All matter—solid, liquid, and gas—is composed of continually jiggling atoms or molecules. Because of this random motion, the atoms and molecules in matter have kinetic energy. The average kinetic energy of these individual particles causes an effect we can sense—warmth.
Temperature and Heat
Temperature • The quantity that tells how hot or cold something is compared with a standard is temperature. • A common thermometer measures temperature by showing the expansion and contraction of a liquid in a glass tube using a scale.
Temperature and Heat
Temperature • Whenever something becomes warmer, the kinetic energy of its atoms or molecules has increased. When the atoms or molecules in matter move faster, the matter gets warmer. Its atoms or molecules have more kinetic energy. • The higher the temperature of a substance, the faster is the motion of its molecules.
Temperature and Heat
Temperature • Temperature is related to the random motions of the molecules in a substance. • The warmth you feel when you touch a hot surface is the kinetic energy transferred by molecules in the surface to molecules in your fingers.
Temperature and Heat
Temperature • Temperature is not a measure of the total kinetic energy of all the molecules in a substance.
Temperature and Heat
Thermal Equilibrium • After objects in thermal contact with each other reach the same temperature, we say the objects are in thermal equilibrium. • When a thermometer is in contact with a substance, heat flows between them until they have the same temperature. • When objects are in thermal equilibrium, no heat flows between them.
Temperature and Heat
Thermal Equilibrium • To read a thermometer we wait until it reaches thermal equilibrium with the substance being measured. • The temperature of the thermometer is also the temperature of the substance. • A thermometer should be small enough that it does not appreciably alter the temperature of the substance being measured.
Temperature and Heat
Thermal Equilibrium • Water seeks a common level with pressures at equal elevations the same. The thermometer and its surroundings reach a common temperature with the average kinetic energy per particle the same.
Temperature and Heat
Thermal Equilibrium Question: Suppose you use a flame to add heat to 1 liter of water, and the water temperature rises by 2°C. If you add the same quantity of heat to 2 liters of water, by how much will its temperature rise?
Temperature and Heat
Thermal Equilibrium Question: Suppose you use a flame to add heat to 1 liter of water, and the water temperature rises by 2°C. If you add the same quantity of heat to 2 liters of water, by how much will its temperature rise? Answer: Its temperature will rise by 1°C, because there are twice as many molecules in 2 liters of water and each molecule receives only half as much energy on average.
Temperature and Heat
Fig. 3 • In fig. 3, two systems are said to be in thermal equilibrium if there is no heat flow between then when they are brought into contact. • Temperature is the indicator of thermal equilibrium in the sense that there is no net flow of heat between two systems in thermal contact that have the same temperature.
Temperature and Heat
The Zeroth Law Fig. 3
Two systems individually in thermal
equilibrium with a third system are in thermal equilibrium with each other.
Temperature and Heat
Temperature Scales Celsius Scale The most widely used temperature scale is the Celsius scale. • The number 0 is the temperature at which water freezes. • The number 100 is the temperature at which water boils. The gap between freezing and boiling is divided into 100 equal parts, called degrees.
Temperature and Heat
Temperature Scales Fahrenheit Scale The temperature scale used commonly in the United States is the Fahrenheit scale. • The number 32 is the temperature at which water freezes. • The number 212 is the temperature at which water boils. • The Fahrenheit scale will become obsolete if and when the United States goes metric.
Temperature and Heat
Temperature Scales Kelvin Scale Scientific research uses the SI scale—the Kelvin scale. • Degrees are the same size as the Celsius degree and are called “kelvins.” • On the Kelvin scale, the number 0 is assigned to the lowest possible temperature—absolute zero. • At absolute zero a substance has no kinetic energy to give up. • Zero on the Kelvin scale corresponds to -273°C.
Temperature and Heat
Temperature Scales Scale Conversion • Arithmetic formulas can be used for converting from one temperature scale to another. • A conversion from Celsius to Fahrenheit, or vice versa, can be very closely approximated by simply reading the corresponding temperature from side- by-side scales.
Temperature and Heat
Temperature Scales Scale Conversion (Fahrenheit -> Celsius) To convert temperatures from Celsius to Fahrenheit, obtain the actual Fahrenheit temperature , multiply the Celsius value by and then add 32°.
= + 32°
Temperature and Heat
Temperature Scales Scale Conversion (Celsius -> Fahrenheit) Subtract 32° to get the number of Fahrenheit degrees above freezing, and then multiply by to obtain the number of Celsius degrees above freezing— that is, the Celsius temperature
= ( 32°)
Temperature and Heat
Temperature Scales Scale Conversion (Celsius -> Kelvin) Simply add 263.15 to the temperature value in Celsius to convert to Kelvin.
= + 273.15
Temperature and Heat
Thermal Expansion • Most forms of matter—solids, liquids, and gases—expand when they are heated and contract when they are cooled. • When the temperature of a substance is increased, its molecules jiggle faster and normally tend to move farther apart.
Temperature and Heat
Thermal Expansion This results in an expansion of the substance. • Gases generally expand or contract much more than liquids. • Liquids generally expand or contract more than solids.
Temperature and Heat
Thermal Expansion Linear Expansion • Suppose a rod of material has a length at some initial temperature • When the temperature changes by the length changes by
• characterizes a proportionality constant (which is different for
different materials)
Temperature and Heat
Thermal Expansion Table 1: Coefficients of Linear Expansion
Temperature and Heat
Thermal Expansion Volume Expansion • Increasing temperature usually causes increases in volume for both solid and liquid materials. • The increase in volume is approximately proportional to both the temperature change and the initial volume .
Temperature and Heat
Thermal Expansion Table 2: Coefficients of Volume Expansion
Temperature and Heat
Thermal Expansion Linear Expansion
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Thermal Expansion Linear Expansion
Temperature Change a)
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Thermal Expansion Linear Expansion
a)
b)
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Thermal Expansion Volume Expansion
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Thermal Expansion Volume Expansion
Temperature Change
a)
Temperature and Heat
Heat • The energy that transfers from one object to another because of a temperature difference between them is called heat. • Heat is energy in transit, moving from a body of higher temperature to one of lower temperature. • The direction of spontaneous energy transfer is always from a warmer to a cooler substance.
Temperature and Heat
Heat • When two substances of different temperatures are in thermal contact, heat flows from the higher-temperature substance into the lower-temperature substance.
Temperature and Heat
Heat • If you touch a hot stove, energy enters your hand from the stove because the stove is warmer than your hand. • If you touch ice, energy passes from your hand into the colder ice.
Temperature and Heat
Heat • Heat will not necessarily flow from a substance with more total molecular kinetic energy to a substance with less. • Heat flows according to temperature differences—that is, average molecular kinetic energy differences. • Heat never flows on its own from a cooler substance into a hotter substance.
Temperature and Heat
Heat • Just as water will not flow uphill by itself, regardless of the relative amounts of water in the reservoirs, heat will not flow from a cooler substance into a hotter substance by itself.
Temperature and Heat
Heat Capacity • Specific heat capacity of a substance is its capacity to store heat depending on its chemical composition.
Temperature and Heat
Heat Capacity • The specific heat capacity of a material is the quantity of heat required to raise the temperature of 1 gram by 1 degree. • A material requires a specific amount of heat to raise the temperature of a given mass a specified number of degrees.
Temperature and Heat
Heat Capacity Table 3: Specific Heat Capacities
Temperature and Heat
Methods of Heat Transfer Conduction • Conduction of heat is the transfer of energy within materials and between different materials that are in direct contact. • In conduction, collisions between particles transfer thermal energy, without any overall transfer of matter.
Temperature and Heat
Methods of Heat Transfer Conduction • Conduction of heat is the transfer of energy within materials and between different materials that are in direct contact. • In conduction, collisions between particles transfer thermal energy, without any overall transfer of matter.
Temperature and Heat
Methods of Heat Transfer Conduction Conduction is explained by collisions between atoms or molecules, and the actions of loosely bound electrons. • When the end of an iron rod is held in a flame, the atoms at the heated end vibrate more rapidly. • These atoms vibrate against neighboring atoms. • Free electrons that can drift through the metal jostle and transfer energy by colliding with atoms and other electrons.
Temperature and Heat
Methods of Heat Transfer Conduction • Materials composed of atoms with “loose” outer electrons are good conductors of heat (and electricity also). • Because metals have the “loosest” outer electrons, they are the best conductors of heat and electricity.
Temperature and Heat
Methods of Heat Transfer Conduction • The tile floor feels cold to the bare feet, while the carpet at the same temperature feels warm. This is because tile is a better conductor than carpet.
Temperature and Heat
Methods of Heat Transfer Conduction An insulator is any material that is a poor conductor of heat and that delays the transfer of heat. • Air is a very good insulator. • Porous materials having many small air spaces are good insulators. • Liquids and gases generally make poor conductors.
Temperature and Heat
Methods of Heat Transfer Conduction • Strictly speaking, there is no “cold” that passes through a conductor or an insulator. • Only heat is transferred. We don’t insulate a home to keep the cold out; we insulate to keep the heat in. • No insulator can totally prevent heat from getting through it. Insulation slows down heat transfer.
Temperature and Heat
Methods of Heat Transfer Conduction Question! If you hold one end of a metal bar against a piece of ice, the end in your hand will soon become cold. Does cold flow from the ice to your hand?
Temperature and Heat
Methods of Heat Transfer Conduction Question! If you hold one end of a metal bar against a piece of ice, the end in your hand will soon become cold. Does cold flow from the ice to your hand? Answer: Cold does not flow from the ice to your hand. Heat flows from your hand to the ice. The metal is cold to your touch because you are transferring heat to the metal.
Temperature and Heat
Methods of Heat Transfer Convection • Convection, is a means of heat transfer by movement of the heated substance itself, such as by currents in a fluid. Essentially, some examples of convection are as follows: • Air in contact with a hot stove rises and warms the region above. • Water heated in a boiler in the basement rises to warm the radiators in the upper floors.
Temperature and Heat
Methods of Heat Transfer Convection • Convection occurs in all fluids, liquid or gas. • When the fluid is heated, it expands, becomes less dense, and rises. • Cooler fluid then moves to the bottom, and the process continues. • In this way, convection currents keep a fluid stirred up as it heats.
Temperature and Heat
Methods of Heat Transfer Convection occurs in all fluids: • Convection currents transfer heat in air. • Convection currents transfer heat in liquid.
Temperature and Heat
Methods of Heat Transfer Convection When the test tube is heated at the top, convection is prevented and heat can reach the ice by conduction only. Since water is a poor conductor, the top water will boil without melting the ice.
Temperature and Heat
Methods of Heat Transfer Convection Think of molecules of air as tiny balls bouncing against one another. • Speed is picked up by a ball when it is hit by another that approaches with a greater speed. • When a ball collides with one that is receding, its rebound speed is reduced.
Temperature and Heat
Methods of Heat Transfer Convection Molecules in a region of expanding air collide more often with receding molecules than with approaching ones.
Temperature and Heat
Methods of Heat Transfer Radiation • How does the sun warm Earth’s surface? • It can’t be through conduction or convection, because there is nothing between Earth and the sun. • The sun’s heat is transmitted by another process. Temperature and Heat Methods of Heat Transfer Radiation
• Radiation is energy transmitted by electromagnetic waves.
• The energy transmitted by radiation is called Radiant energy.
Temperature and Heat
Methods of Heat Transfer Radiation
Most of the heat from a fireplace goes up the chimney by
convection. The heat that warms us comes to us by radiation.
Temperature and Heat
Methods of Heat Transfer Radiation
• Objects at low temperatures emit long waves. Higher-
temperature objects emit waves of shorter wavelengths. • Objects around you emit radiation mostly in the long- wavelength end of the infrared region, between radio and light waves.
Temperature and Heat
Methods of Heat Transfer Radiation
In thermometer readings, the average frequency of radiant
energy is directly proportional to the Kelvin temperature T of the emitter:
And so, the typical infrared thermometer operate in the
ranges between -30°C to 200°C.
Temperature and Heat
Methods of Heat Transfer Radiation
• If everything is emitting energy, why doesn’t everything
finally run out of it? • Everything also absorbs energy from its environment.
Temperature and Heat
Methods of Heat Transfer Radiation Absorption and reflection are opposite processes. • A good absorber of radiant energy reflects very little radiant energy, including the range of radiant energy we call light. • A good absorber therefore appears dark. • A perfect absorber reflects no radiant energy and appears perfectly black.