0% found this document useful (0 votes)
12 views7 pageshaloalkanes pyqs
Pyq
Uploaded by
ansh2153183Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
0% found this document useful (0 votes)
12 views7 pageshaloalkanes pyqs
Pyq
Uploaded by
ansh2153183Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
/ 7
(d) DDT: It is used as an insecticide. It is also called p,
world,
Pdichlorodiphenyltichloroethane, tg n
0
n-bj
an Motep
Chloral 13S04 itt hy
“che Fg t_ ke _
7 (O-1,0) a
1. In which of the following molecules C atom
marked with asterisk is chiral
|
c
@
ne L ss
@) Lm (b) 1.0, m1,1v
(©) 0,11, 1v (4) 1 TIL 1V. [cBsE 2024 Set-1)
2. Consider the following reaction :
LHBr
CHy—CH=CH,
CELT / ED
a.
ppt
The major end product is :
(a) CH; —CH —cH,
I
OH
© CHs—cH— cx,
Br
(©) CH;—CH,—CH,—on
(@ CH,—CH,—CH,—Br
[CBSE Board 2029
Which one of the following contains race
(a) Allythalide (by Alkyl halide
(6) Benzylhalide (4) Vinyl halide
{CBSE Board 2022 Term
|. Which of the following has highest boiling on
@) GH,-F (©) CHCl
(©.GH—Br @ GH
[CBSE Board 2022 Ter,
. Major product formed in the following reaction:
CH,
I
CH, —C—Br + NaOCH, —>
|
cH;
cH, ory
I
(a) CH; —C—ONa (b) CH; —C—OCH,,
|
I
CHs CH
(205 ASSIS iss 12 I I
_c-0—C—CH,
I
CH;
CH;
9 os
cu,
I
ah CH=CH; — [CBSE Board 2022 Term 1]
40
me. x22 y, Compound Yis:
—gi® Compound Y is:
oO
@
which of
elting point ?
i ulcholobenzene
{G)1, }dichlorobenzene
{0) 1 Sedichlorobenzene
(ail isomers have same melting points
[CBSE SQP Term 1 2022}
which of the following is a correct statement of
HBr?
{ Tereacts with metallic Na to give ethane
(0) It gives nitrosthane on heating with aqueous
solution of AgNO;
{o) Tegives CyH,OH on boiling with alcoholic pot
ash
(a It forms diethylthioether on heating with alco-
holic KSH.
[CBSE Board 2022 Term 1]
© Mgr
the following isomer has the highest
[CBSE SOP Term I 2022]
4, Which reagents are required for one step conver
sion of chlorobenzene to toluene ?
{@) CH;CVAICI,
{(@) CH,CI, Na, Dry ether
(9 CH,CVFe dark
(QNaNOJHCVO-S'C [CBSE SOP Term 12022]
40, The reaction of toluene with Cl, in presence of
FeCl, gives ‘X' while the of toluene with Cl; in
presence of light gives "Y’. Thus 'X’ and "Y' are:
(@) X = benzyl chloride
Y = 0-and p-chlorotoluene
()X = m-chlorotoluene
Y = p-chlorotoluene
(¢) X = 0- and p-chlorotoluene
Y = trichloromethylbenzene
(@)X = benzyl chloride,
Y=m-chlorotoluene [CBSE SQP Term I 2022]
(202) EISEN Coss 12
1".
Not
fa)
(b)
(c)
(a)
{e)
12.
13.
14.
15.
16.
Atkenes decolouise bromine water presence Of
CCI, due to formation of :
{@) Allyl bromide
(b) Vinyl bromide
(c) Bromoform
(4) Vicinal dibromide
{cBse SQP Term 12022]
In the following questions a statement of assertio®
followed by a statement of reason is given Choose
the correct answer out of the following choices :
‘Assertion and reason both are true, reason #6 OF
rect explanati
Ass n and reason both are wrong statements.
Assertion is correct but reason is wrong statement.
‘Assertion is wrong but reason is correct statement
‘Assertion and reason both are correct statement
but reason is not correct explanation of assertion.
Assertion + Inversion of configuration is observed
in S,? reaction.
Reason : The reaction proceeds with the formation
of carbocations. [CBSE 2024]
“Assertion ; Inversion of configuration is observed
when I-bromo butane is hydrolysed.
Reason : The reaction of SN? proceeds with the for:
mation of transition state. [CBSE 2024]
‘Assertion : Alkyl halides are insoluble in water
Reason : Alkyl halides have halogen attached to 5?”
hybrid carbon. [CBSE SOP Term 1 2022]
Complete the following analogy
Same molecular formula but different structures :
(@) A: Isomers
(b) A: Enantiomers B: Racemie mixture
(0) A:Stereoisomers B: Retention
(@ B: Isomers B: Stereoisomers
[CBSE SOP Term I 2022]
Idenify A,B, Cand D:
D
fa A = cnts'® = CHon, ¢ ¥ CHING
B ceck
ee eitOH, B = Citly C = CNC,
Oey = cation, c= CCN,
BacyNc
oan, B = cay C= CHEN,
D=GHNC [CBSE 2010 SQP]
WEL Vay 1 Mark
1
2
3.
4a
5.
8
/
Why is chloroform kept in dark coloured bottles ?
ICBSE 2019 Set (56/3/1)]
Define ambident nucleophile with an example.
[CBSE 2019 Set 56/3/1]
Why is t-butyl bromide more reactive towards S,y1
Teaction as compared to n-butyl bromide 7
ICBSE 2019(56/4/1)]
Out of —Chlorobenzene and —_Cyclohex-
yl chloride, which one is more reactive to-
wards nucleophilic substitution reaction and
why? . ICBSE 2019, (56/2/1)]
Write the structure of 1-Bromo-4-Chlorobut-2-ene
ICBSE 2017, Delhi Set 56/1/1]
x
[CBSE 2017, Outside Delhi, Set 56/1/1]
Write the structure of 3-Bromo-2-methylprop-1-
ene. [CBSE 2017 Delhi Set-I 56/1/3]
‘Write the IUPAC name of the following compound:
CH; Br
Io
H,C—C = C—CH,—OH
[CBSE 2017 Set-I 56/1/1]
‘Which of the following reactions is Sx types ?
GHs GHs
jwhich isan example
[CBSE 2016, Delhi, Set 56/1/E]
Out of
CH, —C—CH, — Clana
I
CH, :
CH, — CH, —cH—c1
4
which is more reactive towards Sy} reaction and
why? ICBSE 2016 Set 56/1/2]
Out of
CH,=CH=CH,Cl and CH;—CH;—CH,CI,
Which is more reactive towards Sy! reaction ?
“*) [CBSE 2016, Dethi, Set-56/1/5]
Write the structure of an isomer of compound C,H,
Br which is most reactive towards Sy1 reaction.
ICBSE 2016, Delhi, Set 56/1/C]
13.
14.
15.
16.
~~
Write the IUPAC name of the given com
MPO,
NH,
"nd:
Br
Br
[CBSE 2016 Dey
Ihi S,
Which of the following two reactions 5
Sissi
why ? [CBSE 2016 sop ‘an
Gls) GHs tN
a) katt Yorn
® se ay
Gs GHs
() gars H
x Sct YS cH,
Which would undergo Sx1 reaction
following pair:
CH,—CH,—CH,—Br and CH,—CH_cy,
|
Br
ICBSE 2015 Sets,
Which would undergo Sy2 reaction faster 3.4)
following pair and why ? the
faSter in the
cH;
l
CH,—CH,—Br and CH, —C— cH,
Br
(CBSE 2016, Dethi, Set sac)
EE 2 marks
2.
3.
‘Write equation for the following:
(a) Oxidation of chloroform by air and light,
(b) Reaction of chloro benzene with CH,CVanhyd
AICl. [CBSE 2023]
The following haloalkanes are hydrolysed in pres-
ence of aq KOH:
(a) 1-Chlorobutane
(b) 2-Chloro-2-methylpropane
Which of the above in most likely to give (a) an in-
verted product (b) a racemic mixture ? Justify your
answer. [CBSE 2021 SOP}
Which one of the following compound is more re-
active towards Sy? reaction and why?
(CH,CH(Cl)CH,CH, or CH,CH,CH,Cl
[CBSE 2018, Dethi, Set-56/3 Comptt]
Which alkyl halide from the following pair is (2)
Chiral and (b) undergoes Swi reaction faster:
(@ (CH,),CBr
(ii) CH,CH,CHBrCH,
[CBSE 2017, Delhi, Set-I Compt]
(2 lize] METIS. Class 12 y
gate une definitions of the follow)
agate the defin
5. Wie omic mixture
oR id E
ral Compound [CBSE 2016 Set. ¢,
i 0 Set Cor
5 Wipatane fFOm : ~
i rbatanel
-i-ene
ay But 3
ide Dethi, Set.
Os 1-1 Compt
jch compound in cach
aoe ch of the follow
We will react faster in 82 reaction me
Mout
Gy cHaBror CHst
(py (cHaCCL oF CHACT
[CBSE 2016, Outside Delhi, Set Compt}
3 Marks
account for the following:
| ANalo alkanes react with AgCN to
jeocyanide as main product
¢p) Allgchloride show high reactivity towards Sn’
reaction
{9 Haloarenes are extremely less reactive towards
(0 Nacleophilic sub ie
form
tution reaction
ICBSE 2024 Set-1]
2. Account for the followin,
{) Hatoatkanes react with NaCN to form both
cyanides and isocyanides.
qyfalosrenes donot undergo
‘substitution reaction ea
{g) Benzyl chloride given Sx’ [CBSE 2024 Set-II]
5, {a} Ost of (CH,)kC—Br and (CH,);C—, which one
fe more reactive towards Sy and why ?
Wite the product fornied when p-nitrochloro ben-
zene is heated with aqueous NaOH at 443 K fol-
Jowed by acidification.
Why dextro and Iaevo-rotatory isomers of Butan-
‘ol are difficult to separate by fractional distilla-
tion? [CBSE 2019 Set 56/1/1]
4, (2) Define the following terms
() Enantiomers
(i) Racemic mixture
nucleophilic
©)
©
(b) Why is chlorobenzene resistant to nucleophilic
substitution reaction 7
[CBSE 2019(56/5/1)]
5. Among all the isomers of molecular formula C,H-
Br, identify
{) The one isomer which is optically active.
(&) The one isomer which is highly reactive towards
Sy2.
(2024 ASTENISETA Class 12
(©) The two isomers give same product on dehydroha-
logenation with alcoholic KOH.
[cuse 20191662701
(2) Out of cyctochtorohexene and chlorobenzene
Which one is more reactive towards nucleophilic
substitution reaction and why ?
(6) Predict all alkenes that would be formed by the
Achydrohalogenation of 2-bromabutane.
(6) Ciloroform contains chlorine but it does not give
iver nitrate solution,
[CBSE 2019 Set 56(B)]
[CBSE Marking Scheme]
7. Give reasons for the fallowing :
(4) The presence of —NO, group at ortho or para posi-
on increases the reactivity of haloarenes towards
‘nucleophilic substitution reactions.
(b) p-dichlorobenzene has higher melting point than
that of ortho or meta isomer.
(© Thionyl chloride method is preferred for prepa
ing alkyl chloride from alcohols.
oR
®
Write equation for preparation of 1-iodobutane
from 1-chlorobutane.
(b) Out of 2-bromopentane, 2-bromo-2-methyIbutane
and 1-bromopentane, which compound is most re-
active towards elimination reaction and why ?
(©) Give IUPAC name of
CH;
|
CH,—CH=CH — CH —CH,
_ Icse 201956/4/1)
Following compounds are given to you :
2-Bromopentane, 2-Bromo-2-methylbutane, 1-Bro-
‘mopentane
(a) Write the compound which is most reactive to-
wards $x? reaction.
(b) Write the compound which is optically activ:
(©) Write the compound which is most reactive to-
wards §-elimination reaction.
[CBSE 2017, Delhi, Set 56/1)
9. In the following pairs of the halogen compounds
which compounds undergoes faster Syj1 Reaction.
cH,
\
(@) CH,—CH,—CH,—CH,—Cl and CH,—C—Cl
\
CH;
(b) CHy—CH,—Br and CH,—CH,—1
[CBSE 2016, Delhi Set-I Compt]
NGA 1. The correct name of the given reaction is,
AT=N,X —SHCNIKEN | Ar CN + Ny
(a) Sandmeyer's reaction
(b) Gabriel phthalimide synth
(©) Carbytamine reaction
{) Hoffmann bromamide degradation reaction
ICBSE 2024 Set-1]
2. The correct name of the given reaction is
(a) Hoffmann bromamide degradation reaction
(&) Gabriel phthalimide synthesis
(©) Carbylamine reaction
(a) Gattermann reaction ICBSE 2024 Set-11]
3. Assertion : Chlorobenzene is less renctive towards
nucleophillic substitution reaction.
Reason : Nitro group in chlorobenzene increases
the reactivity towards nucleophillic substitution re-
action. [CBSE Board 2022]
{a) Assertion and reason both are true, reason is cor-
rect explanation of assertion.
(b) Assertion and reason both are wrong statements.
{C)_ Assertion is correct but reason is wrong statement.
{d) Assertion is wrong but reason is correct statement.
(e) Assertion and reason both are correct statement
but reason is not correct explanation of assertion.
iVSA RS
1. Out of chlorobenzene and benzyl chloride, which
one gets easily hydrolyzed by aqueous NaOH and
why? + [CBSE 2018, Delhi, Set-I, 56/2]
2. Write the structure of 2, 4-dinitro chloro-benzene.
ICBSE 2017, Delhi, Set-1 56/2]
3. CHCl, .CH,CH,Cl
onto CY om CY
which is an example of a benzylic halide ?
[CBSE 2017, Outside Delhi, Set 56/3]
yey
which is an example of allylic halide ?
[CBSE 2017, OD Set-1]
1. With the help of reasonating structues explain the
effect of presence of nitro group at ortho position
in Chlorobenzene. (CBSE 2021 SOP)
FET) aS
2. How will you carry out the followin
fa)
(b)
()
ro)
(b)
(©)
3.
fa)
(b)
©)
(b)
2-Bromopropane to I-bromopropan® "¥en
Benzene to p-chloronitrobenzene 7 >
{CBSE 2017, Outside Delhi, set
3 Marks
(a) Out of C>-Cl and ~~ cH,c, Which
‘more reactive towards Sy2 reaction and wh, ™* &
Outof =Cl and ON, which
more reactive towards nucleop! oe i
reaction and why ?
ili substi
owtet Woy mt Ay
on
which one is optically active and why ?
ICBSE 2019 Set (6
(a) Identify the chiral molecule in the follows!
pair :
Ae mw AKA
on on
@ i)
Write the structure of the product when chloro.
benzene is treated with methyl chloride in tre
presence of sodium metal and dry ether,
Write the structure of the alkene formed by dehy.
drohalogenation of 1-bromo-1-methyleyclohesany
with alcoholic KOH.
[CBSE 2018, Delhi, Set-1156/2]
Write the products formed when :
2-Bromopropane undergoes dehydro-haiogena-
tion reaction.
Chlorobenzene undergoes nitration reaction.
Methylbromide is treated with KCN.
ICBSE 2018, Delhi, Set-56/3 Comptt]
(a) Write the structural formula of A, B, Cand Din
the following sequence of reaction :
Comp)
ving
a
! He
CH, —cH—CH, =, A —
cH oH Peroxide
Nal Mg
ayetner ” © Taiyeter
Tilustrate Sandmeyer's reaction with the help of
suitable example.
[CBSE 2017, Delhi, Set-I Compt
9 Qi) MEETS Cass 1? \¢ following :
sunt for the fol Bt
5 Oeetrophilic substitution
ae ‘occur slowly.
prtkanesHowh Pol 9 neclube in wa
Feactions in
tet the following compounds in increasi
e the fol n reas
0 pera reactivity towards Sx2 displacement: -
jno-2-methylbutane,1-Bromo-pentane,
[CBSE 2017, Dethi Set-1 Comptt
fou convert :
jenzene to biphenyl
) Cte to I-iodopropane
0 butane to but-2-ene
fa 20m OR
spite he major product(s) inthe follwoing
CHy-CHy Bra UV light |
rar
jow do
- yb
@
ox
(9 2-H at
a
(9 Hy -CH Be ae
[CBSE 2017 Delhi Set-56/1/C]
4. How can the following conversions be carried out:
{a Aniline to bromobenzene
{5 Chorabenzene to 2-chloroaceto phenone,
{o) Chloroethane to butane:
OR
What happens when :
(0) Chlorobenzene is treated with Cl/FeCl,.
{0 Ethyl chloride is treated with AgNO,
(0 2bromopentane is treated with alcoholic KOH ?
irite the chemical equation in support of your an-
swe. [CBSE 2017 Delhi Set-I]
Give the IUPAC name of the product formed
when:
(6) 2Methy1-1-bromopropane is treated with sodium
inthe presence of dry ether.
0) LMethyl cyclohexene is treated with HI.
(Q Chloroethane is treated with silver nitrite.
[CBSE 2017, SOP]
4 Name the following according to IUPAC system :
() CH—cH—CH,—CH,
1
OH
2re eGR class 12
Be
| om
cH,
|
(i) CH, C—cH, a
|
cH,
ICBSE 2017, Delhi Set-I Compt]
" OR
Give the IUPAC names of the following com-
pounds:
© CH—cH—cH,—cn,
1
Br
'H—CH,—Cl
ICBSE 2017, Oustside Delhi, Set-I Compt]
10. Give reasons :
@) C—CI bond length in chlorobenzene is shorter
* than C—CI bond length in CH,—Cl.
(b) The dipole moment of chlorobenzene is lower
than that of cyclohexyl chloride.
(©) Sy1 reactions are accompanied by racemization in
optically active alkyl halides. [CBSE Delhi 2016
Set-56/1/210]
11. How do you convert :
(a) Chlorobenzene to toluene
(b) But-Lene to But-2-ene
(©) Ethanol to ethyl iodide.
OR
What happens when :
(a) n-butyl chloride is treated with alcoholic KOH.
(b) 2chloropropane is treated with sodium in the
presence of dry ether.
(©) Chlorobenzene is treated with CH,CI in the pres-
ence of anhydrous AICI}.
Write the chemical equations
above reactions. {CBSE 2016, Delhi, Set-56/1/E]
12. What happens when :
(9.2, 4 Gtainitrochlorbenzene is treated with warm
) Mehtorobutane is treated with alcoholic KOH.
(@) Ethyl chloride is treated with Na metal in presence
2 of dry ether.
Write the equation involved in the above reactions.
[CBSE Delhi 2016 Set-l 56/1/5]
i B ZEA 13,
Write the major monohalo product(s) in each of the
following reactions :
-CHy-CH=CH,
o oO “atte
_-CH;,0H heat
© 1O) Hebe >
no
Icbs
Teroxide,
E 2016 Delhi Set-56/1/N]
What happens when :
CH;—Ctis treated with aqueous KOH?
CH,—Clis treated with KCN ?
CH —Br is treated with Mg in the presence of dry
ether? ICBSE 2016, Delhi]
Give reasons :
n-Butyl bromide has higher boiling point than
t-butyl bromide.
Racemic mixture is optically inactive,
The presence of nitro group (—NO, at o/p positions
increases the reactivity of haloarenes towards nuc-
Jeophilic substitution reactions.
[CBSE 2015, Dethi Set-]
5 Marks
