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NDHH-C7-Equilibrium in Multi-Component Systems-2P

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11 views

NDHH-C7-Equilibrium in Multi-Component Systems-2P

Uploaded by

hthethien
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Chapter 8. The Thermodynamics of Multicomponent Mixtures

Chapter 9. Estimation of the Gibbs Energy and Fugacity of a


Component in a Mixture

Chapter 10. Vapor-Liquid Equilibrium in Mixtures

Chapter 11. Other Types of Phase Equilibria in Fluid Mixtures

Chapter 12. Mixture Phase Equilibria Involving Solids


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For ideal mixtures

Volume change on mixing and enthalpy change on mixing


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Enthalpy-concentration
diagram for aqueous sulfuric
acid at 0.1 MPa
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8.2 THE PARTIAL MOLAR GIBBS ENERGY AND THE GENERALIZED 11
GIBBS-DUHEM EQUATION

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8.4 EQUATIONS OF CHANGE FOR A MULTICOMPONENT SYSTEM
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8.4 EQUATIONS OF CHANGE FOR A MULTICOMPONENT SYSTEM

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Chapter 9. Estimation of the Gibbs Energy and Fugacity of a Component 25
in a Mixture

Chapter 9. Estimation of the Gibbs Energy and Fugacity of a Component 26


in a Mixture
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yi: a gas-phase mole fraction


xi: a liquid-phase mole fraction

∑𝒋 𝒚𝒋 𝑩𝒊𝒋

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where, again, A = aP/(RT)2, B = bP/RT, and ZL is the liquid

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9.4-3 Solid Mixtures

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The one-constant Margules equation provides a satisfactory representation for activity coefficient
behavior only for liquid mixtures containing constituents of similar size, shape, and chemical nature.
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For low electrolyte concentrations

δ is sometimes set to 0.1|z+.z−| and sometimes taken to be an adjustable parameter


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Chapter 10. Vapor-Liquid Equilibrium in Mixtures
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Starting point for all phase equilibrium calculations

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Chapter 11. Other Types of Phase Equilibria in Fluid Mixtures
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Chapter 12. Mixture Phase Equilibria Involving Solids
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