TERMINAL I EXAMINATION

11
CHEMISTRY A
70 3hrs 13\09\24
S NO Sec - A MARKS
ANSWER ALL QUESTIONS. EACH QUESTIONS HAVE ONE MARK.
1 Ozonolysis of ethene gives- 1
a) None of these
b) CHO-CHO
c) CH3CHO
d) HCHO
2 Arrange the halogens F2, Cl2, Br2, I2, in order of their increasing reactivity with alkanes. 1
a) Br2<Cl2<F2<I2
b) F2<Cl2<Br2<I2
c) Br2<I2<Cl2<F2
d) I2<Br2<Cl2<F2
3 Which branched chain isomer of the hydrocarbon with molecular mass 72u gives only one 1
isomer of monosubstituted alkyl halide?
a) Tertiary butyl chloride
b) Neohexane
c) Neopentane
d) Isohexane
4 Hydrocarbon which is liquid at room temperature is 1
a) Butane
b) Propane
c) Ethane
d) pentane
5 Phenol on heating with NaNO2 and a few drops of cone, H2SO4 gives- 1
a) p - Nitrosophenol
b) m - Nitrosophenol
c) o - Nitrophenol
d) p - Nitrophenol
6 An olefin on reductive ozonolysis gives only ethanal as the major product. Name of olefin. 1
a) But-1-ene
b) Propene
c) Ethene
d) But-2-ene
7 Isomerization of n-hexane on heating with anhydrous AlCl3 and HCl gas gives-. 1
a) 2-methylpentane
b) 3-methylpenatane
c) 2-methylhexane
d) Mixture of 2-methylpentane and 3-methylpentane
8 A dibromo derivate of an alkane reacts with sodium metal to form an alicyclilc 1
hydrocarbon. The derivative is .
a) 2,2-dibromobutane
b) 1,1-dibromopropane
c) 1,4-dibromobutane
d) 1,2-dibromoethane
9 The position of double bond in alkenes can be located by; 1
a) Hydrogenatin of oil
b) Ozonolysis
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SRI AUROBINDO MIRA UNIVERSAL / G11 /CHEMISTRY /TERMINAL I EXAMINATION
 c) Photolysis
d) Hydration
10 Some meta-directing substituents in aromatic substitution are given. Which one is most 1
deactivating?
a) -C = N
b) -SO3H
c) -COOH
d) -NO2
11 The first fraction obtained during the fractionation of petroleum is: 1
a) Gasoline
b) Diesel Oil
c) Hydrocarbon Gases
d) Kerosene Oil
12 The catalyst used in Friedel - Crafts reaction is 1
a) Aluminium Chloride
b) Anhydrous Aluminium Chloride
c) Ferric Chloride
d) Copper
13 Which of the following compounds will exhibit cis-trans isomerism? 1
a) Butanol
b) 2- Butyne
c) 2- Butenol
d) 2- Butene
14 Geometrical isomers differ in- 1
a) Position of functional group
b) Position of atoms
c) Spatial arrangement of atoms
d) Length of carbon chain
15 Which of the following is a Bayer’s reagent? 1
a) The neutral solution of HCL
b) An alcoholic solution of sodium carbonate
c) An acidic solution of potassium hydroxide
d) An aqueous solution of potassium permanganate
16 Which is the intermediate conformation between eclipsed and staggered? 1
a) Staggered
b) Skew
c) Eclipse
d) Newman
Sec - B
ANSWER ALL QUESTIONS. EACH QUESTIONS HAVE TWO MARKS.
17 How would you convert ethene to ethane molecule? 2
18 How is alkene produced by vicinal dihalide? 2
19 How will you distinguish between propene and propane? 2
20 How will you distinguish between acetylene and ethylene? 2
21 How will you convert ethanoic acid into ethene? 2
Sec - C
ANSWER ALL QUESTIONS. EACH QUESTIONS HAVE THREE MARKS.
22 Write structures of different chain isomers of alkanes corresponding to the molecular 3
formula C6H14. Also, write their IUPAC names.
23 In the presence of peroxide, addition of HBr to propene takes place according to Anti- 3
Markovnikov’s rule but peroxide effect is not seen in the case of HCl and HI. Explain.
24 Explain Wurtz reaction with an example. 3
25 a) How will you distinguish between Ethene and benzene? 3
b) What is Lindlar’s catalyst? Give its use.
26 Define substitution reactions. Why do benzene undergo substitution reactions even though 3

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 they contain doublebonds?
27 When Compound A heating it will give compound B and CO2. compound B react with 3
coke it give Compound C. C is used for ripening of mango and it will react with water will
give compound D. write compound A B C and D
28 Write the cyclic polymerisation reaction of alkynes. 3
Sec - C
ANSWER ALL QUESTIONS. EACH QUESTIONS HAVE FOUR MARKS.
29 Explain the behaviour of acidic nature in alkynes. 4
30 What are the geometrical isomers are present in but 2 ene and explain stability and melting 4
point of them
Sec - E
ANSWER ALL QUESTIONS. EACH QUESTIONS HAVE FIVE MARKS.
31 Assign structures for the following: 2
i. A hydrocarbon ‘Y’ decolourises bromine water. On ozonolysis it gives 3-methyl butanal
and formaldehyde. Give the name of the compound.
ii.
iii. A hydrocarbon (Z) has molecular formula C8H10. It does not decolourise bromine water
and is oxidised to benzoic acid on heating with K2Cr2O7. It can also have three other
isomers A, B and C. Write the structures of Z, A, B and C.
32 i. Draw cis and trans isomers of but-2-ene. Which isomer will have higher boiling point 3
and why?
ii. Name the simplest alkyne and give it uses. 2
33 Write IUPAC name of the products obtained by additiion reactions of HBr to 3 Methyl 5
pent 2 ene in the presence of peroxide and in the absence of per oxide with mechanism.

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SRI AUROBINDO MIRA UNIVERSAL / G11 /CHEMISTRY /TERMINAL I EXAMINATION