EnvironmentalEngineering_lecture4b
EnvironmentalEngineering_lecture4b
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1
2-13 INFLUENCE OF METEOROLOGICAL PHENOMENA ON AIR
QUALITY
Atmospheric dispersion of air contaminants is the result of
ventilation, atmospheric turbulence, and molecular diffusion
انتشار الجزيئي.
2-14 LAPSE RATES AND DISPERSION
By comparing the ambient lapse rate to the adiabatic lapse
rate, it may be possible to predict what will happen to gases
emitted from a stack.
When the ambient lapse rate is super adiabatic (greater than
the adiabatic), the turbulence of the air اضطراب الهواءitself
causes the atmosphere to serve as an effective vehicle of
dispersion.
Fig. 2-7 Effect of lapse rate on plume behavior ( اضطراب الهواءa) looping,
(b) neutral, (e) coning, (d) fanning, (e) lofting, (j) fumigating, and (g) trapping.
2-15 PRESSURE SYSTEMS AND
DISPERSION
• High- pressure systems are related to clear skies, light
winds, and atmospheric stability. When such a system
becomes stagnant over an area for several days, air
contaminants can build up to cause air pollution
problems.
• Conversely, low-pressure systems are associated with
unstable atmospheric conditions and commonly
brining winds and rain; contaminant buildup is less
likely to occur in low-pressure cells. Initially, a warm
front will reduce air-contaminant concentrations,
primarily through the storm activity along its leading
edge. As the warm front develops, however, more
stable conditions will result, with an accompanying
increase in air pollution potential.
2-16 WINDS AND DISPERSION
Wind is one of the most important vehicles in the distribution توزيع,
transport نقل, and dispersion تشتتof air contaminants.
2-17 MOISTURE AND DISPERSION
The presence and amount of water vapor in the atmosphere affects the
amount of solar radiation received and reflected by earth. Water vapor
serves to scatter or absorb radiation energy, and hence humidity has a
major influence on air quality.
Precipitation serves as a cleansing agent عامل التطهيرfor the atmosphere,
removing particulates and soluble gases in a process called washout.
When rainfall removes sulfur dioxide (SO2) from the air, it may react with
the water to form H2SO3 (sulfurous acid) or H2SO4 (sulfuric acid).
2-18 MODELING النمذجة
A knowledge of meteorological phenomena and an understanding
of the variable factors that build weather systems can be used as a
basis for forecasting air pollution potential and for devising air-
pollution prevention and abatement programs
2-18-1 Dispersion Models
Several empirical dispersion models have been developed. These
models, or equations, are mathematical descriptions of the
meteorological transport and dispersion of air contaminants in an
area, and permit estimates of contaminant concentrations, either
in the plume from an elevated or ground-level source. Most of the
equations in use today are based on the following general
equation which was suggested by Pasquill and modified by Gifford.
dC ∂ ∂x ∂ ∂x ∂ ∂x
= Kx + Ky + Kz (2-1)
dt ∂x ∂x ∂y ∂y ∂z ∂z
1 H
2
1 y
2
Q
C x ,y = exp − exp −
(2-2)
u y z 2 z 2 y
where C = pollutant concentration, g/m3
Q = pollutant emission rate, g/s
π = pi, 3.14159
u = mean wind speed, m/s
σy = standard deviation of horizontal plume concentration,
evaluated in terms of downwind distance x, m, (as shown in
Fig. 2-9)
σz = standard deviation of vertical plume concentration evaluated
in terms of downwind distance x, m, (as shown in Fig. 2-10)
exp = base of natural logs, 2.71828183
H = effective stack height, m
x = downwind distance along plume mean centerline from point
source, m
y = crosswind distance from the centerline of the plume, m
This equation may be simplified if concentrations along only
the plume centerline are needed. In this case, Y = 0, and the
equation is as follows:
Q 1 H
2
C x,0 = exp − 2-3)
(
u y z 2 z
The equation may be further simplified if the
effective stack height is zero, such as in a situation of
ground-level burning.
Q
C x ,0 = (2-4)
u y z
Values of σy, and σz, for various distances down-wind (x), with various
stability categories, are indicated in Figs. 2-9 and 2-10. Generalized
categories are included in Table 2-1.
Fig. 2-9 Lateral diffusion coefficient σy, vs. downward
distance from source.
Fig. 2-10 Vertical diffusion coefficient σz
vs. downward distance from source.
Table 2-1 Pasquill stability types
Surface Day
wind Incoming solar radiation Night
speed m/s
Mostly Mostly
Strong Moderate Slight
overcast clear
2< A A-B B
2 A- B B C E F
4 B B-C C D E
6 C C-D 0 D D
6> C 0 D D D
h 1000 g
Q = 458 kg SO 2 / h x x =127 g / s
3600 s kg
2. Determine location of maximum concentration.
For the given atmospheric conditions choose C. For class C.
the σz / σy ratio is a constant for distances up to 1 km from
the stack. Therefore, a = 0.707H = 0.707 x 75 = 53 m
From Fig. 2-11, σz reaches a value of 53 m at a distance of
about 850 m from the stack with class C atmosphere.
Thus. x max = 850m
3. Determine concentration at x max
From Fig. 2-10. σy = 88 m at x = 850 m.
Q 1 H
2
C x,0 = exp −
u y z 2 z
2
127 1 75
Cmax = exp−
x 6 x 53 x 88 2 53
Q
1 H
2
C x ,0 = exp −
u y z 2 z
127
1 75
2
= exp−
x 6 x 170 x 280
2 170
1 H 2
1 y
2
Q
C ( 3 , 0 .4 ) = exp− exp−
u y z 2 z 2 y
127 2
1 85
1 400
2
= exp− exp−
x 6 x 170 x 280
2 170
2 280
v d T d
1.5 +
2.68 x10 p T
−3
h = s (2-6)
u s
where Δh = rise of plume above the stack, m
vs = stack gas velocity, m/s
d = inside stack diameter, m
u = wind speed, m/s
p = atmospheric pressure, millibars
ΔT = stack gas temp. minus air temp., K
Ts =stack gas temperature, K
Fig. 2-11 Effective stack height H
The preceding calculations are suitable for neutral conditions.
For unstable conditions, Δh should be increased by a factor of
1.1 to 1.2, and for stable conditions, Δh should be decreased
by a factor of 0.8 to 0.9.
Davidson and Bryant present another equation for plume rise.
T
1 .4
vs (2-7)
h = d
1 + T
u s
Example 2-3: Calculating effective stack height Determine
the effective height of a stack given the following data.
(a) Physical stack is 203 m tall with 1.07 m inside diameter.
(b) Wind velocity is 3.56 m/s.
(c) Air temperature is 13°C.
(d) Barometric pressure is 1000 millibars.
(e) Stack gas velocity is 9.14 m/s.
(j) Stack gas temperature is 149°C.
SOLUTION
1. Convert temperatures to K.
Ta = 273 + 13 = 286 K
Ts = 273 + 149= 422 K
2. Calculate ΔT.
ΔT = 422 - 286 = 136K
3. Calculate Δh using Eq. (2-7).
v sd T d
1.5 + 2.68 x10 p
−3
h =
u Ts
9.14 x 1.07 − 3 1000x 136 x 1.07
h = +
3.56
1.5 2.68 x10
422
= 6.6 m
4. Calculate effective stack height.
H = h + Δh = 203 + 6.6 = 209.6 m
2-20 EFFECTS OF AIR POLLUTION ON
METEOROLOGICAL CONDITIONS
The interrelatedness of atmospheric conditions and
air quality should be evident from the foregoing
discussion of the effects that meteorological
conditions can have upon the dispersion,
concentration, or removal of atmospheric pollutants.
2-20-1 Changes on the mesoscale and Microscale
On the regional and local scale, reduced visibility,
altered precipitation, and the "urban heat island"
effect are among the changes in weather that have
been attributed to air pollution.
2-20-2 Reduced visibility.
Particulates in the size range of 0.38 to 0.76 µm and gas
molecules (especially sulfur dioxide) are the major
contaminants that contribute to reduced visibility.
2-20-3 Altered Precipitation
Air contaminants either emitted
to or formed in the atmosphere
can result in increased
precipitation. This phenomenon
occurs because small particles act
as nuclei, inducing the formation of
raindrops, the same principle
operant in cloud seeding.