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Task 1

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bintab231
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* H heatof

vaporization
Saturday, January 7. R: constant
gas
F temp C:c onstant

1. From the data below, calculate the total heat (in J)


needed to convert 0.333 mol of gaseous ethanol at 300.°C
and 1.00 atm to liquid ethanol at 25.0°C and 1.00 atm.

Boiling point of ethanol at 1.00 atm: 78.5°C ∆H° vap

= 40.5 kJ/mol 40,500 s/mol


c = 1.43 J/g°C
gas
c liquid
= 2.45
J/g°C

Show your calculation setup clearly, and pay attention to


units and sig figs in the answer.
of ethanol 0.333 mol /H6.07
mass =

gethanol 15.39
=

I mol ethanol ->


g. mCgas T
:

:15.3g 1.437+ (78.5-300)"c


x

g.c
g g, gz g3
+
= +

=
48465
-

=- 4843 - 13500
+ + -
2005
gz nΔHvap
=

=
20400
-

0.333max
=

450
e
=
13,500,
-

93 mC,,g(Tz
= -

T.)

15.39x2.437x(25.0 -785)
=

i
-
2005. 5

2. Assume three sig figs throughout this problem. Methane


(CH ) has a bp of –164°C at 1 atm, and a vapor pressure of
4

42.8 atm at –100°C, What is the heat of vaporization of


CH ? 4

Show your calculation setup clearly, and pay attention to


units and sig figs in the answer. (n(82) wHa [I 1]
=
-

T=- 164 273 109K


+ =

Tz =
-
100 273 173K
+
=

in
(18)
=

8.3,0 tray, [on -

ii]
3.76 =
8.3,04Ar.,,.,285k]
&Huap 8.314(m0( x3.76 18857K
= x

64

8.314SmoT1sx 3.76 18857K


OHvap
x
=

64

=589481.89 s most
34
=9210.65 ( moil

=9.2 175 MOF:9200s/mol

3. a. Watch this video on creating dry ice (solid CO ) with a 2

fire extinguisher and a towel. Draw an arrow on the


approximate, but accurate, part of the CO phase diagram 2

that indicates the phase transition you saw. Hint: Do NOT


be fooled by the appearance that the experiment was done
at room temperature!

b. Starting with dry ice,


how could you melt it
(in other words, make
the phase transition to
liquid CO ) using only
&
2

commonly-available
tools and containers?
Hint: there are videos
about this. By using a
pluggedsyringe we

can holdthe ice in space


that preventit
to

from a

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