NEET : CHAPTER WISE TEST-2

SUBJECT :- CHEMISTRY DATE.............................................................

CLASS :- 11th NAME.............................................................
CHAPTER :- ATOMIC STRUCTURE SECTION.......................................................
(SECTION-A)
1. Cathode ray are : 8. Photon of which light has maximum
(A) stream of electrons energy :
(B) stream of -particles (A) red (B) blue
(C) violet (D) green
(C) radiation
(D) stream of cations 9. The frequency of yellow light having
wavelength 600 nm is :
2. Which of the following rays are affected by (A) 5.0 × 1014 Hz (B) 2.5 × 107 Hz
electric field :
(C) 5.0 × 107 Hz (D) 2.5 × 1014 Hz
(A) Anode rays (B) Cathode rays
(C) Both (A) and (B) (D) None of these 10. Which one of the following is not the
characteristic of Planck's quantum theory
3. The e/m ratio for Anode rays : of radiation-
(A) varies with the element forming the (A) The energy is not absorbed or emitted
anode in the discharge tube. in whole number multiple of quantum.
(B) varies with the gas filled in the discharge
(B) Radiation is associated with energy.
tube.
(C) Radiation energy is not emitted or
(C) is constant.
absorbed continously but in the form of
(D) Both (A) & (B).
small packets called quanta.
(D) This magnitude of energy associated
4. The charge on the atom having 17
with a quantum is proportional to the
protons, 18 neutrons and 18 electrons is
frequency.
(A) + 1 (B) – 1
(C) – 2 (D) zero
11. Light of wavelength  falls on metal having
work function hc/0. Photoelectric effect
5. Number of protons, neutrons and
will take place only if :
electrons in the element are
(A)  0 (B)  20
respectively :
(A) 89, 231, 89 (B) 89, 89, 242 (C)  0 (D)  0/2
(C) 89, 142, 89 (D) 89, 192, 89
12. The energy of a photon is 3.03 × 10 –19 J,
6. Which of the following are isoelectronic then wavelength of this photon is:
with one another ?
(Given, h = 6.63 × 10–34 Js, c = 3.00 ×
(A) Na+ and Ne (B) K+ and O 108 ms–1)
(C) Ne and O (D) Na+ and K+ (A) 6.56 nm (B) 65.6 nm
(C) 656 nm (D) 0.656 nm
7. When atoms are bombarded with alpha
particles, only a few in million suffer 13. Ratio of radii of second and first Bohr
deflection, others pass out undeflected. orbits of H atom is :
(A) 2 (B) 4 (C) 3 (D) 5
This is because
(A) The force of repulsion on the moving
alpha particle is small 14. The ratio of radii of second orbits of He+ ,
(B) The force of attraction on the alpha Li2+ and Be3+ is :
particle to the oppositely charged (A) 1 : 2 : 3 (B) 6 : 4 : 3
electrons is very small (C) 3 : 4 : 6 (D) none of these
(C) There is only one nucleus and large
number of electrons 15. If the radius of Ist orbit of hydrogen atom is
(D) The nucleus occupies much smaller
volume compared to the volume of the 0.53 Å then radius of Ist orbit of He+ is :
atom (A) 1.27 Å (B) 0.265 Å

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 (C) 1.59 Å (D) 0.132 Å (A) 6656 Å (B) 6266 Å
16. If the velocity of the electron in first orbit of (C) 6626 Å (D) 6566 Å
H atom is 2.18 × 106 m/s,what is its value 24. Maximum number of spectral lines in
in third orbit ? Lyman series will be if electron makes
(A) 7.27 × 105 m/s transistion from nth orbit :
(B) 4.36 × 106 m/s (A) n (B) n – 1
(C) 1.24 × 105 m/s (C) n – 2 (D) n (n + 1)
(D) 1.09 × 106 m/s
25. The de Broglie equation suggests that an
17. When an electron drops from a higher electron has
energy level to a low energy level, then : (A) Particle nature
(A) energy is absorbed (B) Wave nature
(B) energy is emitted (C) Both Particle & wave nature
(C) atomic number increases (D) Radiation behaviour
(D) atomic number decreases
26. The wavelength of a charged particle
18. The maximum energy of an electron in an ________the square root of the potential
atom will be at : difference through which it is accelerated :
(A) Nucleus
(B) Ground state (A) is inversely proportional to
(C) First excited state (B) is directly proportional to
(D) Infinite distance from the nucleus (C) is independent of
(D) is unrelated with
19. The ionization energy of H-atom is 13.6 eV.
27. The de-broglie wavelength associated with
The ionization energy of Li+2 ion will be : a ball of mass 1 kg having kinetic energy
(A) 54.4 eV (B) 122.4 eV 0.5 Joule is.
(C) 13.6 eV (D) 27.2 eV
(A) 6.626  10–34 m
20. Correct relation between total energy (TE) (B) 13.20  10–34m
and potential energy (PE) (C) 10.38  10–21 m
TE
PE= (D) 6.626  10–34 Å
(A) 2 (B) TE = PE
PE PE 28. What possibly can be the ratio of the de
TE= TE=
(C) 4 (D) 2
Broglie wavelengths for two electrons each

21. The wavelength of a spectral line for an having zero initial energy and accelerated
electronic transition is inversly related to : through 50 volts and 200 volts ?
(A) No. of electrons undergoing transition (A) 3 : 10 (B) 10 : 3
(B) The nuclear charge of the atom (C) 1 : 2 (D) 2 : 1
(C) The velocity of an electron undergoing
transition 29. A helium molecule is moving with a
(D) The difference in the energy levels
involved in the transition velocity of 2.40 x 102 ms–1 at 300K. The
de-Broglie wave length is about
22. The spectral lines corresponding to the
radiation emitted by an electron jumping (A) 0.416 nm (B) 0.83 nm
from 6th, 5th and 4th orbits to second orbit (C) 803 Å (D) 8000 Å
belong to :
(A) Lyman series (B) Balmer series 30. If wavelength is equal to the distance
(C) Paschen series (D) Pfund series travelled by the electron in one second,
then -
23. Wavelength of first line of Balmer series in
hydrogen spectrum is :
(A)  = (B)  =
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 (A) 3 2 0 +½
(B) 3 1 0 +½
(C)  = (D)  = (C) 3 1 +1 0
31. Select the incorrect relationship among the (D) 3 0 –1 +½
following :
39. Spin angular momentum for an electron is
given as :
(A)
(A)
(B)
(B)
(C)
(C)
(D) (D) None

32. Heisenberg uncertainty principle is not 40. The orbital angular momentum of an
valid for electron in 2s-orbital is -
(A) moving electron
(B) motar car
(C) Stationary particle (A) (B) zero
(D) Both (B) and (C)

33. Magnetic quantum number specifies - (C) (D)

(A) Size of orbitals
(B) Shape of orbitals 41. Which of the following principles limits the
(C) Orientation of orbitals maximum number of electrons in an orbital
(D) Nuclear stability
to two
34. A p-orbital can accommodate (A) Aufbau principle
(A) 4 electrons (B) Pauli's exclusion principle
(B) 6 electrons (C) Hund's rule of maximum multiplicity
(C) 2 electrons with parallel spins (D) Heisenberg's uncertainty principle
(D) 2 electrons with opposite spins
42. Nitrogen has the electronic configuration
35. A given orbital is labeled by the magnetic
and not
quantum number m = –1. This could not
be which is determined
(A) s - orbital (B) p-orbital
(C) d-orbital (D) f-orbital by
(A) Aufbau's principle
(SECTION-B) (B) Pauli's exclusion principle
36. The electrons present in K-shell of the (C) Hund's rule
atom will differ in (D) Uncertainty principle
(A) principal quantum number
(B) azimuthal quantum number 43. For sodium atom the number of electrons
(C) magnetic quantum number with m = 0 will be :
(D) spin quantum number
(A) 2 (B) 7 (C) 9 (D) 8
37. The maximum number of 3d-electrons that
44. Which of the following ions has the

can have s = – , are maximum number of unpaired d-

(A) 10 (B) 3 (C) 5 (D) 7 electrons?

38. A correct set of four quantum numbers for (A) Zn2+ (B) Fe2+
unpaired electron in Cl-atom : (C) Ni3+ (D) Cu+
n l m s

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45. The total spin resulting from a d7 (C) (1 - r, 2 - s, 3 - p, 4 - q)
configuration is : (D) (1 - q, 2 - s, 3 - p, 4 - r)
(A) 1 (B) 2 (C) 5/2 (D) 3/2
49. A : It is not essential that all the lines
46. Which orbital is non-directional available in the emission spectrum will
(A) s (B) p (C) d (D) All also be available in the absorption
47. A 3p-orbital has spectrum
(A) Two non-spherical nodes R : The spectrum of hydrogen atom is only
(B) Two spherical nodes absorption spectrum
(C) One spherical and one Radial nodes (A) Both (A) and (R) are true and (R) is the
(D) One spherical and two non spherical correct explanation of (A)
nodes (B) Both (A) and (R) are true and (R) is not
the correct explanation of (A)
48. Match the following : (C) (A) is true but (R) is false
Column-I (D) (A) is false but (R) is true
Sub-atomic particles
(1) Electron 50. A : deBroglie equation has significance for
(2) Proton any microscopic or submicroscopic particles
(3) Neutron R : deBroglie wavelength is inversely
(4) Nucleus proportional to the mass of the object.
Column-II (A) Both (A) and (R) are true and (R) is the
Persons responsible for discovery correct explanation of (A)
(p) James Chadwick (B) Both (A) and (R) are true and (R) is not
(q) J.J. Thomson the correct explanation of (A)
(r) Rutherford (C) (A) is true but (R) is false
(s) Goldstein (D) (A) is false but (R) is true
(A) (1 - q, 2 - s, 3 - r, 4 - p)
(B) (1 - p, 2 - p, 3 - q, 4 - s)

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