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Assignment of Lowering of Vapour pressure

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Assignment of Lowering of Vapour pressure

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hsbohra653
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© © All Rights Reserved
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Assignment of Relative Lowering of Vapour

Pressure
1. How is vapour pressure of solvent affected when a non-
volatile solute is dissolved in it?

2. Derive the relationship between relative lowering of vapour


pressure and molar mass of the solute.

Q.3 Vapour pressure of water at 20 °C is 17.5 mm Hg.


Calculate the vapour pressure of water at 20 °C when 15 g of
glucose (Molar mass = 180 g mol-1) is dissolved in 150 g of
water.

Q.4 A solution is prepared by dissolving 5 g of non-volatile


solute in 95 g of water. It has a vapour pressure of 23.375 mm
Hg at 25°C. Calculate the molar mass of the solute, (vapour
pressure of pure water at 25 °C is 23.75 mm Hg).
5. Vapour pressure of water at 20 °C is 17.5 mm Hg.
Calculate the vapour pressure of water at 20 °C when 15 g of
glucose (Molar mass = 180 g mol-1) is dissolved in 150 g of
water.

6. A solution is prepared by dissolving 5 g of non-volatile


solute in 95 g of water. It has a vapour pressure of 23.375 mm
Hg at 25°C. Calculate the piolar mass of the solute, (vapour
pressure of pure water at 25 °C is 23.75 mm Hg).

7.Vapour pressure of water at 20 °C is 17.5 mm Hg. Calculate


the vapour pressure of water at 20 °C when 15 g of glucose
(Molar mass = 180 g mol-1) is dissolved in 150 g of water.

8. A solution is prepared by dissolving 5 g of non-volatile


solute in 95 g of water. It has a vapour pressure of 23.375
mm Hg at 25°C. Calculate the piolar mass of the solute,
(vapour pressure of pure water at 25 °C is 23.75 mm Hg).

9. A solution is prepared by dissolving 10 g of non-volatile


solute in 200 g of water. It has a vapour pressure of 31.84 mm
Hg at 308 K. Calculate the molar mass of the solute. (Vapour
pressure of pure water at 308 K = 32 mm Hg)
Q.10 What would be the molar mass of a compound if 6.21 g
of it dissolved in 24.0 g of chloroform forms a solution that
has a boiling point of 68.04 °C? The boiling point of pure
chloroform is 61.7 °C and the boiling point elevation
constant, for chloroform is 3.63 °C/m.
Q.11 Find the boiling point of a solution containing 0.520 g of
glucose (C6H1206) dissolved in 80.2 g of water. [Given: Kb for
water = 0.52 K/m]
Q.12 Calculate the mass of compound (molar mass = 256 g
mol-1) to be dissolved in 75 g of benzene to lower its freezing
point by 0.48 K (Kj = 5.12 K kg mol-1).
13. A solution is prepared by dissolving 10 g of non-volatile
solute in 200 g of water. It has a vapour pressure of 31.84 mm
Hg at 308 K. Calculate the molar mass of the solute. (Vapour
pressure of pure water at 308 K = 32 mm Hg)

14. Define an ideal solution and write one of its


characteristics.
15. At 25 °C the saturated vapour pressure of water is 3.165
kPa (23.75 mm Hg). Find the saturated vapour pressure of a
5% aqueous solution of urea (carbamide) at the same
temperature. (Molar mass of urea = 60.05 g mol-1)
Marking Scheme of Assignment of Relative Lowering
of Vapour Pressure
1. How is vapour pressure of solvent affected when a non-volatile
solute is dissolved in it?
Answer: Vapour pressure of solution decreases because surface consists
of both solute and solvent molecules. The escaping tendency of solvent
into vapours decreases.

2. Derive the relationship between relative lowering of vapour


pressure and molar mass of the solute.
Answer:
Q.3 Vapour pressure of water at 20 °C is 17.5 mm Hg.
Calculate the vapour pressure of water at 20 °C when 15 g of
glucose (Molar mass = 180 g mol-1) is dissolved in 150 g of
water.
Q.4 A solution is prepared by dissolving 5 g of non-volatile solute in
95 g of water. It has a vapour pressure of 23.375 mm Hg at 25°C.
Calculate the molar mass of the solute, (vapour pressure of pure
water at 25 °C is 23.75 mm Hg).

5. Vapour pressure of water at 20 °C is 17.5 mm Hg. Calculate the


vapour pressure of water at 20 °C when 15 g of glucose (Molar
mass = 180 g mol-1) is dissolved in 150 g of water.
Answer:

6. A solution is prepared by dissolving 5 g of non-volatile solute in


95 g of water. It has a vapour pressure of 23.375 mm Hg at 25°C.
Calculate the piolar mass of the solute, (vapour pressure of pure
water at 25 °C is 23.75 mm Hg).
Answer:
7. Vapour pressure of water at 20 °C is 17.5 mm Hg. Calculate the
vapour pressure of water at 20 °C when 15 g of glucose (Molar
mass = 180 g mol-1) is dissolved in 150 g of water.
Answer:

8. A solution is prepared by dissolving 5 g of non-volatile solute in 95


g of water. It has a vapour pressure of 23.375 mm Hg at 25°C.
Calculate the piolar mass of the solute, (vapour pressure of pure
water at 25 °C is 23.75 mm Hg).
Answer:
Q.9 A solution is prepared by dissolving 10 g of non-volatile
solute in 200 g of water. It has a vapour pressure of 31.84 mm
Hg at 308 K. Calculate the molar mass of the solute. (Vapour
pressure of pure water at 308 K = 32 mm Hg)
Q.10 What would be the molar mass of a compound if 6.21 g of it dissolved in 24.0
g of chloroform forms a solution that has a boiling point of 68.04 °C? The boiling
point of pure chloroform is 61.7 °C and the boiling point elevation constant, for
chloroform is 3.63 °C/m.

Answer

Q.11 Find the boiling point of a solution containing 0.520 g of glucose


(C6H1206) dissolved in 80.2 g of water. [Given: Kb for water = 0.52 K/m]

Answer

Q.12 Calculate the mass of compound (molar mass = 256 g mol-1) to


be dissolved in 75 g of benzene to lower its freezing point by 0.48 K
(Kj = 5.12 K kg mol-1).
Answer:

13. A solution is prepared by dissolving 10 g of non-volatile solute in


200 g of water. It has a vapour pressure of 31.84 mm Hg at 308 K.
Calculate the molar mass of the solute. (Vapour pressure of pure
water at 308 K = 32 mm Hg)
Answer:

14. Define an ideal solution and write one of its characteristics.

15. At 25 °C the saturated vapour pressure of water is 3.165 kPa (23.75


mm Hg). Find the saturated vapour pressure of a 5% aqueous solution
of urea (carbamide) at the same temperature. (Molar mass of urea =
60.05 g mol-1)
Answer:

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