Blue Print Unit wise Paper -3

CHAPT MC ASSERTION&R VERY SHORT CASE LONG TOTAL TOTAL TOT

ER Q EASON SHORT ANSWE BASED ANSWE QUESTI MARK AL
NAME QUESTION ANSWE R QUESTI R ON PER S PER MAR
R QUESTI ON QUESTI CHAPT CHAPT KS
QUESTI ON ON ER ER
ON
Solutio 6 2 3 3 1 2 15 37
ns
Chemi 6 2 2 4 1 1 16 33 70
cal
kinetic
s

NAVODAYA VIDYALAYA SAMITI

UNIT WISE PRACTICE PAPER -3 (2024-25)

CHEMISTRY THEORY (043)

Max Marks : 70 Class : 12 Time : 3 hour

General Instructions:

 Read the following instructions carefully.

 There are 35 questions in this question paper with internal choice.
 SECTION A consists of 14 multiple-choice questions carrying 1 mark each and 4 assertion and reason
questions carrying 1 mark each.
 SECTION B consists of 5very short answer questions carrying 2 marks each.
 SECTION C consists of 7 short answer questions carrying 3 marks each.
 SECTION D consists of 2 case-based questions carrying 4 marks each.
 SECTION E consists of 3 long answer questions carrying 5 marks each.
 All questions are compulsory.
 Use of log tables and calculators is not allowed.

SECTION – A

The following section consists of 12 multiple-choice questions carrying 1 mark each and 4 assertion and reason
questions carrying 1 mark each.

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1)The value of Henry’s constant KH is:
(a) greater for gases with higher solubility

(b) greater for gases with lower solubility.

(c) constant for all gases.

(d) not related to the solubility of gases.

2)Increasing the temperature of an aqueous solution will cause:

(a) decrease in molality
(b) decrease in molarity
(c) decrease in mole fraction
(d) decrease in % (w/w)
3)Colligative properties depend on:
(a) the nature of the solute
(b) the number of solute particles in solution
(c) the physical properties of solute
(d) the nature of the solvent
4)The unit of ebullioscopic constant is:
(a) K kg mol-1
(b) K-1 kg mol
(c) K kg-1 mol-1
(d) K kg-1 mol

5)What kind of order of reaction decomposition of Ammonia on platinum surface is:

(a) Zero order reaction

(b) First order reaction
(c) Second order reaction
(d) Fractional order reaction
6)The rate of a chemical reaction tells us about

(a)the reactants taking part in the reaction

(b)the products formed in the reaction
c)how slow or fast the reaction is taking place
(d)none of the above
7)In the rate equation, when the concentration of reactants is unity then the rate is equal to:

(a).specific rate constant

(b)average rate constant
c)instantaneous rate constant
(d)None of the above
8)The rate constant of zero-order reactions has the unit

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 (a)s-1
(b)mol L-1 s-1
c)L2 mol-2 s-1
(d)L mol-1 s-1

9)Which of the following condition is not satisfied by an ideal solution?

(a) ΔHmixing = 0
(b) ΔVmixing = 0
(c) Raoult’s Law is obeyed
(d) Formation of an azeotropic mixture

10)Considering the formation, breaking and strength of hydrogen bond, predict which of the following
mixtures will show a negative deviation from Raoult’s law?
(a) Methanol and acetone.
(b) Chloroform and acetone.
(c) Phenol and aniline.
(d) Cyclohexane and ethanol

11)A catalyst alters, which of the following in a chemical reaction?

(a) Entropy
(b) Enthalpy
(c) Internal energy
(d) Activation energy

12)In chemical equation H2 (g) + I2 (g) ⇌ 2HI (g) the equilibrium constant Kp depends on

(a) total pressure

(b) catalyst used
(c) amount of H2 and I2
(d) temperature

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13)Given below are two statements labelled as Assertion (A) and Reason (R)
Assertion (A): Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling points either
greater than both the components or less than both the components.
Reason (R): The composition of the vapour phase is same as that of the liquid phase of an azeotropic mixture.
Select the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true

14)Given below are two statements labelled as Assertion (A) and Reason (R) Assertion (A):
Molarity of a solution in liquid state changes with temperature. Reason (R): The volume of a
solution changes with change in temperature. Select the most appropriate answer from the options
given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
(e) 15)Assertion: The order and molecularity of a reaction are always the same.
(f) Reason: Order is determined experimentally whereas molecularity by a balanced elementary reaction.
(g) 16)Assertion: Rate constant of a zero-order reaction has the same unit as the rate of a reaction. Reason: Rate
constant of a zero-order reaction does not depend upon the concentration of the reactant.

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 SECTION – B

The following section consists of 5 very short answer questions carrying 2 marks each with internal choice.

17)What do you mean by Raoult’slaw ? What are the limitations of Raoult’s law ?

OR
How many types of azeotropes are there? Define them along with one example of each. 2

18)Plot a graph between vapour pressure and mole fraction of a solution obeying Raoult’s Law at constant
temperature?
19)A mixture of chlorobenzene and bromobenzene is a nearly an ideal solution but a mixture of chloroform and
acetone is not Explain?

20) Identify the reaction order for each of the following rate constant. K=3.1 x 10^-
4 sec^-1

K=4.2x10^-5 L mol^-1 sec^-1

21)Define half life of a reaction. Show that for a 1st order reaction half life is independent of initial
concentration.

SECTION – C

The following section consists of 7 short answer questions carrying 3 marks each with internal choice.

22)Miscible liquid pairs often show positive and negative deviation from Raoult’s law. Explain the reason for such
deviation? Give one example of each of liquid pairs.

23)A solution containing 18 g of non-volatile solute in 200g of water freezes at 272.07 K. calculate the molecular
mass of solute (given Kf = 1.86 K/m)

OR
Calculate the osmotic pressure at 270C of a solution formed by mixing equal volumes of two solutions, one
containing 0.05 mole of glucose in 250 ml of solution and the other containing
3.42 g of C12H22O11 in 250 ml of solution. [R = 0.082 L atm mol-1K-1]
.

24)An aqueous solution freezes at 272.4 K while pure water freezes at 273 K. Determine (i) Molality of solution.
(ii) Boiling point of solution (iii) Lowering of vapour pressure of water at 298 K.

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25)Define the following :

(i) Order of a reaction

(i) Activation energy of a reaction
(ii)
26)The thermal decomposition of HCO2H is a first order reaction with a rate constant of 2.4 × 10-3 s-1 at a
certain temperature. Calculate how long will it take for three-fourths of initial quantity of HCO2 H to
decompose. (log 0.25 = -0.6021) .

27)A first order gas phase reaction: A2B2(g) → 2A(g) + 2B(g) at the temperature 400°C has the rate constant k =
2.0 × 10-4 sec-1. What percentage of A2B2 is decomposed on heating for 900 seconds? (Antilog 0.0781 = 1.197)

28)Derive integrated rate equation for rate constant of a first order reaction.

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 SECTION – D

The following section consists of 2 case-based questions carrying 4 marks each with internal choice.

29)Osmotic pressure results from a reduction in the chemical potential of a solvent in the presence of a solute.
The tendency of a system to have equal cemical potentials over its entire

volume and to reach a state of lowest free energy gives rise to the osmotic diffusion of matter. In ideal and dilute
solutions, the osmotic pressure is independent of the nature of the solvent and solutes. At constant temperature it is
determined only by the number of
kinetically active particles—ions, molecules, associated species, and colloidal particles in a unit volume of
the solution.
For very dilute solutions of nondissociating compounds, osmotic pressure is described with sufficient accuracy by
the equation πV = nRT, where n is the number of moles of solute, V is the
volume of the solution, R is the universal gas constant, and T is the absolute temperature.
(i) Name and define the process/method which is used for purification of water?
(ii) Which colligative property is most suitable to measure molecular mass of proteins and why?
(iii) 200 cm3 of an aqueous solution of a protein contains 1.26 g of the protein. The osmotic pressure of such a
solution at 300 K is found to be 2.57 × 10-3 bar. Calculate the molar mass of the protein.
OR
A solution contains 0.8960g of K2SO4 in 500ml solution. Its osmotic pressure is found to be 0.690atm at 270C.
Calculate the value of Van’t Hoff factor. (K=39.0, S=32, O=16, R=0.082atm mol-1K-1)

30)Read the passage given below and answer the following questions:

The half-life of a reaction is the time required for the concentration of reactant to decrease by half, i.e.,
[A]t = [A]/2
For first order reaction, t1/2 = 0.693/k
this means t1/2 is independent of initial concentration. Figure shows that typical variation of concentration of
reactant exhibiting first order kinetics. It may be noted that though the major portion of the first order kinetics may
be over in a finite time, but the reaction will never cease as the concentration of reactant will be zero only at infinite
time
.

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(i) A first order reaction has a rate constant k=3.01 x 10-3 /s. How long it will take to decompose half of the
reactant?
(ii) The rate constant for a first order reaction is 7.0 x 10-4 s-1. If initial concentration of reactant is 0.080 M,
what is the half-life of reaction?
(iii) The rate of a first order reaction is 0.04 mol L-1 s-1 at 10 minutes and 0.03 mol L-1 s-1 at 20 minutes after
initiation. The half life of the reaction?
(iv)The plot of t1/2 vs initial concentration [A]0 for a first order reaction .

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 OR
. Read the passage given below and answer the following questions :
A first-order reaction can be defined as a chemical reaction for which the reaction rate is entirely dependent on the
concentration of only one reactant. In such reactions, if the concentration of the first-order reactant is doubled, then
the reaction rate is also doubled.
The following reaction, A(g)⟶ΔP(g)+Q(g)+R(g)A(g)⟶ΔP(g)+Q(g)+R(g) follows first order kinetics. The half-
life period of this reaction is 69.3 s at 500°C. The gas A is enclosed in a container at 500°C and at a pressure of 0.4
atm.
Answer the following question: -
(i) The rate constant for the reaction.
(ii) The total pressure of the system after 230 s will be.
(iii) Give an example of first order reaction.
(iv) The plot of ln[A] vs t graph is.

SECTION – E

The following section consists of 3 long answer questions carrying 5 marks each with internal choice.

31). (a) The rate of the chemical reaction doubles for an increase of 10 K in absolute temperature from 298
K. Calculate .
(b) Explain collision frequency.
OR
During nuclear explosion, one of the products is Sr90 with half-life of 28.1 years. If 1 microgram of Sr90 was
absorbed in the bones of a newly born baby instead of calcium, how much of it will remain after 10 years and 60
years if it is not lost metabolically.
32)(i) Two liquids A and B on mixing form an ideal solution. At 300C vapour pressure of solution containing 3 mol
of A and 1 mol of B is 550 mmHg. But when 4 mol of A and 1 mol of B are mixed. The vapour pressure of solution
thus formed is 560 mm Hg. What would be the V.P of pure A and B?

(ii) Explain the fact that Raoult’s Law is a special case of Henry’s Law.
.
OR
(a) 0.6 mL of acetic acid (CH3COOH), having density 1.06 g mL–1, is dissolved in 1 litre of water. The
depression in freezing point observed for this strength of acid was 0.0205°C. Calculate the van’t Hoff factor
and the dissociation constant of acid.
(b) Define Van’t Hoff factor. Give the value of Van’t Hoff factor in case of the following: Association,
Dissociation and neither association nor dissociation of solute when dissolved in a solvent.
33)(a) What is meant by abnormal molar mass of solute? Discuss the factors which bring abnormality in the
experimentally determined molecular masses of solutes using colligative properties.

(b) If N2 gas is bubbled through water at 293 K, how many millimoles of N2 gas would dissolve in 1 litre of
water. Assume that N2 exerts a partial pressure of 0.987 bar. Given that Henry’s law constant for N2 at 293 K is
76.48 kbar.
l Molar Mass/ van’t Hoff factor = 120/4 = 30 g/mol
OR

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(i)why is boiling point of 1 M NaCl solution is more than that of 1M glucose solution?

(ii)A nonvolatile solute X(molar mass =50 g/mol) when dissolved in 78 g of benzene reduced its vapour pressure
to 90%.calculate mass of of X dissolved in the solution.

(iii)Calculate the boiling point of elevation for a solution prepared by adding 10g of MgCl2 to 200 g of water
assuming MgCl2 is completely dissociated.

(kb for water =0.512 Kkg/mol ,molar mass MgCl2=95g/mol)

……………………………………….END……………………………………………

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