Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_NUCLEUS JEE-MAIN Date: 21-12-2024
Time: 09:00AM to 12:00PM QMT-09 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point Pen
only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on the
Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 75 Questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Mathematics, Physics and Chemistry
having 25 Questions in each subject and subject having two sections.
(I) Section –I contains 20 Multiple Choice Questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
(II) Section-II contains 05 Numerical Value Type Questions.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the Nearest Integer
value (Example* i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and
less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted Question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
 SRI CHAITANYA IIT ACADEMY, INDIA 21-12-2024_Jr.Super60_NUCLEUS BT_Jee-Main_QMT-09_Q.P.
21-12-2024_Jr.Super60_NUCLEUS BT_Jee-Main_QMT-09_Test Syllabus

MATHEMATICS : TOPICS COVERED FROM 1ST APRIL TO 19TH DEC

PHYSICS : SYLLABUS COVERED FROM 01-04-2024 TO 20-12-2024
CHEMISTRY : SYLLABUS COVERED FROM 01-04-2024 TO 20-12-2024

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 SRI CHAITANYA IIT ACADEMY, INDIA 21-12-2024_Jr.Super60_NUCLEUS BT_Jee-Main_QMT-09_Q.P.
MATHEMATICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which
ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
 1  cos x sin 2 x
 . , x
1. Let 
f  x  
 
   x 2 ln 1   2  2 x  x 2 is continuous at x   , then  is equal to

 , x 

1 1
1) 1 2) -1 3) 4)
2 4
2
2. If a  R and the equation 3  x   x   2  x   x    a 2  0 (where  x denotes the
greatest integer function  x ) has no integral solution, then all possible values of ‘a’ lie in the
interval
1)  2, 1 2)  , 2    2,   3)  1,0    0,1 4) 1,2 
3. Match the following
Column - I Column - II
A) A line from the origin meets the lines x  2  y  1  z  1 and p) -4
1 2 1
8
x
3  y  3  z 1 at P and Q respectively. If length PQ = d, then d 2 
2 1 1
B) The value of x satisfying, 3
tan 1  x  3  tan 1  x  3  sin 1   are q) 0
5
C) Non-zero vectors a , b and c satisfy a .b  0,  b  a  . b  c   0 and r) 4

2 b  c  b  a . If a   b  4c , then possible value of  is/are

D) Let f be the function on   ,   given by f  0   9 and s) 5
sin kx
f ( x)  for x  0 is continues at x  0 then k  1  .
x
sin  
k
t) 6

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1) (A) - t; (B) - p, r; (C) - p; (D) - r 2) (A)- t; (B)-p, r; (C) -q; (D) - r
3) (A) -t; (B) -q, r (C) -p, s; (D) -q, r 4) (A) -q, r, t; (B) -q, r; (C) -p; (D) -r
 
  2 sin x;   x  3
2

 p cos x  q; 3   x  2
4. If f  x    2 is continuous in  ,3  , then the number of points at

 cos x  2; 2  x  5 
 2
 
 r sin x; 5  x  3
 2
which f  x  is not differentiable is/are
1) 4 2) 2 3) 3 4) 1
 
5. Let O be the origin. Let OP  xi  yj  k and OQ  iˆ  2 ˆj  3xkˆ; x, y  R, x  0 be such
ˆ ˆ ˆ
   
that PQ  20 and the vector OP is perpendicular to OQ . If OR  3iˆ  zjˆ  7 kˆ; z  R
 
, is coplanar with OP and OQ , the value of x 2  y 2  z 2 is equal to____________

1) 7 2) 9 3) 2 4) 1
6. The number of values of  in  0,2  for which 2sin 3   7sin 2   7sin   2
is ____________
1) 3 2) 1 3) 6 4) 4
7. Let f  x   x5  2 x3  3x  1; x  R , and g  x  be a function such that g  f  x    x for
g 7
all x  R . Then is equal to ____________
g1  7 
1) 14 2) 42 3) 7 4) 1

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 SRI CHAITANYA IIT ACADEMY, INDIA 21-12-2024_Jr.Super60_NUCLEUS BT_Jee-Main_QMT-09_Q.P.

x3 sin x cos x
d3
8. Let f  x   6 1 0 , where p is a constant, then  f  x  at x  0
dx3
p p2 p3
is ____________
1) p 2) p  p 2 3) p  p 3 4) 0

9.     
If the value of 1  tan1o 1  tan 2o 1  tan 3o ..... 1  tan 44o 1  tan 45o  is 2 ,
then the sum of the digits of the number of  is
1) 3 2) 6 3) 5 4) 4
2 x  sin 1 x
10. The value of f  0  , so that the function, f  x   is continuous at each point
2 x  tan 1 x
in its domain is ____________
1 1 2 2
1) 2) 3) 4)
3 3 3 3
 1 2 3 4 
11. The sum of n terms of           is ____________
1.3 1.3.5 1.3.5.7 1.3.5.7.9 
1 1  1 1 
1) 1   2) 1 
2  1.3.5      2n  1  2  2.4.6  2n 
1 1  1 1 
3) 1   4) 1 
2  1.3.5     2n  1  2  2.4.6  2n 


12. If x, y, z are in arithmetic progression and tan 1 x, tan 1 y and tan 1 z are also in
Arithmetic progression, then
1) x  y  z 2) x  y   z
3) x  1, y  2, z  3 4) x  2, y  4, z  6

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 SRI CHAITANYA IIT ACADEMY, INDIA 21-12-2024_Jr.Super60_NUCLEUS BT_Jee-Main_QMT-09_Q.P.
  tan  cot  tan 
13. Let    0,  and t1   tan   , t2   tan   , t3   cot   , and
 4
cot 
t4   cot   then
1) t1  t2  t3  t4 2) t4  t3  t1  t2
3) t3  t1  t2  t4 4) t2  t3  t1  t2

1 sin 1 x cos 1 x  2 

14. If 0  x  and  , then the value of sin   is ____________
2       

1) 4 1  x2 1  2x2  2) 4 x 1  x2 1  2x2 

3) 2 x 1  x 2 1  4 x 2  4) 4 1  x2 1  4x2 
   
 1  1  x2  1   1  2 x 1  x2  1
15. The derivative of tan with respect to tan at x  is;
 x   1  2 x2  2
   
2 3 3 2 3 3
1) 2) 3) 4)
5 12 3 10
2
16. The line  k  1 x  ky  2k 2  2  0 passes through the point  m, n  for all real values of
k, then
m m 1
1) m  n  2 2) m  n  6 3) 2 4) 
n n 2
17. Let A be a non singular, symmetric matrix of order three such that A  adj. A  AT  , then

which of the following is true ?

A A
1) A1  2) adj. A1   64 A 3) A1  32 A 4) adj. A1  
16 1024

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 SRI CHAITANYA IIT ACADEMY, INDIA 21-12-2024_Jr.Super60_NUCLEUS BT_Jee-Main_QMT-09_Q.P.
18. Let  ,   be an ordered. Pair of real numbers satisfying the equation,

x 2  4 x  4 y 2  3  0 . If the maximum and minimum, value of a 2   2 are l and s

ls
respectively, then the value of is equal to ____________.
ls
1
1) 2) 2 3) 1 4) 6
2
1 0 0  1 0 0 
19.
   
If A  0 1 1 , I  0 1 0 and A1 
   
1 2
6
A  cA  dI   then sum of values of c
0 2 4  0 0 1 
and d is
1) 7 2) 11 3) 4 4) 5
20. Let R be the set of all real numbers.
   
Statement - I:- The function f :  ,   R defined by f  x   sec x  tan x is a one
 2 2
one function.

Statement - II:- The function f :  0,    R defined by f  x   x 2 is a one-one function

1) Both statement-I and statement-II are true

2) Both statement-I and statement-II are false
3) statement-I is true but statement-II is false
4) statement-I is false but statement-II is true
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

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 SRI CHAITANYA IIT ACADEMY, INDIA 21-12-2024_Jr.Super60_NUCLEUS BT_Jee-Main_QMT-09_Q.P.

x2  x x 1 x2
21. If 2 x 2  3 x  1 3x 3x  3  ax  12, then a  ____________
x2  2 x  3 2x 1 2x 1

22. The number of solution of cos 2 x  cos2 2 x  2 in  0, 20 is equal to ____________

 1  1 
sin  x  4  .tan   x  4 then, f x is non
23. Consider the function, f  x     x4  
0 x4


 x2 
differentiable at x then the value of   is ---------- .  is G.I .F 
 3 

y z y z
24. Two lines L1 : x  5   and L2 : x     are coplanar then  can
3   2 1 2  

p  3q  5r
take values: p, q and r . Then the value of (where p  q  r )
2

is ____________

25. The set of all possible values of  in the interval  0,   for which the points (1, 2) and

 sin  ,cos  lie on the same side of the line x  y  1 is  0,  then the value of 2a
 a
is _________

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 SRI CHAITANYA IIT ACADEMY, INDIA 21-12-2024_Jr.Super60_NUCLEUS BT_Jee-Main_QMT-09_Q.P.
PHYSICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which
ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

26. A particle starts from rest with a constant acceleration of 4m / s 2 along a straight line.
It’s average velocity in third second of its motion (in m/s) is
1) 12 2) 6 3) 3 4) 10
27. A ball is thrown vertically upward with certain velocity from the base of a tower and an another
ball is released from the top of the tower simultaneously. They cross each other at the middle
of tower. The magnitude of the velocity of up-going ball at the time of crossing is
( g  10m / s 2 )
1) 10 m/s 2) 5 m/s 3) 0 4) 2.5 m/s
28. Statement – 1: A system of net non-zero mass can have non – zero kinetic energy without a
net momentum.
Statement – 2: A system of net non-zero mass can have non-zero momentum without a net
kinetic energy.
1) Both the statements are correct
2) Statement – 1 is correct, Statement – 2 is incorrect
3) Statement – 1 is incorrect, Statement – 2 is correct
4) Both the statements are incorrect.
29. A thin rod of length  and mass m moves on a smooth horizontal plane at a velocity V0 in
the direction of its length. The end of the rod hits the end of a second rod of the same mass
and length, which is initially at rest, perpendicular to the first rod. The rods stick together
and the angle between them remains  / 2. The angular speed of the system about the centre
of mass will be

3 V0 3 V0 3 V0
1) 2) 3) 4) 0
5  4
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 SRI CHAITANYA IIT ACADEMY, INDIA 21-12-2024_Jr.Super60_NUCLEUS BT_Jee-Main_QMT-09_Q.P.
30. Assertion (A) : If there is no external torque on a body about its centre of mass, then the
velocity of the centre of mass remains constant.
Reason (R) : The linear momentum of an isolated system remains constant.
1) Both A and R are correct and R is the correct explanation of A
2) Both A and R are correct but R is not the correct explanation of A
3) A is true but R is false
4) A is false but R is true.
31. A block of mass 10kg is released from the top of an inclined plane as shown in the figure. The
maximum compression in the spring when the block hits the spring is (approximately)
( g  10m / s 2 , AB  10m BC  2m (rough) K  100 N / m

1) 1m 2) 6m 3) 2m 4) 5m
32. A cylindrical vessel of height ‘H’ and base area ‘A’ is filled with water. The vessel is placed
vertically on a horizontal plane. Its mouth is open. It has an orifice of area ' A0 ' ( A0  A).
The orifice is opened near the bottom of the vessel. Neglect the viscosity of water. The time
during which total mass of water comes out of the vessel will be
2 2
A0 2 H A 2H  A0  2H  A 2g
1) 2) 3)   4)  
A g A0 g  A g  A0  H
33. A small droplet of density ‘d’ is floating exact half immersed in a liquid of density ‘  ’
and surface-tension ‘S’. The radius of the droplet is (assume that the surface tension applies
an upward force on the droplet)
2S 3S S S
1) 2) 3) 4)
3(d   ) g (2d   ) g (d   ) g (d   ) g

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 SRI CHAITANYA IIT ACADEMY, INDIA 21-12-2024_Jr.Super60_NUCLEUS BT_Jee-Main_QMT-09_Q.P.
34. A uniform elastic plank moves over a smooth horizontal plane due to a constant force ' F0 '
distributed uniformly over the end face. The area of the end face is ‘A’ and Young’s
modulus of the material is ‘Y’. The strain produced in the plank in the direction of the force
is

F0

F0 F0 2F0 F0
1) 2) 3) 4)
2YA YA YA 4YA
35. Match List – I with List – II. List – I has rigid body while List – II has moment of Inertia
(M.I). Symbols have usual meaning.
List – I List – II
a) M.I. of a solid sphere about any tangent (p) 1 2
MR
2
b) M.I. of a circular ring about its diameter (q) 1
M R2
4
c) M.I. of a spherical shell about any tangent (r) 7
M R2
5
d) M.I. of a circular disc about any diameter (s) 5
M R2
3
Choose the correct answer from the options
1) a – p, b – q, c – s, d – r 2) a – q, b – p, c – r, d – s
3) a – q, b – s, c – p, d – r 4) a – r, b – p, c – s, d - q
36. Two identical springs each of spring constant K  100 N / m are joined as shown in the
figure. A mass of 20kg is tied as shown. The system is in equilibrium. Now, the spring – 2 is
cut at point ‘B’. The acceleration of the suspended mass just after cutting the spring is
(take   30 , g  10m / s 2 )

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 SRI CHAITANYA IIT ACADEMY, INDIA 21-12-2024_Jr.Super60_NUCLEUS BT_Jee-Main_QMT-09_Q.P.
A
  C

K K
spring 1
spring 2

B
m

1) 5 m / s 2 at 30 w.r.t. horizontal 2) 2.5 m / s 2 at 60 w.r.t. vertical

3) 10 m / s 2 at 60 w.r.t. vertical 4) 10 m / s 2 at 60 w.r.t. horizontal

37. Two masses ‘A’ and ‘B’ joined by a light string are placed as shown. The pulley is light. The
force of friction between the mass A and the rough inclined plane is

(given mA  2mB ; mB  3kg ,   30 ,   0.5)

1) 15 N up the incline 2) Zero

3) 15 N down the incline 4) 7.5N up the incline.
38. A system of two blocks of masses m1 and m2 connected by a light spring constant K rest on a
smooth horizontal plane as shown in figure. The block of mass m2 is pushed by a small
distance x to the left and then released. The velocity of the centre of mass of the system after
the block of mass m1 breaks of the wall will be {no elastic deformation at the wall}.

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x K m2 K
1) ; 2) x
(m1  m2 ) m2
m1 x K m2 x K
3) ; 4)
(m1  m2 ) m2 (m1  m2 ) m1
39. Two identical iron spheres are shown. The sphere ‘A’ is lying on a thermally insulating
plate while the sphere ‘B’ is suspended from an insulated thread. Both the spheres have
given equal amount of heat. They have same initial temperature.

Statement 1: The gravitational potential energy of both the spheres increases.

Statement – 2: The temperature of the suspended sphere ‘B’ will be higher than that of the
sphere ‘A’:
1) Both the statements are correct
2) Statement – 1correct, statement – 2 is incorrect
3) Statement – 1 is incorrect, statement – 2 is correct
4) Both the statements are incorrect.

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 SRI CHAITANYA IIT ACADEMY, INDIA 21-12-2024_Jr.Super60_NUCLEUS BT_Jee-Main_QMT-09_Q.P.
40. Assertion (A): According to the law of equipartition of energy, internal energy of an ideal gas
at a given temperature, is equally distributed in translational and rotational kinetic energies.
Reason (R): Rotational kinetic energy of a monoatomic gas is zero
1) Both A and R are correct and R is the correct explanation of A
2) Both A and R are correct but R is not the correct explanation of A
3) A is true but R is false
4) A is false but R is true.
41. The thermodynamic process A  B as shown on P-V diagram for one mole of an ideal gas
2/3 T2
obeys the law P V   constant. If V2  8V1 then the ratio is
T1
P
A

B
V
V1 V2
1 1
1) 2) 3) 2 4) 5
2 3
42. Two ends of a conducting rod of varying cross-section are maintained at 100o C and 0o C
respectively. There are two sections marked in the rod ' PQ ' and ' RS ' of same thickness. In
steady state.

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1) Temperature difference across PQ and RS are equal
2) Temperature difference across PQ is less than that of across RS
3) Temperature difference across PQ is greater than that of across RS
4) Temperature difference may be equal or different depending on the thermal conductivity
of the rod.
43. For a particle in simple harmonic motion, the graph of velocity as a function of
displacement is
1) a helix 2) an ellipse 3) a parabola 4) a straight line
44. A non- conducting sphere of radius ‘R’ and a uniform volume charge density ‘  ’ has a

spherical cavity of radius ‘b’. A position vector a locates the centre of the cavity with
respect to the centre of the sphere. The electric field at point ‘P’ inside the cavity is

x
x 
x r p
x o a bc
R
x x x
x x
 
a a
1) ; Uniform in cavity 2) ; Non- uniform in cavity
2 0 3 0
 
a a
3) ; non – uniform in cavity 4) ; uniform in cavity
0 3 0
45. An infinitely long sheet of charge of uniform surface charge density ' ' passes through a
spherical shell of radius ‘R’ at a perpendicular distance ‘d’ from the centre of the shell (d<R).
The electric flux through the spherical shell is

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x
x
x
d
xx O
x R

 (R2  d 2 )  ( R 2  d 2 )  ( R 2  d 2 ) 2  ( R 2  d 2 )
1) 2) 3) 4)
0 2 0 0 3 0
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
46. Two small blocks of masses m1 and m2 interconnected by a light spring rest on a smooth
horizontal plane. The masses are set in motion with initial velocities V1 and V2 respectively
whose directions are mutually perpendicular and lie in the same horizontal planes shown in
the figure. The total K.E of this system in the frame of the centre of mass of the system will
m1m2
be ( x   J . Find value of x. (Take   , m1 & m2 in kg , v1  1 m / s, v2  3m / s )
 m1  m2 

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1
47. A wire of cross sectional area ‘A’ modulus of elasticity  1011 N / m2 and length 2m is
2
stretched between two rigid supports. When the mass M (2kg) is suspended at the middle of
1
the wire, it sags lower from its original position making angle   radian
100
on the points of support. The value of A is _____ n  104 m2 . Find the value of n

(Consider x  l ) g  10m / s
2

2l

x

M
48. 10 divisions on the main scale of a venier calliper coincide with 11 divisions on the vernier
x
scale. If each division the main scale is of 6 units, the least count of the instrument is .
11
Find the value of x:
49. A sonometer wire of resonating length 80cm has a fundamental frequency of 800Hz when
kept under some tension. The resonating length of the wire with fundamental frequency of
1600 Hz under the same tension ……cm.
50. Six equal point charges are placed at the corners of a regular hexagon. This hexagon forms
the base of a pyramid whose slant edge joining the apex is equal to the diagonal of the hexagon.
Each point charge produces an electric field of magnitude ' E0 ' at the apex of the pyramid.

The magnitude of the net electric field at the apex is nE0 3. Find the value of n.

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CHEMISTRY Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which
ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
51. Read the following statements
I. If internuclear axis is taken to be in the z-direction, then both  2 p z and  * 2 p z
molecular orbitals are symmetrical around the bond axis.
II. Each molecular orbital (bonding or anti-bonding) contains positive and negatively
charged regions and are denoted by '+' and '-' signs respectively.
III. According to MOT, both C2 and O2 molecules possess a bond order 'two' - with one 
bond and one  -bond.
IV. According to MOT, C2 molecule is diamagnetic, where as O2 molecule is
paramagnetic.
Among the above statements, the correct statement(s) is/are
1) I only 2) I and III only 3) I and IV only 4) All of the above
52. Given below are two statements. One is labeled as Assertion (A) and the other is labeled as
Reason(R).
Assertion (A) :- Boron is unable to form BF63 ion, where as aluminum can form

AlF63 ion.
Reason (R) :- Maximum covalence of Boron is only 4 due to non availability of d - orbital.
Al has vacant d - orbital and hence can exhibit a covalency of 6.
In the light of the above statements, choose the most appropriate answer.
1) Assertion (A) is correct, but Reason (R) is not correct
2) Both Assertion (A) and Reason (R) are correct, but (R) is not a correct explanation for (A)
3) Both (A) and (R) are not correct
4) Both (A) and (R) are correct, and (R) is the correct explanation for (A)
53. Identify the incorrect statement among the following about group 14 elements
1) Sn(II) is reducing where as Pb (IV) is oxidizing in nature
2) Both CO and GeO are neutral oxides
3) Tin has lowest melting point in the group.
4) Lead is unaffected by water due to a protective oxide film
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54. List I contains the electronic configurations of some octahedral complexes and List II contains
their crystal field stabilization energy values. Match List I and List II
List I List II
Electronic configuration of octahedral fields CFSE
(A) 3 2
t2 g , eg (i) 0.80

(B) (ii) Zero

t25g , eg 0
(C)
t22g , eg 0 (iii) 1.2 0

(D)
t23g , eg 0 (iv) 2.0 0

Select the most appropriate answer from the options given below
1) A   iv  , B   ii  , C   i  , D   iii 
2) A   ii  , B   iv  , C   i  , D   iii 
3) A   iii  , B   i  , C   iv  , D   ii 
4) A   i  , B   iii  , C   ii  , D   iv 
55. Calculated magnetic moments (spin - only values) for the species
4 2
 Mn  CN   ,  Ni  NH 3   and  NiCl4 2 are respectively
 6  6
1) 4.89, 5.85 and 1.73 BM 2) 1.73, 2.83 and 2.83 BM
3) 1, 2 and 0BM 4) 2.83, 3.90, and 4.90 BM
56. What is the shortest wave length that can be recorded in Balmer series of He  ion? (At No.
of He  2 )
R 4 1 9
1) 2) 3) 4)
9 R R 4R
57. The pair of elements having dissimilar polarizing powers of their cations is
1) Mg , Li 2) Na, Rb 3) B, Si 4) Al , Be

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58. Statement - I :- The enthalpy of formation of gaseous oxygen molecule at 298K and a
pressure of 1 bar is zero.
Statement - II :- The entropy of formation gaseous oxygen molecule under the same
conditions is zero.
1) Both statements I and II are true
2) Statement I is false, statement I is true
3) Statement I is true, statement II is false
4) Both statements I and II are false
59. A 100mL solution of 0.2M weak acid HA is being titrated with 0.2M NaOH solution. At
equivalence point, pH of the mixture is found to be 8.7. What is the pH of the solution at
the point when 75mL of NaOH solution is added to the weak acid in the titration?
(Take log 3 = 0.48)
1) 4.88 2) 4.40 3) 5.80 4) 5.68
60. A 10mL solution which is 8%(w/v) in NaOH is diluted to 100mL. 50mL of this dilute alkali
then quantitatively reacts with excess of NH 4Cl . What is the mass of ammonia gas liberated?

(Molar masses : NaOH  40 gmol 1 , NH 3  17 gmol 1 )

1) 6.8g 2) 3.4g 3) 1.7g 4) 0.17g
61. 6.023  10 21 molecules are present in 1g of a substance 'X'. The molarity of a solution
containing 5g of the substance X in 2L solution is
1) 0.25M 2) 0.50M 3) 0.025M 4) 0.04M
62. Two complexes (A) K 3 CoF6  and (B) Co  NH 3   Cl3 are green and yellow colored
 6
respectively. The INCORRECT statement regarding them, is:
1) Crystal field splitting   o  is less in (A) than (B)
2) (A) is an outer orbital complex and (B) is inner orbital complex
3) (A) is paramagnetic and (B) is diamagnetic
4) (A) is low spin complex ,but (B) is high spin complex
63. At 600K, 2 moles of NO are mixed with 1 mole of O2 and the equilibrium
2 NO  g   O2  g   2 NO2  g  is reached with a total pressure of 1atm. Analysis of the
system shows that 0.6moles of oxygen are present at equilibrium. The equilibrium constant
(kp)of the reaction is
1) 0.74 2) 1.93 3) 2.89 4) 5.28
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64. In which of the following structures C-3 is not a chiral centre?
CH3 CH3 CH3 CH3

H OH H Br Br H Br H

H Br H OH H OH HO H

H Br H Br Br H H Br

CH3 CH3 CH3 CH3

1) 2) 3) 4)
65. Which of the following statement is incorrect?
1) Ethanol and water can’t be separated from each other completely by simple distillation
method as they form azeotropic mixture.
2) Naphthalene can be separated from benzoic acid by sublimation
3) Impure glycerin can be purified by steam distillation
4) Ortho-nitrophenol can be purified by steam distillation
66. Which of the following compound has highest dipole moment?

1) 2) 3) 4)
67. How many mono bromo derivatives (excluding stereoisomers) are possible for
2-methyl pentane
1) 3 2) 2 3) 5 4) 4
68. Which of the following reactions results in the formation of a pair of diastereomers?

1) 2)

3) 4)
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69. Which of the following compound on reductive ozonolysis gives 3-oxo-hexane di
carbaldehyde

1) 2) 3) 4)
70. The major product obtained from the following reaction is
Hg 2 / H 
H3C C C CHO  
H 2O

1) 2)

3) 4)

SECTION-II (NUMERICAL VALUE TYPE)

This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
71. When potassium chromate salt is dissolved in an aqueous solution of a strong acid,
a compound X is formed. Oxidation state of the transition metal in compound 'X' is ________
72. 
The equilibrium CaCO3  s   CaO  s   CO2  g  k p  5atm at 819 K is reached at 
819K in two initially evacuated vessels are shown below
22.4L

5.6L
CO2
CO2

819K 819K
CaCO3

The ratio of masses of CO2 produced at equilibrium (at 819K) in the two vessels is:
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73. For a gaseous reaction, k p  50 at 300K. standard enthalpy change H

o
 
of the reaction

is 730J. What is the standard entropy change S

o
 
of the reaction at 300K
(in joul K-1 mol-1) ? (Take R = 8.3JK-1 mol-1 , ln 10 = 2.3, log 5 = 0.7)
74. How many of the following acids reacts with NaHCO3 and liberates CO2 ?
COOH SO3H
O
O

I) II) H  C  OH III) IV) CH 3  C  OH

75. How many of the following can not give Friedel-Craft reaction?

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