Lecturer Department of Textile Engg. • In textile wet or chemical processing the chemical treatments are given to the fabric after being manufactured. Actually the fabric coming from the loom is not having properties like absorbency, softness etc and the most important is that the appearance of the fabric is dirty or pale yellow; we cannot use it directly for making apparels or clothing. So, it is necessary to go for chemical processing of the material to make it wearable. Flow Chart of woven fabric wet processing Steaming/Curing ↓ Washing ↓ Drying ↓ Heat setting ↓ Finishing ↓ Inspection ↓ Packaging Flow Chart of knit fabric wet processing Grey fabric inspection ↓ Batching ↓ Fabric turning ↓ stitching ↓ Loading to the m/c ↓ Pre-treatment (Scouring & Bleaching) ↓ Dyeing ↓ Dewatering ↓ Drying ↓ Compacting & Calendaring ↓ Final inspection & packing Wet Processing Chemicals and Auxiliaries In practice the materials without which a process cannot be completed are termed as “Chemicals” and the other substances which facilitate or improve the performance of that process are termed as auxiliaries.Some commonly used chemicals or auxiliaries are: acid, alkali, salt, oxidizing agent, reducing agent, detergent, wetting agent, levelling agent, softener, sequestering agent etc. Pretreatment Processes • Natural fibers and synthetic fibers contain primary impurities that are contained naturally, and secondary impurities that are added during spinning , knitting and weaving processes. Textile pretreatment is the series of cleaning operations. All impurities which causes adverse effect during dyeing and printing is removed in pretreatment process. Pretreatment processes include desizing,scouring and bleaching which make subsequent dyeing and softening processes easy. Flow chart of pretreatment processes with basic objects Grey fabric inspection Assessment of different types of faults. Stitching Adding two or more fabric together. Brushing To rise up the lying fibers. Shearing and cropping Removal of excess thread from the Fabric. Singeing Removal of short fibers from the fabric surface by burning. Desizing Removal of sizing materials from fabric. Scouring Removal of natural and foreign Materials. Bleaching Destruction of natural coloring materials and improving whiteness. Mercerizing Treatment of cotton fabric in strong alkali under tension. 1)Inspection of grey fabric: The fabric found from loom pr knitting machine is passed through the inspection table to find any kind of fault such as end breakage,picks,holes,neps etc.Then fault free fabric is selected for subsequent processing. Fabric inspection involves three possible steps: perching, burling and mending. 2) Stitching: Sometimes the woven fabric from loom is not of enough length as required and in such cases the fabrics are joined to make it larger through stitching. 3) Shearing and cropping: Shearing and cropping operation consists of cutting the loose strands of fibres from either surface of a fabric or excess warp or weft yarn on fabric edges with a sharp edged razor or scissors. 4) Singeing: The verb ‘singe’ literally means ‘to burn superficially’. Technically, singeing refers to the burning- off of loose fibres not firmly bound into the yarn or fabric structure. Singeing is an important part of pretreatment. This is the burning off of protruding fiber ends from the surface of the fabric. If not done properly, unclear print patterns, mottled fabric surfaces and pilling results. 5) Desizing: Sizing materials are added to increase the strength of warp yarn.During wet processing, various chemicals are applied and before starting these processes we must be sure of maximum absorption of these chemicals.The removal of sizing materials is called desizing.The major methods of desizing are- a) Hydrolytic method: rot steeping,acid steeping,alkali steeping,enzymatic steeping. b) Oxidative method: chlorine,chlorite,bromite. 6) Scouring: The term ‘scouring’ applies to the removal of impurities such as oils, wax, gums, soluble impurities and sold dirt commonly found in textile material and produce a hydrophilic and clean cloth. This process essentially consists of treatment with soap or detergent with addition of alkali. Depending on the fiber type alkali may be weak(soda ash) or strong(caustic soda). Objectives of scouring are- • To remove natural as well as added impurities of essentially hydrophobic character as completely as possible • To increase absorbency of textile material • To leave the fabric in a highly hydrophilic condition without undergoing chemical or physical damage significantly. 7) Bleaching: Bleaching is chemical treatment employed for the removal of natural coloring matter from the substrate. The source of natural color is organic compounds with conjugated double bonds , by doing chemical bleaching the discoloration takes place by the breaking the chromophore , most likely destroying the one or more double bonds with in this conjugated system. The material appears whiter after the bleaching. Bleaching agents are of two types: i)Oxidative agents: are used for natural cellulosic fibers eg; H2O2,Ca(OCl)Cl,NaOCl etc. ii)Reductive agents: are mainly used for protein fibers eg;H2,H2S,SO2,Na2SO4 etc. 8)Souring: After alkaline treatment a neutralization process with weak acid is needed to remove excess alkali.This process is known as ‘souring’.After bleaching the material is treated with dilute H2SO4 or HCl or CH3COOH at room temperature. 9)Mercerization: Mercerizing is a chemical process introduced by John Mercer in 1844 to improve the luster and increase strength.In this process fabric is treated with specific concentration of alkali(NaOH) under tension.This process improves strength and dye absorption of cotton fiber. Fig: Mercerization effect on cotton
10)Washing and rinsing: After every wet process
fabric is washed with hot and cold water for several times. Sometimes soap solutions are also used for washing. 11)Dewatering and drying: The fabric is then dewatered followed by drying to remove water. Dyeing, Printing and Finishing • Textiles are usually coloured to make them attractive for aesthetic appeal. There are two ways of adding colour to a textile substrate-printing and dyeing. Printing adds colour to the surface in discrete places, whereas dyeing completely covers the substrate with colour. • The process of coloration of textiles is termed as dyeing.In this process different types of dyes are used to produce different shades at different fabrics. Theory of dyeing The general theory of dyeing explains the interaction between dye,fiber,water and auxiliaries.The dyeing process is essentially a distribution process.The dyeing process consists of three stages which are: Migration of dye from solution and adsorption on the surface of fiber Diffusion of dye into core of the fiber Bonding between fiber and dye molecules by covalent,ionic,van-der-walls,H-bond or other physical forces Classification of dyes based on application • Direct • Reactive • Vat • Azoic • Sulphur • Disperse • Acid • Basic • Metal Complex Terms and Definition related to Dyeing Shade% : Shade% means the depth of color.It is expressed as percentage(amount of dye in unit weight of fabric). Scale of shade%: Light shade: upto 0.5% on the weight of fabric (owf) Medium shade: 0.6-1.5%; owf Dark shade:1.6% and above ;owf Substantivity: Natural attraction between dyes and fibers is termed as substantivity.This pheomena influence the dye transfer from dye bath to textile materials without any auxiliaries. Affinity: is forced attraction between dyes and fibers.It is a quantitative expression of substantivity. Color strike: Initial absorption of dyes due to result of substantivity is called the color strike.at the starting of dyeing,the rate of dye transfer from solutin to textile material is more than any other time.After 30 seconds,50% dyeing is completed. Exhaustion: Total amount of dyes absorbed by the fiber in a dye bath after the adsorption,sorption and desorption is completed.It is expressed as E%. Fixation: Total mount of dyes finally fixed with the fiber after washing in a dyeing process.It is expressed by F%. F%= E% - (washing+soaping+other treatments) loss Printing Printing is the method of localized application of dyes or pigments that produce particular color effect on fabric according to design. Printing can be described as the controlled placing of defined areas of color on to a substrate. The colorant (dye or pigment) must first be brought to the fiber surface usually in the form of a printing paste. Printing Methods The procedure of creating printing effect according to the design by using different types of instrument is called method of printing. The methods used for printing is given below: a) Block b) Flat press c) Stencil/Spray method d) Screen e) Roller f) Transfer g) Flock h) Engraved roller. i) Burn-out j) Photographic k) Digital or ink jet Style of Printing • Sometimes we use various types of technique in different printing methods to perform the printing effect easily. This effect of printing is called style of printing. Style of printing mostly depends on the behavior of the dye and chemicals to be printed. It can be divided into following groups: a) Direct b) Dyed c) Azoic d) Metal e) Crepe or crepon f) Discharge i. White discharge ii. Color discharge g) Resist h) Raised Printing Procedure Selection of dye according to fabric
Select appropriate style of printing
Select appropriate method of printing
Prepare printing paste
Apply printing paste according to selected method
Fixing the printed fabric (Curing at high temperature)
Finishing The term finishing covers a wide range of processes.It is usually the last stage of fabric procesing.The objective of finishing process is: • Modification of the fabric surface • Value addition • Improve aesthetics and functional ability There are mainly two types of finishing: • Mechanical Finishing: eg; Raising, Shearing, Calendering, Embossing, Shrinking etc. • Chemical Finishing: eg; Water repellent, Anti-pilling, Anti-microbial, Parchmentizing, Soil repellent finishing etc.