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MM : 180 PRACTICE TEST_CHEMISTRY-01 Time : 60 Min.

Section-I

1. What would be the standard free energy change (ΔG ∘

) for the following reaction at 25°C
2Au(s) + 3Ca2(+) (1.0 M) 2Au3(+) (1.0 M) + 3Ca(s)
→

0 0
[E 0 I Ca = −2.87V; E 3⊕
= −1.50V]
Ca Au
I Au

(A) 1.26 × 103 kJ/mol (B) 793.230 kJ/mol

(C) 8.4 × 102 kJ/mol (D) 4.2 × 102 kJ/mol

2. The electrolyte used in hydrogen-oxygen fuel cell is

(A) Aqueous KCl (B) HCl
(C) Conc. aqueous NaOH (D) Aqueous Na2SO4

3. On dilution of strong electrolyte

(A) Λm increases while κ decreases (B) Λm decreases while κ increases
(C) Both Λm and κ decreases (D) Both Λm and κ increases

4. A : Equivalent conductance of all electrolytes decreases with increasing concentration.

R : The inverse of resistance (R) is called conductance (G).
(A) Both Assertion & Reason are true and the reason is the (B) Both Assertion & Reason are true but the reason is not the
correct explanation of the assertion correct explanation of the assertion
(C) Assertion is true statement but Reason is false (D) Both Assertion and Reason are false statements

5. For a spontaneous reaction ΔG, Kc and 0

E will be respectively
cell

(A) –ve, >1, +ve (B) –ve, >1, –ve

(C) +ve, >1, –ve (D) –ve, <1, –ve

6. A : Values of electrode potentials of all electrodes are calculated using SHE.

R : The standard potential of the cell can be obtained by taking the difference of the standard potentials of cathode and anode.
(A) Both Assertion & Reason are true and the reason is the (B) Both Assertion & Reason are true but the reason is not the
correct explanation of the assertion correct explanation of the assertion
(C) Assertion is true statement but Reason is false (D) Both Assertion and Reason are false statements

7. A : During discharging of lead storage battery, pH increases.

R : During discharging formation of PbO2 takes place which is basic oxide.
(A) Both Assertion & Reason are true and the reason is the (B) Both Assertion & Reason are true but the reason is not the
correct explanation of the assertion correct explanation of the assertion
(C) Assertion is true statement but Reason is false (D) Both Assertion and Reason are false statements

8. The resistance of 0.5 M solution of Na2SO4 is 200 ohm. If the cell constant is 5 cm–1, the specific conductance of the solution is
(A) 1.2 × 10
−2 (B) −1
2.5 × 10

(C) 4.0 × 10
1 (D) 2.5 × 10
−2

9. If 0.2 M CH3COOH has molar conductivity λm = 20 S cm

2
mol
−1
and the value of o
λm = 400
2
S cm −1
mol , then the value of
Ka(CH3COOH) will be
(A) 5 × 10–5 (B) 5 × 10–4
(C) 5 × 10–6 (D) 5 × 10–7

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PRACTICE TEST_CHEMISTRY-01

10. Select the cathode reaction taking place in dry cell.

(A) Zn2+(aq) + 2e– → Zn(s) (B) MnO (s) + NH + + e– → MnO(OH) + NH
2 4 3
(C) HgO + H O + 2e–→ Hg(l) + 2OH– (D) ZnO(s) + H O + 2e–→ Zn(Hg) + 2OH–
2 2

11. Identify the incorrect match with respect to the products obtained during the electrolysis of given aq. solution of electrolytes in
presence of Pt-electrodes.
Electrolytes Cathode Anode

(1) Na2SO4 H2(g) O2(g)

(2) KCl H2(g) Cl2(g)

(3) Cu(NO3)2 Cu(s) O2(g)

(4) H2SO4 H2(g) SO3(g)

(A) (1) (B) (2)

(C) (3) (D) (4)

12.
If 0
Λm ( CH3 COOH) = 390.7 S cm2 mol–1 and 0
λm ( H
+
) = 349.7 S cm2 mol–1 then 0 ¯¯
¯
λm (CH3 CO O) (in S cm2 mol–1) is

(A) 41 (B) 21
(C) 82 (D) 20.5

13. The resistance of 0.05 mol L–1 KOH solution present in a column of area of cross-section 0.750 cm2 and length 50 cm is 1 ×

102 Ω. The conductivity of solution is

(A) 2.48 S cm–1 (B) 1.48 S cm–1
(C) 0.67 S cm–1 (D) 0.18 S cm–1

14. The aqueous solution of which of the following is the best conductor of electric current?
(A) C6H12O6 (B) Na2SO4
(C) C12H22O11 (D) K4[Fe(CN)6]

15. For the following reactions :

X + Y ⇌P + Q, E° = A volt, Keq = K1
3X + 3Y ⇌3P + 3Q, E° = B volt, Keq = K2
Then correct relation will be
(A) A = B, K1 = K2 (B) A = 3 B, K1 = 3 K2
(C) A = 3B, K2 = K1
3 (D) 3
A = B1 K2 = K1

16. On the basis of the following E° values, the strongest reducing agent is
4− 3− −
[Fe (CN) ] → [Fe (CN) ] +e E° = −0 .35 V
6 6

2+ −
Fe(s) → Fe (aq) + 2e E° = 0.44 V

(A) Fe (B) Fe2+

(C) [Fe(CN) ]4– (D) [Fe(CN) ]3–
6 6

17. The electrolyte used in hydrogen-oxygen fuel cell is

(A) Aqueous KCl (B) HCl
(C) Conc. aqueous NaOH (D) Aqueous Na2SO4

18. For the given cell, Mg|Mg 2+(0.001M) || Cu2+(0.01M)/Cu the approximate value of equilibrium constant at 25°C will be
(Given E 0
= –2.32 V and E
M g 2+ /M9
= 0.34 V) 0
2+
Cu /Cu

(A) e90 (B) e60

(C) 1030 (D) 1090

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PRACTICE TEST_CHEMISTRY-01

19. At certain temperature molar conductance of 0.2 molar aqueous solution of a weak monoacidic hydroxide is 8.44 S cm2 mol–1

and at infinite dilution its molar conductance is 326 S cm2 mol–1. The degree of ionisation of weak monoacidic hydroxide at the
given concentration and same temperature is
(A) 2.59% (B) 20.90%
(C) 2.09% (D) 5.21%

20. In which of the following hydrogen electrode, half cell potential at 298 K is zero?
(A) Pt |H
+
(aq)(0.1 M)|H2 (g)(0.1 atm) (B) Pt |H
+
(aq)(2 M)|H2 (g)(2 atm)

(C) Pt |H
+
(aq)(2 M)|H2 (g)(4 atm) (D) Pt |H
+
(aq)(4 M)|H2 (g)(2 atm)

21. A dilute aqueous solution of Na2SO4 is electrolysed using platinum electrodes. The products at the anode and cathode are
respectively
(A) O2 and Na (B) O2 and H2
(C) S O 2– and H (D) S O 2– and Na
2 8 2 2 8

22. Cell potential of the cell

Ni | Ni2+(0.01 M) || Cu2+(0.1 M) | Cu is 0.58 V
Standard electrode potential of Ni2+|Ni electrode is (Given E 0
= – 0.34 V)
Oulcu*

(A) – 0.21 V (B) + 0.21 V

(C) – 0.92 V (D) +0.92 V

23. Standard reduction potential for Zn2+/Zn couple is –0.76 V and that for Mg2+/Mg is –2.36 V. These two couples in their standard
state are connected to make a cell. The cell potential will be
(A) 3.12 V (B) –3.12 V
(C) 1.6 V (D) –1.8 V

24. If equilibrium constant of the given galvanic cell is 1 × 10100 at 25°C then standard electrode potential of the cell will be M(s) +

N2+(aq) → M2+ (aq) + N(s)

(A) 1.5 V (B) 2.96 V
(C) 1.85 V (D) 2.50 V

25. Which of the following expression correctly represents the equivalent conductance of Al2(SO4)3 at infinite dilution? (Given that
λ and λ
o

Al
3+
are the molar conductance at infinite dilution of the respective ions)
o

SO
2−

(A) 3λ
o

Al
3+
+ 2λ
o

SO
2−
(B) 1
λ
o
3+
+
1
λ
o
2−
4 6 Al 6 SO
4

(C) 1
λ
o
3+
+
1
λ
o
2−
(D) λ
o
3+
+λ
o
2−
3 2 Al SO
Al SO 4
4

26. For a cell reaction involving a two electron change, the standard e.m.f of the cell is found to be 0.295 V at 25°C. The equilibrium
constant of the reaction at 25°C will be
(A) 10 (B) 1 × 10
10

(C) 1 × 10
−10
(D) 29.5 × 10
−2

27. If E
Ag
o
+
/Ag
= 0.8 V , E
o

C u2+ /Cu
= 0.34 V and E
o

C r3+ /Cr
= −0.7 V then select the correct statement among the following

(A) Ag can oxidize both Cu and Cr (B) Ag can oxidize Cu but not Cr
(C) Ag+ can oxidize Cu but not Cr (D) Cu2+ can oxidize Cr but not Ag

28. Electrolysis of aqueous NaCl solution using inert electrode liberates which substances at cathode and anode respectively?
(A) H2 and O2 (B) O2 and H2
(C) H2 and Cl2 (D) Cl2 and H2

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PRACTICE TEST_CHEMISTRY-01

29. The standard reduction potential of some elements are given

(a) Pb2+/Pb = – 0.13 V
(b) Fe2+/Fe = – 0.44 V
(c) Cu2+/Cu = 0.34 V
(d) Hg2+/Hg = 0.92 V
The elements which will release H2 gas on reaction with acid are
(A) a, b and c (B) a and b
(C) a and c (D) b, c and d

30. Number of Faraday required to produce 9 g of Al from Al2O3 is

(A) F (B) F

(C) 3 F (D) 9 F

31. An increase in molar conductance of CH3COOH with dilution is due to

(A) Increase in mobility of ions only (B) 100% ionisation of acetic acid at normal dilution
(C) Decrease in both number of ions and ionic mobility of H+ (D) Increase in number of ions as well as ionic mobility of ions

32. An aqueous solution containing 1 M each of Au3+, Cu2+, Ag+, Li+ is being electrolysed by using inert electrodes. The value of
standard potentials are
o o
E = 0.80 V E = 0.34 V
Ag + /Ag Cu
2+
/Cu

o o
E = 1.50 V E +
= −3.03 V
Au3+ /Au Li /Li

With increasing voltage, the sequence of deposition of metals on the cathode will be
(A) Li, Cu, Ag, Au (B) Cu, Ag, Au
(C) Au, Ag, Cu (D) Au, Ag, Cu, Li

33. A current of 96.5 A is passed for 18 minutes through 500 mL solution of 2 M CuSO using Pt electrodes. The molarity of Cu2+
4
ion after electrolysis would be (Consider volume constant)
(A) 0.25 M (B) 1.25 M
(C) 0.92 M (D) 0.46 M

34. Which is not true for a standard hydrogen electrode?

(A) The hydrogen ion concentration is 1 M (B) Temperature is 25°C
(C) Pressure of hydrogen is 1 atmosphere (D) It contains a metallic conductor which does not adsorb
hydrogen

35. In an electrolytic cell, flow of electrons is from

(A) Anode to cathode through internal supply (B) Cathode to anode through internal supply
(C) Anode to cathode in solution (D) Cathode to anode through external supply

36. Given
(i) A + 2e → A, E° = 0.2 V
2+ −

(ii) A + e → A , E° = 0.1 V
2+ − +

Electrode potential, E° for the reaction

A+ + e– → A, will be
(A) 0.1 V (B) 0.2 V
(C) 0.3 V (D) 0.4 V

37. Charge required for the reduction of 2 moles of −

MnO to MnO2 is (F = Faraday constant)
4

(A) 1.5 F (B) 3 F

(C) 6 F (D) 5 F

38. The emf of the cell

Fe(s)|Fe2+ (0.01 M)||H+(1M)|H2(g) (1 bar)|Pt(s) is
(E°Fe2+|Fe = –0.44 V)
(A) 0.1 (B) 0.5
(C) 0.7 (D) 0.22

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PRACTICE TEST_CHEMISTRY-01

39. RT
The Nernst equation, Ecell = Eo − ln Q
c
indicates that the Qc will be equal to equilibrium constant Kc when
cell nF

(A) o (B) RT/nF = 1

Ecell = E
cell

(C) Ecell = zero (D) o

E = 1
cell

40. The standard reduction potential for Cu2+ | Cu is + 0.34 V. The reduction potential of Cu2+|Cu electrode in saturated solution of
Cu(OH)2 at pH = 12 is
(Given that: Ksp of Cu(OH)2 is 1.0 × 10–20)
(A) + 0.19 V (B) –0.13 V
(C) + 0.35 V (D) –0.35 V

41. A : Rusting of iron is an example of corrosion.

R : Corrosion of iron occurs in presence of water and air.
(A) Both Assertion & Reason are true and the reason is the (B) Both Assertion & Reason are true but the reason is not the
correct explanation of the assertion correct explanation of the assertion
(C) Assertion is true statement but Reason is false (D) Both Assertion and Reason are false statements

42. Which of the following reactions takes place at anode of a mercury cell?
(A) Hg(l) + 2OH– → HgO + H O + 2e– (B) MnO(OH) + NH → MnO + NH + + e–
2 3 2 4
(C) Zn(Hg) + 2OH– → ZnO(s) + H O + 2e– (D) Zn(s) → Zn2++ 2e–
2

43. If conductivity of 0.1 mol/dm3 solution of KCl is 1.3 × 10–2 S cm–1 at 298 K then its molar conductivity will be
(A) 130 S cm2/mol (B) 250 S cm2/mol
(C) 75 S cm2/mol (D) 182 S cm2/mol

44. Equilibrium constant of a reaction at 25°C involving 2 electrons will be (Given, standard cell potential = 0.295 V)
(A) 10 (B) 1010
(C) 10–10 (D) 1

45. The quantity of electricity required to reduce 0.5 mole of MnO – to Mn2+ is
4
(A) 1.5 × 105 C (B) 2.4 × 105 C
(C) 3.4 × 105 C (D) 5.1 × 105 C