Chemistry

1. Identify the phase of solute and solvent for a 9. A 5.2 molal aqueous solution of methyl alcohol,
solution of amalgam of mercury with sodium. CH3OH is supplied. What is the mole fraction of
Solute Solvent methyl alcohol in the solution?
(a) Tetrasporangiate Liquid (a) 1.100
(b) Bisporangiate Solid (b) 0.090
(c) Trisporangiate Solid (c) 0.086
(d) Monosporangiate Gas (d) 0.050
2. Which of the following is dependent of 10. 25.3 g of sodium carbonate, Na2CO3 is
temperature? dissolved in enough water to make 250 mL of
(a) Molality solution. If sodium carbonate dissociates
(b) Molarity completely, molar concentration of sodium ions,
(c) Mole fraction Na+ and carbonate ions, CO32 respectively are
(d) Weight percentage (Molar mass of Na2CO3 = 106 mole–1)
3. What is the percentage of solute in the resultant (a) 0.477 M and 0.477 M
solution, if it is obtained by mixing 300g of 30% (b) 0.955 M and 1.910 M
and 200g of 20% solution by weight? (c) 1.910 M and 0.955 M
(a) 50% (d) 1.90 M and 1.910 M
(b) 26% 11. How many gram of concentrated nitric acid
(c) 62% solution should be used to prepare 250 mL of 2.0
(d) 32% M HNO3? The concentrated acid is 70% HNO3.
4. 184g ethyl alcohol is mixed with 72g of water. (a) 45.0 g conc. HNO3
The ratio of mole fraction of alcohol to water is (b) 90.0 g conc. HNO3
(a) 3 : 4 (c) 70.0 g conc. HNO3
(b) 1 : 2 (d) 50.0 g conc. HNO3
(c) 1 : 4 12. For a solution of gases in a solvent, consider a
(d) 1 : 1 system as show below:
5. The Na+ ions present in 200 mL of 0.5 M of
NaCl solution is
(a) 6.023 × 1020
(b) 6.023 × 1024
(c) 6.023 × 1022
(d) 6.02 × 1025
6. If molarity of Cu+2 ions is 3 × 10–4, then express
this in ppm Which of the following beaker will have the
(a) 0.3 greater solubility of a gas?
(b) 0.2 (a) Beaker B
(c) 0.1 (b) Beaker A
(d) 0.6 (c) Both will have same solubility
7. Molarity of one litre solution of 22.2g CaCl2 is (d) Solubility remains unaffected by change
(a) 0.4 M in weights
(b) 0.2 M 13. The value of Henry’s law constant for helium
(c) 0.8 M (He), hydrogen (H2) and oxygen (O2) are
(d) 0.6 M respectively 144.97 K bar, 69.16 K bar and 34.86
8. 6.02 × 1020 molecules of urea are present in 100 K bar at 293 K. The correct order of their
mL of its solution. The concentration of solution solubility is
is (a) O2 < He < H2
(a) 0.02 M (b) He < O2 < H2
(b) 0.01 M (c) He < H2 < O2
(c) 0.001 M (d) H2 < He < O2
(d) 0.1 M
 Chemistry

14. Calculate the concentration of nitrogen present (a) 76.0

in the water. Assuming that, the temperature is (b) 752.4
25°C, total pressure is 1 atm and mole fraction (c) 759.0
of nitrogen is 0.78. [KH for nitrogen = 8.42 × 10– (d) 7.6
7
M/mm Hg] 19. One component of a solution follows Raoult’s
(a) 4.99 M law over the entire range 0 < x1 < 1 The second
(b) 4.99 × 10–2 M component must follow Raoult’s law in the
(c) 4.99 × 10–4 M range when x2 is
(d) None of these (a) Close to zero
15. Ratio of O2 and N2 in the air is 1 : 4. Find out (b) Close to 1
the ratio of their solubilities in terms of mole (c) 0 < x2 < 0.5
fractions of O2 and N2 dissolved in water at (d) 0 < x2 < 1
atmospheric pressure and room temperature. 20. Solution of bromoethane and chloroethane
 K H (O2 )  3.30  107 torr  (a) Obeys Raoult’s law over the entire
  range of concentration
 K H (N 2 )  6.60  10 torr 
7
(b) Is a non-ideal solution
(a) 1 : 2 (c) Has ∆mixV ≠ 0
(b) 2 : 1 (d) All of the above
(c) 1 : 1 21. For a binary ideal liquid solution, the variation
(d) None of these in total vapour pressure versues composition of
16. When a binary solution of two volatile liquids is solution is given by which of the curves?
taken in a closed vessel, then
(a) Both the components would evaporate
and an equilibrium would be established
between vapour phase and liquid phase (a)
(b) Both the components would evaporate
but equilibrium would not be
established between vapour phase and
liquid phase
(c) None of components would evaporate
and no equilibrium would be established
(b)
between vapour phase and liquid phase
(d) None of the above
17. What does A point signifies in the figure given
below?

(c)

(d) Both (a) and (b)

22. The vapour pressure of pure CHCl3 and CH2Cl2
are 200 and 41.5 atm respectively. The weight of
CHCl3 and CH2Cl2 are respectively 11.9g and
(a) Vapour pressure of solute 17g. The vapour pressure of solution will be
(b) Vapour pressure of pure solvent (a) 80.5 atm
(c) Vapour pressure of solution (b) 79.5 atm
(d) None of the above (c) 94.3 atm
18. 18 g of glucose (C6H12O6) is added to 178.2g (d) 105.5 atm
water. The vapour pressure of water (in torr) for
this aqueous solution is
 Chemistry

23. If the total vapour pressure formed by mixing (c) 0.435

25.5g of CHCl3 and 40g of CH2Cl2 at 298 K is (d) 0.205
347.9 mm Hg, then the mole fraction of each 29. If molality of the dilute solution is doubled, the
component in vapour phase will be [given value of molal depression constant (Kf) will be
p°CH2Cl2 = 415 mm Hg and p°CHCl3 = 200 mm (a) Doubled
Hg] (b) Halved
(a) yCH2Cl2 = 0.285 yCHCl3 = 0.715 (c) Tripled
(b) yCH2Cl2 = 0.18 yCHCl3 = 0.82 (d) Unchanged
(c) yCH2Cl2 = 0.82 yCHCl3 = 0.18 30. Ethylene glycol is used as an antifreeze in a cold
(d) yCH2Cl2 = 62.4 yCHCl3 = 0.376
climate. Mass of ethylene glycol which should
24. The solution which show large positive
be added to 4 kg of water to prevent it from
deviation from Raoult’s law form
freezing at –6°C will be (Kf for water = 1.86 K
(a) Maximum boiling azeotrope at a
specific composition kg mol–1 and molar mass of ethylene glycol = 62
(b) Maximum freezing azeotrope at a g mol–1)
specific composition (a) 804.32 g
(c) Minimum boiling azeotrope at a specific (b) 204.30 g
composition (c) 400.00 g
(d) Minimum freezing azeotrope at a (d) 304.60 g
specific composition 31. How many grams of methyl alcohol should be
25. The solution that forms maximum boiling added to 10 L tank of water to prevent its
azeotrope is freezing at 268 K?
(a) carbon disulphide – acetone (a) 880.07 g
(b) benzene – toluene (b) 899.04 g
(c) acetone – chloroform (c) 886.02 g
(d) n-hexane – n-heptane
(d) 868.06 g
26. At room temperature, a dilute solution of urea is
32. The van’t Hoff factor for 0.1 M Ba(NO3)2
prepared by dissolving 0.60g of urea in 360g of
solution is 2.74. The degree of dissociation is
water. If the vapour pressure of pure water at this
temperature is 35mm Hg, lowering of vapour (a) 91.3%
pressure will be (b) 87%
(Molar mass of urea = 60g mol–1) (c) 100%
(a) 0.027 mm Hg (d) 74%
(b) 0.031 mm Hg 33. The van’t Hoff factor (i) for a compound which
(c) 0.017 mm Hg undergoes dissociation in one solvent and
(d) 0.028 mm Hg association in other solvent is respectively
27. Lowering of vapour pressure of an aqueous (a) Greater than one and greater than one
solution of a non-volatile, non-electrolyte 1M (b) Less than one and greater than one
aqueous solution at 100°C is (c) Less than one and less than one
(a) 14.12 torr (d) Greater than one and less than one
(b) 312 torr 34. Benzoic acid undergoes dimerization in benzene
(c) 13.45 torr
solution. The van’t Hoff factor (i) is related to
(d) 352 torr
the degree of association ‘x’ of the acid as
28. Vapour pressure of pure benzene is 119 torr and
(a) i = (1 – x)
that of toluene is 37.0 torr at the same
temperature. Mole fraction of toluene in vapour (b) i = (1 + x)
phase which is in equilibrium with solution of  x
(c) i  1  
benzene and toluene having a mole fraction of  2
toluene 0.50, will be  x
(a) 0.137 (d) i  1  
 2
(b) 0.237
 Chemistry

35. If boiling point of water is 100°C. How much

grams of NaCl is added in 500 g of water to
increase its boiling point by approx 1°C?
[(Kb )H2 O  0.52K kg mol1 ]
(a) 2.812 g
(b) 28.12 g
(c) 14.06 g
(d) 7.03 g
36. Arrange the following aqueous solutions in the
order of their increasing boiling points.
I. 10–2 M NaCl
II. 10–3 M MgCl2
III. 10–4 M Urea
IV. 10–4 M NaCl
(a) I < II < IV < III
(b) III < IV < II < I
(c) II < I < III < IV
(d) IV < III < I < II
37. Of the following 0.10 m aqueous solutions,
which one will exhibit the largest freezing point
depression?
(a) KCl
(b) C6H12O6
(c) Al2(SO4)3
(d) K2SO4
38. Which of the following has least freezing point?
(a) 1% sucrose
(b) 1% NaCl
(c) 1% CaCl2
(d) 1% glucose
39. The van’t Hoff factor of BaCl2 at 0.01 M
concentration is 1.98. The percentage of
dissociation of BaCl2 at this concentration is
(a) 49
(b) 69
(c) 89
(d) 98
40. KBr is 80% dissociated in aqueous solution of
0.5 m concentration. (Given, Kf for water = 1.86
kg mol–1). The solution freezes at
(a) 271.326 K
(b) 272 K
(c) 270.5 K
(d) 268.5 K