KENDRIYA VIDYALAYA SANGATHAN ,JAIPUR REGION

Practice Paper 02: 2024-25

CLASS:XII
SUB: CHEMISTRY (CODE:043)
Topics – 1. Solutions
Time Allowed: 40 min. Maximum Marks: 28

Section A (1mark)
1. Two beakers of capacity 500 ml were taken. One of these beakers, labelled as “A”, was filled with 400 ml
water whereas the beaker labelled “B” was filled with 400 ml of 2 M solution of NaCl. At the same
temperature both the beakers were placed in closed containers of same material and same capacity as
shown in Fig.

At a given temperature, which of the following statement is correct about the vapour pressure of pure
water and that of NaCl solution.
(a) vapour pressure in container (A) is more than that in container(B).
(b) vapour pressure in container (A) is less than that in container (B).
(c) vapour pressure is equal in both the containers.
(d) vapour pressure in container (B) is twice the vapour pressure in container (A).
2. Which of the following binary mixtures will have same composition in liquid and vapour phase?
(a) Benzene – Toluene (b) Water-Nitric acid
(c) Water-Ethanol (d) Chloroform-Ethanol
3. An azeotropic solution of two liquids has a boiling point lower than either of the two when it
(a) shows a negative deviation from Raoult’s law. (b) is a saturated solution
(c) shows no deviation from Raoult’s law. (d) shows a positive deviation from Raoult’s law.
4. Elevation of boiling point is inversely proportional to
(a) molal elevation constant (Kb) (b) molality (m)
(c) molar mass of solute(MB) (d) weight of solute (WB)

Section B ( 2 mark)
5. (a) What is the degree of dissociation for 0.1M Ba (NO3)2 if i(Van’t Hof factor) is 2.74 (1+1)
(b) Arrange the following solutions in increasing order of Van’t Hof factor.
0.1M CaCl2, 0.1M KCl , 0.1M C12H22O11 , 0.1 M Al2(SO4)3.

6. The boiling point of benzene is 353.23K. when 1.80 g of a non-volatile solute was dissolved in 90 g of
benzene, the boiling point is raised to 354.11K. Calculate the molar mass of the solute? Kb for benzene is
2.53 K Kg mol-1.

Section C ( 5 mark)
7. (i) What are isotonic solutions?
(ii) Identify which liquid will have a higher vapour pressure at 373 K if the boiling points of two liquids I
and II are 413 K and 453 K, respectively.
 (iii) Calculate the boiling point of solution when 2 g of Na2SO4 (Molar mass =142 g mol-1) was dissolved
in 50 g of water, assuming Na2SO4 undergoes complete dissociation. (Kb for water = 0.52 K kg mol-1)
OR
(a) When 2.56 g of sulphur was dissolved in 100 g of CS2, the freezing point lowered by 0.383 K. Calculate
the formula of sulphur (SX). (Kf for CS2 = 3.83 K kg mol–1, Atomic mass of Sulphur = 32 g mol–1).
(b) Blood cells are isotonic with 0.9% Sodium Chloride solution. What happens if we place blood cells in a
solution containing:
(i) 1.2% Common Salt solution?
(ii) 0.4% Table Salt solution?

8. (a) Write the name of colligative property which is used to find the molecular mass of Macromolecules?
(b) In non-ideal solution what type of deviation shows the formation of minimum boiling azeotropes.
(c) What happens when we place the blood cells in hypotonic solution? Give reason.
(d) A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in 500g of water.
This solution has a boiling point of 100.42°C. What mass of glycerol was dissolved to make this solution?
(Kb for water = 0.512 K kg mol–1)
OR
(a) Define the following terms:
(i) Ideal solution
(ii) Cryoscopic constant
(iii) Mole fraction
(b) 15.0 g of an unknown molecular material is dissolved in 450 g of water. The resulting solution freezes
at –0.34°C. What is the molar mass of the material? (Kf for water = 1.86 K kg mol–1)
9. (a) 0.6 mL of acetic acid 𝐶3𝐶, having density 1.06 g/mL, is dissolved in 1 litre of water. The depression in
freezing point observed for this strength of acid was 0.0205°C. Calculate the van’t Hof factor and the
dissociation constant of acid. (Kf= 1.86 K kg /mol)
(b) How does Raoult’s law become a special case of Henry’s law?
OR
(a)The vapour pressures of pure liquids A and B are 450 mm of Hg and 700 mm of Hg respectively at 350
K. Calculate the composition of the liquid mixture if total vapour pressure is 600 mm of Hg. Also find
the composition in the vapour phase.
(b) What are azeotropes? Give one example each of minimum boiling azeotropes and maximum boiling
azeotropes.

10. (a) Concentrated nitric acid used in the laboratory work is 68% nitric acid by mass in aqueous solution.
What should be the molarity of such a sample of acid if the density of the solution is 1.504 g mL-1 ?.
(b) (i)What will happen if blood cells are placed in saline water (hypertonic solution)?
(ii)Aquatic species are more comfortable in cold waters rather than in warm waters. Why?
(iii) Sprinkling of salt help in clearing the snow covered roads in hilly areas. Name the colligative property
involved in the process. (2+3)
OR
(a)Calculate the mass of a non-volatile solute (molar mass 40g mol-1) which should be dissolved in 114 g
octane to reduce its vapour pressure to 80%.
(b) What type of azeotropes are formed by non-ideal solution showing negative deviation from Raoult’s law?.
(c) Why 0.1 M KCl has a higher boiling point as compare to water, if measured using colligative properties?
(d) What will happen if the pressure applied on the solution side is more than osmotic pressure, when the
solvent and solution are separated by a semipermeable membrane?