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Magnetic Quantum Number
The magnetic quantum number also referred to as the
third quantum number specifies the number of orbitals and their orientation within a subshell, which provides information about the orbital that an electron resides. It is used to represent the orientation of an atomic orbital in space. The magnetic quantum number was proposed by a German-American Physicist, Alfred Lande, who contributed to the field of quantum mechanics theory by giving the Lande g-factor and explaining the Zeeman effect.
The value of the magnetic quantum number (ml)
depends upon the azimuthal or orbital angular quantum number (l). It ranges from – l to +l, therefore, it can be concluded that the value of a magnetic quantum number can be negative, positive, or zero.
Let us discuss the shells, sub-shells, and orbitals in
brief to get a better understanding of the magnetic quantum number.
The energy level of an electron in an atom represents
the shell or orbit of the atom where electrons reside. It is expressed in terms of principal quantum number (n). There could be a maximum of 32 electrons found in a shell.
The shells are further divided into sub-shells s, p, d,
and f that have different angular momentum. It is represented in terms of the azimuthal quantum number (l). It is also considered the pathway of an electron in a shell.
The sub-shells are further into various orbitals which
are represented in terms of magnetic quantum numbers (ml). It has been found that an orbital is a mathematical function describing the wave-like behaviour of an electron. Each orbital can contain a maximum of 2 electrons.
Each electron in an orbital shows a positive and a
negative half-spin which is expressed in terms of spin quantum number (ms ).
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