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1a._Homework_Sheet-_Chemical_Kinetics_-_Google_Docs

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kittylily0011
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‌EKYA‌‌SCHOOLS/CMR‌‌NATIONAL‌‌PUBLIC‌‌SCHOOL‌

‌ R‌‌XII‌‌CHEMISTRY‌
G ‌‌
‌Homework‌‌Sheet-‌‌Chemical‌‌Kinetics‌ ‌
1‌ Define‌‌the‌‌term‌‌chemical‌‌kinetics.‌ ‌

2‌ ‌ Define‌‌the‌‌rate‌‌of‌‌reaction.‌ ‌

3‌ ‌ What‌‌is‌‌the‌‌average‌‌rate‌‌of‌‌a‌‌reaction?‌‌How‌‌is‌‌it‌‌determined?‌ ‌

4‌ ‌ What‌‌are‌‌the‌‌units‌‌of‌‌the‌‌rate‌‌of‌‌reaction?‌ ‌

5‌ ‌ What‌‌is‌‌the‌‌instantaneous‌‌rate‌‌of‌‌reaction?‌‌How‌‌is‌‌it‌‌determined?‌ ‌

6‌ ‌ For‌‌the‌‌following‌‌reactions,‌‌write‌‌the‌‌rate‌‌of‌‌reaction‌‌expression‌‌in‌‌terms‌‌of‌‌reactants‌‌
and‌‌products?‌ ‌

7‌ ‌ For‌‌the‌‌chemical‌‌decomposition‌‌of‌‌SO‌2‌Cl‌2‌,‌‌its‌‌initial‌‌concentration‌‌is‌‌0.8420‌‌mol/L‌‌
and‌‌the‌‌final‌‌concentration‌‌is‌‌0.215‌‌mol/L‌‌in‌‌2‌‌hours.‌‌What‌‌is‌‌the‌‌average‌‌rate‌‌of‌‌this‌‌
reaction?‌ ‌

8‌ ‌ In‌‌the‌‌expression‌‌of‌‌the‌‌rate‌‌of‌‌reaction‌‌in‌‌terms‌‌of‌‌reactants,‌‌what‌‌is‌‌the‌‌significance‌‌
of‌‌the‌‌negative‌‌sign?‌ ‌

9‌ ‌ For‌‌the‌‌reaction,‌ ‌
was‌‌found‌‌to‌‌be‌‌5.0‌‌x‌‌10‌-4‌‌ ‌atm/s.‌‌Determine‌‌the‌‌value‌‌of‌‌△[O‌3‌]‌

/△t‌‌in‌‌atm/s‌‌during‌‌this‌‌period‌‌of‌‌time?‌ ‌

10‌ ‌ A‌‌chemical‌‌reaction‌‌2A‌⇔ ‌ 4B‌‌+‌‌C‌‌in‌‌the‌‌gas‌‌phase‌‌occurs‌‌in‌‌a‌‌closed‌‌vessel.‌‌The‌‌


concentration‌‌of‌‌B‌‌is‌‌found‌‌to‌‌be‌‌increased‌‌by‌‌5‌‌x‌‌10‌-3‌‌ ‌mol‌‌L-1‌
‌ ‌ ‌in‌‌10‌‌seconds.‌‌Calculate‌‌
(i)‌‌the‌‌rate‌‌of‌‌appearance‌‌of‌‌B‌‌(ii)‌‌the‌‌rate‌‌of‌‌disappearance‌‌of‌‌A.‌ ‌

11‌ ‌ A‌‌reaction‌‌of‌‌second‌‌order‌‌with‌‌respect‌‌to‌‌a‌‌reactant.‌‌How‌‌will‌‌the‌‌rate‌‌of‌‌the‌‌reaction‌‌
be‌‌affected‌‌if‌‌the‌‌concentration‌‌of‌‌this‌‌reactant‌‌is:‌‌(i)‌‌Doubled,‌‌(ii)‌‌Reduced‌‌to‌‌half ?‌ ‌

12‌ ‌ The‌‌rate‌‌of‌‌the‌‌chemical‌‌reaction‌‌doubles‌‌for‌‌an‌‌increase‌‌of‌‌10K‌‌in‌‌absolute‌‌
temperature‌‌from‌‌298K.‌‌Calculate‌‌E‌a‌.‌ ‌

13‌ ‌ Nitrogen‌‌pentoxide‌‌decomposes‌‌according‌‌to‌‌the‌‌equation:‌‌ ‌
𝟐𝐍‌𝟐‌𝐎‌𝟓‌‌ ‌(𝐠)‌⟶
‌ ‌‌𝟒𝐍𝐎‌𝟐‌‌ ‌(𝐠)‌‌+‌‌𝐎𝟐‌
‌ ‌ ‌(𝐠).‌‌This‌‌first-order‌‌reaction‌‌was‌‌allowed‌‌to‌‌proceed‌‌at‌‌
𝟒𝟎℃,‌‌and‌‌the‌‌data‌‌below‌‌were‌‌collected:‌ ‌‌
‌
‌
‌

Homework‌‌Sheet-‌‌Chemical‌‌Kinetics‌ ‌1‌ ‌
𝑵𝟐𝑶𝟓‌‌](𝑴)‌ ‌ ‌‌Time‌‌(min)‌‌ ‌
0.400‌ ‌0.00‌‌ ‌
0.289‌ ‌20.0‌ ‌
0.209‌ ‌40.0‌ ‌
0.151‌ ‌60.0‌ ‌
0.109‌ ‌80.0‌ ‌
(a)‌‌Calculate‌‌the‌‌rate‌‌constant.‌‌Include‌‌units‌‌with‌‌your‌‌answer.‌ ‌
‌(b)‌‌What‌‌will‌‌be‌‌the‌‌concentration‌𝑵 ‌ 𝟐‌
‌ 𝑶‌𝟓‌after‌
‌ ‌100‌‌minutes?‌ ‌
‌(c)‌‌Calculate‌‌the‌‌initial‌‌rate‌‌of‌‌reaction.‌ ‌

14‌ ‌ The‌‌rate‌‌constant‌‌for‌‌the‌‌first-order‌‌decomposition‌‌of‌𝑯 ‌ 𝟐‌
‌ 𝑶‌𝟐‌‌ ‌is‌‌given‌‌by‌‌the‌‌following‌‌
4
equation:‌‌𝒍𝒐𝒈‌‌𝑲‌‌=‌𝟏 ‌ 𝟒.𝟐−𝟏.𝟎‌‌×𝟏𝟎‌ /‌‌𝑻‌‌𝑲.‌‌Calculate‌‌𝑬 𝒂‌‌for‌‌this‌‌reaction‌‌and‌‌rate‌‌
constant‌‌k‌‌if‌‌its‌‌half-life‌‌period‌‌is‌‌256‌‌minutes.‌‌(Given:‌‌R‌‌=‌‌8.314‌𝑱‌ 𝑲−𝟏𝒎𝒐𝒍‌−𝟏‌‌ ‌).‌ ‌

15‌ ‌ (a)‌‌For‌‌a‌‌reaction‌‌A‌‌+‌‌B‌⟶‌ ‌‌P,‌‌the‌‌rate‌‌is‌‌given‌‌by‌‌Rate=‌𝒌‌ [𝑨][𝑩]‌‌𝟐‌ ‌ ‌


(i)‌‌How‌‌is‌‌the‌‌rate‌‌of‌‌reaction‌‌affected‌‌if‌‌the‌‌concentration‌‌of‌‌B‌‌is‌‌doubled?‌‌ ‌
(ii)What‌‌is‌‌the‌‌overall‌‌order‌‌of‌‌reaction‌‌if‌‌A‌‌is‌‌present‌‌in‌‌large‌‌excess?‌‌ ‌
(b)‌‌Distinguish‌‌between‌‌reaction‌‌rate‌‌and‌‌reaction‌‌rate‌‌constant‌‌(specific‌‌reaction‌‌rate)‌‌
of‌‌a‌‌reaction.‌ ‌

16‌ ‌ (a)‌𝑨 ‌ ‌‌+‌‌𝟐𝑩‌‌⟶‌‌𝟑𝑪‌‌+‌𝟐 ‌ 𝑫.‌‌The‌‌ratio‌‌of‌‌the‌‌disappearance‌‌of‌‌B‌‌is‌‌×‌𝟏 ‌ 𝟎‌−𝟐‌‌ ‌𝒎𝒐𝒍/𝑳/s.‌‌


What‌‌will‌‌be‌ ‌
(i)‌‌Rate‌‌of‌‌the‌‌reaction‌‌ ‌
(ii)‌‌Rate‌‌of‌‌change‌‌in‌‌concentration‌‌of‌‌A‌‌and‌‌C?‌‌ ‌
(b)‌T ‌ he‌‌decomposition‌‌of‌‌phosphine,‌‌PH‌3‌,‌‌proceeds‌‌according‌‌to‌‌the‌‌following‌‌
equation:‌ ‌
‌𝟒𝑷𝑯‌𝟑‌(𝒈)‌‌⟶‌‌𝑷𝟒‌ ‌ (𝒈)‌‌+‌‌𝟔𝑯‌𝟐‌(𝒈)‌‌ ‌
It‌‌is‌‌found‌‌that‌‌the‌‌reaction‌‌follows‌‌the‌‌following‌‌rate‌‌equation:‌ ‌
‌ 𝑯‌𝟑‌‌ ‌is‌‌37.9‌‌s‌‌at‌‌𝟏𝟐𝟎‌o‌𝑪.‌‌ ‌
‌𝑹𝒂𝒕𝒆‌‌=‌‌𝒌[𝑷𝑯‌𝟑‌‌ ‌].‌‌The‌‌half-life‌‌of‌𝑷
(i)‌‌How‌‌much‌‌time‌‌is‌‌required‌‌for‌‌𝟑/𝟒𝒕𝒉‌‌of‌𝑷 ‌ 𝑯‌𝟑‌‌ ‌to‌‌decompose?‌‌ ‌
(ii)‌‌What‌‌fraction‌‌of‌‌the‌‌original‌‌sample‌‌of‌𝑷 ‌ 𝑯‌𝟑‌remains‌
‌ ‌behind‌‌after‌‌1‌‌minute?‌ ‌
‌
‌
‌
‌
‌
‌
‌
‌

Homework‌‌Sheet-‌‌Chemical‌‌Kinetics‌ ‌2‌ ‌

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