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Chemistry class 11 skim 2

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9 views1 page

skim2

Chemistry class 11 skim 2

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theheaddeader
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OF BASI

READY REFERENCE
QUALITATIVE ANALYSIS RADICALS
solution(0.s).To the
Make the soluon of the
given
CHART FOR conc. HCI, cold
or hot Labelit original O.s. add dil. HCI.
White prpe. mixture in ,in dil, HClor
distilled water,
(Pb?) lf group I is absent, pass H,S gas
through os.for sufhcient time sSthelle
after acidification with dil. HCL. Filter. Boil and cool.
Add NH,OHthu of ammonia. If a ppt, is formed, group III is present.
Conhmation of P Pyt.--Group II If group ll is absent, add solid conc. HNO,tothe O.S. e
Block ppt-(, Cu) NH,CI,, 0.5 ml
part ofthe solution in group IIl pass H,S gas. If a ppt. is obtained
obtained
Boil white ppt. with absent, through a
distilled Pelor ppt.{As) Ifgroup IIl is
water and divide the
solution Dissolve the black ppt. in Reddish brown pp.-(Fe) groupIV is present.
into twO parts
50
OHNO,.To minimum
onenart afek.Leadd
White ppt.-(A") Whiteppt.-(Zn?*) group IV is absent, to the 0.S. add solid NH, CI,NH,OH and (NH),CO, solution.
() Add KI
solution to one part dil. H,SO, and alcohol. If a white ppt. is forme Black ppt.--(Ni and
Co2*)
of above
solution. Yellow Pb is indicated. If no white ppt. is formed, Confrmation of (Fe) Fleshcolouredppt.-(Mn2*) White ppt. (Ba?, S, Ca") If group Vis absent test for Mg?
ppt confirms P. add excess NH,OH to the second part of tne Dissolve the brown pnt. in dil. HCl and divide the () To the 0.S. add a pinch of NH,CL, afee
()Add K,CrO, solution to solutionBlue coloured solution indicates Cu solution into two parts. Confrmationof Zn?
divide Dissolve a part of white ppt. in dil. acetic acid. drops of NH,OH and excess of arom
the second part of the 0To one part of solution add pot. ppt. in dil. HCland phosphatesolution--White ppt-Mg
above solution. Yelow ppt ferrocyanide Dissolve a part of white Boil off CO,
confrms PL2 Confumation of Cu solution. Aprussion blue colour or ppt the solution in two parts. () To one part of the above solution, add () Perform charcoal cavity cobalt nitrate test
() To second part of solution add pot. add pot. ferrocyanide
(0 Add excess of NH,OH solution to original () To one partofsolution
solution-Bluish white ppt. KCrO, solution.Yellow ppt.Confirms Ba'. with white ppt.-A pink aass.
sulphocyanide solution, Ablood red
solution. Deep blue solution. colouration. part of solution add
NaOH () If Ba? is absent, then to the second part of
(i) To second excess. above solution add amm. sulphate solution. Test for NH,
() Acidify the above deep blue solution with solution. White ppt. soluble in Awhite ppt. confirms Sr*
dil. acetic acid. Add Pot. ferrocyanide Conhrmation of Ni and Co2 To the salt add sodium hydroxide solution and
solution. Chocolate brown ppt. contrmsConhrmation of A (iii) If both Ba2* and Sr2* are absent, then to
black Ni2 or Co? is heat. If ammonia gas evolves NH,' is present.
If the ppt. obtained is
Cu2. the third part of the above solution add
the salt
() Perform charcoal
cavity-cobalttr nitratetest indicated. Note the colour of the salt. If anmonium oxlate solution. A white ppt Pass the gas through Nesler's reagent.A
Conhrmation of PL2 with white ppt. Blue mass. indicated and if the salt in confirms Ca?. brownish ppt. or colouration is obtained
is greenish--Ni is
() Pot. iodide test. Tothe O.S. add KI solution. () Lake test. White ppt. + di. HCI+ a few purple Co* is indicated.
drops of blue litmus solution +NH,OH Conhrmation of Co"
Yellow ppt. solution in excess. Ablue ppt., suspended
() Pot. chromate test. To the 0.S. add K,CrO, () Take 0.S. and neutralise the acidby adas Perform the flame test with apart of the salt.
in a colourless medium (called alake). Note: NH, may be tested in the beginning of
Yellow ppt. NH,OH. Add a pinch of potassium nitrite analysis of basic radicals as zero gzou
and acidify with dil. acetic acid -Yellow ppt. (0 Light green flame--Ba' confirmed.
If the ppt. obtained is yellow in colour As' is
indicated. (i) Perform borax bead test with the salt- () Crimson red flame--S confrmed.
Confrmation of As
Blue bead. (tii) Brick red flame-Ca* confirmed.
Conhrmation of N?
() Amm. molybdate test. Yellow ppt. + conc.
HNO, + Amm. molybdate solution i) Take 0.S. and make alkaline by adding
Yellow ppt. NH,OH and then add a few drops of
(i) Magnesia mixture test. To the O.S. add dimethyl glyoxime--Bright red ppt.
magnesia mixture-White ppt. (i) Perform borax bead test with the salt
Brown bead in oxidising lame and grey
bead in reducing flame.
Confrmation of Mn2
(0 Dissolve flesh coloured ppt. in dil. HCl, boil
off H,S, add NaOH and Br, water--White
ppt. turning grey.
(i)Perform borax bead test with group ppt.
Pink bead in oxidising flame and colourless
in reducing flame.

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