 g of an impure sample of magnesium carbonate (containing no thermally decomposable impurities) on complete thermal
decomposition gave 0.44 g of carbon dioxide gas. The percentage of impurity in the sample is
a) 0% b) 4.4% c) 16% d) 8.4%
8. When 6.3 g of sodium bicarbonate is added to 30 g of acetic acid solution, the residual solution is found to weigh 33 g. The
number of moles of carbon dioxide released in the reaction is
a) 3 b) 0.75 c) 0.075 d) 0.3
9. When 22.4 litres of H2 (g) is mixed with 11.2 litres of Cl2 (g), each at 273 K at 1 atm the moles of HCl (g), formed is equal to
a) 2 moles of HCl (g) b) 0.5 moles of HCl (g)
c) 1.5 moles of HCl (g) d) 1 moles of HCl (g)
10. Hot concentrated sulphuric acid is a moderately strong oxidising agent. Which of the following reactions does not show
oxidising behaviour?
a) Cu+ 2H2SO4 → CuSO4 + SO2+2H2O b) C+ 2H2SO4 → CO2+2SO2+2H2O
c) BaCl2 + H2SO4 → BaSO4+2HCl d) none of the above
11. Choose the disproportionation reaction among the following redox reactions.
a) 3Mg (s) + N2 (g) → Mg3N2 (s) b) P4 (s) + 3 NaOH+ 3H2O → PH3(g) + 3NaH2PO2 (aq)
c) Cl2 (g)+ 2KI(aq) → 2KCl(aq) + I2 d) Cr2O3 (s) + 2Al (s) → Al2O3(s) + 2Cr(s)
12. The equivalent mass of potassium permanganate in alkaline medium is MnO-4 + 2H2O+3e-- → MnO2 + 4OH-
a) 31.6 b) 52.7 c) 79 d) None of these
13. Which one of the following represents 180g of water?
a) 5 Moles of water b) 90 moles of water
6.022×1023
c) molecules of water d) 6.022×1024 molecules of water
180
14. 7.5 g of a gas occupies a volume of 5.6 litres at 0o C and 1 atm pressure. The gas is
a) NO b) N2O c) CO d) CO2
15. Total number of electrons present in 1.7 g of ammonia is
6.022×1022
a) 6.022 × 1023 b)
1.7
6.022×1024 6.022×1023
c) d)
1.7 1.7
16. The correct increasing order of the oxidation state of sulphur in the anions SO42-, SO32- , S2O42-, S2O62- is
a) SO32- < SO42- < S2O42-< S2O62- b) SO42- < S2O42- < S2O62-< SO32-
c) S2O42- < SO32- < S2O62-< SO42- d) S2O62- < S2O42- < SO42-< SO32-
17. The equivalent mass of ferrous oxalate is
molar mass of ferrous oxalate molar mass of ferrous oxalate
a) 1
b) 2
mola rmass of ferrous oxlate
c) d) None of these
3
18. If Avogadro number were changed from 6.022 × 1023to 6.022 x 1020, this would change
a) the ratio of chemical species to each other in a
b) the ratio of elements to each other in a compound
balanced equation
c) the definition of mass in units of grams d) the mass of one mole of carbon
19. Two 22.4 litre containers A and B contains 8 g of O2 and 8 g of SO2 respectively at 273 K and 1 atm pressure, then
a) Number of molecules in A and B are same b) Number of molecules in B is more than that in A
c) The ratio between the number of molecules in A to d) Number of molecules in B is three times greater than
number of molecules in B is 2:1 the number of molecules in A
20. What is the mass of precipitate formed when 50 ml of 8.5 % solution of AgNO3 is mixed with 100 ml of 1.865 % potassium
chloride solution?
a) 3.59 g b) 7 g c) 14 g d) 28 g
21. The mass of a gas that occupies a volume of 612.5 ml at room temperature and pressure (25o c and 1 atm pressure) is 1.1g.
The molar mass of the gas is
a) 66.25 g mol-1 b) 44 g mol-1
c) 24.5 g mol-1 d) 662.5 g mol-1
22. Which of the following contain same number of carbon atoms as in 6 g of carbon-12.
a) 7.5 g ethane b) 8 g methane
c) both (a) and (b) d) none of these
23. Which of the following compound(s) has /have percentage of carbon same as that in ethylene (C2H4)
a) propene b) ethyne c) benzene d) ethane
24. Which of the following is/are true with respect to carbon -12.
a) relative atomic mass is 12 u b) oxidation number of carbon is +4 in all its compounds
22
c) 1 mole of carbon-12 contain 6.022 × 10 carbon
d) all of these
atoms
25. Which one of the following is used as a standard for atomic mass.
a) 6C12 b) 7C12
c) 6C13 d) 6C14
26. Which one of the following is the standard for atomic mass?
a) 1H1 b) 6C12
c) 6C14 d) 8016
27. One mole of CO2 contains:
a) 6.023 x 1023 atoms of C b) 6.023 x 1023 atoms of 0
23
c) 18.1 x 10 molecules of CO2 d) 3g atoms of CO2
28. The largest number of molecules is in:
a) 54g of nitrogen pentoxide b) 28g of carbon dioxide
c) 36g of water d) 46g of ethyl alcohol
29. The empirical formula and molecular mass of a compound are CH2O and 180g respectively. What will be the molecular
formula of the compound?
a) C9H19O b) CH2O
c) C6H12O6 d) C2H4O2
30. How much volume of CO2 is produced when 50 g of CaCO3 is heated strongly?
a) 2.24 × 10-2m3 b) 22.4 L
c) 11.2 L d) 22400 cm3
31. Which of the following contains same number of carbon atoms as are in 6.0g of carbon (C-12)?
a) 6.0g ethane b) 8.0g methane
c) 21.0g Propane d) 28.0g CO
32. The mass of one mole of CaCl2 is ________.
a) 101 g mol-1 b) 111 g mol-1
c) 121 g mol-1 d) 131 g mol-1
33. Equal volume of N2 and H2 react to form ammonia under suitable condition then the limiting reagent is
a) H2 b) N2
c) NH3 d) No reactant is a limiting regent
34. In a compound C, H and N atoms are present in 9: 1: 3.5 by weight. Molecular weight of compound is 108. Molecular formula
of compound is
a) C2H6N2 b) C3H4N
c) C6H8N2 d) C9H12N3
35. A compound has an empirical formula C2H4O .If the value of n = 2 the molecular formula of the compound is _____________
.
a) C2H4O b) CH2O
c) CH2 d) C4H8O2
36. Statement I :. Equivalent mass of Mg is determined by Oxide Method.
Statement II : Molecular mass is calculated using vapour density.
b) Both the statements are individually true and statement
a) Both the statements are individually true
II is the correct explanation of statement I .
c) Statement I is true but statement II is false . d) Statement I is false but statement II is true .
37. 12g of Mg (at. mass 24) will react completely with acid to give
a) One mole of H2 b) 1/2 mole of H2
c) 2/3 mole of O2 d) Both 1/2 mol of H2 and 1/2 mol of O2
38. The number of molecule at NTP in 1 ml of an ideal gas will
a) 6x1023 b) 2.69x1019
c) 2.69x10 23 d) None of these
39. Match the List-I and List-II using the correct code given below the list.
List-I (Empirical formula) List-II (Molecular formula)
A. Benzene - CH 1. H2O2
B. Fructose-CH2O 2. C2H2
C. Acetylene - CH 3. C6H6
D. Hydrogen peroxide-OH 4. C2H12O6
a) A - 4, B - 1, C - 3, D - 2 b) A - 3, B - 4, C - 1, D - 2
c) A - 4, B - 3, C - 2, D - 1 d) A - 3, B - 4, C - 2, D - 1
40. One mole of CO2 contains:
a) 6.023 x 1023 atoms of C b) 6.023 x 1023 atoms of 0
23
c) 18.1 x 10 molecules of CO2 d) 3g atoms of CO2
41. 10 11
Boron has two isotopes, B(19%) and B(81%). Calculate average at. wt. of boron in the periodic table
a) 10.8 b) 10.2 c) 11.2 d) 10.0
42. What weight of SO2 can be made by burning sulphur in 5.0 moles of oxygen
a) 640 grams b) 160 grams c) 80 grams d) 320 grams
43. The percentage weight of Zn in white vitriol [ZnSO4 .7H2O] is approximately equal to (Zn 65,S 32,O 16 and H = 1)
a) 33.65% b) 32.56% c) 23.65% d) 22.65%
44. Equivalent weight of a bivalent metal is 37.2. The molecular weight of its chloride is
a) 412.2 b) 216 c) 145.4 d) 108.2
45. 1.520 g of the hydroxide of a metal on ignition gave 0.995 gm of oxide. The equivalent weight of metal is
a) 1.520 b) 0.995 c) 19.00 d) 9.00
46. In the reaction, 4NH3 + 5O2 --------> 4NO + 6H2O when 1 mole of ammonia and 1 mole of O2 are made to react to
completion.
a) All the oxygen will be consumed b) 1.0 mole of NO will be produced
c) 1.0 mole of H2O is produced d) All the ammonia will be consumed
47. 24
The number of gram molecules of oxygen in 6.02 × 10 CO molecules is
a) 10 gm molecules b) 5 gm molecules
c) 1 gm molecules d) 0.5 gm molelcules
48. How many molecules are present in one gram of hydrogen
a) 6.02x1023 b) 3.01x1023
c) 2.5x1023 d) 1.5x1023
49. The number of molecules in 16g of methane is __________.
a) 6.23×1023 b) 6.23×1022
c) 6.023×1020 d) 6.023×1023
50. An organic compound contaicarbon, hydrogen and oxygen. It elemental analysis gave C, 38.71% and H, 9.67%. The empirical
formula of the compound would be
a) CHO b) CH4O c) CH3O d) CH2O
51. The largest number of molecules is in
a) 34g of water b) 28g of CO2
c) 46g of CH3OH d) 54g of N2O5
52. Which one of the following is not a redox reaction?
a) Rusting of iron b) Electroplating
c) Extraction of metal Na d) Aluminothermic process
53. Calculate the percentage of N in ammonia molecule .
a) 121.42% b) 28.35% c) 82.35% d) 28.53%
54. The number of moles of H2 in 0.224 litre of hydrogen gas at STP is ________.
a) 0.1 b) 0.01 c) 0.001 d) 1
55. The mass of an atom of nitrogen is ________.
14 16
a) b)
6.023×1023 6.023×1023
18 20
c) d)
6.023×1023 6.023×1023
56. A compound (80 g) on analysis gave C = 24 g, H = 4 g, O = 32 g. Its empirical formula is
a) C2H2O2 b) C2H2O
c) CH2O2 d) CH2O
57. Statement-1: Volume of a gas is inversely proportional to the number of moles of gas. Statement-2: The ratio by volume of
gaseous reactants and products is in agreement with their mole ratio.
a) Statement- 1 is True, Statement-2 is True, Statement-2 b) Statement -1 is True, Statement -2 is True; Statement-2
is a correct explanation for Statement -1 is NOT a correct explanation for Statement - 1
c) Statement - 1 is True, Statement- 2 is False d) Statement -1 is False, Statement -2 is True
58. Which has maximum molecules?
a) 7 g N2 b) 2g H2
c) 16g NO2 d) 16g O2
59. Calculate the volume at STP occupied by 240 gm of SO2
a) 64 b) 84 c) 59 d) 73
60. The volume occupied by 4.4 g of CO2 at STP is
a) 22.4 L b) 2.24 L c) 0.224 L d) 0.1 L
61. What should be the equivalent weight of phosphorous acid, if P=31; O=16; H=1
a) 82 b) 41 c) 20.5 d) None of these
62. 5.6 litres of oxygen at STP is equivalent to ________.
a) 1 mole b) 1/2 mole c) 1/3 mole d) 1/4 mole
63. The number of molecules in 40 g of sodium hydroxide is __________.
a) 6.023 × 1023 b) 6.023 × 1022
c) 6.23 × 10 22 d) 6.23 × 1023
64. The simplest formula of a compound containing 50% of element X (atomic mass 10) and 50% of element Y (atomic mass 20)
is
a) XY b) X2Y
c) XY3 d) X2Y3
65. Assertion : When 4 moles of H2 reacts with 2 moles of O2 , then 4 moles of water is formed.
Reason : O2 will act as limiting reagent.
a) Both assertion and reason are true and reason is the b) Both assertion and reason are true but reason is not the
correct explanation of assertion correct explanation of assertion
c) Only assertion is true but reason is false d) Both assertion and reason are false
66. How many grams are contained in 1 gram atom of Na?
a) 1 g b) 13 g c) 23 g d) 1/23 g
67. Assertion :Molecular weight of oxygen is 16. Reason: Atomic weight of oxygen is 16.
c) If
assertion
a) If both assertion and reason are true and the b) If both assertion and reason are true but reason is is true
reason is the correct explanation of the assertion not the correct explanation of the assertion but
reason is
false
d) If the assertion and reason both are false. e) If assertion is false but reason is true.
68. Which one of the following pairs of gases contains the same number of molecules
a) 16 g of O2 and 14 g of N2 b) 8 g of O2 and 22 g of CO2
c) 28 g of N2 and 22 g of CO2 d) 32 g of O2 and 32 g of N2
69. The oxidation number of carbon is zero in ______.
a) HCHO b) C12H22O11
c) C6H12O6 d) all the above
70. The oxidation state of a substance in its elementary state is equal to ________.
a) 0 b) 1 c) 2 d) 4
71. The compound in which mass percentage of carbon is 75% and that of hydrogen is 25% is
a) C2H6 b) C2H2
c) CH4 d) C2H4
72. Which one of the following is an example for disproportionation reaction?
a) CuSO4 +Zn → ZnSO4 + Cu b) 2KCIO3 → 2KCl + 3O2
c) PCI5 → PCI3 + Cl2 d) 4H3PO3→ 3H3PO4 + PH3
73. Which of the following contains maximum number of atoms
a) 6.023x1021 molecules of CO2 b) 22.4 L of CO2 at STP
c) 0.44 g of CO2 d) None of these
74. Give an example of molecule in which the ratio of the molecular formula is six times the empirical formula .
a) C6H12O6 b) CH2O
c) CH4 d) Na2CO3
75. Assertion: Atomicity of oxygen is 2. Reason: 1 mole of an element contains 6.023x1023 atoms.
c) If
assertion
a) If both assertion and reason are true and the b) If both assertion and reason are true but reason is is true
reason is the correct explanation of the assertion. not the correct explanation of the assertion. but
reason is
false
d) If the assertion and reason both are false. e) If assertion is false but reason is true
76. 2+
The mass in grams of 0.45 mole of Ca ions ___________.
a) 14 b) 16 c) 18 d) 20
77. Choose the incorrect statement.
a) Empirical formula shows the actual number of atoms b) Ozone (O3) is another form of oxygen gas at room
of different elements in one molecule of the compound. temperature.
d) Pressure is defined as force divided by the area to
c) Gases are easily compressible.
which the force is applied.
78. What amount of dioxygen (in gram) contains 1.8 × 1022 molecules?
a) 0.0960 b) 0.960 c) 9.60 d) 96.0
79. Match the list-I with list-II and select the correct answer using the code given below the lists.
List-I List-II
A Molecular formula 1 Completely consumed
B Stoichiometric Equation 2 Left unreacted
C Limiting reagent 3 n x Empirical formula
D Excess reagent 4 Balanced equation
a) 3 4 2 1 b) 3 4 1 2 c) 4 3 2 1 d) 4 3 1 2
80. Which property of an element is always a whole number
a) Atomic weight b) Equivalent weight
c) Atomic number d) Atomic volume
81. Match list I with list II and identify the correct code.
List I List II
A Bronze 1 Element
B Table salt 2 Homogeneous mixture
C Gold 3 Alloy
D Petrol 4 Compound
a) 1 4 2 3 b) 3 4 1 2 c) 2 3 4 1 d) 4 2 3 1
82. The oxidation number of fluorine in all its compounds is equal to _______.
a) -1 b) +1 c) -2 d) +2
83. The equivalent mass of NaCl is ________.
a) 40 b) 58.5 c) 35.5 d) 23
84. Two elements X and Y ( atomic mass of X = 75 ; Y = 16) combine to give a compound having 76% of X. The formula of the
compound is?
a) XY b) X2Y
c) X2Y2 d) X2Y3
85. Which of the following contains only one element
a) Marble b) Diamond c) Glass d) Sand
86. 12 g of carbon-12 contains _______________ carbon atoms.
a) 6.022 x 1023 b) 6
c) 12 d) 12.022 x 1023
87. The percentage of oxygen in NaOH is
a) 40 b) 60 c) 8 d) 10
88. Total number of atoms represented by the compound CuSO4.5H2O is
a) 27 b) 21 c) 5 d) 8
89. 3 g of an oxide of a metal is converted to chloride completely and it yielded 5 g of chloride. The equivalent weight of the
metal is
a) 3.325 b) 33.25 c) 12 d) 20
90. Equivalent mass of KMnO4 in acidic medium, concentrated alkaline medium and dilute basic medium respectively are M/5,
M. Reduced products can be:
a) MnO2, MnO42-, Mn2+ b) MnO2, Mn2+, MnO42-
c) Mn2+, MnO2, MnO42- d) Mn2+,MnO42-, MnO2
91. Match the List-I and List-II using the correct code given below the list.
List-I List-II (Molecular formula)
A. Molar volume 1. Atomic mass / Valency
B. Avogadro Number 2. 2 × Vapour density
C. Equivalent mass 3. 2.24 × 10-2m3
D. Molecular mass 4. 6.023 x 1023
a) A - 3, B - 4, C - 2, D - 1 b) A - 4, B - 3, C - 2, D - 1
c) A - 2, B - 1, C - 4, D - 3 d) A - 3, B - 4, C - 1, D - 2
92. The equivalent mass of potassium permanganate in alkaline medium is MnO-4 + 2H2O+3e-- → MnO2 + 4OH-
a) 31.6 b) 52.7 c) 79 d) None of these
93. Assertion (A) : Among halogens fluorine is the best oxidant.
Reason (R) : Fluorine is the most electronega-tive atom
a) Both A and R are true and R explains A b) Both A and R are true but R does not explain A
c) A is true but R is false d) Both A and R are false
94. Among the three metals , zinc , copper and silver , the electron releasing tendency decreases in the following order .
a) zinc > silver > copper b) zinc > copper > silver
c) silver > copper > zinc d) copper > silver > zinc
-
95. Number of valency electrons in 4.2 gram of N3 ion is
a) 4.2 NA b) 0.1 NA
c) 1.6 NA d) 3.2 NA
96. The number of moles of sodium oxide in 620g of it is
a) 1 mol b) 10 moles c) 18 moles d) 100 moles
97. Sulphur forms the chlorides S2Cl2 and SCl2. The equivalent mass of sulphur in SCl2 is
a) 8 g/mol b) 16 g/mol c) 64.8 g/mol d) 32 g/mol
98. One mole of Sulphuric acid contains _______ oxygen atoms .
a) 4 x 1023 b) 4 x 6.023 x 10-23
c) 4 x 6.023 x 10 23 d) 4 x 6.023 x 1032
99. 12 L of H2 and 11.2 L of Cl2 are mixed and exploded. Find the composition by volume of mixture.
a) 11.2, 11.2, 22.4 b) 0.8, 0, 22.4
c) 0.8, 0.8, 22.4 d) 0.8, 11.2, 22.4
100. When 22.4 litres of H2 is mixed with 11.2 litres of Cl2, each at S.T.P, the moles of hCl formed is equal to
a) 1 mol of HCl(g) b) 2 mol of HCl(g)
c) 0.5 mol of HCl(g) d) 1.5 mol of HCl(g)