Chapter 1 , CHEMISTRY
Chapter 1 , CHEMISTRY
Soln:
Explanation:
Particles of matter are continuously moving as they possess kinetic energy. When
temperature is raised particles of matter intermix with each other which is called
diffusion.
Evaporation means conversion of liquid state into vapour state. When we increase
temperature molecules move and vibrate so quickly that they escape into the
atmosphere in the form of vapours.
2. Seema visited a Natural Gas Compressing Unit and found that the gas can
be liquefied under specific conditions of temperature and pressure. While
sharing her experience with friends she got confused. Help her to identify the
correct set of conditions
Soln:
Explanation:
To compress gas into liquid, low temperature and high pressure are required.
Between the particles of gas there is a lot of space. On applying pressure, particles
get closer and they start attracting each other to form a liquid. A lot of heat is
generated when gas is compresses hence it is necessary to cool it. Cooling lowers
the temperature of compressed gas and helps in liquefying it.
Soln:
Explanation:
In gases and liquids intermolecular force of attraction between the particles is less
and they facilitate flow of these states of matter.
4. During summer, water kept in an earthen pot becomes cool because of the
phenomenon of
(a) diffusion
(b) transpiration
(c) osmosis
(d) evaporation
Soln:
Answer is d) evaporation
Explanation:
Movement of water through plants and evaporation through its aerial parts is called
transpiration.
Soln:
Explanation:
The intermolecular force of attraction is less in gases than liquid and solid. Solids
have higher intermolecular attraction compared to liquid. In the answer, oxygen is a
gas which has lesser intermolecular attraction than water-a liquid and sugar- a
crystalline solid.
6. On converting 25°C, 38°C and 66°C to kelvin scale, the correct sequence of
temperature will be
(a) 298 K, 311 K and 339 K
Soln:
Explanation:
Add 273 to respective temperature to get the temperature in kelvin. 25°-298K, 38°-
311K, 66°-339K
(a) Conversion of solid into vapours without passing through the liquid state is
called sublimation.
(b) Conversion of vapours into solid without passing through the liquid state is
called vaporisation.
(c) Conversion of vapours into solid without passing through the liquid state is
called freezing.
Soln:
Answer is a) Conversion of solid into vapours without passing through the liquid
state is called sublimation.
Explanation:
8. The boiling points of diethyl ether, acetone and n-butyl alcohol are 35°C,
56°C and 118°C respectively. Which one of the following correctly represents
their boiling points in kelvin scale?
(a) 306 K, 329 K, 391 K
Soln:
Explanation:
9. Which condition out of the following will increase the evaporation of water?
Soln:
Explanation:
Increase in temperature of water increases the kinetic energy of the water which will
make more particles to attain enough energy to convert into the vapour state. This is
how an increase in temperature favours evaporation.
On the other hand, the exposed surface is also responsible for the evaporation.
Higher the exposed surface, higher will be the evaporation.
When common salt is added to water then the surface is occupied by the solvent as
well as non-volatile solute particles.
This makes the escaping tendency of solvent particles decrease and thus the
evaporation of water decreases. Hence options (b), (c) and (d) will decrease the
evaporation of water.
10. In which of the following conditions, the distance between the molecules of
hydrogen gas would increase?
(iv) Adding more hydrogen gas to the container without increasing the volume
of the container
Soln:
Explanation
Soln:
The boiling point of pure water is 100 °C and the melting point is 0°C at 1
atmospheric pressure. Here the water boils at 102 °C hence it is not pure water and
freezes at a temperature below 0°C.
12. A student heats a beaker containing ice and water. He measures the
temperature of the content of the beaker as a function of time. Which of the
following (Fig. 1.1) would correctly represent the result? Justify your choice.
Soln:
Answer is d) because at the start of the experiment temperature of the mixture would
be zero as water and ice will be in equilibrium. When students start heating initially
latent heat will be utilised to melt the ice. Hence the temperature did not increase for
a certain amount of time. When students heat the mixture further the temperature of
the water increases gradually.
13. Fill in the blanks:
(b) At room temperature the forces of attraction between the particles of solid
substances are———than those which exist in the gaseous state.
(c) The arrangement of particles is less ordered in the ——— state. However,
there is no order in the ——— state.
(d) ——— is the change of solid state directly to vapour state without going
through the ———state.
(e) The phenomenon of change of a liquid into the gaseous state at any
temperature below its boiling point is called———.
Soln:
a. Cooling
b. Stronger
c. Liquid, gaseous
d. Sublimation, liquid
e. Evaporation
14. Match the physical quantities given in column A to their S I units given in
column B:
(A) (B)
Soln:
(c) — (v) The SI unit of density is kilogram per cubic metre (kg/m3).
(d) — (ii) The SI unit of mass is the kilogram (kg).
15. The non-SI and SI units of some physical quantities are given in column A
and column B respectively. Match the units belonging to the same physical
quantity:
(A) (B)
Soln:
(a) — (iv) Degree Celsius and kelvin are the units of temperature.
(c) — (v) Gram per centimetre cube and kilogram per metre cube are the units of
density.
Soln:
Diffusion in liquids and gases is the movement of particles from high concentration to
low concentration. Osmosis is the movement of particles from the low concentration
to high concentration through a semi-permeable membrane. This movement
happens due to diffusion. Hence, osmosis is a special kind of diffusion.
Soln:
a) Osmosis
b) Diffusion
c) Osmosis
d) Osmosis
e) Osmosis
f) Diffusion
g) Osmosis
Explanation:
b) Spreading the virus through sneezing is diffusion because the virus enters the air
in tiny droplets. They remain suspended for a long time and move here and there in
the air from higher to lower concentrations.
d) The shrinking of grapes in thick sugar syrup is Osmosis because water will move
down from higher to lower concentrations via a semipermeable membrane.
e) The Preserving of pickles in salt is Osmosis because salt helps to remove water
from the cells and helps to preserve pickles.
f) The spreading of the smell of cake being baked throughout the house is Diffusion
because the particles of cake move from a region of higher concentration to lower
concentration through diffusion hence, producing the smell.
18. Water as ice has a cooling effect, whereas water as steam may cause
severe burns. Explain these observations.
Soln:
Water as steam has more latent heat as compared to water as solid and liquid.
Hence it causes severe burns while water as ice causes a cooling effect.
19. Alka was making tea in a kettle. Suddenly she felt intense heat from the
puff of steam gushing out of the spout of the kettle. She wondered whether the
temperature of the steam was higher than that of the water boiling in the kettle.
Comment.
Steam and the temperature of water boiling in the kettle is the same. But the
particles of steam have more energy in the form of latent heat of vaporisation than
the particles of water. This energy is released when the steam condenses to water.
Therefore, steam is hotter than boiling water.
20. A glass tumbler containing hot water is kept in the freezer compartment of
a refrigerator (temperature < 0°C). If you could measure the temperature of the
content of the tumbler, which of the following graphs (Fig.1.2) would correctly
represent the change in its temperature as a function of time.
Soln:
Graph (a) is the right answer because water will cool initially until its temperature
reaches 0 °C. After reaching the freezing point (0 °C) temperature will remain
constant until the water becomes ice. After that point temperature would decrease
again.
21. Look at Fig. 1.3 and suggest in which of the vessels A,B, C or D the rate of
evaporation will be the highest? Explain.
Soln:
22.
(a) Conversion of solid to vapour is called sublimation. Name the term used to
denote the conversion of vapour to solid.
(b) Conversion of solid state to liquid state is called fusion; what is meant by
latent heat of fusion?
Soln:
b) The amount of heat energy released or absorbed when a solid change to liquid at
atmospheric pressure at its melting point is known as the latent heat of fusion.
Soln:
24. It is a hot summer day, Priyanshi and Ali are wearing cotton and nylon
clothes respectively. Who do you think would be more comfortable and why?
Soln:
Hot summer leads to a lot of sweating. Cotton absorbs moisture whereas Nylon will
not absorb the moisture as efficiently as cotton does. Hence cotton absorbs the
sweat faster that Nylon does. Evaporation of moisture from the cotton cloth will give
a cool feeling, especially when the wind blows. Hence, it can be concluded that
Priyanshi will be more comfortable in summer days.
25. You want to wear your favourite shirt to a party, but the problem is that it is
still wet after a wash. What steps would you take to dry it faster?
Soln:
Drying of clothes is due to the process of evaporation hence the following steps
should be taken to dry the shirt faster.
1. Dry the shirt under a fan with high speed. With an increase in the speed of fan, water
vapours will move away. This decreases water vapour in the surroundings which will
increase the evaporation and the shirt gets dried faster.
2. Spread the shirt on a hanger which will increase surface area. Increase in the surface
area makes the shirt dry quickly.
3. Dry the shirt in sunlight. Because of high-temperature water evaporates faster. Thus the
shirt gets dried easily.
4. Iron the shirt. Heat increases the speed of vaporization and evaporation. This dries the
shirt faster.
Soln:
a) When a liquid evaporates it takes latent heat from the object it touches. This will
make the object cooler. Hence evaporation causes cooling.
b) When there is an increase in the humidity water vapour in the atmosphere will be
more. Hence the atmosphere will not take water vapours easily which decreases the
process of evaporation.
c) Sponge is a solid because it has definite shape and volume which does not
change until you press it. It has minute pores in which air is filled. When you press it,
air passes out through pores this makes it a compressible solid.
27. Why does the temperature of a substance remain constant during its
melting point or boiling point?
The temperature of a substance remains constant during melting and boiling points
till the completion of melting and boiling because of the latent heat of fusion used by
the substances. Latent heat of fusion helps to overcome the force of attraction
between particles of solid to change into a liquid when they melt. Hence temperature
remains constant.