11th JEE Advanced

AJAA4.1/03 Test- 03

DURATION : 180 Minutes DATE : 22/12/2024 M.MARKS : 180

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (2.00) 19. (1.00) 37. (0.50)
2. (3.70) 20. (2.50) 38. (580.00)
3. (60.00) 21. (5.81) 39. (1.00)
4. (30.00) 22. (69.50) 40. (4.00)
5. (11.00) 23. (6.90) 41. (1.00)
6. (7.00) 24. (14.00) 42. (2.00)
7. (960.00) 25. (9.00) 43. (31.00)
8. (27.00) 26. (30.60) 44. (6.00)
9. (B, C) 27. (B, C, D) 45. (A, B)
10. (A, B, C, D) 28. (A, C, D) 46. (A, C)
11. (A, C) 29. (A, C) 47. (C, D)
12. (A, B) 30. (A, B, C) 48. (B, D)
13. (C, D) 31. (A, B, D) 49. (A, C)
14. (B, D) 32. (A, C, D) 50. (B, D)
15. (D) 33. (D) 51. (A)
16. (A) 34. (A) 52. (B)
17. (B) 35. (D) 53. (A)
18. (D) 36. (D) 54. (D)

[1]
 PART-I (PHYSICS)
1. (2.00) 4. (30.00)
V1 cos θ = V2 sin θ Figure shows the corresponding situation. Let the
V1 = V2 tan θ two shells collide at point A(x, y). If we take t1 and
t2 be the durations of the shells from shot to
V1 = V2 3 (given θ = 600)
reaching the point A, for first and second shell
Fixed respectively. We have x and y coordinate of A for
Vertical the two shells
Guide x = u cos t1 = u cos t2 (1)
m
1 2 1
V1 y = u sin t1 − gt1 = u sin t2 − gt22  (2)
2 2
P

V2 M

O

Now using conservation of energy.

1 1
mga (1− cos θ) = mv12 + Mv22
2 2 cos 
From equation − (1) t1 = t2 (3)
 2ga = 2v + 4v 2
1
2
2
cos 
Substituting this value in equation (2), we get
40 = 6v12 + 4v22
2
cos  1  cos  
 10v = 402
we get u sin  t2 − g  t2 
2
cos  2  cos  
 V2 = 2 m /s
1
 V1 = 2 3 m /s = u sin t2 − gt22
2
v1 sin  + v2 cos  2u cos  sin( − )
= = 2 rad / s On solving, we get t2 =
a (
g cos 2  − cos 2  )
Using value of t2 in (3) we get
2. (3.70)
2u cos  sin( − )
E(t) = A2e−at t1 =
dA dt
(
g cos 2  − cos 2  )
−1
Given :  = 0.2 s , = 1.25%, = 1.50% Time difference in firing, leading to the collision
A t
of the shells is
dE dA dt
 = 2  t 2u sin( − )
E A t t = t1 − t2 or t = = 30 seconds
g (cos  + cos )
= 2(1.25)  0.2(1.5)(4)
= 2.50  1.20 = 3.70% 5. (11.00)

3. (60.00)
The equation of the straight line shown in the
graph is
2
x = −1
v
dx At any time t
But v =
dt ωA = ωB = ω/R
2dt vt = ωBx
 x= − 1  xdx = 2dt − dx u
dx vt = x
15 t 15 R
  xdx = 2 dt −  dx vb = u
3 0 3
dx
1 Vx2 + Vr2 = u Vr =
 [225 − 9] = 2t − [15 − 3] dt
2 2
 108 + 12 = 2t  t = 60 s  u  2  dx 
 2 x +  =u
2
R   dt 

[2]
 2 x2  at / 2 = 0.5 m / s2 so at = 1m / s2 and v0 = 2 m / s
2
 dx 
  = u  1 − 2
 dt   R  The accelerations at times t1 = 2 s and t2 = js can
be calculated as the resultant vector of the
R t
dx tangential and normal (centripetal) accelerations,
 = u  dt
whose magnitude is:
x2
0
1− 0
2
R 2  v2 
a= at2 + an2 = at2 + 
R
 x
R
 
R sin −1  = ut
 R 0 v = v0 + at t .
22
28 
7 = ut
2
t = 11 sec.

6. (7.00)
VmM = 4iˆ + 3 ˆj
Substituting this into the expression for
Vm = uiˆ + 3 ˆj acceleration, we obtain:
VM = −Viˆ
( v0 + at t1 )4 1
 R 2 at2 + ( v0 + at t1 )
4
Here, along horizontal direction mVm + MVM = 0 a1 = at2 + 2
=
4 R R
um
V= = u and u + V = 4  u =
M 1+ 
To move one meter w.r.t. ground ( v0 + at t2 )4 1
 R 2 at2 + ( v0 + at t2 )
4
a2 = at2 + 2
=
4 R R
2 3
1+  24 14
1= 1+  = or  = = 1.40
g g 10 The ratio of the accelerations is given:
R 2 at2 + ( v0 + at 1 )
4
a1 1
= =
R 2 at2 + ( v0 + at 2 )
t2 2 4

7. (960.00) Squaring the equation and isolating the radius

give:
1 ( v0 + a1t2 ) − 4 ( v0 + a1t1 )
4 4
R=
a1 3
Substituting known values, we find:

( 2 m / s + 1m / s  5 s ) − 4 ( 2 m / s + 1m / s  2 s )
2 4 2 4
u2 1
r = Net R=
a⊥ 1m / s2 3
uNet = 120 m/sec s 2401m / s − 1024 m / s 4
2 4 4 4
a⊥ = a0 sin37° =
m 3
a⊥ = 15 m/sec2
1377 2
r = 960 m = m = 459 m
3
8. (27.00)
Since the distance covered is a quadratic function 9. (B, C)
of time, velocity must be a linear function of time. The ball would strike the ground with minimum
In general, if the distance covered can be written
speed only when it were projected with minimum
in the form of
1 mechanical energy.
s = at t 2 + v0t then v = v0 + at t ,
2  2
umin + 2 gh = vg2 ….(i)
where v0 is the initial velocity, at is the tangential
acceleration and t is the time elapsed. Comparing 2 ( h − R cos  )
the parametric equation with the one given in this  umin = R sin  ….(ii)
g
case:
s = 0.5t 2 + 2t 2 g ( h − R cos  )
 tan  = ….(iii)
it follows that umin

[3]
  2
umin = Rg cos  v2
 aT =
R
R  1 + cos 2  
 h=  
2  cos   dv v 2
− =
dt R
 1 
 vg2 = Rg cos  + Rg  + cos  
 cos   v2
 dv = − dt
Rg R
 vg2 = 2 Rg cos  +
cos  1
v
1
− =− t
 1  v v0 R
 2 cos  + 2 2
 cos   v
1 1
 for (vg) minimum − =− t
v v0 R
( vg )min = 2 1
2
 2 Rg when cos  = 1 1 t
2  = +
v v0 R
Rg
2
umin =
2 v0
v=
vt
Rg 1+ 0
umin = R
2
v2 dv
hmin =
3R Since, aT = aN = and aT = v
2 2 R dS
dv v2
v =−
10. (A, B, C, D) dS R
v dv 1 S
mv0 = 2mv '  v ' =
v0  = −  dS
v0 v R 0
2
v0 v S
Just after collision, v A = and vB = 0  log e v v = −
2 0 R
 v  S
 log e   = −
 v0  R
S
v v −
mv0 = 3mv ''  v '' = 0  =e R
3 v0
2 2
v  1 v  S
1 2 1 −
kx0 = 2m  0  − 3m  0   v = v0 e R
2 2  2 2  3
m
 x0 = v0 13. (C, D)
6k
2
1 1 v  mv 2
Loss in KE = mv02 − (2m)  0  = 0
2 2  2 4

11. (A, C)
Since pull of string on both the blocks are equal
and limiting friction on the block B is smaller than
that on block A, the block B slides whereas block mv 2
 mg cos  − N = ….(i)
A does not slide on the plank under the given R
conditions. 1 2
 mv = mgR (1 − cos  ) …(ii)
2
12. (A, B)  N = mg (3 cos β – 2)
Given that, aT = aN N ' = Mg + 2mg cos ( )( 3cos  − 2 )

[4]
 dN ' 3x
=0 y=
d 2
1 By solving, we will get the answer
 minimum at cos (  ) =
3 40
a1 = m / s2
2 19
' = Mg − mg
N min
3
17. (B)
14. (B, D) [Acceleration] = LT −2 
 
The front and the rear cars travel the distances
5
s2 and s1 respectively in the interval [t1, t2]. The  unit of acceleration = (1 km)(1 min) −2 = m / s2
18
front and the rear cars spend the intervals [t1, t3]
and For( B) : [Kineticenergy] =  ML2 T −2 
 
[t2, t4] respectively on the bridge.
 Unit of kinetic energy = (1 Quintal)(1km)2 (1min)−2
s
v1 = 1 = 25 m / s 5
t2 − t1 = 105 kgm 2 s −2
18
s2
v2 = = 10 m / s For(C) : [Pressure] = ML−1 T −2 
t2 − t1  
s2 ( t3 − t1 )  Unit of pressure = (1Quintal)(1km)−1 (1min)−2
= 700 m
( t2 − t1 ) 5
= 10−4 kgm −1 s −2
18
15. (D)
For(D) : [Work] = ML2 T −2 
 
vB2 = u 2A − 2 ghAB = (9 g ) − (2 g ) = 7 g
 Unit of power = (1Quintal)(1km)2 (1min)−3
 vB = 7 g
5
 104 kg m 2 sec −3
v2 108
 B =7
g
18. (D)
mvB2
Further, TB = = 7mg By conservation of linear momentum, we have
mv = mg A + mvB
T 7
 B =  v A + vB = v …(1)
2mg 2
Also, applying the definition of e, we get
Again vC2 = v2A − 2 ghAC = (9 g ) − 2 g (2 ) = 5g v −v 
e = − A B 
 vC = 5g  0−v 
 v A − vB = ev …(2)
vC2
 =5 From equations (1) and (2), we get
g
1− e  1+ e 
mvC2 vB =   v and v A =  v
Further, TC + mg =  2   2 
From equations (1) and (2), we get
 TC = 4mg
1− e  1+ e 
T vB =   v and v A =  v
 C =4  2   2 
mg For elastic collision, e=1 so vA = v
v
For perfectly inelastic collision, v A =
16. (A) 2
m1 g − T2 − T1 = m1a1 1 3v
For inelastic collision having e = , v A =
m1 g − 2T1 − T1 = m1a1 …(1) 2 4
2T1 − m2 g = m2 a2 …(2) 1
For inelastic collision having e = , v A =
5v
x 4 8
y= +x
2

[5]
 PART-II (CHEMISTRY)
19. (1.00) 22.24
in given sample =  100 = 69.5
The equilibrium constant of second reaction is 32
very large and hence the equilibrium
concentrations may be determined by adding the 23. (6.90)
reactions K = K1  K2 = 1 10Al + 6KMnO4 + 27H 2SO4 →
A + B D + E 6KHSO4 + 5Al2 (SO4 )3 + 6MnSO4 + 24H2O
Initial moles 2 5 0 0
Moles at equilibrium 2−x 5−x x x 24. (14.00)
Equilibrium 2−x 5−x x x
concentration 2 2 2 2
 x  x 
K=
 D E  =  2  
 2 
 A B  2 − x  5 − x 
  
 2  2 
x2
1=  x = 1.428
( 2 − x )( 5 − x )
C 
x
C D 
K1 =  5  10−6 = 2
A 2−x  a =10
  b =3
 2 
c =1
[C] = 2  10–6 M
25. (9.00)
n =1, then X = H; A = N
20. (2.50)
Pb (i) NH −2
Z =1+
RT (ii) NH3
b  (iii) NH +4
So, slope = =
RT 985.2 lone pair a =2, b = 1, c = 0
 4 a 3 + b2 + c = (2)3 + (1)2 + (0) = 9
b=  RT = 4  r 3  N A
985.2 3
0.0821 300  10−3 16 26. (30.60)
=  6  1023 r 3
492.6 3 Z2
−10 KE = 13.6 
 r = 2.5  10 m n2
 r = 2.5 Å 32
= 13.6  = 30.6eV
22
21. (5.81)
2
SA = 0.5R ln 27. (B, C, D)
(A) When 0 mL HCl is added, CO3−2 is present
1
= 2.905 Joule
which undergoes hydrolysis in two steps
Same for B, SB = 2.905 Joule
As Ka2 < < Ka1
 STout = 2.905 + 2.905 = 5.81 Joule 1 1

Ka 2 Ka1
22. (69.50)
Kw Kw
m.eq. of FeSO4 .7H 2O in 1 litre  
Ka 2 Ka1
 1000 
= 20  0.02  5    = 80 Kh1 > > Kh2
 25  [Hence, 2nd step of hydrolysis is neglected]
W 1
  1  1000 = 80  W = 22.24  pH = 7 + ( pKa 2 + log C )
278 2
Mass of FeSO4 .7H 2O 1 1 
= 7 + 10.3 + log 
2 50 

[6]
 1 n. f. for S2O32− = 1, N× V = (0.5 × 1) × 1000 =
=7+ (10.3 − 1.7 )
2 500
1 n. f. for I2 = 2
= 7 + ( 8.6 )
2
= 7 + 4.3 32. (A, C ,D)
pH = 11.3 1 mole NH3 = 17gm
1 mole Ag =108gm
1 mole Ca = 40gm
28. (A, C, D)
 1 33. (D)
1 1 
= RZ2  2 − 2  Based on structure of given species.
 n 
 i nf 
1 1 1  34. (A)
= R  (4)2   − 2  (I) Dissolution of CO2 (or any gas) in water is
 1 4  exothermic and takes place with a decrease
1 15 in volume.
= R  16 
 16 Hence, low temperature and high pressure
1 favour the process.
 (II) ΔH < 0, Δng or ΔV < 0. Low temperature
15R
2 and high pressure favour the process.
4
E n = −13.6  = −13.6eV (III)
42
= −2.176  10−18 Joule H = 2Hf ( NO2 ) − Hf ( N2O4 ) = 2  33.2 − 9.2
1  1 1  = 57.2 kJ  0.n g or V  0. Hence
= RZ2  2 − 2 
 n 
 i nf  favourable conditions-high T and low P .
For longest , n i = 4, n f = 5 (IV) H = 2Hf (NO) − Hf ( N 2 ) − Hf ( O2 )
= 2  90 − 0 − 0 = 180 kJ  0 High
29. (A, C) temperature favours the reaction. Pressure
Gas is undergoing free expansion, so, process is has no effect, for Δng = 0
irreversible adiabatic as well as isothermal.
V 35. (D)
Ssyst = nR n 2
V1 (I→P,R,T) In isothermal process, w= –2.303 RT
2.73 Vi V 
= nR ln = nR log  2 
Vi  V1 
PV (II→S) In adiabatic process,
Ssyst = i i
nR
Ti −w = ( T2 − T1 )
(  − 1)
(III→Q,T) In free expansion, w=0
30. (A, B, C) (IV→Q,T) In free expansion, w=0
7.5 3 3
(A) KE =   RT = RT 36. (D)
30 2 8
In case of isoelectronic ion size increase with
increase in negative charge
(B) Na   F  O−2  N3− .
nRT 3  0.1RT 3 RT As we move down the group, ionic radius
V= = =  increases while hydration decreases. Therefore
P P 10 P
ionic mobility of hydrated ions decreases
M WNH
(D)
rH 2
= 3
=
17
= 2.92 Li  Na   K   Rb  Cs
rNH3 M WH 2 Due to high electron density electron affinity
2
decreases.
Cl  K  Ca 2 + Sc3+
31. (A, B, D) ⎯⎯⎯⎯⎯⎯⎯⎯→
Size decreases
(N  V) I 2 = (2×1) × 250 = 500 EN increases
EA increases
n. f. for Cu2S= 10, N × V = (0.5 × 10) × 100 =
500
n. f. for CuS=8, N× V = (0.5 × 8) × 125 = 500

[7]
 PART-III (MATHEMATICS)
37. (0.50) 1 3
 Roots are , 1, and 2
for K = 1,
3
(
1 1 1
)
C0 +1 C1 =  2 =
3
2
3 x4
2 2

2  =4
( 2 C0 +2 C1 +2 C2 ) =  23 
1 x1
for K = 2, 2
3
3 41. (1.00)
for K = 3,
33
1
(
C0 + C1 + C2 + C3
3 3 3 3
) 2
= 
3
 (1 + tanx°) (1 + tan(x + 1)°(1 + tan (x + 2)°
…. (1 + tan (x + 44)°))) = 223
____________________ We have
____________________ (1 + tan 1°) (1 + tan2°) (1 + tan3°) ….. (1 +
tan44°) (1 + tan45°) = 223
12 2 2 
2 2
 sum =  +   +   + .....  Equality occurs at x = 1
4  3  3   3  

 2  42. (2.00)
1 3  2
=   = = 0.50 (
f ( x ) = cos x sin x + sin 2 x + sin 2  )
4 1− 2  4
 3  f ( x ) sec x = sin x + sin 2 x + sin 2 
 (f (x) sec x – sinx)2 = sin2x + sin2θ
38. (580.00)  f 2 (x) (1 + tan2x) – 2f (x) tan x = sin2θ
10 IIT students T1, T2,.....T10 can be arranged in  f 2 ( x ) tan 2 x − 2 f ( x ) tan x + f 2 ( x ) − sin 2  = 0
10! ways. Now the number of ways in which two
tan x is Real  D  0
NEET student can be placed will be equal to the
number of ways in which 3 consecutive IIT  (
4 f 2 ( x )  4 f 2 ( x ) f 2 ( x ) − sin 2  )
students can be taken i.e. in 8 ways and can be
arranged in two ways  (10 !) (8) (2 !).  f 2 ( x )  1 + sin 2   f ( x )  1 + sin 2 
Alternatively,3 IIT students can be selected in
10
C3 ways. Now each selection of 3 IIT and 2 43. (31.00)
NEET students in P1T1T2T3P2 can be arranged in −
| x|

(2!) (3!) ways. Call this box X. Now this X and ( x − 3) x ( x − 4) 4 (17 − x)
0
the remaining IIT students can be arranged in 8!
ways
( )
− x − x 2 + x − 1 (| x | −32 )

 Total ways 10C3 (2!) (3!) (8!)] = 58060800 For − x to be defined x < 0
−| x|
39. (1.00)  =1
x
Since ( x − 4)2 , − x are positive & –x2 + x – 1
is always negative
( x − 3)( x − 17)
0
x + 32
Let f(x) =ax2 + (a – 2) x – 2 1
x0   0  x = 31
f (0) = –2 and f (–1) = 0 x + 32
Since the quadratic expression is negative for
exactly two integral values 44. (6.00)
 f(1) < 0 and f(2)  0   
 a + a – 2 – 2 < 0 and 4a + 2a – 4 – 2  0 Let x = , y = ,z =
a b c
 a<2 and a  1 L.H.S reduced to
 a  [1, 2) 2

40. (4.00)
(  a b c
a 2 + b2 + c 2  + + 
  
)
Equation has four positive real root. Using A.M  G.M.
1 2 3 4 1


+ + +
x1 x2 x3 x4 

24 
1/4

 =2
a 2 + b2 + c 2
a+b+c
( )
  2 a  2b  2 c a + b + c
4  x1.x2 .x3 .x4  a b c
 ++  
1


1
=
2
=
3
=
4
=k   1 1 1  a + b+c
 a b c 
x1 x2 x3 x4 a+b+c    
 k=2
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 2 48. (B, D)
( a b c
)
 a 2 + b2 + c 2  + +   ( a + b + c )
3
20 20
      ar xr =  ar 2r −10  x20−r
r =0 r =0
( a + b + c )3 = 216, a + b + c = 6 2
(by replacing x by and compare coff. of x7)
x
45. (A, B) a7
Equation reduces to x (x – 1) (x2 – x + 1) + a = 0  =8
a13
Let x2 – x = t
a
t2 + t = − 49. (A, C)
8
 log 3 3 
 1
2
1 a log tan   + log 3 3  = −1
 t +  = −  log 3 tan  
3 3
 2 4 8
1  1 a  2 
 t + =  c  Let c = −   log 3 tan   + 3  = −1
2  4 8  log 3 tan  
1 Let log 3 tan  = y
 x2 − x = −  c
2
2
 1 1
2  y + 3 = −1
 x−  =−  c y
 2 4
2 1
1 1  +3 =−
 x=  −  c y y
2 4
2 1
1  +3= 2
(i) if c > 0 and c  then 2 non real roots, sum = 1 y y
4
(ii) if c < 0 4 non real roots, sum = 2  y 3 y 2 + 2 y − 1 = 0
 
y<0
46. (A, C) y = –1
sinβ + sinγ + sinδ = 1 – sinα y cannot be positive
cos2α + 1 – 2sin2β + 1 – 2 sin2γ + 1 – 2sin2δ   log 3 tan  = −1
10/3
1
1  tan  =
 cos 2  + 2sin 2  + sin 2  + sin 2  3
3
 7
1 ( sin  + sin  + sin  ) 2  = and
 1 − 2sin   + 2
2 6 6
3 3  There are two value of θ in [0, 2π]
1 + 2 (1 − sin  )
2
= 50. (B, D)
3
N = 210 33 55
 3 − 6sin 2   2sin 2  − 4sin  + 3  No of divisors = 11  4  6 = 264
 8sin2 α – 4sin α  0 No. of even divisors = 10  4  6 = 240
 
    0, 
 6 51. (A)
1
(I) t( n +1) = tn +
47. (C, D) 2
t1, t2, t3 , ….. is an AP with common
 1 1 1 
Here y − x = 3  + + + ...  1
2 2
4 2
62
 difference
2
1 1 1
and x − z = + + + ... (II) a1 + 2d + a1 + 4d + a1 + 10d + a1 + 16d + a1
22 42 62 + 18d = 5a, + 50d
 y − x = 3 ( x − z )  y − x = 3x − 3z = 5(a1 + 10d) =10
 4x = y + 3z i.e. a1 + 10d = 2
Now,
4 x y 3z
 = + 21
21
6 6 6  ai = 2  2a1 + 20d  = 21( a1 + 10d ) = 42
x y z y x z i =1
 2   = +  , , are in A.P.
3 6 2 6 3 2

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 (III) S = 1 + 5 + 13 + 29 + …. + t10 
S = 1 + 5 + 13 + …. + t9 + t10 Correct  = ,3
6
Subtrating (II) Equation
t10 = 1 + 4 + 8 + 16 + …. up to 10 terms  (cot (x + y) – tan (x + y))2 + (y + 1)2 = 0
= 1 + (4 + 8 + 16 +…. Up to 9 terms) 
= 2045  y = −1, x + y = 
(IV) (11 + 13 + … + 99) – (15 + 21 + … + 99) 4
= 1620.    
PQ = −  −  =
4  4 2
52. (B) (III) |(1, 1) (1, 2) (1, 3) (2, 1) (2, 2) (3, 1)| 6
(16+3−1)C 18  17 points
(I) 3−1 = 18C2 = = 153
2 (IV) Area = 2  1 / 2  6  6 = 6
n 6
(II) +1 = +1 = 4
2 2 54. (D)
(III) Total number of terms – rational terms (I) (t, 2 – t)  |4 (t) + 3(2 – t) – 12| = 5
= Irrational terms  101 – 4 = 97  t = 11, 1
 1 2
12 (II) Let shifted to (a, b)  (x + a)2 + (x + a) (y +
(IV) put x = y = z = 1  1 + +  = 212 b) – 3(x + a) – (y + b) + 2 = 0 for given is
 3 3 true it a = 1 and b = 1
(III) Line passed through the centroid
53. (A) (IV) (a, b) = (2, 4) or (4, 2)
(I) x = 0; y = 0
1 1
x= ; y=
2 2
1 1
0  sin 2    0  sin   ;
2 2

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